JP2010037182A - Liquid fertilizer - Google Patents

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JP2010037182A
JP2010037182A JP2009061183A JP2009061183A JP2010037182A JP 2010037182 A JP2010037182 A JP 2010037182A JP 2009061183 A JP2009061183 A JP 2009061183A JP 2009061183 A JP2009061183 A JP 2009061183A JP 2010037182 A JP2010037182 A JP 2010037182A
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liquid fertilizer
phosphorous acid
mass
aqueous solution
alkaline compound
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JP5373443B2 (en
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Keitaro Kawamura
啓太郎 川村
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Koei Chemical Co Ltd
Koei Chemical Industry Co Ltd
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Koei Chemical Co Ltd
Koei Chemical Industry Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a new liquid fertilizer having phosphorous acid as the component. <P>SOLUTION: An aqueous solution is obtained by mixing 20-40 pts.mass of phosphorous acid and 10 pts.mass of an alkaline compound. Monopotassium phosphate may be added. Since the presence of the alkaline compound results in a greater pH value (i.e. shifted to the alkaline side) of the aqueous solution than that of an aqueous solution of phosphorous acid alone, the aqueous solution dissolves phosphorous acid at a higher concentration than the one containing only phosphorous acid. The solution, therefore, makes a liquid fertilizer containing phosphorous acid at a high concentration. The liquid fertilizer may be used without being diluted or after being diluted e.g. 10-1,000 times. Foliar application and root drench are possible. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、液体肥料の技術分野に属する。   The present invention belongs to the technical field of liquid fertilizers.

リン(P)は肥料の3要素の一つとして知られ、例えばリン酸、亜リン酸等の形態で使用されてきた。リン酸肥料の肥効としては、発根・分けつ促進、着果・着色促進、細胞皮(膜)の硬化促進、病気への抵抗力強化などが知られている。   Phosphorus (P) is known as one of the three elements of fertilizer, and has been used in the form of phosphoric acid, phosphorous acid, and the like. Known fertilizer effects of phosphate fertilizer include rooting / sharing promotion, fruit set / coloring promotion, cell skin (film) hardening, and disease resistance enhancement.

特開2006−28000号公報には、亜リン酸が含まれる水溶液を肥料として使用する技術が開示されている。   Japanese Patent Application Laid-Open No. 2006-28000 discloses a technique of using an aqueous solution containing phosphorous acid as a fertilizer.

特開2006−28000号公報JP 2006-28000 A

亜リン酸の水溶液を葉面に散布すると葉面から直接吸収されるので、その点では散布効率が良いと言える。
一方、単に亜リン酸の水溶液を調製しただけでは、濃度に不満がある場合もあった。
When an aqueous solution of phosphorous acid is sprayed on the leaf surface, it is absorbed directly from the leaf surface, and in this respect, it can be said that the spraying efficiency is good.
On the other hand, there were cases where the concentration was unsatisfactory simply by preparing an aqueous solution of phosphorous acid.

請求項1記載の液体肥料は、
亜リン酸と、
アルカリ性化合物と
を溶質とした水溶液であることを特徴とする。
The liquid fertilizer according to claim 1,
With phosphorous acid,
It is an aqueous solution in which an alkaline compound is used as a solute.

請求項2記載の液体肥料は、
前記2成分の他にリン酸一カリウムをも溶質とした水溶液であることを特徴とする請求項1記載の液体肥料である。
The liquid fertilizer according to claim 2
The liquid fertilizer according to claim 1, wherein the liquid fertilizer is an aqueous solution containing not only the two components but also monopotassium phosphate as a solute.

請求項3記載の液体肥料は、
液体肥料全体に占めるアルカリ性化合物の配合比が4〜10質量%であることを特徴とする請求項1又は2記載の液体肥料である。
The liquid fertilizer according to claim 3
The liquid fertilizer according to claim 1 or 2, wherein the blending ratio of the alkaline compound in the entire liquid fertilizer is 4 to 10% by mass.

請求項4記載の液体肥料は、
アルカリ性化合物を10質量部としたときに
亜リン酸が20〜40質量部であることを特徴とする請求項1、2又は3記載の液体肥料である。
The liquid fertilizer according to claim 4 is:
The liquid fertilizer according to claim 1, wherein phosphorous acid is 20 to 40 parts by mass when the alkaline compound is 10 parts by mass.

