JP2011077225A5 - - Google Patents

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JP2011077225A5
JP2011077225A5 JP2009225906A JP2009225906A JP2011077225A5 JP 2011077225 A5 JP2011077225 A5 JP 2011077225A5 JP 2009225906 A JP2009225906 A JP 2009225906A JP 2009225906 A JP2009225906 A JP 2009225906A JP 2011077225 A5 JP2011077225 A5 JP 2011077225A5
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thermal expansion
semiconductor chip
electrode
low thermal
expansion plate
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Claims (15)

半導体基板の両面に金属電極膜が形成された半導体チップと、
前記半導体チップの下に第一の接合層を介して接合された第一の低熱膨張板と、
前記第一の低熱膨張板の下に第二の接合層を介して接合されたベース電極と、
前記半導体チップの上に第三の接合層を介して接合された第二の低熱膨張板と、
前記第二の低熱膨張板の上に第四の接合層を介して接合されたリード電極と、
前記ベース電極及びリード電極の一部と半導体チップと低熱膨張板と各接合層を覆うように形成された絶縁樹脂とを備え、
前記第一と第三の接合層が液相温度:300〜500℃の鉛を含まないはんだ材料で構成されており、前記第二と第三の接合層が空孔率20〜70%の多孔質なAg層から構成されいることを特徴とする半導体装置。
A semiconductor chip having metal electrode films formed on both sides of the semiconductor substrate;
A first low thermal expansion plate bonded via a first bonding layer under the semiconductor chip;
A base electrode joined via a second joining layer under the first low thermal expansion plate;
A second low thermal expansion plate bonded via a third bonding layer on the semiconductor chip;
A lead electrode bonded on the second low thermal expansion plate via a fourth bonding layer;
A part of the base electrode and the lead electrode, a semiconductor chip, a low thermal expansion plate, and an insulating resin formed so as to cover each bonding layer,
The first and third bonding layers are made of a lead-free solder material having a liquidus temperature of 300 to 500 ° C., and the second and third bonding layers are porous with a porosity of 20 to 70%. wherein a that consists quality of Ag layer.
半導体基板の両面に金属電極膜が形成された半導体チップと、
前記半導体チップの下に第一の接合層を介して接合された低熱膨張板と、
前記低熱膨張板の下に第二の接合層を介して接合されたベース電極と、
前記半導体チップの上に第の接合層を介して接合されたリード電極と、
前記リード電極及びベース電極の一部と半導体チップと低熱膨張板と各接合層を覆うように形成された絶縁樹脂とを備え、
前記第一の接合層が液相温度:300〜500℃の鉛を含まないはんだ材料から構成され、前記第二と第三の接合層が空孔率20〜70%の多孔質なAg層で構成された構造となっていることを特徴とする半導体装置。
A semiconductor chip having metal electrode films formed on both sides of the semiconductor substrate;
A low thermal expansion plate bonded via a first bonding layer under the semiconductor chip;
A base electrode joined via a second joining layer under the low thermal expansion plate;
A lead electrode joined via a third joining layer on the semiconductor chip;
A portion of the lead electrode and base electrode, a semiconductor chip, a low thermal expansion plate, and an insulating resin formed to cover each bonding layer;
The first bonding layer is composed of a solder material containing no lead having a liquidus temperature of 300 to 500 ° C., and the second and third bonding layers are porous Ag layers having a porosity of 20 to 70%. A semiconductor device having a structured structure.
請求項1または2において、
液相温度:300〜500℃の鉛を含まないはんだ材料が、Sn,Sb,Ag,Cuを主要構成元素とする多元系の高温はんだで構成され、
低熱膨張板の面方向の熱膨張率が8ppm以下となっていることを特徴とする半導体装置。
In claim 1 or 2,
Liquid phase temperature: 300-500 ° C. lead-free solder material is composed of multi-component high-temperature solder whose main constituent elements are Sn, Sb, Ag, Cu,
A semiconductor device characterized in that the coefficient of thermal expansion in the surface direction of the low thermal expansion plate is 8 ppm or less.
