JP2012515238A - 液体光開始剤ブレンド - Google Patents
液体光開始剤ブレンド Download PDFInfo
- Publication number
- JP2012515238A JP2012515238A JP2011545704A JP2011545704A JP2012515238A JP 2012515238 A JP2012515238 A JP 2012515238A JP 2011545704 A JP2011545704 A JP 2011545704A JP 2011545704 A JP2011545704 A JP 2011545704A JP 2012515238 A JP2012515238 A JP 2012515238A
- Authority
- JP
- Japan
- Prior art keywords
- hydroxy
- irgacure
- phenyl
- methyl
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 99
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- 239000003085 diluting agent Substances 0.000 claims abstract description 15
- 239000007787 solid Substances 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 150000003254 radicals Chemical class 0.000 claims abstract description 5
- -1 fatty acid amine Chemical class 0.000 claims description 45
- 239000003973 paint Substances 0.000 claims description 18
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 17
- 239000000194 fatty acid Substances 0.000 claims description 17
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- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 11
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 9
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 9
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 8
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- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 claims description 8
- 150000004665 fatty acids Chemical class 0.000 claims description 8
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 6
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- LFOXEOLGJPJZAA-UHFFFAOYSA-N [(2,6-dimethoxybenzoyl)-(2,4,4-trimethylpentyl)phosphoryl]-(2,6-dimethoxyphenyl)methanone Chemical compound COC1=CC=CC(OC)=C1C(=O)P(=O)(CC(C)CC(C)(C)C)C(=O)C1=C(OC)C=CC=C1OC LFOXEOLGJPJZAA-UHFFFAOYSA-N 0.000 claims description 5
- GUCYFKSBFREPBC-UHFFFAOYSA-N [phenyl-(2,4,6-trimethylbenzoyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C(=O)C1=C(C)C=C(C)C=C1C GUCYFKSBFREPBC-UHFFFAOYSA-N 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
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- MRBZZNMTRWISRD-UHFFFAOYSA-N 2-hydroxy-1-[4-[5-(2-hydroxy-2-methylpropanoyl)-1,3,3-trimethyl-2h-inden-1-yl]phenyl]-2-methylpropan-1-one Chemical compound C1=CC(C(=O)C(C)(O)C)=CC=C1C1(C)C2=CC=C(C(=O)C(C)(C)O)C=C2C(C)(C)C1 MRBZZNMTRWISRD-UHFFFAOYSA-N 0.000 claims description 4
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- MWDGNKGKLOBESZ-UHFFFAOYSA-N 2-oxooctanal Chemical compound CCCCCCC(=O)C=O MWDGNKGKLOBESZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000003999 initiator Substances 0.000 claims description 3
- 229920005604 random copolymer Polymers 0.000 claims description 3
- PUBNJSZGANKUGX-UHFFFAOYSA-N 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=C(C)C=C1 PUBNJSZGANKUGX-UHFFFAOYSA-N 0.000 claims description 2
- JLZIXYIYQIKFHP-UHFFFAOYSA-N 2-methyl-1-(4-methylphenyl)-2-morpholin-4-ylpropane-1-thione Chemical compound C1=CC(C)=CC=C1C(=S)C(C)(C)N1CCOCC1 JLZIXYIYQIKFHP-UHFFFAOYSA-N 0.000 claims description 2
