MX2014008376A - Proceso para la fabricacion de hmf y derivados de hmf de azucares, con recuperacion de azucares sin reaccionar apropiados para la fermentacion directa a etanol. - Google Patents
Proceso para la fabricacion de hmf y derivados de hmf de azucares, con recuperacion de azucares sin reaccionar apropiados para la fermentacion directa a etanol.Info
- Publication number
- MX2014008376A MX2014008376A MX2014008376A MX2014008376A MX2014008376A MX 2014008376 A MX2014008376 A MX 2014008376A MX 2014008376 A MX2014008376 A MX 2014008376A MX 2014008376 A MX2014008376 A MX 2014008376A MX 2014008376 A MX2014008376 A MX 2014008376A
- Authority
- MX
- Mexico
- Prior art keywords
- hmf
- sugars
- ethanol
- recovery
- product
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
- C07D307/48—Furfural
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
- C07D307/48—Furfural
- C07D307/50—Preparation from natural products
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P13/00—Preparation of nitrogen-containing organic compounds
- C12P13/04—Alpha- or beta- amino acids
- C12P13/08—Lysine; Diaminopimelic acid; Threonine; Valine
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
- C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
- C12P7/06—Ethanol, i.e. non-beverage
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
- C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
- C12P7/18—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic polyhydric
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
- C12P7/56—Lactic acid
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Abstract
El hidroximetilfurfural se obtiene a partir de una solución de azúcar de hexosa acuosa, especialmente a partir de un producto de jarabe de maíz con alto contenido de fructosa. Al calentar rápidamente la solución de azúcar hasta las temperaturas elevadas implicadas, así como al enfriar rápidamente la mezcla del producto resultante, se obtiene una conversión por paso limitada en HMF; por lo tanto, sin embargo, la exposición general al HMF que se forma en condiciones ácidas con temperaturas elevadas también está limitada, de modo que los productos derivados se reducen. La separación y recuperación de los productos se simplifica y los niveles de HMF y otros productos de deshidratación de hexosa que se sabe inhiben la producción de etanol por fermentación se reducen en el producto de azúcares residuales en una media tal que el producto de azúcares residuales es adecuado para fermentarse directamente en etanol o para otros usos.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261584900P | 2012-01-10 | 2012-01-10 | |
PCT/US2012/066708 WO2013106136A1 (en) | 2012-01-10 | 2012-11-28 | Process for making hmf and hmf derivatives from sugars, with recovery of unreacted sugars suitable for direct fermentation to ethanol |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2014008376A true MX2014008376A (es) | 2015-04-09 |
Family
ID=48781802
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014008376A MX2014008376A (es) | 2012-01-10 | 2012-11-28 | Proceso para la fabricacion de hmf y derivados de hmf de azucares, con recuperacion de azucares sin reaccionar apropiados para la fermentacion directa a etanol. |
Country Status (13)
Country | Link |
---|---|
US (1) | US20140315262A1 (es) |
