JP2010037420A - Method for manufacturing coke for waste melting furnace, apparatus for manufacturing the same and waste melting treatment method utilizing the coke for waste melting furnace - Google Patents

Method for manufacturing coke for waste melting furnace, apparatus for manufacturing the same and waste melting treatment method utilizing the coke for waste melting furnace Download PDF

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JP2010037420A
JP2010037420A JP2008200960A JP2008200960A JP2010037420A JP 2010037420 A JP2010037420 A JP 2010037420A JP 2008200960 A JP2008200960 A JP 2008200960A JP 2008200960 A JP2008200960 A JP 2008200960A JP 2010037420 A JP2010037420 A JP 2010037420A
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coke
furnace
waste melting
melting furnace
waste
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JP5319980B2 (en
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Takeshi Nishi
猛 西
Yu Kashiwabara
友 柏原
Yasuhiko Kato
也寸彦 加藤
Kosuke Hoshisawa
康介 星沢
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Nippon Steel Engineering Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/40Valorisation of by-products of wastewater, sewage or sludge processing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/58Construction or demolition [C&D] waste

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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for manufacturing coke for a waste melting furnace which increases the calorific value by a calorific value-adjusting material and reduces the ash content, an apparatus for manufacturing the same, and a waste melting treatment method utilizing the coke for waste melting furnace. <P>SOLUTION: The method for manufacturing coke for the waste melting furnace comprises carbonizing waste, adding a calorific value-adjusting material and a binder to the carbonized product to knead the resulting mixture, subjecting the kneaded mixture to press molding, and again carbonizing the molded product to increase the calorific value and to reduce the ash content. The apparatus for manufacturing the coke for the waste melting furnace comprises a carbonization furnace 1 which carbonizes a raw material, a kneader 6 which adds a caloric value-adjusting material and a binder to the carbonized product discharged from the carbonization furnace 1 to knead the resulting mixture, a molding machine 7 which subjects the kneaded product to press molding, and a carbonization furnace which carbonizes the molded product. The coke for the waste melting furnace alone produced in the above method is introduced into a waste melting furnace to burn the coke at high temperatures to melt the ash content in the coke for the waste melting furnace. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、一般廃棄物及び/または産業廃棄物(建築混合廃棄物、下水汚泥、製紙スラッジ、家畜糞など)を利用した低コストで高品位の廃棄物溶融炉用コークスの製造方法およびその製造装置ならびに廃棄物溶融炉用コークスを利用した廃棄物溶融処理方法に関する。   The present invention relates to a method for producing low-cost, high-quality waste coke for waste melting furnace using general waste and / or industrial waste (such as building mixed waste, sewage sludge, paper sludge, and livestock excrement) and the production thereof. The present invention relates to a waste melting treatment method using coke for an apparatus and a waste melting furnace.

コークスは、製鉄や廃棄物溶融炉で熱源や還元剤として使用されるが、原料として強粘結炭を多く利用するため、コスト高であるだけでなく、コークスはCO排出量が多い化石燃料であるため、地球温暖化抑制の観点から、廃棄物やバイオマスの利用などの対策が求められている。 Coke is used as a heat source and reducing agent in steelmaking and waste melting furnaces, but because it uses a large amount of caking coal as a raw material, it is not only expensive, but coke has a high CO 2 emission. Therefore, from the viewpoint of suppressing global warming, measures such as the use of waste and biomass are required.

廃棄物を利用した炭化物の製造方法が提案されている。例えば、特許文献1には、家畜糞尿や下水汚泥を炭化処理し、得られる炭化物を石炭と混合、粉砕して混合燃料を製造する方法が開示されている。また、特許文献2には、農産廃棄物、畜産糞、廃プラスチック等の有機物を成形後、乾燥熱処理室に入れ、木炭粉末間で炭化した燃料用成形木炭を製造する方法が記載されている。   A method for producing carbide using waste has been proposed. For example, Patent Document 1 discloses a method of producing a mixed fuel by carbonizing livestock manure and sewage sludge and mixing and pulverizing the resulting carbide with coal. Patent Document 2 describes a method for producing molded charcoal for fuel obtained by molding organic matter such as agricultural waste, livestock excrement, and waste plastic into a dry heat treatment chamber and carbonizing between charcoal powders.

前記特許文献1,2の方式は、ボイラー用燃料(石炭代替)、調理用燃料としてのものであり、製鉄用および廃棄物溶融炉用コークスとしては強度が小さく、用途が限定されるという、問題がある。   The methods disclosed in Patent Documents 1 and 2 are used as fuel for boilers (coal substitute) and fuel for cooking, and are low in strength and limited in use as iron coke and waste melting furnace coke. There is.

そこで、引用文献3には、高強度の成形塊状物を製造するため、乾留炉にて原料を乾留して成形塊状物を製造する方法において、乾留後の成形塊状物を篩分けにより分級し、篩下の成形塊状物にバインダを添加し加圧成形した後同一の乾留炉に戻して、原料と共に乾留する方法が開示されている。   Therefore, in Cited Document 3, in order to produce a high-strength shaped lump, in the method of producing a shaped lump by dry distillation of the raw material in a dry distillation furnace, the shaped lump after dry distillation is classified by sieving, A method is disclosed in which a binder is added to a molding lump under a sieve and pressure-molded, then returned to the same dry distillation furnace, and carbonized together with raw materials.

図4は前記特許文献3に記載された成形塊状物の製造方法を示す工程概略図である。   FIG. 4 is a process schematic diagram showing the method for producing a molded lump described in Patent Document 3.

原料はシャフト炉式乾留炉1の炉上部から装入され、炉内の高温還元雰囲気により乾留される。乾留により、原料中の揮発分は、可燃性ガス、可燃性ダストおよびタールとなり、シャフト炉上部より排出される。原料中より揮発分が揮散した乾留残渣は、シャフト炉式乾留炉1の下部に設置したスクリューコンベヤ2により排出され、原料により混入する鉄分やその他金属および瓦礫類を磁選機3や選別機4により除去した後、篩選別機5により篩選別される。   The raw material is charged from the upper part of the shaft furnace type carbonization furnace 1 and is carbonized in a high temperature reducing atmosphere in the furnace. By dry distillation, the volatile matter in the raw material becomes combustible gas, combustible dust and tar, and is discharged from the upper part of the shaft furnace. The dry distillation residue from which the volatile components are volatilized out of the raw material is discharged by the screw conveyor 2 installed at the lower part of the shaft furnace type dry distillation furnace 1, and the iron content and other metals and debris mixed with the raw material are removed by the magnetic separator 3 and the separator 4. After the removal, the sieve is sorted by the sieve sorter 5.

