JP2015504069A - エタノールへの直接発酵に好適な未反応の糖類の回収とともに、糖類からｈｍｆおよびｈｍｆ誘導体を製造する方法 - Google Patents

エタノールへの直接発酵に好適な未反応の糖類の回収とともに、糖類からｈｍｆおよびｈｍｆ誘導体を製造する方法 Download PDF

Info

Publication number
JP2015504069A
JP2015504069A JP2014551244A JP2014551244A JP2015504069A JP 2015504069 A JP2015504069 A JP 2015504069A JP 2014551244 A JP2014551244 A JP 2014551244A JP 2014551244 A JP2014551244 A JP 2014551244A JP 2015504069 A JP2015504069 A JP 2015504069A
Authority
JP
Japan
Prior art keywords
product
hmf
residual
hydroxymethylfurfural
sugar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2014551244A
Other languages
English (en)
Japanese (ja)
Inventor
サンボーン，アレクサンドラ
トーマス ピー． ビンダー，
トーマス ピー． ビンダー，
ホファート，エイプリル
Original Assignee
アーチャー−ダニエルズ−ミッドランド カンパニー
アーチャー−ダニエルズ−ミッドランド カンパニー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by アーチャー−ダニエルズ−ミッドランド カンパニー, アーチャー−ダニエルズ−ミッドランド カンパニー filed Critical アーチャー−ダニエルズ−ミッドランド カンパニー
Publication of JP2015504069A publication Critical patent/JP2015504069A/ja
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C07D307/50—Preparation from natural products
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P13/00—Preparation of nitrogen-containing organic compounds
    • C12P13/04—Alpha- or beta- amino acids
    • C12P13/08—Lysine; Diaminopimelic acid; Threonine; Valine
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06—Ethanol, i.e. non-beverage
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/18—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic polyhydric
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
    • C12P7/56—Lactic acid
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Microbiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Saccharide Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)
JP2014551244A 2012-01-10 2012-11-28 エタノールへの直接発酵に好適な未反応の糖類の回収とともに、糖類からｈｍｆおよびｈｍｆ誘導体を製造する方法 Pending JP2015504069A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261584900P 2012-01-10 2012-01-10
US61/584,900 2012-01-10
PCT/US2012/066708 WO2013106136A1 (en) 2012-01-10 2012-11-28 Process for making hmf and hmf derivatives from sugars, with recovery of unreacted sugars suitable for direct fermentation to ethanol

Publications (1)

Publication Number Publication Date
JP2015504069A true JP2015504069A (ja) 2015-02-05

Family

ID=48781802

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2014551244A Pending JP2015504069A (ja) 2012-01-10 2012-11-28 エタノールへの直接発酵に好適な未反応の糖類の回収とともに、糖類からｈｍｆおよびｈｍｆ誘導体を製造する方法

Country Status (13)

Country Link
US (1) US20140315262A1 (enExample)
EP (1) EP2802570A4 (enExample)
JP (1) JP2015504069A (enExample)
KR (1) KR20140117522A (enExample)
CN (1) CN104053649A (enExample)
AU (1) AU2012364787A1 (enExample)
BR (1) BR112014016687A8 (enExample)
CA (1) CA2860834A1 (enExample)
EA (1) EA201491190A1 (enExample)
IN (1) IN2014DN06491A (enExample)
MX (1) MX2014008376A (enExample)
SG (1) SG11201403204TA (enExample)
WO (1) WO2013106136A1 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110035999A (zh) * 2016-12-02 2019-07-19 甜糖股份公司 羟甲基糠醛制备方法
JP2021525732A (ja) * 2018-05-29 2021-09-27 ズートツッカー アーゲー 塩と酸との混合物により触媒されるｈｍｆの製造
JP2021525753A (ja) * 2018-05-29 2021-09-27 ズートツッカー アーゲー 陽極液画分により触媒されるｈｍｆの製造
JP2023544969A (ja) * 2020-09-01 2023-10-26 ブラスケム エス．エー． フランジメタノールの嫌気的発酵産生とフランジカルボン酸の酵素的産生

