JP2009221138A - Detergent composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a detergent composition that exhibits high cleansing effects for simply removing a component hard to remove such as an oily cosmetic, a hair-styling agent and the like and yet is excellent in foam volume when ejected from a non-gas foamer container, foam retention, elastic feelings of foam upon use, and feelings of use such as smoothness and the like. <P>SOLUTION: The detergent composition for a non-gas foamer comprises the following components (a), (b) and (c): (a) an anionic surfactant; (b) ethyl alcohol; (c) a cationic surfactant, where the component (a) comprises one or two or more selected from among N-acylalkyltaurine salts in an amount of at least 20 mass% in the whole amount of the component (a) and the compounded amount of the component (b) is 2-20 mass% based on the whole composition. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

  The present invention relates to a detergent composition for a non-gas former, and more specifically, a detergent composition used by filling a non-gas former container that is discharged in the form of foam without using a propellant (gas). Thus, the present invention relates to a detergent composition that has a high cleansing effect and is excellent in foam amount during discharge, foam retention, elasticity of foam during use, and smoothness.

  The cleaning composition is used for the purpose of removing dirt such as sebum and dust and cleaning the skin and hair. Conventionally, anionic surfactants have been used as main skeletons in detergent compositions, and amphoteric surfactants and nonionic surfactants have been incorporated in order to adjust the feeling of use such as foam quality and viscosity. In particular, in the detergent composition for hair, the conditioning ingredients are often added and the cationic surfactant is used because only these washing ingredients can cause the hair to become stiff, squeezed, and feel unusable. Agents and cationic polymers are widely used.

  On the other hand, in recent years, with the spread of hair styling agents, many people enjoy hair arrangements using styling agents, and hard styling agents such as oil-based bases that solidify hair are widely used. However, a hard styling agent generally contains a resin having a high film-forming property in order to firmly solidify the hair, and this film-forming resin is a detergent having a main skeleton as a normal anionic surfactant. There was a problem that it was difficult to remove with the composition. Therefore, after using a hard styling agent, you must remove the styling film formed on the hair surface with a hair cleansing agent or repeat shampooing a few times to remove it. There was a case.

  In order to solve such problems, a W / O-type cleaning agent for oily cosmetics containing a silicone oil (for example, Patent Document 1) or a C2-C4 monochromic compound containing silicone oil in order to remove dirt from a strong oily cosmetic. An alcohol-based hair cleansing agent (for example, Patent Document 2) has been proposed.

However, although the cleaning agent of Patent Document 1 has a cleansing effect, it is difficult to wash away with an emulsion, and the anionic surfactant may be inferior to the main skeleton cleaning agent. In addition, the C2-C4 monoalcohol-based hair cleansing agent of Patent Document 2 is a so-called dry shampoo, which is used during and after use, compared to a type of detergent in which an anionic surfactant is washed away from the main skeleton. In some cases, it was inferior to the refreshing feeling (satisfaction that it was possible to remove stains and cosmetic ingredients that were difficult to remove, and was refreshed). In addition, when an anionic surfactant is blended with ethyl alcohol in a main skeleton cleaning agent, the cleansing power that generally removes a film-forming resin, etc. is increased, but foaming due to ethyl alcohol is reduced. The amount of ethyl alcohol was difficult to formulate because the amount was small, the foam was inferior, the spread was poor, and the usability was impaired.
Therefore, the problem to be solved by the present invention is that in the detergent composition, the anionic surfactant has the same usability and feel as the main skeleton detergent, while the oily cosmetic and hair styling. It is to have a high cleansing effect that can easily remove oily components contained in the agent and the like and components that are difficult to remove, such as a film-forming resin.
JP 2007-261955 A JP 2005-255680 A

  In view of such circumstances, the present inventors have conducted intensive studies, and as a result, in the detergent composition, particularly in the detergent composition to be used in a non-gas former container, the anionic surfactant, the cationic surfactant, and the specific Even if an amount of ethyl alcohol is blended, and a specific amount of N-acylalkyl taurine salt is blended in an anionic surfactant, a certain amount of ethyl alcohol is blended, and a high cleansing effect is exhibited. It was found that a sufficient amount of foam was obtained when discharging from a non-gas former container, the foam was good, and the detergent composition had a feeling of elasticity of foam during use and a smooth feeling of use. The problem was solved and the present invention was completed.

That is, the present invention comprises the following components (a), (b) and (c);
(A) Anionic surfactant (b) Ethyl alcohol (c) A cationic surfactant is blended, and component (a) is one or more selected from N-acylalkyltaurine salts. The present invention provides a detergent composition for a non-gas former, which is contained in a total amount of 20% by mass or more and the blending amount of the component (b) is 2 to 20% by mass of the whole composition.

