DE102007001987A1 - Use of a hydrocarbon mixture according to the parent of this application as a fuel for oil-burning installations - Google Patents
Use of a hydrocarbon mixture according to the parent of this application as a fuel for oil-burning installations Download PDFInfo
- Publication number
- DE102007001987A1 DE102007001987A1 DE200710001987 DE102007001987A DE102007001987A1 DE 102007001987 A1 DE102007001987 A1 DE 102007001987A1 DE 200710001987 DE200710001987 DE 200710001987 DE 102007001987 A DE102007001987 A DE 102007001987A DE 102007001987 A1 DE102007001987 A1 DE 102007001987A1
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- Prior art keywords
- oil
- mixture according
- fuel
- hydrocarbon mixture
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1691—Hydrocarbons petroleum waxes, mineral waxes; paraffines; alkylation products; Friedel-Crafts condensation products; petroleum resins; modified waxes (oxidised)
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1857—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion Of Fluid Fuel (AREA)
Abstract
Description
Die
Erfindung betrifft die Verwendung von russarm verbrennenden Kohlenwasserstoff-Gemischen (KW-Gemisch)
gemäß
Bei dem normalen Betrieb von Ölfeuerungsanlagen kommt es mit der Zeit zu einem Abfall des Düsendurchsatzes und somit zu einem möglichen Leistungsabfall des Ölbrenners. Im Extremfall kann dieser Mangel zum Stillstand bzw. zum Ausfall der Ölfeuerungsanlage führen. Dieses Problem wird möglicherweise ausgelöst durch Partikel oder Sedimente aus dem Öllagertank, die durch die Ölbrennerpumpe angesaugt werden.at The normal operation of oil firing systems comes with it the time to a drop in the nozzle throughput and thus to a possible power loss of the oil burner. In extreme cases, this deficiency can lead to a standstill or failure lead the oil firing system. This problem will possibly triggered by particles or sediments from the oil storage tank, through the oil burner pump be sucked.
Eine Aufgabe der Erfindung ist es, einen Brennstoff zur Verfügung zu stellen, der geeignet ist, einen wie oben beschriebenen Leistungsabfall zu verhindern.A The object of the invention is to provide a fuel to provide a power drop as described above to prevent.
Gelöst
wurde die Aufgabe durch die Verwendung eines KW-Gemischs gemäß
Besonders deutlich zeigt sich die Russ mindernde Wirkung bei Heizölen, insbesondere extra leichtflüssigen, z. B. der Qualität HEL. Die genaue Spezifikation derartiger Produkte ist durch DIN-Normen festgelegt. Heizöle dienen, wie der Name schon sagt, zu Heizzwecken. Zur Wärmeerzeugung werden sie mittels eigens dafür entwickelten, speziellen Brennern unter Luftzufuhr verbrannt. Derartige Brenner kommen also in Ölfeuerungsanlagen zum Einsatz, beispielsweise in Multi-Ölbrennwertanlagen. Hierbei werden die Vorteile der vorliegenden Erfindung besonders deutlich.Especially clearly shows the soot-reducing effect on fuel oils, especially extra-liquid, z. B. the quality HEL. The exact specification of such products is by DIN standards established. Fuel oils serve, as the name implies, too Heating purposes. For heat generation they are by means of own designed for this, special burners under air supply burned. Such burners thus come in oil firing systems used, for example in multi-oil fired value systems. Here, the advantages of the present invention become particularly clear.
Durch Langzeittests mit dem erfindungsgemäßen KW-Gemisch als Brennstoff für Ölbrenner wurden weitere positive Wirkungsweisen und somit weitere vorteilhafte Verwendungen des additivierten KW-Gemischs gemäß Hauptpatent festgestellt. Diese Vorteile werden nachstehend erläutert und sind durch die Messergebnisse eines Langzeittests in Tabelle 1 (Tab.1) dokumentiert.By Long-term tests with the hydrocarbon mixture according to the invention as a fuel for oil burners were more positive Modes of action and thus further advantageous uses of the additive KW mixture according to the main patent. These Advantages are explained below and are covered by the Measurement results of a long-term test are documented in Table 1 (Tab.1).
