JP2010539316A - 表面からカラーコートおよび種々の汚損層を除去するための配合物、その配合物の製造方法、および洗浄方法 - Google Patents
表面からカラーコートおよび種々の汚損層を除去するための配合物、その配合物の製造方法、および洗浄方法 Download PDFInfo
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- JP2010539316A JP2010539316A JP2010525365A JP2010525365A JP2010539316A JP 2010539316 A JP2010539316 A JP 2010539316A JP 2010525365 A JP2010525365 A JP 2010525365A JP 2010525365 A JP2010525365 A JP 2010525365A JP 2010539316 A JP2010539316 A JP 2010539316A
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- water
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- ethyl
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
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- C11D2111/14—
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- C11D2111/24—
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3427—Organic compounds containing sulfur containing thiol, mercapto or sulfide groups, e.g. thioethers or mercaptales
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3472—Organic compounds containing sulfur additionally containing -COOH groups or derivatives thereof
Abstract
【選択図】なし
Description
a)4g/L未満の水に対する溶解度を有する少なくとも1つの水不溶性物質(油)と、
b)少なくとも1つの両親媒性物質、NP−MCA、であって、整列した親水性−疎水性界面活性剤構造を有しておらず、それ自体は構造形成性ではなく、すなわちミセルを形成せず、水または油に対するその溶解度は4g/L〜1,000g/Lであり、かつ油−水界面に優先的には蓄積しない少なくとも1つの両親媒性物質、NP−MCA(ただしこのNP−MCAは、2−エチル−1,3−ヘキサンジオール、2−メチル−2,4−ペンタンジオール、2−(n−ブチル)−2−エチル−1,3−プロパンジオールから、および/または1,2−ジオールからは選択されない)と、
c)少なくとも1つのアニオン性、カチオン性、両性および/または非イオン性の界面活性剤と、
d)水および/またはヒドロキシ官能性を有する水溶性の溶剤と、
任意に、補助物質と、
を含むことを特徴とする洗浄用組成物を提供することにより成し遂げられる。
i)X点、
ii)一相領域から二相領域への境界領域と、Lα領域の開始点における温度座標と平行に引かれた接線との上側の交点、
iii)一相領域から二相領域への境界領域と、Lα領域の開始点における温度座標と平行に引かれた接線との下側の交点、
によって定められる相図に含まれる三角形の面積の少なくとも5%の増加をもたらすことを特徴とする。
M.Kahlweit、R.Strey、D.Haase、H.Kunieda、T.Schmeling、B.Faulhaber、M.Borkovec、H.F.Eicke、G.Busse、F.Eggers、T.Funck、H.Richmann、L.Magid、O.Soderman、P.Stilbs、J.Winkler、A.Dittrich、およびW.Jahn:「How to Study Microemulsions」、J.Colloid Interf.Sci.、118(2)、436(1987)、