  The cleaning composition of the present invention has a high cleansing effect that can easily remove components that are difficult to remove with ordinary cleaning agents, such as oily components and film-forming resins contained in oily cosmetics and hair styling agents. It has the advantages of excellent foam volume and foam retention when discharged from a non-gas former container, and excellent elasticity and smoothness of the foam during use.

In the cleaning composition of the present invention, an anionic surfactant is blended in order to develop a cleaning effect that is a basic function of the cleaning composition.
As the anionic surfactant of component (a) used in the present invention, any anionic surfactant can be used without particular limitation, except that an N-acylalkyltaurine salt is essential.
For example, higher fatty acid salts such as sodium laurate, potassium laurate, potassium coconut oil fatty acid; polyoxyethylene alkyl such as sodium polyoxyethylene lauryl ether sulfate, polyoxyethylene lauryl ether ammonium sulfate, polyoxyethylene lauryl ether sulfate triethanolamine Ether sulfates; alkyl sulfates such as sodium lauryl sulfate and triethanolamine lauryl sulfate; α-olefin sulfonates such as sodium tetradecenesulfonate and potassium tetradecenesulfonate; N-lauroyl-L-sodium glutamate, N- Lauroyl-L-ammonium glutamate, N-lauroyl sarcosine sodium, N-coconut oil fatty acid sarcosine sodium, N-coconut oil fatty acid acylglycine potassium N-acyl amino acid salts such as N-lauroyl-N-methylalanine triethanolamine, N-coconut oil fatty acid acyl-L-glutamic acid triethanolamine, etc .; sodium N-lauroylisethionate, potassium N-laureuylisethionate, etc. Acyl isethionate salts; N-acyl polypeptide salts such as coconut oil fatty acid hydrolyzed collagen potassium and lauroyl hydrolyzed silk sodium; hydroxy ether carboxylates such as sodium dodecane-1,2-diol ether acetate; sodium sulfosuccinate Examples include sulfosuccinic acid. By blending one or two or more of these, it is possible to form a foam suitable for washing and wash away skin and hair stains.
Moreover, as an anionic surfactant of the component (a) of the present invention, an N-acylalkyl taurine salt is essentially blended. In the present invention, the N-acylalkyltaurine salt, like other anionic surfactants, exhibits a cleaning effect, and even when discharged from a non-gas former container even in the presence of component (b) ethyl alcohol. The amount of foam is not impaired, the foam retention is good, and in combination with the cationic surfactant of component (c), the foam feels soft and smooth on the hair and skin when used. A feeling of use can be given.
The N-acylalkyltaurine salt used in the present invention is not particularly limited as long as it is usually used in a detergent composition and can give the above-mentioned effects. Specifically, N-lauroyl methyl taurine sodium, N-coconut oil fatty acid methyl taurine potassium, N-coconut oil fatty acid methyl taurine sodium, and the like can be used. Among them, the N-coconut oil fatty acid methyl taurine sodium is particularly preferable because an excellent foam amount and foam retention can be obtained even in the presence of the component (b) ethyl alcohol.

The compounding amount of the anionic surfactant of component (a) used in the cleaning composition of the present invention is not particularly limited, but is preferably 5 to 50% by mass (hereinafter simply referred to as “%”) in the composition. ), More preferably 7 to 30%. When the anionic surfactant of the component (a) is blended in this range, a suitable foam is formed, the feeling of use is excellent, and the dirt on the skin and hair can be washed off.
Further, among the component (a) anionic surfactant used in the cleaning composition of the present invention, the amount of the N-acylalkyltaurine salt to be blended is the total amount of the anionic surfactant of component (a). The content is 20% or more, preferably 25 to 70%. If blended in this range, the composition does not solidify at low temperatures and the discharge part of the container is not clogged, it has excellent foam volume and foam retention at the time of discharge, it is easy to apply to the skin and hair and is smooth and good A cleaning composition having a good feeling of use can be obtained.

  The component (b) ethyl alcohol used in the cleaning composition of the present invention is used to enhance the cleansing effect, and it is difficult to remove oily components and film-forming resins blended in oily cosmetics and hair styling agents. It is formulated for the purpose of easily removing ingredients and giving a smooth and smooth feel.

  The compounding quantity of the component (b) used for the cleaning composition of this invention is 2 to 20% of the whole composition, and 5 to 10% is more preferable. When component (b) is blended in this range, a cleansing composition having a high cleansing effect that can easily remove components that are difficult to remove, such as oily components and film-forming resins, and a smooth and smooth use feeling is obtained. be able to.

