JP2010209328A - 乾燥用物質、その調製および使用 - Google Patents
乾燥用物質、その調製および使用 Download PDFInfo
- Publication number
- JP2010209328A JP2010209328A JP2010044619A JP2010044619A JP2010209328A JP 2010209328 A JP2010209328 A JP 2010209328A JP 2010044619 A JP2010044619 A JP 2010044619A JP 2010044619 A JP2010044619 A JP 2010044619A JP 2010209328 A JP2010209328 A JP 2010209328A
- Authority
- JP
- Japan
- Prior art keywords
- tube
- drying
- polymer
- polymer material
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000001035 drying Methods 0.000 title claims description 209
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000000126 substance Substances 0.000 title abstract description 31
- 229920000642 polymer Polymers 0.000 claims abstract description 138
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 136
- 238000005373 pervaporation Methods 0.000 claims abstract description 61
- 239000012530 fluid Substances 0.000 claims abstract description 48
- 150000001875 compounds Chemical class 0.000 claims abstract description 42
- 125000000542 sulfonic acid group Chemical group 0.000 claims abstract description 28
- 238000012545 processing Methods 0.000 claims abstract description 25
- 230000003213 activating effect Effects 0.000 claims abstract description 9
- 239000012528 membrane Substances 0.000 claims description 124
- 229920001577 copolymer Polymers 0.000 claims description 108
- 239000000463 material Substances 0.000 claims description 92
- 238000000034 method Methods 0.000 claims description 92
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 83
- 239000002861 polymer material Substances 0.000 claims description 78
- 230000008569 process Effects 0.000 claims description 64
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 61
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 53
- 239000004793 Polystyrene Substances 0.000 claims description 27
- 229920002223 polystyrene Polymers 0.000 claims description 22
- 238000006277 sulfonation reaction Methods 0.000 claims description 22
- 239000007788 liquid Substances 0.000 claims description 21
- 238000001704 evaporation Methods 0.000 claims description 18
- 230000008020 evaporation Effects 0.000 claims description 18
- 238000001125 extrusion Methods 0.000 claims description 17
- 230000004913 activation Effects 0.000 claims description 16
- 238000000465 moulding Methods 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 14
- 229920002313 fluoropolymer Polymers 0.000 claims description 13
- 238000010521 absorption reaction Methods 0.000 claims description 11
- 239000004811 fluoropolymer Substances 0.000 claims description 11
- 230000003014 reinforcing effect Effects 0.000 claims description 10
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 claims description 9
- 229920000578 graft copolymer Polymers 0.000 claims description 7
- 229920000098 polyolefin Polymers 0.000 claims description 5
- 150000003440 styrenes Chemical class 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- 229920001467 poly(styrenesulfonates) Polymers 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 21
- 239000000178 monomer Substances 0.000 description 70
- 229920000557 Nafion® Polymers 0.000 description 59
- 239000011148 porous material Substances 0.000 description 49
- 239000007789 gas Substances 0.000 description 39
- 239000000203 mixture Substances 0.000 description 37
- 239000000243 solution Substances 0.000 description 31
- 125000000129 anionic group Chemical group 0.000 description 25
- 125000002091 cationic group Chemical group 0.000 description 24
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 23
- 229910002091 carbon monoxide Inorganic materials 0.000 description 23
- 239000002131 composite material Substances 0.000 description 23
- 239000004695 Polyether sulfone Substances 0.000 description 22
- 229920006393 polyether sulfone Polymers 0.000 description 22
- 229920001519 homopolymer Polymers 0.000 description 20
- -1 H 2 O 2 Substances 0.000 description 17
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 16
- 238000007334 copolymerization reaction Methods 0.000 description 16
- 238000005470 impregnation Methods 0.000 description 16
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- 238000004458 analytical method Methods 0.000 description 13
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 12
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 12
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 12
- 238000004132 cross linking Methods 0.000 description 12
- 230000008859 change Effects 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000010408 film Substances 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 230000035515 penetration Effects 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 238000010586 diagram Methods 0.000 description 9
- 239000012510 hollow fiber Substances 0.000 description 9
- 150000002978 peroxides Chemical class 0.000 description 9
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 9
- 239000004926 polymethyl methacrylate Substances 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 8
- 239000001569 carbon dioxide Substances 0.000 description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 230000002209 hydrophobic effect Effects 0.000 description 8
- 239000003999 initiator Substances 0.000 description 8
- 238000005259 measurement Methods 0.000 description 8
- 230000035699 permeability Effects 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 230000018044 dehydration Effects 0.000 description 7
- 238000006297 dehydration reaction Methods 0.000 description 7
- 239000010410 layer Substances 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 150000001768 cations Chemical class 0.000 description 6
- 239000003431 cross linking reagent Substances 0.000 description 6
- 230000008570 general process Effects 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 6
- 239000007800 oxidant agent Substances 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 229920002492 poly(sulfone) Polymers 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000004800 polyvinyl chloride Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 150000003254 radicals Chemical class 0.000 description 6
- 238000005070 sampling Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 5
- 239000010813 municipal solid waste Substances 0.000 description 5
- 229920000915 polyvinyl chloride Polymers 0.000 description 5
- 239000010409 thin film Substances 0.000 description 5
- 238000000108 ultra-filtration Methods 0.000 description 5
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 101001102158 Homo sapiens Phosphatidylserine synthase 1 Proteins 0.000 description 4
- 239000002033 PVDF binder Substances 0.000 description 4
- 102100039298 Phosphatidylserine synthase 1 Human genes 0.000 description 4
- 229920012266 Poly(ether sulfone) PES Polymers 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 229960004592 isopropanol Drugs 0.000 description 4
- 238000012544 monitoring process Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 230000037361 pathway Effects 0.000 description 4
- 229920002959 polymer blend Polymers 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 239000012966 redox initiator Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 3
- RRZIJNVZMJUGTK-UHFFFAOYSA-N 1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene Chemical compound FC(F)=C(F)OC(F)=C(F)F RRZIJNVZMJUGTK-UHFFFAOYSA-N 0.000 description 3
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 3
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 229920006362 Teflon® Polymers 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 150000008064 anhydrides Chemical class 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 3
- 235000013985 cinnamic acid Nutrition 0.000 description 3
- 229930016911 cinnamic acid Natural products 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 230000008595 infiltration Effects 0.000 description 3
- 238000001764 infiltration Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 3
- 239000012466 permeate Substances 0.000 description 3
- 229920002239 polyacrylonitrile Polymers 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 230000029058 respiratory gaseous exchange Effects 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- 239000011800 void material Substances 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- NCNYEGJDGNOYJX-NSCUHMNNSA-N (e)-2,3-dibromo-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Br)=C(/Br)C=O NCNYEGJDGNOYJX-NSCUHMNNSA-N 0.000 description 2
- PLPDHGOODMBBGN-VOTSOKGWSA-N (e)-4-oxo-4-phenylbut-2-enoic acid Chemical compound OC(=O)\C=C\C(=O)C1=CC=CC=C1 PLPDHGOODMBBGN-VOTSOKGWSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 2
- PMBXCGGQNSVESQ-UHFFFAOYSA-N 1-Hexanethiol Chemical compound CCCCCCS PMBXCGGQNSVESQ-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- YYPNJNDODFVZLE-UHFFFAOYSA-N 3-methylbut-2-enoic acid Chemical compound CC(C)=CC(O)=O YYPNJNDODFVZLE-UHFFFAOYSA-N 0.000 description 2
- WKRBKYFIJPGYQC-UHFFFAOYSA-N 3-methylglutaconic acid Chemical compound OC(=O)CC(C)=CC(O)=O WKRBKYFIJPGYQC-UHFFFAOYSA-N 0.000 description 2
- NGSWKAQJJWESNS-UHFFFAOYSA-N 4-coumaric acid Chemical compound OC(=O)C=CC1=CC=C(O)C=C1 NGSWKAQJJWESNS-UHFFFAOYSA-N 0.000 description 2
