JP2011032216A - 固形油性化粧料 - Google Patents
固形油性化粧料 Download PDFInfo
- Publication number
- JP2011032216A JP2011032216A JP2009180288A JP2009180288A JP2011032216A JP 2011032216 A JP2011032216 A JP 2011032216A JP 2009180288 A JP2009180288 A JP 2009180288A JP 2009180288 A JP2009180288 A JP 2009180288A JP 2011032216 A JP2011032216 A JP 2011032216A
- Authority
- JP
- Japan
- Prior art keywords
- titanium oxide
- titanate
- component
- extract
- solid oily
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 28
- 239000007787 solid Substances 0.000 title claims abstract description 21
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 39
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 39
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000011248 coating agent Substances 0.000 claims abstract description 17
- 238000000576 coating method Methods 0.000 claims abstract description 14
- QPQANCNBWQXGTQ-UHFFFAOYSA-N trihydroxy(trimethylsilylperoxy)silane Chemical compound C[Si](C)(C)OO[Si](O)(O)O QPQANCNBWQXGTQ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002245 particle Substances 0.000 claims abstract description 5
- -1 isopropylisostearoyl titanate Chemical compound 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 10
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 5
- 239000000470 constituent Substances 0.000 abstract 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
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- 238000011282 treatment Methods 0.000 description 8
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- 239000011164 primary particle Substances 0.000 description 5
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- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
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- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 2
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- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
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- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
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- 229920001436 collagen Polymers 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
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- 235000019258 dehydroacetic acid Nutrition 0.000 description 1
- 229940061632 dehydroacetic acid Drugs 0.000 description 1
- JEQRBTDTEKWZBW-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1=C(O)OC(C)=CC1=O JEQRBTDTEKWZBW-UHFFFAOYSA-N 0.000 description 1
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Natural products CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 description 1
- XMQYIPNJVLNWOE-UHFFFAOYSA-N dioctyl hydrogen phosphite Chemical compound CCCCCCCCOP(O)OCCCCCCCC XMQYIPNJVLNWOE-UHFFFAOYSA-N 0.000 description 1
- KNXNFEMPRRJNKP-UHFFFAOYSA-N dioctyl phosphono phosphate propan-2-ol titanium Chemical compound [Ti].CC(C)O.CCCCCCCCOP(=O)(OP(O)(O)=O)OCCCCCCCC.CCCCCCCCOP(=O)(OP(O)(O)=O)OCCCCCCCC.CCCCCCCCOP(=O)(OP(O)(O)=O)OCCCCCCCC KNXNFEMPRRJNKP-UHFFFAOYSA-N 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229940007062 eucalyptus extract Drugs 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