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105026542A (zh) 2013-03-05 2015-11-04 阿彻丹尼尔斯米德兰德公司 用于糖醇的酸脱水的方法
JP6394221B2 (ja) * 2013-09-20 2018-09-26 三菱ケミカル株式会社 精製糖液の製造方法、有機化合物の製造方法および微生物の培養方法
CN106029642B (zh) 2014-01-27 2019-11-29 阿彻丹尼尔斯米德兰公司 含果糖的原料向含hmf的产物的转化
MX386276B (es) * 2014-04-10 2025-03-04 Archer Daniels Midland Co Deshidratacion de un alcohol de azucar con combinacion mixta de catalizadores de acido.
AU2015303871B2 (en) * 2014-08-19 2018-11-29 Archer Daniels Midland Company Catalyst and process for producing 2,5-furandicarboxylic acid from hydromethylfurfural in water
KR101626808B1 (ko) 2014-10-29 2016-06-02 군산대학교산학협력단 목질계 바이오매스 가수분해액으로부터 당을 정제하는 방법
WO2016126671A1 (en) * 2015-02-03 2016-08-11 Archer Daniels Midland Company One vessel process for making 1,2-propanediol from a high fructose feedstock
ES2900753T3 (es) 2015-02-10 2022-03-18 Furanix Technologies Bv Composición de combustible que comprende huminas
US10538499B2 (en) 2015-04-14 2020-01-21 Dupont Industrial Biosciences Usa, Llc Processes for producing 2,5-furandicarboxylic acid and derivatives thereof and polymers made therefrom
EP3337790A4 (en) 2015-08-21 2019-01-23 GFBiochemicals Limited PROCESS FOR THE PREPARATION OF HYDROXYMETHYL FURFURAL DERIVATIVES
US10208006B2 (en) 2016-01-13 2019-02-19 Stora Enso Oyj Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
EP3424914A1 (de) * 2017-07-05 2019-01-09 AVALON Industries AG Verfahren zur extraktion von 5-hydroxymethylfurfural (5-hmf)
WO2019014382A1 (en) 2017-07-12 2019-01-17 Stora Enso Oyj PURIFIED PRODUCTS OF THE 2.5-FURANDICARBOXYLIC ACID PATHWAY
CN116615479A (zh) 2020-12-18 2023-08-18 巴斯夫欧洲公司 包含2,5-双(羟甲基)四氢呋喃的聚酯多元醇

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2929823A (en) * 1956-11-26 1960-03-22 Merck & Co Inc Production of 5-hydroxymethylfurfural
US4740605A (en) * 1986-01-17 1988-04-26 Suddeutsche Zucker-Aktiengesellschaft Process for preparing pure 5-hydroxymethylfurfuraldehyde
JP2009529551A (ja) * 2006-03-10 2009-08-20 フラニックス テクノロジーズ ベスローテン フェンノートシャップ ５−ヒドロキシメチルフルフラルの有機酸エステルの合成方法及びそれらの使用
JP2011506478A (ja) * 2007-12-12 2011-03-03 アーチャー ダニエルズ ミッドランド カンパニー 炭水化物からヒドロキシメチルフルフラール（ｈｍｆ）への変換及び誘導体
JP2011078327A (ja) * 2009-10-05 2011-04-21 Gunma Univ 糖溶液からの発酵阻害物質の分離方法
WO2011133536A1 (en) * 2010-04-19 2011-10-27 The University Of Toledo Aldose-ketose transformation for separation and/or chemical conversion of c6 and c5 sugars from biomass materials

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB600871A (en) * 1945-10-17 1948-04-21 Walter Norman Haworth Improvements relating to the manufacture of 5-hydroxymethyl 2-furfural
CA1174191A (en) * 1980-03-05 1984-09-11 Peter L. Rogers Ethanol production
FR2664273B1 (fr) * 1990-06-27 1994-04-29 Beghin Say Sa Nouveau procede de preparation du 5-hydroxymethylfurfural a partir de saccharides.
WO1999067409A1 (en) * 1998-06-23 1999-12-29 The Regents Of The University Of California Method of treating biomass material
EP1834950A1 (en) * 2006-03-10 2007-09-19 Avantium International B.V. Method for the synthesis of 5-alkoxymethylfurfural ethers and their use
ATE498616T1 (de) * 2007-09-07 2011-03-15 Furanix Technologies Bv In ionischen flüssigkeiten erzeugte hydroxymethylfurfuralether und -ester
ES2564184T3 (es) * 2008-11-17 2016-03-18 Ingelia, S.L. Sistema de control de presión y temperatura de al menos un reactor químico para tratar biomasa
CN101475543A (zh) * 2009-02-11 2009-07-08 中国科学院山西煤炭化学研究所 一种由糖类低温常压制取羟甲基糠醛的方法
FR2945543B1 (fr) * 2009-05-15 2011-05-06 Inst Francais Du Petrole Procede de production d'alcools et/ou de solvants a partir de biomasse lignocellulosique avec recyclage acide des residus solides
US20100311137A1 (en) * 2009-06-08 2010-12-09 Ut-Battelle, Llc Microorganisms Having Enhanced Tolerance To Inhibitors and Stress
CN102260229A (zh) * 2010-05-28 2011-11-30 中国科学院大连化学物理研究所 一种制备5-羟甲基糠醛及5-烷氧基甲基糠醛的方法
WO2013138153A1 (en) * 2012-03-12 2013-09-19 Archer Daniels Midland Company Process for making sugar and/or sugar alcohol dehydration products