- HRXZRAXKKNUKRF-UHFFFAOYSA-N 4-ethylaniline Chemical compound CCC1=CC=C(N)C=C1 HRXZRAXKKNUKRF-UHFFFAOYSA-N 0.000 description 2
- PSCXFXNEYIHJST-UHFFFAOYSA-N 4-phenylbut-3-enoic acid Chemical compound OC(=O)CC=CC1=CC=CC=C1 PSCXFXNEYIHJST-UHFFFAOYSA-N 0.000 description 2
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- UIERETOOQGIECD-ARJAWSKDSA-N angelic acid Chemical compound C\C=C(\C)C(O)=O UIERETOOQGIECD-ARJAWSKDSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical compound C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical compound OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 2
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000012761 high-performance material Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229920001179 medium density polyethylene Polymers 0.000 description 2
- 239000004701 medium-density polyethylene Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- WUXWWSDWRUVSNE-UHFFFAOYSA-N methyl propane-1-sulfonate;prop-2-enamide Chemical compound NC(=O)C=C.CCCS(=O)(=O)OC WUXWWSDWRUVSNE-UHFFFAOYSA-N 0.000 description 2
- TXXHDPDFNKHHGW-UHFFFAOYSA-N muconic acid Chemical compound OC(=O)C=CC=CC(O)=O TXXHDPDFNKHHGW-UHFFFAOYSA-N 0.000 description 2
- IOXXVNYDGIXMIP-UHFFFAOYSA-N n-methylprop-2-en-1-amine Chemical compound CNCC=C IOXXVNYDGIXMIP-UHFFFAOYSA-N 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 230000002572 peristaltic effect Effects 0.000 description 2
- 229920000867 polyelectrolyte Polymers 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920005629 polypropylene homopolymer Polymers 0.000 description 2
- 229920005630 polypropylene random copolymer Polymers 0.000 description 2
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 210000002345 respiratory system Anatomy 0.000 description 2
- PCMORTLOPMLEFB-UHFFFAOYSA-N sinapic acid Chemical compound COC1=CC(C=CC(O)=O)=CC(OC)=C1O PCMORTLOPMLEFB-UHFFFAOYSA-N 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
- 150000003460 sulfonic acids Chemical class 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- HJUGFYREWKUQJT-UHFFFAOYSA-N tetrabromomethane Chemical compound BrC(Br)(Br)Br HJUGFYREWKUQJT-UHFFFAOYSA-N 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- UIERETOOQGIECD-ONEGZZNKSA-N tiglic acid Chemical compound C\C=C(/C)C(O)=O UIERETOOQGIECD-ONEGZZNKSA-N 0.000 description 2
- 230000036962 time dependent Effects 0.000 description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
- UAXOELSVPTZZQG-UHFFFAOYSA-N trimethyl acrylic acid Chemical compound CC(C)=C(C)C(O)=O UAXOELSVPTZZQG-UHFFFAOYSA-N 0.000 description 2
- AIUAMYPYEUQVEM-UHFFFAOYSA-N trimethyl(2-prop-2-enoyloxyethyl)azanium Chemical class C[N+](C)(C)CCOC(=O)C=C AIUAMYPYEUQVEM-UHFFFAOYSA-N 0.000 description 2
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical class [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- QHFAXRHEKNHTDH-UHFFFAOYSA-N (2-ethenylphenyl)boronic acid Chemical compound OB(O)C1=CC=CC=C1C=C QHFAXRHEKNHTDH-UHFFFAOYSA-N 0.000 description 1
- ZODNDDPVCIAZIQ-UHFFFAOYSA-N (2-hydroxy-3-prop-2-enoyloxypropyl) 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(O)COC(=O)C=C ZODNDDPVCIAZIQ-UHFFFAOYSA-N 0.000 description 1
- NIONDZDPPYHYKY-SNAWJCMRSA-N (2E)-hexenoic acid Chemical compound CCC\C=C\C(O)=O NIONDZDPPYHYKY-SNAWJCMRSA-N 0.000 description 1
- CWMPPVPFLSZGCY-VOTSOKGWSA-N (2E)-oct-2-enoic acid Chemical compound CCCCC\C=C\C(O)=O CWMPPVPFLSZGCY-VOTSOKGWSA-N 0.000 description 1
- AFMZGMJNKXOLEM-JXMROGBWSA-N (2e)-3,7-dimethylocta-2,6-dien-1-amine Chemical compound CC(C)=CCC\C(C)=C\CN AFMZGMJNKXOLEM-JXMROGBWSA-N 0.000 description 1
- JMMVHMOAIMOMOF-UHFFFAOYSA-N (4-prop-2-enoyloxyphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=C(OC(=O)C=C)C=C1 JMMVHMOAIMOMOF-UHFFFAOYSA-N 0.000 description 1
- AMVYAIXPAGBXOM-AATRIKPKSA-N (E)-2-(trifluoromethyl)cinnamic acid Chemical compound OC(=O)\C=C\C1=CC=CC=C1C(F)(F)F AMVYAIXPAGBXOM-AATRIKPKSA-N 0.000 description 1
- 239000001373 (E)-2-methylpent-2-enoic acid Substances 0.000 description 1
- AFDXODALSZRGIH-QPJJXVBHSA-N (E)-3-(4-methoxyphenyl)prop-2-enoic acid Chemical compound COC1=CC=C(\C=C\C(O)=O)C=C1 AFDXODALSZRGIH-QPJJXVBHSA-N 0.000 description 1
- KSBWHDDGWSYETA-SNAWJCMRSA-N (E)-3-(trifluoromethyl)cinnamic acid Chemical compound OC(=O)\C=C\C1=CC=CC(C(F)(F)F)=C1 KSBWHDDGWSYETA-SNAWJCMRSA-N 0.000 description 1
- XVOUMQNXTGKGMA-OWOJBTEDSA-N (E)-glutaconic acid Chemical compound OC(=O)C\C=C\C(O)=O XVOUMQNXTGKGMA-OWOJBTEDSA-N 0.000 description 1
- 239000001602 (E)-hex-3-enoic acid Substances 0.000 description 1
- SDVVLIIVFBKBMG-ONEGZZNKSA-N (E)-penta-2,4-dienoic acid Chemical compound OC(=O)\C=C\C=C SDVVLIIVFBKBMG-ONEGZZNKSA-N 0.000 description 1
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
- YQGLILFFFRYHAW-UTCJRWHESA-N (Z)-2-acetyl-3-hydroxy-5-oxohex-3-enoic acid Chemical compound CC(=O)\C=C(/O)C(C(C)=O)C(O)=O YQGLILFFFRYHAW-UTCJRWHESA-N 0.000 description 1
- XODAOBAZOQSFDS-JXMROGBWSA-N (e)-2-acetamido-3-phenylprop-2-enoic acid Chemical compound CC(=O)N\C(C(O)=O)=C\C1=CC=CC=C1 XODAOBAZOQSFDS-JXMROGBWSA-N 0.000 description 1
- SOWPGKJPEXNMCS-OWOJBTEDSA-N (e)-2-bromobut-2-enedioic acid Chemical compound OC(=O)\C=C(\Br)C(O)=O SOWPGKJPEXNMCS-OWOJBTEDSA-N 0.000 description 1
- ZQHJVIHCDHJVII-OWOJBTEDSA-N (e)-2-chlorobut-2-enedioic acid Chemical compound OC(=O)\C=C(\Cl)C(O)=O ZQHJVIHCDHJVII-OWOJBTEDSA-N 0.000 description 1
- WMDBQMYVAIBBDH-NSCUHMNNSA-N (e)-2-chlorobut-2-enoic acid Chemical compound C\C=C(\Cl)C(O)=O WMDBQMYVAIBBDH-NSCUHMNNSA-N 0.000 description 1
- KFSQJVOLYQRELE-HWKANZROSA-N (e)-2-ethylbut-2-enoic acid Chemical compound CC\C(=C/C)C(O)=O KFSQJVOLYQRELE-HWKANZROSA-N 0.000 description 1
- WOWYPHJOHOCYII-VOTSOKGWSA-N (e)-2-ethylhex-2-enoic acid Chemical compound CCC\C=C(/CC)C(O)=O WOWYPHJOHOCYII-VOTSOKGWSA-N 0.000 description 1
- DMXDUJPYGUWROU-FNORWQNLSA-N (e)-2-methyl-3-(3-nitrophenyl)prop-2-enoic acid Chemical compound OC(=O)C(/C)=C/C1=CC=CC([N+]([O-])=O)=C1 DMXDUJPYGUWROU-FNORWQNLSA-N 0.000 description 1
- AWWVCUPVXCDDHS-VOTSOKGWSA-N (e)-2-methyl-3-(4-nitrophenyl)prop-2-enoic acid Chemical compound OC(=O)C(/C)=C/C1=CC=C([N+]([O-])=O)C=C1 AWWVCUPVXCDDHS-VOTSOKGWSA-N 0.000 description 1
- XNCRUNXWPDJHGV-BQYQJAHWSA-N (e)-2-methyl-3-phenylprop-2-enoic acid Chemical compound OC(=O)C(/C)=C/C1=CC=CC=C1 XNCRUNXWPDJHGV-BQYQJAHWSA-N 0.000 description 1
- UBJNPHAYKBNFOC-XNWCZRBMSA-N (e)-2-phenylbut-2-enoic acid Chemical compound C\C=C(\C(O)=O)C1=CC=CC=C1 UBJNPHAYKBNFOC-XNWCZRBMSA-N 0.000 description 1
- IUUKDBLGVZISGW-OWOJBTEDSA-N (e)-3-(2,3,4,5,6-pentafluorophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=C(F)C(F)=C(F)C(F)=C1F IUUKDBLGVZISGW-OWOJBTEDSA-N 0.000 description 1
- VNQFOGSHTGKBDN-SNAWJCMRSA-N (e)-3-(2,4,6-trimethylphenyl)prop-2-enoic acid Chemical compound CC1=CC(C)=C(\C=C\C(O)=O)C(C)=C1 VNQFOGSHTGKBDN-SNAWJCMRSA-N 0.000 description 1
- MEBWABJHRAYGFW-DUXPYHPUSA-N (e)-3-(2,4-dichlorophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC=C(Cl)C=C1Cl MEBWABJHRAYGFW-DUXPYHPUSA-N 0.000 description 1
- PQDXPFJQTKGTFP-DUXPYHPUSA-N (e)-3-(2,4-difluorophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC=C(F)C=C1F PQDXPFJQTKGTFP-DUXPYHPUSA-N 0.000 description 1
- YIKHDPHTFYWYJV-GQCTYLIASA-N (e)-3-(2,4-dimethoxyphenyl)prop-2-enoic acid Chemical compound COC1=CC=C(\C=C\C(O)=O)C(OC)=C1 YIKHDPHTFYWYJV-GQCTYLIASA-N 0.000 description 1
- XAWHCSKPALFWBI-DAFODLJHSA-N (e)-3-(2,5-difluorophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC(F)=CC=C1F XAWHCSKPALFWBI-DAFODLJHSA-N 0.000 description 1
- JMUOYANNVIFGFN-SNAWJCMRSA-N (e)-3-(2,6-difluorophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=C(F)C=CC=C1F JMUOYANNVIFGFN-SNAWJCMRSA-N 0.000 description 1
- OMHDOOAFLCMRFX-AATRIKPKSA-N (e)-3-(2-bromophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC=CC=C1Br OMHDOOAFLCMRFX-AATRIKPKSA-N 0.000 description 1
- NDWALECYVLNBQG-SNAWJCMRSA-N (e)-3-(2-chloro-6-fluorophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=C(F)C=CC=C1Cl NDWALECYVLNBQG-SNAWJCMRSA-N 0.000 description 1
- KJRRTHHNKJBVBO-AATRIKPKSA-N (e)-3-(2-chlorophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC=CC=C1Cl KJRRTHHNKJBVBO-AATRIKPKSA-N 0.000 description 1
- IOUDZAFBPDDAMK-AATRIKPKSA-N (e)-3-(2-fluorophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC=CC=C1F IOUDZAFBPDDAMK-AATRIKPKSA-N 0.000 description 1
- PHIWFMZBVZFEQJ-OWOJBTEDSA-N (e)-3-(3,4,5-trifluorophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC(F)=C(F)C(F)=C1 PHIWFMZBVZFEQJ-OWOJBTEDSA-N 0.000 description 1
- RRLUFPHCTSFKNR-DUXPYHPUSA-N (e)-3-(3,4-dichlorophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC=C(Cl)C(Cl)=C1 RRLUFPHCTSFKNR-DUXPYHPUSA-N 0.000 description 1
- MBAWRXICVNIUGY-OWOJBTEDSA-N (e)-3-(3,5-difluorophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC(F)=CC(F)=C1 MBAWRXICVNIUGY-OWOJBTEDSA-N 0.000 description 1
- VLSRUFWCGBMYDJ-ONEGZZNKSA-N (e)-3-(3,5-dimethoxyphenyl)prop-2-enoic acid Chemical compound COC1=CC(OC)=CC(\C=C\C(O)=O)=C1 VLSRUFWCGBMYDJ-ONEGZZNKSA-N 0.000 description 1
- YEMUSDCFQUBPAL-SNAWJCMRSA-N (e)-3-(3-bromophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC=CC(Br)=C1 YEMUSDCFQUBPAL-SNAWJCMRSA-N 0.000 description 1
- RTSIUKMGSDOSTI-SNAWJCMRSA-N (e)-3-(3-fluorophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC=CC(F)=C1 RTSIUKMGSDOSTI-SNAWJCMRSA-N 0.000 description 1
