JP2011506709A5 - - Google Patents
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- Publication number
- JP2011506709A5 JP2011506709A5 JP2010538462A JP2010538462A JP2011506709A5 JP 2011506709 A5 JP2011506709 A5 JP 2011506709A5 JP 2010538462 A JP2010538462 A JP 2010538462A JP 2010538462 A JP2010538462 A JP 2010538462A JP 2011506709 A5 JP2011506709 A5 JP 2011506709A5
- Authority
- JP
- Japan
- Prior art keywords
- adsorbent
- biofuel
- silica
- layer
- treating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003463 adsorbent Substances 0.000 claims 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 16
- 239000002551 biofuel Substances 0.000 claims 10
- 238000000034 method Methods 0.000 claims 9
- 229910044991 metal oxide Inorganic materials 0.000 claims 8
- 150000004706 metal oxides Chemical class 0.000 claims 8
- 239000000377 silicon dioxide Substances 0.000 claims 8
- 239000012530 fluid Substances 0.000 claims 5
- 239000000203 mixture Substances 0.000 claims 5
- 230000001172 regenerating effect Effects 0.000 claims 4
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- 125000005907 alkyl ester group Chemical group 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 239000002798 polar solvent Substances 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- -1 extrudates Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 claims 1
- 239000012528 membrane Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 claims 1
Claims (18)
- (a)バイオ燃料を含む流体を吸着剤と接触させ;そして
(b)該吸着剤を再生する;
ことを含み、該吸着剤が少なくとも2種類の異なる金属酸化物を含む、バイオ燃料の処理方法。 - 該バイオ燃料が、エステル、アルコール、又はこれらの混合物を含む、請求項1に記載の方法。
- 該金属酸化物が、シリカ、アルミナ、アルミノシリケート、又はこれらの混合物を含む、請求項1又は2に記載の方法。
- 請求項1〜3のいずれか1項に記載の方法によって製造される生成物。
- 請求項1〜3のいずれか1項に記載の方法を用いる装置。
- (a)バイオ燃料を含む流体を第1の吸着剤と接触させ;
(b)該流体を第2の吸着剤と接触させ;そして
(c)第1及び第2の吸着剤の少なくとも1つを再生する;
ことを含む、バイオ燃料の処理方法。 - (a)バイオ燃料を含む流体を吸着剤と接触させ;そして
(b)バイオ燃料の製造において用いた極性溶媒を用いて吸着剤を再生する;
ことを含む、バイオ燃料の処理方法。 - 該極性溶媒がアルコールを含む、請求項7に記載の方法。
- (a)アルキルエステルを含む流体を吸着剤と接触させ;そして
(b)該吸着剤を再生する;
ことを含む、アルキルエステルの処理方法。 - 少なくとも2種類の異なる金属酸化物を含む、バイオ燃料を処理するための吸着剤。
- 該吸着剤が、粒子、押出物、膜、複合体、層、床、又はこれらの組み合わせを含む、請求項10に記載の吸着剤。
- 該金属酸化物が、シリカ、アルミナ、アルミノシリケート、又はこれらの混合物を含む、請求項10又は11に記載の吸着剤。
- 該吸着剤が固定床の形態である、請求項10〜12のいずれか1項に記載の吸着剤。
- 少なくとも2種類の異なる金属酸化物が、第2の金属酸化物の第1の層と第2の金属酸化物の第3の層との間の層の形態の第1の金属酸化物を含む、請求項10〜13のいずれか1項に記載の吸着剤。
- 該第1の吸着剤がアルミノシリケートを含み、該第2の吸着剤がシリカを含む、請求項14に記載の吸着剤。
- 該第1の層が第1のシリカを含み、該第3の層が、第1のシリカと同じ組成、形状、又は物理的形態を有する第2のシリカを含む、請求項14に記載の吸着剤。
- 該第1の層が、該第3の層中の第2のシリカと異なる組成、形状、又は物理的形態を有する第1のシリカを含む、請求項14に記載の吸着剤。
- 請求項10〜17のいずれか1項に記載の吸着剤を含む、バイオ燃料を処理するための装置。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US867107P | 2007-12-21 | 2007-12-21 | |
PCT/EP2008/010835 WO2009080287A2 (en) | 2007-12-21 | 2008-12-18 | Treatment of biofuels |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2011506709A JP2011506709A (ja) | 2011-03-03 |
JP2011506709A5 true JP2011506709A5 (ja) | 2012-01-19 |
Family
ID=40474787
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010538462A Withdrawn JP2011506709A (ja) | 2007-12-21 | 2008-12-18 | バイオ燃料の処理 |
Country Status (13)
Country | Link |
---|---|
US (1) | US8876922B2 (ja) |
EP (1) | EP2238220A2 (ja) |
JP (1) | JP2011506709A (ja) |
KR (1) | KR20100107473A (ja) |
