JP2009500466A5 - - Google Patents

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JP2009500466A5
JP2009500466A5 JP2008519015A JP2008519015A JP2009500466A5 JP 2009500466 A5 JP2009500466 A5 JP 2009500466A5 JP 2008519015 A JP2008519015 A JP 2008519015A JP 2008519015 A JP2008519015 A JP 2008519015A JP 2009500466 A5 JP2009500466 A5 JP 2009500466A5
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fuel
compounds
additive composition
iron
mixtures
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（ｉ）鉄化合物、マンガン化合物、カルシウム化合物、セリウム化合物及びそれらの混合物から選択される金属化合物；並びに、
（ii）二環式モノテルペン、置換二環式モノテルペン、アダマンタン、プロピレンカーボネート及びそれらの混合物から選択される有機化合物
を含む燃料用添加剤組成物であって、
前記添加剤組成物が、少なくとも１００ｐｐｍの有機化合物（ii）を含むことを特徴とする燃料用添加剤組成物。 (I) a metal compound selected from iron compounds, manganese compounds, calcium compounds, cerium compounds and mixtures thereof; and
(Ii) A fuel additive composition comprising an organic compound selected from bicyclic monoterpenes, substituted bicyclic monoterpenes, adamantane, propylene carbonate and mixtures thereof,
The additive composition for fuels, wherein the additive composition contains at least 100 ppm of the organic compound (ii). さらに溶媒を含むことを特徴とする請求項１記載の燃料用添加剤組成物。 The fuel additive composition according to claim 1, further comprising a solvent. 溶媒が、芳香族化合物、パラフィン化合物及びそれらの混合物から選択されることを特徴とする請求項２記載の燃料用添加剤組成物。 3. The fuel additive composition according to claim 2, wherein the solvent is selected from aromatic compounds, paraffin compounds, and mixtures thereof. 添加剤組成物が、３ｐｐｍ〜３０，０００ｐｐｍの金属を提供するのに十分な量の金属化合物（ｉ）を含むことを特徴とする請求項１〜３のいずれか記載の燃料用添加剤組成物。 The additive composition for fuel according to any one of claims 1 to 3, wherein the additive composition contains an amount of the metal compound (i) sufficient to provide 3 ppm to 30,000 ppm of metal. . 添加剤組成物が、１００ｐｐｍ〜７００，０００ｐｐｍの有機化合物（ii）を含むことを特徴とする請求項１〜４のいずれか記載の燃料用添加剤組成物。 The additive composition for fuel according to any one of claims 1 to 4, wherein the additive composition contains 100 ppm to 700,000 ppm of an organic compound (ii). 請求項１〜５のいずれか記載の添加剤組成物及び燃料を含む燃料組成物。 A fuel composition comprising the additive composition according to any one of claims 1 to 5 and a fuel. 添加剤組成物と燃料との比率が、１：１００〜１：１０，０００であることを特徴とする請求項６記載の燃料組成物。 The fuel composition according to claim 6, wherein the ratio of the additive composition to the fuel is 1: 100 to 1: 10,000. 以下を含む燃料組成物：
（ｉ）鉄化合物、マンガン化合物、カルシウム化合物、セリウム化合物及びそれらの混合物から選択される金属化合物；
（ii）二環式モノテルペン、置換二環式モノテルペン、アダマンタン、プロピレンカーボネート及びそれらの混合物から選択される有機化合物；並びに、
（iii）バイオ燃料、ディーゼル、船舶用燃料、暖房用灯油、中間蒸留油及び重油から選択される燃料。 Fuel composition comprising:
(I) a metal compound selected from iron compounds, manganese compounds, calcium compounds, cerium compounds and mixtures thereof;