J.Lyklemaによって編集されたFundamentals of Interface and Colloid Science、第V巻、Academic Press(2005)の中のT.SottmannおよびR.Strey、Microemulsions
に記載されている。
i)第一級または第二級の炭素原子上の末端の非極性鎖のうちで4以上の炭素原子を有するものはない。その鎖がより長い場合は、その鎖は、分子量の20%より多くの部分を構成してはならない;
ii)その分子の内部または第三級炭素原子上の非極性鎖は、7炭素原子以下の長さであり(すなわち、例えば1,9−ノナンジオールより大きい)、かつその分子量の20%より多くの部分を構成しない。より大きい鎖は非極性の領域に存在することができるが、他方でその分子の極性部分は親水性の領域に見出されるべきである;
iii)単環式アルコールにおいては、その環を通る最短経路が鎖長として選択され、項目iおよびiiに従って鎖長が決定される;
iv)多環式アルコールにおいては、完全に非極性の環だけが、項目iおよびiiに対応する鎖長の決定のために考慮され、炭素原子の最小の数が、ここでの鎖長として採用される;
ように、混合される。
R1R2COH−(CH2)n−COHR1R2 [式I]
(式中、
nは0、1、2、3または4であってもよく、
R1およびR2は、各々、互いに独立に、水素または非分枝状もしくは分枝状のC1〜C3アルキルであるが、ただしn=0の場合、R1は水素ではあり得ず、かつこのこのジオールは2−メチル−2,4−ペンタンジオールではない)
から選択される。
C(R3)3−CO−CH2−CO−O−R4 [式II]
(式中、
R3は、各々、互いに独立に、水素またはC1〜C2アルキルであり、
R4は分枝状または非分枝状のC1〜C4アルキルである)
、または式IIIのアセト酢酸エステル:
CH3−CO−CH2−CO−O−R5 [式III]
(式中、R5はC1〜C4アルキルである)
から選択される。
CH3−(CH2)p−CO−(CH2)q−CO−(CH2)r−CH3 [式IV]
(式中、p、q、rは、互いに独立に0、1または2であるが、ただしp、qおよびrの和=2である場合、式IVの化合物は環状(シクロヘキサンジオン)であってもよい)
から選択される。
R6−CO−O−R7 [式V]
(式中、
R6はR7に対する環結合、CH3またはCOCH3であり、
R7はR6に対する(CH2)2−O−環結合、(CH2)2−O−(CH2)3−CH3、CH2−CH3またはR6に対するCH2−CH(CH3)−O−環結合である)
から選択される。
R8−HN−CO−C=C−CO−O−R9 [式VI]
(式中、
R8は水素、分枝状もしくは非分枝状のC1〜C4アルキル、または分枝状もしくは非分枝状の、直鎖状もしくは環状のC1〜C6アルキルであり、式中、このC1〜C6アルキルはOH、NH2、COOH、CO、SO3H、OP(OH)2から選択される1以上の基によって置換されており、
R9は水素または分枝状または非分枝状のC1〜C4アルキルである)
から選択される。
a)増粘:使用におけるほとんどの表面は、低粘度液体が落書きによる損壊部位から下方向にすぐに流れ出す垂直壁である。それゆえこの液体の増粘は、この流れ出しを遅らせまたは防止さえするために、好ましい。実験から得られた低粘度液体を増粘するために、市販の増粘剤を用いることができる。例えばアエロジル(Aerosil)(登録商標) 380などの焼成シリカは特に好ましい。
b)防炎:当該落書き除去剤は、いくつかの高揮発性物質を含有することができるため、防炎剤が適切である場合がある。当該組成物は、例えばリン酸トリエチル(TEP)またはリン酸トリオクチル(リン酸トリス(2−エチルヘキシル)(TEHP))などを加えることによって、自己消火性として配合できる。