EP (1) | EP2802570A4 (es) |
JP (1) | JP2015504069A (es) |
KR (1) | KR20140117522A (es) |
CN (1) | CN104053649A (es) |
AU (1) | AU2012364787A1 (es) |
BR (1) | BR112014016687A8 (es) |
CA (1) | CA2860834A1 (es) |
EA (1) | EA201491190A1 (es) |
IN (1) | IN2014DN06491A (es) |
MX (1) | MX2014008376A (es) |
SG (1) | SG11201403204TA (es) |
WO (1) | WO2013106136A1 (es) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014137619A1 (en) | 2013-03-05 | 2014-09-12 | Archer Daniels Midland Company | Process for acid dehydration of sugar alcohols |
JP6394221B2 (ja) * | 2013-09-20 | 2018-09-26 | 三菱ケミカル株式会社 | 精製糖液の製造方法、有機化合物の製造方法および微生物の培養方法 |
BR112016016751B1 (pt) * | 2014-01-27 | 2021-08-31 | Archer-Daniels-Midland Company | Processo para a produção de um produto que compreende hmf e água |
KR102107274B1 (ko) * | 2014-04-10 | 2020-05-06 | 아처 다니엘 미드랜드 캄파니 | 산 촉매의 혼합 조합을 이용한 당 알코올의 탈수 |
HUE058236T2 (hu) * | 2014-08-19 | 2022-07-28 | Archer Daniels Midland Co | Katalizátor és eljárás 2,5-furándikarbonsav elõállítására hidrometilfurfurolból vízben |
KR101626808B1 (ko) | 2014-10-29 | 2016-06-02 | 군산대학교산학협력단 | 목질계 바이오매스 가수분해액으로부터 당을 정제하는 방법 |
PL3253486T3 (pl) * | 2015-02-03 | 2020-04-30 | Archer Daniels Midland Company | Jednozbiornikowy sposób wytwarzania 1,2-propanodiolu z surowca wysokofruktozowego |
US10858601B2 (en) | 2015-02-10 | 2020-12-08 | Avantium Knowledge Centre B.V. | Fuel composition comprising humins |
ES2965441T3 (es) | 2015-04-14 | 2024-04-15 | E I Du Pont De Nemours | Procedimientos para producir ácido 2,5-furandicarboxílico y derivados del mismo |
EP3337790A4 (en) * | 2015-08-21 | 2019-01-23 | GFBiochemicals Limited | PROCESS FOR THE PREPARATION OF HYDROXYMETHYL FURFURAL DERIVATIVES |
KR20180107143A (ko) | 2016-01-13 | 2018-10-01 | 스토라 엔소 오와이제이 | 2,5-푸란디카르복실산 및 그의 중간체 및 유도체의 제조 방법 |
DE102016224073A1 (de) * | 2016-12-02 | 2018-06-07 | Südzucker AG | Verbessertes HMF-Herstellungsverfahren |
EP3424914A1 (de) * | 2017-07-05 | 2019-01-09 | AVALON Industries AG | Verfahren zur extraktion von 5-hydroxymethylfurfural (5-hmf) |
JP7158462B2 (ja) | 2017-07-12 | 2022-10-21 | ストラ エンソ オーユーイー | 精製2,5-フランジカルボン酸経路生成物 |
DE102018208510A1 (de) | 2018-05-29 | 2019-12-05 | Südzucker AG | Salz- und Säuregemisch-katalysierte HMF-Herstellung |
DE102018208507A1 (de) | 2018-05-29 | 2019-12-05 | Südzucker AG | Anolytfraktion-katalysierte HMF-Herstellung |
WO2022129136A1 (en) | 2020-12-18 | 2022-06-23 | Basf Se | Polyester polyols comprising 2,5-bis(hydroxymethyl)tetrahydrofuran |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB600871A (en) * | 1945-10-17 | 1948-04-21 | Walter Norman Haworth | Improvements relating to the manufacture of 5-hydroxymethyl 2-furfural |
US2929823A (en) * | 1956-11-26 | 1960-03-22 | Merck & Co Inc | Production of 5-hydroxymethylfurfural |
CA1174191A (en) * | 1980-03-05 | 1984-09-11 | Peter L. Rogers | Ethanol production |
DE3601281A1 (de) * | 1986-01-17 | 1987-07-23 | Sueddeutsche Zucker Ag | Verfahren zur herstellung von 5-hydroxymethylfurfural einschliesslich eines kristallinen produktes unter ausschliesslicher verwendung von wasser als loesungsmittel |
FR2664273B1 (fr) * | 1990-06-27 | 1994-04-29 | Beghin Say Sa | Nouveau procede de preparation du 5-hydroxymethylfurfural a partir de saccharides. |
