JP2014156612A - 配合組成物 - Google Patents
配合組成物 Download PDFInfo
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- JP2014156612A JP2014156612A JP2014115627A JP2014115627A JP2014156612A JP 2014156612 A JP2014156612 A JP 2014156612A JP 2014115627 A JP2014115627 A JP 2014115627A JP 2014115627 A JP2014115627 A JP 2014115627A JP 2014156612 A JP2014156612 A JP 2014156612A
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- 239000000203 mixture Substances 0.000 title abstract description 33
- 238000002156 mixing Methods 0.000 title abstract 4
- 150000001875 compounds Chemical class 0.000 claims description 66
- -1 polyoxypropylene group Polymers 0.000 claims description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 10
- 239000012459 cleaning agent Substances 0.000 claims description 8
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 239000000344 soap Substances 0.000 claims 1
- 239000003093 cationic surfactant Substances 0.000 abstract description 18
- 239000002736 nonionic surfactant Substances 0.000 abstract description 9
- 230000000845 anti-microbial effect Effects 0.000 abstract 4
- 230000002070 germicidal effect Effects 0.000 abstract 4
- 230000000844 anti-bacterial effect Effects 0.000 description 75
- 239000000243 solution Substances 0.000 description 15
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 10
- 229960004670 didecyldimethylammonium chloride Drugs 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 239000003599 detergent Substances 0.000 description 8
- 238000013329 compounding Methods 0.000 description 7
- 239000003205 fragrance Substances 0.000 description 7
- 239000002781 deodorant agent Substances 0.000 description 6
- 239000000645 desinfectant Substances 0.000 description 6
- 229920001817 Agar Polymers 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 239000008272 agar Substances 0.000 description 4
- 239000003242 anti bacterial agent Substances 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- 230000007794 irritation Effects 0.000 description 4
- 239000002453 shampoo Substances 0.000 description 4
- 229920003002 synthetic resin Polymers 0.000 description 4
- 239000000057 synthetic resin Substances 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- 230000000843 anti-fungal effect Effects 0.000 description 3
- 229940121375 antifungal agent Drugs 0.000 description 3
- 229960000686 benzalkonium chloride Drugs 0.000 description 3
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 3
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 3
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 3
- 238000011010 flushing procedure Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 description 2
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 229960001950 benzethonium chloride Drugs 0.000 description 2
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical group [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 description 2
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 2
- 239000005018 casein Substances 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000077 insect repellent Substances 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002504 physiological saline solution Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- JMHWNJGXUIJPKG-UHFFFAOYSA-N CC(=O)O[SiH](CC=C)OC(C)=O Chemical compound CC(=O)O[SiH](CC=C)OC(C)=O JMHWNJGXUIJPKG-UHFFFAOYSA-N 0.000 description 1
- CXRFDZFCGOPDTD-UHFFFAOYSA-M Cetrimide Chemical compound [Br-].CCCCCCCCCCCCCC[N+](C)(C)C CXRFDZFCGOPDTD-UHFFFAOYSA-M 0.000 description 1