請求項5記載の液体肥料は、
リン酸一カリウムを10質量部としたときに
亜リン酸が20〜30質量部であることを特徴とする請求項2又は請求項2を引用する請求項3もしくは4記載の液体肥料である。
The liquid fertilizer according to claim 5 is:
The liquid fertilizer according to claim 3 or 4, wherein phosphorous acid is 20 to 30 parts by mass when monopotassium phosphate is 10 parts by mass.

請求項6記載の液体肥料は、
アルカリ性化合物が水酸化カルシウムであることを特徴とする請求項1〜5のいずれか記載の液体肥料である。
The liquid fertilizer according to claim 6 is:
The liquid fertilizer according to any one of claims 1 to 5, wherein the alkaline compound is calcium hydroxide.

本発明に使用されるアルカリ性化合物とは、その水溶液がアルカリ性となる化合物で、言うまでもなく水溶性である。
具体的な例としては、請求項6に記載の水酸化カルシウムを挙げることができる。また、水酸化ナトリウム、水酸化カリウム等の金属水酸化物も好適である。なお、複数種類のアルカリ性化合物を混用することもできる。
The alkaline compound used in the present invention is a compound in which the aqueous solution becomes alkaline, and needless to say, it is water-soluble.
As a specific example, the calcium hydroxide of Claim 6 can be mentioned. Metal hydroxides such as sodium hydroxide and potassium hydroxide are also suitable. A plurality of types of alkaline compounds can be mixed.

亜リン酸と、アルカリ性化合物とを溶質とした水溶液では、アルカリ性化合物の存在により、亜リン酸の単独の水溶液よりもpH値が大きくなる(すなわち、アルカリ性側に変位する)。すると、亜リン酸単独の場合よりも高濃度で亜リン酸を溶解させることができる。   In an aqueous solution containing phosphorous acid and an alkaline compound as a solute, the pH value is larger than that of an aqueous solution of phosphorous acid alone (ie, displaced to the alkaline side) due to the presence of the alkaline compound. Then, phosphorous acid can be dissolved at a higher concentration than in the case of phosphorous acid alone.

請求項1記載の液体肥料にあっては、亜リン酸とアルカリ性化合物との2成分の他に、肥料成分を添加することもできる。請求項2に記載のリン酸一カリウムが、その一例である。リン酸一カリウムは、リン酸肥料かつカリウム肥料としての肥効がある。   In the liquid fertilizer according to claim 1, a fertilizer component may be added in addition to the two components of phosphorous acid and an alkaline compound. The monopotassium phosphate according to claim 2 is an example. Monopotassium phosphate has a fertilizing effect as a phosphate fertilizer and potassium fertilizer.

なお、リン酸一カリウムの好ましい配合比は請求項5記載の配合比、すなわちリン酸一カリウムを10質量部としたときに亜リン酸が20〜30質量部となる範囲が好ましい。
本発明の液体肥料は、根本は亜リン酸肥料であり、アルカリ性化合物はいわば助剤であるから、その配合比が過剰又は過少になるのは好ましくない。使用するアルカリ性化合物の種類にもよるが、一般的には請求項3に記載の配合比、すなわち液体肥料全体に占めるアルカリ性化合物の配合比が4〜10質量%が好ましい。
The preferable blending ratio of monopotassium phosphate is preferably the blending ratio according to claim 5, that is, the range in which phosphorous acid is 20 to 30 parts by mass when the monopotassium phosphate is 10 parts by mass.
Since the liquid fertilizer of the present invention is basically a phosphite fertilizer and the alkaline compound is an auxiliary agent, it is not preferable that the mixing ratio is excessive or too small. Although it depends on the kind of the alkaline compound to be used, generally, the blending ratio according to claim 3, that is, the blending ratio of the alkaline compound in the entire liquid fertilizer is preferably 4 to 10% by mass.

