JP2011526835A5 - - Google Patents
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- Publication number
- JP2011526835A5 JP2011526835A5 JP2011516803A JP2011516803A JP2011526835A5 JP 2011526835 A5 JP2011526835 A5 JP 2011526835A5 JP 2011516803 A JP2011516803 A JP 2011516803A JP 2011516803 A JP2011516803 A JP 2011516803A JP 2011526835 A5 JP2011526835 A5 JP 2011526835A5
- Authority
- JP
- Japan
- Prior art keywords
- coating
- superhydrophobic
- polysilicate gel
- gel
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000000576 coating method Methods 0.000 claims description 131
- 239000011248 coating agent Substances 0.000 claims description 95
- 230000003075 superhydrophobic effect Effects 0.000 claims description 95
- 239000002904 solvent Substances 0.000 claims description 56
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 40
- 239000003795 chemical substances by application Substances 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 28
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 21
- 125000000524 functional group Chemical group 0.000 claims description 21
- 239000000758 substrate Substances 0.000 claims description 17
- 239000002243 precursor Substances 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 239000012530 fluid Substances 0.000 claims description 14
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 claims description 14
- 230000002209 hydrophobic effect Effects 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- 239000011148 porous material Substances 0.000 claims description 12
- 239000005051 trimethylchlorosilane Substances 0.000 claims description 10
- 239000004744 fabric Substances 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000003446 ligand Substances 0.000 claims description 7
- 238000004528 spin coating Methods 0.000 claims description 7
- RCHUVCPBWWSUMC-UHFFFAOYSA-N trichloro(octyl)silane Chemical compound CCCCCCCC[Si](Cl)(Cl)Cl RCHUVCPBWWSUMC-UHFFFAOYSA-N 0.000 claims description 7
- DWAWYEUJUWLESO-UHFFFAOYSA-N trichloromethylsilane Chemical compound [SiH3]C(Cl)(Cl)Cl DWAWYEUJUWLESO-UHFFFAOYSA-N 0.000 claims description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000919 ceramic Substances 0.000 claims description 6
- 239000004033 plastic Substances 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 150000004756 silanes Chemical class 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- GLISZRPOUBOZDL-UHFFFAOYSA-N 3-bromopropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCBr GLISZRPOUBOZDL-UHFFFAOYSA-N 0.000 claims description 3
- OXYZDRAJMHGSMW-UHFFFAOYSA-N 3-chloropropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCCl OXYZDRAJMHGSMW-UHFFFAOYSA-N 0.000 claims description 3
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 claims description 3
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 3
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 3
- FPOSCXQHGOVVPD-UHFFFAOYSA-N chloromethyl(trimethoxy)silane Chemical compound CO[Si](CCl)(OC)OC FPOSCXQHGOVVPD-UHFFFAOYSA-N 0.000 claims description 3
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 claims description 3
- 238000003618 dip coating Methods 0.000 claims description 3
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 3
- 230000007062 hydrolysis Effects 0.000 claims description 3
- 238000006460 hydrolysis reaction Methods 0.000 claims description 3