- 239000004155 Chlorine dioxide Substances 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- 235000010254 Jasminum officinale Nutrition 0.000 description 1
- 240000005385 Jasminum sambac Species 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 244000246386 Mentha pulegium Species 0.000 description 1
- 235000016257 Mentha pulegium Nutrition 0.000 description 1
- 235000004357 Mentha x piperita Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 241000736892 Thujopsis dolabrata Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 235000016720 allyl isothiocyanate Nutrition 0.000 description 1
- TUFYVOCKVJOUIR-UHFFFAOYSA-N alpha-Thujaplicin Natural products CC(C)C=1C=CC=CC(=O)C=1O TUFYVOCKVJOUIR-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- 229960001927 cetylpyridinium chloride Drugs 0.000 description 1
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940078672 didecyldimethylammonium Drugs 0.000 description 1
- WLCFKPHMRNPAFZ-UHFFFAOYSA-M didodecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCC WLCFKPHMRNPAFZ-UHFFFAOYSA-M 0.000 description 1
- ZCPCLAPUXMZUCD-UHFFFAOYSA-M dihexadecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCC ZCPCLAPUXMZUCD-UHFFFAOYSA-M 0.000 description 1
- RSHHCURRBLAGFA-UHFFFAOYSA-M dimethyl-di(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCC RSHHCURRBLAGFA-UHFFFAOYSA-M 0.000 description 1
- LOKCTEFSRHRXRJ-UHFFFAOYSA-I dipotassium trisodium dihydrogen phosphate hydrogen phosphate dichloride Chemical compound P(=O)(O)(O)[O-].[K+].P(=O)(O)([O-])[O-].[Na+].[Na+].[Cl-].[K+].[Cl-].[Na+] LOKCTEFSRHRXRJ-UHFFFAOYSA-I 0.000 description 1
- 235000021186 dishes Nutrition 0.000 description 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
- XJWSAJYUBXQQDR-UHFFFAOYSA-M dodecyltrimethylammonium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)C XJWSAJYUBXQQDR-UHFFFAOYSA-M 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical class C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- XQSBLCWFZRTIEO-UHFFFAOYSA-N hexadecan-1-amine;hydrobromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[NH3+] XQSBLCWFZRTIEO-UHFFFAOYSA-N 0.000 description 1
- 235000001050 hortel pimenta Nutrition 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000002953 phosphate buffered saline Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 229940068968 polysorbate 80 Drugs 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- CEYYIKYYFSTQRU-UHFFFAOYSA-M trimethyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)C CEYYIKYYFSTQRU-UHFFFAOYSA-M 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 229930007845 β-thujaplicin Natural products 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
【解決手段】抗菌・殺菌作用を有する特定のカチオン性界面活性剤、および特定のノニオン性界面活性剤を含有する配合組成物に関する。カチオン性界面活性剤の重量濃度が0.1〜5.0ppmであることが好ましく、前記カチオン性界面活性剤1重量部に対して、前記ノニオン性界面活性剤が3重量部以上であることが好ましい。
【選択図】なし
Description
下記一般式(1):
下記一般式(2):
で表され、ポリオキシプロピレン残基の平均分子量が1300〜4000であり、かつエチレンオキサイドの含有率が0〜45重量%である化合物
を含有する配合組成物に関する。
で表される化合物、および
下記一般式(2):
で表され、ポリオキシプロピレン残基の平均分子量が1300〜4000であり、かつエチレンオキサイドの含有率が0〜45重量%である化合物
を含有する。ここで、前記一般式(1)で表される化合物は、本明細書中において「化合物(1)」といい、前記一般式(2)で表され、ポリオキシプロピレン残基の平均分子量が1300〜4000であり、かつエチレンオキサイドの含有率が0〜45重量%である化合物は、本明細書中において「化合物(2)」という。
滅菌精製水(大塚製薬株式会社製)を用いて、ジデシルジメチルアンモニウムクロライド(一般式(1)において、R1、R2=デシル基、R3、R4=メチル基)(三洋化成工業株式会社製)の6000ppm水溶液を調製した。調製した6000ppm水溶液を100倍希釈して60ppm水溶液とした後、さらに100倍希釈して0.6ppm水溶液を調製した。その水溶液に、表1に記載したポリオキシエチレン・ポリオキシプロピレングリコール(一般式(2)において、l=2、m=30、n=2)(エパン610、第一工業製薬株式会社製)を各濃度(6、8、10ppm)となるように添加、撹拌して配合組成物を作製した。