篩下は、ミキサー6において、バインダとなる軟ピッチを混練し、乾留残渣と共に150℃に加熱し、成形機7にて加圧成形される。成形物8は、再び原料と共にシャフト炉式乾留炉1へ戻され、乾留によりバインダがコークス化し、強度のある成形塊状物が製造できる。一方、シャフト炉上部より揮散した可燃性ガスから、除じん機9によりガス中の可燃性ダストを捕集し、捕集した可燃性ダストは、篩選別機5へ導入され、篩下と共に成形され、再び乾留される。     Under the sieve, the mixer 6 kneads a soft pitch that becomes a binder, heats it together with the dry distillation residue to 150 ° C., and is pressure-molded by the molding machine 7. The molded product 8 is returned to the shaft furnace type dry distillation furnace 1 together with the raw material, and the binder is coke by dry distillation to produce a strong molded lump. On the other hand, the combustible dust in the gas is collected from the combustible gas volatilized from the upper part of the shaft furnace by the dust remover 9, and the collected combustible dust is introduced into the sieve sorter 5 and molded together with the sieve bottom. And carbonized again.

可燃性ダストを除去した可燃性ガスは、触媒10によりタール改質することにより清浄なガスとなり、このガスをガスエンジン発電機11に導入して発電できる。
特開2006−241206号公報 特開2007−332274号公報 特開2006−111645号公報
The combustible gas from which the combustible dust is removed becomes a clean gas by tar reforming by the catalyst 10 and can be generated by introducing this gas into the gas engine generator 11.
JP 2006-241206 A JP 2007-332274 A JP 2006-111645 A

前記引用文献3では、一般廃棄物などを原料とする場合、乾留により発生する残渣は2000〜3000kcal/kgと低カロリかつ高灰分である。この残渣を成型および乾留した場合、コークスとして熱量が不足する。   In the cited document 3, when a general waste or the like is used as a raw material, a residue generated by dry distillation has a low calorie and a high ash content of 2000 to 3000 kcal / kg. When this residue is molded and carbonized, the amount of heat is insufficient as coke.

製鉄用のコークスは、石炭を粉砕して乾留し、その過程で石炭が軟化溶融し粒子同士が結合することで強固な組織となり、コークスとしての強度を発現する。しかし、前記引用文献3では、原料として石炭も使用可能であるが、乾留炉に投入した石炭の粒のままコークス化してしまい、その粒状のコークスにバインダを加えて成型および乾留しても粒子同士の結合が弱いことから、強度が小さい。   Coke for iron making is pulverized and dry-distilled, and the coal softens and melts in the process, and particles are bonded to each other to form a strong structure and develop strength as coke. However, in the cited document 3, coal can be used as a raw material, but the coal particles are coke as they are put into the dry distillation furnace, and even if the particles are formed and dry distilled by adding a binder to the granular coke. Since the bond of is weak, the strength is small.

そこで、本発明は、発熱量調整材を添加して再度乾留することにより発熱量を高くするとともに、灰分を少なくした廃棄物溶融炉用コークスの製造方法およびその製造装置ならびに得られた廃棄物溶融炉用コークスを利用した廃棄物溶融処理方法を提供するものである。   Therefore, the present invention increases a calorific value by adding a calorific value adjusting material and re-distilling again, and at the same time, a method for producing coke for a waste melting furnace with reduced ash, a production apparatus therefor, and the obtained waste melting The present invention provides a waste melting method using furnace coke.

本発明は、廃棄物を乾留し、発熱量調整材とバインダを加えて混練し、加圧成型後、再度乾留することにより、発熱量を高くするとともに、灰分を少なくした廃棄物溶融炉用コークスを製造する。   The present invention is a method of coke for waste melting furnaces, in which waste is carbonized, calorific value adjusting material and binder are added and kneaded, and after pressure molding, the calorific value is increased and ash content is reduced by dry distillation again. Manufacturing.

請求項1の廃棄物溶融炉用コークスの製造方法は、廃棄物の乾留物に発熱量調整材とバインダを添加し、混錬および加圧成型したものを乾留することを特徴とする。   The method for producing a coke for a waste melting furnace according to claim 1 is characterized in that a calorific value adjusting material and a binder are added to a dry distillate of waste, and the mixture is kneaded and pressure-molded and dry-distilled.

請求項2の廃棄物溶融炉用コークスの製造方法は、発熱量調整材が石炭、オガクズ、稲藁のうちの1種類またはその混合物であり、3mm以下に粉砕することを特徴とする。   The method for producing coke for a waste melting furnace according to claim 2 is characterized in that the calorific value adjusting material is one kind or a mixture of coal, sawdust and rice straw, and pulverized to 3 mm or less.

請求項3の廃棄物溶融炉用コークスの製造方法は、前記原料の乾留物の発熱量、固定炭素、灰分、揮発分、炭素含有量の少なくとも1項目を測定・分析し、その結果に応じて、発熱量調整材の添加量を調整することを特徴とする。   The method for producing coke for a waste melting furnace according to claim 3 measures and analyzes at least one item of calorific value, fixed carbon, ash content, volatile content, and carbon content of the dry distillation product of the raw material, and according to the result The addition amount of the calorific value adjusting material is adjusted.

請求項4の廃棄物溶融炉用コークスの製造方法は、請求項1〜3のいずれか1項において、前記バインダとしてタール、ピッチ、リグニン、フェノール樹脂、フェノールの少なくとも1種類を使用することを特徴とする。   The method for producing coke for a waste melting furnace according to claim 4 is characterized in that in any one of claims 1 to 3, at least one of tar, pitch, lignin, phenol resin, and phenol is used as the binder. And

請求項5の廃棄物溶融炉用コークスの製造方法は、請求項1〜4のいずれか1項において、乾留時に発生する乾留ガスからタール分を回収し、バインダとすることを特徴とする。   The method for producing coke for a waste melting furnace according to claim 5 is characterized in that, in any one of claims 1 to 4, a tar content is recovered from a dry distillation gas generated during dry distillation and used as a binder.

請求項6の廃棄物溶融炉用コークスの製造方法は、請求項1〜5のいずれか1項において、乾留温度が700〜1200℃であることを特徴とする。   The method for producing coke for a waste melting furnace according to claim 6 is characterized in that, in any one of claims 1 to 5, a dry distillation temperature is 700 to 1200 ° C.

請求項7の廃棄物溶融炉用コークスの製造方法は、請求項1〜6のいずれか1項において、バインダ添加量が2〜50%(重量比)であることを特徴とする。   The method for producing coke for a waste melting furnace according to claim 7 is characterized in that, in any one of claims 1 to 6, the amount of binder added is 2 to 50% (weight ratio).

