JP2014200711A - ポリシラン誘導体を含むエマルション、ポリシラン誘導体を含むマイクロカプセル、及びケイ素単体を含む活物質粒子、並びにこれらの製造方法 - Google Patents
ポリシラン誘導体を含むエマルション、ポリシラン誘導体を含むマイクロカプセル、及びケイ素単体を含む活物質粒子、並びにこれらの製造方法 Download PDFInfo
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- JP2014200711A JP2014200711A JP2013076680A JP2013076680A JP2014200711A JP 2014200711 A JP2014200711 A JP 2014200711A JP 2013076680 A JP2013076680 A JP 2013076680A JP 2013076680 A JP2013076680 A JP 2013076680A JP 2014200711 A JP2014200711 A JP 2014200711A
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- emulsion
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- active material
- polymerizable monomer
- polysilane derivative
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- 235000010288 sodium nitrite Nutrition 0.000 description 1
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- 239000012798 spherical particle Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
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- 239000005720 sucrose Substances 0.000 description 1
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- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
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- 125000006296 sulfonyl amino group Chemical group [H]N(*)S(*)(=O)=O 0.000 description 1
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- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- JIYXDFNAPHIAFH-UHFFFAOYSA-N tert-butyl 3-tert-butylperoxycarbonylbenzoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC(C(=O)OC(C)(C)C)=C1 JIYXDFNAPHIAFH-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
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- 125000001544 thienyl group Chemical group 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000004306 triazinyl group Chemical group 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229960000834 vinyl ether Drugs 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 238000000733 zeta-potential measurement Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Colloid Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Manufacturing Of Micro-Capsules (AREA)
Abstract
【解決手段】特定の孔を通過させる工程を経て内部にポリシラン誘導体を含むW/O/W型、S/O/W型、又はO/W型エマルションを製造し、次いで、エマルションの油相のモノマーを重合させてマイクロカプセルを製造し、そして、マイクロカプセルの有機物を炭素化することで、単分散の球状活物質粒子を得る。
【選択図】なし
Description
R1、R2、R3、R4は水素、置換基で置換されていても良いアルキル基、置換基で置換されていても良いアルケニル基、置換基で置換されていても良いアルキニル基、置換基で置換されていても良い芳香族基、ハロゲン、水酸基、置換基で置換されていても良いアルコキシ基、−OC(O)R5からそれぞれ独立に選択され、R5は置換基で置換されていても良いアルキル基であり、nは2以上の整数である。
R6、R7は水素、置換基で置換されていても良いアルキル基、置換基で置換されていても良いアルケニル基、置換基で置換されていても良いアルキニル基、置換基で置換されていても良い芳香族基、ハロゲン、水酸基、置換基で置換されていても良いアルコキシ基、−OC(O)R8からそれぞれ独立に選択され、R8は置換基で置換されていても良いアルキル基であり、mは3以上の整数である。
