JP2013133329A - 新規有機化合物 - Google Patents
新規有機化合物 Download PDFInfo
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- JP2013133329A JP2013133329A JP2011286778A JP2011286778A JP2013133329A JP 2013133329 A JP2013133329 A JP 2013133329A JP 2011286778 A JP2011286778 A JP 2011286778A JP 2011286778 A JP2011286778 A JP 2011286778A JP 2013133329 A JP2013133329 A JP 2013133329A
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- 0 Cc1c[s]c(-c2nc(*)c[s]2)n1 Chemical compound Cc1c[s]c(-c2nc(*)c[s]2)n1 0.000 description 3
- JJGOHQBRYCPZTQ-UHFFFAOYSA-N CC(C)Oc1cccc(OC)c1-c([s]c(-c1cc(C#N)c(-c(c(OC(C)C)ccc2)c2OC)[s]1)c1)c1C#N Chemical compound CC(C)Oc1cccc(OC)c1-c([s]c(-c1cc(C#N)c(-c(c(OC(C)C)ccc2)c2OC)[s]1)c1)c1C#N JJGOHQBRYCPZTQ-UHFFFAOYSA-N 0.000 description 1
- UKBLPNQNTUTUFX-UHFFFAOYSA-N CC(C)Oc1cccc(OC)c1-c([s]c(-c1cc(C(OC)=O)c(-c(c(OC(C)C)ccc2)c2OC)[s]1)c1)c1C(OC)=O Chemical compound CC(C)Oc1cccc(OC)c1-c([s]c(-c1cc(C(OC)=O)c(-c(c(OC(C)C)ccc2)c2OC)[s]1)c1)c1C(OC)=O UKBLPNQNTUTUFX-UHFFFAOYSA-N 0.000 description 1
- LNJMDHSHWARGDN-UHFFFAOYSA-N COC(c(cc1)ccc1-c1c(-c(c(OC)ccc2)c2OC)[s]c(-c2cc(-c(cc3)ccc3C(OC)=O)c(-c(c(OC)ccc3)c3OC)[s]2)c1)=O Chemical compound COC(c(cc1)ccc1-c1c(-c(c(OC)ccc2)c2OC)[s]c(-c2cc(-c(cc3)ccc3C(OC)=O)c(-c(c(OC)ccc3)c3OC)[s]2)c1)=O LNJMDHSHWARGDN-UHFFFAOYSA-N 0.000 description 1
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- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
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- Thiazole And Isothizaole Compounds (AREA)
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Abstract
Description
* Gaussian 03, Revision D.01,
M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria,
M. A. Robb, J. R. Cheeseman, J. A. Montgomery, Jr., T. Vreven,
K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi,
V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega,
G. A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota,
R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao,
H. Nakai, M. Klene, X. Li, J. E. Knox, H. P. Hratchian, J. B. Cross,
V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann,
O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski,
P. Y. Ayala, K. Morokuma, G. A. Voth, P. Salvador, J. J. Dannenberg,
V. G. Zakrzewski, S. Dapprich, A. D. Daniels, M. C. Strain,
O. Farkas, D. K. Malick, A. D. Rabuck, K. Raghavachari,
J. B. Foresman, J. V. Ortiz, Q. Cui, A. G. Baboul, S. Clifford,
J. Cioslowski, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz,
I. Komaromi, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham,
C. Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill,
B. Johnson, W. Chen, M. W. Wong, C. Gonzalez, and J. A. Pople,
Gaussian, Inc., Wallingford CT, 2004.
<例示化合物A−6の合成>
1H−NMR(CDCl3)σ(ppm):7.5(s,2H),7.17(t,2H),6.66(d,2H),6.63(d,2H),4.54(sept,2H),3.48(s,6H),1.32(s,12H).
13C−NMR(CDCl3)σ(ppm):158.27,156.32,134.26,128.23,128.06,115.18,108.30,104.70,71.78,56.24,22.49.
<例示化合物A−11の合成>
1H−NMR(CDCl3)σ(ppm):7.21(t,2H),6.63(d,2H),6.60(d,2H),4.41(m,2H),4.20(s,4H),3.81(s,6H),1.25(s,6H),1.24(s,6H).
13C−NMR(CDCl3)σ(ppm):159.01,157.52,138.10,129.20,112.07,108.96,108.36,104.53,71.80,64.49,56.06,22.23.
<例示化合物A−18の合成>
1H−NMR(CDCl3)σ(ppm):7.3(t,2H),6.62(d,2H),6.58(d,2H),4.48(m,2H),3.75(s,6H),2.51(br,4H),1.64(m,4H),1.56(d,12H)、1.29−1.13(m、20H)、0.81(t,6H).
13C−NMR(CDCl3)σ(ppm):160.89,159.47,157.61,156.54,130.33,125.07,110.58,107.01,103.68,71.06,56.06,32.05,30.36,29.36,29.28,22.96,22.43,22.39,14.46.
<例示化合物B−7の合成>
1H−NMR(CDCl3)σ(ppm):7.48(d,2H),7.18(t,2H),7.17(d,2H),6.65(d,2H),6.62(d,2H),4.58(sept,2H),3.87(s,6H),1.36(s,12H).
13C−NMR(CDCl3)σ(ppm):158.12,156.14,137.72,133.35,130.02,128.42,122.49,114.24,107.88,104.54,71.88,56.27,22.46.