c)臭気の改善:最終使用者のためにこの配合物の臭気を改善しようとする場合は、これは多くの従来の香気物質を用いて行うことができる。言及してもよい例は、ブタン酸メチル(パイナップル)、メタン酸エチル(ラズベリー)、エタン酸ペンチル(バナナ)、ペンタン酸ペンチル(リンゴ)、ブタン酸ペンチル(アプリコット)、エタン酸オクチル(オレンジ)などのエステルである。これらは、例えば本発明に係る液体における親油性の活性化合物の例を代表することができるオレンジテルペンまたはD−リモネンと組み合わせることもできる。他の香気物質も、例えばゲラニオールなど、テルペンの分野で見出すことができる。
1〜90%の水不溶性物質a)と、
1〜80%のNP−MCA b)と、
2〜45%の界面活性剤c)(任意にさらなる両親媒性物質を含む)と、
1〜90%の水と、
任意に、最高10%までの補助物質と
(この百分率データは、いずれの場合も、当該洗浄用組成物の総重量に関する)を含有する。
a)従来の溶剤ベースの従来の落書き除去剤(図1を参照)、剥離配合物またはマニキュア液除去剤よりも、または溶剤一般よりも(たとえ、これらが良好な溶媒和特性を有することが公知であっても)、
b)個々の成分それ自体よりも(図2を参照)、
c)水を含まずかつ/または界面活性剤を含まない、溶剤成分の混合物よりも、
d)公知のエマルションベースの従来の落書き除去剤または溶剤成分から調製されるエマルションよりも、
e)水および界面活性剤の混合物よりも、
著しくより効果的に、よりきれいにおよびある場合にはより迅速に、種々の基材からラッカーおよびコーティング引き剥がす。
a)ラッカー結合剤はこの液体によって分子的に分散した形態で溶解されないから、主たる洗浄効果は、先験的にラッカーの物理的溶解にあるわけではなく、
b)ラッカーの著しい膨潤(ある場合には、波のような形状になり、ある場合にはラッカー層の中に微視的に小さい孔を伴う)、およびその後のおよそ100μm〜2mmのサイズのラッカーの小片へのラッカー層の破壊(断片化)、および
c)そのラッカー層のうちの大きな領域の下の移動(その後の、層の持ち上がりを伴う)にある。
d)すべての処理された、様々な構造の基材は、ラッカーが湿った掃除用具または低圧スプレー(3〜20bar(0.3〜2MPa))で処理されたときに、事実上、色の痕跡を示さなかった。これは、この液体が分子的に分散した形態でラッカーを溶解させず、それゆえ微粉化された色素粒子を放出せず、水と組み合わさって洗浄用液体として機能するからである。
a)未希釈の形態において:通常、ラッカーの断片化と組み合わせて、落書き塗料の結合剤系の膨潤または表面的な溶解(膨潤の場合には、塗料層の下での基材への移行も)、
b)例えば湿ったスポンジ、ブラシまたは刷毛の中で起こるように、少量の水と一緒に:洗浄用液体の生成およびその基材からの膨潤したかつ/または溶解したラッカー粒子の持ち上げ。
(図1)
実施例2による本発明に係る落書き除去剤と、1−メトキシ−2−プロパノールに基づく従来の落書き除去剤(Baufan RICO Graffiti−Killer)との比較。落書きによって損なわれた粗い下塗りを有する壁の写真(落書きの年数は少なくとも1年)。同時でかつ同じ長さの時間の落書き除去剤の作用、5分後のスポンジを用いた上記除去剤の拭き取り、およびその後の低圧の水噴射(<3bar(<0.3MPa))を用いた壁の洗い流し:
a)本発明に係る配合物は、色の痕跡を示さず、もとの正面用塗料(白色)の機能障害も示さず、そして端縁における色のグラジエントも示さず、未処理の領域からのシャープな境界を示す。
b)1−メトキシ−2−プロパノールに基づく従来の落書き除去剤は、他方で、落書き塗料の塗り広がりによって引き起こされる作用部位から未処理領域への不鮮明な端縁を伴うより劣悪な塗料の除去を示す。さらに、この組成物で希釈された塗料は、一部は石膏の孔に吸収され、これが色の痕跡を生成し、これは、苦労してようやく後で除去することができる。
ラッカー溶剤としての酢酸エチルを有する従来のマニキュア液除去剤essence(登録商標)、実施例5の本発明に係るマニキュア液除去剤、および個々の成分の活性。
a)良好なマニキュア液の除去、端縁に向けての塗り広がり、
b)ナノ相流体による良好なマニキュア液の除去、膨潤した領域を伴うシャープな端縁、
c)実質的に引き剥がしなし、膨潤なし、
