IN2014DN06491A - - Google Patents

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Publication number
IN2014DN06491A
IN2014DN06491A IN6491DEN2014A IN2014DN06491A IN 2014DN06491 A IN2014DN06491 A IN 2014DN06491A IN 6491DEN2014 A IN6491DEN2014 A IN 6491DEN2014A IN 2014DN06491 A IN2014DN06491 A IN 2014DN06491A
Authority
IN
India
Prior art keywords
hmf
product
reduced
sugar solution
residual sugars
Prior art date
Application number
Inventor
Alexandra Sanborn
Thomas P Binder
April Hoffart
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of IN2014DN06491A publication Critical patent/IN2014DN06491A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C07D307/50—Preparation from natural products
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P13/00—Preparation of nitrogen-containing organic compounds
    • C12P13/04—Alpha- or beta- amino acids
    • C12P13/08—Lysine; Diaminopimelic acid; Threonine; Valine
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06—Ethanol, i.e. non-beverage
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/18—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic polyhydric
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
    • C12P7/56—Lactic acid
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Microbiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Saccharide Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)

Abstract

Hydroxymethylfurfural is made from an aqueous hexose sugar solution especially from a high fructose corn syrup product. By rapidly heating the sugar solution to the elevated temperatures involved as well as rapidly cooling the resultant product mixture a limited per pass conversion to HMF is obtained; correspondingly however the overall exposure of the HMF that is formed to acidic elevated temperature conditions is also limited so that byproducts are reduced. Separation and recovery of the products is simplified and levels of HMF and other hexose dehydration products known to inhibit ethanol production by fermentation are reduced in the residual sugars product to an extent whereby the residual sugars product is suited to be directly fermented to ethanol or for other uses.
IN6491DEN2014 2012-01-10 2012-11-28 IN2014DN06491A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261584900P 2012-01-10 2012-01-10
PCT/US2012/066708 WO2013106136A1 (en) 2012-01-10 2012-11-28 Process for making hmf and hmf derivatives from sugars, with recovery of unreacted sugars suitable for direct fermentation to ethanol

Publications (1)

Publication Number Publication Date
IN2014DN06491A true IN2014DN06491A (en) 2015-06-12

Family

ID=48781802

Family Applications (1)

Application Number Title Priority Date Filing Date
IN6491DEN2014 IN2014DN06491A (en) 2012-01-10 2012-11-28

Country Status (13)

Country Link
US (1) US20140315262A1 (en)
EP (1) EP2802570A4 (en)
JP (1) JP2015504069A (en)
KR (1) KR20140117522A (en)
CN (1) CN104053649A (en)
AU (1) AU2012364787A1 (en)
BR (1) BR112014016687A8 (en)
CA (1) CA2860834A1 (en)
EA (1) EA201491190A1 (en)
IN (1) IN2014DN06491A (en)
MX (1) MX2014008376A (en)
SG (1) SG11201403204TA (en)
WO (1) WO2013106136A1 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6267240B2 (en) 2013-03-05 2018-01-24 アーチャー−ダニエルズ−ミッドランド カンパニー Method for acid dehydration of sugar alcohols
JP6394221B2 (en) * 2013-09-20 2018-09-26 三菱ケミカル株式会社 Method for producing purified sugar solution, method for producing organic compound, and method for culturing microorganism
WO2015113060A2 (en) * 2014-01-27 2015-07-30 Rennovia, Inc. Conversion of fructose-containing feedstocks to hmf-containing product
JP6275278B2 (en) * 2014-04-10 2018-02-07 アーチャー−ダニエルズ−ミッドランド カンパニー Dehydration of sugar alcohols using a combination mixture of acid catalysts
US9957244B2 (en) * 2014-08-19 2018-05-01 Archer Daniels Midland Company Catalyst and process for producing 2,5-furandicarboxylic acid from hydroxymethylfurfural in water
KR101626808B1 (en) 2014-10-29 2016-06-02 군산대학교산학협력단 Method of purification of sugars in lignocellulose biomass hydrolysates
ES2769040T3 (en) * 2015-02-03 2020-06-24 Archer Daniels Midland Co One-pot process to make 1,2-propanediol from a high fructose raw material
ES2900753T3 (en) 2015-02-10 2022-03-18 Furanix Technologies Bv Fuel composition comprising humins
EP4306569A3 (en) 2015-04-14 2024-04-10 E I Du Pont De Nemours Processes for producing 2,5-furandicarboxylic acid and derivatives thereof and polymers made therefrom
EP3337790A4 (en) 2015-08-21 2019-01-23 GFBiochemicals Limited Process to prepare hydroxymethylfurfural derivatives
US10208006B2 (en) 2016-01-13 2019-02-19 Stora Enso Oyj Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
DE102016224073A1 (en) 2016-12-02 2018-06-07 Südzucker AG Improved HMF manufacturing process
EP3424914A1 (en) * 2017-07-05 2019-01-09 AVALON Industries AG Method for the extraction of (5-hydroxymethylfurfural,5-hmf)
CN110997647A (en) 2017-07-12 2020-04-10 斯道拉恩索公司 Purified 2, 5-furandicarboxylic acid pathway products
DE102018208507A1 (en) 2018-05-29 2019-12-05 Südzucker AG Anolyte fraction-catalyzed HMF production
DE102018208510A1 (en) 2018-05-29 2019-12-05 Südzucker AG Salt and acid mixture catalyzed HMF production
WO2022129136A1 (en) 2020-12-18 2022-06-23 Basf Se Polyester polyols comprising 2,5-bis(hydroxymethyl)tetrahydrofuran