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- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
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- 238000001723 curing Methods 0.000 description 7
- 150000002148 esters Chemical group 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
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- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 5
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 5
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 5
- 239000004435 Oxo alcohol Substances 0.000 description 5
- 238000003848 UV Light-Curing Methods 0.000 description 5
- 125000002947 alkylene group Chemical group 0.000 description 5
- 229920001983 poloxamer Polymers 0.000 description 5
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 5
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- 238000003756 stirring Methods 0.000 description 5
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 5
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- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
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- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 3
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
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- FHLPGTXWCFQMIU-UHFFFAOYSA-N [4-[2-(4-prop-2-enoyloxyphenyl)propan-2-yl]phenyl] prop-2-enoate Chemical compound C=1C=C(OC(=O)C=C)C=CC=1C(C)(C)C1=CC=C(OC(=O)C=C)C=C1 FHLPGTXWCFQMIU-UHFFFAOYSA-N 0.000 description 1
- 150000008062 acetophenones Chemical class 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 150000008365 aromatic ketones Chemical class 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 229960002903 benzyl benzoate Drugs 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- AJCHRUXIDGEWDK-UHFFFAOYSA-N bis(ethenyl) butanedioate Chemical compound C=COC(=O)CCC(=O)OC=C AJCHRUXIDGEWDK-UHFFFAOYSA-N 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- XASDPFJPXUSDAO-UHFFFAOYSA-N bis[4-(chloromethyl)phenyl]methanone;methyl 2-benzoylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C(=O)C1=CC=CC=C1.C1=CC(CCl)=CC=C1C(=O)C1=CC=C(CCl)C=C1 XASDPFJPXUSDAO-UHFFFAOYSA-N 0.000 description 1
- VYHBFRJRBHMIQZ-UHFFFAOYSA-N bis[4-(diethylamino)phenyl]methanone Chemical compound C1=CC(N(CC)CC)=CC=C1C(=O)C1=CC=C(N(CC)CC)C=C1 VYHBFRJRBHMIQZ-UHFFFAOYSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
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- 150000001639 boron compounds Chemical class 0.000 description 1
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
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- 239000000084 colloidal system Substances 0.000 description 1
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- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
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- 150000002170 ethers Chemical class 0.000 description 1
- 125000005677 ethinylene group Chemical group [*:2]C#C[*:1] 0.000 description 1