Ein
Ergebnis dieser Test ist es, dass bei Verwendung eines KW-Gemischs
gemäß
Weiterhin zeigen die Tests, dass sich mit der Zeit die Funktion der Brennerdüsen verbessert, was sich insbesondere durch eine Zunahme des Durchsatzes des Brennstoffs bei ansonsten gleich bleibenden Bedingungen äußert. Die Verwendung des KW-Gemischs bewirkt also eine Verbesserung der Funktion, insbesondere des Durchsatzes, von Ölbrennerdüsen.Farther The tests show that over time the function of the burner nozzles improved, in particular by an increase in throughput of the fuel at otherwise constant conditions expresses. The use of the KW mixture thus causes an improvement in the Function, in particular the throughput of oil burner nozzles.
Auch zeigt sich, dass im Dauerbetrieb eines Ölbrenners mit dem KW-Gemisch als Brennstoff sich nach einiger Zeit eine Verbesserung der Verbrennung, nämlich eine Erhöhung des Wirkungsgrades einstellt. Auch der erniedrigte Wert für Sauerstoff im Abgas zeigt in Verbindung mit der Zunahme an CO2 eine Verbesserung der Verbrennung. Die Verwendung des KW-Gemischs ist demnach geeignet zur Verbesserung der Verbrennung (Wirkungsgrad) von Ölfeuerungsanlagen.It also turns out that in continuous operation of an oil burner with the HC mixture as fuel after some time, an improvement in combustion, namely an increase in the efficiency sets. Also, the lowered value of oxygen in the exhaust gas, in conjunction with the increase in CO 2, shows an improvement in combustion. The use of the HC mixture is therefore suitable for improving the combustion (efficiency) of oil firing systems.
Wie die Tests des Weiteren belegen, verbessern sich auch wesentliche Abgaswerte einer Ölfeuerungsanlage, nachdem sie einige Zeit mit dem KW-Gemisch als Brennstoff betrieben worden ist. So sinkt beispielsweise der Wert für Kohlenmonoxid im Abgas der Anlage um bis zu 36% bezogen auf den Anfangswert. Auch die Werte für NOx und NO gehen signifikant zurück. Die Verwendung des KW-Gemischs ist somit geeignet zur Verbesserung wesentlicher Abgaswerte bei der Verbrennung in Ölfeuerungsanlagen.As The tests also prove that significant ones are also improving Exhaust gas values of an oil-burning system, after having some Time has been operated with the HC mixture as fuel. So For example, the value of carbon monoxide in the exhaust gas decreases up to 36% of the initial value. Also the values for NOx and NO decrease significantly. The usage of the HC mixture is thus suitable for improving essential Exhaust emissions during combustion in oil firing systems.
Durch die Verwendung des KW-Gemischs wird also als ein Stillstand oder gar ein Ausfall der Ölfeuerungsanlage, z. B. durch Verstopfung der Brennerdüsen vermieden. Des Weiteren wird die Verbrennung verbessert und der Ausstoß schädlicher Abgase minimiert. Insgesamt führt somit die Verwendung des KW-Gemischs zur Erhöhung der Betriebssicherheit von Ölfeuerungsanlagen.By the use of the KW mixture is thus as a standstill or even a failure of the oil firing system, z. B. by constipation the burner nozzles avoided. Furthermore, the combustion improved and the emission of harmful exhaust gases minimized. Overall, thus results in the use of the KW mixture to increase the operational safety of oil firing systems.
BeispieleExamples
Versuchsanlage:Test range:
- Ölbrennwert-Wandgerät, Fabr.:Multi-Oil Typ 3, Leistung 20,0 KW, Baujahr 1998Oil rated wall unit, make.:Multi-Oil Type 3, power 20.0 KW, built in 1998
Öldüse:oil nozzle:
- Fluidcs 0,30/80° SFFluidcs 0,30 / 80 ° SF
Ölpumpendruck:Oil pump pressure:
- 21,0 bar21.0 bar
Brennstoff:Fuel:
- Heizöl-Extra-Leicht-SchwefelarmHeating oil extra light-suphur
Betriebsart der Anlage:Operating mode of the system:
- Taktbetrieb, 5 min Betrieb, 10 min. StillstandCycle operation, 5 min operation, 10 min. standstill
Standort der Versuchsanlage:Location of the pilot plant:
- Betriebsgelände der Innospec Ltd. Niederlassung Deutschland, Thiesstr. 61, 44649 HerneCompany premises of Innospec Ltd. branch Germany, Thiesstr. 61, 44649 Herne
Versuchszeitraum:Trial period:
- Beginn 03.03.2006, Ende 15.05.2006Beginning 03.03.2006, end 15.05.2006
Durchführung:Execution:
Das Ölbrennwertgerät wurde vor Testbeginn gereinigt, die Öldüse sowie der Ölvorfiltereinsatz wurden erneuert.The oil burner was cleaned before the test, the oil nozzle as well the oil prefilter insert was renewed.
