JP2017218383A - Cleaning agent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a detergent that combines washing power, foaming fastness, creamy property of foam, feeling of rinsing, feeling after drying, and a less irritating feeling when entering the eye.SOLUTION: According to the present invention, there is provided a cleaning agent composition that comprises: (A) diester of oleic acid and methyl glucose or polyethylene glycol ether of triester; (B) alkyl glucoside selected from lauryl glucoside and/or decyl glucoside; (C) polyoxyethylene alkyl ether sulfuric acid ester salt; and (D) a betaine-type amphoteric surfactant selected from lauramidopropyl betaine and/or cocamidopropyl betaine betaine.SELECTED DRAWING: None

Description

  The present invention relates to a cleaning agent that combines detergency, foaming speed, foam creaminess, rinsing feel, and feeling after drying, and has little irritation when entering the eyes.

Conventionally, in the field of detergents such as shampoos and body shampoos, it has been required to provide basic functions such as cleaning power, speed of foaming, foam creaminess, rinsing feel, and feeling after drying. . The surfactant is an essential component for the cleaning agent, and the current cleaning agent includes various types of surfactants that give the above-mentioned quality.
On the other hand, there are many needs for a whole body shampoo that can wash hair and body at the same time for the purpose of washing infants and shortening bathing time. A characteristic function required for the whole body shampoo is that the eyes do not itch when they enter the eyes.

  Conventionally, in order to improve detergency, speed of foaming, and creaminess of foam, anionic surfactants such as polyoxyethylene alkyl ether sulfates and amphoteric surfactants such as betaines are rarely contained. Absent. In addition, in order to reduce irritation when entering the eyes, sugar surfactants such as alkyl glucosides may be contained. (For example, refer patent documents 1-8).

JP-T-2006-519808 Special table 2015-521597 gazette Japanese Patent Laid-Open No. 2003-113073 JP 2006-036775 A JP 2006-257084 A JP 2010-265189 A JP 2011-136922 A JP 2014-122196 A

However, detergents using anionic surfactants or amphoteric surfactants have good detergency, quick foaming, foam creaminess and rinsing feeling, but no irritation when entering the eyes. Is not always enough. On the other hand, detergents using sugar surfactants such as alkyl glucosides have good irritation when they enter the eyes, but they have good cleaning power, quick foaming, foam creaminess and rinsing feeling. Not always enough.

The present invention has been made in view of the above circumstances, and has detergency, speed of foaming, foamy creaminess, rinsing feeling, and feeling after drying, and is excellent in lack of irritation when entering the eyes. It is an object of the present invention to provide a cleaning composition.

As a result of intensive studies, the present inventors have found that a specific oleic acid and methyl glucose diester or triester polyethylene glycol ether, a specific lauryl glucoside and / or decyl glucoside alkyl glucoside, and polyoxyethylene alkyl ether sulfate. By blending a certain proportion of a betaine amphoteric surfactant selected from esters, lauramidopropyl betaine and / or cocamidopropyl betaine betaine into the detergent composition, detergency, speed of foaming, foam creaminess The present inventors have found that it has a feeling of rinsing and a feeling after drying, and that the feeling of irritation when entering the eyes can be remarkably improved.

That is, this invention has the following aspects.
[1] A cleaning composition comprising the following components (A) to (D).
(A) Polyethylene glycol ether of diester or triester of oleic acid and methyl glucose (B) Alkyl glucoside selected from lauryl glucoside and / or decyl glucoside (C) Polyoxyethylene alkyl ether sulfate salt (D) Lauramide propyl betaine Betaine amphoteric surfactant selected from and / or cocamidopropyl betaine betaine

[2] The content of the component (A) is 0.01 to 5% by mass, the content of the component (B) is 0.1 to 10% by mass, and the content of the component (C) is It is 0.1-10 mass%, Content of the said (D) component is 0.1-5 mass% mass%, The cleaning composition as described in [1] characterized by the above-mentioned.

The cleaning composition of the present invention combines detergency, speed of foaming, foam creaminess, rinsing feeling, and feeling after drying, and is excellent in no irritation when entering the eyes.

Hereinafter, the present invention will be described in detail.
The cleaning composition of the present invention is a cleaning composition containing the following components (A) to (D).