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- 229940038487 grape extract Drugs 0.000 description 1
- OIKBVOIOVNEVJR-UHFFFAOYSA-N hexadecyl 6-methylheptanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCC(C)C OIKBVOIOVNEVJR-UHFFFAOYSA-N 0.000 description 1
- 229960004881 homosalate Drugs 0.000 description 1
- 235000020721 horse chestnut extract Nutrition 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
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- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- NFIDBGJMFKNGGQ-UHFFFAOYSA-N isopropylmethylphenol Natural products CC(C)CC1=CC=CC=C1O NFIDBGJMFKNGGQ-UHFFFAOYSA-N 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 229940083980 lavender extract Drugs 0.000 description 1
- 235000020723 lavender extract Nutrition 0.000 description 1
- 229940069445 licorice extract Drugs 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229940078752 magnesium ascorbyl phosphate Drugs 0.000 description 1
- 201000001441 melanoma Diseases 0.000 description 1
- LZXXNPOYQCLXRS-UHFFFAOYSA-N methyl 4-aminobenzoate Chemical compound COC(=O)C1=CC=C(N)C=C1 LZXXNPOYQCLXRS-UHFFFAOYSA-N 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 235000013557 nattō Nutrition 0.000 description 1
- 229960003921 octisalate Drugs 0.000 description 1
- WCJLCOAEJIHPCW-UHFFFAOYSA-N octyl 2-hydroxybenzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1O WCJLCOAEJIHPCW-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 210000002826 placenta Anatomy 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZUFQODAHGAHPFQ-UHFFFAOYSA-N pyridoxine hydrochloride Chemical compound Cl.CC1=NC=C(CO)C(CO)=C1O ZUFQODAHGAHPFQ-UHFFFAOYSA-N 0.000 description 1
- 229960004172 pyridoxine hydrochloride Drugs 0.000 description 1
- 235000019171 pyridoxine hydrochloride Nutrition 0.000 description 1
- 239000011764 pyridoxine hydrochloride Substances 0.000 description 1
- 229940048084 pyrophosphate Drugs 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 229940092258 rosemary extract Drugs 0.000 description 1
- 235000020748 rosemary extract Nutrition 0.000 description 1
- 239000001233 rosmarinus officinalis l. extract Substances 0.000 description 1
- 229940109850 royal jelly Drugs 0.000 description 1
- 229940119485 safflower extract Drugs 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 229940112950 sage extract Drugs 0.000 description 1
- 235000020752 sage extract Nutrition 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 201000000849 skin cancer Diseases 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
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- 239000004299 sodium benzoate Substances 0.000 description 1
- 229960003885 sodium benzoate Drugs 0.000 description 1
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- 229940079839 sodium dehydroacetate Drugs 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
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- 235000011088 sodium lactate Nutrition 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