(Ii) an organic compound selected from bicyclic monoterpenes, substituted bicyclic monoterpenes, adamantane, propylene carbonate and mixtures thereof; and
(Iii) Fuel selected from biofuel, diesel, marine fuel, heating kerosene, middle distillate oil and heavy oil. （ｉ）鉄化合物、マンガン化合物、カルシウム化合物、セリウム化合物及びそれらの混合物から選択される金属化合物；
（ii）二環式モノテルペン、置換二環式モノテルペン、アダマンタン、プロピレンカーボネート及びそれらの混合物から選択される有機化合物；並びに、
（iii）燃料
を含む燃料組成物を提供するステップ；並びに、
排気中の煤分及び灰分が減少するように前記燃料組成物を燃焼させるステップ
を含む、排気を伴う燃焼系中で燃料組成物を燃焼させる方法。 (I) a metal compound selected from iron compounds, manganese compounds, calcium compounds, cerium compounds and mixtures thereof;
(Ii) an organic compound selected from bicyclic monoterpenes, substituted bicyclic monoterpenes, adamantane, propylene carbonate and mixtures thereof; and
(Iii) providing a fuel composition comprising fuel; and
A method of combusting a fuel composition in a combustion system with exhaust, comprising the step of combusting the fuel composition so as to reduce soot and ash in the exhaust. 少なくとも０．０３ｐｐｍの金属を提供するのに十分な量の金属化合物（ｉ）を含むことを特徴とする請求項６〜８のいずれか記載の燃料組成物。 9. The fuel composition according to any one of claims 6 to 8 , comprising a sufficient amount of the metal compound (i) to provide at least 0.03 ppm of metal. ２．４０ｐｐｍ以下の金属を提供する量の金属化合物（ｉ）を含むことを特徴とする請求項６〜８及び１０のいずれか記載の燃料組成物。 11. A fuel composition according to any one of claims 6 to 8 and 10, comprising an amount of metal compound (i) that provides no more than 2.40 ppm of metal. ７０ｐｐｍ以下の有機化合物（ii）を含むことを特徴とする請求項６〜８及び１０〜１１のいずれか記載の燃料組成物。 The fuel composition according to any one of claims 6 to 8, and 10 to 11, comprising 70 ppm or less of an organic compound (ii). 少なくとも１ｐｐｍの有機化合物（ii）を含むことを特徴とする請求項６〜８及び１０〜１２のいずれか記載の燃料組成物。 The fuel composition according to any one of claims 6 to 8 and 10 to 12, comprising at least 1 ppm of an organic compound (ii). １０ｐｐｍ〜６０ｐｐｍの有機化合物（ii）を含むことを特徴とする請求項６〜８及び１０〜１３のいずれか記載の燃料組成物。 The fuel composition according to any one of claims 6-8 and 10-13, characterized in that it comprises 1 0Ppm～60ppm organic compound of (ii). 燃料燃焼系の排気中の煤分及び灰分を減少させるための、以下の使用：
（ｉ）鉄化合物、マンガン化合物、カルシウム化合物、セリウム化合物及びそれらの混合物から選択される金属化合物；並びに、
（ii）二環式モノテルペン、置換二環式モノテルペン、アダマンタン、プロピレンカーボネート及びそれらの混合物から選択される有機化合物。 The following uses to reduce soot and ash in the exhaust of fuel combustion systems:
(I) a metal compound selected from iron compounds, manganese compounds, calcium compounds, cerium compounds and mixtures thereof; and