The cationic surfactant of component (c) used in the cleaning composition of the present invention is generally imparted with conditioning effects such as smoothness and flexibility, but in the present invention, the components (a) and (b) This combination is also added for the purpose of imparting elasticity to the foam.
The cationic surfactant of component (c) used in the cleaning composition of the present invention is not particularly limited as long as it is usually used in cosmetics and can impart the above-described effects. Examples include amine salts such as polyamines and aminoalcohol fatty acid derivatives, alkyl quaternary ammonium salts, aromatic quaternary ammonium salts, pyridium salts, imidazolium salts, and the like.
Specifically, cetyl trimethyl ammonium chloride, cetyl trimethyl ammonium bromide, stearyl trimethyl ammonium chloride, stearyl trimethyl ammonium bromide, behenyl trimethyl ammonium chloride, behenyl trimethyl ammonium bromide, behenyl trimethyl ammonium methyl sulfate, distearyl dimethyl ammonium chloride, Quaternary ammonium salts such as dioleyl dimethyl ammonium bromide, cetyl behenyl dimethyl ammonium methyl sulfate, stearyl dimethyl benzyl ammonium chloride, stearoyl lysine butyl ester / hydrochloride, N-coconut oil fatty acid acyl L-arginine ethyl DL-pyrrolidone carboxylic Mono-N-long chain acyl basic amino acid lower alkyl such as acid salt, lauroyl-ornithine propyl ester / acetate Examples thereof include guanidine derivatives such as luster salt, decylguanidine acetate, 2-guanidinoethyllaurylamide hydrochloride, 2-guanidinobutyl stearamide / DL-pyrrolidonecarboxylate, and the like. Can be blended.
In the present invention, quaternary ammonium such as cetyltrimethylammonium chloride, cetyltrimethylammonium bromide, stearyltrimethylammonium chloride, stearyltrimethylammonium bromide, behenyltrimethylammonium chloride, behenyltrimethylammonium bromide, distearyldimethylammonium chloride, etc. Salts are particularly preferred because they are excellent in the elasticity of foam, smoothness to hair and skin, and imparting flexibility.

  Although the compounding quantity of the component (c) used for the cleaning composition of this invention does not have a restriction | limiting in particular, 0.01-2% is preferable and 0.1-1% is more preferable. When the component (c) is blended within this range, the skin and hair can be sufficiently imparted with conditioning effects such as smoothness and suppleness without impairing the foam amount and foam retention at the time of discharge. ) And (b), it is possible to obtain a detergent composition having excellent foam elasticity.

  In the cleaning composition of the present invention, in addition to the components (a) to (c) above, the cosmetic composition, quasi-drug, topical medicine, etc. are usually used in a quantitative and qualitative range that does not impair the effects of the present invention. Ingredients used in the formulation of the above: water (purified water, hot spring water, deep water, etc.), oil agent, surfactants other than components (a) and (c), metal soap, gelling agent, powder, the above components Alcohols other than (b), water-soluble polymers, moisturizers, antibacterial agents, fragrances, deodorants, salts, pH adjusters, refreshing agents, plant extracts, vitamins, hair repair components, and the like can be appropriately blended.