- LBOUHDMYVURTMA-AATRIKPKSA-N (e)-3-(4-formylphenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC=C(C=O)C=C1 LBOUHDMYVURTMA-AATRIKPKSA-N 0.000 description 1
- SJDOOXOUSJDYFE-VMPITWQZSA-N (e)-3-(4-propan-2-ylphenyl)prop-2-enoic acid Chemical compound CC(C)C1=CC=C(\C=C\C(O)=O)C=C1 SJDOOXOUSJDYFE-VMPITWQZSA-N 0.000 description 1
- ROTBALNVXDGIQY-DAFODLJHSA-N (e)-3-(5-bromo-2-fluorophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC(Br)=CC=C1F ROTBALNVXDGIQY-DAFODLJHSA-N 0.000 description 1
- ZCJLOOJRNPHKAV-ONEGZZNKSA-N (e)-3-(furan-2-yl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC=CO1 ZCJLOOJRNPHKAV-ONEGZZNKSA-N 0.000 description 1
- CQNPVMCASGWEHM-VMPITWQZSA-N (e)-3-[4-(dimethylamino)phenyl]prop-2-enoic acid Chemical compound CN(C)C1=CC=C(\C=C\C(O)=O)C=C1 CQNPVMCASGWEHM-VMPITWQZSA-N 0.000 description 1
- VUVORVXMOLQFMO-ONEGZZNKSA-N (e)-3-pyridin-3-ylprop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC=CN=C1 VUVORVXMOLQFMO-ONEGZZNKSA-N 0.000 description 1
- QRRCTLYMABZQCS-NSCUHMNNSA-N (e)-4,4,4-trifluoro-3-methylbut-2-enoic acid Chemical compound FC(F)(F)C(/C)=C/C(O)=O QRRCTLYMABZQCS-NSCUHMNNSA-N 0.000 description 1
- VQVQEUFKSRHRCT-AATRIKPKSA-N (e)-4-(4-chlorophenyl)-4-oxobut-2-enoic acid Chemical compound OC(=O)\C=C\C(=O)C1=CC=C(Cl)C=C1 VQVQEUFKSRHRCT-AATRIKPKSA-N 0.000 description 1
- YANJKPZKTWMMOF-NSCUHMNNSA-N (e)-4-hydroxypent-2-enoic acid Chemical compound CC(O)\C=C\C(O)=O YANJKPZKTWMMOF-NSCUHMNNSA-N 0.000 description 1
- JLIDBLDQVAYHNE-IBPUIESWSA-N (s)-(+)-Abscisic acid Natural products OC(=O)\C=C(/C)\C=C\[C@@]1(O)C(C)=CC(=O)CC1(C)C JLIDBLDQVAYHNE-IBPUIESWSA-N 0.000 description 1
- PMNMPRXRQYSFRP-UPHRSURJSA-N (z)-2,3-dibromobut-2-enedioic acid Chemical compound OC(=O)C(\Br)=C(\Br)C(O)=O PMNMPRXRQYSFRP-UPHRSURJSA-N 0.000 description 1
- LUMLZKVIXLWTCI-IHWYPQMZSA-N (z)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(\Cl)C=O LUMLZKVIXLWTCI-IHWYPQMZSA-N 0.000 description 1
- YQYHCJZVJNOGBP-UPHRSURJSA-N (z)-2,3-dichloroprop-2-enoic acid Chemical compound OC(=O)C(\Cl)=C\Cl YQYHCJZVJNOGBP-UPHRSURJSA-N 0.000 description 1
- BZCOSCNPHJNQBP-UPHRSURJSA-N (z)-2,3-dihydroxybut-2-enedioic acid Chemical compound OC(=O)C(\O)=C(\O)C(O)=O BZCOSCNPHJNQBP-UPHRSURJSA-N 0.000 description 1
- HBMGEXMZDMAEDN-VURMDHGXSA-N (z)-2-bromo-3-phenylprop-2-enoic acid Chemical compound OC(=O)C(\Br)=C\C1=CC=CC=C1 HBMGEXMZDMAEDN-VURMDHGXSA-N 0.000 description 1
- SOWPGKJPEXNMCS-UPHRSURJSA-N (z)-2-bromobut-2-enedioic acid Chemical compound OC(=O)\C=C(/Br)C(O)=O SOWPGKJPEXNMCS-UPHRSURJSA-N 0.000 description 1
- ZQHJVIHCDHJVII-UPHRSURJSA-N (z)-2-chlorobut-2-enedioic acid Chemical compound OC(=O)\C=C(/Cl)C(O)=O ZQHJVIHCDHJVII-UPHRSURJSA-N 0.000 description 1
- JFQJADVATLPJRF-IHWYPQMZSA-N (z)-3-bromobut-2-enoic acid Chemical compound C\C(Br)=C\C(O)=O JFQJADVATLPJRF-IHWYPQMZSA-N 0.000 description 1
- FZBYZQPNENFBLV-RQOWECAXSA-N (z)-4-hydroxypent-3-enoic acid Chemical compound C\C(O)=C\CC(O)=O FZBYZQPNENFBLV-RQOWECAXSA-N 0.000 description 1
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
- CYIGRWUIQAVBFG-UHFFFAOYSA-N 1,2-bis(2-ethenoxyethoxy)ethane Chemical compound C=COCCOCCOCCOC=C CYIGRWUIQAVBFG-UHFFFAOYSA-N 0.000 description 1
- VDYWHVQKENANGY-UHFFFAOYSA-N 1,3-Butyleneglycol dimethacrylate Chemical compound CC(=C)C(=O)OC(C)CCOC(=O)C(C)=C VDYWHVQKENANGY-UHFFFAOYSA-N 0.000 description 1
- QRWVOJLTHSRPOA-UHFFFAOYSA-N 1,3-bis(prop-2-enyl)urea Chemical compound C=CCNC(=O)NCC=C QRWVOJLTHSRPOA-UHFFFAOYSA-N 0.000 description 1
- YERHJBPPDGHCRJ-UHFFFAOYSA-N 1-[4-(1-oxoprop-2-enyl)-1-piperazinyl]-2-propen-1-one Chemical compound C=CC(=O)N1CCN(C(=O)C=C)CC1 YERHJBPPDGHCRJ-UHFFFAOYSA-N 0.000 description 1
- PYWLBQPICCQJFF-UHFFFAOYSA-N 1-[5-(aminomethyl)-4-hydroxyoxolan-2-yl]-5-methylpyrimidine-2,4-dione Chemical compound O=C1NC(=O)C(C)=CN1C1OC(CN)C(O)C1 PYWLBQPICCQJFF-UHFFFAOYSA-N 0.000 description 1
- KFQPRNVTVMCYEH-UHFFFAOYSA-N 1-amino-3-(4-methoxyphenoxy)propan-2-ol Chemical compound COC1=CC=C(OCC(O)CN)C=C1 KFQPRNVTVMCYEH-UHFFFAOYSA-N 0.000 description 1
- VEEPGIBHWRABJA-UHFFFAOYSA-N 1-benzyl-3,5-dimethylpyrazol-4-amine Chemical compound CC1=C(N)C(C)=NN1CC1=CC=CC=C1 VEEPGIBHWRABJA-UHFFFAOYSA-N 0.000 description 1
- SAMJGBVVQUEMGC-UHFFFAOYSA-N 1-ethenoxy-2-(2-ethenoxyethoxy)ethane Chemical compound C=COCCOCCOC=C SAMJGBVVQUEMGC-UHFFFAOYSA-N 0.000 description 1
- WDRZVZVXHZNSFG-UHFFFAOYSA-N 1-ethenylpyridin-1-ium Chemical class C=C[N+]1=CC=CC=C1 WDRZVZVXHZNSFG-UHFFFAOYSA-N 0.000 description 1
- GDKOYYDQISQOMH-UHFFFAOYSA-N 1-ethynylcyclohexan-1-amine Chemical compound C#CC1(N)CCCCC1 GDKOYYDQISQOMH-UHFFFAOYSA-N 0.000 description 1
- LRZPQLZONWIQOJ-UHFFFAOYSA-N 10-(2-methylprop-2-enoyloxy)decyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCCCCCOC(=O)C(C)=C LRZPQLZONWIQOJ-UHFFFAOYSA-N 0.000 description 1
- BDKDHWOPFRTWPP-UHFFFAOYSA-N 2,2-bis(prop-2-enoxymethyl)butan-1-ol Chemical compound C=CCOCC(CO)(CC)COCC=C BDKDHWOPFRTWPP-UHFFFAOYSA-N 0.000 description 1
- WMUBNWIGNSIRDH-UHFFFAOYSA-N 2,3,3-trichloroprop-2-enoic acid Chemical compound OC(=O)C(Cl)=C(Cl)Cl WMUBNWIGNSIRDH-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- JPQWWJZORKTMIZ-ZZXKWVIFSA-N 2,5-Dimethoxycinnamic acid Chemical compound COC1=CC=C(OC)C(\C=C\C(O)=O)=C1 JPQWWJZORKTMIZ-ZZXKWVIFSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- PRAMZQXXPOLCIY-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethanesulfonic acid Chemical compound CC(=C)C(=O)OCCS(O)(=O)=O PRAMZQXXPOLCIY-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- VLSRKCIBHNJFHA-UHFFFAOYSA-N 2-(trifluoromethyl)prop-2-enoic acid Chemical compound OC(=O)C(=C)C(F)(F)F VLSRKCIBHNJFHA-UHFFFAOYSA-N 0.000 description 1
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 1
- UIERETOOQGIECD-ARJAWSKDSA-M 2-Methyl-2-butenoic acid Natural products C\C=C(\C)C([O-])=O UIERETOOQGIECD-ARJAWSKDSA-M 0.000 description 1
- JJYWRQLLQAKNAD-UHFFFAOYSA-N 2-Methyl-2-pentenoic acid Natural products CCC=C(C)C(O)=O JJYWRQLLQAKNAD-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- CWMPPVPFLSZGCY-UHFFFAOYSA-N 2-Octenoic Acid Natural products CCCCCC=CC(O)=O CWMPPVPFLSZGCY-UHFFFAOYSA-N 0.000 description 1
- SCWPNMHQRGNQHH-AATRIKPKSA-N 2-[(e)-2-carboxyethenyl]benzoic acid Chemical compound OC(=O)\C=C\C1=CC=CC=C1C(O)=O SCWPNMHQRGNQHH-AATRIKPKSA-N 0.000 description 1
- JFZBUNLOTDDXNY-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)propoxy]propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(C)OCC(C)OC(=O)C(C)=C JFZBUNLOTDDXNY-UHFFFAOYSA-N 0.000 description 1
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 1
- LTHJXDSHSVNJKG-UHFFFAOYSA-N 2-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOCCOC(=O)C(C)=C LTHJXDSHSVNJKG-UHFFFAOYSA-N 0.000 description 1
- NXBXJOWBDCQIHF-UHFFFAOYSA-N 2-[hydroxy-[2-(2-methylprop-2-enoyloxy)ethoxy]phosphoryl]oxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOP(O)(=O)OCCOC(=O)C(C)=C NXBXJOWBDCQIHF-UHFFFAOYSA-N 0.000 description 1
- UFDFFEMHDKXMBG-UHFFFAOYSA-N 2-acetamidoprop-2-enoic acid Chemical compound CC(=O)NC(=C)C(O)=O UFDFFEMHDKXMBG-UHFFFAOYSA-N 0.000 description 1
- BOBATFKNMFWLFG-UHFFFAOYSA-N 2-amino-2-cyano-n-methylacetamide Chemical compound CNC(=O)C(N)C#N BOBATFKNMFWLFG-UHFFFAOYSA-N 0.000 description 1
- XSHISXQEKIKSGC-UHFFFAOYSA-N 2-aminoethyl 2-methylprop-2-enoate;hydron;chloride Chemical compound Cl.CC(=C)C(=O)OCCN XSHISXQEKIKSGC-UHFFFAOYSA-N 0.000 description 1
- FLYIRERUSAMCDQ-UHFFFAOYSA-N 2-azaniumyl-2-(2-methylphenyl)acetate Chemical compound CC1=CC=CC=C1C(N)C(O)=O FLYIRERUSAMCDQ-UHFFFAOYSA-N 0.000 description 1
- HMENQNSSJFLQOP-UHFFFAOYSA-N 2-bromoprop-2-enoic acid Chemical compound OC(=O)C(Br)=C HMENQNSSJFLQOP-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- TYHGMXVAEPEGRT-UHFFFAOYSA-N 2-fluoro-3-iodo-6-methylpyridine Chemical compound CC1=CC=C(I)C(F)=N1 TYHGMXVAEPEGRT-UHFFFAOYSA-N 0.000 description 1
- ZGGWKQRHPWUSNY-UHFFFAOYSA-N 2-hydroxy-4-phenylbut-3-enoic acid Chemical compound OC(=O)C(O)C=CC1=CC=CC=C1 ZGGWKQRHPWUSNY-UHFFFAOYSA-N 0.000 description 1
- FEGVSPGUHMGGBO-UHFFFAOYSA-N 2-methoxy cinnamic acid Natural products COC1=CC=CC=C1C=CC(O)=O FEGVSPGUHMGGBO-UHFFFAOYSA-N 0.000 description 1
- OPRIWFSSXKQMPB-UHFFFAOYSA-N 2-methyl-2-(prop-2-enoylamino)propane-1-sulfonic acid;sodium Chemical group [Na].OS(=O)(=O)CC(C)(C)NC(=O)C=C OPRIWFSSXKQMPB-UHFFFAOYSA-N 0.000 description 1
- JJYWRQLLQAKNAD-PLNGDYQASA-N 2-methyl-2-pentenoic acid Chemical compound CC\C=C(\C)C(O)=O JJYWRQLLQAKNAD-PLNGDYQASA-N 0.000 description 1
- BMDISKTZXDELHS-UHFFFAOYSA-N 2-methyl-n-(2-methylbut-3-en-2-yl)butan-2-amine Chemical compound CCC(C)(C)NC(C)(C)C=C BMDISKTZXDELHS-UHFFFAOYSA-N 0.000 description 1
- QZIVTSHQTWUMNU-UHFFFAOYSA-N 2-methyl-n-(2-methylbut-3-yn-2-yl)butan-2-amine Chemical compound CCC(C)(C)NC(C)(C)C#C QZIVTSHQTWUMNU-UHFFFAOYSA-N 0.000 description 1
- TURITJIWSQEMDB-UHFFFAOYSA-N 2-methyl-n-[(2-methylprop-2-enoylamino)methyl]prop-2-enamide Chemical compound CC(=C)C(=O)NCNC(=O)C(C)=C TURITJIWSQEMDB-UHFFFAOYSA-N 0.000 description 1
- XEEYSDHEOQHCDA-UHFFFAOYSA-N 2-methylprop-2-ene-1-sulfonic acid Chemical compound CC(=C)CS(O)(=O)=O XEEYSDHEOQHCDA-UHFFFAOYSA-N 0.000 description 1
- BBQDLDVSEDAYAA-AATRIKPKSA-N 2-nitrocinnamic acid Chemical compound OC(=O)\C=C\C1=CC=CC=C1[N+]([O-])=O BBQDLDVSEDAYAA-AATRIKPKSA-N 0.000 description 1
