JP2013209241A - 5−アミノレブリン酸含有固形肥料及びその製造方法 - Google Patents
5−アミノレブリン酸含有固形肥料及びその製造方法 Download PDFInfo
- Publication number
- JP2013209241A JP2013209241A JP2012080428A JP2012080428A JP2013209241A JP 2013209241 A JP2013209241 A JP 2013209241A JP 2012080428 A JP2012080428 A JP 2012080428A JP 2012080428 A JP2012080428 A JP 2012080428A JP 2013209241 A JP2013209241 A JP 2013209241A
- Authority
- JP
- Japan
- Prior art keywords
- group
- solid fertilizer
- aminolevulinic acid
- acid
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 119
- 239000007787 solid Substances 0.000 title claims abstract description 104
- ZGXJTSGNIOSYLO-UHFFFAOYSA-N 88755TAZ87 Chemical compound NCC(=O)CCC(O)=O ZGXJTSGNIOSYLO-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 229960002749 aminolevulinic acid Drugs 0.000 title claims abstract description 61
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 49
- 150000003839 salts Chemical class 0.000 claims abstract description 13
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 12
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 10
- 125000002252 acyl group Chemical group 0.000 claims abstract description 9
- 125000004423 acyloxy group Chemical group 0.000 claims abstract description 9
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims abstract description 9
- 125000005194 alkoxycarbonyloxy group Chemical group 0.000 claims abstract description 9
- 125000003118 aryl group Chemical group 0.000 claims abstract description 8
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 7
- 125000002102 aryl alkyloxo group Chemical group 0.000 claims abstract description 7
- 125000004104 aryloxy group Chemical group 0.000 claims abstract description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 6
- 125000003277 amino group Chemical group 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 17
- 239000002994 raw material Substances 0.000 claims description 15
- 239000002374 bone meal Substances 0.000 claims description 11
- 229940036811 bone meal Drugs 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 13
- 210000000988 bone and bone Anatomy 0.000 abstract description 11
- 239000000843 powder Substances 0.000 abstract description 6
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 238000003860 storage Methods 0.000 description 34
- 239000003795 chemical substances by application Substances 0.000 description 24
- 125000004432 carbon atom Chemical group C* 0.000 description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 235000015165 citric acid Nutrition 0.000 description 14
- 230000001737 promoting effect Effects 0.000 description 14
- 230000012010 growth Effects 0.000 description 13
- 239000002245 particle Substances 0.000 description 12