(Ii) An organic compound selected from bicyclic monoterpenes, substituted bicyclic monoterpenes, adamantane, propylene carbonate and mixtures thereof. 金属化合物（ｉ）が、鉄化合物及びそれらの混合物から選択されることを特徴とする請求項１〜５のいずれか記載の添加剤組成物。 The additive composition according to any one of claims 1 to 5 , wherein the metal compound (i) is selected from iron compounds and mixtures thereof . 鉄化合物が、ビス−シクロペンタジエニル鉄、置換ビス−シクロペンタジエニル鉄、鉄タレート及びそれらの混合物から選択される鉄錯体であることを特徴とする請求項１６記載の添加剤組成物。 17. The additive composition according to claim 16, wherein the iron compound is an iron complex selected from bis-cyclopentadienyl iron, substituted bis-cyclopentadienyl iron, iron tartrate and mixtures thereof . 金属化合物（ｉ）が、ビス−シクロペンタジエニル鉄であることを特徴とする請求項１６記載の添加剤組成物。 The additive composition according to claim 16, wherein the metal compound (i) is bis-cyclopentadienyl iron. 鉄化合物が、アダマンチルビス−シクロペンタジエニル鉄、ビス（ジシクロペンタジエニル鉄）ジカルボニル及びそれらの混合物から選択される置換ビス−シクロペンタジエニル鉄であることを特徴とする請求項１６記載の添加剤組成物。 17. The iron compound is a substituted bis-cyclopentadienyl iron selected from adamantyl bis-cyclopentadienyl iron, bis (dicyclopentadienyl iron) dicarbonyl, and mixtures thereof. The additive composition described. 有機化合物（ii）が、ショウノウ、カンフェン、酢酸イソボルニル、ジプロピレングリコール−イソボルニルエーテル及びそれらの混合物から選択される二環式モノテルペン又は置換二環式モノテルペンであることを特徴とする請求項１〜５又は１６〜１９のいずれか記載の添加剤組成物。 The organic compound (ii) is a bicyclic monoterpene or a substituted bicyclic monoterpene selected from camphor, camphene, isobornyl acetate, dipropylene glycol-isobornyl ether and mixtures thereof The additive composition in any one of claim | item 1 -5 or 16-19 . 有機化合物（ii）が、ショウノウであることを特徴とする請求項１〜５又は１６〜２０のいずれか記載の添加剤組成物。 The additive composition according to any one of claims 1 to 5, or 16 to 20, wherein the organic compound (ii) is camphor. 金属化合物（ｉ）がビス−シクロペンタジエニル鉄であり、有機化合物（ii）がショウノウであることを特徴とする請求項１〜５のいずれか記載の添加剤組成物。 The additive composition according to any one of claims 1 to 5 , wherein the metal compound (i) is bis-cyclopentadienyl iron and the organic compound (ii) is camphor. 金属化合物（ｉ）と有機化合物（ii）との比率が、９：１〜１：７００であることを特徴とする請求項１〜５又は１６〜２２のいずれか記載の添加剤組成物。 The additive composition according to any one of claims 1 to 5 or 16 to 22, wherein the ratio of the metal compound (i) to the organic compound (ii) is 9: 1 to 1: 700. 金属化合物（ｉ）により提供される金属と有機化合物（ii）との比率が、６：１０〜３：１０００であることを特徴とする請求項１〜５又は１６〜２３のいずれか記載の添加剤組成物。 The ratio of metal compound metal and an organic compound provided by the (i) and (ii), 6: 10-3: addition of any one of claims 1-5 or 16-23, characterized in that the 1000 Agent composition . 請求項１６〜２４のいずれか記載の添加剤組成物と燃料とを含むことを特徴とする燃料組成物。 A fuel composition comprising the additive composition according to any one of claims 16 to 24 and a fuel. 請求項６〜８、１０〜１４及び２５のいずれか記載の燃料を提供し、排気中の煤分及び灰分が減少するように前記燃料を燃焼させることを特徴とする排気を伴う燃焼系中で燃料組成物を燃焼させる方法。
 A fuel system according to any one of claims 6 to 8, 10 to 14 and 25, wherein the fuel is combusted so as to reduce soot and ash in the exhaust. A method of burning a fuel composition .