<(A) component>
The component (A) is a polyethylene glycol ether of a diester or triester of oleic acid and methyl glucose.
The component (A), a diester or triester polyethylene glycol ether of oleic acid and methylglucose, improves the creaminess of the foam, the softness of the hair after drying, and the lack of irritation when entering the eyes. Contained.
Examples of the polyethylene glycol ether of diester or triester of oleic acid and methyl glucose as the component (A) include PEG-120 methyl glucose dioleate, PEG-120 methyl glucose trioleate, and the like. These may be commercially available products or may be appropriately synthesized. Examples of the commercially available products include PEG-120 methylglucose dioleate, trade name: GLUCAMATE DOE-120 (manufactured by Luvrizol), and PEG-120 methylglucose trioleate, trade name: GLUCAMATE VLT Thickener (manufactured by Luvrizol). ) And the like. These may be used alone or in combination of two or more. Among these, PEG-120 methyl glucose trioleate is preferable from the viewpoint of creaminess of foam, softness of the hair after drying, and lack of irritation when entering the eyes. In PEG-120, PEG represents polyethylene glycol, and 120 represents the average number of moles added of polyethylene glycol.

  Content of polyethylene glycol ether of diester or triester of oleic acid and methylglucose as component (A) mentioned above is the speed of foaming, creaminess of foam, softness of hair after drying, smoothness of skin after drying From the point of lack of irritation when entering the eyes, it is 0.01% by mass to 5% by mass and preferably 0.1% by mass to 4% by mass with respect to the total amount of the skin cleansing composition. When the content is less than 0.01% by mass, the creaminess of foam, the softness of the hair after drying, and the lack of irritation when entering the eyes may be insufficient. Exceeding may cause insufficient foaming and insufficient smoothness of the skin after drying.

<(B) component>
The component (B) is an alkyl glucoside selected from lauryl glucoside and / or decyl glucoside.
The alkyl glucoside selected from the lauryl glucoside and / or decyl glucoside of the component (B) has a quick foaming, foam creaminess, smooth skin when rinsing, smooth skin after drying, and eyes. Contained to improve the absence of irritation.
As the lauryl glucoside and / or decyl glucoside of the component (B), commercially available products may be used, or those appropriately synthesized may be used. Examples of the commercially available product include, for example, trade name: Plantacare 1200UP (manufactured by BASF) as lauryl glucoside, trade name: Mydoll 12 (manufactured by Kao), and trade name: Plantacare 2000UP (manufactured by BASF). ), Trade name: Mydoll 10 (manufactured by Kao). These may be used alone or in combination of two or more.

  The content of the alkyl glucoside selected from the lauryl glucoside and / or decyl glucoside of the component (B) is the speed of foaming, creaminess of foam, no irritation when entering the eyes, From the point of smoothness, smoothness of the skin after drying, and no irritation when entering the eyes, it is 0.1% by mass to 10% by mass with respect to the total amount of the skin cleansing composition, and 0.5 The mass% to 5 mass% is preferable. When the content is less than 0.1% by mass, the speed of foaming, the creaminess of foam, the smoothness of the skin when rinsing, the smoothness of the skin after drying, and the feeling of irritation when entering the eyes When the amount exceeds 10% by mass, the speed of foaming and the smoothness of the skin after drying may be insufficient.

<(C) component>
Component (C) is a polyoxyethylene alkyl ether sulfate ester salt.
The (C) component polyoxyethylene alkyl ether sulfate ester salt is contained in order to improve detergency, speed of foaming, and creaminess of foam.
(C) A component is shown by the anionic surfactant containing the polyoxyethylene alkyl ether sulfate represented by following General formula (1).

R ₁ O (CH2CH2O) mSO3M ・ ・ ・ General formula (1)

[In the general formula (1), R ₁ represents an alkyl group having 10 to 14 carbon atoms, M represents any one of alkali metal, ammonium, and alkanolamine, and m represents an average addition mole. A number from 1 to 5 is shown. ]

The polyoxyethylene alkyl ether sulfate salt of the component (C) preferably has 10 to 14 carbon atoms in the alkyl group R ₁ portion of the polyoxyethylene alkyl ether sulfate ester salt from the viewpoint of rapid foaming. Is more preferable. When the carbon number is less than 10 or exceeds 14, the speed of foaming of the skin cleansing composition may be insufficient.
The average added mole number m of ethylene oxide of the polyoxyethylene alkyl ether sulfate ester salt is preferably 1 to 5 and more preferably 2 to 3 from the viewpoint of foam stability. When the average added mole number of the ethylene oxide is less than 1 or exceeds 5, the creamy property of the foam may be insufficient.

