JP2010247524A - 物品、積層体及び関連方法 - Google Patents
物品、積層体及び関連方法 Download PDFInfo
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- JP2010247524A JP2010247524A JP2010027072A JP2010027072A JP2010247524A JP 2010247524 A JP2010247524 A JP 2010247524A JP 2010027072 A JP2010027072 A JP 2010027072A JP 2010027072 A JP2010027072 A JP 2010027072A JP 2010247524 A JP2010247524 A JP 2010247524A
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- Prior art keywords
- selectively permeable
- agent
- membrane
- permeable coating
- article
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Images
Classifications
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D5/00—Composition of materials for coverings or clothing affording protection against harmful chemical agents
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- A41—WEARING APPAREL
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Abstract
【解決手段】物品10は、多孔質膜11、この膜に支持された第1の選択的透過性コーティング12及び多孔質膜11及び/又はそこに設けられた他のコーティングからの選択的透過性コーティング12の層間剥離から保護する成分である。第1の選択的透過性コーティング12は抗化学薬品剤、抗生物剤、抗放射線剤及び/又は抗微生物剤物質を含んでおり、保護成分は単独で又は第1の選択的透過性コーティング12若しくは第2の選択的透過性コーティングの1つの成分である。
【選択図】図1
Description
(22) R3N+R0 nSiX4-nY-
ここで、各R及び各R0は独立に非加水分解性の有機基であり、各Xは独立に加水分解性の基であり、nは0〜3の整数であり、Y-は式Iの化合物の塩を形成するのに適したアニオン部分である。Y-は幾つかの実施形態ではハロゲン化物であり得る。幾つかの実施形態では、2つのRがメチルであり得、1つのRがオクタデシルであり得る。一実施形態では、R0はプロペニルであり、各Xはメトキシであり得、nは1であり得、Yは塩化物であり得る。式22の1つの代表的なケイ素含有第四アンモニウムモノマーは3−(トリメトキシシリル)プロピルジメチルオクタデシルアンモニウムクロリドである。
(23) R3N+R0 nSiX1 4-nY-
ここで、各R及び各R0は独立に、限定されることはないが1〜約22個の炭素原子のアルキル基又はアリール基、例えばフェニルのような非加水分解性の有機基であり、各X1は−OR1、−OH又は−O−Siであり、ここでR1は1〜約22個の炭素原子のアルキル基又は6個の炭素原子のアリール基であり、nは0〜3の整数であり、Yは式(23)の繰返し単位の塩を形成するのに適したアニオン部分、例えばハロゲン化物、ヒドロキシル、アセテート、SO4 -2、CO3 -2及びPO4 -2対イオンである。幾つかの実施形態では、Yはハロゲン化物である。幾つかの実施形態では、R基は各々独立にメチル、エチル、プロピル、ブチル、オクチル、ドデシル、テトラデシル又はオクタデシルであり、R0基は各々独立にメチレニル、エチレニル、プロピレニル、ブチレニル、オクチレニル、ドデシレニル、テトラデシレニル又はオクタデシレニルであり、各X1は−OR1であり、ここでR1はメチル、エチル、プロピル又はブチルである。
(24) (R1)3SiR2N+(R3)(R4)(R5)Y-
(25) (R1)3SiR2N(R3)(R4)