d)ほとんど何もマニキュア液の除去はない、
e)端縁に向けての重度の塗り広がりを伴う、マニキュア液の除去、
ナノ相流体b)の個々の成分c)およびd)は、それ自体は、このマニキュア液の引き剥がしについての活性を示さない;成分e)は貧溶媒である。
a)洗浄前の状態およびb)洗浄後の状態で示す、汚れ除去剤としての本発明に係る洗浄用組成物の活性。市販の洗浄用組成物は1の下で使用され、ナノ相構造形成を伴う本発明に係る洗浄用組成物は2の下で使用された。
a)洗浄前の状態およびb)洗浄後の状態で示す、化粧品除去剤としての本発明に係る洗浄用組成物の活性。市販の化粧品除去剤は1の下で使用され、ナノ相構造形成を有する本発明に係る洗浄用組成物は2の下で使用された。b)の中の下側の数字は、その領域が、洗浄サイクル、すなわち対応する洗浄用組成物を含浸した脱脂綿のパッドを用いて軽い圧力で一方向のみで何回上を拭き取られたかを示す。
a)洗浄後の状態およびb)洗浄前の状態で示す、毛髪脱色剤としての本発明に係る洗浄用組成物の活性。
a)アセト酢酸エチル、b)アセトン、c)本発明に係る洗浄用組成物 落書きCRACK、d)本発明に係る洗浄用組成物LisoCLEAR、e)本発明に係る洗浄用組成物V1113に関する、液体系の中でのナノ構造形成の検出のためのレーザー光線の散乱。
ナノ相を形成しない洗浄用組成物と比較した、ラッカーの除去における本発明に係る洗浄用組成物の活性であり、洗浄後の結果はa)アセト酢酸エチル、b)V141(ナノ相なし)、c)本発明に係る洗浄用組成物NP1、d)本発明に係る洗浄用組成物NP2、e)本発明に係る洗浄用組成物NP3、f)V142(ナノ相なし)について示される。
ナノ相を形成しない洗浄用組成物と比較した、タイルの洗浄における本発明に係る洗浄用組成物の活性であり、いずれの場合もa)洗浄前の状態およびb)洗浄後の状態で示す。マイクロエマルションについての結果は1)の下に示され、エマルション系についての結果は2)の下に示され、本発明に係るナノ相系の結果は3)の下に示される。
図9では、流体NP2のナノ構造形成を凍結割断法電子顕微鏡写真によって見ることができる。より小さい球状構造(矢印)は、小さい構造形成された油相内に分散されているおよそ20〜50nmのサイズの水層のミセルである。
洗浄用組成物の一相および二相およびラメラ存在領域の過程を界面活性剤濃度および温度の関数として表す相図(魚型ダイヤグラムまたは鯨型ダイヤグラム)。マイクロエマルションとしての組成物はa)に示され、ナノ相流体としての、さらに4%のNP−MCAを含有する同じ組成物はb)に示される。この洗浄用組成物の一相存在領域の温度範囲、ΔTが示され、ΔTは、下側および上側の、この洗浄用組成物の一相存在領域と二相存在領域との間の分離線と、温度軸に平行なLα領域に対する接線との交点(複数)によって区切られている、その接線の、この魚型ダイヤグラムにおいて決定される長さによって決定される。図10から分かるように、NP−MCAの存在により温度範囲ΔTの増加がもたらされる。
背景:種々の基材からの汚れの除去は、いまだ、一部しか解決されていない課題である。多くの場合、市販の洗浄用組成物は、マイクロメートルサイズの孔の中に浸透できず、汚れの粒子を溶かし出しまたはしっかりと付着した汚れを他のやり方で引き剥がすことはできない。他方、ナノ構造が形成された液体は、低表面張力、徐々に浸透する性質およびナノ粒子および微粒子を取り込む傾向のため、それができる。
左側の写真(1):市販の界面活性剤洗浄用組成物は洗浄効果をもたらさなかった。
右側の写真(2):ナノ構造が形成された配合物を用いた洗浄後、この樺の木の樹脂は残渣なく引き剥がれた。
微細な孔のあるセラミックまたは鉱物性基材(割り石タイル、下塗り、コンクリートなど)からの汚れの除去は、いまだ、一部しか解決されていない課題である。多くの場合、市販の洗浄用組成物は、マイクロメートルサイズの孔の中に浸透できず、汚れの粒子を溶かし出しまたはしっかりと付着した汚れを他のやり方で引き剥がすことはできない。他方、ナノ相流体が形成された液体は、低表面張力、徐々に浸透する性質およびナノ粒子および微粒子を取り込む傾向のため、それができる。
組成物1はマイクロエマルションであり、