CN (1) | CN101981159B (ja) |
AR (1) | AR069859A1 (ja) |
AU (1) | AU2008340728A1 (ja) |
BR (1) | BRPI0821652A2 (ja) |
CA (1) | CA2710089A1 (ja) |
MX (1) | MX2010006711A (ja) |
MY (1) | MY158569A (ja) |
RU (1) | RU2010130541A (ja) |
WO (1) | WO2009080287A2 (ja) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8097049B2 (en) | 2008-02-07 | 2012-01-17 | The Dallas Group Of America, Inc. | Biodiesel purification by a continuous regenerable adsorbent process |
DE102008058393A1 (de) * | 2008-11-21 | 2010-05-27 | Süd-Chemie AG | Aluminiumoxidhaltige Adsorbentien zur Aufreinigung von Biodiesel |
DE102010022139A1 (de) | 2010-05-20 | 2011-11-24 | Lurgi Gmbh | Verfahren zur Herstellung von Biodiesel |
ES2374937B1 (es) * | 2010-06-01 | 2013-02-12 | Bioenergética Extremeña 2020, S.L. | Procedimiento para el refinado de biodiésel, independientemente del origen de la materia prima utilizada en su fabricación. |
PL2586870T3 (pl) * | 2010-06-23 | 2017-05-31 | Bernard A. J. Stroïazzo-Mougin | Sposób wytwarzania surowego biooleju z mikroglonów |
US20120135485A1 (en) * | 2010-11-29 | 2012-05-31 | Georgia Tech Research Corporation | Sorbent and process for removing fermentation inhibitors |
WO2012177348A1 (en) | 2011-06-21 | 2012-12-27 | W. R. Grace & Co.-Conn. | Catalytic purification of fatty acid alkyl esters used in fuels |
WO2015056767A1 (ja) | 2013-10-18 | 2015-04-23 | 独立行政法人産業技術総合研究所 | 高品質バイオディーゼル燃料の製造方法 |
US10072231B2 (en) * | 2016-12-02 | 2018-09-11 | Ag Chem, Llc | Process for the conversion of free fatty acids to glycerol esters and production of novel catalyst systems |
EP3404082A1 (de) * | 2017-05-19 | 2018-11-21 | GEA Mechanical Equipment GmbH | Verfahren zur verringerung des gehalts an monoglyceriden (mg), insbesondere an gesättigten monoglyceriden (gmg), in einem roh-biodiesel |
US10596487B2 (en) * | 2017-09-27 | 2020-03-24 | Rj Lee Group, Inc. | Methods and apparatus for clarification of pyrolysis oils |
SG10201803633UA (en) * | 2018-04-30 | 2019-11-28 | Green Technology Research Co Ltd | Process using bio-based material and the products thereof |
WO2019212421A1 (en) * | 2018-04-30 | 2019-11-07 | Green Technology Research Co., Ltd | Method of processing a bio-based material and apparatus for processing the same |
Family Cites Families (69)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3472786A (en) | 1966-04-13 | 1969-10-14 | Universal Oil Prod Co | Regeneration of spent adsorbents |
SE372555B (ja) * | 1968-10-01 | 1974-12-23 | Mizusawa Industrial Chem | |
FR2188612A5 (en) * | 1972-06-12 | 1974-01-18 | Inst Organicheskogo Kataliza I | Adsorbant - contg metal oxide cement and clay or alumina |
GB1541017A (en) | 1975-03-10 | 1979-02-21 | Unilever Ltd | Degumming process for triglyceride oils |
US4273621A (en) | 1980-05-05 | 1981-06-16 | The Lummus Company | Process for dehydrating ethanol and for the production of gasohol therefrom |
US4310440A (en) | 1980-07-07 | 1982-01-12 | Union Carbide Corporation | Crystalline metallophosphate compositions |
US4319057A (en) | 1980-12-08 | 1982-03-09 | Grain Processing Corporation | Regeneration of molecular sieves |