  As the oil agent, oily components such as higher alcohols, hydrocarbon oils, ester oils, fatty acids, fats and oils, and silicones can be used. For example, lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, behenyl alcohol, hexadecyl alcohol, oleyl alcohol, isostearyl alcohol, hexyldodecanol, octyldodecanol, cetostearyl alcohol, 2-decyltetradecinol, cholesterol, phytosterol , Higher alcohols such as sitosterol, lanosterol, monostearyl glycerol ether (batyl alcohol), hydrocarbons such as ozokerite, squalane, squalene, ceresin, paraffin, paraffin wax, liquid paraffin, pristane, polyisobutylene, microcrystalline wax, petrolatum, etc. , Diisobutyl adipate, 2-hexyldecyl adipate, adipic acid 2-heptylundecyl, N-alkyl glycol monoisostearate, isocetyl isostearate, trimethylolpropane triisostearate, ethylene glycol di-2-ethylhexanoate, cetyl 2-ethylhexanoate, tri-2-ethylhexanoic acid Trimethylolpropane, tetra-2-ethylhexanoic acid pentaerythritol, cetyl octanoate, octyldodecyl gum ester, oleyl oleate, octyldodecyl oleate, decyl oleate, neopentyl glycol dicaprate, triethyl citrate, 2-succinate Ethyl hexyl, amyl acetate, ethyl acetate, butyl acetate, isocetyl stearate, butyl stearate, diisopropyl sebacate, di-2-ethylhexyl sebacate, cetyl lactate, Acid myristyl, isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, 2-heptylundecyl palmitate, cholesteryl 12-hydroxystearylate, dipentaerythritol fatty acid ester, isopropyl myristate, octyldodecyl myristate, Ester oils such as 2-hexyldecyl myristate, myristyl myristate, hexyldecyl dimethyloctanoate, ethyl laurate, hexyl laurate, diisostearyl malate, waxes such as beeswax, carnauba wax, candelilla wax, whale wax Animal oil such as beef tallow, beef leg fat, beef bone fat, hardened beef tallow, hardened oil, turtle oil, pork tallow, horse fat, mink oil, liver oil, egg yolk oil, vegetable oil such as olive oil, camellia oil, macadamian nut oil, Ranori Lanolin derivatives such as lanolin, liquid lanolin, reduced lanolin, lanolin alcohol, hard lanolin, lanolin acetate, lanolin fatty acid isopropyl, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid, oleic acid, linoleic acid, arachidone Acids, fatty acids such as docosahexaenoic acid (DHA), isostearic acid, 12-hydroxystearic acid, low polymerization dimethylpolysiloxane, high polymerization dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetra Siloxane, tetramethyltetrahydrogencyclotetrasiloxane, polyether-modified polysiloxane, polyoxyalkylene / alkylmethylpolysiloxane / methylpolysiloxane copolymer Alkoxy-modified polysiloxane, alkyl-modified polysiloxane, cross-linked organopolysiloxane, fluorine-modified polysiloxane, amino-modified polysiloxane, glycerin-modified polysiloxane, higher alkoxy-modified silicone, higher fatty acid-modified silicone, silicone resin, silicone rubber, silicone resin, etc. Is mentioned.

The surfactant is a surfactant other than components (a) and (c), and examples thereof include amphoteric surfactants and nonionic surfactants.
Amphoteric surfactants include octyldimethylaminoacetic acid betaine, lauryldimethylaminoacetic acid betaine, coconut oil fatty acid amidopropyl betaine, coconut oil fatty acid alkyldimethylaminoacetic acid betaine, myristyldimethylaminoacetic acid betaine, cetyldimethylaminoacetic acid betaine, coconut oil fatty acid Acetyldimethylaminoacetic acid betaine, lauric acid amidopropyldimethylaminoacetic acid betaine, lauryl dihydroxyethylaminoacetic acid betaine, cetyldihydroxyethylaminoacetic acid betaine, and the like, acetic acid betaine type surfactants, N-coconut oil fatty acid acyl-N-carboxymethyl- N-hydroxyethylethylenediamine sodium, N-coconut oil fatty acid acyl-N-carboxymethoxyethyl-N-carboxymethylethylenediamine dinat Imidazoline type surface active agents such as Um like. Moreover, sodium lauryl aminodiacetate etc. are mentioned.
Nonionic surfactants include sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycol fatty acid ester, polyethylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, poly Oxyethylene alkyl phenyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene propylene glycol fatty acid ester, polyoxyethylene castor oil, polyoxyethylene Hydrogenated castor oil, polyoxyethylene phytostanol ether, polyoxyethylene N-phytosterol ether, polyoxyethylene cholestanol ether, polyoxyethylene cholesteryl ether, polyoxyalkylene-modified organopolysiloxane, polyoxyalkylene-alkyl co-modified organopolysiloxane, lauric acid diethanolamide, coconut oil fatty acid diethanolamide, coconut oil fatty acid Monoethanolamide, polyoxyethylene coconut oil fatty acid monoethanolamide, lauric acid monoisopropanolamide, coconut oil fatty acid monoisopropanolamide, polyoxyprolene coconut oil fatty acid monoisopananolamide, alkanolamide, sugar ether, sugar amide etc. Can be mentioned.

  As the metal soap, 12-hydroxy aluminum stearate, zinc stearate, aluminum stearate, calcium stearate, magnesium stearate, zinc myristate, magnesium myristate, zinc cetyl phosphate, calcium cetyl phosphate, zinc sodium cetyl phosphate, zinc laurate And zinc undecylenate.

  Gelling agents include amino acid derivatives such as N-lauroyl-L-glutamic acid, α, γ-di-n-butylamine, dextrins such as dextrin palmitate, dextrin stearate, dextrin 2-ethylhexanoate palmitate, etc. Fatty acid esters, sucrose fatty acid esters such as sucrose palmitate, sucrose stearate, benzylidene derivatives of sorbitol such as monobenzylidene sorbitol, dibenzylidene sorbitol, dimethylbenzyl dodecyl ammonium montmorillonite clay, dimethyl dioctadecyl ammonium montmorillonite clay, etc. Examples include organically modified clay minerals.