組成物2はエマルション系であり、および
組成物3はナノ相系 lisoCLEAR 55 nPMAである(この配合物はタイル、セラミック、正面の壁およびラッカーを洗浄するために開発された)。
背景:耐水性のキスしても落ちない化粧品および涙で落ちない化粧品はこれまで以上に頻繁に市場で見出すことができ、さらに、最近はその品質が一層よくなった。かかる化粧品もまた、もはや温水を用いても容易に除去することはできない。
黒色のヘアカラーで着色した毛髪の房を流体42の中に一晩(16.5時間)保持した。脱色した毛髪(a)を未処理の毛髪の房(b)と比較した:結果を図5に示す。処理した毛髪の脱色が起こったことが見出される。
ナノ相系のナノ構造形成の検出のためのレーザー光線の散乱についての実験。
a)アセト酢酸エチル:緑色のレーザー光線はこの液体の中では見えない、すなわち散乱はなく、それゆえナノ構造形成はない。
b)アセトン:緑色のレーザー光線はこの液体の中では見えない、すなわち散乱はなく、それゆえナノ構造形成はない。
c)落書きCRACK:緑色のレーザー光線は散乱によって見える、すなわちこの液体はナノ構造を有している。赤色のレーザー光線はさらにほとんど散乱しなかった。これは、この赤色の光の波長が、ここでの相互作用には長すぎるからである。
d)lisoCLEAR:緑色のレーザー光線は散乱によって見える、すなわちこの液体はナノ構造を有している。
e)マニキュア液除去剤(処方V113):緑色のレーザー光線は散乱によって見える、すなわちこの液体はナノ構造を有している。
多孔性基材上のラッカーの引き剥がし/溶解特性の比較試験のために、6つの液体を試験した:
a)溶剤としての作用を有するアセト酢酸エチル − ナノ構造は形成されていない:このラッカーの塗り広がり。
b)溶剤混合物(V141) − ナノ構造は形成されていない:このラッカーの塗り広がり。
グリセロール:8.34%、エタノール:8.30%、ジアセトンアルコール:35.02%、アセト酢酸エチル:21.00%、酢酸n−ブチル:6.64%、ヘキサノール:8.26%、酢酸ベンジル:8.30%、オレンジテルペン:4,15%。
赤色:Produkt Auto K(20330、VW/Audi、マルスレッド、L31 B)
黄色:Produkt Auto K(22218、FORD、シグナルイエロー、77 KLP/97)
緑色:Produkt Auto K(21395、OPEL、ミントグリーン、361)
銀色:Produkt Monex、Lack Spray(Rallye ホイールリム シルバー、7093)
青色:Produkt Dupli Color、(空色、サテンマット、DCP 5200/RAL 5015)。
Claims (15)
- 洗浄用組成物であって、マイクロエマルションまたは流体ナノ相系を含有し、かつ以下の構成要素:
a)4g/L未満の水に対する溶解度を有する少なくとも1つの水不溶性物質と、
b)少なくとも1つの両親媒性物質、NP−MCA、であって、界面活性剤構造を有しておらず、それ自体は構造形成性ではなく、水または油に対するその溶解度は4g/L〜1,000g/Lであり、かつ油−水界面に優先的には蓄積しない少なくとも1つの両親媒性物質、NP−MCA(ただし前記NP−MCAは、2−エチル−1,3−ヘキサンジオール、2−メチル−2,4−ペンタンジオール、2−(n−ブチル)−2−エチル−1,3−プロパンジオールから、および/または1,2−ジオールからは選択されない)と、
c)少なくとも1つのアニオン性、カチオン性、両性および/または非イオン性の界面活性剤と、
d)水および/またはヒドロキシ官能性を有する水溶性の溶剤と、
任意に、補助物質と、
を含むことを特徴とする、洗浄用組成物。 - 前記NP−MCAが、前記構成要素a)、c)およびd)を含有する油−水−界面活性剤系に前記系の総重量に基づき4重量%を添加した際に前記NP−MCAが、3つの端点:
i)X点、
ii)一相領域から二相領域への境界領域と、Lα領域の開始点における温度座標と平行に引かれた接線との上側の交点、
iii)前記一相領域から前記二相領域への境界領域と、前記Lα領域の開始点における前記温度座標と平行に引かれた前記接線との下側の交点、