US4609500A (en) | 1981-10-15 | 1986-09-02 | Cpc International Inc. | Refining of oil and product thereof |
IN156223B (ja) | 1982-06-26 | 1985-06-01 | Lever Hindustan Ltd | |
IN156362B (ja) | 1982-06-26 | 1985-07-06 | Lever Hindustan Ltd | |
DE3227669C1 (de) | 1982-07-23 | 1983-07-07 | Hermann Dr. 4400 Münster Stage | Verfahren und Anlage zum Desodorieren und/oder Entsaeuern von Speiseoelen,Fetten und Estern |
US4601790A (en) | 1982-07-23 | 1986-07-22 | Hermann Stage | Process for deodorizing and/or physical refining of cocoa butter and cocoa butter substitutes |
US4440871A (en) | 1982-07-26 | 1984-04-03 | Union Carbide Corporation | Crystalline silicoaluminophosphates |
GB2135661B (en) | 1983-02-25 | 1986-04-23 | Coal Ind | Regenerating sorbents |
LU84923A1 (fr) | 1983-07-19 | 1985-04-17 | Metallurgie Hoboken | Procede pour defluorer une solution acide de sulfate |
US4613410A (en) | 1983-10-07 | 1986-09-23 | Rivers Jr Jacob B | Methods for dynamically refining and deodorizing fats and oils |
US4971660A (en) | 1983-10-07 | 1990-11-20 | Rivers Jr Jacob B | Method for dynamically refining and deodorizing fats and oils by distillation |
US4588745A (en) | 1984-04-17 | 1986-05-13 | A. E. Staley Manufacturing Company | Treatment of vegetable oils |
US4629588A (en) | 1984-12-07 | 1986-12-16 | W. R. Grace & Co. | Method for refining glyceride oils using amorphous silica |
US4734226A (en) | 1986-01-28 | 1988-03-29 | W. R. Grace & Co. | Method for refining glyceride oils using acid-treated amorphous silica |
US4880574A (en) | 1984-12-07 | 1989-11-14 | W. R. Grace & Co.-Conn. | Method for refining glyceride oils using partially dried amorphous silica hydrogels |
US4726818A (en) | 1984-12-20 | 1988-02-23 | Union Carbide Corporation | Bulk removal of water from organic liquids |
GB8506907D0 (en) | 1985-03-18 | 1985-04-24 | Safinco Coordination Centre Nv | Removal of non-hydratable phoshatides from vegetable oils |
US4939115A (en) | 1986-01-28 | 1990-07-03 | W. R. Grace & Co.-Conn. | Organic acid-treated amorphous silicas for refining glyceride oils |
US5336794A (en) | 1986-05-14 | 1994-08-09 | W. R. Grace & Co.-Conn. | Dual phase adsorption and treatment of glyceride oils |
US5231201A (en) | 1986-05-14 | 1993-07-27 | W. R. Grace & Co.-Conn. | Modified caustic refining of glyceride oils for removal of soaps and phospholipids |
US4804555A (en) | 1986-10-21 | 1989-02-14 | General Mills, Inc. | Physical process for simultaneous deodorization and cholesterol reduction of fats and oils |
US4996072A (en) | 1987-03-02 | 1991-02-26 | General Mills, Inc. | Physical process for the deodorization and/or cholesterol reduction of fats and oils |
BE1001858A3 (nl) | 1988-06-29 | 1990-03-20 | Schelde Delta Bv Ba | Werkwijze voor het raffineren van olien. |
US4927544A (en) | 1988-07-06 | 1990-05-22 | N.V. Vandemoortele International | Process for the continuous removal of a gum phase from triglyceride oil |
US5264597A (en) | 1988-09-30 | 1993-11-23 | Van Den Bergh Foods, Co., Division Of Conopco, Inc. | Process for refining glyceride oil using precipitated silica |
US5079208A (en) | 1988-12-30 | 1992-01-07 | Van Den Bergh Foods Co., Division Of Conopco, Inc. | Synthetic, macroporous, amorphous alumina silica and a process for refining glyceride oil |