請求項8の廃棄物溶融炉用コークスの製造方法は、請求項1〜7のいずれか1項において、乾留炉にて原料を乾留し、乾留後の乾留物を篩分けにより分級し、篩下の乾留物に発熱量調整材とバインダを添加し、混練および加圧成型したものを前記乾留炉に戻して、前記原料と共に乾留することを特徴とする。   The method for producing coke for a waste melting furnace according to claim 8 is the method according to any one of claims 1 to 7, wherein the raw material is dry-distilled in a dry distillation furnace, and the dry distillate after the dry distillation is classified by sieving. A calorific value adjusting material and a binder are added to the dry-distilled product, and the kneaded and pressure-molded product is returned to the dry-distilling furnace and dry-distilled with the raw materials.

請求項9の廃棄物溶融炉用コークスの製造方法は、請求項1〜8のいずれか1項において、乾留炉より発生する可燃性ガスを燃焼させ、乾留炉の熱源とすることを特徴とする。   The method for producing coke for a waste melting furnace according to claim 9 is characterized in that, in any one of claims 1 to 8, combustible gas generated from the dry distillation furnace is burned and used as a heat source for the dry distillation furnace. .

請求項10の廃棄物溶融炉用コークスの製造装置は、原料を乾留する乾留炉と、乾留炉から排出した乾留物に発熱量調整材とバインダを添加し混練する混練装置と、混練物を加圧成型する成型機と、成型物を乾留する乾留炉からなることを特徴とする。   The apparatus for producing coke for a waste melting furnace according to claim 10 comprises: a carbonization furnace for carbonizing raw materials; a kneading apparatus for adding a calorific value adjusting material and a binder to the carbonized product discharged from the carbonization furnace; It consists of a molding machine for pressure molding and a carbonization furnace for carbonizing the molded product.

請求項11の廃棄物溶融炉用コークスの製造装置は、請求項10において、原料を乾留して生成した乾留物の発熱量、固定炭素、灰分、揮発分、炭素含有量の少なくとも1項を測定・分析する装置を設置したことを特徴とする。   The apparatus for producing a coke for a waste melting furnace according to claim 11 measures at least one of calorific value, fixed carbon, ash, volatile matter, and carbon content of a dry distillation product produced by dry distillation of a raw material according to claim 10.・ It is characterized by the equipment to be analyzed.

請求項12の廃棄物溶融炉用コークスの製造装置は、請求項10または11において、原料と乾留する乾留炉と成型物を乾留する乾留炉が同一の乾留炉であり、かつ乾留物を篩分けする篩機を設置し、篩分けした篩下の乾留物を混練機に導入する機構を設けたことを特徴とする。   The apparatus for producing coke for a waste melting furnace according to claim 12 is the same as in claim 10 or 11, wherein the raw material, the carbonization furnace for carbonizing, and the carbonization furnace for carbonizing the molded product are the same carbonization furnace, and sieved the carbonized product The sieving machine is installed, and a mechanism is provided for introducing the sifted dry-distilled material into the kneader.

請求項13の廃棄物溶融炉用コークスの製造装置は、請求項10〜12のいずれか1項において、乾留炉から排出されるガスを導くダクトと導通した乾留ガス燃焼炉と、燃焼炉の排ガスを前記乾留炉に導くためのダクトを設けたことを特徴とする。   The apparatus for producing coke for a waste melting furnace according to claim 13 is the dry distillation gas combustion furnace connected to the duct for guiding the gas discharged from the dry distillation furnace according to any one of claims 10 to 12, and the exhaust gas of the combustion furnace It is characterized in that a duct is provided for guiding the gas to the carbonization furnace.

請求項14の廃棄物溶融処理方法は、廃棄物溶融炉に、請求項1〜8のいずれかに記載の方法で製造した廃棄物溶融炉用コークスを単独で投入、あるいは塩基度調整材とともに投入し、高温燃焼させて廃棄物溶融炉用コークス中の灰分を溶融させることを特徴とする。   The waste melting treatment method according to claim 14 is a method in which the waste melting furnace coke produced by the method according to any one of claims 1 to 8 is added to the waste melting furnace alone or together with the basicity adjusting material. And ash in the coke for the waste melting furnace is melted by high temperature combustion.

本発明は、発熱量調整材を添加して再度乾留することにより発熱量を高くするとともに、灰分を少なくした廃棄物溶融炉用コークスが得られる。   In the present invention, coke for a waste melting furnace with a high calorific value and a reduced ash content is obtained by adding a calorific value adjusting material and performing dry distillation again.

また、本発明により廃棄物から得られた廃棄物溶融炉用コークスを単独、あるいは塩基度調整材とともに投入し、高温燃焼させて溶融処理することにより、外部エネルギー投入量を極小化し、CO排出量を低減することが可能となる。 Moreover, waste melting furnace coke obtained from waste by the present invention was charged, alone or basicity adjusting agent, by melting treatment by hot combustion to minimize the external energy input, CO 2 emissions The amount can be reduced.

図1は本発明による廃棄物溶融炉用コークスの製造方法を示す工程概略図である。   FIG. 1 is a process schematic diagram showing a method for producing coke for a waste melting furnace according to the present invention.

図4に示す従来技術と同じく、一般廃棄物、建築混合廃棄物、下水汚泥、製紙スラッジ、家畜糞などの有機物質を含有する廃棄物は、シャフト炉式乾留炉1の炉上部から装入され、炉内の高温還元雰囲気により乾留される。乾留炉1は、ロータリーキルン、シャフト炉、流動床などさまざまな乾留装置が適用可能である。   As in the prior art shown in FIG. 4, waste containing organic substances such as general waste, building mixed waste, sewage sludge, paper sludge, and livestock manure is charged from the top of the shaft furnace type dry distillation furnace 1. The dry distillation is performed in a high-temperature reducing atmosphere in the furnace. Various dry distillation apparatuses such as a rotary kiln, a shaft furnace, and a fluidized bed can be applied to the dry distillation furnace 1.

乾留により、揮発分は、可燃性ガス、可燃性ダストおよびタールとなり、シャフト炉式乾留炉1の上部より排出される。揮発分が飛散した乾留残渣は、シャフト炉式乾留炉1の下部に設置したスクリューコンベヤ2により排出される。乾留残渣に混入している鉄分やその他金属および瓦礫類を磁選機3や選別機4により除去した後、篩選別機5により篩選別をする。   By dry distillation, the volatile matter becomes combustible gas, combustible dust and tar, and is discharged from the upper part of the shaft furnace type dry distillation furnace 1. The dry distillation residue from which volatile matter has been scattered is discharged by a screw conveyor 2 installed at the lower part of the shaft furnace type dry distillation furnace 1. After iron content and other metals and rubbles mixed in the dry distillation residue are removed by the magnetic separator 3 and the separator 4, the sieve is sorted by the sieve separator 5.

