JP2010523703A5 - - Google Patents
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- Publication number
- JP2010523703A5 JP2010523703A5 JP2010503224A JP2010503224A JP2010523703A5 JP 2010523703 A5 JP2010523703 A5 JP 2010523703A5 JP 2010503224 A JP2010503224 A JP 2010503224A JP 2010503224 A JP2010503224 A JP 2010503224A JP 2010523703 A5 JP2010523703 A5 JP 2010523703A5
- Authority
- JP
- Japan
- Prior art keywords
- liquid
- mixture
- dichlorohydrin
- phase
- vapor contact
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- SSZWWUDQMAHNAQ-UHFFFAOYSA-N 3-chloropropane-1,2-diol Chemical compound OCC(O)CCl SSZWWUDQMAHNAQ-UHFFFAOYSA-N 0.000 claims description 81
- 238000000034 method Methods 0.000 claims description 55
- 239000000203 mixture Substances 0.000 claims description 45
- 239000007788 liquid Substances 0.000 claims description 37
- 150000002148 esters Chemical class 0.000 claims description 34
- 239000007791 liquid phase Substances 0.000 claims description 33
- DEWLEGDTCGBNGU-UHFFFAOYSA-N 1,3-dichloropropan-2-ol Chemical compound ClCC(O)CCl DEWLEGDTCGBNGU-UHFFFAOYSA-N 0.000 claims description 29
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 17
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 17
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 17
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 17
- 239000008346 aqueous phase Substances 0.000 claims description 15
- 238000004821 distillation Methods 0.000 claims description 14
- 239000012074 organic phase Substances 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000009835 boiling Methods 0.000 claims description 11
- 239000012320 chlorinating reagent Substances 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 11
- 239000006227 byproduct Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 238000000926 separation method Methods 0.000 claims description 9
- 238000010992 reflux Methods 0.000 claims description 8
- 238000004064 recycling Methods 0.000 claims description 6
- 239000012808 vapor phase Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000005194 fractionation Methods 0.000 claims description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 4
- XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 238000007038 hydrochlorination reaction Methods 0.000 claims description 3
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 230000007423 decrease Effects 0.000 claims description 2
- 238000006735 epoxidation reaction Methods 0.000 claims description 2
- 238000001704 evaporation Methods 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 238000000746 purification Methods 0.000 claims description 2
- 238000010977 unit operation Methods 0.000 claims description 2
- 239000012071 phase Substances 0.000 claims 3
- -1 water Chemical class 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US92302007P | 2007-04-12 | 2007-04-12 | |
| PCT/US2008/059979 WO2008128013A1 (en) | 2007-04-12 | 2008-04-11 | Process and apparatus for azeotropic recovery of dichlorohydrins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2010523703A JP2010523703A (ja) | 2010-07-15 |
| JP2010523703A5 true JP2010523703A5 (cg-RX-API-DMAC7.html) | 2011-05-19 |
Family
ID=39643205
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010503224A Pending JP2010523703A (ja) | 2007-04-12 | 2008-04-11 | ジクロロヒドリンの共沸回収方法及び装置 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8629305B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP2137124A1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP2010523703A (cg-RX-API-DMAC7.html) |