JP2008519015A 2005-07-07 2006-07-06 Composition Active JP5555423B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102005032119A DE102005032119A1 (en) 2005-07-07 2005-07-07 Russarm burning fuel oil
DE102005032119.4 2005-07-07
PCT/IB2006/002243 WO2007007191A1 (en) 2005-07-07 2006-07-06 Composition

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JP2009500466A JP2009500466A (en) 2009-01-08
JP2009500466A5 true JP2009500466A5 (en) 2009-07-30
JP5555423B2 JP5555423B2 (en) 2014-07-23

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CN (1) CN101258226B (en)
AU (1) AU2006268005B2 (en)
DE (1) DE102005032119A1 (en)
HK (1) HK1114631A1 (en)
SG (1) SG170800A1 (en)
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Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007001987A1 (en) 2005-07-07 2008-07-10 Innospec Deutschland Gmbh Use of a hydrocarbon mixture according to the parent of this application as a fuel for oil-burning installations
GB0700534D0 (en) * 2007-01-11 2007-02-21 Innospec Ltd Composition
WO2009013536A2 (en) * 2007-07-20 2009-01-29 Innospec Limited Improvements in or relating to hydrocarbon compositions
WO2009035658A1 (en) * 2007-09-13 2009-03-19 Timburn, Inc. Method for reducing flammable creosote and other organic deposits in fireboxes
GB0821603D0 (en) * 2008-11-26 2008-12-31 Innospec Ltd Improvements in or relating to fuel additive compositions
JP2010163529A (en) * 2009-01-15 2010-07-29 Taihokohzai:Kk Fuel additive
DE102009020544A1 (en) 2009-05-08 2010-11-11 Heinrich-Heine-Universität Düsseldorf Preparing a copolymer, useful to produce e.g. plastics, comprises providing a cyclodextrin compound, providing a metallocene compound with double bonds and providing a styrene compound, adding an initiator and polymerizing components
WO2012021640A1 (en) * 2010-08-10 2012-02-16 Best Tech Brands Llc Diesel fuel combustion enhancing additive
KR101537159B1 (en) * 2013-08-13 2015-07-16 금종자원개발주식회사 The Ion-fuel (Addition in the air fuel)
DE102014113817A1 (en) 2013-10-15 2015-04-16 Electronics And Telecommunications Research Institute Device and method for recognizing an object in an image
RU2756770C1 (en) * 2020-10-19 2021-10-05 Акционерное Общество «Кемико» Depressor-dispersing additive for diesel fuels and method for production thereof
KR20240035547A (en) 2021-07-16 2024-03-15 이노스펙 리미티드 Fuel oil compositions, and methods and uses related thereto

Family Cites Families (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3127351A (en) 1964-03-31 Xxvii
US2680756A (en) 1952-06-03 1954-06-08 Du Pont Dicyclopentadienyliron and process of making the same
FR1083936A (en) 1952-10-01 1955-01-13 Du Pont Process for manufacturing cyclopentadienyl compounds
US2769828A (en) 1953-01-02 1956-11-06 California Research Corp Production of iron biscyclopentadienyl
US2834796A (en) 1953-03-02 1958-05-13 California Research Corp Preparation of iron cyclopentadienides
US3341311A (en) 1953-07-27 1967-09-12 Du Pont Liquid hydrocarbon fuels
GB763550A (en) 1953-11-02 1956-12-12 Bataafsche Petroleum Dialkyl and diacyl derivatives of ferrocene and processes for the preparation thereof
US2804468A (en) 1954-03-23 1957-08-27 Du Pont Preparation of dicyclopentadienyliron compounds
US2898360A (en) 1954-05-17 1959-08-04 Phillips Petroleum Co Production of dicyclopentadienyl iron
US2828417A (en) 1954-11-12 1958-03-25 Monroe Calculating Machine Clamping circuit means
US2818417A (en) 1955-07-11 1957-12-31 Ethyl Corp Cyclomatic compounds
US2898354A (en) 1955-07-11 1959-08-04 Ethyl Corp Process for the preparation of cyclomatic manganese tricarbonyls
US2959604A (en) 1956-10-03 1960-11-08 Ethyl Corp Cyclomatic compounds
US2868816A (en) 1956-11-08 1959-01-13 Ethyl Corp Process for the preparation of cyclopentadienyl manganese tricarbonyl compounds
US2960514A (en) 1957-07-24 1960-11-15 Ethyl Corp Manufacture of cyclopentadienyl manganese carbonyl compounds