  If the powder is used in ordinary cosmetics, its shape (spherical, needle-like, plate-like, etc.), particle size (smoke-like, fine particles, pigment grade, etc.), particle structure (porous) Any inorganic powder can be used, for example, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, synthetic mica. , Mica, kaolin, sericite, muscovite, synthetic mica, phlogopite, saucite, biotite, lithia mica, silicic acid, anhydrous silicic acid, aluminum silicate, magnesium silicate, aluminum magnesium silicate, calcium silicate, Barium silicate, strontium silicate, metal tungstate, hydroxyapatite, vermiculite, hydrite, montmorillonite, z Light, ceramic powder, dicalcium phosphate, alumina, aluminum hydroxide, boron nitride, boron nitride, etc .; organic powders include polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane, benzoguanamine powder, polymethyl Benzoguanamine powder, tetrafluoroethylene powder, polymethyl methacrylate powder, cellulose, silk powder, nylon powder, 12 nylon, 6 nylon, styrene / acrylic acid copolymer, divinylbenzene / styrene copolymer, vinyl resin, urea resin, phenol Resin, fluororesin, silicon resin, acrylic resin, melamine resin, epoxy resin, polycarbonate resin, microcrystalline fiber powder, Lauro Luridine, etc .; Colored pigments include inorganic red pigments such as iron oxide, iron hydroxide and iron titanate, inorganic brown pigments such as γ-iron oxide, yellow inorganic oxides such as yellow iron oxide and loess, black iron oxide, Inorganic black pigments such as carbon black, inorganic purple pigments such as manganese violet and cobalt violet, inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide and cobalt titanate, inorganic blue pigments such as bitumen and ultramarine, tar Dye raked, natural dye raked, composite powder made by combining these powders, etc .; pearl pigments include titanium oxide-coated mica, titanium oxide-coated mica, bismuth oxychloride, titanium oxide Coated bismuth oxychloride, titanium oxide coated talc, fish scale foil, titanium oxide coated colored mica, etc .; -Powder, stainless steel powder, etc. As tar pigments, Red No. 3, Red No. 104, Red No. 106, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 227 , Red 228, Red 230, Red 401, Red 505, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Yellow 204, Yellow 401, Blue 1, Blue 2, Blue No. 201, Blue No. 404, Green No. 3, Green No. 201, Green No. 204, Green No. 205, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 206, Orange No. 207, etc .; A powder selected from acids, laccaic acid, calsamine, bradylin, crocin, etc., and these powders are compounded or surface treated with oils, silicones, or fluorine compounds It may be carried out powder.

  Examples of alcohols other than component (b) include lower alcohols such as butyl alcohol and isopropanol, glycerin, diglycerin, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, There are polyhydric alcohols such as polyethylene glycol.

  Water-soluble polymers include cationic polymers such as cationized cellulose (polyquaternium-10), cationized guar gum, cationized starch, dimethyldiallylammonium chloride / acrylamide copolymer (polyquaternium-7), vinylpyrrolidone N, N- Examples thereof include dimethylaminoethyl methacrylic acid copolymer (polyquaternium-11) and polydimethylmethylenediperinium chloride (polyquaternium-6). (Methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (octylacrylamide / hydroxypropyl acrylate / butylaminoethyl methacrylate) copolymer, acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer (polyquaternium-39) Etc. In addition, mucopolysaccharides selected from chondroitin sulfate, hyaluronic acid, mucin, dermatan sulfate, heparin and keratan sulfate and their salts, gum arabic, tragacanth, galactan, carob gum, guar gum, caraya gum, carrageenan, pectin, agar, quince seed, algae Colloid, plant gum, locust bean gum, galactomannan and other plant polymers, xanthan gum, dextran, succinoglucan, pullulan and other microbial polymers, starch, carboxymethyl starch, methylhydroxypropyl starch and other starch polymers, Methylcellulose, ethylcellulose, methylhydroxypropylcellulose, carboxymethylcellulose, hydroxymethylcellulose, hydroxypropylcellulose, nitrocell Cellulose, sodium sulfate sodium, carboxymethylcellulose sodium, crystalline cellulose, cellulose-based cellulose polymer, alginic acid-based polymers such as sodium alginate, propylene glycol alginate, polyvinyl methyl ether, carboxyvinyl polymer, alkyl-modified carboxyvinyl polymer, etc. Vinyl polymer, polyoxyethylene polymer, polyoxyethylene polyoxypropylene copolymer polymer, acrylic polymer such as sodium polyacrylate, polyethyl acrylate, polyacrylamide, polyethyleneimine, bentonite, laponite, There are inorganic water-soluble polymers such as hectorite.