<例示化合物B−5の合成>
1H−NMR(CDCl3)σ(ppm):7.21(t,2H),6.61(d,2H),6.58(d,2H),4.43(sept,2H),4.14(br,8H),3.79(s,6H),1.24(d,12H).
13C−NMR(CDCl3)σ(ppm):159.52,157.85,138.58,136.46,129.74,111.49,108.52,107.11,104.46,71.66,65.21,64.84,56.43,22.54.
<例示化合物C−3の合成>
1H−NMR(CDCl3)σ(ppm):7.27(t,2H),7.06(s,2H),7.01(s,2H),6.62(d,2H),6.59(d,2H),4.43(m,2H),3.77(s,6H),2.31(t,4H),1.53(m,4H),1.32−1.10(m,24H),0.84(t,6H).
13C−NMR(CDCl3)σ(ppm):159.15,157.53,141.83,136.37,135.99,129.51,128.33,124.36,123.29,112.85,107.51,103.63,71.09,55.86,31.74,29.97,29.21,29.11,22.61,22.13,22.08,14.13.
<エレクトロクロミック特性>
実施例1から6に示した化合物をクロロホルムに溶解し、この溶液について紫外可視分光光度計(日本分光株式会社製V−560)を用いて中性状態(消色状態)における吸収スペクトルを測定した。また、酸化(着色)時の吸収スペクトルの測定は、作用電極に白金、対向電極に白金、参照電極に銀を用い、支持電解質としてのテトラブチルアンモニウム過塩素酸塩のジクロロメタン溶液(0.1mol/L)中に実施例の化合物を溶解(5.0×10−4mol/L)した溶液について、化合物の第一酸化電位以上で定電位酸化を行うことにより、その吸収スペクトル・透過率スペクトル変化を測定し、エレクトロクロミック特性の確認を行った。
<酸化還元サイクルの耐久安定性>
本発明に係る有機EC化合物A−6、A−11、A−18、B−1、B−5、C−3および比較例として公知の化合物Ref−1の酸化還元サイクルに対する耐久安定性を評価した。比較例の化合物Ref−1は公知の還元着色性EC化合物(ジエチルビオロゲンジパークロレート)である。Ref−1の構造式を下記に示す。
12 イソプロポキシ基およびメトキシ基が置換されたフェニル基
Claims (3)
- 下記一般式[1]で示されることを特徴とする有機化合物。
[1]
式中、A1およびA2は水素原子、炭素原子数1以上20以下のアルキル基、炭素原子数1以上20以下のアルコキシ基、置換基を有していてもよいアリール基からそれぞれ独立に選ばれる。
ただし、A1およびA2の少なくともいずれか一方は前記アルキル基、前記アルコキシ基または前記アリール基である。前記アリール基は炭素原子数1以上4以下のアルキル基または炭素原子数1以上4以下のアルコキシ基を置換基として有していてもよい。
R1は水素原子、ハロゲン原子、炭素原子数1以上20以下のアルキル基、炭素原子数1以上20以下のアルコキシ基、炭素原子数1以上20以下のアルキルエステル基、置換基を有していてもよいアリール基、置換基を有していても良いアミノ基、またはシアノ基を表す。前記アリール基は炭素原子数1以上4以下のアルキル基を置換基として有していてもよい。nは1から3で表わされる整数である。
Xは下記一般式[2]乃至[4]のいずれかの構造であり、nが2または3の場合、Xは下記構造よりそれぞれ独立に選ばれる。
[2]
[3]
[4]
式中、R2、R3、およびR5は水素原子、ハロゲン原子、炭素原子数1以上20以下のアルキル基、炭素原子数1以上20以下のアルコキシ基、置換基を有していてもよいアリール基、炭素原子数1以上20以下アルキルエステル基、置換基を有していても良いアミノ基、またはシアノ基からそれぞれ独立に選ばれる。R4は、炭素原子数1以上20以下アルキレン基である。 - 前記A1および前記A2の少なくともいずれか一方は炭素原子数1以上20以下のアルコキシ基であることを特徴とする請求項1に記載の有機化合物。
- 前記A1および前記A2の少なくともいずれか一方はメトキシ基またはイソプロポキシ基であることを特徴とする請求項2に記載の有機化合物。
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JP2014073996A (ja) * | 2012-10-05 | 2014-04-24 | Canon Inc | 新規有機化合物およびそれを有するエレクトロクロミック素子 |
WO2016006204A1 (en) * | 2014-07-11 | 2016-01-14 | Canon Kabushiki Kaisha | Electrochromic composition and electrochromic element |
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US10703722B2 (en) | 2010-04-27 | 2020-07-07 | Calcimedica, Inc. | Compounds that modulate intracellular calcium |
JP2015166338A (ja) | 2014-02-12 | 2015-09-24 | キヤノン株式会社 | 有機化合物及びこれを用いたエレクトロクロミック素子 |
CN114712513A (zh) | 2015-02-27 | 2022-07-08 | 钙医学公司 | 胰腺炎治疗 |
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WO2016006204A1 (en) * | 2014-07-11 | 2016-01-14 | Canon Kabushiki Kaisha | Electrochromic composition and electrochromic element |
JP2016020410A (ja) * | 2014-07-11 | 2016-02-04 | キヤノン株式会社 | エレクトロクロミック組成物およびエレクトロクロミック素子 |
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US9284328B2 (en) | 2016-03-15 |
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