  Examples of the counter ion M of the (C) component polyoxyethylene alkyl ether sulfate ester salt include alkali metal ions such as sodium and potassium; ammonium ions; alkanolamines such as monoethanolamine, diethanolamine and triethanolamine. Can be mentioned. Among these, alkali metal ions are preferable and sodium is more preferable from the viewpoint of rapid foaming.

  As the polyoxyethylene alkyl ether sulfate ester salt of component (C), a commercially available product may be used, or an appropriately synthesized product may be used. Examples of the commercially available products include polyoxyethylene (1) sodium lauryl ether sulfate (also known as sodium laureth sulfate (1)), trade name: Sinoline SPE-1100 (manufactured by Shin Nippon Rika Co., Ltd.), trade name: Sinoline. SPE-1150 (manufactured by Shin Nippon Rika Co., Ltd.), trade name: Emar 125HP (manufactured by Kao Corporation), trade name: Emar 170J (manufactured by Kao Corporation), and the like.

As polyoxyethylene (2) sodium lauryl ether sulfate (aka: sodium laureth sulfate (2)), trade name: Sinoline SPE-1200K (manufactured by Shin Nippon Rika Co., Ltd.), trade name: Sinoline SPE-1250 (Shin Nihon Rika Co., Ltd.) Product name: Texapon 27L (manufactured by BASF), product name: Arscope A-225B (manufactured by Toho Chemical Industry Co., Ltd.), product name: Arscope A-225B (manufactured by Toho Chemical Industry Co., Ltd.), product name: Emar 270J (made by Kao Corporation), trade name: Emar E-27C (made by Kao Corporation), trade name: Emar 227HP (made by Kao Corporation), trade name: Emar E-227S-S (made by Kao Corporation), and the like.

Polyoxyethylene (3) sodium lauryl ether sulfate (also known as sodium laureth sulfate (3)) is trade name: Sinoline SPE-1300 (manufactured by Shin Nippon Rika Co., Ltd.), trade name: Sinoline SPE-1350 (Shin Nihon Rika Co., Ltd.) Product name: Sannol LMT-1430 (manufactured by Lion), product name: Emar 327 (manufactured by Kao), product name: Emar 20C (manufactured by Kao), product name: Emar 20CM (manufactured by Kao) Can be mentioned.

These may be used alone or in combination of two or more. Among these, polyoxyethylene (2) sodium lauryl ether sulfate and polyoxyethylene (3) sodium lauryl ether sulfate are preferable from the viewpoint of the speed of foaming and creaminess of the foam. In addition, the number in () represents the average addition mole number of the ethylene oxide of the said polyoxyethylene alkyl ether sulfate ester salt.

  The content of the component (C) polyoxyethylene alkyl ether sulfate ester salt is detergency, speed of foaming, creaminess of foam, softness of hair after drying, lack of irritation when entering eyes From the point, it is 0.1 mass%-5 mass% with respect to the skin cleaning composition whole quantity, and 0.5 mass%-4 mass% are preferable. When the content is less than 0.1% by mass, the detergency, the speed of foaming, and the creaminess of the foam may be insufficient. When the content exceeds 5% by mass, the speed of foaming, after drying The softness of the hair and the lack of irritation when entering the eyes may be insufficient.

<(D) component>
The component (D) is a betaine amphoteric surfactant selected from lauramidopropyl betaine and / or cocamidopropyl betaine.
The betaine amphoteric surfactant selected from the component (D), lauramidopropyl betaine and / or cocamidopropyl betaine betaine, is included to improve detergency, speed of foaming, and smoothness of the skin during rinsing. Has been.

As the lauramidopropyl betaine and / or cocamidopropyl betaine as the component (D), commercially available products may be used, or those appropriately synthesized may be used.

Examples of the commercially available products include, for example, lauramide propyl betaine, trade name: Amphitol 20AB (manufactured by Kao Corporation), trade name: Amphorex LB-2 (manufactured by Miyoshi Oil & Fats Co., Ltd.), trade name: Enagicol L-30B (Lion Product name: Softazolin LPB (manufactured by Kawaken Fine Chemical Co., Ltd.), product name: Softazolin LPB-R (manufactured by Kawaken Fine Chemical Co., Ltd.), product name: Nissan Anon BDL-S (manufactured by NOF Corporation), product name: Nissan Anon BDL-SF (manufactured by NOF Corporation), product name: Marpovister LAP (manufactured by Matsumoto Yushi Seiyaku Co., Ltd.), product name: Adeka Anhhot PB-30L (manufactured by ADEKA), product name: Anholex KSB-40 (Miyoshi Oil & Fat Co., Ltd.) Product name): Anholex ASH (manufactured by Miyoshi Oil & Fats Co., Ltd.).