- 241000196324 Embryophyta Species 0.000 description 11
- -1 n-propoxycarbonyl group Chemical group 0.000 description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 230000008635 plant growth Effects 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 230000007774 longterm Effects 0.000 description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 5
- 238000005469 granulation Methods 0.000 description 5
- 230000003179 granulation Effects 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 3
- 244000233513 Brassica perviridis Species 0.000 description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 229930003270 Vitamin B Natural products 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 3
- 235000019156 vitamin B Nutrition 0.000 description 3
- 239000011720 vitamin B Substances 0.000 description 3
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 2
- KPGXRSRHYNQIFN-UHFFFAOYSA-N 2-oxoglutaric acid Chemical compound OC(=O)CCC(=O)C(O)=O KPGXRSRHYNQIFN-UHFFFAOYSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 description 2
- RYQOILLJDKPETL-UHFFFAOYSA-N 5-aminolevulinic acid hexyl ester Chemical compound CCCCCCOC(=O)CCC(=O)CN RYQOILLJDKPETL-UHFFFAOYSA-N 0.000 description 2
- 229950000258 5-aminolevulinic acid hexyl ester Drugs 0.000 description 2
- 229950010481 5-aminolevulinic acid hydrochloride Drugs 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- DCXYFEDJOCDNAF-UHFFFAOYSA-N Asparagine Natural products OC(=O)C(N)CC(N)=O DCXYFEDJOCDNAF-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- DCXYFEDJOCDNAF-REOHCLBHSA-N L-asparagine Chemical compound OC(=O)[C@@H](N)CC(N)=O DCXYFEDJOCDNAF-REOHCLBHSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- NWBJYWHLCVSVIJ-UHFFFAOYSA-N N-benzyladenine Chemical compound N=1C=NC=2NC=NC=2C=1NCC1=CC=CC=C1 NWBJYWHLCVSVIJ-UHFFFAOYSA-N 0.000 description 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- LCTONWCANYUPML-UHFFFAOYSA-N Pyruvic acid Chemical compound CC(=O)C(O)=O LCTONWCANYUPML-UHFFFAOYSA-N 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 229940024606 amino acid Drugs 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 2
- 229960001230 asparagine Drugs 0.000 description 2
- 235000009582 asparagine Nutrition 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 2
- 230000002542 deteriorative effect Effects 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- OVBPIULPVIDEAO-LBPRGKRZSA-N folic acid Chemical compound C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-LBPRGKRZSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 125000003707 hexyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 2
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
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- 238000012423 maintenance Methods 0.000 description 2