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB600871A (en) * 1945-10-17 1948-04-21 Walter Norman Haworth Improvements relating to the manufacture of 5-hydroxymethyl 2-furfural
US2929823A (en) * 1956-11-26 1960-03-22 Merck & Co Inc Production of 5-hydroxymethylfurfural
CA1173381A (en) * 1980-03-05 1984-08-28 Peter L. Rogers Ethanol production in a continuous process with cell recycle
DE3601281A1 (en) 1986-01-17 1987-07-23 Sueddeutsche Zucker Ag METHOD FOR PRODUCING 5-HYDROXYMETHYLFURFURAL, INCLUDING A CRYSTALINE PRODUCT, WITH THE EXCLUSIVE USE OF WATER AS A SOLVENT
FR2664273B1 (en) * 1990-06-27 1994-04-29 Beghin Say Sa NEW PROCESS FOR THE PREPARATION OF 5-HYDROXYMETHYLFURFURAL FROM SACCHARIDES.
WO1999067409A1 (en) * 1998-06-23 1999-12-29 The Regents Of The University Of California Method of treating biomass material
EP1834950A1 (en) * 2006-03-10 2007-09-19 Avantium International B.V. Method for the synthesis of 5-alkoxymethylfurfural ethers and their use
EP2050742B1 (en) * 2006-03-10 2010-07-07 Furanix Technologies B.V Use of an organic acid esters of 5-hydroxymethylfurfural
EP2183236B1 (en) * 2007-09-07 2011-02-16 Furanix Technologies B.V. Hydroxymethylfurfural ethers and esters prepared in ionic liquids
EP2423205B9 (en) * 2007-12-12 2020-03-18 Archer-Daniels-Midland Company Conversion of carbohydrates to hydroxymethylfurfural (HMF) and derivatives
EP2366757B1 (en) * 2008-11-17 2016-02-17 Ingelia, S.L. Pressure and temperature control system for at least one chemical reactor for treating biomass
CN101475543A (en) * 2009-02-11 2009-07-08 中国科学院山西煤炭化学研究所 Method for preparing hydroxymethyl-furfural from glucide under low temperature and normal pressure
FR2945543B1 (en) * 2009-05-15 2011-05-06 Inst Francais Du Petrole PROCESS FOR THE PRODUCTION OF ALCOHOLS AND / OR SOLVENTS FROM LIGNOCELLULOSIC BIOMASS WITH ACIDIC RECYCLING OF SOLID RESIDUES
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Also Published As

Publication number Publication date
BR112014016687A2 (en) 2017-06-13
US20140315262A1 (en) 2014-10-23
AU2012364787A1 (en) 2014-07-03
MX2014008376A (en) 2015-04-09
JP2015504069A (en) 2015-02-05
EA201491190A1 (en) 2014-12-30
CN104053649A (en) 2014-09-17
SG11201403204TA (en) 2014-09-26
EP2802570A4 (en) 2016-01-06
CA2860834A1 (en) 2013-07-18
WO2013106136A1 (en) 2013-07-18
EP2802570A1 (en) 2014-11-19
BR112014016687A8 (en) 2017-07-04
KR20140117522A (en) 2014-10-07

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