  Antibacterial agents include benzoic acid, sodium benzoate, salicylic acid, coalic acid, sorbic acid, potassium sorbate, paraoxybenzoic acid ester, parachlorometacresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, photosensitive Element, bis (2-pyridylthio-1-oxide) zinc, phenoxyethanol, isopropylmethylphenol and the like.

  Examples of pH adjusters include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, malic acid, potassium carbonate, sodium bicarbonate, ammonium bicarbonate, sodium hydroxide, potassium hydroxide, triethanolamine, monoethanolamine, Examples of the refreshing agent include L-menthol and camphor.

  Vitamins such as vitamin A and derivatives thereof, vitamin B and derivatives thereof, vitamin C and derivatives thereof, vitamin D and derivatives thereof, vitamin E and derivatives thereof, linolenic acid and derivatives thereof; phytonadione, menaquinone, Vitamin Ks such as menadione and menadiol; vitamins P such as eriocitrin and hesperidin; and biotin, carcinine, ferulic acid and the like.

  Examples of the hair repair component include amino acids, amino acid derivatives, peptides, saccharides and derivatives thereof, hair lipid components, phospholipids and derivatives thereof, and plant extracts containing these components. Specifically, examples of amino acids include glycine, alanine, valine, isoleucine, serine, threonine, aspartic acid, glutamic acid, asparagine, glutamine, lysine, hydroxylysine, arginine, cystine, cysteine, acetylcysteine, methionine, phenylalanine, Examples include tyrosine, proline, hydroxyproline, ortinin, citrulline, theanine, creatine, and creatinine. As amino acid derivatives, N-lauroyl-L-glutamate di (phytosteryl 2-octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl behenyl octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl Octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl, behenyl, 2-octyldodecyl), N-lauroyl-L-glutamate di (2-octyldodecyl), N-acylglutamate lysine condensate and the like. Peptides may be derived from animals, fish, shellfish, plants, and specifically, collagen and derivatives thereof or hydrolysates thereof, elastin and derivatives thereof or hydrolysates thereof, keratin and derivatives thereof or the like. Degradation products, wheat proteins and derivatives thereof or hydrolysates thereof, soybean proteins and derivatives or hydrolysates thereof, and the like. Examples of sugars include sorbitol, erythritol, maltose, maltitol, xylitol, xylose, trehalose, inositol, glucose, mannitol, pentaerythritol, fructose, sucrose and esters thereof, dextrin and derivatives thereof, honey, brown sugar extract, and the like. . Examples of the hair lipid component include ceramide and derivatives thereof, 18-methyleicosanoic acid and the like. Examples of phospholipids and their derivatives include phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingophospholipids, and the like, or compositions containing these, i.e., soy lecithin, egg yolk Examples include lecithin or hydrogenated products thereof, and examples of the phospholipid derivative include a homopolymer of 2-methacryloyloxyethyl phosphorylcholine or a copolymer of 2-methacryloyloxyethyl phosphorylcholine and a hydrophobic monomer. . One or two or more of these may be appropriately selected or combined.

  There is no limitation in particular as a manufacturing method of the cleaning composition of this invention, It can manufacture by a conventional method. For example, the essential components (a) to (c) and optionally added components as necessary are produced by uniformly mixing with water. By putting this in a non-gas former container and discharging it from the container in the form of foam at the time of use, a sufficient amount of foam can be obtained even in the presence of ethyl alcohol, and it can be used satisfactorily. As a form of the composition, any liquid or emulsion may be used as long as it can be discharged from a non-gas former container, and it can be applied as a cleaning composition such as a shampoo, a facial cleanser, a body cleaning agent, and particularly a styling for hair. It can be preferably applied to a shampoo as a detergent composition of the agent.

  In addition, the non-gas former container is not particularly limited as long as it has a mechanism capable of mixing the composition with air and ejecting it in the form of foam, and is used with a pump former container equipped with a pump mechanism or squeezed. A squeeze foamer container or the like can be used. For example, the thing provided with the mechanism in which a composition passes porous bodies, such as a mesh, and becomes foamy by pushing the head (pressing part) of a pump container is mentioned.

Further, as a method of using the cleaning composition of the present invention, the entire cleaning part such as the face, body or hair is wetted with water, and then the cleaning composition of the present invention discharged in a foam form is applied and washed. It is preferable that the entire part is stretched so as to be wrapped with foam and washed away after being blended with dirt or a cosmetic film, since the cleansing effect of the present invention becomes higher.