変動係数(CV(%))=(平均粒径の標準偏差/平均粒径)×100
本発明のW/O/W型エマルションを以下のとおり製造した。
得られたW/O/W型エマルション含有液を、窒素ガス雰囲気下、70℃に加温して、500rpmの速度で20時間撹拌した。その結果、W/O/W型エマルションの油相に含まれるスチレンが重合しポリスチレンとなったマイクロカプセルを得た。光学顕微鏡及び走査型電子顕微鏡で観察したところ、粒径54μm程度のマイクロカプセルを多数確認できた。
2kWの高周波加熱炉を用いて、本発明のマイクロカプセルをAr雰囲気下600℃で20分間加熱焼成した。誘導加熱による熱が均一になるように、本発明のマイクロカプセルはカーボン坩堝内に収納され、さらにその坩堝が銅箔で包まれた状態で焼成された。
得られた活物質粒子を走査型電子顕微鏡で観察したところ、ポリスチレンおよび架橋剤であるエチレングリコールジメタクリレートが炭化された、粒径3μm程度の炭化複合型Si活物質球状粒子を多数確認できた。
焼成後の本発明の活物質粒子の走査型電子顕微鏡写真を図7〜図10に示す。
エチレングリコールジメタクリレートをジビニルベンゼンに替えた以外は、実施例1と同様の方法で、本発明のW/O/W型エマルション、マイクロカプセル及び活物質粒子を製造した。
実施例1と同様の方法でW/O型エマルション含有液を得た。
実施例1に記載の連続相溶液とW/O型エマルション含有液を混合した後、超音波乳化機を用いて150W、40kHzの条件下で超音波を発生させ、W/O/W型エマルションを形成させた。
得られたW/O/W型エマルション含有液を、孔径10〜30μmのSPG膜を備えた窒素ガス加圧タイプのSPG膜乳化装置(SPGテクノ株式会社製)の分散相タンクに充填した。分散相タンクのW/O/W型エマルション含有液を6kPaの圧力で加圧し、SPG膜を通過させ(第2孔通過工程に相当する。)、本発明のW/O/W型エマルションを得た。
以下、実施例1と同様の方法で、マイクロカプセル及び活物質粒子を製造した。
実施例1と同様の方法で本発明のW/O/W型エマルションを製造した。
W/O/W型エマルション含有液を-30℃で凍結させ、次いで真空乾燥させて、氷(外相の水)を除去した。得られた粒子を電気炉に仕込み、Ar雰囲気中、100℃に加熱し、2時間保持することで、油相のスチレンを重合させてマイクロカプセルを形成させた。重合後にさらに電気炉を600℃に昇温し、20分保持することで、マイクロカプセルを焼成し、活物質粒子を得た。
本発明のO/W型エマルションを以下のとおり製造した。
市販のポリシラン誘導体2.0gを実施例1又は実施例2の重合性モノマーを含む有機溶媒に溶解した。
得られたポリシラン誘導体溶液を、孔径10〜30μmのSPG膜を備えた窒素ガス加圧タイプのSPG膜乳化装置(SPGテクノ株式会社製)の分散相タンクに充填し、また、実施例1で用いたのと同等の連続相溶液をSPG膜乳化装置の連続相容器に充填した。分散相タンクのポリシラン誘導体溶液を6kPaの圧力で加圧し、SPG膜を通過させた。そして、SPG膜通過液を、500rpmの速度で撹拌中の連続相溶液に分散させて、O/W型エマルションを得た。光学顕微鏡で観察したところ、粒径30μm程度のO/W型エマルションを多数確認できた。
得られたO/W型エマルション含有液を、窒素ガス雰囲気下、70℃に加温して、500rpmの速度で20時間撹拌した。その結果、O/W型エマルションの油相に含まれるスチレンが重合しポリスチレンとなったマイクロカプセルを得た。光学顕微鏡及び走査型電子顕微鏡で観察したところ、粒径54μm程度のマイクロカプセルを多数確認できた。
実施例1の活物質粒子を用いて以下のとおりに電池を作製した。実施例1の活物質粒子45質量部と、天然黒鉛粉末40質量部と、アセチレンブラック5質量部と、バインダー溶液33質量部とを混合してスラリーを調製した。バインダー溶液としては、ポリアミドイミド(PAI)樹脂をN-メチル−2−ピロリドンに30質量%の濃度で溶解させた溶液を用いた。このスラリーを、厚さ約20μmの電解銅箔(集電体)の表面にドクターブレードを用いて塗布し、銅箔上に負極活物質層を形成させた。その後、ロールプレス機により、集電体と負極活物質層を強固に密着接合させた。これを100℃で2時間真空乾燥し、負極活物質層の厚さが16μmの負極を形成した。
応用実施例1で用いた実施例1の活物質粒子を、市販のポリシラン誘導体に変更した以外は、応用実施例1と同様にして、リチウムイオン二次電池を得た。
応用実施例1及び比較例1のリチウムイオン二次電池について、温度25℃、電流0.2mAの条件で充電した際の初期充電容量を測定し、続けて、電流0.2mAの条件で放電させた際の放電容量を測定した。初期効率(放電容量/充電容量×100(%))を算出し、その結果を表2に示す。
Claims (8)
- 重合性モノマーを含む有機溶媒にポリシラン誘導体を含む極性液を加えるW/O型エマルション形成工程、重合性モノマーを含む有機溶媒にポリシラン誘導体を分散させるS/O型サスペンション形成工程、重合性モノマーを含む有機溶媒にポリシラン誘導体を溶解する溶解工程のいずれかから選択される第1工程と、
前記第1工程で得られた液を、孔を有する膜又は隔壁の該孔を通過させる第1孔通過工程と、
前記第1孔通過工程を経た液を極性の連続相溶液に分散させる第1エマルション形成工程と、
を有することを特徴とするW/O/W型、S/O/W型又はO/W型エマルションの製造方法。 - 重合性モノマーを含む有機溶媒にポリシラン誘導体を含む極性液を加えるW/O型エマルション形成工程、重合性モノマーを含む有機溶媒にポリシラン誘導体を分散させるS/O型サスペンション形成工程、重合性モノマーを含む有機溶媒にポリシラン誘導体を溶解する溶解工程のいずれかから選択される第1工程と、
前記第1工程で得られた液を極性の連続相溶液に分散させる第2エマルション形成工程と、
前記第2エマルション形成工程で形成されたエマルション含有溶液を、孔を有する膜又は隔壁の該孔を通過させる第2孔通過工程と、