篩下の乾留物、発熱量調整材、バインダをミキサー6にて混練する。   The dried product under the sieve, the calorific value adjusting material, and the binder are kneaded by the mixer 6.

篩選別機5の篩下の乾留物は、分析・測定装置12により、発熱量、固定炭素、灰分、揮発分、炭素含有量の少なくとも1項目を測定・分析し、その結果に応じて、発熱量調整材の添加量を調整する。一般廃棄物などの炭化物は、発熱量が低く、このまま成型コークスとしても、発熱量が低い成型コークスとなり、廃棄物溶融炉用のコークスとしては熱量不足であるが、本発明では、発熱量調整材を加えることで、廃棄物溶融炉用のコークスとして適用可能な発熱量とすることができる。発熱量調整材は、例えば、石炭、オガクズ、稲藁のうちの1種類またはそれらの混合物であり、3mm以下に粉砕する。これらの発熱量調整材は乾留物の発熱量が高いだけでなく、石炭は乾留時に軟化溶融し、オガクズ、稲藁は加圧成型時に析出するリグニンのバインダとしての効果によりコークスの強度上昇に寄与する。   The dry distillation product under the sieve of the sieve sorter 5 measures and analyzes at least one item of calorific value, fixed carbon, ash content, volatile content, and carbon content by the analysis / measurement device 12, and generates heat according to the result. Adjust the amount of addition of the amount adjusting material. Carbides such as general wastes have a low calorific value, and even if they are molded coke, the calorific value is low, and the calorific value is insufficient as coke for waste melting furnaces. The amount of heat generated can be applied as coke for a waste melting furnace. The calorific value adjusting material is, for example, one of coal, sawdust, rice straw or a mixture thereof, and pulverized to 3 mm or less. These calorific value adjustment materials not only have a high calorific value of the carbonized product, but also coal softens and melts during carbonization, and sawdust and rice straw contribute to an increase in coke strength by the effect of lignin that precipitates during pressure molding. To do.

発熱量調整材の添加量は、原料の乾留物の発熱量、固定炭素、灰分、揮発分、炭素含有量の少なくとも1項目を測定・分析し、その結果に応じて、調整する。   The addition amount of the calorific value adjusting material is adjusted according to the result of measuring / analyzing at least one item of calorific value, fixed carbon, ash content, volatile content, and carbon content of the raw carbonized material.

図2(a)は1回目の乾留で得られた乾留物の発熱量とこの乾留物に添加する発熱量調整材添加量の関係を示すグラフ、(b)は1回目の乾留で得られた乾留物の灰分量とこの乾留物に添加する発熱量調整材添加量の関係を示すグラフである。1回目の乾留で得られた乾留物の発熱量が大きいと発熱量調整材添加量が少なくて済み、1回目の乾留で得られた乾留物の灰分量が多いと発熱量調整材添加量も多くする必要がある。   FIG. 2 (a) is a graph showing the relationship between the calorific value of the dry distillation product obtained in the first carbonization and the addition amount of the calorific value adjusting material added to this dry distillation, and (b) was obtained in the first carbonization. It is a graph which shows the relationship between the ash content of a dry distillation thing, and the calorific value adjustment material addition amount added to this dry distillation thing. If the calorific value of the dry distillation product obtained by the first dry distillation is large, the amount of addition of the calorific value adjustment material is small. There is a need to do more.

一般廃棄物の乾留物の性状と木質バイオマスの乾留物の性状は大きく異なるので、前記項目の少なくとも1つを測定、分析することで乾留物の性状を管理し、石炭の混合物を調整することで、成型コークスの発熱量を安定させることが可能となる。   Since the properties of general waste dry distillate and wood biomass dry distillate are significantly different, by measuring and analyzing at least one of the above items, the properties of the dry distillate can be controlled and the coal mixture adjusted. It is possible to stabilize the calorific value of the molded coke.

バインダとしてタール、ピッチ、リグニン、フェノール樹脂、フェノールの少なくとも1種類を使用する。乾留時に発生する乾留ガスからタール分を凝縮分離させて回収し、バインダとして使用することもでき、バインダのコスト削減が可能となる。バインダとして粒子同士を結合させ、それを乾留した際、粒子間のバインダが炭化し、粒子同士の結合力を維持する。また、室炉コークスの製造法においては、安価な一般炭にタールなどを添加することで、強粘結炭並の軟化溶融性を発揮することが知られており、本発明の場合は、発熱量調整材としての石炭が軟化溶融し、成型コークスの強度上昇に寄与する。バインダ添加量は2〜50%(重量比)であり、例えばタール、ピッチ等常温で粘性の高いバインダの場合バインダを50〜200℃に加熱することも可能である。乾留する廃棄物の性状により、乾留物の発熱量および発熱量調整材の添加量が異なる。例えば、木材を乾留した場合は、その発熱量は高いが、乾留物の密度が小さく、バインダの添加量は40%程度必要である。一方、発熱量調整材として、オガクズを使用する場合は、オガクズから析出するリグニンがバインダの機能を果たすため、バインダの添加率は3%程度でも十分である。   As the binder, at least one of tar, pitch, lignin, phenol resin, and phenol is used. The tar content can be condensed and recovered from the dry distillation gas generated during the dry distillation and used as a binder, and the cost of the binder can be reduced. When particles are bonded as a binder and carbonized, the binder between the particles is carbonized, and the bonding force between the particles is maintained. In addition, in the method for producing blast furnace coke, it is known that by adding tar or the like to cheap steam coal, it exhibits softening and melting properties comparable to those of strong caking coal. Coal as a quantity adjusting material softens and melts and contributes to an increase in strength of molded coke. The added amount of the binder is 2 to 50% (weight ratio). For example, in the case of a binder having a high viscosity at room temperature such as tar and pitch, the binder can be heated to 50 to 200 ° C. The calorific value of the dry distillation product and the amount of the calorific value adjusting material added differ depending on the properties of the waste to be carbonized. For example, when wood is carbonized, the calorific value is high, but the density of the carbonized material is small, and the amount of binder added is about 40%. On the other hand, when sawdust is used as the calorific value adjusting material, since the lignin precipitated from sawdust serves as a binder, a binder addition rate of about 3% is sufficient.

混練物を加熱し、成形機7にて、加圧成形する。成型機は、成型物の強度が求められるため、押出成型機、ダブルロール式成型機、射出成型機、プレス成型機などの適用が可能であるが、より大量生産が可能なダブルロール式成型機が望ましい。   The kneaded product is heated and pressure-molded by the molding machine 7. Since the molding machine requires strength of the molded product, it can be applied to extrusion molding machines, double roll molding machines, injection molding machines, press molding machines, etc., but double roll molding machines capable of mass production. Is desirable.

