JP2012524979A - 有機顔料による触媒粒径制御 - Google Patents
有機顔料による触媒粒径制御 Download PDFInfo
- Publication number
- JP2012524979A JP2012524979A JP2012507418A JP2012507418A JP2012524979A JP 2012524979 A JP2012524979 A JP 2012524979A JP 2012507418 A JP2012507418 A JP 2012507418A JP 2012507418 A JP2012507418 A JP 2012507418A JP 2012524979 A JP2012524979 A JP 2012524979A
- Authority
- JP
- Japan
- Prior art keywords
- fuel cell
- layer
- cell catalyst
- catalyst according
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 105
- 239000002245 particle Substances 0.000 title claims abstract description 35
- 239000012860 organic pigment Substances 0.000 title claims abstract description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 65
- 239000000446 fuel Substances 0.000 claims abstract description 33
- 239000000463 material Substances 0.000 claims abstract description 26
- 239000007787 solid Substances 0.000 claims abstract description 13
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 12
- 239000010409 thin film Substances 0.000 claims abstract description 11
- ZZSIDSMUTXFKNS-UHFFFAOYSA-N perylene red Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N(C(=O)C=1C2=C3C4=C(OC=5C=CC=CC=5)C=1)C(=O)C2=CC(OC=1C=CC=CC=1)=C3C(C(OC=1C=CC=CC=1)=CC1=C2C(C(N(C=3C(=CC=CC=3C(C)C)C(C)C)C1=O)=O)=C1)=C2C4=C1OC1=CC=CC=C1 ZZSIDSMUTXFKNS-UHFFFAOYSA-N 0.000 claims abstract description 9
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910001260 Pt alloy Inorganic materials 0.000 claims abstract description 5
- 125000003118 aryl group Chemical group 0.000 claims abstract description 5
- 239000010410 layer Substances 0.000 description 50
- 238000000576 coating method Methods 0.000 description 13
- 238000011068 loading method Methods 0.000 description 13
- 239000011248 coating agent Substances 0.000 description 12
- 239000012528 membrane Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 238000002441 X-ray diffraction Methods 0.000 description 7
- 238000000151 deposition Methods 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 230000008021 deposition Effects 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 238000001771 vacuum deposition Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000005566 electron beam evaporation Methods 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 238000000859 sublimation Methods 0.000 description 2
- 230000008022 sublimation Effects 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000010411 electrocatalyst Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000001017 electron-beam sputter deposition Methods 0.000 description 1
- 238000000313 electron-beam-induced deposition Methods 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002120 nanofilm Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000000717 platinum sputter deposition Methods 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 238000002061 vacuum sublimation Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
- H01M4/8867—Vapour deposition
- H01M4/8871—Sputtering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9008—Organic or organo-metallic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/921—Alloys or mixtures with metallic elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Catalysts (AREA)
- Inert Electrodes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17211109P | 2009-04-23 | 2009-04-23 | |
| US61/172,111 | 2009-04-23 | ||
| PCT/US2010/032204 WO2010124186A1 (en) | 2009-04-23 | 2010-04-23 | Catalyst particle size control with organic pigments |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2012524979A true JP2012524979A (ja) | 2012-10-18 |
| JP2012524979A5 JP2012524979A5 (enExample) | 2014-07-24 |
Family
ID=42315552
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012507418A Pending JP2012524979A (ja) | 2009-04-23 | 2010-04-23 | 有機顔料による触媒粒径制御 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20100273093A1 (enExample) |
| EP (1) | EP2422392A1 (enExample) |
| JP (1) | JP2012524979A (enExample) |
| CN (1) | CN102439773B (enExample) |
| WO (1) | WO2010124186A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5676334B2 (ja) * | 2011-03-28 | 2015-02-25 | 株式会社東芝 | 層状触媒層、膜電極接合体、および電気化学セル |
| US20140066299A1 (en) * | 2012-08-31 | 2014-03-06 | Basf Se | Particles Containing One Or More Multi-Layered Dots On Their Surface, Their Use, and Preparation of Such Particles |
| CN104701549B (zh) * | 2013-12-06 | 2017-02-22 | 中国科学院上海高等研究院 | 一种无碳膜电极组件 |
| JP7321100B2 (ja) * | 2017-06-05 | 2023-08-04 | スリーエム イノベイティブ プロパティズ カンパニー | 電極用触媒含有分散組成物及びそれによる物品 |
