JP2009280532A - 水性洗浄剤組成物 - Google Patents
水性洗浄剤組成物 Download PDFInfo
- Publication number
- JP2009280532A JP2009280532A JP2008135412A JP2008135412A JP2009280532A JP 2009280532 A JP2009280532 A JP 2009280532A JP 2008135412 A JP2008135412 A JP 2008135412A JP 2008135412 A JP2008135412 A JP 2008135412A JP 2009280532 A JP2009280532 A JP 2009280532A
- Authority
- JP
- Japan
- Prior art keywords
- component
- salt
- detergent composition
- aqueous
- alkyl ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 42
- 239000003599 detergent Substances 0.000 title claims abstract description 19
- -1 polyoxyethylene Polymers 0.000 claims abstract description 65
- 239000003205 fragrance Substances 0.000 claims abstract description 23
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 20
- 235000007586 terpenes Nutrition 0.000 claims abstract description 16
- 150000003839 salts Chemical class 0.000 claims abstract description 15
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- 150000003505 terpenes Chemical class 0.000 claims abstract description 10
- 238000004140 cleaning Methods 0.000 claims description 26
- 239000000796 flavoring agent Substances 0.000 claims description 6
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- 239000002304 perfume Substances 0.000 abstract description 2
- 229920001296 polysiloxane Polymers 0.000 description 15
- 239000006260 foam Substances 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 11
- 239000000194 fatty acid Substances 0.000 description 11
- 229930195729 fatty acid Natural products 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 8
- 239000002585 base Substances 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- 150000004665 fatty acids Chemical class 0.000 description 8
- 238000005406 washing Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
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- 230000002378 acidificating effect Effects 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 5
- 238000005187 foaming Methods 0.000 description 5
- PRNCMAKCNVRZFX-UHFFFAOYSA-N 3,7-dimethyloctan-1-ol Chemical compound CC(C)CCCC(C)CCO PRNCMAKCNVRZFX-UHFFFAOYSA-N 0.000 description 4
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- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- 150000001342 alkaline earth metals Chemical class 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 229920006317 cationic polymer Polymers 0.000 description 4
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- 238000001035 drying Methods 0.000 description 4
- 235000019634 flavors Nutrition 0.000 description 4
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- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 4
- 239000000341 volatile oil Substances 0.000 description 4
- ZHWLEUGSDGROJS-UHFFFAOYSA-N (2-tert-butylcyclohexyl) ethyl carbonate Chemical compound CCOC(=O)OC1CCCCC1C(C)(C)C ZHWLEUGSDGROJS-UHFFFAOYSA-N 0.000 description 3
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
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- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 2
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 2
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- 239000004475 Arginine Substances 0.000 description 2
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 2