成形物8は、再び原料と共にシャフト炉式乾留炉1へ戻され、乾留することにより、バインダがコークス化し、強度のある成形塊状物が製造できる。乾留温度は700〜1200℃である。乾留温度が700℃以下では、成型コークスの揮発分が10%以上となる。廃棄物溶融炉に適用した場合、揮発分の高い成型コークスは、溶融炉下部の高温還元雰囲気中で崩壊し、高温火格子を形成できない。また、乾留温度1200℃以上では、成型コークスの強度に大差がなく、経済的な問題が発生する。そこで、乾留温度は700〜1200℃であることが望ましい。   The molded product 8 is returned to the shaft furnace type carbonization furnace 1 together with the raw material, and is subjected to carbonization, whereby the binder is coke and a strong molded lump can be produced. The dry distillation temperature is 700 to 1200 ° C. When the carbonization temperature is 700 ° C. or less, the volatile content of the molded coke is 10% or more. When applied to a waste melting furnace, molded coke with a high volatile content collapses in a high-temperature reducing atmosphere at the lower part of the melting furnace and cannot form a high-temperature grate. Moreover, when the carbonization temperature is 1200 ° C. or higher, there is no great difference in the strength of the molded coke, which causes an economic problem. Therefore, it is desirable that the dry distillation temperature is 700 to 1200 ° C.

一方、シャフト炉上部より飛散した可燃性ガスは、除じん器9によりガス中の可燃性ダストを捕集し、捕集した可燃性ダストは、篩選別機5へ導入され、篩下と共に成形され、再び乾留される。可燃性ダストを除去した可燃性ガスは、触媒10によりタール改質することにより、清浄なガスとなり、このガスをガスエンジン発電機11に導入することで発電に利用することができる。   On the other hand, the combustible gas scattered from the upper part of the shaft furnace collects the combustible dust in the gas by the dust remover 9, and the collected combustible dust is introduced into the sieve sorter 5 and molded together with the sieve bottom. And carbonized again. The combustible gas from which the combustible dust is removed becomes a clean gas by tar reforming by the catalyst 10, and can be used for power generation by introducing this gas into the gas engine generator 11.

また、可燃性ガスの全量もしくは一部を燃焼炉13で燃焼させて高温の排ガスを発生させ、この高温ガスを乾留炉1の乾留熱源として利用することで、省エネルギー化を図ることができる。また、可燃性ガス中のタールは、触媒改質のほかタール分を凝縮させ、バインダとしてミキサー6に投入することも可能である。   Further, by burning all or part of the combustible gas in the combustion furnace 13 to generate high-temperature exhaust gas and using this high-temperature gas as a dry distillation heat source of the dry distillation furnace 1, energy saving can be achieved. Further, the tar in the combustible gas can be condensed into the tar component in addition to the catalyst reforming, and can be put into the mixer 6 as a binder.

篩選別機5の篩上の、再度乾留された乾留物は、発熱量が高く、灰分を少なくした廃棄物溶融炉用コークスとして利用される。   The re-distilled dry matter on the sieve of the sieve sorter 5 has a high calorific value and is used as coke for a waste melting furnace having a low ash content.

こうして得られた廃棄物溶融炉用コークスは、従来の廃棄物溶融炉による溶融処理と同様に、廃棄物とともに廃棄物溶融炉に投入し、廃棄物溶融炉用コークスでコークスベットを形成して廃棄物を溶融処理することができる。   The coke for the waste melting furnace thus obtained is thrown into the waste melting furnace together with the waste, and the coke bed is formed with the coke for the waste melting furnace, and discarded. The product can be melt processed.

また、従来、廃棄物溶融炉の燃料として、高コストな製鉄用コークスを使用しているが、本発明により廃棄物から得られた廃棄物溶融炉用コークスだけを廃棄物溶融炉に投入し、高温燃焼させ、廃棄物溶融炉用コークス中の灰分を溶融させることにより、外部エネルギー投入量を極小化し、CO排出量を低減した廃棄物溶融処理が可能となる。このとき、廃棄物溶融炉コークス中の灰分量および塩基度(CaO/SiO)に応じて、例えば石灰石や珪砂等の塩基度調整材を添加することで、排出される溶融スラグの流動性や品質を安定させることが可能である。 Conventionally, as a fuel for the waste melting furnace, high-cost iron coke is used, but only the waste melting furnace coke obtained from the waste according to the present invention is put into the waste melting furnace, By burning at a high temperature and melting the ash in the coke for the waste melting furnace, it is possible to minimize the amount of external energy input and to achieve a waste melting process with reduced CO 2 emissions. At this time, depending on the ash content and basicity (CaO / SiO 2 ) in the waste melting furnace coke, for example, by adding a basicity adjusting material such as limestone or silica sand, It is possible to stabilize the quality.

本実施例では、図1に示す製造方法により、成型コークスを製造した。原料として、家庭から排出される一般廃棄物を使用した。この図に示すように、一般廃棄物はシャフト炉式乾留炉1の炉上部から装入され、炉内の高温還元雰囲気により、水分の乾燥及び乾留がなされる。乾留により、可燃性ガス、可燃性ダスト及びタールが炉上部より排出される。
原料中より揮発分が揮散した乾留残渣は、シャフト炉式乾留炉1下部に設置したスクリューコンベヤ2により排出され、一般廃棄物中に混入する鉄分やその他金属類及び瓦礫類を磁選機3や各種選別機4により除去した後、篩選別機5により篩選別される。ここで、節目の大きさを変更することにより、製品の粒度分布は容易に調整可能であるが、本実施例では、通常の廃棄物溶融炉にあわせて、節目を20mmとした。
In this example, molded coke was manufactured by the manufacturing method shown in FIG. General waste discharged from households was used as a raw material. As shown in this figure, the general waste is charged from the upper part of the shaft furnace type dry distillation furnace 1, and the moisture is dried and dry distilled by the high temperature reducing atmosphere in the furnace. By dry distillation, combustible gas, combustible dust and tar are discharged from the upper part of the furnace.
The carbonization residue from which the volatile components are volatilized out of the raw material is discharged by the screw conveyor 2 installed at the lower part of the shaft furnace type carbonization furnace 1, and the iron content and other metals and debris mixed in the general waste are separated by the magnetic separator 3 and various kinds. After removal by the sorter 4, the sieve is sorted by the sieve sorter 5. Here, the particle size distribution of the product can be easily adjusted by changing the size of the knots, but in this example, the knots were set to 20 mm in accordance with a normal waste melting furnace.