GB8906443D0 (en) | 1989-03-21 | 1989-05-04 | Unilever Plc | Process for refining glyceride oil using silica hydrogel |
HU208037B (en) | 1990-08-23 | 1993-07-28 | Noevenyolajipari Mososzergyart | Process for diminishing nonhydratable slime- and vax-content of plant-oils |
US5252762A (en) * | 1991-04-03 | 1993-10-12 | W. R. Grace & Co.-Conn. | Use of base-treated inorganic porous adsorbents for removal of contaminants |
CA2040677A1 (en) | 1991-04-03 | 1992-10-04 | Gabriella J. Toeneboehn | Fatty chemicals and wax esters |
US5449797A (en) | 1992-04-13 | 1995-09-12 | W. R. Grace & Co.-Conn. | Process for the removal of soap from glyceride oils and/or wax esters using an amorphous adsorbent |
US5298638A (en) | 1992-05-05 | 1994-03-29 | W. R. Grace & Co.-Conn. | Adsorptive removal of sulfur compounds from fatty materials |
EP0689578B1 (en) | 1993-03-17 | 1997-11-12 | Unilever N.V. | Removal of phospholipids from glyceride oil |
US5308365A (en) | 1993-08-31 | 1994-05-03 | Arco Chemical Technology, L.P. | Diesel fuel |
US5532392A (en) | 1994-01-13 | 1996-07-02 | Gheorghiu; Mihail | Process for the preparation of methyl fatty acid esters starting from natural oil or fat, methyl esters obtained in this way and use thereof |
GB9407504D0 (en) | 1994-04-15 | 1994-06-08 | Crown Chemtech Ltd | Stripping of volatile substances from less volatile fluids |
US5525126A (en) | 1994-10-31 | 1996-06-11 | Agricultural Utilization Research Institute | Process for production of esters for use as a diesel fuel substitute using a non-alkaline catalyst |
DE4447116A1 (de) | 1994-12-29 | 1996-07-04 | Sueddeutsche Kalkstickstoff | Verfahren zur Fraktionierung bzw. Raffination von lipiden Naturstoffen |
US6346286B1 (en) | 1995-04-26 | 2002-02-12 | Oil-Dri Corporation Of America | Sorptive purification for edible oils |
US5578090A (en) | 1995-06-07 | 1996-11-26 | Bri | Biodiesel fuel |
AUPN475095A0 (en) | 1995-08-11 | 1995-09-07 | Hyam Myers Consulting Pty. Limited | Removal of free fatty acids from oil and fats |
US5713965A (en) | 1996-04-12 | 1998-02-03 | The United States Of America As Represented By The Secretary Of Agriculture | Production of biodiesel, lubricants and fuel and lubricant additives |
US6015440A (en) | 1997-10-31 | 2000-01-18 | Board Of Regents Of The University Of Nebraska | Process for producing biodiesel fuel with reduced viscosity and a cloud point below thirty-two (32) degrees fahrenheit |
ES2178282T3 (es) | 1997-11-24 | 2002-12-16 | Energea Umwelttechnologie Gmbh | Procedimiento de fabricacion de esteres metilicos de acidos grasos e instalacion para la ejecucion del mismo. |
US6242620B1 (en) | 1998-03-05 | 2001-06-05 | Henkel Corporation | Process for making carboxylic acid esters |
US6172248B1 (en) | 1998-11-20 | 2001-01-09 | Ip Holdings, L.L.C. | Methods for refining vegetable oils and byproducts thereof |
US6447557B1 (en) | 1999-12-21 | 2002-09-10 | Exxonmobil Research And Engineering Company | Diesel fuel composition |
AU2001264880A1 (en) | 2000-05-24 | 2001-12-03 | The Texas A And M University System | Degumming of edible oils by ultrafiltration |