- JOZKFWLRHCDGJA-LLVKDONJSA-N Citronellyl acetate Natural products CC(=O)OCC[C@H](C)CCC=C(C)C JOZKFWLRHCDGJA-LLVKDONJSA-N 0.000 description 2
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 239000005792 Geraniol Substances 0.000 description 2
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 2
- 239000004472 Lysine Substances 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- IGODOXYLBBXFDW-UHFFFAOYSA-N alpha-Terpinyl acetate Chemical compound CC(=O)OC(C)(C)C1CCC(C)=CC1 IGODOXYLBBXFDW-UHFFFAOYSA-N 0.000 description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
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- 229910052791 calcium Inorganic materials 0.000 description 2
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- 150000001768 cations Chemical class 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
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- 229940043350 citral Drugs 0.000 description 2
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 2
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- 230000000052 comparative effect Effects 0.000 description 2
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 description 2
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Abstract
【解決手段】成分(A)、(B)及び(C)を含有する水性洗浄剤組成物。
(A)ポリオキシエチレンアルキルエーテルカルボン酸又はその塩
(B)炭素数8〜12の脂肪族アルデヒド
(C)テルペン系香料化合物
【選択図】なし
Description
(A)ポリオキシエチレンアルキルエーテルカルボン酸又はその塩
(B)炭素数8〜12の脂肪族アルデヒド
(C)テルペン系香料化合物
例えば下記一般式で表されるものが挙げられる。
(Me)3SiO-[(Me)2SiO]d-Si(Me)3
〔式中、Meはメチル基を示し、dは3〜20000の数を示す。〕
各種のアミノ変性シリコーンが使用できるが、特に平均分子量が約3000〜100000の、アモジメチコーン(Amodimethicone)の名称でCTFA辞典(米国,Cosmetic Ingredient Dictionary)中に記載されているものが好ましい。このアミノ変性シリコーンは水性乳濁液として用いるのが好ましく、市販品としては、SM 8704C(東レ・ダウコーニング社)、DC 929(ダウコーニング社)等が挙げられる。
上記以外に、ポリエーテル変性シリコーン、メチルフェニルポリシロキサン、脂肪酸変性シリコーン、アルコール変性シリコーン、アルコキシ変性シリコーン、エポキシ変性シリコーン、フッ素変性シリコーン、環状シリコーン、アルキル変性シリコーン等が挙げられる。
表1及び2に示す組成の水性洗浄剤組成物を製造し、各香料素材及び調合香料を表中に示す量添加し、使用前のボトル口、使用中の両場面で香りを官能評価した。各評価結果も表中に併せて示す。
表1及び2に示す成分を秤量してイオン交換水中に添加し、50℃で十分に攪拌して、水性洗浄剤組成物を得た。水酸化ナトリウムを適量添加して、20倍希釈液のpHが弱酸性になるように調整した。
水性洗浄剤組成物の香り(ボトル口での香り、洗浄中の香り)について、評価を行った。評価は5名の専門パネルにより以下の評価基準で行い、その平均値を、表1及び2に示した。
4:脂肪族アルデヒド臭がまったく臭わない。
3:脂肪族アルデヒド臭が若干臭う。
2:脂肪族アルデヒド臭が臭う。
1:脂肪族アルデヒド臭がかなり臭う。
各水性洗浄剤組成物20gを、広口規格瓶(PS-No.6)に入れ、ボトル口から香りを評価した。
各水性洗浄剤組成物約3gを片方の手に取り、水道水を用いて希釈して泡立てた後、両腕(肘から先)を洗浄し、洗浄中の香りを評価した。
表3に示す成分を秤量してイオン交換水中に添加し、50℃で十分に攪拌して、水性洗浄剤組成物を得た。水酸化ナトリウムを適量添加して、20倍希釈液のpHが弱酸性になるように調整した。なお、成分(C)及びその他の香料成分としては、表4〜6に示す香料組成物を使用した。
常法に従って、表7に示す食器用洗浄剤を調製する。
Claims (3)
- 成分(A)、(B)及び(C)を含有する水性洗浄剤組成物。
(A)ポリオキシエチレンアルキルエーテルカルボン酸又はその塩
(B)炭素数8〜12の脂肪族アルデヒド
(C)テルペン系香料化合物 - 成分(B)と成分(C)の質量比が、(B):(C)=500:1〜1:1000である請求項1記載の水性洗浄剤組成物。
- 更に、成分(D)ローズ調香料化合物を含有する請求項1又は2記載の水性洗浄剤組成物。
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Cited By (2)
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JP2016113427A (ja) * | 2014-12-17 | 2016-06-23 | クラシエホームプロダクツ株式会社 | 真珠様光沢洗浄剤組成物及びその製造方法 |
JP2020500227A (ja) * | 2016-10-14 | 2020-01-09 | インターナショナル フレーバーズ アンド フラグランシズ インコーポレイテッド | 高性能、高影響のブルームアコード |
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JP2016113427A (ja) * | 2014-12-17 | 2016-06-23 | クラシエホームプロダクツ株式会社 | 真珠様光沢洗浄剤組成物及びその製造方法 |
JP2020500227A (ja) * | 2016-10-14 | 2020-01-09 | インターナショナル フレーバーズ アンド フラグランシズ インコーポレイテッド | 高性能、高影響のブルームアコード |
JP7069139B2 (ja) | 2016-10-14 | 2022-05-17 | インターナショナル フレーバーズ アンド フラグランシズ インコーポレイテッド | 高性能、高影響のブルームアコード |
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