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical group CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000007761 roller coating Methods 0.000 claims description 3
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 3
- IZRJPHXTEXTLHY-UHFFFAOYSA-N triethoxy(2-triethoxysilylethyl)silane Chemical compound CCO[Si](OCC)(OCC)CC[Si](OCC)(OCC)OCC IZRJPHXTEXTLHY-UHFFFAOYSA-N 0.000 claims description 3
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 claims description 2
- 238000007171 acid catalysis Methods 0.000 claims 1
- 239000000499 gel Substances 0.000 description 75
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 30
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 238000005260 corrosion Methods 0.000 description 10
- 230000007797 corrosion Effects 0.000 description 10
- 239000010410 layer Substances 0.000 description 9
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 6
- 229910000077 silane Inorganic materials 0.000 description 6
- 238000005406 washing Methods 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 4
- -1 salt ions Chemical class 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 230000005587 bubbling Effects 0.000 description 3
- 230000005661 hydrophobic surface Effects 0.000 description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000003377 acid catalyst Substances 0.000 description 2
- 238000005903 acid hydrolysis reaction Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000007123 defense Effects 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 238000006884 silylation reaction Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 241000321453 Paranthias colonus Species 0.000 description 1
- 239000004964 aerogel Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000005103 alkyl silyl group Chemical group 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003124 biologic agent Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7714508P | 2008-06-30 | 2008-06-30 | |
| US61/077,145 | 2008-06-30 | ||
| PCT/US2009/049208 WO2010002859A2 (en) | 2008-06-30 | 2009-06-30 | A superhydrophobic aerogel that does not require per-fluoro compounds or contain any fluorine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2011526835A JP2011526835A (ja) | 2011-10-20 |
| JP2011526835A5 true JP2011526835A5 (enExample) | 2012-07-26 |
Family
ID=41466560
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011516803A Pending JP2011526835A (ja) | 2008-06-30 | 2009-06-30 | パーフルオロ化合物を必要としない、またはフッ素を含まない、超疎水性エアロゲル |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US9040435B2 (enExample) |
| EP (1) | EP2294152B1 (enExample) |
| JP (1) | JP2011526835A (enExample) |
| KR (1) | KR20110042268A (enExample) |
| CN (1) | CN102119197A (enExample) |
| AU (1) | AU2009267062A1 (enExample) |
| CA (1) | CA2727920A1 (enExample) |
| WO (1) | WO2010002859A2 (enExample) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2294152B1 (en) * | 2008-06-30 | 2012-11-14 | Stc.Unm | A superhydrophobic aerogel that does not require per-fluoro compounds or contain any fluorine |
| US8663742B2 (en) * | 2008-06-30 | 2014-03-04 | Stc.Unm | Durable polymer-aerogel based superhydrophobic coatings, a composite material |
| WO2010042668A1 (en) | 2008-10-07 | 2010-04-15 | Ross Technology Corporation | Spill resistant surfaces having hydrophobic and oleophobic borders |
| MX2012010669A (es) | 2010-03-15 | 2013-02-07 | Ross Technology Corp | Destacadores y metodos para producir supreficies hidrofobas. |
