JP2014533770A - イミド化アクリル樹脂でのポリオキシメチレンの改質 - Google Patents
イミド化アクリル樹脂でのポリオキシメチレンの改質 Download PDFInfo
- Publication number
- JP2014533770A JP2014533770A JP2014543486A JP2014543486A JP2014533770A JP 2014533770 A JP2014533770 A JP 2014533770A JP 2014543486 A JP2014543486 A JP 2014543486A JP 2014543486 A JP2014543486 A JP 2014543486A JP 2014533770 A JP2014533770 A JP 2014533770A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- acrylic resin
- composition
- polyoxymethylene
- imidized acrylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920006324 polyoxymethylene Polymers 0.000 title claims abstract description 91
- 229930040373 Paraformaldehyde Natural products 0.000 title claims abstract description 85
- 239000004925 Acrylic resin Substances 0.000 title claims abstract description 49
- 229920000178 Acrylic resin Polymers 0.000 title claims abstract description 49
- -1 polyoxymethylene Polymers 0.000 title claims abstract description 38
- 230000004048 modification Effects 0.000 title 1
- 238000012986 modification Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 111
- 239000002253 acid Substances 0.000 claims abstract description 57
- 238000000034 method Methods 0.000 claims abstract description 40
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 28
- 238000002156 mixing Methods 0.000 claims abstract description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 9
- 229920001577 copolymer Polymers 0.000 claims description 23
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 19
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 18
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 16
- 230000000052 comparative effect Effects 0.000 claims description 16
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 16
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 16
- 239000000155 melt Substances 0.000 claims description 14
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 10
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 10
- 229920001519 homopolymer Polymers 0.000 claims description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 9
- 239000005977 Ethylene Substances 0.000 claims description 9
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 8
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 claims description 8
- 229920001169 thermoplastic Polymers 0.000 claims description 7
- 239000004416 thermosoftening plastic Substances 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
- 229920002319 Poly(methyl acrylate) Polymers 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 description 46
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 33
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- 239000000463 material Substances 0.000 description 18
- 238000012360 testing method Methods 0.000 description 15
- 239000000047 product Substances 0.000 description 14
- 239000011347 resin Substances 0.000 description 12
- 229920005989 resin Polymers 0.000 description 12
- 239000000523 sample Substances 0.000 description 12
- 150000008064 anhydrides Chemical group 0.000 description 11
- 238000012546 transfer Methods 0.000 description 10
- 230000006872 improvement Effects 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 239000008188 pellet Substances 0.000 description 8
- 150000001412 amines Chemical class 0.000 description 7
- 125000004122 cyclic group Chemical group 0.000 description 7
- 238000001746 injection moulding Methods 0.000 description 7
- 238000002844 melting Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 6
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 6
- 125000002843 carboxylic acid group Chemical group 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 125000005462 imide group Chemical group 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- 238000005452 bending Methods 0.000 description 5
- 125000004185 ester group Chemical group 0.000 description 5
- 230000032050 esterification Effects 0.000 description 5
- 238000005886 esterification reaction Methods 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 229910052582 BN Inorganic materials 0.000 description 4
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 4
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000006266 etherification reaction Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical group CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 3
- 229920004943 Delrin® Polymers 0.000 description 3
- 239000004609 Impact Modifier Substances 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical group CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- 229930182556 Polyacetal Natural products 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 229960000458 allantoin Drugs 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 150000003949 imides Chemical class 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 150000003141 primary amines Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000012815 thermoplastic material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- WSNMPAVSZJSIMT-UHFFFAOYSA-N COc1c(C)c2COC(=O)c2c(O)c1CC(O)C1(C)CCC(=O)O1 Chemical compound COc1c(C)c2COC(=O)c2c(O)c1CC(O)C1(C)CCC(=O)O1 WSNMPAVSZJSIMT-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 229920005027 Ultraform® Polymers 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000000712 assembly Effects 0.000 description 2
- 238000000429 assembly Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229920005622 compatible polymer blend Polymers 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 125000001033 ether group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000006358 imidation reaction Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 125000005702 oxyalkylene group Chemical group 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000003856 thermoforming Methods 0.000 description 2
- FQERLIOIVXPZKH-UHFFFAOYSA-N 1,2,4-trioxane Chemical compound C1COOCO1 FQERLIOIVXPZKH-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920005372 Plexiglas® Polymers 0.000 description 1
