JP2010102270A5 - Photosensitive resin composition, method for producing photosensitive resin used therefor, and method for producing cured coating film - Google Patents

Photosensitive resin composition, method for producing photosensitive resin used therefor, and method for producing cured coating film Download PDF

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JP2010102270A5
JP2010102270A5 JP2008276084A JP2008276084A JP2010102270A5 JP 2010102270 A5 JP2010102270 A5 JP 2010102270A5 JP 2008276084 A JP2008276084 A JP 2008276084A JP 2008276084 A JP2008276084 A JP 2008276084A JP 2010102270 A5 JP2010102270 A5 JP 2010102270A5
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photosensitive resin
compound
producing
resin composition
reacting
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JP2008276084A
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JP5161032B2 (en
JP2010102270A (en
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Priority to JP2008276084A priority Critical patent/JP5161032B2/en
Priority claimed from JP2008276084A external-priority patent/JP5161032B2/en
Priority to PCT/JP2009/062446 priority patent/WO2010050272A1/en
Priority to KR1020117006587A priority patent/KR101267111B1/en
Priority to CN200980137692.1A priority patent/CN102164977B/en
Publication of JP2010102270A publication Critical patent/JP2010102270A/en
Publication of JP2010102270A5 publication Critical patent/JP2010102270A5/en
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Claims (6)

(A)三価の有機リン化合物とナフテン酸ジルコニウム及びオクチル酸ジルコニウムの少なくとも1種との存在下で、多官能エポキシ化合物と不飽和一塩基酸とを反応させ、更に多塩基酸無水物を反応させることにより生成したカルボキシル基に不飽和二重結合を有するモノエポキシ化合物及び水溶性モノエポキシ化合物を反応させて得られる感光性樹脂、(B)エポキシ樹脂、(C)光重合開始剤並びに(D)反応性希釈剤を含有することを特徴とする感光性樹脂組成物。   (A) A polyfunctional epoxy compound is reacted with an unsaturated monobasic acid in the presence of a trivalent organophosphorus compound and at least one of zirconium naphthenate and zirconium octylate, and further a polybasic acid anhydride is reacted Photosensitive resin obtained by reacting a monoepoxy compound having an unsaturated double bond and a water-soluble monoepoxy compound with a carboxyl group generated by the reaction, (B) epoxy resin, (C) photopolymerization initiator and (D 2.) A photosensitive resin composition comprising a reactive diluent. 前記感光性樹脂が、前記カルボキシル基1モルに対して、前記不飽和二重結合を有するモノエポキシ化合物及び前記水溶性モノエポキシ化合物を総量で0.15モル〜0.25モル(但し、水溶性モノエポキシ化合物は0.03モル未満)反応させて得られたものであることを特徴とする請求項1に記載の感光性樹脂組成物。   The photosensitive resin is such that the total amount of the monoepoxy compound having the unsaturated double bond and the water-soluble monoepoxy compound is 0.15 mol to 0.25 mol (however, the water solubility is per 1 mol of the carboxyl group). 2. The photosensitive resin composition according to claim 1, wherein the monoepoxy compound is obtained by reacting (less than 0.03 mol). 前記ナフテン酸ジルコニウム及びオクチル酸ジルコニウムの少なくとも1種を、質量基準で、三価の有機リン化合物の少なくとも4倍使用することを特徴とする請求項1又は2に記載の感光性樹脂組成物。   The photosensitive resin composition according to claim 1 or 2, wherein at least one of zirconium naphthenate and zirconium octylate is used at least 4 times as much as a trivalent organic phosphorus compound on a mass basis. 三価の有機リン化合物とナフテン酸ジルコニウム及びオクチル酸ジルコニウムの少なくとも1種との存在下で、多官能エポキシ化合物と不飽和一塩基酸とを反応させる第一工程と、
第一工程で得られた生成物に多塩基酸無水物を反応させる第二工程と、
第二工程で得られた生成物に不飽和二重結合を有するモノエポキシ化合物及び水溶性モノエポキシ化合物を反応させる第三工程と
を含むことを特徴とする感光性樹脂の製造方法。
A first step of reacting a polyfunctional epoxy compound with an unsaturated monobasic acid in the presence of a trivalent organic phosphorus compound and at least one of zirconium naphthenate and zirconium octylate;
A second step of reacting a polybasic acid anhydride with the product obtained in the first step;
A process for producing a photosensitive resin comprising the step of reacting a monoepoxy compound having an unsaturated double bond and a water-soluble monoepoxy compound with the product obtained in the second step.
空気を吹き込みながら前記第一工程における反応を行うことを特徴とする請求項4に記載の感光性樹脂の製造方法。   The method for producing a photosensitive resin according to claim 4, wherein the reaction in the first step is carried out while blowing in air. 請求項1〜3のいずれか一項に記載の感光性樹脂組成物を塗工し、乾燥して乾燥塗膜を得、この塗膜を露光した後、加熱することを特徴とする硬化塗膜の製造方法。A cured coating film characterized in that the photosensitive resin composition according to any one of claims 1 to 3 is coated and dried to obtain a dried coating film, and the coating film is exposed and then heated. Manufacturing method.
JP2008276084A 2008-10-27 2008-10-27 Photosensitive resin composition, method for producing photosensitive resin used therefor, and method for producing cured coating film Active JP5161032B2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2008276084A JP5161032B2 (en) 2008-10-27 2008-10-27 Photosensitive resin composition, method for producing photosensitive resin used therefor, and method for producing cured coating film
PCT/JP2009/062446 WO2010050272A1 (en) 2008-10-27 2009-07-08 Photosensitive resin composition and method for producing photosensitive resin used therein
KR1020117006587A KR101267111B1 (en) 2008-10-27 2009-07-08 Photosensitive resin composition and method for producing photosensitive resin used therein
CN200980137692.1A CN102164977B (en) 2008-10-27 2009-07-08 Photosensitive resin composition and method for producing photosensitive resin used therein