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- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- YUUAYBAIHCDHHD-UHFFFAOYSA-N methyl 5-aminolevulinate Chemical compound COC(=O)CCC(=O)CN YUUAYBAIHCDHHD-UHFFFAOYSA-N 0.000 description 2
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- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
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- Fertilizers (AREA)
Abstract
【解決手段】次の成分(A)、(B)及び(C):
(A)下記一般式(I)
R2R1NCH2COCH2CH2COR3 (I)
(式中、R1及びR2は各々独立に、水素原子、アルキル基、アシル基、アルコキシカルボニル基、アリール基又はアラルキル基を示し;R3はヒドロキシ基、アルコキシ基、アシルオキシ基、アルコキシカルボニルオキシ基、アリールオキシ基、アラルキルオキシ基又はアミノ基を示す。)で表される5−アミノレブリン酸、その誘導体又はそれらの塩、
(B)骨粉、
(C)クエン酸
を含有することを特徴とする固形肥料。
【選択図】なし
Description
また、溶液で与える場合、5−アミノレブリン酸による成長促進効果の持続期間としては2週間程度であることが知られており、十分な成長促進効果を得るためには定期的な数多くの投与が必要であった。
従って、本発明の目的は施用回数が少なく、簡便に5−アミノレブリン酸の優れた植物成長促進効果を奏するための手段を提供することにある。
そこで、本発明者は、5−アミノレブリン酸が含有された固形肥料であって、成形性をそこなうことなく製造でき、かつ植物成長促進効果を有し、さらに保存安定性に優れた固形肥料を開発すべく、種々研究を重ねた結果、5−アミノレブリン酸含有固形肥料において、骨粉及びクエン酸を配合することにより、成形性をそこなうことなく製造でき、かつ長期保存安定性に優れた固形肥料が得られるとの知見を得て、本発明を完成するに至った。
[1]次の成分(A)、(B)及び(C):
(A)下記一般式(I)
R2R1NCH2COCH2CH2COR3 (I)
(式中、R1及びR2は各々独立に、水素原子、アルキル基、アシル基、アルコキシカルボニル基、アリール基又はアラルキル基を示し;R3はヒドロキシ基、アルコキシ基、アシルオキシ基、アルコキシカルボニルオキシ基、アリールオキシ基、アラルキルオキシ基又はアミノ基を示す。)で表される5−アミノレブリン酸、その誘導体又はそれらの塩、
(B)骨粉、
(C)クエン酸
を含有することを特徴とする固形肥料。
[2]水分含有量が、固形肥料全量中に10質量%以下である[1]記載の固形肥料。
[3]成分(A)を0.0001〜1質量%、成分(B)を10〜80質量%、成分(C)を6〜20質量%含有する[1]又は[2]記載の固形肥料。
[4]次の工程(a)及び(b):
(a)成分(B)及び成分(C)を含む固形肥料原料混合物に、下記一般式(I)
R2R1NCH2COCH2CH2COR3 (I)
(式中、R1及びR2は各々独立に、水素原子、アルキル基、アシル基、アルコキシカルボニル基、アリール基又はアラルキル基を示し;R3はヒドロキシ基、アルコキシ基、アシルオキシ基、アルコキシカルボニルオキシ基、アリールオキシ基、アラルキルオキシ基又はアミノ基を示す。)で表される5−アミノレブリン酸、その誘導体又はそれらの塩(A)を含有する溶液を噴霧添加する工程、
(b)成型する工程
を含むことを特徴とする[1]〜[3]のいずれかに記載の固形肥料の製造方法。
キシ基又はアラルキルオキシ基が好ましく、より好ましくはヒドロキシ基又は炭素数1〜12のアルコキシ基、特にメトキシ基又はヘキシルオキシ基が好ましい。
また、本発明の固形肥料中の成分(A)と成分(C)の含有質量比(A/C)は、保存安定性及び成形性の点から、0.0001〜0.15が好ましく、0.0001〜0.1がより好ましい。
硫酸アンモニウム、塩化カリウム、蒸製骨粉(粒径:0.1〜50mm)、菜種油かす、生ぬか、乾燥菌体、クエン酸で構成される肥料原料に、5−アミノレブリン酸として、0.3質量%、0.03質量%となるよう5−アミノレブリン酸塩酸塩(ALA・HCl)水溶液を噴霧添加し、ペレット造粒機で造粒した後、十分に温度を下げ、5−アミノレブリン酸含有固形肥料A〜Cをそれぞれ作製した。肥料原料は、肥料組成として、窒素(T−N)、リン酸(P2O5)、カリ(K2O)の含量でそれぞれ5−5−5%となるように配合した。この時、5−アミノレブリン酸塩酸塩を含まない同様の固形肥料Dも造粒した。調製した固形肥料A〜Dの組成を表1に示す。
〔実施例2〕5−アミノレブリン酸含有有機化成肥料による小松菜成長促進効果
実施例1で得られた5−アミノレブリン酸含有固形肥料を用いて、小松菜の成長促進効果を試験した。直径15cmのポリマルチポットに培養土0.8kgと、試験肥料10gと混合し、小松菜を4粒播種した。この時、施肥量はそれぞれ窒素の要素量当たりで10aあたり28kgであった。試験に用いる肥料は、ALA非含有固形肥料DとALA含有固形肥料A〜Cのそれぞれとを9:1の割合で混合させることで、5−アミノレブリン酸含有量がそれぞれ0.03%、0.003%および0.0003%の固形肥料E〜Gを作製し試験に用いた。固形肥料E〜Gの組成は表2の通りである。播種30日後、本葉展開時にポット当たり1株に間引きを行った。施肥58日後に収穫し、新鮮重量を測定することで小松菜の成長量を評価した(n=100)。結果を図1に示す。
固形有機質非含有固形肥料による小松菜成長促進効果
実施例1において、固形有機質のかわりに固形無機肥料原料を用い、この無機肥料原料に、5−アミノレブリン酸水溶液を噴霧することで、5−アミノレブリン酸濃度0.3、0.003%、0.003%の5−アミノレブリン酸含有無機肥料を作製した(5−アミノレブリン酸濃度0.3%の組成を組成5とする)。化成肥料の組成は、窒素(T−N)、リン酸(P2O5)、カリ(K2O)の含量でそれぞれ13−8−10%であった。
