MX2014008376A - Proceso para la fabricacion de hmf y derivados de hmf de azucares, con recuperacion de azucares sin reaccionar apropiados para la fermentacion directa a etanol. - Google Patents

Proceso para la fabricacion de hmf y derivados de hmf de azucares, con recuperacion de azucares sin reaccionar apropiados para la fermentacion directa a etanol.

Info

Publication number
MX2014008376A
MX2014008376A MX2014008376A MX2014008376A MX2014008376A MX 2014008376 A MX2014008376 A MX 2014008376A MX 2014008376 A MX2014008376 A MX 2014008376A MX 2014008376 A MX2014008376 A MX 2014008376A MX 2014008376 A MX2014008376 A MX 2014008376A
Authority
MX
Mexico
Prior art keywords
hmf
sugars
ethanol
recovery
product
Prior art date
Application number
MX2014008376A
Other languages
English (en)
Inventor
Thomas P Binder
Alexandra Sanborn
April Hoffart
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of MX2014008376A publication Critical patent/MX2014008376A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C07D307/50—Preparation from natural products
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P13/00—Preparation of nitrogen-containing organic compounds
    • C12P13/04—Alpha- or beta- amino acids
    • C12P13/08—Lysine; Diaminopimelic acid; Threonine; Valine
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06—Ethanol, i.e. non-beverage
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/18—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic polyhydric
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
    • C12P7/56—Lactic acid
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Microbiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Saccharide Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)

Abstract

El hidroximetilfurfural se obtiene a partir de una solución de azúcar de hexosa acuosa, especialmente a partir de un producto de jarabe de maíz con alto contenido de fructosa. Al calentar rápidamente la solución de azúcar hasta las temperaturas elevadas implicadas, así como al enfriar rápidamente la mezcla del producto resultante, se obtiene una conversión por paso limitada en HMF; por lo tanto, sin embargo, la exposición general al HMF que se forma en condiciones ácidas con temperaturas elevadas también está limitada, de modo que los productos derivados se reducen. La separación y recuperación de los productos se simplifica y los niveles de HMF y otros productos de deshidratación de hexosa que se sabe inhiben la producción de etanol por fermentación se reducen en el producto de azúcares residuales en una media tal que el producto de azúcares residuales es adecuado para fermentarse directamente en etanol o para otros usos.
MX2014008376A 2012-01-10 2012-11-28 Proceso para la fabricacion de hmf y derivados de hmf de azucares, con recuperacion de azucares sin reaccionar apropiados para la fermentacion directa a etanol. MX2014008376A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261584900P 2012-01-10 2012-01-10
PCT/US2012/066708 WO2013106136A1 (en) 2012-01-10 2012-11-28 Process for making hmf and hmf derivatives from sugars, with recovery of unreacted sugars suitable for direct fermentation to ethanol

Publications (1)

Publication Number Publication Date
MX2014008376A true MX2014008376A (es) 2015-04-09

Family

ID=48781802

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014008376A MX2014008376A (es) 2012-01-10 2012-11-28 Proceso para la fabricacion de hmf y derivados de hmf de azucares, con recuperacion de azucares sin reaccionar apropiados para la fermentacion directa a etanol.

Country Status (13)