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2929823A (en) * 1956-11-26 1960-03-22 Merck & Co Inc Production of 5-hydroxymethylfurfural
US4740605A (en) * 1986-01-17 1988-04-26 Suddeutsche Zucker-Aktiengesellschaft Process for preparing pure 5-hydroxymethylfurfuraldehyde
JP2009529551A (ja) * 2006-03-10 2009-08-20 フラニックス テクノロジーズ ベスローテン フェンノートシャップ ５−ヒドロキシメチルフルフラルの有機酸エステルの合成方法及びそれらの使用
JP2011506478A (ja) * 2007-12-12 2011-03-03 アーチャー ダニエルズ ミッドランド カンパニー 炭水化物からヒドロキシメチルフルフラール（ｈｍｆ）への変換及び誘導体
JP2011078327A (ja) * 2009-10-05 2011-04-21 Gunma Univ 糖溶液からの発酵阻害物質の分離方法
WO2011133536A1 (en) * 2010-04-19 2011-10-27 The University Of Toledo Aldose-ketose transformation for separation and/or chemical conversion of c6 and c5 sugars from biomass materials

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110035999A (zh) * 2016-12-02 2019-07-19 甜糖股份公司 羟甲基糠醛制备方法
JP2020511405A (ja) * 2016-12-02 2020-04-16 ズートツッカー アーゲー Ｈｍｆ製造方法
JP7042272B2 (ja) 2016-12-02 2022-03-25 ズートツッカー アーゲー Ｈｍｆ製造方法
JP2021525732A (ja) * 2018-05-29 2021-09-27 ズートツッカー アーゲー 塩と酸との混合物により触媒されるｈｍｆの製造
JP2021525753A (ja) * 2018-05-29 2021-09-27 ズートツッカー アーゲー 陽極液画分により触媒されるｈｍｆの製造
JP7339284B2 (ja) 2018-05-29 2023-09-05 ズートツッカー アーゲー 陽極液画分により触媒されるｈｍｆの製造
JP7410058B2 (ja) 2018-05-29 2024-01-09 ズートツッカー アーゲー 塩と酸との混合物により触媒されるｈｍｆの製造
JP2023544969A (ja) * 2020-09-01 2023-10-26 ブラスケム エス．エー． フランジメタノールの嫌気的発酵産生とフランジカルボン酸の酵素的産生

Also Published As

Publication number Publication date
WO2013106136A1 (en) 2013-07-18
BR112014016687A8 (pt) 2017-07-04
US20140315262A1 (en) 2014-10-23
IN2014DN06491A (enExample) 2015-06-12
CA2860834A1 (en) 2013-07-18
KR20140117522A (ko) 2014-10-07
BR112014016687A2 (pt) 2017-06-13
EP2802570A1 (en) 2014-11-19
AU2012364787A1 (en) 2014-07-03
CN104053649A (zh) 2014-09-17
MX2014008376A (es) 2015-04-09
SG11201403204TA (en) 2014-09-26
EA201491190A1 (ru) 2014-12-30
EP2802570A4 (en) 2016-01-06

Similar Documents

Publication Publication Date Title
US20140315262A1 (en) Process for making hmf and hmf derivatives from sugars, with recovery of unreacted sugars suitable for direct fermentation to ethanol
US12371753B2 (en) Co-solvent to produce reactive intermediates from biomass
Roque et al. Liquid-liquid extraction: A promising alternative for inhibitors removing of pentoses fermentation
Azadi et al. Catalytic conversion of biomass using solvents derived from lignin
US10138218B2 (en) Process for preparing furfural from biomass
US9090579B2 (en) Processes for making sugar and/or sugar alcohol dehydration products
US9957244B2 (en) Catalyst and process for producing 2,5-furandicarboxylic acid from hydroxymethylfurfural in water
US9776980B1 (en) Process for making HMF from sugars with reduced byproduct formation, and improved stability HMF compositions
CN102089292A (zh) 糠基衍生物的氢解方法

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20151106

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20160812

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20161110

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20161110

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20170425

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20180122