| US20220059849A1 (en) * | 2018-12-13 | 2022-02-24 | 3M Innovative Properties Company | Catalyst |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001520446A (ja) * | 1997-10-10 | 2001-10-30 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 膜電極の作製方法 |
| JP2003518721A (ja) * | 1999-12-29 | 2003-06-10 | スリーエム イノベイティブ プロパティズ カンパニー | 向上した改質油耐性のための亜酸化物燃料電池触媒 |
| JP2005087864A (ja) * | 2003-09-17 | 2005-04-07 | Matsushita Electric Ind Co Ltd | 電極触媒の製造方法 |
| JP2007507328A (ja) * | 2003-09-29 | 2007-03-29 | スリーエム イノベイティブ プロパティズ カンパニー | 燃料電池カソード触媒 |
| JP2009508318A (ja) * | 2005-09-13 | 2009-02-26 | スリーエム イノベイティブ プロパティズ カンパニー | 膜電極接合体の電流密度の均一性を高める触媒層 |
| JP2009512163A (ja) * | 2005-10-12 | 2009-03-19 | スリーエム イノベイティブ プロパティズ カンパニー | 燃料電池用ナノ触媒 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0419062D0 (en) * | 2004-08-27 | 2004-09-29 | Johnson Matthey Plc | Platinum alloy catalyst |
| US20080020923A1 (en) * | 2005-09-13 | 2008-01-24 | Debe Mark K | Multilayered nanostructured films |
| US8383293B2 (en) * | 2006-11-22 | 2013-02-26 | GM Global Technology Operations LLC | Supports for fuel cell catalysts based on transition metal silicides |
| US20100035124A1 (en) * | 2008-08-11 | 2010-02-11 | Gm Clobal Technology Operations, Inc. | Hybrid particle and core-shell electrode structure |
-
2010
- 2010-04-23 US US12/766,304 patent/US20100273093A1/en not_active Abandoned
- 2010-04-23 JP JP2012507418A patent/JP2012524979A/ja active Pending
- 2010-04-23 WO PCT/US2010/032204 patent/WO2010124186A1/en not_active Ceased
- 2010-04-23 CN CN201080018063.XA patent/CN102439773B/zh not_active Expired - Fee Related
- 2010-04-23 EP EP10719483A patent/EP2422392A1/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001520446A (ja) * | 1997-10-10 | 2001-10-30 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 膜電極の作製方法 |
| JP2003518721A (ja) * | 1999-12-29 | 2003-06-10 | スリーエム イノベイティブ プロパティズ カンパニー | 向上した改質油耐性のための亜酸化物燃料電池触媒 |
| JP2005087864A (ja) * | 2003-09-17 | 2005-04-07 | Matsushita Electric Ind Co Ltd | 電極触媒の製造方法 |
| JP2007507328A (ja) * | 2003-09-29 | 2007-03-29 | スリーエム イノベイティブ プロパティズ カンパニー | 燃料電池カソード触媒 |
| JP2009508318A (ja) * | 2005-09-13 | 2009-02-26 | スリーエム イノベイティブ プロパティズ カンパニー | 膜電極接合体の電流密度の均一性を高める触媒層 |
| JP2009512163A (ja) * | 2005-10-12 | 2009-03-19 | スリーエム イノベイティブ プロパティズ カンパニー | 燃料電池用ナノ触媒 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102439773B (zh) | 2014-12-24 |
| WO2010124186A1 (en) | 2010-10-28 |
| US20100273093A1 (en) | 2010-10-28 |
| EP2422392A1 (en) | 2012-02-29 |
| CN102439773A (zh) | 2012-05-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4837822B2 (ja) | 膜電極組体のための触媒 | |
| EP2736633B1 (en) | Cost-effective core-shell catalyst with high electrochemical stability | |
| US8603400B2 (en) | Nanostructured platinum alloys for use as catalyst materials | |
| JP6117728B2 (ja) | 相互混合した無機物による触媒特性制御 | |
| US11936050B2 (en) | Pt—Ni—Ir catalyst for fuel cell | |
| US20150093685A1 (en) | Platinum Based Oxygen Reaction Reduction Catalyst | |
| JP2012524979A (ja) | 有機顔料による触媒粒径制御 | |
| JP2019534148A (ja) | 燃料電池用pt−ni−ir触媒 | |
| CN112042023B (zh) | 催化剂 | |
| EP3776702A1 (en) | Catalyst comprising pt, ni, and ta | |
| WO2023279563A1 (zh) | 薄膜催化剂的生产设备及生产方法 | |
| Garsuch et al. | Alternative catalyst supports deposited on nanostructured thin films for proton exchange membrane fuel cells | |
| Torimoto et al. | Top‐Down Synthesis Methods for Nanoscale Catalysts | |
| Yin et al. | Preparation of anatase, rutile and brookite type anion doped titania photocatalyst nanoparticles and thin films | |
| EP3895238B1 (en) | Catalyst | |
| CN117684128A (zh) | 金属材料及其制备方法 | |
| US20130209898A1 (en) | Mesostructured thin-films as electrocatalysts with tunable compositions and surface morphology | |
| Bernsmeier | Noble metal nanoparticles supported in ordered mesoporous carbon coatings as efficient electrocatalysts for the hydrogen evolution reaction | |
| CN116673042A (zh) | 一种单原子金属催化剂及其制备方法和应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130326 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20130326 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130821 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130827 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140218 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20140515 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20140522 |
|
| A524 | Written submission of copy of amendment under article 19 pct |
Free format text: JAPANESE INTERMEDIATE CODE: A524 Effective date: 20140605 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20141209 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150306 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20150804 |