JP2011162644A - 光電変換用増感色素及びそれを用いた光電変換素子及び色素増感太陽電池 - Google Patents
光電変換用増感色素及びそれを用いた光電変換素子及び色素増感太陽電池 Download PDFInfo
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- JP2011162644A JP2011162644A JP2010026341A JP2010026341A JP2011162644A JP 2011162644 A JP2011162644 A JP 2011162644A JP 2010026341 A JP2010026341 A JP 2010026341A JP 2010026341 A JP2010026341 A JP 2010026341A JP 2011162644 A JP2011162644 A JP 2011162644A
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- photoelectric conversion
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- sensitizing dye
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Landscapes
- Photovoltaic Devices (AREA)
- Hybrid Cells (AREA)
Abstract
Description
下記一般式(1)で表される光電変換用増感色素。
前記一般式(1)において、nが2〜4の整数であることを特徴とする[1]記載の光電変換用増感色素。
下記一般式(2)で表される[1]または[2]に記載の光電変換用増感色素。
下記一般式(3)で表される[3]に記載の光電変換用増感色素。
下記一般式(4)で表される[3]に記載の光電変換用増感色素。
下記一般式(5)で表される[3]に記載の光電変換用増感色素。
下記一般式(6)で表される[3]に記載の光電変換用増感色素。
下記一般式(7)で表される[3]に記載の光電変換用増感色素。
[1]〜[8]のいずれか一つに記載の光電変換用増感色素を含有することを特徴とする光電変換素子。
トルエン30ml中に下記の化合物(B−1)0.6g、ロダニン−3−酢酸0.3g、ピペリジン0.4gを加えて6時間加熱撹拌した。室温まで冷却後、固体をろ取し、酢酸水溶液に分散してしばらく撹拌してから、結晶を濾取した。得られた結晶は0.3gで収率は76%であった。
1−ピレンボロン酸2.0gと5’’−ブロモ−[2,2’;5’,2’’]ターチオフェン−5−カルバルデヒド2.4gをDMSO溶媒中、酢酸パラジウム、ブチルジ−1−アダマンチルホスフィン、酢酸カリウム存在下で反応させた。後処理して、下記の化合物(B−2)を1.3g得た。
エタノール100ml中に下記の化合物(B−3)1.0g、ロダニン−3−酢酸0.5g、ピペリジン0.5gを加えて5時間加熱撹拌した。室温まで冷却後、固体をろ取し、酢酸水溶液に分散してしばらく撹拌してから、結晶をろ取した。得られた結晶は1.3gで収率は93%であった。
フッ素ドープの酸化スズ薄膜をコートしたガラス基板上に酸化チタンペースト(Solaronix製Ti−Nanoxide T)をスキージ法により塗布した。110℃で1時間乾燥後、450℃で30分間焼成し、膜厚6μmの酸化チタン薄膜を得た。次に、増感色素(A−5)をメタノールに溶解して濃度100μMの溶液50mlを作製し、この溶液中に、酸化チタンを塗布焼結したガラス基板を室温で15時間浸漬して色素を吸着させ、光電極とした。
光電変換用増感色素として、実施例4で使用した(A−5)の代わりにそれぞれ表1に示す増感色素を用い、それ以外は実施例4と同様にして光電変換素子を作製して特性を測定した。結果を表1及び表2に示す。
光電変換用増感色素として、実施例4で使用した(A−5)の代わりにそれぞれ下記の(C−1)〜(C−4)に示す色素を用い、それ以外は実施例4と同様にして光電変換素子を作製して特性を測定した。結果を表1及び表2に示す。
Claims (10)
- 下記一般式(1)で表される光電変換用増感色素。
- 前記一般式(1)において、nが2〜4の整数であることを特徴とする請求項1記載の光電変換用増感色素。
- 下記一般式(3)で表される請求項3に記載の光電変換用増感色素。
- 請求項1〜8のいずれか一項に記載の光電変換用増感色素を含有することを特徴とする光電変換素子。
- 対向電極間に少なくとも半導体層及び電解質層が設けられている色素増感太陽電池において、請求項1〜8のいずれか一項に記載の光電変換用増感色素を半導体層に担持させて得られることを特徴とする色素増感太陽電池。
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JP2010026341A JP5700937B2 (ja) | 2010-02-09 | 2010-02-09 | 光電変換用増感色素及びそれを用いた光電変換素子及び色素増感太陽電池 |
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JP2010026341A JP5700937B2 (ja) | 2010-02-09 | 2010-02-09 | 光電変換用増感色素及びそれを用いた光電変換素子及び色素増感太陽電池 |
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JP2011162644A true JP2011162644A (ja) | 2011-08-25 |
JP5700937B2 JP5700937B2 (ja) | 2015-04-15 |
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CN110690350A (zh) * | 2014-02-24 | 2020-01-14 | 株式会社理光 | 光电转换元件和太阳能电池 |
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