を有することを特徴とするW/O/W型、S/O/W型又はO/W型エマルションの製造方法。 - 請求項1又は2に記載の製造方法で得られたW/O/W型、S/O/W型、又はO/W型エマルションに含まれる重合性モノマーを重合させる重合工程を有するマイクロカプセルの製造方法。
- 請求項3に記載の製造方法で得られたマイクロカプセルを焼成する焼成工程を有する活物質粒子の製造方法。
- ポリシラン誘導体を含む内水相若しくはポリシラン誘導体を含む固体相、重合性モノマーを含む油相及び外水相からなるW/O/W型又はS/O/W型エマルション。
- ポリシラン誘導体及び重合性モノマーを含む油相、並びに外水相からなるO/W型エマルション。
- ポリシラン誘導体を含有し、油相の主成分がポリマーであるマイクロカプセル。
- ケイ素単体を含有し、残部の主成分が炭素である球状の活物質粒子。
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018172431A1 (fr) * | 2017-03-21 | 2018-09-27 | Calyxia | Procédé de préparation de capsules avec des propriétés de rétention améliorées et capsules obtenues |
CN114975943A (zh) * | 2022-06-08 | 2022-08-30 | 陕西科技大学 | 基于乳化自组装法构建明胶/硅纳米颗粒微球的制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09501983A (ja) * | 1994-01-27 | 1997-02-25 | ワッカー−ケミー・ゲゼルシャフト・ミツト・ベシュレンクテル・ハフツング | 再分散性ケイ素変性分散粉末組成物、その製造方法及びその使用 |
JP2000243396A (ja) * | 1999-02-23 | 2000-09-08 | Hitachi Ltd | リチウム二次電池とその製造方法及びその負極材並びに電気機器 |
US20040152788A1 (en) * | 2003-01-31 | 2004-08-05 | Wu Huey Shen | Uniform emulsion by membrane emulsification |
WO2011062132A1 (ja) * | 2009-11-20 | 2011-05-26 | コニカミノルタホールディングス株式会社 | W/o/wエマルションの製造方法およびこれを用いたリポソームの製造方法、並びにこれらの方法に用いられる孔膜 |
JP2012204203A (ja) * | 2011-03-25 | 2012-10-22 | Mitsui Chemicals Inc | 非水系二次電池用バインダー樹脂組成物、非水系二次電池用負極及び非水系二次電池 |
-
2013
- 2013-04-02 JP JP2013076680A patent/JP5999439B2/ja not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09501983A (ja) * | 1994-01-27 | 1997-02-25 | ワッカー−ケミー・ゲゼルシャフト・ミツト・ベシュレンクテル・ハフツング | 再分散性ケイ素変性分散粉末組成物、その製造方法及びその使用 |
JP2000243396A (ja) * | 1999-02-23 | 2000-09-08 | Hitachi Ltd | リチウム二次電池とその製造方法及びその負極材並びに電気機器 |
US20040152788A1 (en) * | 2003-01-31 | 2004-08-05 | Wu Huey Shen | Uniform emulsion by membrane emulsification |
WO2011062132A1 (ja) * | 2009-11-20 | 2011-05-26 | コニカミノルタホールディングス株式会社 | W/o/wエマルションの製造方法およびこれを用いたリポソームの製造方法、並びにこれらの方法に用いられる孔膜 |
JP2012204203A (ja) * | 2011-03-25 | 2012-10-22 | Mitsui Chemicals Inc | 非水系二次電池用バインダー樹脂組成物、非水系二次電池用負極及び非水系二次電池 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018172431A1 (fr) * | 2017-03-21 | 2018-09-27 | Calyxia | Procédé de préparation de capsules avec des propriétés de rétention améliorées et capsules obtenues |
FR3064193A1 (fr) * | 2017-03-21 | 2018-09-28 | Calyxia | Procede de preparation de capsules avec des proprietes de retention ameliorees et capsules obtenues |
US11033872B2 (en) | 2017-03-21 | 2021-06-15 | Calyxia | Method for preparing capsules with improved retention properties and capsules obtained therefrom |
CN114975943A (zh) * | 2022-06-08 | 2022-08-30 | 陕西科技大学 | 基于乳化自组装法构建明胶/硅纳米颗粒微球的制备方法 |
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