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- 235000019382 gum benzoic Nutrition 0.000 description 1
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- 235000012907 honey Nutrition 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
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- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- BOWVQLFMWHZBEF-KTKRTIGZSA-N oleoyl ethanolamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCO BOWVQLFMWHZBEF-KTKRTIGZSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
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- 239000012071 phase Substances 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- HPAFOABSQZMTHE-UHFFFAOYSA-N phenyl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)C1=CC=CC=C1 HPAFOABSQZMTHE-UHFFFAOYSA-N 0.000 description 1
- LYXOWKPVTCPORE-UHFFFAOYSA-N phenyl-(4-phenylphenyl)methanone Chemical compound C=1C=C(C=2C=CC=CC=2)C=CC=1C(=O)C1=CC=CC=C1 LYXOWKPVTCPORE-UHFFFAOYSA-N 0.000 description 1
- 125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 description 1
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 description 1
- 235000010988 polyoxyethylene sorbitan tristearate Nutrition 0.000 description 1
- 239000001816 polyoxyethylene sorbitan tristearate Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
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- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
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- 229960004129 sorbitan tristearate Drugs 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical class C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 125000005409 triarylsulfonium group Chemical group 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
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- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/0048—Photosensitive materials characterised by the solvents or agents facilitating spreading, e.g. tensio-active agents
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/031—Organic compounds not covered by group G03F7/029
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- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
Description
"均一な液体ブレンド"という用語は、一般に、分離してよい第二の液滴又は粒子相が存在しない、液相中での物質を記載している。液体ブレンドは、室温で3000mPs以下の粘度を有し、かつ従って、液体材料のポンピング及び混合のための標準技術要求を有する液体として加工されうる。
式、C1〜C22アルキル−O−(AO)n−H又はC1〜C22アルキル−O−(AO)n−C1〜C6アルキルのアルコールアルコキシレート(グリコールエーテル)、
式、C1〜C22アルキル−COO−(AO)n−Hの又は式、C1〜C22アルキル−COO−(AO)n−C1〜C6アルキルの脂肪酸アルコキシレート、
式、C1〜C22アルキル−NRa−(AO)n−H;C1〜C22アルキル−NRa−(AO)n−C1〜C6アルキルの脂肪酸アミンアルコキシレート、又は
式、C1〜C22アルキル−CO−NRa−(AO)n−H;C1〜C22アルキル−NRa−CO−(AO)n−C1〜C6アルキルの脂肪酸アミドアルコキシレート
[式中、Raは、C1〜C6アルキル又は基−(AO)n−Hであり、かつそれぞれAOは、独立してエチレンオキシド又はプロピレンオキシドであり、かつ指数nの分子量における合計は、有利には2〜80、より有利には3〜40の範囲内である]
フェノール又はアルキル置換したフェノールのアルコキシレート、
エチレンオキシド及びプロピレンオキシドのブロックコポリマー又はランダムコポリマー、
アルキン−アルコール又はアルキン−ジオールのアルコキシレート、
ヒマシ油のアルコキシレート、
ソルビタン脂肪酸エステルのアルコキシレート。
前記光開始剤は、遊離基タイプのものである。該光開始剤は、室温で固体である。
前記光開始剤は、合計ブレンドに対して、少なくとも30質量%、より有利には少なくとも50質量%、及び最も有利には少なくとも65質量%の量で存在する。
本発明の均一な液体ブレンドは、