によって定められる相図に含まれる三角形の面積の少なくとも5%の増加をもたらすことを特徴とする、請求項1に記載の洗浄用組成物。 - 前記洗浄用組成物がさらなる両親媒性物質を含むことを特徴とする、請求項1または請求項2に記載の洗浄用組成物。
- 前記NP−MCAが、
a)式Iのジオール:
R1R2COH−(CH2)n−COHR1R2 [式I]
(式中、
nは0、1、2、3または4であることができ、
R1およびR2は、各々、互いに独立に、水素または非分枝状もしくは分枝状のC1〜C3アルキルであるが、ただしn=0の場合、R1は水素ではあり得ず、かつ前記ジオールは2−メチル−2,4−ペンタンジオールではない)
から選択されるか、または1,3−プロパンジオール、1,3−ブタンジオール、1,4−ブタンジオール、1,5−ペンタンジオール、1,6−ヘキサンジオール、2,3−ブタンジオール、2,4−ペンタンジオールまたは2,5−ジメチル−2,5−ヘキサンジオールから選択されるか、
b)式IIのアセト酢酸エステル:
C(R3)3−CO−CH2−CO−O−R4 [式II]
(式中、
R3は、各々、互いに独立に、水素またはC1〜C2アルキルであり、
R4は、分枝状または非分枝状のC1〜C4アルキルである)
から選択されるか、または
式IIIのアセト酢酸エステル:
CH3−CO−CH2−CO−O−R5 [式III]
(式中、R5はC1〜C4アルキルである)
から選択されるか、またはアセト酢酸エチル、アセト酢酸イソ−プロピル、アセト酢酸メチル、アセト酢酸n−ブチル、アセト酢酸n−プロピルまたはアセト酢酸tert−ブチルから選択されるか、
c)式IVのジオン:
CH3−(CH2)p−CO−(CH2)q−CO−(CH2)r−CH3 [式IV]
(式中、p、q、rは、互いに独立に、0、1または2であることができるが、ただしp、qおよびrの和=2である場合は、式IVに係る化合物は環状(シクロヘキサンジオン)であることもできる)
から選択されるか、または2,3−ブタンジオン(ジアセチル)、2,4−ペンタンジオン(アセチルアセトン)、3,4−ヘキサンジオン、2,5−ヘキサンジオン、2,3−ペンタンジオン、2,3−ヘキサンジオン、1,4−シクロヘキサンジオンまたは1,3−シクロヘキサンジオンから選択されるか、
d)式Vのエステル:
R6−CO−O−R7 [式V]
(式中、
R6はR7への環結合、CH3またはCOCH3であり、
R7は、R6への(CH2)2−O−環結合、(CH2)2−O−(CH2)3−CH3、CH2−CH3またはR6へのCH2−CH(CH3)−O−環結合である)
から選択されるか、または酢酸(1−メトキシ−2−プロピル)、酢酸(2−ブトキシエチル)、炭酸エチレン、ピルビン酸エチル(2−オキソプロピオン酸エチルエステル)または炭酸プロピレンから選択されるか、
e)式VIのマレイン酸アミドまたはフマル酸アミド:
R8−HN−CO−C=C−CO−O−R9 [式VI]
(式中、
R8は、水素、分枝状もしくは非分枝状のC1〜C4アルキル、または分枝状もしくは非分枝状の、直鎖状もしくは環状のC1〜C6アルキルであり、前記C1〜C6アルキルはOH、NH2、COOH、CO、SO3H、OP(OH)2から選択される1以上の基によって置換されており、
R9は水素または分枝状または非分枝状のC1〜C4アルキルである)
から選択されるか、以下のマレイン酸アミドならびにそのメチル、エチル、プロピルおよびブチルエステル:N−メチルマレアミド;N−エチルマレアミド;N−(n−プロピル)−マレアミド;N−(i−プロピル)−マレアミド;N−(n−ブチル)−マレアミド;N−(i−ブチルマレアミド);N−(tert−ブチルマレアミド)、ならびに対応するフマル酸アミドならびにそのメチル、エチル、プロピルおよびブチルエステルから選択されるか、
f)2,2−ジメトキシプロパン、ピルビンアルデヒド1,1−ジメチルアセタール、ジアセトンアルコール(2−メチル−2−ペンタノール−4−オン)、2−ブタノール、2−アセチル−γ−ブチロラクトン、3−アミノ−1H−1,2,4−トリアゾール、γ−ブチロラクトン、ニコチンアミド、アスコルビン酸、N−アセチルアミノ酸、特にN−アセチルグリシン、N−アセチルアラニン、N−アセチルシステイン、N−アセチルバリンまたはN−アセチルアルギニン、リン酸トリエチル、酢酸n−ブチル、ジメチルスルホキシドまたは2,2,2−トリフルオロエタノールから選択される