- ONPJWQSDZCGSQM-UHFFFAOYSA-N 2-phenylprop-2-enoic acid Chemical compound OC(=O)C(=C)C1=CC=CC=C1 ONPJWQSDZCGSQM-UHFFFAOYSA-N 0.000 description 1
- UDXXYUDJOHIIDZ-UHFFFAOYSA-N 2-phosphonooxyethyl prop-2-enoate Chemical compound OP(O)(=O)OCCOC(=O)C=C UDXXYUDJOHIIDZ-UHFFFAOYSA-N 0.000 description 1
- WWFHNTLFRMYXKQ-CMDGGOBGSA-N 2-prop-2-enoyloxyethyl (e)-3-phenylprop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)\C=C\C1=CC=CC=C1 WWFHNTLFRMYXKQ-CMDGGOBGSA-N 0.000 description 1
- HYODZVPUCNBWNY-UHFFFAOYSA-N 3,3-dichloroacrylic acid Chemical compound OC(=O)C=C(Cl)Cl HYODZVPUCNBWNY-UHFFFAOYSA-N 0.000 description 1
- YTFVRYKNXDADBI-SNAWJCMRSA-N 3,4,5-trimethoxycinnamic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC(OC)=C1OC YTFVRYKNXDADBI-SNAWJCMRSA-N 0.000 description 1
- HJBWJAPEBGSQPR-GQCTYLIASA-N 3,4-dimethoxycinnamic acid Chemical compound COC1=CC=C(\C=C\C(O)=O)C=C1OC HJBWJAPEBGSQPR-GQCTYLIASA-N 0.000 description 1
- SCJHPUGWYHCYAZ-UHFFFAOYSA-N 3,5-diethyl-2-propylpyridine Chemical compound CCCC1=NC=C(CC)C=C1CC SCJHPUGWYHCYAZ-UHFFFAOYSA-N 0.000 description 1
- QAXPUWGAGVERSJ-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enoic acid Chemical compound COC1=CC=CC(C=CC(O)=O)=C1OC QAXPUWGAGVERSJ-UHFFFAOYSA-N 0.000 description 1
- FFKGOJWPSXRALK-UHFFFAOYSA-N 3-(3-chlorophenyl)prop-2-enoic acid Chemical compound OC(=O)C=CC1=CC=CC(Cl)=C1 FFKGOJWPSXRALK-UHFFFAOYSA-N 0.000 description 1
- BZIRMMAJZSOLEW-ONEGZZNKSA-N 3-(4,5-dimethoxy-2-nitrophenyl)acrylic acid Chemical compound COC1=CC(\C=C\C(O)=O)=C([N+]([O-])=O)C=C1OC BZIRMMAJZSOLEW-ONEGZZNKSA-N 0.000 description 1
- SVJGKQYKYNDYMU-UHFFFAOYSA-N 3-(4-bromo-2-fluorophenyl)prop-2-enoic acid Chemical compound OC(=O)C=CC1=CC=C(Br)C=C1F SVJGKQYKYNDYMU-UHFFFAOYSA-N 0.000 description 1
- BDDPVHVBYYSHBM-UHFFFAOYSA-N 3-(4-methyl-3-nitrophenyl)prop-2-enoic acid Chemical compound CC1=CC=C(C=CC(O)=O)C=C1[N+]([O-])=O BDDPVHVBYYSHBM-UHFFFAOYSA-N 0.000 description 1
- VFQOFJQVKVEXIY-UHFFFAOYSA-N 3-(phenylmethoxycarbonylamino)-3-piperidin-3-ylpropanoic acid Chemical compound C1CCNCC1C(CC(=O)O)NC(=O)OCC1=CC=CC=C1 VFQOFJQVKVEXIY-UHFFFAOYSA-N 0.000 description 1
- LZPNXAULYJPXEH-AATRIKPKSA-N 3-Methoxycinnamic acid Chemical compound COC1=CC=CC(\C=C\C(O)=O)=C1 LZPNXAULYJPXEH-AATRIKPKSA-N 0.000 description 1
- OIETYYKGJGVJFT-UHFFFAOYSA-N 3-[dimethyl-[3-(2-methylprop-2-enoylamino)propyl]azaniumyl]propane-1-sulfonate Chemical compound CC(=C)C(=O)NCCC[N+](C)(C)CCCS([O-])(=O)=O OIETYYKGJGVJFT-UHFFFAOYSA-N 0.000 description 1
- WOZHZOLFFPSEAM-UHFFFAOYSA-N 3-butene-1,2,3-tricarboxylic acid Chemical compound OC(=O)CC(C(O)=O)C(=C)C(O)=O WOZHZOLFFPSEAM-UHFFFAOYSA-N 0.000 description 1
- VWXZFDWVWMQRQR-UHFFFAOYSA-N 3-ethenylbenzoic acid Chemical compound OC(=O)C1=CC=CC(C=C)=C1 VWXZFDWVWMQRQR-UHFFFAOYSA-N 0.000 description 1
- WHNOKDNCUNZBLW-UHFFFAOYSA-N 3-ethylpent-1-yn-3-amine Chemical compound CCC(N)(CC)C#C WHNOKDNCUNZBLW-UHFFFAOYSA-N 0.000 description 1
- NOJXPGXFDASWEI-UHFFFAOYSA-N 3-ethylsulfanylprop-1-ene Chemical compound CCSCC=C NOJXPGXFDASWEI-UHFFFAOYSA-N 0.000 description 1
- NNKQLUVBPJEUOR-UHFFFAOYSA-N 3-ethynylaniline Chemical compound NC1=CC=CC(C#C)=C1 NNKQLUVBPJEUOR-UHFFFAOYSA-N 0.000 description 1
- QNPZXLANENFTFK-UHFFFAOYSA-N 3-methyl-4-pentenoic acid Chemical compound C=CC(C)CC(O)=O QNPZXLANENFTFK-UHFFFAOYSA-N 0.000 description 1
- FYRWKWGEFZTOQI-UHFFFAOYSA-N 3-prop-2-enoxy-2,2-bis(prop-2-enoxymethyl)propan-1-ol Chemical compound C=CCOCC(CO)(COCC=C)COCC=C FYRWKWGEFZTOQI-UHFFFAOYSA-N 0.000 description 1
- NYUTUWAFOUJLKI-UHFFFAOYSA-N 3-prop-2-enoyloxypropane-1-sulfonic acid Chemical compound OS(=O)(=O)CCCOC(=O)C=C NYUTUWAFOUJLKI-UHFFFAOYSA-N 0.000 description 1
- NYYSPVRERVXMLJ-UHFFFAOYSA-N 4,4-difluorocyclohexan-1-one Chemical compound FC1(F)CCC(=O)CC1 NYYSPVRERVXMLJ-UHFFFAOYSA-N 0.000 description 1
- XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 description 1
- LBSXSAXOLABXMF-UHFFFAOYSA-N 4-Vinylaniline Chemical compound NC1=CC=C(C=C)C=C1 LBSXSAXOLABXMF-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- GXLIFJYFGMHYDY-ZZXKWVIFSA-N 4-chlorocinnamic acid Chemical compound OC(=O)\C=C\C1=CC=C(Cl)C=C1 GXLIFJYFGMHYDY-ZZXKWVIFSA-N 0.000 description 1
- IRQWEODKXLDORP-UHFFFAOYSA-N 4-ethenylbenzoic acid Chemical compound OC(=O)C1=CC=C(C=C)C=C1 IRQWEODKXLDORP-UHFFFAOYSA-N 0.000 description 1
- KFBZWZGIZHLUBX-UHFFFAOYSA-N 4-ethynylpyridine;hydrochloride Chemical compound Cl.C#CC1=CC=NC=C1 KFBZWZGIZHLUBX-UHFFFAOYSA-N 0.000 description 1
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 1
- OBZFLUDUSNCZKL-UHFFFAOYSA-N 5-aminocyclohexa-1,3-diene-1-carboxylic acid;hydron;chloride Chemical compound Cl.NC1CC(C(O)=O)=CC=C1 OBZFLUDUSNCZKL-UHFFFAOYSA-N 0.000 description 1
- NNWNNQTUZYVQRK-UHFFFAOYSA-N 5-bromo-1h-pyrrolo[2,3-c]pyridine-2-carboxylic acid Chemical compound BrC1=NC=C2NC(C(=O)O)=CC2=C1 NNWNNQTUZYVQRK-UHFFFAOYSA-N 0.000 description 1
- SAPGBCWOQLHKKZ-UHFFFAOYSA-N 6-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCOC(=O)C(C)=C SAPGBCWOQLHKKZ-UHFFFAOYSA-N 0.000 description 1
- OFCPMJGTZUVUSM-UHFFFAOYSA-N 6-heptynoic acid Chemical compound OC(=O)CCCCC#C OFCPMJGTZUVUSM-UHFFFAOYSA-N 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- RUZXDTHZHJTTRO-UHFFFAOYSA-N 7-amino-4h-1,4-benzoxazin-3-one Chemical compound N1C(=O)COC2=CC(N)=CC=C21 RUZXDTHZHJTTRO-UHFFFAOYSA-N 0.000 description 1
- YJVIKVWFGPLAFS-UHFFFAOYSA-N 9-(2-methylprop-2-enoyloxy)nonyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCCCCOC(=O)C(C)=C YJVIKVWFGPLAFS-UHFFFAOYSA-N 0.000 description 1
- ZDZVKPXKLLLOOA-UHFFFAOYSA-N Allylmalonic acid Chemical compound OC(=O)C(C(O)=O)CC=C ZDZVKPXKLLLOOA-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- XWUNIDGEMNBBAQ-UHFFFAOYSA-N Bisphenol A ethoxylate diacrylate Chemical compound C=1C=C(OCCOC(=O)C=C)C=CC=1C(C)(C)C1=CC=C(OCCOC(=O)C=C)C=C1 XWUNIDGEMNBBAQ-UHFFFAOYSA-N 0.000 description 1
- NRUZLEQIXBELPG-UHFFFAOYSA-N BrC=1C=C(C=CC(=O)O)C=CC1F.BrC1=CC=C(C=CC(=O)O)C=C1 Chemical compound BrC=1C=C(C=CC(=O)O)C=CC1F.BrC1=CC=C(C=CC(=O)O)C=C1 NRUZLEQIXBELPG-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- RSMOFLNOAXSILF-UHFFFAOYSA-N C(C#C)(=O)O.C(CC)(=O)O Chemical compound C(C#C)(=O)O.C(CC)(=O)O RSMOFLNOAXSILF-UHFFFAOYSA-N 0.000 description 1
- OFIMLDVVRXOXSK-HAQNSBGRSA-N CC(=C)C(=O)O[C@H]1CC[C@@H](CC1)OC(=O)C(C)=C Chemical compound CC(=C)C(=O)O[C@H]1CC[C@@H](CC1)OC(=O)C(C)=C OFIMLDVVRXOXSK-HAQNSBGRSA-N 0.000 description 1
- SWBRTXAKRKRGPH-STWYSWDKSA-N CC=CC=CC(O)=O.C\C=C\C=C\C(O)=O Chemical compound CC=CC=CC(O)=O.C\C=C\C=C\C(O)=O SWBRTXAKRKRGPH-STWYSWDKSA-N 0.000 description 1
- 229920002574 CR-39 Polymers 0.000 description 1
- INSLSHNRSFOTLH-AVRNHWNZSA-N C\C(=C(/C(=O)O)\C)\C(=O)O.O\C(=C(/C(=O)O)\O)\C(=O)O Chemical compound C\C(=C(/C(=O)O)\C)\C(=O)O.O\C(=C(/C(=O)O)\O)\C(=O)O INSLSHNRSFOTLH-AVRNHWNZSA-N 0.000 description 1
- XXHDAWYDNSXJQM-UHFFFAOYSA-N Chloride-3-Hexenoic acid Natural products CCC=CCC(O)=O XXHDAWYDNSXJQM-UHFFFAOYSA-N 0.000 description 1
- HJBWJAPEBGSQPR-UHFFFAOYSA-N DMCA Natural products COC1=CC=C(C=CC(O)=O)C=C1OC HJBWJAPEBGSQPR-UHFFFAOYSA-N 0.000 description 1
- 239000004287 Dehydroacetic acid Substances 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- CUDSBWGCGSUXDB-UHFFFAOYSA-N Dibutyl disulfide Chemical compound CCCCSSCCCC CUDSBWGCGSUXDB-UHFFFAOYSA-N 0.000 description 1
- CETBSQOFQKLHHZ-UHFFFAOYSA-N Diethyl disulfide Chemical compound CCSSCC CETBSQOFQKLHHZ-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical class CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- GUUVPOWQJOLRAS-UHFFFAOYSA-N Diphenyl disulfide Chemical compound C=1C=CC=CC=1SSC1=CC=CC=C1 GUUVPOWQJOLRAS-UHFFFAOYSA-N 0.000 description 1
- 229920002633 Kraton (polymer) Polymers 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- QFQYZMGOKIROEC-DUXPYHPUSA-N Methylenedioxycinnamic acid Chemical compound OC(=O)\C=C\C1=CC=C2OCOC2=C1 QFQYZMGOKIROEC-DUXPYHPUSA-N 0.000 description 1
- TXXHDPDFNKHHGW-CCAGOZQPSA-N Muconic acid Natural products OC(=O)\C=C/C=C\C(O)=O TXXHDPDFNKHHGW-CCAGOZQPSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- YTFVRYKNXDADBI-UHFFFAOYSA-N O-Methylsinapic acid Natural products COC1=CC(C=CC(O)=O)=CC(OC)=C1OC YTFVRYKNXDADBI-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- AMFGWXWBFGVCKG-UHFFFAOYSA-N Panavia opaque Chemical compound C1=CC(OCC(O)COC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OCC(O)COC(=O)C(C)=C)C=C1 AMFGWXWBFGVCKG-UHFFFAOYSA-N 0.000 description 1
- QFQYZMGOKIROEC-UHFFFAOYSA-N Piperonylideneacetic acid Natural products OC(=O)C=CC1=CC=C2OCOC2=C1 QFQYZMGOKIROEC-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 229920002359 Tetronic® Polymers 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- NIONDZDPPYHYKY-UHFFFAOYSA-N Z-hexenoic acid Natural products CCCC=CC(O)=O NIONDZDPPYHYKY-UHFFFAOYSA-N 0.000 description 1
- RBTAJLKAPFBZDQ-BQYQJAHWSA-N [(e)-oct-1-enyl]boronic acid Chemical compound CCCCCC\C=C\B(O)O RBTAJLKAPFBZDQ-BQYQJAHWSA-N 0.000 description 1
- ULQMPOIOSDXIGC-UHFFFAOYSA-N [2,2-dimethyl-3-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(C)(C)COC(=O)C(C)=C ULQMPOIOSDXIGC-UHFFFAOYSA-N 0.000 description 1
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
- AWWMYIFREIUBNZ-UHFFFAOYSA-N [4-[(dimethylamino)methyl]phenyl]-phenylmethanone Chemical class C1=CC(CN(C)C)=CC=C1C(=O)C1=CC=CC=C1 AWWMYIFREIUBNZ-UHFFFAOYSA-N 0.000 description 1