請求項1または2において、
ベース電極及びリード電極及び低熱膨張板及び半導体チップがNiめっきされた部品であり、
多孔質なAg層で金属接合されるNiめっき部品の接続面に、接合層に比べて空孔率が小さくかつ空孔サイズも小さい多孔質なAgの膜が形成された構造となっていることを特徴とする半導体装置。
In claim 1 or 2,
The base electrode, the lead electrode, the low thermal expansion plate and the semiconductor chip are Ni-plated parts,
The structure is such that a porous Ag film having a smaller porosity and smaller pore size than the joining layer is formed on the connection surface of the Ni-plated component that is metal-joined with a porous Ag layer. A semiconductor device characterized by the above.
請求項1または2において、
多孔質なAg層で構成された接合層中に、最大粒径がAg接合層の1/2以上のサイズを有する貴金属めっきされたCu,Ni,Al,Mg,Mo,Wのいずれか1種以上の高導電金属粒子が分散配置されていることを特徴とする半導体装置。
In claim 1 or 2,
Any one of Cu, Ni, Al, Mg, Mo, and W plated with a noble metal having a maximum particle size of 1/2 or more of the Ag bonding layer in the bonding layer composed of a porous Ag layer A semiconductor device characterized in that the above highly conductive metal particles are dispersedly arranged.
半導体チップとリード電極とベース電極と低熱膨張板と絶縁樹脂からなる半導体装置において、
部材のNiめっき面の上に空孔率が1〜30%で、その内の密閉系の空孔比率が50%以上で、厚さが1〜30μmの多孔質なAgのメタライズ膜が形成され、その上に空孔率が20〜70%で、その内の開放系の空孔比率が50%以上で、厚さが70〜500μmの多孔質なAgの接合層が形成され、多孔質なAg接合層内の開放形の空洞部の少なくとも一部に熱硬化性の樹脂が充填された接続構造を有し、
リード電極とベース電極の一部を除いて全体が絶縁樹脂で覆われた構造となっていることを特徴とする半導体装置。
In a semiconductor device comprising a semiconductor chip, a lead electrode, a base electrode, a low thermal expansion plate, and an insulating resin,
A porous Ag metallized film having a porosity of 1 to 30%, a closed pore ratio of 50% or more, and a thickness of 1 to 30 μm is formed on the Ni plating surface of the member. A porous Ag bonding layer having a porosity of 20 to 70%, an open system porosity ratio of 50% or more, and a thickness of 70 to 500 μm is formed on the porous layer. Having a connection structure in which at least a part of the open cavity in the Ag bonding layer is filled with a thermosetting resin;
A semiconductor device characterized in that the entire structure is covered with an insulating resin except for part of a lead electrode and a base electrode.
請求項6において、リード電極及びベース電極がCuにNiめっきされた部材であり、
Agメタライズ膜は接続面周辺の限られた領域のみに形成されていることを特徴とする半導体装置。
In Claim 6, the lead electrode and the base electrode are members plated with Ni on Cu,
An Ag metallized film is formed only in a limited region around a connection surface.