  Hereinafter, the present invention will be described in more detail with reference to examples. Note that these do not limit the present invention.

Examples 1-7, Comparative Examples 1-6; Shampoo (pump former container)
Shampoos were prepared according to the composition shown in Table 1 and the following production method. Each shampoo obtained was filled into a commercially available pump former container (150 mesh, 2 passes) to give a sample, and for each sample, (a) the amount of foam at the time of discharge and (b) the foam retention was evaluated by the following evaluation method 1. Evaluation was performed, and (c) the feeling of elasticity of the foam, (d) the feel (smoothness) during use, and (e) the cleansing effect were subjected to sensory evaluation by the following evaluation method 2.

(Composition and results)

(Production method)
A: Components 1 to 5 and 8 to 13 are uniformly dissolved by heating.
B: A is cooled.
C: Components 6 and 7 were added to B to obtain a shampoo.

[Evaluation method 1]: Foam amount at the time of discharge, evaluation of foam retention Examples 1 to 7 and Comparative Examples 1 to 6 were filled in a commercially available pump former container (150 mesh passed twice), and the diameter The head of the pump former container was pressed 10 times into a 50 mm high 115 mm glass container and discharged, and the height of the foam immediately after discharge and the height of the foam 5 minutes after discharge were measured.
The height of foam immediately after discharge is defined as (a) the amount of foam at the time of discharge, and the height of foam 5 minutes after discharge relative to the height of the foam immediately after discharge is defined as (b) foam retention. Evaluated.

[Evaluation Criteria 1]: (A) Foam amount during discharge [Evaluation Result]: [Score]
The height of the foam immediately after discharge is 50 mm or more: ◎
Bubble height immediately after discharge is 40 mm or more and less than 50 mm: ○
The height of the foam immediately after discharge is 30 mm or more and less than 40 mm: Δ
Bubble height immediately after discharge is less than 30 mm: ×
[Evaluation Criteria 2]: (B) Foam retention [Evaluation Result]: [Score]
Bubble height after 5 minutes of discharge / bubble height immediately after discharge is 85% or more: ◎
Bubble height 5 minutes after discharge / bubble height immediately after discharge is 65% or more and less than 85%: ○
Bubble height 5 minutes after discharge / bubble height immediately after discharge is 45% or more and less than 65%: Δ
Bubble height after 5 minutes of discharge / bubble height immediately after discharge is less than 45%: ×

[Evaluation Method 2]: Evaluation of foam elasticity, feel during use (smoothness), and cleansing effect 20 hard female hair styling sprays prepared by the following Reference Formula 1 and the following manufacturing method were applied to 20 professional female panels. After 2 hours, the hair was washed with each sample of Examples 1 to 7 and Comparative Examples 1 to 6 put in a pump former container (passed through 150 mesh twice). First, (c) Evaluate the elasticity of the foam with the following Evaluation Criteria 3 and stretch it over the entire hair with your fingers. (D) Evaluate the feel (smoothness) when using it with the following Evaluation Criteria 4 It was. Then, it was rinsed off with hot water, and the drop of the hair styling spray was evaluated according to the following evaluation standard 5 as a (e) cleansing effect.
Furthermore, each average value of the scores of (c) to (e) was determined according to the following criteria.

Reference formulation 1: Hair styling spray (hard type)
(Stock solution) (%)
1. Ethyl alcohol 92.1
2. (Octylacrylamide / Hydroxypropyl acrylate /
(Butylaminomethyl methacrylate) copolymer 5
3. Octyl palmitate 1
4.1,3-Butylene glycol 1
5. AMP 0.9
(Production method)
A: Components 1 to 5 are mixed uniformly to obtain a stock solution.
B: The aerosol can was filled with the propellant 40 (liquefied petroleum gas / dimethyl ether = 16/24) with respect to the stock solution 60 of A to obtain a hair styling spray (hard type).

[Evaluation Criteria 3]: (C) Elasticity of bubbles [Evaluation Result]: [Score]
The feel of the foam is very fine and plump: 5 points The feel of the foam is fine and plump: 4 points The feel of elasticity is: 3 points The foam is uneven and the elasticity is too much Not felt: 2 points Bubbles collapse and feel no elasticity: 1 point [Evaluation Criteria 4]: (D) Feel when using (smoothness)
[Evaluation Result]: [Score]
Very smooth: 5 points Comparative smooth: 4 points Smooth: 3 points Not very smooth: 2 points Not smooth: 1 [Evaluation Criteria 5]: (e) Cleansing effect [Evaluation Result]: [Rating]
Hair styling spray (hard type) can be completely removed with one shampoo: 5 points Can be almost removed with one shampoo: 4 points Can be almost removed with two shampoos: Three points Can not be dropped too much: 2 points Can hardly be dropped even if shampooed three times: 1 point [Criteria]
[Average score]: [Judgment]
4.5 or more: ◎
3.5 or more and less than 4.5: ○
1.5 or more and less than 3.5: △
Less than 1.5: ×