| KR101187653B1 (ko) | 2010-07-20 | 2012-10-05 | 한국과학기술연구원 | 초소수성 표면 제조 방법 |
| CN102453465B (zh) * | 2010-10-27 | 2014-09-03 | 中国科学院大连化学物理研究所 | 一种粘附型超疏水材料及其制备方法 |
| MX2013009609A (es) | 2011-02-21 | 2013-09-16 | Ross Technology Corp | Revestimiento suoerhidrofobos y oleofobos con sistemas aglutinantes con bajo contenido de compuestos organicos volatiles. |
| WO2012167017A2 (en) * | 2011-06-01 | 2012-12-06 | The University Of North Carolina At Chapel Hill | Superhydrophobic coatings and methods for their preparation |
| US9364859B2 (en) | 2011-07-28 | 2016-06-14 | Kimberly-Clark Worldwide, Inc. | Superhydrophobic surfaces |
| US9217094B2 (en) | 2011-07-28 | 2015-12-22 | The Board Of Trustees Of The University Of Illinois | Superhydrophobic compositions |
| EP2791255B1 (en) | 2011-12-15 | 2017-11-01 | Ross Technology Corporation | Composition and coating for superhydrophobic performance |
| CN102643029B (zh) * | 2012-04-24 | 2015-01-28 | 奇瑞汽车股份有限公司 | 憎水修饰剂及其修饰的憎水玻璃、憎水玻璃的制备方法 |
| US9273305B1 (en) | 2012-04-25 | 2016-03-01 | Sandia Corporation | Cell-based composite materials with programmed structures and functions |
| CN104520392A (zh) | 2012-06-25 | 2015-04-15 | 罗斯科技公司 | 具有疏水和/或疏油性质的弹性体涂层 |
| CN103045083A (zh) * | 2013-01-08 | 2013-04-17 | 天津大学 | 一种单组份氟硅橡胶防覆冰涂层材料及其制备方法 |
| US9803100B2 (en) | 2013-04-30 | 2017-10-31 | Kimberly-Clark Worldwide, Inc. | Non-fluorinated water-based superhydrophobic surfaces |
| US10005917B2 (en) | 2013-04-30 | 2018-06-26 | Kimberly-Clark Worldwide, Inc. | Non-fluorinated water-based superhydrophobic compositions |
| US9587142B2 (en) * | 2013-07-23 | 2017-03-07 | Lotus Leaf Coatings, Inc. | Process for preparing an optically clear superhydrophobic coating solution |
| CN104003406A (zh) * | 2014-05-30 | 2014-08-27 | 武汉理工大学 | 一种超疏水性SiO2气凝胶粉体的制备方法及应用 |
| RU2572974C1 (ru) * | 2014-09-19 | 2016-01-20 | Закрытое акционерное общество "Научно-технический центр "Электросети" | Композиция супергидрофобного покрытия и способ получения супергидрофобного покрытия из нее |
| BR112017008787A2 (pt) | 2014-10-28 | 2017-12-26 | 3M Innovative Properties Co | componentes de um sistema de aplicação de aspersões que compreende uma superfície repelente & métodos |
| WO2016077532A1 (en) * | 2014-11-12 | 2016-05-19 | University Of Houston System | Soil-resistant, stain-resistant coatings and methods of applying on textile or other flexible materials |
| CA2967599C (en) * | 2014-11-12 | 2023-09-12 | University Of Houston System | Soil-resistant, stain-resistant fluorine-free coatings and methods of applying on materials |
| WO2016089345A1 (en) * | 2014-12-01 | 2016-06-09 | Hewlett-Packard Development Company, L.P. | Coated substrates |
| US10533096B2 (en) | 2015-02-27 | 2020-01-14 | Kimberly-Clark Worldwide, Inc. | Non-fluorinated water-based superhydrophobic compositions |
| DE102015211812A1 (de) * | 2015-06-25 | 2016-12-29 | Wacker Chemie Ag | Wirtschaftliches Verfahren zur Herstellung von organisch modifizierten Lyo- oder Aerogelen |
| WO2017074708A1 (en) * | 2015-10-28 | 2017-05-04 | 3M Innovative Properties Company | Articles subject to ice formation comprising a repellent surface |
| CN113145341A (zh) | 2015-10-28 | 2021-07-23 | 3M创新有限公司 | 包括拒液表面的喷雾施用系统部件和方法 |
| AU2017209440B2 (en) | 2016-01-22 | 2022-09-22 | Edgewell Personal Care Brands, Llc | Hydrophobic topical compositions |
| CN109071992A (zh) | 2016-04-26 | 2018-12-21 | 3M创新有限公司 | 包括包含硅氧烷材料的排斥性表面的经受冰形成的制品 |