- SFRAURMUQMJLPG-ZIKNSQGESA-N [4-[(e)-2-carboxyethenyl]phenyl]azanium;chloride Chemical compound Cl.NC1=CC=C(\C=C\C(O)=O)C=C1 SFRAURMUQMJLPG-ZIKNSQGESA-N 0.000 description 1
- GSFXLBMRGCVEMO-UHFFFAOYSA-N [SiH4].[S] Chemical compound [SiH4].[S] GSFXLBMRGCVEMO-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229940091181 aconitic acid Drugs 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- YIYBQIKDCADOSF-UHFFFAOYSA-N alpha-Butylen-alpha-carbonsaeure Natural products CCC=CC(O)=O YIYBQIKDCADOSF-UHFFFAOYSA-N 0.000 description 1
- 229920005603 alternating copolymer Polymers 0.000 description 1
- 229910001579 aluminosilicate mineral Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 229940072049 amyl acetate Drugs 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- YVEJDOBFMBXLPV-UHFFFAOYSA-N benzyl-dimethyl-prop-2-enylazanium Chemical class C=CC[N+](C)(C)CC1=CC=CC=C1 YVEJDOBFMBXLPV-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 125000000319 biphenyl-4-yl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C1=C([H])C([H])=C([*])C([H])=C1[H] 0.000 description 1
- KVUDZUPUUSUAAJ-UHFFFAOYSA-N bis(chloromethyl) carbonate Chemical compound ClCOC(=O)OCCl KVUDZUPUUSUAAJ-UHFFFAOYSA-N 0.000 description 1
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- HABAXTXIECRCKH-UHFFFAOYSA-N bis(prop-2-enyl) butanedioate Chemical compound C=CCOC(=O)CCC(=O)OCC=C HABAXTXIECRCKH-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- VIAFSCDEGBWNKN-UHFFFAOYSA-N but-2-ynoic acid Chemical compound CC#CC(O)=O.CC#CC(O)=O VIAFSCDEGBWNKN-UHFFFAOYSA-N 0.000 description 1
- WWNGFHNQODFIEX-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;styrene Chemical compound C=CC=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WWNGFHNQODFIEX-UHFFFAOYSA-N 0.000 description 1
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 1
- YTIVTFGABIZHHX-UHFFFAOYSA-N butynedioic acid Chemical compound OC(=O)C#CC(O)=O YTIVTFGABIZHHX-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001723 carbon free-radicals Chemical class 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000007156 chain growth polymerization reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000019258 dehydroacetic acid Nutrition 0.000 description 1
- 229940061632 dehydroacetic acid Drugs 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- XUDOZULIAWNMIU-UHFFFAOYSA-N delta-hexenoic acid Chemical compound OC(=O)CCCC=C XUDOZULIAWNMIU-UHFFFAOYSA-N 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical class C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- HJWBBBADPXPUPA-UHFFFAOYSA-N ethyl 3-(4-chlorophenyl)-5-methyl-1,2-oxazole-4-carboxylate Chemical compound CCOC(=O)C1=C(C)ON=C1C1=CC=C(Cl)C=C1 HJWBBBADPXPUPA-UHFFFAOYSA-N 0.000 description 1
- JYGHNNMPKVPTKF-UHFFFAOYSA-N ethyl 3-amino-3-ethoxyprop-2-enoate;hydrochloride Chemical compound [Cl-].CCOC([NH3+])=CC(=O)OCC JYGHNNMPKVPTKF-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- KSEBMYQBYZTDHS-HWKANZROSA-N ferulic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-N 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000004868 gas analysis Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- QQVKNEQDEIZBLC-UHFFFAOYSA-N hepta-2,6-dienoic acid Chemical compound OC(=O)C=CCCC=C QQVKNEQDEIZBLC-UHFFFAOYSA-N 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- GWFKSQSXNUNYAC-UHFFFAOYSA-N hex-1-enylboronic acid Chemical compound CCCCC=CB(O)O GWFKSQSXNUNYAC-UHFFFAOYSA-N 0.000 description 1
- VPFMEXRVUOPYRG-UHFFFAOYSA-N hex-5-ynoic acid Chemical compound OC(=O)CCCC#C VPFMEXRVUOPYRG-UHFFFAOYSA-N 0.000 description 1
- KUQWZSZYIQGTHT-UHFFFAOYSA-N hexa-1,5-diene-3,4-diol Chemical compound C=CC(O)C(O)C=C KUQWZSZYIQGTHT-UHFFFAOYSA-N 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- IKXNIQJDNKPPCH-UHFFFAOYSA-N hydron;prop-2-yn-1-amine;chloride Chemical compound [Cl-].[NH3+]CC#C IKXNIQJDNKPPCH-UHFFFAOYSA-N 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 230000005660 hydrophilic surface Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910001869 inorganic persulfate Inorganic materials 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000008863 intramolecular interaction Effects 0.000 description 1
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 description 1
- QURCVMIEKCOAJU-HWKANZROSA-N isoferulic acid Chemical compound COC1=CC=C(\C=C\C(O)=O)C=C1O QURCVMIEKCOAJU-HWKANZROSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- TYQCGQRIZGCHNB-JLAZNSOCSA-N l-ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(O)=C(O)C1=O TYQCGQRIZGCHNB-JLAZNSOCSA-N 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- KKSDGJDHHZEWEP-UHFFFAOYSA-N m-hydroxycinnamic acid Natural products OC(=O)C=CC1=CC=CC(O)=C1 KKSDGJDHHZEWEP-UHFFFAOYSA-N 0.000 description 1
- FSQQTNAZHBEJLS-UPHRSURJSA-N maleamic acid Chemical compound NC(=O)\C=C/C(O)=O FSQQTNAZHBEJLS-UPHRSURJSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 238000001471 micro-filtration Methods 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- PKDBSOOYVOEUQR-UHFFFAOYSA-N mucobromic acid Natural products OC1OC(=O)C(Br)=C1Br PKDBSOOYVOEUQR-UHFFFAOYSA-N 0.000 description 1
- XHIRWEVPYCTARV-UHFFFAOYSA-N n-(3-aminopropyl)-2-methylprop-2-enamide;hydrochloride Chemical compound Cl.CC(=C)C(=O)NCCCN XHIRWEVPYCTARV-UHFFFAOYSA-N 0.000 description 1
- MVBJSQCJPSRKSW-UHFFFAOYSA-N n-[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]prop-2-enamide Chemical compound OCC(CO)(CO)NC(=O)C=C MVBJSQCJPSRKSW-UHFFFAOYSA-N 0.000 description 1
- AYGYHGXUJBFUJU-UHFFFAOYSA-N n-[2-(prop-2-enoylamino)ethyl]prop-2-enamide Chemical compound C=CC(=O)NCCNC(=O)C=C AYGYHGXUJBFUJU-UHFFFAOYSA-N 0.000 description 1
- LQFLWKPCQITJIH-UHFFFAOYSA-N n-allyl-aniline Chemical compound C=CCNC1=CC=CC=C1 LQFLWKPCQITJIH-UHFFFAOYSA-N 0.000 description 1
- AXTLFVLHXSDZOW-UHFFFAOYSA-N n-ethyl-2-methylprop-2-en-1-amine Chemical compound CCNCC(C)=C AXTLFVLHXSDZOW-UHFFFAOYSA-N 0.000 description 1
- SQGBZKZDUMBTIJ-UHFFFAOYSA-N n-prop-2-enylcyclohexanamine Chemical compound C=CCNC1CCCCC1 SQGBZKZDUMBTIJ-UHFFFAOYSA-N 0.000 description 1
- CTSIKBGUCQWRIM-UHFFFAOYSA-N n-prop-2-enylcyclopentanamine Chemical compound C=CCNC1CCCC1 CTSIKBGUCQWRIM-UHFFFAOYSA-N 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000009828 non-uniform distribution Methods 0.000 description 1
- PMOWTIHVNWZYFI-UHFFFAOYSA-N o-Coumaric acid Natural products OC(=O)C=CC1=CC=CC=C1O PMOWTIHVNWZYFI-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- AFDXODALSZRGIH-UHFFFAOYSA-N p-coumaric acid methyl ether Natural products COC1=CC=C(C=CC(O)=O)C=C1 AFDXODALSZRGIH-UHFFFAOYSA-N 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- MINRDQDGBLQBGD-UHFFFAOYSA-N pent-2-ynoic acid Chemical compound CCC#CC(O)=O MINRDQDGBLQBGD-UHFFFAOYSA-N 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-N pent-4-enoic acid Chemical compound OC(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-N 0.000 description 1
- MLBYLEUJXUBIJJ-UHFFFAOYSA-N pent-4-ynoic acid Chemical compound OC(=O)CCC#C MLBYLEUJXUBIJJ-UHFFFAOYSA-N 0.000 description 1
- 238000005371 permeation separation Methods 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- IPOVLZSJBYKHHU-UHFFFAOYSA-N piperidin-3-ylmethanamine Chemical compound NCC1CCCNC1 IPOVLZSJBYKHHU-UHFFFAOYSA-N 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920001713 poly(ethylene-co-vinyl alcohol) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- GHUURDQYRGVEHX-UHFFFAOYSA-N prop-1-ynylbenzene Chemical compound CC#CC1=CC=CC=C1 GHUURDQYRGVEHX-UHFFFAOYSA-N 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- XVSSGIXTKVRGAR-UHFFFAOYSA-N prop-2-enoxycarbonyl prop-2-enyl carbonate Chemical compound C=CCOC(=O)OC(=O)OCC=C XVSSGIXTKVRGAR-UHFFFAOYSA-N 0.000 description 1
- JKANAVGODYYCQF-UHFFFAOYSA-N prop-2-yn-1-amine Chemical compound NCC#C JKANAVGODYYCQF-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- JXOHGGNKMLTUBP-HSUXUTPPSA-N shikimic acid Chemical compound O[C@@H]1CC(C(O)=O)=C[C@@H](O)[C@H]1O JXOHGGNKMLTUBP-HSUXUTPPSA-N 0.000 description 1
- JXOHGGNKMLTUBP-JKUQZMGJSA-N shikimic acid Natural products O[C@@H]1CC(C(O)=O)=C[C@H](O)[C@@H]1O JXOHGGNKMLTUBP-JKUQZMGJSA-N 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 238000007155 step growth polymerization reaction Methods 0.000 description 1
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical compound S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- MHMUCYJKZUZMNJ-OWOJBTEDSA-N trans-3-chloroacrylic acid Chemical compound OC(=O)\C=C\Cl MHMUCYJKZUZMNJ-OWOJBTEDSA-N 0.000 description 1
- KKSDGJDHHZEWEP-SNAWJCMRSA-N trans-3-coumaric acid Chemical compound OC(=O)\C=C\C1=CC=CC(O)=C1 KKSDGJDHHZEWEP-SNAWJCMRSA-N 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- XXHDAWYDNSXJQM-ONEGZZNKSA-N trans-hex-3-enoic acid Chemical compound CC\C=C\CC(O)=O XXHDAWYDNSXJQM-ONEGZZNKSA-N 0.000 description 1
- YIYBQIKDCADOSF-ONEGZZNKSA-N trans-pent-2-enoic acid Chemical compound CC\C=C\C(O)=O YIYBQIKDCADOSF-ONEGZZNKSA-N 0.000 description 1
- LOIYMIARKYCTBW-OWOJBTEDSA-N trans-urocanic acid Chemical compound OC(=O)\C=C\C1=CNC=N1 LOIYMIARKYCTBW-OWOJBTEDSA-N 0.000 description 1
