JP2012501383A5 - - Google Patents
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- Publication number
- JP2012501383A5 JP2012501383A5 JP2011524388A JP2011524388A JP2012501383A5 JP 2012501383 A5 JP2012501383 A5 JP 2012501383A5 JP 2011524388 A JP2011524388 A JP 2011524388A JP 2011524388 A JP2011524388 A JP 2011524388A JP 2012501383 A5 JP2012501383 A5 JP 2012501383A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- mononuclear
- particularly preferably
- alkoxy
- substituted phenol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- -1 aryl alcohol Chemical compound 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-Naphthol Chemical class C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
- 125000002560 nitrile group Chemical group 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- 241001120493 Arene Species 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000000732 arylene group Chemical group 0.000 description 1
- 125000000649 benzylidene group Chemical group [H]C(=[*])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical class OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Description
アリールアルコールをベースとする芳香族は、単核又は多核であってもよい。好ましくは、芳香族は単核（フェノール誘導体）であるか、あるいは二核（ナフトール誘導体）であり、特に単核である。アリールアルコールはさらに他の置換基を有していてもよい。この置換基は互いに独立して、Ｃ１〜Ｃ１０−アルキル基、ハロゲン、Ｃ１〜Ｃ１０−アルコキシ基、酸素又は硫黄によって中断されたアルキレン基又はアリーレン基、Ｃ１〜Ｃ１０−アルコキシカルボキシル基、ニトリル基、ニトロ基並びにＣ１〜Ｃ１０−アルコキシカルバモイル基、特に好ましくはメチル基、エチル基、ｎ−プロピル基、イソプロピル基、ｎ−ブチル基、トリフルオロメチル基、フッ素、塩素、臭素、ヨウ素、メトキシ基、エトキシ基、メチレン基、エチレン基、プロピレン基、イソプロピレン基、ベンジリデン基、ニトリル基、ニトロ基、特に好ましくはメチル基、メトキシ基、メチレン基、エチレン基、トリフルオロメチル基、フッ素及び臭素である。新規方法を用いて、アリールアルコールについて多彩に使用することができる。特に好ましくは、電子に富むアレーン、例えば１又はそれ以上置換されたフェノール並びにナフトール（α−及びβ−）及びその置換された誘導体、とりわけ好ましくは４−アルキル置換フェノール並びに２，４−ジアルキル置換フェノールである。
Claims (1)
- 使用されたアリールアルコールのＯＨ基が直接芳香族に結合されている、請求項１に記載の方法。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08163356 | 2008-09-01 | ||
| EP08163356.2 | 2008-09-01 | ||
| PCT/EP2009/061101 WO2010023258A1 (de) | 2008-09-01 | 2009-08-28 | Verfahren zur anodischen dehydrodimerisierung von substituierten arylalkoholen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012501383A JP2012501383A (ja) | 2012-01-19 |
| JP2012501383A5 true JP2012501383A5 (ja) | 2012-10-11 |
| JP5535215B2 JP5535215B2 (ja) | 2014-07-02 |
Family
ID=41413363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011524388A Expired - Fee Related JP5535215B2 (ja) | 2008-09-01 | 2009-08-28 | 置換アリールアルコールのアノード脱水素二量化のための方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8449755B2 (ja) |
| EP (1) | EP2318569B1 (ja) |
| JP (1) | JP5535215B2 (ja) |
| AT (1) | ATE551445T1 (ja) |
| WO (1) | WO2010023258A1 (ja) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8747646B2 (en) | 2009-06-05 | 2014-06-10 | Basf Se | Process for the anodic cross-dehydrodimerization of arenes |
| US8747645B2 (en) * | 2009-06-05 | 2014-06-10 | Basf Se | Process for preparing unsymmetrical biaryl alcohols |
| DE102013203866A1 (de) * | 2013-03-07 | 2014-09-11 | Evonik Industries Ag | Elektrochemische Kupplung eines Phenols mit einem Naphthol |
| DE102013211744A1 (de) | 2013-06-21 | 2014-12-24 | Evonik Industries Ag | Elektrochemisches Verfahren zur Herstellung von symmetrischen Biphenolen unter Verwendung einer Glaskohlenstoffanode |
| DE102013211745A1 (de) | 2013-06-21 | 2014-12-24 | Evonik Industries Ag | Elektrochemisches Verfahren zur Herstellung von symmetrischen Biphenolen unter Verwendung von Essigsäure als Elektrolyt |
| DE102014209976A1 (de) | 2014-05-26 | 2015-11-26 | Evonik Degussa Gmbh | Verfahren zur Herstellung von 2,2'-Biphenolen unter Verwendung von Selendioxid und halogeniertem Lösungsmittel |
| DE102014209967A1 (de) | 2014-05-26 | 2015-12-17 | Evonik Degussa Gmbh | Verfahren zur Herstellung von 2,2'-Biphenolen unter Verwendung von Selendioxid |
| SG10201601501QA (en) | 2015-03-05 | 2016-10-28 | Evonik Degussa Gmbh | Preparation of 2,2`-biaryls in the presence of molybdenum(v) chloride |
| EP3095776A1 (de) | 2015-05-20 | 2016-11-23 | Evonik Degussa GmbH | Kupplung von einem Phenol und einem Aren unter Verwendung von Selendioxid |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4101391A (en) | 1976-01-05 | 1978-07-18 | Monsanto Company | Electrolytic oxidative methyl-methyl coupling of cresol salts |
| JPH0243388A (ja) * | 1988-08-03 | 1990-02-13 | Mitsubishi Kasei Corp | ４，４’−ジヒドロキシビフェニル類の製造法 |
| DE102004005508A1 (de) | 2004-02-04 | 2005-08-25 | Basf Ag | Anodische Dimerisierung substituierter Benzole |
| DE102005003012A1 (de) | 2005-01-21 | 2006-07-27 | Basf Ag | Anodische Dimerisierung von Hydroxy-substituierten Aromaten |
-
2009
- 2009-08-28 EP EP09782303A patent/EP2318569B1/de not_active Not-in-force
- 2009-08-28 AT AT09782303T patent/ATE551445T1/de active
- 2009-08-28 WO PCT/EP2009/061101 patent/WO2010023258A1/de active Application Filing
- 2009-08-28 US US13/059,548 patent/US8449755B2/en active Active
- 2009-08-28 JP JP2011524388A patent/JP5535215B2/ja not_active Expired - Fee Related
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