- 229920005431 Plexiglas® V920 Polymers 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920009382 Polyoxymethylene Homopolymer Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 230000002152 alkylating effect Effects 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000006352 cycloaddition reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000015872 dietary supplement Nutrition 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
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- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
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- 239000010419 fine particle Substances 0.000 description 1
- 230000037406 food intake Effects 0.000 description 1
- 235000012631 food intake Nutrition 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000001907 polarising light microscopy Methods 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/24—Homopolymers or copolymers of amides or imides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/306,806 | 2011-11-29 | ||
| US13/306,757 US8445089B1 (en) | 2011-11-29 | 2011-11-29 | Polyoxymethylene modified with imidized acrylic resins |
| US13/306,806 US20130137811A1 (en) | 2011-11-29 | 2011-11-29 | Modifying Polyoxymethylene Imidized Acrylic Resins |
| US13/306,757 | 2011-11-29 | ||
| PCT/US2012/063921 WO2013081785A1 (en) | 2011-11-29 | 2012-11-07 | Modifying polyoxymethylene with imidized acrylic resins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014533770A true JP2014533770A (ja) | 2014-12-15 |
| JP2014533770A5 JP2014533770A5 (enrdf_load_stackoverflow) | 2015-12-24 |
Family
ID=48535940
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014543486A Pending JP2014533770A (ja) | 2011-11-29 | 2012-11-07 | イミド化アクリル樹脂でのポリオキシメチレンの改質 |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP2014533770A (enrdf_load_stackoverflow) |
| DE (1) | DE112012004979B4 (enrdf_load_stackoverflow) |
| WO (1) | WO2013081785A1 (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10808067B2 (en) | 2017-11-30 | 2020-10-20 | Hyundai Motor Company | Polyoxymethylene resin composition and molded article manufactured with the same |
| JP7527303B2 (ja) | 2019-03-13 | 2024-08-02 | デュポン ポリマーズ インコーポレイテッド | ポリオキシメチレン組成物 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6234943A (ja) * | 1985-08-06 | 1987-02-14 | Mitsubishi Rayon Co Ltd | 熱可塑性樹脂組成物 |
| JP2007516312A (ja) * | 2003-05-13 | 2007-06-21 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 装飾用途のための改質ポリアセタール |
| JP2011225760A (ja) * | 2010-04-22 | 2011-11-10 | Kaneka Corp | 成形加工性が改善されたイミド樹脂の製造方法 |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2146209A (en) | 1936-07-31 | 1939-02-07 | Du Pont | Preparation of resinous imides of substituted acrylic acids |
| US2998409A (en) | 1954-04-16 | 1961-08-29 | Du Pont | Polyoxymethylene carboxylates of improved thermal stability |
| DE1088231B (de) | 1958-03-22 | 1960-09-01 | Roehm & Haas Gmbh | Verfahren zur Herstellung Stickstoff enthaltender Derivate der Polymethacrylsaeure |
| US3960984A (en) | 1974-04-16 | 1976-06-01 | E. I. Du Pont De Nemours And Company | Composition of oxymethylene polymer and amide oligomers |
| US4098843A (en) | 1976-12-20 | 1978-07-04 | E. I. Du Pont De Nemours And Company | Stabilized polyoxymethylene molding compositions |
| US4169924A (en) | 1977-06-09 | 1979-10-02 | Gaf Corporation | Preparation of linear cyclic polyimides from latices |
| US4246374A (en) | 1979-04-23 | 1981-01-20 | Rohm And Haas Company | Imidized acrylic polymers |
| US4217424A (en) | 1979-05-07 | 1980-08-12 | Rohm And Haas Company | Impact modification of polyglutarimides |
| US4255322A (en) | 1980-02-19 | 1981-03-10 | Rohm And Haas Company | Blends of imide polymers and vinyl chloride polymers |
| US4874817A (en) | 1982-05-07 | 1989-10-17 | E. I. Du Pont De Nemours And Company | Compositions of imidized acrylic polymers and polyamides |
| US4415706A (en) | 1982-11-10 | 1983-11-15 | Rohm And Haas Company | Compatible blends of polyglutarimides and polyamides |
| US4518717A (en) | 1983-11-07 | 1985-05-21 | Long John V | Low density, modified polyimide foams and methods of making same |
| US4595727A (en) | 1985-05-02 | 1986-06-17 | Doak Kenneth W | Blends of a polyglutarimide with a rubber-modified vinyl chloride resin |
| US4727117A (en) | 1985-08-27 | 1988-02-23 | Rohm And Haas Company | Imide polymers |
| US5264483A (en) | 1985-08-27 | 1993-11-23 | Rohm And Haas Company | Imide polymers |
| US4954574A (en) | 1985-08-27 | 1990-09-04 | Rohm And Haas Company | Imide polymers |
| US5004777A (en) | 1985-08-27 | 1991-04-02 | Rohm And Haas Company | Imide polymers |
| US4766168A (en) | 1986-04-15 | 1988-08-23 | E. I. Du Pont De Nemours And Company | Stabilized polyacetal compositions |
| US4814397A (en) | 1986-04-15 | 1989-03-21 | E. I. Du Pont De Nemours And Company | Stabilized polyacetal compositions |
| JP2600816B2 (ja) | 1988-07-04 | 1997-04-16 | 富士通株式会社 | Ｉｃソケット |
| US5011890A (en) | 1989-03-17 | 1991-04-30 | E. I. Du Pont De Nemours And Company | Polyacetal resins containing non-meltable polymer stabilizers |
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- 2012-11-07 DE DE112012004979.9T patent/DE112012004979B4/de active Active
- 2012-11-07 JP JP2014543486A patent/JP2014533770A/ja active Pending
- 2012-11-07 WO PCT/US2012/063921 patent/WO2013081785A1/en active Application Filing
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10808067B2 (en) | 2017-11-30 | 2020-10-20 | Hyundai Motor Company | Polyoxymethylene resin composition and molded article manufactured with the same |
| JP7527303B2 (ja) | 2019-03-13 | 2024-08-02 | デュポン ポリマーズ インコーポレイテッド | ポリオキシメチレン組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013081785A1 (en) | 2013-06-06 |
| DE112012004979B4 (de) | 2019-03-07 |
| DE112012004979T5 (de) | 2014-08-28 |
| CN104254550A (zh) | 2014-12-31 |
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