請求項6において、多孔質なAgメタライズ膜中に、膜厚と同等以上のAg粒子が埋設された構造を有していることを特徴とする半導体装置。   7. The semiconductor device according to claim 6, wherein the porous Ag metallized film has a structure in which Ag particles equal to or larger than the film thickness are embedded. 請求項7において、Agメタライズ膜はNi面上に有機Ag錯体の溶液を塗布し、大気中で加熱・焼成する方法で形成されたAg膜であることを特徴とする半導体装置。   8. The semiconductor device according to claim 7, wherein the Ag metallized film is an Ag film formed by a method of applying a solution of an organic Ag complex on a Ni surface and heating and baking in the air. 表面にNiめっきが施された高導電性のリード電極及びベース電極と、
表面にNiめっきが施された低熱膨張板と、
半導体基板の両面にNiを含む金属電極膜が形成された半導体チップと、
リード電極及びベース電極の一部を除いて全体を覆うように形成された絶縁樹脂からなる半導体装置の製造方法において、
リード電極及びベース電極の接合面と低熱膨張板の片方の面に有機Ag錯体溶液あるいはナノAg粒子を分散した有機溶液を塗布して大気中で200〜350℃に加熱焼成処理してAgメタライズする工程と、
半導体チップの両面に前記低熱膨張板のNiめっき側を還元雰囲気中の加熱処理によって高温鉛フリーはんだで接合して接合部品を作製する工程と、
ベース電極のAgメタライズされた領域に焼結タイプのAgペーストを塗布しその上に半導体チップと低熱膨張板の前記接合部品を搭載しさらに接合部品の上側のAgメタライズされた領域に焼結タイプのAgペーストを塗布してその上にリード電極を搭載するマウント工程と、
マウントされた組立体を大気中で加熱速度20℃/分以下の緩やかな昇温で200〜350℃の温度に加熱して焼結・接合する工程と、
リード電極とベース電極の一部を除いて絶縁樹脂が全体を覆うように供給し加熱・硬化処理する工程とを含むことを特徴とする半導体装置の製造方法。
A highly conductive lead electrode and base electrode with Ni plating on the surface;
A low thermal expansion plate with Ni plating on the surface;
A semiconductor chip in which a metal electrode film containing Ni is formed on both sides of a semiconductor substrate;
In the manufacturing method of a semiconductor device made of an insulating resin formed so as to cover the whole except for a part of the lead electrode and the base electrode,
An organic Ag complex solution or an organic solution in which nano-Ag particles are dispersed is applied to the joint surface of the lead electrode and the base electrode and one surface of the low thermal expansion plate, and is heat-baked at 200 to 350 ° C. in the atmosphere to be Ag metallized. Process,
A step of producing a joining component by joining the Ni plating side of the low thermal expansion plate to both surfaces of a semiconductor chip with a high-temperature lead-free solder by heat treatment in a reducing atmosphere;
A sintered type Ag paste is applied to the Ag metallized region of the base electrode, and the joining component of the semiconductor chip and the low thermal expansion plate is mounted thereon. Further, the sintered type Ag paste is applied to the Ag metallized region on the upper side of the joining component. A mounting step of applying an Ag paste and mounting a lead electrode thereon;
Heating and mounting the mounted assembly to a temperature of 200 to 350 ° C. at a moderate temperature increase of 20 ° C./min or less in the atmosphere;
A method of manufacturing a semiconductor device, comprising: supplying an insulating resin so as to cover the entire surface except for a part of the lead electrode and the base electrode, and performing a heating and curing process.
請求項10において、
組立体を焼結・接合処理した後に、多孔質の焼結Ag接合層に液状の熱硬化性樹脂を含浸させ加熱・硬化処理する工程を追加したことを特徴とする半導体装置の製造方法。
In claim 10,
A method for manufacturing a semiconductor device, comprising adding a step of impregnating a porous sintered Ag bonding layer with a liquid thermosetting resin after the assembly is sintered and bonded, followed by heating and curing.
請求項11において、
多孔質の焼結Ag接合層に液状の熱硬化性樹脂を含浸させる前に、組立接合体に有機Zn錯体溶液を塗布し250〜350℃の温度で大気中の焼成処理を行う工程を加えたことを特徴とする半導体装置の製造方法。
In claim 11,
Before impregnating the porous sintered Ag bonding layer with the liquid thermosetting resin, a step of applying an organic Zn complex solution to the assembly bonded body and performing a baking treatment in the atmosphere at a temperature of 250 to 350 ° C. was added. A method for manufacturing a semiconductor device.