- LOIYMIARKYCTBW-UHFFFAOYSA-N trans-urocanic acid Natural products OC(=O)C=CC1=CNC=N1 LOIYMIARKYCTBW-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical class CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M16/00—Devices for influencing the respiratory system of patients by gas treatment, e.g. mouth-to-mouth respiration; Tracheal tubes
- A61M16/08—Bellows; Connecting tubes ; Water traps; Patient circuits
- A61M16/0875—Connecting tubes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M16/00—Devices for influencing the respiratory system of patients by gas treatment, e.g. mouth-to-mouth respiration; Tracheal tubes
- A61M16/08—Bellows; Connecting tubes ; Water traps; Patient circuits
- A61M16/0816—Joints or connectors
- A61M16/0841—Joints or connectors for sampling
- A61M16/085—Gas sampling
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M16/00—Devices for influencing the respiratory system of patients by gas treatment, e.g. mouth-to-mouth respiration; Tracheal tubes
- A61M16/10—Preparation of respiratory gases or vapours
- A61M16/14—Preparation of respiratory gases or vapours by mixing different fluids, one of them being in a liquid phase
- A61M16/142—Preparation of respiratory gases or vapours by mixing different fluids, one of them being in a liquid phase with semi-permeable walls separating the liquid from the respiratory gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/28—Selection of materials for use as drying agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0093—Chemical modification
- B01D67/00931—Chemical modification by introduction of specific groups after membrane formation, e.g. by grafting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/125—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/28—Polymers of vinyl aromatic compounds
- B01D71/281—Polystyrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/30—Polyalkenyl halides
- B01D71/32—Polyalkenyl halides containing fluorine atoms
- B01D71/34—Polyvinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/08—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/123—Treatment by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B5/00—Measuring for diagnostic purposes; Identification of persons
- A61B5/08—Detecting, measuring or recording devices for evaluating the respiratory organs
- A61B5/083—Measuring rate of metabolism by using breath test, e.g. measuring rate of oxygen consumption
- A61B5/0836—Measuring rate of CO2 production
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M2230/00—Measuring parameters of the user
- A61M2230/40—Respiratory characteristics
- A61M2230/43—Composition of exhalation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/38—Graft polymerization
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Pulmonology (AREA)
- Hematology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Anesthesiology (AREA)
- Biomedical Technology (AREA)
- Heart & Thoracic Surgery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Transplantation (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Investigating Or Analysing Biological Materials (AREA)
Abstract
【解決手段】スルホン酸基を有する化合物でグラフト化150されたポリマーを含む乾燥用ポリマー物質170であって、この物質は、ポリマーを所望の形態に加工する工程120と、このポリマーの少なくとも一部分を活性化する工程140と、このポリマーの活性化された部分を、スルホン化160されるように適合された基を有する化合物でグラフトする工程とを含むプロセス。
【選択図】図1
Description
パーベーパレーションによる気体の脱水のために従来から使用される方法は、プロトン交換膜燃料電池で使用される膜などのプロトン伝導性膜を使用することである。これらの膜の例はデュポン(DuPont)によりナフィオン(登録商標)の商標で販売されるが、それはペルフルオロ化スルホン酸ポリマーから作製される。完全フッ素化ポリマーであるナフィオン(登録商標)膜は高い化学安定性および熱安定性を有し、約100℃までの温度で強塩基、強い酸化性および還元性の酸、H2O2、Cl、H2およびO2中での化学的攻撃に対しても安定である。ナフィオン(登録商標)は、スルホン酸基が化学的に結合されているフッ素重合体骨格からなる。しかしながら、通常十分な性能を提供するが、ナフィオン(登録商標)は高価な材料であり、このことがナフィオン(登録商標)をほとんどの用途で経済的には魅力のないものにしている。
いくつかの実施形態によれば、膜またはチューブなど(これらに限定されない)の乾燥用ポリマー物質であって、芳香族基(例えば、フェニル基)などの基を有する化合物でグラフト化されたポリマーを含み、この基はスルホン化することができる乾燥用ポリマー物質が提供される。かかる基の例としては、スチレンまたはそれらのいずれかの誘導体を挙げることができる。いくつかの実施形態によれば、この乾燥用ポリマー物質はまた、選択的な水(蒸気または液体)輸送を生成するように適合されているいずれかの材料、特にスルホン酸基タイプの基(またはそのいずれかの誘導体もしくは塩)(これらに限定されない)も含んでいてよい。かかる乾燥用ポリマー物質の例はポリ(フッ化ビニリデン)−グラフト−ポリ(スチレンスルホン酸)(PVDF−g−PSSA)共重合体である。
1)水吸収[%]、
2)漏出[マイクロリットル/分]、
3)ΔCO2(二酸化炭素の変化)、
4)水エバポレーション[マイクロリットル/時間]、および
5)水蒸気浸透[マイクロリットル/時間]。
− PVDF−g−PSSAチューブはナフィオン(登録商標)チューブよりも有意に良好な(より高い)水吸収を示す。
− PVDF−g−PSSAチューブはナフィオン(登録商標)チューブよりも良好な(高い)水エバポレーション速度を示す。
− PVDF−g−PSSAチューブはナフィオン(登録商標)チューブと比べてより良好な水蒸気浸透性能を示す(ナフィオン(登録商標)チューブの151[マイクロリットル/時間]とは異なり水蒸気浸透の痕跡はゼロ)。
− 同時に、PVDF−g−PSSAチューブはCO2バリア特性の減退を示さないことが見出された。換言すれば、使用中のチューブからのCO2の喪失は実質的にないことは明らかであり、それゆえ当該PVDF−g−PSSAチューブは、例えば呼気検査におけるCO2分析のために使用することができる。
1)スチレン化が55℃で行われたPVDF−g−PSSA共重合体、
2)スチレン化が25℃で行われたPVDF−g−PSSA共重合体、
3)スチレン化が55℃で行われたPVDF−g−PSSA単独重合体、
4)スチレン化が55℃で行われたPVDF−g−PSSA単独重合体および共重合体、
5)スチレン化が25℃で行われたPVDF−g−PSSA単独重合体および共重合体、および
6)ナフィオン(登録商標)。
1)グラフト化度[%]、
2)水吸収[%]、
3)漏出[マイクロリットル/分]、
4)ΔCO2(二酸化炭素の変化)、
5)水エバポレーション[マイクロリットル/時間]、
6)水蒸気浸透[マイクロリットル/時間]およびPVC測定値からのΔ(差)、
7)化学反応(スチレン化およびスルホン化)に起因する厚さの変化[%]、
8)化学反応(スチレン化およびスルホン化)に起因する直径の変化[%]、
9)パーベーパレーション作用に起因するチューブ厚さの変化[%]、および
10)パーベーパレーション作用に起因するチューブ直径の変化[%]。
以下のチューブの水吸収は、ナフィオン(登録商標)の水吸収と同程度であるかまたはナフィオン(登録商標)の水吸収よりも高かった:
スチレン化が55℃で行われたPVDF−g−PSSA共重合体、スチレン化が25℃で行われたPVDF−g−PSSA共重合体、スチレン化が55℃で行われたPVDF−g−PSSA単独重合体および共重合体ならびにスチレン化が25℃で行われたPVDF−g−PSSA単独重合体および共重合体。
スチレン化が55℃で行われたPVDF−g−PSSA共重合体、スチレン化が25℃で行われたPVDF−g−PSSA共重合体ならびにスチレン化が55℃で行われたPVDF−g−PSSA単独重合体および共重合体。
下記の表3は、ナフィオン(登録商標)チューブの機械的特性と比べたPVDF−g−PSSAチューブの機械的特性を示す。
いくつかの実施形態によれば、2以上のポリマーを含む不均一相ポリマー組成物を含む乾燥用ポリマー物質であって、この2以上のポリマーのうちの少なくとも1つがスルホン酸基を含み、この物質は流体の極性に依存する流体の透過性を有し、この透過性は極性の増加に伴って増加する乾燥用ポリマー物質が提供される。例えば、このポリマー物質は、CO2(これは実質的に非極性の化合物である)に対してよりも水(これは極性の化合物である)に対して良好な透過性を呈してもよい。
a)独特の相溶化剤を加えて、PVDFをポリスチレン(PS)(またはスチレン共重合体)とともに、実質的に均一なブレンド化合物へと物理的にブレンドすること、
b)押出によってチューブを生成すること、およ
c)スルホン化プロセスを適用してPVDF/PSSA乾燥用チューブを生成すること
によって生成されてもよい。
a)相溶化剤を用いて2以上のポリマーおよび/または共重合体を(例えば、PVDFをポリスチレン(PS)および/またはスチレン−エチレン−ブチレン−スチレン(SEBS)などのスチレン共重合体と)実質的に均一なブレンド化合物へと混合する工程、
b)(例えば押出により、または射出成形などの成形により)このポリマー混合物を加工してチューブなどの所望の形態を生成する工程、および
c)スルホン化プロセスを適用して乾燥用チューブを生成する工程。
(a)PVDF/PS/PMMA−70/20/10(70%PVDF/20%PS/10%PMMA)、
(b)PVDF/SEBS(KRATON)/MBS(PARALOID相溶化剤)−49/49/2(49%PVDF/49%SEBS/2%MBS)。
1)水吸収[%]、
2)漏出[マイクロリットル/分]、
3)ΔCO2(二酸化炭素の変化)、
4)水エバポレーション[マイクロリットル/時間]、および
5)水蒸気浸透[マイクロリットル/時間]。
下記の表6は、ナフィオン(登録商標)チューブの機械的特性と比較した、PVDF/SEBS/MBSチューブの機械的特性を示す。
いくつかの実施形態によれば、本発明は、パーベーパレーションプロセスによる空気およびCO2などのより極性が低い気体からの水などの極性の流体の選択的な除去のために設計された堅牢な、高性能物質(膜またはチューブなど)を提供する。いくつかの実施形態によれば、かかる物質(これらは本願明細書において脱水物質または乾燥用物質と呼ぶことができる)は、所望の選択性および流量を与えるために制御された比で正および負に帯電した官能性の両方を有する架橋共重合体が組み込まれている支持部材、一般に支持体ポリマー部材(支持膜または支持チューブなど)を含む複合膜を備えていてもよい。この電荷を帯びた基の比およびこの支持部材に組み込まれた共重合体の量を変えることによって、流量および選択性は、特定の用途での使用のために制御することができる。
(a)支持部材であって、この支持部材を通って延在する複数の細孔(またはマイクロチャネル)を有する支持部材と、
(b)(i)カチオン性単量体およびアニオン性単量体ならびに/または(ii)双性イオン単量体を含む架橋共重合体であって、この架橋共重合体は上記支持部材の細孔を充填し、かつ流体の極性に依存する流体の透過性を有し、この透過性は極性の増加に伴って増加する、架橋共重合体と
を備える複合膜を提供する。
支持部材(複合膜)内での架橋共重合体の生成は、本発明のいくつかの実施形態によれば、以下の工程を含んでもよい:
a)多孔性支持部材の調製、
b)表面活性化、
c)多孔性支持部材への単量体溶液の含浸、
d)この単量体のグラフト共重合、および
e)架橋。
高分子支持部材は、当該技術分野で公知のいずれの方法によって生成されてもよい。この高分子支持部材の細孔に存在する水溶性のポリマーを抽出(除去)するためにおよび所望の多孔性支持部材を生成するために、得られた高分子支持部材を水または水溶液で洗浄することが行われる。従って、この洗浄または抽出工程は、細孔を望ましくない不純物(単独重合体など)から清浄にする。
多孔性支持部材を生成した後、表面活性化の工程が必要とされる場合がある。この表面活性化工程は、支持部材の表面および/または多孔性支持部材の細孔の表面に影響を及ぼす。この表面活性化は、多孔性支持部材の細孔(より正確に言えば、細孔の表面)への極性の単量体(後で重合および架橋されて共重合体細孔「充填剤」を形成するカチオンおよびアニオン単量体/双性イオンなど)の付着(adhesion)を容易にするように適合されている。この工程は、多孔性支持部材が疎水性の場合(PESなど)は、特に必要とされる。いくつかの実施形態によれば、この表面活性化工程は酸化を含み、(上記単量体に結合することができる)カルボニル基をそのポリマー多孔性支持部材に導入するように適合されている。
多孔性支持部材を表面活性化した後、多孔性支持部材への単量体溶液の含浸の工程が行われる。この工程は、この多孔性支持部材に、後で重合および架橋されて共重合体細孔「充填剤」を形成するカチオンおよびアニオン単量体を含む溶液/双性イオン溶液を物理的に導入することを含む。この溶液は、予め重合された(pre−polymerized)ポリマー前駆体溶液と呼ばれることがある。この溶液はまた、電解質ポリマー、重合開始剤、架橋剤またはいずれかの他の適切な添加剤を含んでいてもよい。
カチオンおよびアニオン単量体/双性イオン(およびいずれかの他の必要とされる添加剤)を含む溶液が多孔性支持部材に物理的に導入されると、グラフト共重合の工程が行われる。この工程は、多孔性支持部材へのその単量体の化学結合の形成、およびその単量体を共重合して共重合体を生成することを含む。この共重合体は支持膜の細孔内の適所に化学結合され繋ぎ止められる。
架橋の機能は架橋共重合体の柔軟性を制御および調節することである。いくつかの実施形態によれば、共重合体の架橋はその共重合体を固くし(例えば、共重合体を液体からゲル形態に変換する)、共重合体が細孔から外へ漏出するのを防ぐ。支持部材内での共重合体の架橋は、共重合の後または共重合の間に行われてもよい。使用される架橋剤は、非常に反応性であり、低い揮発性を有しかつカチオン性/アニオン性共重合体との三次元的な架橋構造を形成するための少なくとも2つの不飽和基を有してもよい。
PES繊維の表面を、溶液中の5%エタノールを使用して、室温で30分間洗浄した。
実施例2は、管路の表面活性化のための方法を例証する。適切な液体を用いてPES繊維の表面を洗浄して、いくらかの不純物を除去した。
ここで、いくつかの実施形態に係る乾燥用チューブの製造のプロセス手順の一例を説明するスキームを示す図6を参照する。工程1は、ポリマー多孔性チューブ、この場合はPES多孔性チューブを入手して、それを、スルホン酸部分を有する化合物を多孔性ポリマーチューブの基礎構造へと導入するために別の物質でコーティングすることを含む。この場合、コーティングは、PES多孔性チューブをアクリルアミド−メチル−プロパンスルホネート(AMPS)の溶液の中に10分間浸漬し、AMPSでコーティングおよび充填されたPESチューブを生成することによって行われる。工程2では、過硫酸カリウムまたは過酸化物を50℃で1時間使用することによって、AMPSでコーティングおよび充填されたPESチューブを表面活性化し、重合したAMPSを有するPESチューブを生成する。工程3では、重合したAMPSを有するPESチューブを80℃で1時間架橋し、洗浄し、乾燥してPES−g−AMPS架橋膜チューブを得る。
下記の表7は、ナフィオン(登録商標)チューブの性能と比較して、本発明のいくつかの実施形態に係る多孔性経路チューブの性能を示す。第1の例は、表面活性化用アルコール溶液中の0.1重量%の過硫酸アンモニウム酸化剤で前処理したPES多孔性中空繊維チューブを指し、第2の例は、表面活性化用アルコール溶液の1.0重量%の過硫酸アンモニウム酸化剤で前処理したPES多孔性中空繊維チューブを指す。
1)漏出[マイクロリットル/分]、
2)ΔCO2(二酸化炭素の変化)、
3)水エバポレーション[マイクロリットル/時間]、および
4)水蒸気浸透[マイクロリットル/時間]。
1)高密度のポリマーを通る透過、
2)細孔を通る粘性の高い流れ、および
3)非常に微細な細孔を通るクヌーセン流れ、
であるかも知れない。
気体乾燥用チューブの機械的特性
当該「多孔性コーティング」チューブは、ナフィオン(登録商標)チューブと直接比較することはできない。なぜなら、その基本となるマトリクスは、ナフィオン(登録商標)およびブレンドおよびグラフト化された種類のチューブにおけるような連続的なモルホロジーではないからである。
いくつかの実施形態によれば、(「グラフト化(高密度)経路」、「ブレンド(高密度)経路」および「多孔性経路」によるなど(これらに限定されない)のいずれかのプロセスで製造された)乾燥用ポリマーチューブは種々の形態および形状にあってもよい。特定の形状は、そのチューブの機械的特性(強度、ねじれまたはいずれかの他の特性など)およびそのパーベーパレーション能力に影響を及ぼすために選択されてもよい。
Claims (43)
- スルホン酸基を有する化合物でグラフト化されたポリマーを含み、かつ流体をパーベーパレーションするように適合された乾燥用ポリマー物質。
- 前記流体が水、水蒸気またはその両方を含む、請求項1に記載の乾燥用ポリマー物質。