ことを特徴とする、請求項1〜請求項3のいずれか1項に記載の洗浄用組成物。 - 前記NP−MCAが、式IIIのアセト酢酸エステル:
CH3−CO−CH2−CO−O−R5 [式III]
(式中、R5はC1〜C4アルキルである)
から選択されることを特徴とする、請求項1〜請求項4のいずれか1項に記載の洗浄用組成物。 - 前記水不溶性物質が2g/L未満の水溶性を有し、前記物質が、アルカン、シクロアルカン、芳香族化合物、長鎖アルカン酸エステル、ジカルボン酸もしくはトリカルボン酸のエステル、テルペン、またはこれらの混合物を含む群から選択されることを特徴とする、請求項1〜請求項5のいずれか1項に記載の洗浄用組成物。
- 以下の組成:
1〜90%の水不溶性物質a)、
1〜80%のNP−MCA b)、
2〜45%の界面活性剤c)(任意にさらなる両親媒性物質を含む)、
1〜90%の水
任意に最高10%までの補助物質
(前記百分率データは、いずれの場合も前記洗浄用組成物の総重量に関する)を有することを特徴とする、請求項1〜請求項6のいずれか1項に記載の洗浄用組成物。 - 前記洗浄用組成物が、2〜25重量%のNP−MCA(前記百分率データは前記洗浄用組成物の総重量に関する)を含むことを特徴とする、請求項1〜請求項7のいずれか1項に記載の洗浄用組成物。
- 前記アセト酢酸エステル化合物がアセト酢酸エチルであることを特徴とする、請求項1〜請求項8のいずれか1項に記載の洗浄用組成物。
- 前記洗浄用組成物が9〜16重量%の請求項1のc)に記載の界面活性剤(前記百分率データは前記洗浄用組成物の総重量に関する)を含むことを特徴とする、請求項1〜請求項9のいずれか1項に記載の洗浄用組成物。
- 請求項1〜請求項10のいずれか1項に記載の洗浄用組成物の調製のためのプロセスであって、水またはヒドロキシ官能性を有する溶剤が最初に準備され、アニオン性、カチオン性、両性および/または非イオン性の界面活性剤が、撹拌しながら10〜90℃で前記水またはヒドロキシ官能性を有する溶剤の中に溶解され、水不溶性物質が前記界面活性剤の添加と並行してまたは添加後に添加され、次いで形成されたエマルションは、さらなる両親媒性物質およびNP−MCAの添加により視覚的に透明なマイクロエマルションまたはナノ相系へと変換され、かつ補助物質が任意に、前記混合操作の最後に加えられることを特徴とする、プロセス。
- 表面から望ましくない塗料およびラッカーを除去するための方法であって、請求項1〜請求項10のいずれか1項に記載の洗浄用組成物が前記望ましくない塗料または前記ラッカーに付与され、作用し、次いで前記塗料または前記ラッカーは水で除去され、前記作用時間は、落書き除去剤については約10秒間〜約30分間、剥離配合物については約20分間〜約3時間、およびマニキュア液除去剤については約3〜約30秒間であることを特徴とする、方法。
- 落書き除去剤、剥離配合物またはマニキュア液除去剤としての、請求項1〜請求項10のいずれか1項に記載の洗浄用組成物の使用。
- 表面から汚れ(カーボンブラック、脂肪、油、シリコーン、細塵、樹脂およびこれらの構成要素の1以上を含む混合物)を除去するため、化粧品を除去するため、または毛髪を脱色するための方法であって、請求項1〜請求項10のいずれか1項に記載の洗浄用組成物が前記汚れ、除去しようとする前記化粧品または脱色しようとする前記毛髪に付与され、作用し、次いで前記汚れ、前記組成物または前記色は水で除去され、前記作用時間は、汚れ除去剤については約10秒間〜約3時間、化粧品除去剤については約10秒間〜約30分間、および毛髪脱色剤については約2分間〜約24時間であることを特徴とする、方法。
- 汚れ除去剤、タイル洗浄剤、化粧品除去剤または毛髪脱色剤としての、請求項1〜請求項10のいずれか1項に記載の洗浄用組成物の使用。
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2007