・光開始剤少なくとも30質量%をその融点より高い温度まで加熱する工程
・液体表面活性剤の少なくとも1つのアルコキシル化液体表面活性剤の1〜70質量%を添加する工程、及び場合により希釈剤を添加する工程
・室温まで冷却して、液体ブレンドを得る工程
を含むプロセスによって得られる。
本発明の易流動性液体は、水性及び溶剤を基礎とした系に適している。
(A)少なくとも1つのエチレン性不飽和の光重合可能な化合物、及び
(B)前記の光開始剤及び界面活性剤の少なくとも均一な液体ブレンド
を含む光重合可能な組成物に関する。
前記のような均一な液体ブレンドを、溶剤を有さない、溶剤を基礎とした又は水を基礎とした表面塗料、印刷インク、スクリーン印刷インク、オフセット印刷インク、フレキソ印刷インク、レジスト材料又は画像記録材料を製造するために、特に対応する水系の製造において使用する。
次の光開始剤の液体光開始剤の生成物型を製造した:
ESACURE KIP 150(登録商標)オリゴマー多官能価アルファ−ヒドロキシケトン、Lamberti社製。
純度>90%を有する1−ヒドロキシ−シクロヘキシル−フェニル−ケトン(IRGACURE 184)75gを、60℃で反応器中で溶融する。Hedipin R/200(PEG−20ヒマシ油)10gを添加し、テトラエチレングリコール15gを添加し、そしてその混合物を均一になるまで60℃で撹拌する。該混合物を、室温までゆっくりと冷却する。その生成物型は透明な、無色〜黄色の液体である。
純度>90%を有する1−ヒドロキシ−シクロヘキシル−フェニル−ケトン(IRGACURE 184)75gを、60℃で反応器中で溶融する。Hedipin R/200(PEG−20ヒマシ油)10gを添加し、ポリ(エチレングリコール)350モノメチルエーテル15gを添加し、そしてその混合物を均一になるまで60℃で撹拌する。該混合物を、室温までゆっくりと冷却する。その生成物型は透明な、無色〜黄色の液体である。
純度>90%を有する1−ヒドロキシ−シクロヘキシル−フェニル−ケトン(IRGACURE 184)70gを、60℃で反応器中で溶融する。Tween 80(ポリ(エチレングリコール)ソルビタンモノオレエート)8g及びSpan 80(ソルビタンモノオレエート)2gを添加し、ポリ(エチレングリコール)350モノメチルエーテル20gを添加し、そしてその混合物を均一になるまで60℃で撹拌する。該混合物を、室温までゆっくりと冷却する。その生成物型は透明な、無色〜黄色の液体である。
純度>90%を有する1−ヒドロキシ−シクロヘキシル−フェニル−ケトン(IRGACURE 184)90gを、60℃で反応器中で溶融する。Brij 30(テトラエチレングリコールドデシルエーテル)10gを添加し、そしてその混合物を均一になるまで60℃で撹拌する。該混合物を、室温までゆっくりと冷却する。その生成物型は透明な無色〜黄色の液体である。
2,4,6−トリメチルベンゾイル−ジフェニル−ホスフィンオキシド(DAROCURE TPO)31gを、Hedipin R/200(PEG−20ヒマシ油)10gと、ポリ(エチレングリコール)350モノメチルエーテル59gと共に混合する。その混合物を、均一になるまで90℃で反応器中で撹拌する。該混合物を、室温までゆっくりと冷却する。その生成物型は透明な黄色の液体である。
1,2−オクタンジオン,1−[4−(フェニルチオ)フェニル]−,2−(O−ベンジルオキシム)(IRGACURE OXE01)50gを、Hedipin R/200(PEG−20ヒマシ油)10gと、ポリ(エチレングリコール)350モノメチルエーテル40gと共に混合する。その混合物を、均一になるまで60℃で反応器中で撹拌する。該混合物を、室温までゆっくりと冷却する。その生成物型は透明な黄色の液体である。
2,2−ジメトキシ−1,2−ジフェニルエタン−1−オン(IRGACURE 651)31gを、Hedipin R/200(PEG−20ヒマシ油)10gと、ポリ(エチレングリコール)350モノメチルエーテル59gと共に混合する。その混合物を、均一になるまで70℃で反応器中で撹拌する。該混合物を、室温までゆっくりと冷却する。その生成物型は透明な黄色の液体である。
2−ヒドロキシ−1−{1−[4−(2−ヒドロキシ−2−メチル−プロピオニル)−フェニル]−1,3,3−トリメチル−インダン−5−イル}−2−メチル−プロパン−1−オン(Esacure ONE)70gを、Tween 80(ポリ(エチレングリコール)ソルビタンモノオレエート)8gとSpan 80(ソルビタンモノオレエート)2gとテトラエチレングリコール20gと共に混合する。その混合物を115℃まで加熱し、そして均一になるまで撹拌する。該混合物を、室温までゆっくりと冷却する。その生成物型は透明な、無色〜黄色の粘着性の液体である。
以下において、光開始剤は、本発明の液体ブレンドデリバリー型に関し、有効含有量ではない。
4.w/bの透明なUV硬化調合物の硬化
前記光開始剤試料を、2つの異なる水を基礎としたクリアコート調合物中で試験した。WB−調合物1:前記に記載されている
WB−調合物2:
ESACURE KIP 150の70gを70℃に加熱する。Hedipin R/200(PEG−20ヒマシ油)10g、及びテトラエチレングリコール20gを添加し、そしてその混合物を均一になるまで70℃で撹拌する。該均一混合物を、室温までゆっくりと冷却する。その生成物型は透明な黄色の液体である。
実施例9の適用特性を、オーバープリントワニス(OPV)において評価した。実施例9を、その純型でEsacure KIP 150に対して試験した。評価は、取扱い、取り込み、効果効率及び黄変(視覚的)であった。
Esacure KIP 150を、ハンマーで抽出し、そしてOPV中で1時間45℃溶解した。対照的に、実施例9は、蜂蜜に似た粘度を有し、かつOPV中に直接注がれてよい。
KIP 150及び実施例9の双方を3%活性で試験した。硬化速度をボール紙及びコイル被覆上で比較した。
Claims (11)
- 遊離基タイプの固体光開始剤の全体のブレンドに関して少なくとも30質量%、及び少なくとも1つのアルコキシル化液体表面活性剤1〜70質量%、及び場合により有機希釈剤を含有する、室温で液体である均一な液体ブレンド。
- 前記光開始剤の濃度が、少なくとも50質量%、及び最も有利には少なくとも65質量%である、請求項1に記載の均一な液体ブレンド。
- 前記表面活性剤が、エチレンオキシド及び/又はプロピレンオキシドを有する付加物を基礎としたアルコキシル化化合物から選択される、請求項1に記載の均一な液体ブレンド。
- 前記表面活性剤が、アルコールアルコキシレート(グリコールエーテル)、脂肪酸アルコキシレート、脂肪酸アミンアルコキシレート、又は脂肪酸アミドアルコキシレート、フェノール又はアルキル置換したフェノールのアルコキシレート、エチレンオキシド及びプロピレンオキシドのブロックコポリマー又はランダムコポリマー、アルキン−アルコール又はアルキン−ジオールのアルコキシレート、ヒマシ油のアルコキシレート、ソルビタン脂肪酸エステルのアルコキシレート、並びにそれらの混合物から選択される、請求項1に記載の均一な液体ブレンド。