エパン610の代わりに、表1に記載した一般式(2)で表される化合物(ノニオン性界面活性剤)を使用した以外は、実施例1と同様の方法で配合組成物を作製した。
得られた配合組成物の殺菌効果を、以下の方法で評価した。
A溶液:滅菌生理食塩水(大塚製薬株式会社)のみ(ブランク)
B溶液:0.3ppmジデシルジメチルアンモニウムクロライド(化合物(1))のみの水溶液
C溶液:4〜10ppm濃度の各種ノニオン性界面活性剤(表1に記載の一般式(2)で表される化合物)のみの水溶液
D溶液:実施例1〜6及び比較例1〜9の水溶液
抗菌活性値=log[A(滅菌生理食塩水のみ)の菌数]―log[B〜Dの各溶液それぞれの菌数]
1未満 : ×
1以上2.0未満 : 〇
2.0以上 : ◎
Claims (6)
- 一般式(1)において、R1およびR2で表される置換基が炭素数8〜18のアルキル基であり、R3およびR4で表される置換基がメチル基である請求項1記載の水洗トイレ用洗浄剤。
- 一般式(1)で表される化合物の重量濃度が0.1〜5.0ppmである請求項1または2に記載の水洗トイレ用洗浄剤。
- 一般式(1)で表される化合物の重量濃度が0.3〜0.8ppmである請求項3に記載の水洗トイレ用洗浄剤。
- 一般式(1)で表される化合物1重量部に対して、一般式(2)で表される化合物が3重量部以上である請求項1〜4のいずれか1項に記載の水洗トイレ用洗浄剤。
- オンタンク型である、請求項1〜5のいずれか1項に記載の水洗トイレ用洗浄剤。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014115627A JP5974043B2 (ja) | 2014-06-04 | 2014-06-04 | 配合組成物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014115627A JP5974043B2 (ja) | 2014-06-04 | 2014-06-04 | 配合組成物 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009224247A Division JP5581031B2 (ja) | 2009-09-29 | 2009-09-29 | 配合組成物 |
Publications (2)
Publication Number | Publication Date |
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JP2014156612A true JP2014156612A (ja) | 2014-08-28 |
JP5974043B2 JP5974043B2 (ja) | 2016-08-23 |
Family
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JP2014115627A Active JP5974043B2 (ja) | 2014-06-04 | 2014-06-04 | 配合組成物 |
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JP (1) | JP5974043B2 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018521202A (ja) * | 2015-05-19 | 2018-08-02 | エコラボ ユーエスエー インコーポレイティド | プラスチック及びすべてのタイプの器物上で効率的な界面活性剤系 |
Citations (2)
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---|---|---|---|---|
JPS54130607A (en) * | 1978-03-21 | 1979-10-11 | Jeyes Group Ltd | Production of tablet for cleaning flush toilet |
US6268327B1 (en) * | 1998-04-14 | 2001-07-31 | Reckitt Benckiser Inc. | Aqueous cleaning and disinfecting compositions based on quaternary ammonium componunds including alkylamphoacetates having reduced irritation characteristics |
-
2014
- 2014-06-04 JP JP2014115627A patent/JP5974043B2/ja active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54130607A (en) * | 1978-03-21 | 1979-10-11 | Jeyes Group Ltd | Production of tablet for cleaning flush toilet |
US6268327B1 (en) * | 1998-04-14 | 2001-07-31 | Reckitt Benckiser Inc. | Aqueous cleaning and disinfecting compositions based on quaternary ammonium componunds including alkylamphoacetates having reduced irritation characteristics |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018521202A (ja) * | 2015-05-19 | 2018-08-02 | エコラボ ユーエスエー インコーポレイティド | プラスチック及びすべてのタイプの器物上で効率的な界面活性剤系 |
US10550354B2 (en) | 2015-05-19 | 2020-02-04 | Ecolab Usa Inc. | Efficient surfactant system on plastic and all types of ware |
US10683466B2 (en) | 2015-05-19 | 2020-06-16 | Ecolab Usa Inc. | Efficient surfactant system on plastic and all types of ware |
US11198836B2 (en) | 2015-05-19 | 2021-12-14 | Ecolab Usa Inc. | Efficient surfactant system on plastic and all types of ware |
US11274265B2 (en) | 2015-05-19 | 2022-03-15 | Ecolab Usa. Inc. | Efficient surfactant system on plastic and all types of ware |
US11773346B2 (en) | 2015-05-19 | 2023-10-03 | Ecolab Usa Inc. | Efficient surfactant system on plastic and all types of ware |
US11912960B2 (en) | 2015-05-19 | 2024-02-27 | Ecolab Usa Inc. | Efficient surfactant system on plastic and all types of ware |
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