篩機により選別された篩下の発熱量を測定した。本実施例では、一般的な発熱量測定法である、断熱ボンベ式発熱量測定装置を用いた。なお、ここでは、この方法を用いたが、乾留物は、大部分が固定炭素と灰分から構成されるため、発熱量のほか、固定炭素、灰分、揮発分、炭素含有量などの一般的な分析により代用可能である。   The calorific value under the sieve selected by the sieving machine was measured. In this example, a heat insulation cylinder type calorific value measuring device, which is a general calorific value measuring method, was used. Although this method was used here, most of the dry distillate is composed of fixed carbon and ash, so in addition to the calorific value, general carbon such as fixed carbon, ash, volatile, and carbon content It can be substituted by analysis.

発熱量を測定した結果、乾留物の発熱量は2800kcal/kgであった。そこで、図2(a)に基づき、発熱量調整材として、石炭(一般炭)を53%(重量比:外数)および、バインダとして、コークス炉から排出されるタール15%(重量比:外数)をミキサー6に投入し、ミキサー内部を150℃に加熱して3分間混練した。ここで、ミキサーの形式としては、特に制限されるものではなく、乾留物の性状に適合した物を適宜選択すればよい。   As a result of measuring the calorific value, the calorific value of the dry distillation product was 2800 kcal / kg. Therefore, based on FIG. 2 (a), 53% (weight ratio: external number) of coal (general coal) as the calorific value adjusting material and 15% of tar discharged from the coke oven as a binder (weight ratio: external) Number) was put into the mixer 6 and the inside of the mixer was heated to 150 ° C. and kneaded for 3 minutes. Here, the form of the mixer is not particularly limited, and a mixer suitable for the properties of the dry distillation product may be selected as appropriate.

ミキサー6で混練した混練物は、ダブルロール成型機7に投入し、2t/cmの線圧にて加圧成型し、ブリケットを作成した。成型物は、原料とともに再びシャフト炉式乾留炉1へ戻され、乾留することにより、石炭が軟化溶融し、粒子の結合力が強まり、バインダとともにコークス化することで、強度のある成型コークスが製造できる。   The kneaded material kneaded by the mixer 6 was put into a double roll molding machine 7 and subjected to pressure molding at a linear pressure of 2 t / cm to prepare a briquette. The molded product is returned to the shaft furnace type carbonization furnace 1 together with the raw material, and the coal is softened and melted by the carbonization, the bonding force of the particles is strengthened, and coke with the binder to produce a strong molded coke. it can.

一方、シャフト炉式乾留炉1上部より排出された可燃性ガスは、除じん器9によりガス中の可燃性ダストを固気分離し、分離した可燃性ダストは、節選別機5へ導入され、節下とともに成型し、再び乾留する。可燃性ダストを除去した可燃性ガスは、一部は燃焼炉にて、空気比λ=1.0付近で燃焼させ、その低酸素濃度かつ高温の排ガスをシャフト炉式乾留炉1の下部から吹き込み、乾留熱源とした。また、可燃性ガスの一部は、凝縮器にてタールを回収した後、さらに、触媒にて凝縮できなかったタールを改質した後、ガスエンジン発電機にて発電し、設備の駆動電力として利用した。当然であるが、この可燃性ガスを化学原料として使用することも可能であるし、燃焼後廃熱ボイラに導入して蒸気タービン発電機にて発電する事も可能である。   On the other hand, the combustible gas discharged from the upper part of the shaft furnace type distillation furnace 1 is separated into combustible dust in the gas by the dust remover 9, and the separated combustible dust is introduced into the node sorting machine 5 for saving. Mold with the bottom and dry distillation again. A part of the combustible gas from which combustible dust has been removed is burned in a combustion furnace at an air ratio of about λ = 1.0, and the exhaust gas having a low oxygen concentration and high temperature is blown from the bottom of the shaft furnace type dry distillation furnace 1 A heat source for dry distillation was used. In addition, some of the combustible gas is recovered by using a condenser, then further reforming tar that could not be condensed by a catalyst, and then generating power with a gas engine generator to drive the equipment. used. As a matter of course, this combustible gas can be used as a chemical raw material, or can be introduced into a waste heat boiler after combustion and generated by a steam turbine generator.

スクリューコンベヤ2より排出される乾留残渣は、後のバインダ混練工程にて加熱する必要があるため、排出時の温度がなるべく温度が高いほうがエネルギー節減につながるが、発火の恐れがあるため、排出される乾留残渣は150℃以下に冷却するか、もしくは、スクリューコンベヤ2出口から成形機7出口まで連続して配置し、乾留残渣の通路に気密性を持たせ、内部に例えば窒素のような不活性ガスを封入することで、バインダ混練時の加熱が不要となる。   Since the carbonization residue discharged from the screw conveyor 2 needs to be heated in the subsequent binder kneading process, the higher the temperature at the time of discharge, the more energy is saved. The dry distillation residue is cooled to 150 ° C. or lower, or is continuously arranged from the outlet of the screw conveyor 2 to the outlet of the molding machine 7 so that the passage of the dry distillation residue is airtight, and is inert inside, for example, nitrogen. By enclosing the gas, heating during binder kneading becomes unnecessary.

また、本発明において、各設備のレイアウトは、本実施例のようなレイアウトに制限されるものではなく、立地条件に応じて適宜変更可能であり、例えば、篩選別機5の篩下を気流搬送し、シャフト炉式乾留炉1の上に配置したミキサー6及び成形機7で混練及び加圧成形した成形炭をそのままシャフト炉式乾留炉1に投入することも可能である。     Further, in the present invention, the layout of each facility is not limited to the layout as in the present embodiment, and can be appropriately changed according to the location conditions. For example, the air flow is carried under the sieve of the sieve sorter 5 Then, it is possible to put the charcoal kneaded and pressure-molded by the mixer 6 and the molding machine 7 disposed on the shaft furnace type carbonization furnace 1 as it is into the shaft furnace type carbonization furnace 1.

本実施例では、乾留温度800℃とした。運転開始当初は、篩下しか排出されず、すべて発熱量調整材の石炭及びバインダであるタールと共に成形した後再乾留した。原料装入開始約4時間後より、篩上に製品コークスが残るようになった。シャフト炉式乾留炉の滞留時間はおよそ2時間であることから、本実施例の原料は2回乾留することで成形塊状物として製造可能であることがわかる。ここで、別の原料を使用する場合や、求める粒径が異なる場合は、篩上に残るまでの乾留回数が自然と増減することになるだけで、特別な操作は不要である。   In this example, the carbonization temperature was 800 ° C. At the beginning of the operation, only the sieving was discharged, and all were formed together with coal as the calorific value adjusting material and tar as the binder, and then re-distilled. Product coke remained on the sieve after about 4 hours from the start of raw material charging. Since the residence time of the shaft furnace type carbonization furnace is about 2 hours, it can be seen that the raw material of this example can be produced as a molded lump by dry distillation twice. Here, when another raw material is used or when the required particle size is different, only the number of dry distillation until it remains on the sieve will naturally increase and decrease, and no special operation is required.