- 前記希釈剤が存在する、請求項1に記載の均一な液体ブレンド。
- 前記光開始剤が、ベンゾフェノン、芳香族α−ヒドロキシケトン、ベンジルケタール、芳香族α−アミノケトン、フェニルグリオキサル酸エステル、モノ−アシルホスフィンオキシド、ビス−アシルホスフィンオキシド、トリス−アシルホスフィンオキシド及び芳香族ケトンから誘導されるオキシムエステルから選択される、請求項1に記載の均一な液体ブレンド。
- 前記光開始剤が、ベンゾフェノン(DAROCURE(登録商標)BP)、ベンジルジメチルケタール(IRGACURE(登録商標)651)、1−ヒドロキシ−シクロヘキシル−フェニル−ケトン(IRGACUR 184)、1−[4−(2−ヒドロキシエトキシ)−フェニル]−2−ヒドロキシ−2−メチル−1−プロパン−1オン(IRGACURE(登録商標)2959)、2−ヒドロキシ−1−{4−[4−(2−ヒドロキシ−2−メチル−プロピオニル)−ベンジル]−フェニル}−2−メチル−プロパン−1−オン(IRGACURE(登録商標)127)、(4−メチルチオ−ベンゾイル)−1−メチル−1−モルホリノエタン(IRGACURE(登録商標)907)、(4−モルホリノベンゾイル)−1−ベンジル−1−ジメチルアミノプロパン(IRGACURE(登録商標)369)、(4−モルホリノベンゾイル)−1−(4−メチルベンジル)−1−ジメチルアミノプロパン(IRGACURE(登録商標)379)、(2,4,6−トリメチルベンゾイル)ジフェニルホスフィンオキシド(DAROCUR(登録商標)TPO)、ビス(2,6−ジメトキシ−ベンゾイル)−(2,4,4−トリメチル−ペンチル)ホスフィンオキシド、ビス(2,4,6−トリメチルベンゾイル)−フェニルホスフィンオキシド(IRGACURE(登録商標)819)及び2−ヒドロキシ−1−{1−[4−(2−ヒドロキシ−2−メチル−プロピオニル)−フェニル]−1,3,3−トリメチル−インダン−5−イル}−2−メチル−プロパン−1−オン、(ESACURE ONE(登録商標))、1,2−オクタンジオン、1−[4−(フェニルチオ)フェニル]−,2−(O−ベンジルオキシム)(IRGACURE OXE01(登録商標))から選択される、請求項1に記載の均一な液体ブレンド。
- 前記開始剤が、1−ヒドロキシ−シクロヘキシル−フェニル−ケトン(IRGACURE 184)、2−ヒドロキシ−1−{1−[4−(2−ヒドロキシ−2−メチルプロピオニル)−フェニル]−1,3,3−トリメチル−インダン−5−イル}−2−メチル−プロパン−1−オン、(ESACURE ONE)、ビス(2,6−ジメトキシ−ベンゾイル)−(2,4,4−トリメチル−ペンチル)ホスフィンオキシド、ビス(2,4,6−トリメチルベンゾイル)−フェニルホスフィンオキシド(IRGACURE(登録商標)819)、1−[4−(2−ヒドロキシエトキシ)−フェニル]−2−ヒドロキシ−2−メチル−1−プロパン−1−オン(IRGACURE2959)から選択される、請求項7に記載の均一な液体ブレンド。
- 以下の工程、
・光開始剤少なくとも30質量%をその融点より高い温度まで加熱する工程
・少なくとも1つのアルコキシル化液体表面活性剤1〜70質量%を添加する工程、及び場合により希釈剤を添加する工程
・室温まで冷却して、均一な液体ブレンドを得る工程
を含む、請求項1に記載の均一な液体ブレンドの製造方法。 - 以下、
(A)少なくとも1つのエチレン性不飽和の光重合可能な化合物、及び
(B)請求項1に記載の少なくとも均一な液体ブレンド
を含む、光重合可能な組成物。 - 溶剤を有さない、溶剤を基礎とした及び水を基礎とした表面塗料、印刷インク、スクリーン印刷インク、オフセット印刷インク、フレキソ印刷インク、レジスト材料又は画像記録材料の製造における、請求項1に記載の均一な液体ブレンドの使用。
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JP2017514964A (ja) * | 2014-05-07 | 2017-06-08 | チュビタック (ターキー ビリムセル ヴィ テクノロジク アラスティルマ クルム)Tubitak (Turkiye Bilimsel Ve Teknolojik Arastirma Kurumu) | 眼内レンズ(iol)を生産するための組成物及びレンズ製造方法 |
KR102408921B1 (ko) | 2015-01-07 | 2022-06-14 | 삼성디스플레이 주식회사 | 포토레지스트 조성물 및 이를 이용한 블랙 매트릭스의 제조방법 |
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CN108948232B (zh) * | 2017-05-24 | 2022-03-15 | 深圳有为技术控股集团有限公司 | 新型光引发剂混合物 |
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JPH04142302A (ja) * | 1990-09-06 | 1992-05-15 | Fratelli Lamberti Spa | 光重合開始剤の水性分散系及びそれらの用途 |
JP2004534117A (ja) * | 2001-04-27 | 2004-11-11 | ユ セ ベ ソシエテ アノニム | 光開始剤組成物 |
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WO2010081749A1 (en) | 2010-07-22 |
PL2387589T3 (pl) | 2016-02-29 |
US8426484B2 (en) | 2013-04-23 |
KR101734588B1 (ko) | 2017-05-11 |
JP5701221B2 (ja) | 2015-04-15 |
EP2387589A1 (en) | 2011-11-23 |
AU2010205793A1 (en) | 2011-07-28 |
US20120035292A1 (en) | 2012-02-09 |
EP2387589B1 (en) | 2015-09-23 |
BRPI1006180A2 (pt) | 2019-09-24 |
MX2011007229A (es) | 2011-08-03 |
CN102282178B (zh) | 2014-03-19 |
CN102282178A (zh) | 2011-12-14 |
KR20110119701A (ko) | 2011-11-02 |
ES2556341T3 (es) | 2016-01-15 |
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