平均粒径0.1〜3μmの粒状Agで表面に200℃以下で分解する有機保護膜を形成したAg粒子と、ペースト化のための有機溶媒と、粒径3〜30μmのAg粒子と、粒径50〜500μmの球状の貴金属粒子あるいは貴金属めっきした球状のCu,Ni,Al,Mg,Mo,Wなどの高導電粒子とから構成されたペースト状の接続材料。   Ag particles having an average particle size of 0.1 to 3 μm formed with an organic protective film that decomposes at 200 ° C. or less on the surface, an organic solvent for pasting, Ag particles having a particle size of 3 to 30 μm, A paste-like connecting material composed of spherical noble metal particles having a diameter of 50 to 500 μm or highly conductive particles such as noble metal plated spherical Cu, Ni, Al, Mg, Mo and W. 接続部材の熱膨張率差が5ppm以上で接続面の長手方向の寸法が3mm以上である接続箇所が多孔質のAg層を介して金属接合された構造を有し、接続部の熱膨張差が5ppm未満の接続箇所が鉛フリーの高温はんだで接合された構造を有し、
半導体チップと1つ以上の低熱膨張部材と複数の高導電性電極部材から構成された半導体装置。
The connecting part has a structure in which the difference in the thermal expansion coefficient of the connecting member is 5 ppm or more and the length of the connecting surface in the longitudinal direction is 3 mm or more and is metal-bonded through a porous Ag layer. It has a structure where the connection points of less than 5ppm are joined with lead-free high-temperature solder,
A semiconductor device comprising a semiconductor chip, one or more low thermal expansion members, and a plurality of highly conductive electrode members.
半導体基板の両面に最表面が貴金属の金属電極膜が形成された半導体チップと、A semiconductor chip in which a metal electrode film having a noble metal on the outermost surface is formed on both sides of the semiconductor substrate;
前記半導体チップの下に第一の接合層を介して接合された最表面に空孔を有する貴金属膜が形成されたベース電極と、A base electrode in which a noble metal film having pores is formed on the outermost surface bonded via a first bonding layer under the semiconductor chip;
前記半導体チップの上に第二の接合層を介して接合された最表面に空孔を有する貴金属膜が形成されたリード電極と、A lead electrode formed with a noble metal film having a hole on the outermost surface bonded to the semiconductor chip via a second bonding layer;
前記リード電極及びベース電極の一部と半導体チップと各接合層を覆うように形成された絶縁樹脂とを備え、Insulating resin formed so as to cover a part of the lead electrode and the base electrode, the semiconductor chip and each bonding layer,
前記第一と第二の接合層が空孔率20〜70%の多孔質なAg層で構成された構造となっていることを特徴とする半導体装置。The semiconductor device according to claim 1, wherein the first and second bonding layers have a structure composed of a porous Ag layer having a porosity of 20 to 70%.
JP2009225906A 2009-09-30 2009-09-30 Semiconductor device, connection structure and manufacturing method thereof Expired - Fee Related JP5449958B2 (en)

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* Cited by examiner, † Cited by third party
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NL2005112C2 (en) 2010-07-19 2012-01-23 Univ Leiden Process to prepare metal nanoparticles or metal oxide nanoparticles.
WO2014080449A1 (en) 2012-11-20 2014-05-30 トヨタ自動車株式会社 Semiconductor device
JP6026900B2 (en) * 2013-01-30 2016-11-16 京セラ株式会社 Electronic component storage package and electronic device using the same
JP6168586B2 (en) * 2013-02-15 2017-07-26 国立研究開発法人産業技術総合研究所 Bonding method and semiconductor module manufacturing method
WO2014129626A1 (en) 2013-02-22 2014-08-28 古河電気工業株式会社 Connecting structure, and semiconductor device
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Family Cites Families (3)

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JPH08167625A (en) * 1994-12-14 1996-06-25 Hitachi Ltd Pressure welded semiconductor device manufacturing method
JP4275005B2 (en) * 2004-05-24 2009-06-10 株式会社日立製作所 Semiconductor device
JP5123633B2 (en) * 2007-10-10 2013-01-23 ルネサスエレクトロニクス株式会社 Semiconductor devices and connecting materials

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