AU4700199A (en) * | 1998-06-23 | 2000-01-10 | Regents Of The University Of California, The | Method of treating biomass material |
EP2053047A1 (en) * | 2006-03-10 | 2009-04-29 | Furanix Technologies B.V | Method for the synthesis of organic acid esters of 5-hydroxymethylfurfural and their use |
EP1834950A1 (en) * | 2006-03-10 | 2007-09-19 | Avantium International B.V. | Method for the synthesis of 5-alkoxymethylfurfural ethers and their use |
DE602008005035D1 (de) * | 2007-09-07 | 2011-03-31 | Furanix Technologies Bv | In ionischen flüssigkeiten erzeugte hydroxymethylfurfuralether und -ester |
JP2011506478A (ja) * | 2007-12-12 | 2011-03-03 | アーチャー ダニエルズ ミッドランド カンパニー | 炭水化物からヒドロキシメチルフルフラール(hmf)への変換及び誘導体 |
ES2564184T3 (es) * | 2008-11-17 | 2016-03-18 | Ingelia, S.L. | Sistema de control de presión y temperatura de al menos un reactor químico para tratar biomasa |
CN101475543A (zh) * | 2009-02-11 | 2009-07-08 | 中国科学院山西煤炭化学研究所 | 一种由糖类低温常压制取羟甲基糠醛的方法 |
FR2945543B1 (fr) * | 2009-05-15 | 2011-05-06 | Inst Francais Du Petrole | Procede de production d'alcools et/ou de solvants a partir de biomasse lignocellulosique avec recyclage acide des residus solides |
US20100311137A1 (en) * | 2009-06-08 | 2010-12-09 | Ut-Battelle, Llc | Microorganisms Having Enhanced Tolerance To Inhibitors and Stress |
JP2011078327A (ja) * | 2009-10-05 | 2011-04-21 | Gunma Univ | 糖溶液からの発酵阻害物質の分離方法 |
WO2011133536A1 (en) * | 2010-04-19 | 2011-10-27 | The University Of Toledo | Aldose-ketose transformation for separation and/or chemical conversion of c6 and c5 sugars from biomass materials |
CN102260229A (zh) * | 2010-05-28 | 2011-11-30 | 中国科学院大连化学物理研究所 | 一种制备5-羟甲基糠醛及5-烷氧基甲基糠醛的方法 |
JP6148720B2 (ja) * | 2012-03-12 | 2017-06-14 | アーチャー−ダニエルズ−ミッドランド カンパニー | 糖および/または糖アルコール脱水物を製造する方法 |
-
2012
- 2012-11-28 US US14/358,363 patent/US20140315262A1/en not_active Abandoned
- 2012-11-28 BR BR112014016687A patent/BR112014016687A8/pt not_active Application Discontinuation
- 2012-11-28 AU AU2012364787A patent/AU2012364787A1/en not_active Abandoned
- 2012-11-28 WO PCT/US2012/066708 patent/WO2013106136A1/en active Application Filing
- 2012-11-28 IN IN6491DEN2014 patent/IN2014DN06491A/en unknown
- 2012-11-28 EP EP12864693.2A patent/EP2802570A4/en not_active Withdrawn
- 2012-11-28 SG SG11201403204TA patent/SG11201403204TA/en unknown
- 2012-11-28 MX MX2014008376A patent/MX2014008376A/es unknown
- 2012-11-28 CA CA2860834A patent/CA2860834A1/en not_active Abandoned
- 2012-11-28 KR KR1020147022308A patent/KR20140117522A/ko not_active Application Discontinuation
- 2012-11-28 CN CN201280066380.8A patent/CN104053649A/zh active Pending
- 2012-11-28 JP JP2014551244A patent/JP2015504069A/ja active Pending
- 2012-11-28 EA EA201491190A patent/EA201491190A1/ru unknown
Also Published As
Publication number | Publication date |
---|---|
KR20140117522A (ko) | 2014-10-07 |
WO2013106136A1 (en) | 2013-07-18 |
CN104053649A (zh) | 2014-09-17 |
US20140315262A1 (en) | 2014-10-23 |
IN2014DN06491A (es) | 2015-06-12 |
BR112014016687A2 (pt) | 2017-06-13 |
SG11201403204TA (en) | 2014-09-26 |
CA2860834A1 (en) | 2013-07-18 |
AU2012364787A1 (en) | 2014-07-03 |
BR112014016687A8 (pt) | 2017-07-04 |
EP2802570A1 (en) | 2014-11-19 |
EP2802570A4 (en) | 2016-01-06 |
JP2015504069A (ja) | 2015-02-05 |
EA201491190A1 (ru) | 2014-12-30 |
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