Der Brennstoff war additiviert mit 7 ppm Ferrocen und 40 ppm Kampher (2-Bornanon) und entspricht damit einem KW-Gemisch gemäß Hauptpatent.Of the Fuel was additized with 7 ppm ferrocene and 40 ppm camphor (2-Bornanon) and thus corresponds to a KW mixture according to the main patent.
Die Brennanlage wurde zu Testbeginn gemäß Herstellerangaben optimal eingestellt, z. B. wurde das zugeführte Luftvolumen pro Zeiteinheit eingestellt. Die einstellbaren Parameter wurden während des gesamten Testablaufs nicht verändert.The Burning plant was at the beginning of the test according to the manufacturer optimally adjusted, z. B. was the volume of air supplied set per unit of time. The adjustable parameters were not changed during the entire test procedure.
Die
Messwerte in Tab. 1 sind Mittelwerte einer jeweils einstündigen
Betriebsphase zu Beginn des Tests, nach 500 Stunden und nach 1000
Stunden Betriebsdauer. Ergebnisse der Messungen:
ZITATE ENTHALTEN IN DER BESCHREIBUNGQUOTES INCLUDE IN THE DESCRIPTION
Diese Liste der vom Anmelder aufgeführten Dokumente wurde automatisiert erzeugt und ist ausschließlich zur besseren Information des Lesers aufgenommen. Die Liste ist nicht Bestandteil der deutschen Patent- bzw. Gebrauchsmusteranmeldung. Das DPMA übernimmt keinerlei Haftung für etwaige Fehler oder Auslassungen.This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.
Zitierte PatentliteraturCited patent literature
- - DE 102005032119 [0001, 0004, 0007] - DE 102005032119 [0001, 0004, 0007]
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200710001987 DE102007001987A1 (en) | 2005-07-07 | 2007-01-08 | Use of a hydrocarbon mixture according to the parent of this application as a fuel for oil-burning installations |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005032119A DE102005032119A1 (en) | 2005-07-07 | 2005-07-07 | Russarm burning fuel oil |
DE200710001987 DE102007001987A1 (en) | 2005-07-07 | 2007-01-08 | Use of a hydrocarbon mixture according to the parent of this application as a fuel for oil-burning installations |
Publications (1)
Publication Number | Publication Date |
---|---|
DE102007001987A1 true DE102007001987A1 (en) | 2008-07-10 |
Family
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Application Number | Title | Priority Date | Filing Date |
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DE200710001987 Ceased DE102007001987A1 (en) | 2005-07-07 | 2007-01-08 | Use of a hydrocarbon mixture according to the parent of this application as a fuel for oil-burning installations |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010061223A1 (en) * | 2008-11-26 | 2010-06-03 | Innospec Limited | Improvement in or relating to fuel additive compositions |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005032119A1 (en) | 2005-07-07 | 2007-01-18 | Octel Deutschland Gmbh | Russarm burning fuel oil |
-
2007
- 2007-01-08 DE DE200710001987 patent/DE102007001987A1/en not_active Ceased
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005032119A1 (en) | 2005-07-07 | 2007-01-18 | Octel Deutschland Gmbh | Russarm burning fuel oil |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010061223A1 (en) * | 2008-11-26 | 2010-06-03 | Innospec Limited | Improvement in or relating to fuel additive compositions |
US9255233B2 (en) | 2008-11-26 | 2016-02-09 | Innospec Limited | Fuel additive compositions |
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