| KR (1) | KR20090130123A (cg-RX-API-DMAC7.html) |
| CN (1) | CN101657405A (cg-RX-API-DMAC7.html) |
| TW (2) | TW201518267A (cg-RX-API-DMAC7.html) |
| WO (1) | WO2008128013A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20100016455A (ko) * | 2007-04-12 | 2010-02-12 | 다우 글로벌 테크놀로지스 인크. | 공증류에 의한 다이클로로하이드린 회수 방법 및 장치 |
| TW201518267A (zh) | 2007-04-12 | 2015-05-16 | Dow Global Technologies Llc | 用於二氯丙醇的共沸回收之方法與設備 |
| US8471077B2 (en) | 2008-04-09 | 2013-06-25 | Dow Global Technologies Llc | Process and apparatus for efficient recovery of dichlorohydrins |
| EP2448898A1 (en) | 2009-07-03 | 2012-05-09 | Akzo Nobel Chemicals International B.V. | Process for preparing dichlorohydrin |
| BR112012030071A2 (pt) * | 2010-05-26 | 2016-08-09 | Dow Global Technologies Inc | processo para produção de cloridrina, um éster de cloridrina, ou uma mistura dos mesmos e produto |
| TWI547470B (zh) * | 2015-12-18 | 2016-09-01 | 長春人造樹脂廠股份有限公司 | 製造二氯丙醇之方法 |
| RU2716433C1 (ru) * | 2016-08-11 | 2020-03-11 | ВЕРСАЛИС С.п.А. | Способ очистки растворителя, использованного при получении эластомерных смесей |
| CN109107207B (zh) * | 2018-07-18 | 2021-07-23 | 万华化学集团股份有限公司 | 一种带有外循环系统的反应精馏装置及其应用 |
| CN111875477A (zh) * | 2020-08-03 | 2020-11-03 | 岳阳隆兴实业公司 | 一种邻氯醇共沸提纯方法 |
| CN111943805A (zh) * | 2020-09-16 | 2020-11-17 | 安徽工业大学 | 一种(r)-3-氯-1,2-丙二醇的制备方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE197308C (cg-RX-API-DMAC7.html) | ||||
| JPS60258171A (ja) * | 1984-06-04 | 1985-12-20 | Showa Denko Kk | エピクロルヒドリンの製造方法 |
| CZ20032346A3 (cs) | 2003-09-01 | 2005-04-13 | Spolek Pro Chemickou A Hutní Výrobu,A.S. | Způsob přípravy dichlorpropanolů z glycerinu |
| EA200800128A1 (ru) * | 2003-11-20 | 2008-04-28 | Солвей (Сосьете Аноним) | Способ получения хлорированного органического соединения, эпихлоргидрина и эпоксидных смол из возобновляемого сырья |
| US6908038B1 (en) * | 2004-02-27 | 2005-06-21 | Imotion Corp. | Multi-connector memory card with retractable sheath to protect the connectors |
| JP2008507526A (ja) | 2004-07-21 | 2008-03-13 | ダウ グローバル テクノロジーズ インコーポレイティド | 多ヒドロキシル化脂肪族炭化水素又はそのエステルのクロロヒドリンへの転化 |
| EP1762556A1 (en) * | 2005-05-20 | 2007-03-14 | SOLVAY (Société Anonyme) | Process for producing dichloropropanol from glycerol |
| CA2608956A1 (en) * | 2005-05-20 | 2006-09-28 | Solvay (Societe Anonyme) | Method for making chlorohydrin in liquid phase in the presence of heavy compounds |
| CN100509726C (zh) | 2007-01-26 | 2009-07-08 | 江苏工业学院 | 一种从甘油制备二氯丙醇的方法 |
| KR20100016455A (ko) * | 2007-04-12 | 2010-02-12 | 다우 글로벌 테크놀로지스 인크. | 공증류에 의한 다이클로로하이드린 회수 방법 및 장치 |
| TW201518267A (zh) | 2007-04-12 | 2015-05-16 | Dow Global Technologies Llc | 用於二氯丙醇的共沸回收之方法與設備 |
| TWI432407B (zh) * | 2007-04-12 | 2014-04-01 | Dow Global Technologies Llc | 回收二氯丙醇之多階方法和裝置 |
-
2008
- 2008-04-11 TW TW104101060A patent/TW201518267A/zh unknown
- 2008-04-11 EP EP08745564A patent/EP2137124A1/en not_active Withdrawn
- 2008-04-11 TW TW097113155A patent/TWI490193B/zh not_active IP Right Cessation
- 2008-04-11 KR KR1020097023535A patent/KR20090130123A/ko not_active Ceased
- 2008-04-11 JP JP2010503224A patent/JP2010523703A/ja active Pending
- 2008-04-11 CN CN200880011774A patent/CN101657405A/zh active Pending
- 2008-04-11 WO PCT/US2008/059979 patent/WO2008128013A1/en not_active Ceased
- 2008-04-11 US US12/595,493 patent/US8629305B2/en not_active Expired - Fee Related