- 前記ポリマーがポリオレフィン、フッ素重合体またはこれらの組み合わせを含む、請求項1に記載の乾燥用ポリマー物質。
- 前記フッ素重合体がポリ(フッ化ビニリデン)(PVDF)またはそのいずれかの誘導体を含む、請求項3に記載の乾燥用ポリマー物質。
- 前記スルホン酸基を有する化合物がスルホン化スチレン、スルホン化ポリスチレン、スルホン化スチレン共重合体またはそれらのいずれかの誘導体を含む、請求項1に記載の乾燥用ポリマー物質。
- 前記乾燥用ポリマー物質がポリ(フッ化ビニリデン)−グラフト−ポリ(スチレンスルホン酸)(PVDF−g−PSSA)またはそのいずれかの塩もしくは誘導体を含む、請求項1に記載の乾燥用ポリマー物質。
- スルホン化ポリマーの前の前記ポリマーのグラフト化の割合(%)が20〜50%の範囲にある、請求項1に記載の乾燥用ポリマー物質。
- 前記乾燥用ポリマー物質の前記スルホン化の割合(%)が40〜100%の範囲にある、請求項1に記載の乾燥用ポリマー物質。
- 前記乾燥用ポリマー物質が膜を含む、請求項1に記載の乾燥用ポリマー物質。
- 前記乾燥用ポリマー物質が乾燥用チューブを含む、請求項1に記載の乾燥用ポリマー物質。
- 前記チューブの内径が1.0±0.1ミリメートル(mm)であり、前記チューブの外径が1.24±0.02mmであり、前記チューブの長さが50mmである場合に、前記チューブが、22℃の温度および湿度34%で100%を超える水吸収を有する、請求項10に記載の乾燥用ポリマー物質。
- 前記チューブの内径が1.0±0.1ミリメートル(mm)であり、前記チューブの外径が1.24±0.02mmであり、前記チューブの長さが50mmである場合に、前記チューブが、22℃の温度および湿度34%で150マイクロリットル/時間を超える水エバポレーション速度を有する、請求項10に記載の乾燥用ポリマー物質。
- 前記乾燥用チューブが実質的に円形の内側断面を有する、請求項10に記載の乾燥用ポリマー物質。
- 前記乾燥用チューブが、実質的に円形の内側断面および非円形の外側断面を有する、請求項10に記載の乾燥用ポリマー物質。
- 前記乾燥用チューブが、非円形の内側断面および実質的に円形の外側断面を有する、請求項10に記載の乾燥用ポリマー物質。
- 前記乾燥用チューブが、非円形の内側断面および合致する非円形の外側断面を有する、請求項10に記載の乾燥用ポリマー物質。
- 前記乾燥用ポリマー物質が乾燥用チューブを含み、前記乾燥用チューブが内側導管を含み、前記内側導管の少なくとも一部分の内側断面が実質的に非円形であり、かつ前記内側導管の内壁に近接して液体を集めるように適合され、従って前記乾燥用チューブの中には実質的に液体の流れを有しないようにできるように適合されている、請求項1に記載の乾燥用ポリマー物質。
- 前記内側導管の前記断面が実質的にn個の突起の星型(nは2〜10の値を有する整数である)に類似している、請求項17に記載の乾燥用ポリマー物質。
- 前記内側導管の前記断面が実質的にn枚の花びらの花型(nは2〜10の値を有する整数である)に類似している、請求項17に記載の乾燥用ポリマー物質。
- 約20MPa以上の極限引張強さを有する、請求項1に記載の乾燥用ポリマー物質。
- 約150MPa以上のヤング率を有する、請求項1に記載の乾燥用ポリマー物質。
- 80%以上の伸びを呈する、請求項1に記載の乾燥用ポリマー物質。
- 流体をパーベーパレーションするように適合された乾燥用ポリマー物質の調製のためのプロセスであって、
ポリマーを所望の形態に加工する工程と、
前記ポリマーの少なくとも一部分を活性化する工程と、
前記ポリマーの活性化された部分を、スルホン化されるように適合された基を有する化合物でグラフトする工程と
を含むプロセス。 - 前記流体が水、水蒸気またはその両方を含む、請求項23に記載のプロセス。
- 前記ポリマーがポリオレフィン、フッ素重合体またはこれらの組み合わせを含む、請求項23に記載のプロセス。
- 前記フッ素重合体がポリ(フッ化ビニリデン)(PVDF)またはそのいずれかの誘導体を含む、請求項23に記載のプロセス。
- 前記スルホン化されるように適合された基がスチレン、ポリスチレン、スチレン共重合体またはそれらのいずれかの誘導体を含む、請求項23に記載のプロセス。
- 前記乾燥用ポリマー物質がポリ(フッ化ビニリデン)−グラフト−ポリ(スチレンスルホン酸)(PVDF−g−PSSA)またはそのいずれかの塩もしくは誘導体を含む、請求項23に記載のプロセス。
- 前記ポリマーのグラフト化の割合(%)が20〜50%の範囲にある、請求項23に記載のプロセス。
- グラフト化されたポリマーの基をスルホン化して、これにより水をパーベーパレーションするように適合されたポリマー物質を得る工程をさらに含む、請求項23に記載のプロセス。
- 前記乾燥用ポリマー物質のスルホン化の割合(%)が40〜100%の範囲にある、請求項30に記載のプロセス。
- 活性化が照射を含む、請求項23に記載のプロセス。
- 加工する工程が押出、成形またはその両方を含む、請求項23に記載のプロセス。
- 前記所望の形態がチューブを含み、前記得られた乾燥用ポリマー物質が乾燥用チューブを含む、請求項23に記載のプロセス。
- 前記乾燥用チューブが実質的に円形の内側断面を有する、請求項34に記載のプロセス。
- 前記乾燥用チューブが実質的に円形の内側断面および非円形の外側断面を有する、請求項34に記載のプロセス。
- 前記乾燥用チューブが非円形の内側断面および合致する非円形の外側断面を有する、請求項34に記載のプロセス。
- 前記乾燥用チューブが非円形の内側断面および合致する非円形の外側断面を有する、請求項34に記載のプロセス。
- 呼気採取システムであって、
スルホン酸基を有する化合物でグラフト化されたポリマーを含み、かつ流体をパーベーパレーションするように適合された乾燥用ポリマーチューブと、
前記乾燥用ポリマーチューブを呼気採取チューブに接続するように適合されたコネクタ、および強化要素のうちの少なくとも1つと
を含む呼気採取システム。 - 前記流体が水、水蒸気またはその両方を含む、請求項39に記載のシステム。
- 前記コネクタ、前記強化要素、またはその両方が、前記乾燥用ポリマーチューブとともに成形されている、請求項39に記載のシステム。
- 水パーベーパレーションに適合された管路系の調製方法であって、
1以上のさらなるチューブに接続するように適合された少なくとも1つのコネクタ、少なくとも1つの強化要素またはこれらの組み合わせを有するチューブの形態にポリマーを成形する工程と、
前記チューブの少なくとも一部分を活性化する工程と、
前記チューブの活性化された部分を、スルホン化されるように適合された基を有する化合物でグラフトする工程と
を含む方法。 - 前記スルホン化されるように適合された基をスルホン化して、これにより水をパーベーパレーションするように適合されたチューブと、1以上のさらなるチューブに接続するように適合された少なくとも1つのコネクタおよび/または少なくとも1つの強化要素とを含む管路系を得る工程をさらに含む、請求項42に記載の方法。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/379,833 US9067035B2 (en) | 2009-03-03 | 2009-03-03 | Drying substances, preparation and use thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2010209328A true JP2010209328A (ja) | 2010-09-24 |
JP2010209328A5 JP2010209328A5 (ja) | 2013-03-21 |
Family
ID=42153858
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010044619A Pending JP2010209328A (ja) | 2009-03-03 | 2010-03-01 | 乾燥用物質、その調製および使用 |
Country Status (4)
Country | Link |
---|---|
US (1) | US9067035B2 (ja) |
EP (2) | EP2226341A3 (ja) |
JP (1) | JP2010209328A (ja) |
CN (1) | CN101822950A (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012232067A (ja) * | 2011-05-09 | 2012-11-29 | Nippon Koden Corp | 水分捕集装置 |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR0102116B1 (pt) | 2000-05-10 | 2010-09-21 | componente para um membro de circuito de respiração. | |
US7559324B2 (en) | 2000-06-21 | 2009-07-14 | Fisher & Paykel Healthcare Limited | Conduit with heated wick |
AU2003244171B2 (en) | 2002-09-09 | 2007-11-15 | Fisher & Paykel Healthcare Limited | Limb for Breathing Circuit |
US7493902B2 (en) | 2003-05-30 | 2009-02-24 | Fisher & Paykel Healthcare Limited | Breathing assistance apparatus |
AU2004203870B2 (en) | 2003-09-17 | 2011-03-03 | Fisher & Paykel Healthcare Limited | Breathable Respiratory Mask |
GB2455962A (en) | 2007-12-24 | 2009-07-01 | Ethicon Inc | Reinforced adhesive backing sheet, for plaster |
US8372050B2 (en) | 2008-03-05 | 2013-02-12 | Kci Licensing, Inc. | Dressing and method for applying reduced pressure to and collecting and storing fluid from a tissue site |
US8747752B2 (en) * | 2009-03-03 | 2014-06-10 | Oridion Medical (1987) Ltd. | Drying substances, preparation and use thereof |
US8366811B2 (en) | 2009-03-03 | 2013-02-05 | Oridion Medical (1987) Ltd. | Drying substances, preparation and use thereof |
CA2785433C (en) | 2009-12-22 | 2024-01-09 | Fisher & Paykel Healthcare Limited | Components for medical circuits |
US8814842B2 (en) | 2010-03-16 | 2014-08-26 | Kci Licensing, Inc. | Delivery-and-fluid-storage bridges for use with reduced-pressure systems |
US9784708B2 (en) | 2010-11-24 | 2017-10-10 | Spec Sensors, Llc | Printed gas sensor |
US8985474B2 (en) | 2011-01-17 | 2015-03-24 | Paragon Space Development Corporation | Space humidity control systems |
GB2488749A (en) | 2011-01-31 | 2012-09-12 | Systagenix Wound Man Ip Co Bv | Laminated silicone coated wound dressing |
GB201106491D0 (en) | 2011-04-15 | 2011-06-01 | Systagenix Wound Man Ip Co Bv | Patterened silicone coating |
US10940047B2 (en) | 2011-12-16 | 2021-03-09 | Kci Licensing, Inc. | Sealing systems and methods employing a hybrid switchable drape |
CN103987348B (zh) | 2011-12-16 | 2016-05-11 | 凯希特许有限公司 | 可释放的医用布单 |
FR2985438A1 (fr) * | 2012-01-10 | 2013-07-12 | Alstom Technology Ltd | Membrane pour procede de filtration d'effluents gazeux d'une installation industrielle |
JP6313294B2 (ja) * | 2012-06-25 | 2018-04-18 | フィッシャー アンド ペイケル ヘルスケア リミテッド | 加湿および凝縮液管理を行うための微細構造を備える医療用部品 |
EP3669842B1 (en) | 2012-11-16 | 2023-09-27 | 3M Innovative Properties Company | Medical drape with pattern adhesive layers |
GB201222770D0 (en) | 2012-12-18 | 2013-01-30 | Systagenix Wound Man Ip Co Bv | Wound dressing with adhesive margin |
EP3909633B1 (en) | 2013-03-14 | 2023-11-22 | Fisher & Paykel Healthcare Limited | Humidification chamber with a mixing element comprising microstructures |
CA3177441A1 (en) | 2013-03-15 | 2014-09-18 | Fisher & Paykel Healthcare Limited | Nasal cannula assemblies and related parts |
ES2914031T3 (es) | 2013-08-09 | 2022-06-07 | Fisher & Paykel Healthcare Ltd | Elementos y accesorios asimétricos de administración nasal para interfaces nasales |
US9489623B1 (en) | 2013-10-15 | 2016-11-08 | Brain Corporation | Apparatus and methods for backward propagation of errors in a spiking neuron network |
WO2015065742A1 (en) | 2013-10-28 | 2015-05-07 | Kci Licensing, Inc. | Hybrid sealing tape |
WO2015065615A1 (en) * | 2013-10-30 | 2015-05-07 | Kci Licensing, Inc. | Absorbent conduit and system |
WO2015065616A1 (en) | 2013-10-30 | 2015-05-07 | Kci Licensing, Inc. | Dressing with sealing and retention intereface |
WO2015065614A1 (en) | 2013-10-30 | 2015-05-07 | Kci Licensing, Inc. | Dressing with differentially sized perforations |
WO2015065612A1 (en) * | 2013-10-30 | 2015-05-07 | Kci Licensing, Inc. | Condensate absorbing and dissipating system |
CA2940730C (en) | 2014-02-28 | 2022-07-26 | Kci Licensing, Inc. | Hybrid drape having a gel-coated perforated mesh |
US11026844B2 (en) | 2014-03-03 | 2021-06-08 | Kci Licensing, Inc. | Low profile flexible pressure transmission conduit |
EP3137029B1 (en) | 2014-05-02 | 2020-09-09 | KCI Licensing, Inc. | Fluid storage devices, systems, and methods |
EP3281616B1 (en) | 2014-06-05 | 2020-01-01 | KCI Licensing, Inc. | Dressing with fluid acquisition and distribution characteristics |
EP3191834A4 (en) * | 2014-09-12 | 2018-10-10 | Spec Sensors LLC | Breath sampling devices and methods of breath sampling using sensors |
US10398604B2 (en) | 2014-12-17 | 2019-09-03 | Kci Licensing, Inc. | Dressing with offloading capability |
US10722663B2 (en) * | 2015-02-06 | 2020-07-28 | Fisher & Paykel Healthcare Limited | System for humidification of medical gases |
WO2016182977A1 (en) | 2015-05-08 | 2016-11-17 | Kci Licensing, Inc. | Low acuity dressing with integral pump |
WO2016191552A1 (en) | 2015-05-26 | 2016-12-01 | Spec Sensors, Llc | Wireless near-field gas sensor system and methods of manufacturing the same |
JP6878318B2 (ja) | 2015-06-26 | 2021-05-26 | インテグリス・インコーポレーテッド | グラフト化ポリスルホン膜 |
WO2017040045A1 (en) | 2015-09-01 | 2017-03-09 | Kci Licensing, Inc. | Dressing with increased apposition force |
EP3892310A1 (en) | 2015-09-17 | 2021-10-13 | 3M Innovative Properties Co. | Hybrid silicone and acrylic adhesive cover for use with wound treatment |
CN115569281A (zh) * | 2016-06-07 | 2023-01-06 | 菲舍尔和佩克尔保健有限公司 | 用于呼吸设备的呼吸回路部件 |
CN106215293A (zh) * | 2016-09-07 | 2016-12-14 | 深圳永胜宏基医疗器械有限公司 | 一种防气透水装置及机械通气系统 |
USD870269S1 (en) | 2016-09-14 | 2019-12-17 | Fisher & Paykel Healthcare Limited | Nasal cannula assembly |