本発明の目的は酸化チタンが有する優れた紫外線遮蔽効果を十分に発揮し得る固形油性化粧料を提供することである。
【解決手段】(A)トリメチルシロキシケイ酸、(B)有機チタネート被覆処理酸化チタンを含有することを特徴とする固形油性化粧料。好ましくは成分(B)の構成成分である有機チタネートがイソプロピルイソステアロイルチタネートであること、成分(B)の構成成分である酸化チタンの平均粒子径が0.1〜0.4μmであること、有機チタネートの被覆量が有機チタネート被覆処理酸化チタン100重量%あたり、0.2〜10重量%である。
【選択図】なし
Description
しかし有機チタネート被覆処理とトリメチルシロキシケイ酸を併用することによって併用しない場合より高SPFを得られることは全く知られていない。
本発明は、かかる知見に基づいて開発されたものである。
トリメチルシロキシケイ酸はネイルエナメル等の皮膜剤として普通に使用されている。
A:メチルハイドロジェンポリシロキサン2%被覆処理酸化チタン
B:(ジメチコン/メチコン)コポリマー2%被覆処理酸化チタン
C:N−ステアロイルL−グルタミン酸ナトリウム2%被覆処理酸化チタン
D:イソプロピルイソステアロイルチタネート2%被覆処理酸化チタン
A〜Dは実験例1の酸化チタンを上記素材で被覆処理した。
日本化粧品工業連合会の方法(2007年8月10日通達)に準じて、SPF値を測定した。
日本化粧品工業連合会の方法(2007年8月10日通達)に準じて、SPF値を測定した。
(1)ジメチルジステアリルアンモニウムベントナイト 1.5
(2)トリメチルシロキシケイ酸(信越シリコン社製;シリコンKF−7312K)
5.0
(3)ソルビタンモノイソステアリン酸エステル 0.5
(4)固形パラフィン 3.0
(5)マイクロクリスタリンワックス 7.0
(6)ワセリン 13.5
(7)ジメチルポリシロキサン 3.0
(8)スクワラン 5.0
(9)ミリスチン酸オクチルドデシル 11.5
(10)酢酸トコフェロール 0.2
(11)タルク 2.8
(12)カオリン 19.8
(13)マイカ 3.0
(14)イソプロピルイソステアロイルチタネート5重量%被覆処理 酸化チタン
20.0
(15)イソプロピルイソステアロイルチタネート5重量%被覆処理ベンガラ 1.0
(16)イソプロピルイソステアロイルチタネート5重量%黄酸化鉄 2.9
(17)イソプロピルイソステアロイルチタネート5重量%被覆処理黒酸化鉄 0.2
(18)香料 0.1
(1)固形パラフィン 3.0
(2)マイクロクリスタリンワックス 7.0
(3)ワセリン 15.0
(4)ジメチルポリシロキサン 3.0
(5)スクワラン 5.0
(6)パルミチン酸イソプロピル 17.0
(7)酢酸トコフェロール 0.2
(8)タルク 2.8
(9)カオリン 29.7
(10)マイカ 3.0
(11)イソプロピルイソステアロイルチタネート2重量%被覆処理酸化チタン
10.0
(12)イソプロピルイソステアロイルチタネート2重量%被覆処理ベンガラ 1.0
(13)イソプロピルイソステアロイルチタネート2重量%被覆処理黄酸化鉄 3.0
(14)イソプロピルイソステアロイルチタネート2重量%被覆処理黒酸化鉄 0.2
(15)香料 0.1
(1)デカメチルシクロペンタシロキサン 残量
(2)トリメチルシロキシケイ酸 (信越シリコン社製;シリコンKF-7312K)
10.0
(3)メチルフェニルポリシロキサン 10.0
(4)イソオクタン酸セチル 10.0
(5)イソプロピルイソステアロイルチタネート5重量%被覆処理処理酸化チタン
15.0
(6)イソプロピルイソステアロイルチタネート5重量%被覆処理処理酸化鉄(黄、赤、
黒) 3.0
(7)イソプロピルイソステアロイルチタネート5重量%被覆処理処理セリサイト
5.0
(8)シリカ 5.0
(9)ポリアクリル酸アルキル 2.0
(10)ナイロン末 2.0
(11)香料 適量
Claims (5)
- (A)トリメチルシロキシケイ酸、(B)有機チタネート被覆処理酸化チタンを含有することを特徴とする固形油性化粧料。
- メイクアップ化粧料であることを特徴とする請求項1の固形油性化粧料。
- 成分(B)の構成成分である有機チタネートがイソプロピルイソステアロイルチタネートであることを特徴とする請求項1または請求項2に記載の固形油性化粧料。
- 成分(B)の構成成分である酸化チタンの平均粒子径が0.1〜0.4μmであることを特徴とする請求項1乃至請求項3に記載の固形油性化粧料。
- 成分(B)の構成成分である有機チタネート被覆処理酸化チタンにおいて有機チタネートの被覆量が有機チタネート被覆処理酸化チタン100重量%あたり、0.2〜10重量%であることを特徴とする請求項1乃至請求項4に記載の固形油性化粧料。
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JPH09208438A (ja) * | 1995-11-28 | 1997-08-12 | Ishihara Sangyo Kaisha Ltd | 微粒子二酸化チタンシリコ−ン分散体 |
JP2004203788A (ja) * | 2002-12-25 | 2004-07-22 | Kose Corp | 固形状油中水型乳化化粧料 |
JP2007217380A (ja) * | 2006-02-20 | 2007-08-30 | Shiseido Co Ltd | 油中水型乳化日焼け止め化粧料 |
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JPH09208438A (ja) * | 1995-11-28 | 1997-08-12 | Ishihara Sangyo Kaisha Ltd | 微粒子二酸化チタンシリコ−ン分散体 |
JP2004203788A (ja) * | 2002-12-25 | 2004-07-22 | Kose Corp | 固形状油中水型乳化化粧料 |
JP2007217380A (ja) * | 2006-02-20 | 2007-08-30 | Shiseido Co Ltd | 油中水型乳化日焼け止め化粧料 |
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WO2012121309A1 (ja) * | 2011-03-08 | 2012-09-13 | 株式会社資生堂 | 油性固形化粧料 |
JP2012197270A (ja) * | 2011-03-08 | 2012-10-18 | Shiseido Co Ltd | 油性固形化粧料 |
CN103415282A (zh) * | 2011-03-08 | 2013-11-27 | 株式会社资生堂 | 油性固体化妆品 |
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