| US10327338B2 (en) | 2016-06-17 | 2019-06-18 | Nanoshield Technology Co., Ltd. | Method for coating a device and devices having nanofilm thereon |
| US10271435B2 (en) | 2016-06-17 | 2019-04-23 | Nanoshield Technology Co., Ltd. | Method for coating devices and resulting products |
| CN106120339B (zh) * | 2016-07-06 | 2019-02-26 | 烟台大学 | 一种空气和油中具有超疏水性能的织物及制备方法和用途 |
| US10538632B1 (en) | 2016-09-30 | 2020-01-21 | National Technology & Engineering Solutions Of Sandia, Llc | Shape-preserving polymeric replication of biological matter |
| CN106752214B (zh) * | 2017-01-13 | 2020-01-31 | 吉林大学 | 一种基于非连续性润湿性改良的仿生防结冰表面 |
| US11603329B2 (en) | 2020-04-22 | 2023-03-14 | Waymo Llc | Methods for preparing a superomniphobic coating |
| US11155490B1 (en) | 2020-04-22 | 2021-10-26 | Waymo Llc | Superomniphobic thin film |
| CN119751969A (zh) * | 2024-12-18 | 2025-04-04 | 南京大学 | 超疏水海绵及其制备方法和在受污染地下水中的应用 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA823554B (en) * | 1981-06-19 | 1983-03-30 | Dow Corning Ltd | Siloxane compositions and process for treatment of materials |
| JPS59170157A (ja) * | 1983-03-18 | 1984-09-26 | Toray Silicone Co Ltd | プライマ−組成物 |
| US4701508A (en) | 1984-12-14 | 1987-10-20 | Mitsui Sekiyu Kagaku Kogyo Kabushiki Kaisha | Solvent soluble fluorine-containing polymer, coating composition containing the same and coating process thereof |
| JP4772953B2 (ja) * | 2000-09-08 | 2011-09-14 | 東レ・ダウコーニング株式会社 | 水性塗料組成物、およびその製造方法 |
| WO2002088262A1 (en) * | 2001-05-01 | 2002-11-07 | Dow Corning Corporation | Protective coating composition |
| JP4947855B2 (ja) * | 2001-07-31 | 2012-06-06 | 東レ・ダウコーニング株式会社 | 皮膜形成性シリコーン樹脂組成物 |
| EP1479738A1 (en) * | 2003-05-20 | 2004-11-24 | DSM IP Assets B.V. | Hydrophobic coatings comprising reactive nano-particles |
| JP4384898B2 (ja) * | 2003-11-28 | 2009-12-16 | 日油株式会社 | 撥水撥油性被膜の製造方法 |
| EP1717278A1 (en) * | 2005-04-26 | 2006-11-02 | Nuplex Resins B.V. | Coated particles and coating compositions comprising coated particles |
| CN100384726C (zh) | 2005-05-19 | 2008-04-30 | 同济大学 | 表面活性可调的纳米多孔二氧化硅气凝胶及其制备方法 |
| JP4953426B2 (ja) | 2005-06-09 | 2012-06-13 | ペンタックスリコーイメージング株式会社 | シリカエアロゲル膜の製造方法 |
| US20060292345A1 (en) * | 2005-06-14 | 2006-12-28 | Dave Bakul C | Micropatterned superhydrophobic silica based sol-gel surfaces |
| CN1317188C (zh) | 2005-07-15 | 2007-05-23 | 清华大学 | 以稻壳灰为原料制备疏水性二氧化硅气凝胶的方法 |
| BRPI0808993B1 (pt) * | 2007-03-16 | 2018-12-04 | Cabot Corp | método de fabricação de partículas de aerogel |
| EP2294152B1 (en) * | 2008-06-30 | 2012-11-14 | Stc.Unm | A superhydrophobic aerogel that does not require per-fluoro compounds or contain any fluorine |
-
2009
- 2009-06-30 EP EP20090774310 patent/EP2294152B1/en not_active Not-in-force
- 2009-06-30 CA CA2727920A patent/CA2727920A1/en not_active Abandoned
- 2009-06-30 CN CN200980125283XA patent/CN102119197A/zh active Pending
- 2009-06-30 US US13/121,166 patent/US9040435B2/en not_active Expired - Fee Related
- 2009-06-30 KR KR1020107029367A patent/KR20110042268A/ko not_active Withdrawn
- 2009-06-30 AU AU2009267062A patent/AU2009267062A1/en not_active Abandoned
- 2009-06-30 JP JP2011516803A patent/JP2011526835A/ja active Pending
- 2009-06-30 WO PCT/US2009/049208 patent/WO2010002859A2/en not_active Ceased
-
2015
- 2015-04-03 US US14/678,533 patent/US20150240123A1/en not_active Abandoned
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