また、アルカリ性化合物の好ましい配合比は亜リン酸との比率によって規定することもでき、その場合は請求項4記載の配合比、すなわちアルカリ性化合物を10質量部としたときに亜リン酸が20〜40質量部となる範囲が好ましい。
[実施例]
下記の表1に示す配合比で液体肥料を調製した。この液体肥料は、そのまま希釈せずに使用してもよいが、通常は10倍〜1000倍に希釈して葉面散布や株もとに灌注する形態で使用される。
Moreover, the preferable compounding ratio of an alkaline compound can also be prescribed | regulated by the ratio with phosphorous acid, In that case, when the compounding ratio of Claim 4, ie, 10 mass parts of alkaline compounds, phosphorous acid is 20- A range of 40 parts by mass is preferred.
[Example]
A liquid fertilizer was prepared with the blending ratio shown in Table 1 below. Although this liquid fertilizer may be used without being diluted as it is, it is usually used in a form in which it is diluted 10-fold to 1000-fold and applied to the foliar surface or irrigated to the base.

Figure 2010037182
[施用実験]
実施例(表1)の液体肥料をウンシュウミカンに施用して、その果実品質に及ぼす影響を調査した。
試験方法
1)供試品種:「青島温州」 青島温州28年生樹(交互結実、シートマルチ栽培樹)
2)試験区:散布区(実施例の液体肥料の1000倍希釈液を散布)、無処理
3)散布月日:2008年10月20日、10月29日、11月7日、11月20日
4)処理区:樹冠散布;1区1樹6反復
5)調査日:収穫;12月22日 着色、果汁内容;12月25日 果皮障害果;12月28日
6)調査結果:表2に示す通り。
Figure 2010037182
[Application experiment]
The liquid fertilizer of an Example (Table 1) was applied to Satsuma mandarin, and the influence on the fruit quality was investigated.
Test method 1) Test variety: “Qingdao Wenzhou” Qingdao Wenzhou 28-year-old tree (alternative fruiting, sheet cultivated tree)
2) Test plot: spray plot (spread with 1000-fold diluted liquid fertilizer of the example), no treatment 3) spray date: October 20, 2008, October 29, November 7, November 20 Day 4) Treatment area: tree spraying; 1st area 1 tree 6 repetitions 5) Investigation day: Harvest; December 22 Coloring, fruit juice content: December 25 Pericarp fruit; December 28 6) Investigation result: Table 2 As shown in

Figure 2010037182
表2に示すとおり、実施例の液体肥料には糖度向上効果及び浮皮軽減効果が認められた。
Figure 2010037182
As shown in Table 2, the liquid fertilizer of the examples was found to have an effect of improving sugar content and an effect of reducing skin float.

Claims (6)

亜リン酸と、
アルカリ性化合物と
を溶質とした水溶液であることを特徴とする液体肥料。
With phosphorous acid,
A liquid fertilizer characterized by being an aqueous solution having an alkaline compound as a solute.
前記2成分の他にリン酸一カリウムをも溶質とした水溶液であることを特徴とする請求項1記載の液体肥料。   The liquid fertilizer according to claim 1, wherein the liquid fertilizer is an aqueous solution containing monopotassium phosphate as a solute in addition to the two components. 液体肥料全体に占めるアルカリ性化合物の配合比が4〜10質量%であることを特徴とする請求項1又は2記載の液体肥料。   The liquid fertilizer according to claim 1 or 2, wherein the compounding ratio of the alkaline compound in the entire liquid fertilizer is 4 to 10% by mass. アルカリ性化合物を10質量部としたときに
亜リン酸が20〜40質量部であることを特徴とする請求項1、2又は3記載の液体肥料。
The liquid fertilizer according to claim 1, 2, or 3, wherein phosphorous acid is 20 to 40 parts by mass when the alkaline compound is 10 parts by mass.
リン酸一カリウムを10質量部としたときに
亜リン酸が20〜30質量部であることを特徴とする請求項2又は請求項2を引用する請求項3もしくは4記載の液体肥料。
The liquid fertilizer according to claim 3 or 4, wherein phosphorous acid is 20 to 30 parts by mass when monopotassium phosphate is 10 parts by mass.
アルカリ性化合物が水酸化カルシウムであることを特徴とする請求項1〜5のいずれか記載の液体肥料。   The liquid fertilizer according to any one of claims 1 to 5, wherein the alkaline compound is calcium hydroxide.
JP2009061183A 2008-07-11 2009-03-13 Liquid fertilizer for Citrus unshiu Expired - Fee Related JP5373443B2 (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102826883A (en) * 2012-06-18 2012-12-19 中化(烟台)作物营养有限公司 Deflocculating humic acid liquid water soluble fertilizer and preparation method thereof
JP2013014496A (en) * 2011-06-06 2013-01-24 Koei Kagaku Kogyo Kk Fertilizer for wetland rice and method for wetland rice culture
CN103073348A (en) * 2012-11-12 2013-05-01 北京依科曼生物技术有限公司 Compound water soluble fertilizer used for citrus crops, preparation method and application method
CN103739352A (en) * 2013-12-10 2014-04-23 邵阳柳创农化有限公司 Citrus leaf retention agent and using method
CN104892146A (en) * 2015-05-24 2015-09-09 何政学 Fertilizer applicable to application in fruit swelling period of orange trees and preparation method of fertilizer
CN108129237A (en) * 2018-01-16 2018-06-08 湖南农业大学 A kind of liquid fertilizer for promoting plant root growth and preparation method thereof