本実施例では、本発明の方法で製造した廃棄物溶融炉用コークスを廃棄物溶融炉で使用する例である。一般廃棄物、産業廃棄物等の廃棄物の処理方法として、例えばシャフト炉型の廃棄物溶融炉で廃棄物を乾燥、熱分解、燃焼、溶融して、スラグとメタルにする廃棄物溶融処理がある。   In this embodiment, the waste melting furnace coke produced by the method of the present invention is used in the waste melting furnace. As a method for treating waste such as general waste and industrial waste, for example, there is a waste melting process in which waste is dried, pyrolyzed, burned and melted in a shaft furnace type waste melting furnace to form slag and metal. is there.

図3は、本発明に係る廃棄物溶融炉用コークスを用いた廃棄物処理のための工程概略図である。この図に示すように、廃棄物溶融炉22には、廃棄物が副資材であるコークス、石灰石とともに、炉上部から2重シール弁機構の装入装置23を介して装入され、炉内で乾燥、熱分解、燃焼、溶融の過程を経て出滓口24からはスラグが排出される。廃棄物中の可燃物は、一部が乾留されてガスとなって排出され、また、一部は炉下部で羽口から吹き込まれた空気及び酸素によって燃焼するが、残りの可燃物は可燃性ダストとなって溶融炉22の炉頂から排出される。   FIG. 3 is a process schematic diagram for waste treatment using the waste melting furnace coke according to the present invention. As shown in this figure, the waste melting furnace 22 is charged with waste coke and limestone as auxiliary materials from the top of the furnace via a charging device 23 of a double seal valve mechanism. Slag is discharged from the outlet 24 through the processes of drying, thermal decomposition, combustion, and melting. Some of the combustibles in the waste are carbonized and discharged as gas, and some are combusted by air and oxygen blown from the tuyeres at the bottom of the furnace, while the rest are combustible. It becomes dust and is discharged from the top of the melting furnace 22.

溶融炉22から排出された可燃性ガスと可燃性ダストは、燃焼室25で燃焼され、ボイラー26で熱回収が行われ、発生した蒸気は蒸気タービン・発電装置27へ送られる。ボイラー26の排ガスは、集じん装置28で固気分離され、ブロワ29により煙突30から排出される。廃棄物溶融炉22の炉上部から装入されたコークスは、炉下部に取り付けた下段羽口31から吹き込まれる酸素富化空気により燃焼し、炉下部で高温の火格子を形成することにより、廃棄物中の灰分を溶融し、スラグ化させる。   The combustible gas and combustible dust discharged from the melting furnace 22 are combusted in the combustion chamber 25, heat recovery is performed in the boiler 26, and the generated steam is sent to the steam turbine / power generation device 27. The exhaust gas from the boiler 26 is separated into solid and gas by a dust collector 28 and discharged from a chimney 30 by a blower 29. The coke charged from the upper part of the waste melting furnace 22 is combusted by oxygen-enriched air blown from the lower tuyere 31 attached to the lower part of the furnace, and is discarded by forming a high-temperature grate at the lower part of the furnace. The ash content in the product is melted and made into slag.

本実施例では、廃棄物溶融炉22の炉上部から、実施例1で製造した廃棄物溶融炉用コークスのみもしくは、廃棄物溶融炉用コークスと、塩基度調整材として石灰石を投入し、廃棄物溶融炉22の下段羽口31より酸素富化空気を吹き込んだ。溶融炉の運転条件を表1に示す。

Figure 2010037420
In the present embodiment, only the waste melting furnace coke produced in Example 1 or the waste melting furnace coke and limestone as a basicity adjusting material are introduced from the upper part of the waste melting furnace 22 to produce waste. Oxygen-enriched air was blown from the lower tuyere 31 of the melting furnace 22. Table 1 shows the operating conditions of the melting furnace.
Figure 2010037420

表1の条件で運転したところ、溶融物の排出もスムーズで、安定操業が可能であった。しかし、石灰石を添加しない条件No.1では、スラグの塩基度が0.3程度と低いため、スラグの粘性が高く、溶融物排出をスムーズにするには、羽口から吹き込む酸素富化空気の酸素濃度を4%程度上昇させる必要があった。   When operated under the conditions shown in Table 1, the discharge of the melt was smooth and stable operation was possible. However, condition no. In No. 1, since the basicity of slag is as low as about 0.3, the viscosity of the slag is high, and in order to smoothly discharge the melt, it is necessary to increase the oxygen concentration of the oxygen-enriched air blown from the tuyere by about 4%. was there.

本発明による廃棄物溶融炉用コークスの製造方法を示す工程概略図である。It is process schematic which shows the manufacturing method of the coke for waste melting furnaces by this invention. (a)は1回目の乾留物の発熱量と添加する発熱量調整材(石炭)の添加量の関係を示すグラフ、(b)は1回目の乾留物の配分量と添加する発熱量調整材(石炭)の添加量との関係を示すグラフである。(A) is a graph showing the relationship between the calorific value of the first dry distillation product and the addition amount of the calorific value adjusting material (coal) to be added, (b) is the distribution amount of the first dry distillation product and the calorific value adjusting material to be added. It is a graph which shows the relationship with the addition amount of (coal). 本発明に係る廃棄物溶融炉用コークスを用いた廃棄物処理のための工程概略図である。It is process schematic for the waste processing using the coke for waste melting furnaces which concerns on this invention. 従来の成形塊状物の製造方法を示す工程概略図である。It is process schematic which shows the manufacturing method of the conventional molded lump.

符号の説明Explanation of symbols

1:乾留炉 2:スクリューコンベヤ
3:磁選機 4:選別機
5:篩選別機 6:ミキサー
7:成形機 8:成形物
9:除じん器 10:触媒
11:ガスエンジン発電機 12:分析・測定装置
13:燃焼炉 22:廃棄物溶融炉
23:装入装置 24:出滓口
25:燃焼室 26:ボイラー
27:蒸気タービン・発電装置 28:集じん装置29:ブロワ
30:煙突 31:下段羽口
1: Carbonization furnace 2: Screw conveyor 3: Magnetic separator 4: Sorter 5: Sieve sorter 6: Mixer 7: Molding machine 8: Molded product 9: Dust remover 10: Catalyst 11: Gas engine generator 12: Analysis Measuring device 13: Combustion furnace 22: Waste melting furnace 23: Charging device 24: Outlet 25: Combustion chamber 26: Boiler 27: Steam turbine / power generation device 28: Dust collector 29: Blower 30: Chimney 31: Lower stage Tuyere

Claims (14)