As is apparent from the results in Table 1, the non-gas former shampoos of Examples 1 to 7 are excellent in the amount of foam at the time of discharge and the foam retention while being a system in which a certain amount or more of ethyl alcohol is blended. The foam was excellent in elasticity, smoothness and cleansing power.
On the other hand, the comparative example 1 which does not contain an N-acylalkyl taurine salt in the component (a) and the comparative example 2 in which the blending amount of the N-acylalkyl taurine salt in the component (a) is low are smooth when used (smooth) In addition, although there was a cleansing effect, the dischargeability was poor, the amount of foam was lacking, and the foam was crushed. Moreover, although the comparative example 3 which does not mix | blend the ethyl alcohol of a component (b) and the comparative example 4 with few compounding quantities of a component (b) have the touch (smoothness) at the time of use, hair styling spray (hard type) ) Was not effective in cleansing the cosmetic film sufficiently, and the discharge property was poor, and the foam amount, foam retention and foam elasticity were poor. On the other hand, Comparative Example 5 having a large amount of component (b) ethyl alcohol has good foam amount and cleansing effect at the time of discharge, but the foam collapses, and the foam retention and foam elasticity, The touch (smoothness) was poor. Further, Comparative Example 6 in which the cationic surfactant of component (c) is not blended is good in foam amount at the time of discharge, foam retention and cleansing effect, but feels the elasticity of the foam and feel (smoothness) during use. Was bad.

Example 8: Face-wash foam (component) (%)
1. Coconut oil fatty acid potassium 2
2. (Lauric acid / Myristic acid) Triethanolamine 1.5
3. Lauryldimethylaminoacetic acid betaine 1.5
4). N-coconut oil fatty acid methyl taurine sodium 1
5. Dipropylene glycol 5
6). Phenoxyethanol 0.5
7). Betaine 0.3
8). Stearyltrimethylammonium chloride 0.1
9. Edetate disodium 0.1
10. Sorbitol 1
11. Fragrance 0.1
12 Ethyl alcohol 2
13. Purified water remaining

(Production method)
A: Components 1 to 8 are mixed and dissolved uniformly.
B: Components 9 to 13 are mixed and dissolved uniformly.
C: A is added to B and mixed uniformly.
D: C was filled into a pump former container to obtain a face-washing foam.
The face-washing foam of Example 8 is excellent in the amount of foam at the time of discharge, foam retention and foam elasticity, and feeling of use (smoothness), and forms a strong cosmetic film such as W / O type cosmetics and oily cosmetics. It was an excellent cleansing effect that can be easily removed with a single face wash.

Example 9: Cleaning agent for body (component) (%)
1. Lauryl sulfate triethanolamine 5
2. Palm oil fatty acid amidopropyl betaine 1
3. N-lauroylmethyl taurine sodium 4
4.1,2-Pentanediol 0.1
5. Polyquaternium 39 0.05
6). Edetate disodium 0.05
7). Distearyldimethylammonium chloride 0.2
8). Glycerin 0.1
9. Propylene glycol 0.5
10. Ethyl alcohol 5
11. Phenoxyethanol 0.2
12 Fragrance 0.5
13. Ethylene glycol distearate 0.5
14 Palm oil fatty acid monoethanolamide 2.5
15. Purified water remaining

(Production method)
A: Components 1 to 6 and 7 to 12 are mixed uniformly.
B: Components 13 to 14 are heated and dissolved uniformly.
C: B is cooled.
D: Add A and C to 15 and mix uniformly.
E: D was filled into a squeeze foamer container to obtain a body cleaning material.
The body cleanser of Example 9, which is an embodiment of the present invention, is excellent in the amount of foam at the time of ejection, foam retention and foam elasticity, and feeling of use (smoothness), and is a W / O type sunscreen cosmetic. It was an excellent cleansing effect that can easily remove cosmetics that form a strong decorative film.

Claims (2)

The following components (a), (b) and (c);
(A) Anionic surfactant (b) Ethyl alcohol (c) A cationic surfactant is blended, and component (a) is one or more selected from N-acylalkyltaurine salts. A cleaning composition for a non-gas former, which is contained in a total amount of 20% by mass or more and the compounding amount of the component (b) is 2 to 20% by mass of the whole composition. The cleaning composition according to claim 1, which is for hair.