JP6307298B2 - 光電変換用増感色素およびそれを用いた光電変換素子ならびに色素増感太陽電池 - Google Patents
光電変換用増感色素およびそれを用いた光電変換素子ならびに色素増感太陽電池 Download PDFInfo
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- JP6307298B2 JP6307298B2 JP2014028145A JP2014028145A JP6307298B2 JP 6307298 B2 JP6307298 B2 JP 6307298B2 JP 2014028145 A JP2014028145 A JP 2014028145A JP 2014028145 A JP2014028145 A JP 2014028145A JP 6307298 B2 JP6307298 B2 JP 6307298B2
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Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
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- Photovoltaic Devices (AREA)
Description
窒素置換した反応容器中に、トルエン15ml、3,9−ジブロモベンゾアントロン764mg、ジフェニルアミン667mg、ナトリウム−tert−ブトキシド530mg、ビス(ジベンジリデンアセトン)パラジウム34mg、1,1’−ビス(ジフェニルホスフィノ)フェロセン98mgを加え、82℃で2時間加熱攪拌した。反応溶液を室温まで冷却した後、クロロホルム100mlを加えて攪拌し、有機層を抽出した。水洗、飽和食塩水による洗浄を順次行い、得られた有機層を硫酸マグネシウムで乾燥し、減圧下で溶媒を留去することによって粗製物を得た。粗製物を、シリカゲルカラムクロマトグラフィー(担体:シリカゲル、溶離液:n−ヘキサン/トルエン)により精製し、減圧乾燥することによって、下記化合物(C−1)304mg(収率32%)の濃茶色オイルを得た。
フッ素ドープの酸化スズ薄膜をコートしたガラス基板上に、酸化チタンペースト(日揮触媒化成株式会社製、PST−18NR)をスキージ法により塗布した。110℃で1時間乾燥後、450℃で30分間焼成し、膜厚7μmの酸化チタン薄膜を得た。次に、合成例1で得られた光電変換用増感色素(A−2)およびデオキシコール酸を、それぞれ濃度が100μMおよび1mMになるようにアセトニトリル/tert−ブチルアルコール=1/1の混合溶媒に溶解して溶液50mlを調製し、この溶液中に、酸化チタンを塗布焼結したガラス基板を、室温において15時間浸漬して色素を吸着させ、光電極とした。
光電変換用増感色素として、(A−2)の代わりにそれぞれ表1に示す増感色素を用いた以外は、実施例1と同様に光電変換素子を作製し、電流−電圧特性を測定した。また、光を20時間照射した後についても光電変換効率の測定を行い、特性変化を評価した。測定結果を表1にまとめて示した。
光電変換用増感色素として、(A−2)の代わりに、本発明に属さない以下の(D−1)および(D−2)に示す光電変換用増感色素を用いた以外は、実施例1と同様に光電変換素子を作製し、電流−電圧特性を測定した。また、光を20時間照射した後についても光電変換効率の測定を行い、特性変化を評価した。測定結果を表1にまとめて示した。
2 色素担持半導体層
3 電解質層
4 対極
5 導電性支持体
Claims (8)
- 下記一般式(1)で表される光電変換用増感色素。
- 前記一般式(1)において、XまたはYのいずれか一方が水素原子であることを特徴とする、請求項1記載の光電変換用増感色素。
- 前記一般式(1)において、Yが水素原子であることを特徴とする、請求項1または請求項2のいずれか一項に記載の光電変換用増感色素。
- 前記一般式(1b)において、Aが前記一般式(A1)で示される1価基であることを特徴とする、請求項1〜請求項3のいずれか一項に記載の光電変換用増感色素。
- 前記一般式(1)において、R1〜R7が全て水素原子であることを特徴とする、請求項1〜請求項4のいずれか一項に記載の光電変換用増感色素。
- 一対の対向する電極間に、少なくとも半導体層および電解質層が設けられている色素増感型の光電変換素子において、請求項1〜請求項5のいずれか一項に記載の光電変換用増感色素が前記半導体層に担持されていることを特徴とする光電変換素子。
- 前記光電変換素子において、前記電解質層が4−tert−ブチルピリジンを含有することを特徴とする、請求項6記載の光電変換素子。
- 光電変換素子を有する色素増感太陽電池であって、請求項6または請求項7のいずれか一項に記載の光電変換素子をモジュール化し、所定の電気配線を設けることによって得られることを特徴とする色素増感太陽電池。
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