一般廃棄物および/または建築混合廃棄物、下水汚泥、製紙スラッジ、家畜糞などの産業廃棄物の乾留物に発熱量調整材とバインダを添加し、混錬及び加圧成型したものを乾留することを特徴とする廃棄物溶融炉用コークスの製造方法。   Heat-regulating materials and binders are added to industrial waste such as general waste and / or building mixed waste, sewage sludge, paper sludge, and livestock excrement, and then kneaded and pressure-molded. A method for producing coke for a waste melting furnace. 前記発熱量調整材が石炭、オガクズ、稲藁のうちの1種類またはそれらの混合物であり、3mm以下に粉砕したものであることを特徴とする請求項1に記載の廃棄物溶融炉用コークスの製造方法。   2. The waste melting furnace coke according to claim 1, wherein the calorific value adjusting material is one of coal, sawdust, rice straw or a mixture thereof and is pulverized to 3 mm or less. Production method. 前記乾留物の発熱量、固定炭素、灰分、揮発分、炭素含有量の少なくとも1項目を測定・分析し、その結果に応じて、発熱量調整材の添加量を調整することを特徴とする請求項1または2に記載の廃棄物溶融炉用コークスの製造方法。   Measuring and analyzing at least one item of calorific value, fixed carbon, ash, volatile content, and carbon content of the dry distillate, and adjusting the addition amount of the calorific value adjusting material according to the result. Item 3. A method for producing coke for waste melting furnaces according to Item 1 or 2. 前記バインダとしてタール、ピッチ、リグニン、フェノール樹脂、フェノールの少なくとも1種類を使用することを特徴とする請求項1〜3のいずれか1項に記載の廃棄物溶融炉用コークスの製造方法。   The method for producing coke for a waste melting furnace according to any one of claims 1 to 3, wherein at least one of tar, pitch, lignin, phenol resin, and phenol is used as the binder. 乾留時に発生する乾留ガスからタール分を回収し、バインダとすることを特徴とする請求項1〜4のいずれか1項に記載の廃棄物溶融炉用コークスの製造方法。   The method for producing coke for a waste melting furnace according to any one of claims 1 to 4, wherein a tar content is recovered from a dry distillation gas generated during dry distillation and used as a binder. 乾留温度が700〜1200℃であることを特徴とする請求項1〜5のいずれか1項に記載の廃棄物溶融炉用コークスの製造方法。   The method for producing coke for a waste melting furnace according to any one of claims 1 to 5, wherein a carbonization temperature is 700 to 1200 ° C. バインダ添加量が2〜50%(重量比)であることを特徴とする請求項1〜6のいずれか1項に記載の廃棄物溶融炉用コークスの製造方法。   Binder addition amount is 2 to 50% (weight ratio), The manufacturing method of the coke for waste melting furnaces of any one of Claims 1-6 characterized by the above-mentioned. 乾留炉にて原料を乾留し、乾留後の乾留物を篩分けにより分級し、篩下の乾留物に発熱量調整材とバインダを添加し、混練および加圧成型したものを前記乾留炉に戻して、前記原料と共に乾留することを特徴とする請求項1〜7のいずれか1項に記載の廃棄物溶融炉用コークスの製造方法。   The raw material is carbonized in a carbonization furnace, the carbonized product after carbonization is classified by sieving, a calorific value adjusting material and a binder are added to the carbonized product under the sieve, and the kneaded and pressure-molded product is returned to the carbonization furnace. The method for producing coke for a waste melting furnace according to any one of claims 1 to 7, wherein the carbonization is carried out together with the raw material. 乾留炉より発生する可燃性ガスを燃焼させ、乾留炉の熱源とすることを特徴とする請求項1〜8のいずれか1項に記載の廃棄物溶融炉用コークスの製造方法。   The method for producing coke for a waste melting furnace according to any one of claims 1 to 8, wherein combustible gas generated from the carbonization furnace is combusted and used as a heat source for the carbonization furnace. 原料を乾留する乾留炉と、乾留炉から排出した乾留物に発熱量調整材とバインダを添加し混練する混練装置と、混練物を加圧成型する成型機と、成型物を乾留する乾留炉からなることを特徴とする廃棄物溶融炉用コークスの製造装置。   From a carbonization furnace for carbonizing raw materials, a kneading device for adding a calorific value adjusting agent and a binder to the carbonized product discharged from the carbonization furnace, a molding machine for pressure-molding the kneaded material, and a carbonization furnace for carbonizing the molded product An apparatus for producing coke for a waste melting furnace. 原料を乾留して生成した乾留物の発熱量、固定炭素、灰分、揮発分、炭素含有量の少なくとも1項を測定・分析する装置を設置したことを特徴とする請求項10に記載の廃棄物溶融炉用コークスの製造装置。   The waste according to claim 10, wherein a device for measuring and analyzing at least one of calorific value, fixed carbon, ash content, volatile content, and carbon content of the carbonized product produced by carbonizing the raw material is installed. Production equipment for coke for melting furnaces. 原料と乾留する乾留炉と成型物を乾留する乾留炉が同一の乾留炉であり、かつ乾留物を篩分けする篩機を設置し、篩分けした篩下の乾留物を混練機に導入する機構を設けたことを特徴とする請求項10または11に記載の廃棄物溶融炉用コークスの製造装置。   The carbonization furnace for carbonizing the raw material and the carbonized product and the carbonization furnace for carbonizing the molded product are the same carbonization furnace, and a mechanism for sieving the dried product is installed, and the dried product under the screened sieve is introduced into the kneader. The apparatus for producing coke for a waste melting furnace according to claim 10 or 11, wherein: 乾留炉から排出されるガスを導くダクトと導通した乾留ガス燃焼炉と、燃焼炉の排ガスを前記乾留炉に導くためのダクトを設けたことを特徴とする請求項10〜12のいずれか1項に記載の廃棄物溶融炉用コークスの製造装置。   13. A dry distillation gas combustion furnace that is electrically connected to a duct that guides gas discharged from the dry distillation furnace, and a duct that guides exhaust gas from the combustion furnace to the dry distillation furnace. An apparatus for producing coke for a waste melting furnace as described in 1. 請求項1〜8のいずれかに記載の廃棄物溶融炉用コークスの製造方法で製造した廃棄物溶融炉用コークス中の灰分を溶融処理する方法において、廃棄物溶融炉に、廃棄物溶融炉用コークスを単独、または塩基度調整材とともに投入して高温燃焼させて溶融させることを特徴とする廃棄物溶融処理方法。   A method for melting ash content in coke for waste melting furnace produced by the method for producing coke for waste melting furnace according to any one of claims 1 to 8, wherein the waste melting furnace is for waste melting furnace. A waste melting treatment method characterized in that coke is added alone or together with a basicity adjusting material and is burned at a high temperature to be melted.
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