ここで、各R1は独立にハロゲン又はR6Oであり、R6はH、1〜約22個の炭素原子のアルキル、アセチル、アセトキシ、アシル、プロピレングリコール、エチレングリコール、ポリエチレングリコール、ポリプロピレングリコール、エチレン及びプロピレングリコール、プロピレングリコール、エチレングリコール、ポリエチレングリコール、ポリプロピレングリコールの1〜約22個の炭素原子のアルキルモノエーテルのブロックポリマー又はコポリマー、エチレン及びプロピレングリコール又は1〜約22個の炭素原子の炭酸のモノエステル及びプロピレングリコール、エチレングリコール、ポリエチレングリコール、ポリプロピレングリコールのブロックポリマー又はコポリマー、エチレン及びプロピレングリコールのブロックポリマー又はコポリマー、オクチルフェノール、ノニルフェノール又はソルビタンエーテルであり、
R2はベンジル、ビニル又は1〜約22個の炭素原子のアルキルであり、
R3及びR4は、独立に、1〜約6個の炭素原子の低級アルキルアルコール、1〜約6個の炭素原子の低級アルコキシ、1〜約22個の炭素原子のアルキルであるか又はR3及びR4は一緒になってモルホリン又は式(26)の
can、togエーテル form a 環式又は複素環式で不飽和又は飽和の5〜7員環を形成することができ、
(26) −R3−(R7)k−R4−
ここで、kは0〜2の整数であり、
また、環が飽和である場合、R7はCH2、O、S、NH、NH2 +、NCH2CH2NH2、NCH2CH2NH3 +、NCH2CH2N(R8)(R9)、NCH2CH2N+(R8)(R9)(R10)、N(アルキル)、N(アリール)、N(ベンジル)であり、各R8、R9及びR10は、独立に、ベンジル、ポリエーテル、1〜4個の炭素原子の低級アルキルアルコール、1〜4個の炭素原子の低級アルコキシ又は1〜約22個の炭素原子のアルキルであり、環が不飽和である場合、R7はCH、N、N+H、N+(アルキル)、N+(アリール)、N+(ベンジル)、NCH2N、N+HCH2N、N+(アルキル)CH2N、N+(アリール)CH2N又はN+(ベンジル)CH2Nであり、
環は置換されてないか又は1〜22個の炭素原子のアルキル、エステル、アルデヒド、カルボキシレート、アミド、チオ−アミド、ニトロ、アミン又はハロゲン化物で置換されており、
R5は1〜6個の炭素原子の低級アルキルアルコール、CH2C6H5、ポリエーテル、アルキル、アルコキシ、ペルフルオロアルキル、ペルフルオロアルキルスルホネート又はペルフルオロアルキルカルボキシレートであり、ここでアルキル アルコキシ、ペルフルオロアルキル、ペルフルオロアルキルスルホネート又はペルフルオロアルキルカルボキシレートは1〜約22個の炭素原子であるか又は上記式Vの5〜7員環であり、
Y-は式(24)又は(25)の化合物の塩を形成するのに適したアニオン部分であり、好ましくは、塩化物、臭化物又はヨウ化物である。
Claims (10)
- 多孔質膜、
前記膜に支持されており、有効量の抗化学薬品剤、抗生物剤、抗放射線剤及び/又は抗微生物剤物質を含む第1の選択的透過性コーティング、並びに
多孔質膜及び/又はそこに設けられている他のあらゆるコーティングからの前記選択的透過性コーティングの層間剥離から保護する成分
を含んでなる物品。 - 前記成分が前記第1の選択的透過性コーティングの1つの成分からなる、請求項1記載の物品。
- 前記成分が第2の選択的透過性コーティングの1つの成分からなる、請求項1記載の物品。
- 前記第1の選択的透過性コーティングがさらに、化学剤、生物剤、放射線剤又は抗微生物剤物質に対して活性なポリマー成分を含んでいる、請求項1記載の物品。
- 前記ポリマー成分がヒドロキシアルキルで置換されたポリアルキレンイミンからなる、請求項4記載の物品。
- 請求項1記載の物品及び1以上の追加の膜を含んでなる積層体。
- 請求項6記載の積層体を含んでなる衣料品であって、前記衣料品が上着からなる、前記衣料品。
- 多孔質膜に、(i)有効量の抗化学薬品剤、抗生物剤、抗放射線剤及び/又は抗微生物剤物質を含む第1の選択的透過性コーティング及び(ii)前記多孔質膜及び/又はそこに設けられている他のあらゆるコーティングからの前記選択的透過性コーティングの層間剥離から保護する成分を適用することを含んでなる方法。
- 前記成分が前記選択的透過性コーティングの1つの成分でもある、請求項8記載の方法。
- 前記第1の選択的透過性コーティングがさらにポリマー成分を含んでおり、前記方法がさらに前記ポリマー成分を硬化させることを含む、請求項8記載の方法。
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Also Published As
Publication number | Publication date |
---|---|
KR20100113976A (ko) | 2010-10-22 |
EP2241440B1 (en) | 2013-05-29 |
CN101863155A (zh) | 2010-10-20 |
EP2241440A1 (en) | 2010-10-20 |
US20100077529A1 (en) | 2010-04-01 |
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