US3042693A (en) 1957-10-18 1962-07-03 Ethyl Corp Organometallic compounds
US2987529A (en) 1958-04-25 1961-06-06 Ethyl Corp Use of transition metal carbonyls in the manufacture of cyclopentadienyl manganese tricarbonyl
US3007953A (en) 1959-03-26 1961-11-07 Ethyl Corp Aryl manganese carbonyl compounds and process
US3437634A (en) 1964-06-01 1969-04-08 Mc Donnell Douglas Corp Reactive ferrocene polymers
US3925031A (en) 1970-07-23 1975-12-09 Eugenio G Villacampa Fuel and oil additive
DE2147994A1 (en) 1970-09-29 1972-03-30 Gino Bologna Maccaferri (Italien) Additive to the combustion air of internal combustion engines
JPS49105805A (en) * 1973-01-18 1974-10-07
SU514885A1 (en) * 1974-12-02 1976-05-25 Fuel composition
US4370147A (en) 1979-10-01 1983-01-25 Horizon Chemical, Inc. Fuel for compression ignition engines
US4265639A (en) 1980-03-20 1981-05-05 Scholtz Myndert T Combustion catalysts
US4389220A (en) 1980-06-04 1983-06-21 Syntex (U.S.A.) Inc. Method of conditioning diesel engines
IT1179351B (en) 1980-07-07 1987-09-16 Mario Scifoni COMBUSTIBLE MIXTURE
DE3418648A1 (en) 1984-05-18 1985-11-21 TUNAP Industrie Chemie GmbH & Co Produktions KG, 8190 Wolfratshausen Method and device for optimising fuel-oil combustion
DE3504934A1 (en) * 1985-02-13 1986-08-14 Am Produkte Ag ADDITIVES TO FUELS AND FUELS
US4673412A (en) 1985-09-24 1987-06-16 The Lubrizol Corporation Fuel additive comprising a metal compound and an oxime and fuel compositions containing same
US5116390A (en) 1986-08-21 1992-05-26 Carlos Rodriguez Catalytically enhanced combustion process
ES2060058T3 (en) * 1990-09-20 1994-11-16 Ethyl Petroleum Additives Ltd HYDROCARBON FUEL COMPOSITIONS AND ADDITIVES FOR THEM.
GB2248068A (en) 1990-09-21 1992-03-25 Exxon Chemical Patents Inc Oil compositions and novel additives
GB2254610B (en) 1991-04-02 1994-10-05 Ass Octel Method for the preparation of aquo and other small protic lewis base complexes of metal salts of organic acids
US5344467A (en) 1991-05-13 1994-09-06 The Lubrizol Corporation Organometallic complex-antioxidant combinations, and concentrates and diesel fuels containing same
DE69319899T2 (en) 1992-10-22 1998-12-10 Akcionernoe Obscestvo Achinskij Neftepererabatyvajuscij Zavod, Achinski FUEL CONNECTION FOR INTERNAL COMBUSTION ENGINES
RU2105041C1 (en) * 1993-08-31 1998-02-20 Александр Петрович Ильин Motor fuel-based fuel composition
CN1073146C (en) * 1997-01-14 2001-10-17 孙黎 Water-base fuel oil and its synthetic process
JP2002509180A (en) 1998-01-15 2002-03-26 ジ アソシエーテッド オクテル カンパニー リミテッド Fuel additive
AU8604001A (en) 2000-08-31 2002-03-13 Ass Octel Compositions comprising dimeric or oligomeric ferrocenes
DE10043144C1 (en) 2000-08-31 2001-12-13 Octel Deutschland Gmbh Use of solutions of 2,2-bisferrocenylalkanes in an aromatic solvent as combustion-promoting diesel fuel additives
CN1325945A (en) * 2001-07-11 2001-12-12 李鸿图 Oil-saving additive of diesel oil
DE10208326B4 (en) 2002-02-27 2008-06-19 Innospec Deutschland Gmbh Additives for liquid fuels
JP4081005B2 (en) 2001-08-30 2008-04-23 ザ アソーシエーテッド オクテル カンパニー リミテッド Composition
KR100440724B1 (en) * 2001-12-26 2004-07-21 주식회사 세인트크로스 Composition of lamp fuel for colored flames and manufacturing method thereof
US6948926B2 (en) 2002-02-04 2005-09-27 Clean Diesel Technologies, Inc. Reduced-emissions combustion utilizing multiple-component metallic combustion catalyst
CN1544583A (en) * 2003-11-14 2004-11-10 哈尔滨宏浩新能源实业有限公司 Oil-saving diesel additive
CN1204234C (en) * 2003-12-11 2005-06-01 孙怀道 Highly effective diesel fuel additive and its production method
CN1236023C (en) * 2004-07-31 2006-01-11 于雷 Cleaning gasoline with alcohol ether base
EP1954788B1 (en) * 2005-11-18 2013-09-18 Ferox, Inc. Biphenyl carrier for ferrocene catalysts and methods of using the same

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