実施例2と同様の方法でコマツナの栽培試験を行った(n=100)。結果を図2に示す。
固形肥料Aにおける蒸製骨粉として、粒径:0.1mm未満のものを使用する以外は、実施例1と同様にして表3に示す組成の固形肥料Hを調製した。固形肥料Aおよび固形肥料Hの製造状況(製造装置安定性)および成形性(製品製造性)、調製した固形肥料の品質について、結果を表4に示す。
特に、表4にあるように、粒子径が0.1〜50mmの骨粉を原料として用いることにより、製造装置へ原料が付着することを防止することができ、安定的に固形肥料を製造することができる。
クエン酸含量を0、1、2、5、9.1%とする以外は、固形肥料Aと同様の組成で固形肥料I〜Lを配合した(ペレット造粒は未実施)。配合した固形肥料I〜Lについて、40℃、14日後の固形肥料中の5−アミノレブリン酸含有量を測定し、5−アミノレブリン酸残存率を算出した。結果を図3に示す。
表5に示す組成の固形肥料Mにおいて、吸湿させたもの(水分含量23%)、調製直後のもの(水分含量6.0%)、および40℃、14h乾燥を行なったもの(水分含量3.3%)の3種類の固形肥料について、40℃、外部湿度75%で密閉容器中に15日間保存した後の固形肥料に含まれる5−アミノレブリン酸含有量を測定した。保存後の固形肥料中の5−アミノレブリン酸残存率を図4に示す。
Claims (4)
- 次の成分(A)、(B)及び(C):
(A)下記一般式(I)
R2R1NCH2COCH2CH2COR3 (I)
(式中、R1及びR2は各々独立に、水素原子、アルキル基、アシル基、アルコキシカルボニル基、アリール基又はアラルキル基を示し;R3はヒドロキシ基、アルコキシ基、アシルオキシ基、アルコキシカルボニルオキシ基、アリールオキシ基、アラルキルオキシ基又はアミノ基を示す。)で表される5−アミノレブリン酸、その誘導体又はそれらの塩、
(B)骨粉、
(C)クエン酸
を含有することを特徴とする固形肥料。 - 水分含有量が、固形肥料全量中に10質量%以下である請求項1記載の固形肥料。
- 成分(A)を0.0001〜1質量%、成分(B)を10〜80質量%、成分(C)を6〜20質量%含有する請求項1又は2記載の固形肥料。
- 次の工程(a)及び(b):
(a)成分(B)および成分(C)を含む固形肥料原料混合物に、下記一般式(I)
R2R1NCH2COCH2CH2COR3 (I)
(式中、R1及びR2は各々独立に、水素原子、アルキル基、アシル基、アルコキシカルボニル基、アリール基又はアラルキル基を示し;R3はヒドロキシ基、アルコキシ基、アシルオキシ基、アルコキシカルボニルオキシ基、アリールオキシ基、アラルキルオキシ基又はアミノ基を示す。)で表される5−アミノレブリン酸、その誘導体又はそれらの塩(A)を含有する溶液を噴霧添加する工程、
(b)成形する工程
を含むことを特徴とする請求項1〜3のいずれかに記載の固形肥料の製造方法。
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Cited By (4)
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JP2014189469A (ja) * | 2013-03-28 | 2014-10-06 | Cosmo Oil Co Ltd | 5−アミノレブリン酸類含有固形肥料 |
JP6491380B1 (ja) * | 2018-03-19 | 2019-03-27 | 雅哉 齋藤 | 液肥成分含有穀物ペレットを混入した粒状混合固形肥料の製造方法 |
WO2020184327A1 (ja) * | 2019-03-11 | 2020-09-17 | 雅哉 齋藤 | 液肥成分含有有機物を内部に保持する固形肥料の製造方法 |
CN113875778A (zh) * | 2021-09-29 | 2022-01-04 | 季红进 | 含有植物免疫活性蛋白和5-氨基乙酰丙酸或其衍生物的生物刺激剂 |
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JPH08151304A (ja) * | 1994-11-28 | 1996-06-11 | Cosmo Sogo Kenkyusho:Kk | 植物の耐塩性向上剤 |
JPH10218691A (ja) * | 1997-02-03 | 1998-08-18 | Bio Sci Kk | 肥料組成物と散布方法 |
WO2007029775A1 (ja) * | 2005-09-09 | 2007-03-15 | Suntory Limited | 低照度栽培方法及び植物生長促進剤 |
JP2012031163A (ja) * | 2010-07-05 | 2012-02-16 | Seiwa:Kk | 5−アミノレブリン酸の補助剤及びその使用方法 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2014189469A (ja) * | 2013-03-28 | 2014-10-06 | Cosmo Oil Co Ltd | 5−アミノレブリン酸類含有固形肥料 |
JP6491380B1 (ja) * | 2018-03-19 | 2019-03-27 | 雅哉 齋藤 | 液肥成分含有穀物ペレットを混入した粒状混合固形肥料の製造方法 |
JP2019163179A (ja) * | 2018-03-19 | 2019-09-26 | 雅哉 齋藤 | 液肥成分含有穀物ペレットを混入した粒状混合固形肥料の製造方法 |
WO2020184327A1 (ja) * | 2019-03-11 | 2020-09-17 | 雅哉 齋藤 | 液肥成分含有有機物を内部に保持する固形肥料の製造方法 |
CN113875778A (zh) * | 2021-09-29 | 2022-01-04 | 季红进 | 含有植物免疫活性蛋白和5-氨基乙酰丙酸或其衍生物的生物刺激剂 |
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