US11414757B2 (en) * | 2017-11-13 | 2022-08-16 | Taiwan Semiconductor Manufacturing Company, Ltd. | Gas tube, gas supply system and manufacturing method of semiconductor device using the same |
WO2019229749A1 (en) | 2018-05-28 | 2019-12-05 | Beair Water And Air Technologies Ltd. | Atmospheric water generation method, device and system |
CN113334522B (zh) * | 2021-06-23 | 2023-02-03 | 海林市佳采科技发展有限公司 | 一种木质薄皮吸管的制造方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03278826A (ja) * | 1990-03-29 | 1991-12-10 | Tokuyama Soda Co Ltd | 複合膜 |
JP2000237547A (ja) * | 1999-02-19 | 2000-09-05 | Ceramiques Techniques Soc | 濾過、分離、もしくは反応用要素のシート、そのようなシートを含むモジュール、シート形成方法、モジュール形成方法 |
JP2005539117A (ja) * | 2002-09-20 | 2005-12-22 | バラード パワー システムズ インコーポレイティド | 膜において有用なグラフトコポリマーの製造プロセス |
JP2006507044A (ja) * | 2002-10-08 | 2006-03-02 | アールアイシー・インベストメンツ・インコーポレイテッド | 一体型検体セル−フィルタ及びそれを使用する装置 |
Family Cites Families (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL171534C (nl) | 1970-06-16 | 1983-04-18 | Monsanto Co | Werkwijze voor het afscheiden van water uit mengsels die water en formaldehyd bevatten. |
US3753558A (en) | 1970-12-30 | 1973-08-21 | Delfold Corp | Sheet-folding machine |
BE788373A (fr) | 1971-09-09 | 1973-01-02 | Anvar | Procede pour le fractionnement de melanges par transfert a travers des membranes a base de polymere fluore porteur de groupes actifs |
JPS57212232A (en) | 1981-06-24 | 1982-12-27 | Asahi Chem Ind Co Ltd | Composite hydrophilic membrane and its preparation |
DE3220570A1 (de) | 1982-06-01 | 1983-12-01 | GFT Ingenieurbüro für Industrieanlagenbau, 6650 Homburg | Mehrschichtige membran und ihre verwendung zur trennung von fluessigkeitsgemischen nach dem pervaporationsverfahren |
DE3650465T2 (de) | 1985-02-09 | 1996-09-12 | Asahi Chemical Ind | Durchlässige Polymer-Membran für die Gastrocknung |
US4704324A (en) | 1985-04-03 | 1987-11-03 | The Dow Chemical Company | Semi-permeable membranes prepared via reaction of cationic groups with nucleophilic groups |
US4705543A (en) | 1986-09-19 | 1987-11-10 | Perma Pure Products, Inc. | Fluid drying tube |
US4808201A (en) * | 1986-09-19 | 1989-02-28 | Perma Pure Products, Inc. | Connector construction for fluid drying tube |
JPH02501391A (ja) | 1987-09-10 | 1990-05-17 | ヒューレット・パッカード・カンパニー | 水蒸気透過材料 |
US4935144A (en) | 1987-09-17 | 1990-06-19 | Texaco Inc. | Concentration of water-ketone compositions |
US4802988A (en) | 1987-09-17 | 1989-02-07 | Texaco Inc. | Dehydration of glycols |
US5334314A (en) | 1989-12-01 | 1994-08-02 | Deutsche Carbone Ag | Composition membrane for separating water from fluids containing organic components by means of pervaporation |
SE502780C2 (sv) | 1991-09-25 | 1996-01-08 | Siemens Elema Ab | Avfuktningsanordning |
US5334341A (en) | 1992-05-27 | 1994-08-02 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process for controlling carbon content of injection molding steels during debinding |
US5387378A (en) * | 1993-04-21 | 1995-02-07 | Tulane University | Integral asymmetric fluoropolymer pervaporation membranes and method of making the same |
US6051343A (en) * | 1996-09-25 | 2000-04-18 | Tdk Corporation | Polymeric solid electrolyte and lithium secondary cell using the same |
US6444343B1 (en) * | 1996-11-18 | 2002-09-03 | University Of Southern California | Polymer electrolyte membranes for use in fuel cells |
US7351314B2 (en) * | 2003-12-05 | 2008-04-01 | Semitool, Inc. | Chambers, systems, and methods for electrochemically processing microfeature workpieces |
US6413298B1 (en) * | 2000-07-28 | 2002-07-02 | Dais-Analytic Corporation | Water- and ion-conducting membranes and uses thereof |
US6635104B2 (en) | 2000-11-13 | 2003-10-21 | Mcmaster University | Gas separation device |
JP4989843B2 (ja) | 2001-07-20 | 2012-08-01 | マクマスター ユニヴァーシティ | 非対称性ゲル充填微多孔質膜 |
US6779522B2 (en) | 2001-10-16 | 2004-08-24 | Perma Pure, Inc. | Method and apparatus for treating breathing gases |
ATE428489T1 (de) | 2002-11-30 | 2009-05-15 | Gambro Lundia Ab | Geschäumte membran |
US20040150827A1 (en) * | 2003-02-04 | 2004-08-05 | General Electric Company | Device arrays and methods for operation in aggressive solvents and for measurements of barrier properties of plurality of coatings |
US20050118372A1 (en) * | 2003-12-02 | 2005-06-02 | Anthony Bonnet | Use of a structure based on a grafted fluoropolymer for storing and transporting chemicals |
US7597733B2 (en) | 2004-01-23 | 2009-10-06 | Ric Investments, Llc | Liquid absorbing filter assembly and system |
US7604746B2 (en) | 2004-04-27 | 2009-10-20 | Mcmaster University | Pervaporation composite membranes |
US7753991B2 (en) | 2004-07-30 | 2010-07-13 | Kertzman Systems, Inc. | Water transport method and assembly including a thin film membrane for the addition or removal of water from gases or liquids |
US7396880B2 (en) | 2005-05-24 | 2008-07-08 | Arkema Inc. | Blend of ionic (co)polymer resins and matrix (co)polymers |
US8240187B2 (en) * | 2005-08-16 | 2012-08-14 | Oridion Medical (1987) Ltd. | Breath sampling device and method for using same |
CN100337727C (zh) * | 2005-10-31 | 2007-09-19 | 浙江大学 | 含交联超支化分子的聚合物微孔膜及其制备方法 |
WO2007109106A1 (en) | 2006-03-16 | 2007-09-27 | Bdf Ip Holdings Ltd. | Fluorination of a porous hydrocarbon-based polymer for use as composite membrane |
JP4997625B2 (ja) | 2006-03-24 | 2012-08-08 | 独立行政法人日本原子力研究開発機構 | 燃料電池用高分子電解質膜の製造方法、その電解質膜、およびその膜を使用した燃料電池用膜電極接合体 |
US8366811B2 (en) | 2009-03-03 | 2013-02-05 | Oridion Medical (1987) Ltd. | Drying substances, preparation and use thereof |
US8747752B2 (en) | 2009-03-03 | 2014-06-10 | Oridion Medical (1987) Ltd. | Drying substances, preparation and use thereof |
-
2009
- 2009-03-03 US US12/379,833 patent/US9067035B2/en active Active
-
2010
- 2010-02-26 EP EP20100154961 patent/EP2226341A3/en not_active Withdrawn
- 2010-02-26 EP EP20130181034 patent/EP2666795A1/en not_active Withdrawn
- 2010-03-01 JP JP2010044619A patent/JP2010209328A/ja active Pending
- 2010-03-03 CN CN201010122628A patent/CN101822950A/zh active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03278826A (ja) * | 1990-03-29 | 1991-12-10 | Tokuyama Soda Co Ltd | 複合膜 |
JP2000237547A (ja) * | 1999-02-19 | 2000-09-05 | Ceramiques Techniques Soc | 濾過、分離、もしくは反応用要素のシート、そのようなシートを含むモジュール、シート形成方法、モジュール形成方法 |
JP2005539117A (ja) * | 2002-09-20 | 2005-12-22 | バラード パワー システムズ インコーポレイティド | 膜において有用なグラフトコポリマーの製造プロセス |
JP2006507044A (ja) * | 2002-10-08 | 2006-03-02 | アールアイシー・インベストメンツ・インコーポレイテッド | 一体型検体セル−フィルタ及びそれを使用する装置 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012232067A (ja) * | 2011-05-09 | 2012-11-29 | Nippon Koden Corp | 水分捕集装置 |
Also Published As
Publication number | Publication date |
---|---|
EP2226341A3 (en) | 2010-09-29 |
US9067035B2 (en) | 2015-06-30 |
CN101822950A (zh) | 2010-09-08 |
US20100226824A1 (en) | 2010-09-09 |
EP2226341A2 (en) | 2010-09-08 |
EP2666795A1 (en) | 2013-11-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5443213B2 (ja) | 乾燥用物質、その調製および使用 | |
US9067035B2 (en) | Drying substances, preparation and use thereof | |
US9090766B2 (en) | Drying substances, preparation and use thereof | |
JP2578281B2 (ja) | 促進輸送プロセス用複合膜 | |
EP1239000B1 (en) | Porous hydrophilic membranes | |
Kee et al. | Permeability performance of different molecular weight cellulose acetate hemodialysis membrane | |
AU2017254972B2 (en) | Asymmetric composite membranes and modified substrates used in their preparation | |
JPWO2002009857A1 (ja) | 改質された中空糸膜 | |
US5352511A (en) | Hydrophilic compositions with increased thermal resistance | |
JP7367369B2 (ja) | 加湿用中空糸膜およびこれを用いた加湿用中空糸膜モジュール | |
Lusiana et al. | The Effect of Temperature, Sulfonation, and PEG Addition on Physicochemical Characteristics of PVDF Membranes and Its Application on Hemodialysis Membrane | |
US20190200631A1 (en) | Durable asymmetric composite membranes and modified substrates used in their preparation | |
Cohen et al. | Irradiation‐induced grafting of poly (vinylidene fluoride)‐graft‐poly (styrene sulfonic acid) for the preparation of planar and tube‐shaped air‐drying membranes | |
Khulbe et al. | Surface modification of synthetic polymeric membranes for filtration and gas separation | |
Wijaya et al. | The Effect of Temperature, Sulfonation, and PEG Addition on Physicochemical Characteristics of PVDF Membranes and Its Application on Hemodialysis Membrane Retno Ariadi Lusiana1, Ayub Indra1, Nor Basid Adiwibawa Prasetya1, Nurwarrohman Andre Sasongko1, Parsaoran Siahaan1, Choiril Azmiyawati1, Nanik Wijayanti2 | |
NZ733706B (en) | Asymmetric composite membranes and modified substrates used in their preparation | |
NZ755706A (en) | Asymmetric composite membranes and modified substrates used in their preparation | |
WO2016094511A1 (en) | Carbon nanotube composite membrane | |
JPH08141377A (ja) | 多孔質分離膜 | |
TW200828655A (en) | Humidifier membrane |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130204 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20130204 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130731 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130820 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20131120 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20131125 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140219 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20140805 |