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04202080A (en) * 1990-11-30 1992-07-22 Mitsubishi Gas Chem Co Inc Fertilizer for foliage dressing
JPH08149924A (en) * 1994-11-30 1996-06-11 Otsuka Chem Co Ltd Method for supplying calcium supplying agent
JP2000264802A (en) * 1999-03-17 2000-09-26 Sankyo Co Ltd Fertilizer for increasing efficacy of microbicide
JP2001206796A (en) * 1999-11-15 2001-07-31 Denki Kagaku Kogyo Kk Liquid calcium fertilizer
JP2004307359A (en) * 2003-04-02 2004-11-04 Koei Kagaku Kogyo Kk Plant growth regulator
JP2006028000A (en) * 2004-07-21 2006-02-02 Nippon Iyakuhin Kaihatsu Kenkyusho:Kk Method of manufacturing fertilizer composition
JP2006176390A (en) * 2004-10-12 2006-07-06 Biagro Western Sales Inc High calcium fertilizer composition
JP2008074750A (en) * 2006-09-20 2008-04-03 Koei Kagaku Kogyo Kk Rind puffing inhibitor of citrus fruit
JP2008143879A (en) * 2006-12-07 2008-06-26 Maruwa Biochemical Co Ltd Manure to increase axillary bud

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04202080A (en) * 1990-11-30 1992-07-22 Mitsubishi Gas Chem Co Inc Fertilizer for foliage dressing
JPH08149924A (en) * 1994-11-30 1996-06-11 Otsuka Chem Co Ltd Method for supplying calcium supplying agent
JP2000264802A (en) * 1999-03-17 2000-09-26 Sankyo Co Ltd Fertilizer for increasing efficacy of microbicide
JP2001206796A (en) * 1999-11-15 2001-07-31 Denki Kagaku Kogyo Kk Liquid calcium fertilizer
JP2004307359A (en) * 2003-04-02 2004-11-04 Koei Kagaku Kogyo Kk Plant growth regulator
JP2006028000A (en) * 2004-07-21 2006-02-02 Nippon Iyakuhin Kaihatsu Kenkyusho:Kk Method of manufacturing fertilizer composition
JP2006176390A (en) * 2004-10-12 2006-07-06 Biagro Western Sales Inc High calcium fertilizer composition
JP2008074750A (en) * 2006-09-20 2008-04-03 Koei Kagaku Kogyo Kk Rind puffing inhibitor of citrus fruit
JP2008143879A (en) * 2006-12-07 2008-06-26 Maruwa Biochemical Co Ltd Manure to increase axillary bud

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013014496A (en) * 2011-06-06 2013-01-24 Koei Kagaku Kogyo Kk Fertilizer for wetland rice and method for wetland rice culture
CN102826883A (en) * 2012-06-18 2012-12-19 中化(烟台)作物营养有限公司 Deflocculating humic acid liquid water soluble fertilizer and preparation method thereof
CN103073348A (en) * 2012-11-12 2013-05-01 北京依科曼生物技术有限公司 Compound water soluble fertilizer used for citrus crops, preparation method and application method
CN103739352A (en) * 2013-12-10 2014-04-23 邵阳柳创农化有限公司 Citrus leaf retention agent and using method
CN104892146A (en) * 2015-05-24 2015-09-09 何政学 Fertilizer applicable to application in fruit swelling period of orange trees and preparation method of fertilizer
CN108129237A (en) * 2018-01-16 2018-06-08 湖南农业大学 A kind of liquid fertilizer for promoting plant root growth and preparation method thereof

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