EP1258524B1 (en) | 2001-05-14 | 2005-12-07 | De Smet Engineering N.V. | Equipment and process for physical refining and/or deodorisation of edible oils and fats |
US6398707B1 (en) | 2001-05-31 | 2002-06-04 | Wen-Teng Wu | Method of preparing lower alkyl fatty acids esters and in particular biodiesel |
FR2838433B1 (fr) * | 2002-04-11 | 2005-08-19 | Inst Francais Du Petrole | Procede de production d'esters alkyliques a partir d'une huile vegetale ou animale et d'un monoalcool aliphatique |
ES2337692T3 (es) | 2003-10-09 | 2010-04-28 | The Dallas Group Of America, Inc. | Purificacion de biodiesel con materiales adsorbentes. |
US7160360B2 (en) * | 2003-12-08 | 2007-01-09 | Air Products And Chemicals, Inc. | Purification of hydride gases |
AU2003290414B2 (en) * | 2003-12-30 | 2010-11-04 | Council Of Scientific And Industrial Research | Improved process for preparing fatty acid alkylesters using as biodiesel |
US20050188607A1 (en) * | 2004-01-31 | 2005-09-01 | Lastella Joseph P. | System for removal of methanol from crude biodiesel fuel |
US7279147B2 (en) * | 2005-05-25 | 2007-10-09 | Selma Turkay | Method of producing an adsorbent from rice hull ash |
JP2007091852A (ja) * | 2005-09-28 | 2007-04-12 | Nof Corp | ポリオキシエチレン多価アルコール脂肪酸エステルの製造方法。 |
US7767178B2 (en) | 2005-10-18 | 2010-08-03 | Archer-Daniels-Midland Company | Regenerating molecular sieve absorbents used for alcohol dehydration |
EP1984476A2 (en) * | 2006-02-15 | 2008-10-29 | Honeywell International Inc. | Apparatus and method for removing sulfur containing compounds from a post-refinery fuel stream |
AU2007220657B2 (en) | 2006-02-28 | 2012-07-05 | Grace Gmbh & Co. Kg | Physical refining process using adsorbent particles for the production of biodiesel fuel |
KR20060029671A (ko) * | 2006-03-18 | 2006-04-06 | 최영철 | 폐튀김유를 이용한 고순도 바이오디젤을 합성하기 위한선택성 촉매흡착 정제공법 |
WO2008101032A1 (en) | 2007-02-13 | 2008-08-21 | Sartec Corporation | Devices and methods for selective removal of contaminants from a composition |
WO2009002878A1 (en) * | 2007-06-22 | 2008-12-31 | Biofuelbox Corporation | System for production and purification of biofuel |
-
2008
- 2008-12-18 JP JP2010538462A patent/JP2011506709A/ja not_active Withdrawn
- 2008-12-18 AU AU2008340728A patent/AU2008340728A1/en not_active Abandoned
- 2008-12-18 KR KR1020107016159A patent/KR20100107473A/ko not_active Application Discontinuation
- 2008-12-18 WO PCT/EP2008/010835 patent/WO2009080287A2/en active Application Filing
- 2008-12-18 CA CA2710089A patent/CA2710089A1/en not_active Abandoned
- 2008-12-18 US US12/808,913 patent/US8876922B2/en active Active
- 2008-12-18 RU RU2010130541/04A patent/RU2010130541A/ru unknown
- 2008-12-18 EP EP08864332A patent/EP2238220A2/en not_active Ceased
- 2008-12-18 MY MYPI2010002914A patent/MY158569A/en unknown
- 2008-12-18 BR BRPI0821652A patent/BRPI0821652A2/pt not_active IP Right Cessation
- 2008-12-18 CN CN200880127243.4A patent/CN101981159B/zh not_active Expired - Fee Related
- 2008-12-18 MX MX2010006711A patent/MX2010006711A/es unknown
- 2008-12-19 AR ARP080105604A patent/AR069859A1/es not_active Application Discontinuation
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