Country Link
US (1) US20140315262A1 (es)
EP (1) EP2802570A4 (es)
JP (1) JP2015504069A (es)
KR (1) KR20140117522A (es)
CN (1) CN104053649A (es)
AU (1) AU2012364787A1 (es)
BR (1) BR112014016687A8 (es)
CA (1) CA2860834A1 (es)
EA (1) EA201491190A1 (es)
IN (1) IN2014DN06491A (es)
MX (1) MX2014008376A (es)
SG (1) SG11201403204TA (es)
WO (1) WO2013106136A1 (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6267240B2 (ja) 2013-03-05 2018-01-24 アーチャー−ダニエルズ−ミッドランド カンパニー 糖アルコールの酸脱水のための方法
JP6394221B2 (ja) * 2013-09-20 2018-09-26 三菱ケミカル株式会社 精製糖液の製造方法、有機化合物の製造方法および微生物の培養方法
WO2015113060A2 (en) * 2014-01-27 2015-07-30 Rennovia, Inc. Conversion of fructose-containing feedstocks to hmf-containing product
JP6275278B2 (ja) * 2014-04-10 2018-02-07 アーチャー−ダニエルズ−ミッドランド カンパニー 酸触媒の組合せ混合物を用いた糖アルコールの脱水
US9957244B2 (en) * 2014-08-19 2018-05-01 Archer Daniels Midland Company Catalyst and process for producing 2,5-furandicarboxylic acid from hydroxymethylfurfural in water
KR101626808B1 (ko) 2014-10-29 2016-06-02 군산대학교산학협력단 목질계 바이오매스 가수분해액으로부터 당을 정제하는 방법
ES2769040T3 (es) * 2015-02-03 2020-06-24 Archer Daniels Midland Co Proceso de un recipiente para elaborar 1,2-propanodiol a partir de una materia prima con alto contenido de fructosa
ES2900753T3 (es) 2015-02-10 2022-03-18 Furanix Technologies Bv Composición de combustible que comprende huminas
EP4306569A3 (en) 2015-04-14 2024-04-10 E I Du Pont De Nemours Processes for producing 2,5-furandicarboxylic acid and derivatives thereof and polymers made therefrom
EP3337790A4 (en) 2015-08-21 2019-01-23 GFBiochemicals Limited PROCESS FOR THE PREPARATION OF HYDROXYMETHYL FURFURAL DERIVATIVES
US10208006B2 (en) 2016-01-13 2019-02-19 Stora Enso Oyj Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
DE102016224073A1 (de) 2016-12-02 2018-06-07 Südzucker AG Verbessertes HMF-Herstellungsverfahren
EP3424914A1 (de) * 2017-07-05 2019-01-09 AVALON Industries AG Verfahren zur extraktion von 5-hydroxymethylfurfural (5-hmf)
CN110997647A (zh) 2017-07-12 2020-04-10 斯道拉恩索公司 纯化的2,5-呋喃二甲酸途径产物
DE102018208507A1 (de) 2018-05-29 2019-12-05 Südzucker AG Anolytfraktion-katalysierte HMF-Herstellung
DE102018208510A1 (de) 2018-05-29 2019-12-05 Südzucker AG Salz- und Säuregemisch-katalysierte HMF-Herstellung
WO2022129136A1 (en) 2020-12-18 2022-06-23 Basf Se Polyester polyols comprising 2,5-bis(hydroxymethyl)tetrahydrofuran

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GB600871A (en) * 1945-10-17 1948-04-21 Walter Norman Haworth Improvements relating to the manufacture of 5-hydroxymethyl 2-furfural
US2929823A (en) * 1956-11-26 1960-03-22 Merck & Co Inc Production of 5-hydroxymethylfurfural
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DE3601281A1 (de) 1986-01-17 1987-07-23 Sueddeutsche Zucker Ag Verfahren zur herstellung von 5-hydroxymethylfurfural einschliesslich eines kristallinen produktes unter ausschliesslicher verwendung von wasser als loesungsmittel
FR2664273B1 (fr) * 1990-06-27 1994-04-29 Beghin Say Sa Nouveau procede de preparation du 5-hydroxymethylfurfural a partir de saccharides.
WO1999067409A1 (en) * 1998-06-23 1999-12-29 The Regents Of The University Of California Method of treating biomass material
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EP2423205B9 (en) * 2007-12-12 2020-03-18 Archer-Daniels-Midland Company Conversion of carbohydrates to hydroxymethylfurfural (HMF) and derivatives
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Also Published As

Publication number Publication date
BR112014016687A2 (pt) 2017-06-13
US20140315262A1 (en) 2014-10-23
AU2012364787A1 (en) 2014-07-03
JP2015504069A (ja) 2015-02-05
EA201491190A1 (ru) 2014-12-30
CN104053649A (zh) 2014-09-17
SG11201403204TA (en) 2014-09-26
EP2802570A4 (en) 2016-01-06
CA2860834A1 (en) 2013-07-18
WO2013106136A1 (en) 2013-07-18
EP2802570A1 (en) 2014-11-19
BR112014016687A8 (pt) 2017-07-04
IN2014DN06491A (es) 2015-06-12
KR20140117522A (ko) 2014-10-07

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