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- 2007-09-19 AT AT07116792T patent/ATE554743T1/de active
-
2008
- 2008-09-19 CN CN201610147706.XA patent/CN105779146A/zh active Pending
- 2008-09-19 EP EP10004122.7A patent/EP2223995B8/de active Active
- 2008-09-19 JP JP2010525365A patent/JP5844523B2/ja active Active
- 2008-09-19 CN CN200880116681.0A patent/CN101861381B/zh active Active
- 2008-09-19 US US12/678,809 patent/US20110229424A1/en not_active Abandoned
- 2008-09-19 EP EP08804501A patent/EP2195408A2/de not_active Withdrawn
- 2008-09-19 WO PCT/EP2008/062573 patent/WO2009037349A2/de active Application Filing
- 2008-09-19 BR BRPI0817128A patent/BRPI0817128A2/pt not_active Application Discontinuation
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2014
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012521281A (ja) * | 2009-03-26 | 2012-09-13 | バブルズ アンド ビヨンド ゲーエムベーハー | 物体を洗浄するための方法及び組成物 |
JP2015510964A (ja) * | 2012-03-20 | 2015-04-13 | ベルント シュベークマン ゲーエムベーハー ウント コー カーゲー | マイクロエマルションベースの洗浄剤 |
JP2021091903A (ja) * | 2013-10-11 | 2021-06-17 | インテリジェント フルーイド ゲーエムベーハー | 高機能溶液を用いたフォトレジスト剥離 |
JP7022226B2 (ja) | 2013-10-11 | 2022-02-17 | インテリジェント フルーイド ゲーエムベーハー | 高機能溶液を用いたフォトレジスト剥離 |
Also Published As
Publication number | Publication date |
---|---|
EP2223995A2 (de) | 2010-09-01 |
WO2009037349A2 (de) | 2009-03-26 |
WO2009037349A3 (de) | 2009-12-30 |
BRPI0817128A2 (pt) | 2015-10-27 |
JP5844523B2 (ja) | 2016-01-20 |
ATE554743T1 (de) | 2012-05-15 |
US20110229424A1 (en) | 2011-09-22 |
CN101861381B (zh) | 2016-03-30 |
CN101861381A (zh) | 2010-10-13 |
EP2223995B1 (de) | 2018-03-07 |
EP2223995A3 (de) | 2011-04-20 |
EP2195408A2 (de) | 2010-06-16 |
CN105779146A (zh) | 2016-07-20 |
EP2045320B1 (de) | 2012-04-25 |
EP2045320A1 (de) | 2009-04-08 |
EP2223995B8 (de) | 2018-06-13 |
US20140274855A1 (en) | 2014-09-18 |
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