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JP2008276084A JP5161032B2 (en) 2008-10-27 2008-10-27 Photosensitive resin composition, method for producing photosensitive resin used therefor, and method for producing cured coating film

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JP2010102270A JP2010102270A (en) 2010-05-06
JP2010102270A5 true JP2010102270A5 (en) 2011-08-18
JP5161032B2 JP5161032B2 (en) 2013-03-13

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JP (1) JP5161032B2 (en)
KR (1) KR101267111B1 (en)
CN (1) CN102164977B (en)
WO (1) WO2010050272A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4723658B2 (en) * 2009-02-16 2011-07-13 昭和電工株式会社 Photosensitive resin composition and method for producing photosensitive resin used therefor
KR101349622B1 (en) * 2011-08-26 2014-01-10 롬엔드하스전자재료코리아유한회사 Photopolymerizable unsaturated resin, photosensitive resin composition comprising the same, and light shielding spacer and liquid crystal display device formed therefrom
CN105086602B (en) * 2015-07-02 2017-06-16 深圳市容大感光科技股份有限公司 Photocuring thermally curable resin composition ink, purposes and use its wiring board
CN105086604A (en) * 2015-07-13 2015-11-25 深圳市容大感光科技股份有限公司 Printing ink composition, application thereof and printed circuit board
CN105086605B (en) * 2015-07-13 2018-07-27 深圳市容大感光科技股份有限公司 A kind of photocuring heat-curing composition ink, purposes and the wiring board containing it
JP2017088538A (en) * 2015-11-10 2017-05-25 日本メナード化粧品株式会社 Filaggrin production promoter
CN108164686B (en) * 2018-02-01 2020-01-21 江南大学 Modified epoxy acrylate and solder resist containing same

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JP2001026624A (en) * 1999-07-15 2001-01-30 Tamura Kaken Co Ltd Photosensitive resin, photosensitive resin composition and printed-wiring board
JP4655362B2 (en) * 1999-12-28 2011-03-23 Dic株式会社 Method for producing photosensitive resin
JP2002308957A (en) * 2001-04-17 2002-10-23 Showa Highpolymer Co Ltd Modified novolak resin and photosensitive resin composition
JP2003057821A (en) * 2001-08-13 2003-02-28 Showa Highpolymer Co Ltd Photosensitive resin and photosensitive resin composition
JP2004131526A (en) * 2002-10-08 2004-04-30 Great Eastern Resins Industrial Co Ltd Photosensitive thermosetting resin and method for producing the same and solder-resistant ink composition comprising the resin
JP4682340B2 (en) 2003-07-25 2011-05-11 昭和電工株式会社 Method for producing photosensitive resin
JP4655928B2 (en) * 2005-06-30 2011-03-23 Dic株式会社 Photosensitive resin composition

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