As the cocamidopropyl betaine, trade name: Tego Bet Tegoaine L7 (Evonic), trade name: Anhitoal 55AB (Kao), trade name: Anholex CB-1 (Miyoshi Oil & Fats Co., Ltd.), trade name: Enagicol C -30B (manufactured by Lion), product name: ovazoline CAB-30 (manufactured by Toho Chemical Industry Co., Ltd.), product name: softazolin CPB (manufactured by Kawaken Fine Chemical Co., Ltd.), product name: softazolin CPB-R (manufactured by Kawaken Fine Chemical Co., Ltd.) , Product name: Nissan Anon BDF-S (manufactured by NOF Corporation), product name: NISSAN ANON BDF-SF (manufactured by NOF Corporation), product name: Marpovistor CAP-H (manufactured by Matsumoto Yushi Seiyaku Co., Ltd.), product name: Marpovister And CAP-Y (Matsumoto Yushi Seiyaku Co., Ltd.). These may be used alone or in combination of two or more.

  The content of the betaine amphoteric surfactant selected from the component (D), lauramidopropyl betaine and / or cocamidopropyl betaine betaine, is detergency, speed of foaming, and lack of irritation when in contact with eyes. From the point of smoothness of the skin at the time of rinsing and lack of irritation when entering the eyes, it is 0.1% by mass to 10% by mass and 0.5% by mass with respect to the total amount of the skin cleansing composition. -5 mass% is preferable. When the content is less than 0.1% by mass, the detergency, the speed of foaming, and the smoothness of the skin at the time of rinsing may be insufficient. When the content exceeds 10% by mass, The smoothness of the skin, the softness of the hair after drying, and the lack of irritation when entering the eyes may be insufficient.

<Optional component>
The emulsified fuel of the present invention contains, in addition to the components (A) to (D), other components that are used in ordinary cleaning compositions within the range that does not impair the effects of the present invention, if necessary. You may contain suitably.

  The other components are not particularly limited and may be appropriately selected depending on the purpose. For example, oil, alcohols, humectants, thickeners, preservatives, antioxidants, chelating agents, pH adjusters , UV absorbers / scattering agents, vitamins, amino acids, fragrances, pigments, water and the like can be appropriately contained as necessary. These may be used alone or in combination of two or more. In addition, the other component contained in the cleaning composition of this invention is not limited to the said other component.

  Examples of the oil component include castor oil, olive oil, cacao oil, hydrogenated palm oil, coconut oil, coconut oil, tree wax, jojoba oil, grape seed oil, avocado oil and the like, or their ester compounds; mink oil, Animal fats such as egg yolk oil; waxes such as beeswax, whale wax, lanolin, hydrogenated lanolin, carnauba wax, candelilla wax; hydrocarbons such as liquid paraffin, squalane, microcrystalline wax, ceresin wax, paraffin wax, petroleum jelly Natural and synthetic fatty acids such as lauric acid, myristic acid, stearic acid, oleic acid, isostearic acid, behenic acid; glycerol tri-2-ethylhexanoate, 2-ethylhexyl stearate, butyl stearate, isopropyl myristate, Isopropyl palmitate Octyldodecyl myristate, octyldodecyl oleate, esters such as cholesterol oleate; such as dimethylpolysiloxane.

  Examples of the alcohols include natural and synthetic higher alcohols such as cetyl alcohol, oleyl alcohol, stearyl alcohol, hexyl decanol, octyl decanol, and lauryl alcohol.

  Examples of the humectant include 1,3-butanediol, isoprene glycol, 1,2-pentanediol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, diethylene glycol monoalkyl ether, polyethylene glycol (average molecular weight of 190 to 1,650), polypropylene glycol, polyethylene glycol / polypropylene glycol, hydrogenated castor oil (30E.O.), glycerin, diglycerin, triglycerin, polyglycerin, sorbitol and the like.

  Examples of the thickener include natural polymers such as sodium alginate, xanthan gum, aluminum silicate, quince seed extract, tragacanth gum and starch; semi-synthetic polymers such as methylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose and soluble starch. Molecules: Synthetic polymer compounds such as carboxyvinyl polymer, polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, methacryloylethylbetaine / methacrylic acid ester copolymer, and the like.

  Examples of the preservative include benzoate, sorbate, dehydroacetate, paraoxybenzoate, 2,4,4′-trichloro-2′-hydroxydiphenyl ether, and 3,4,4′-trichlorocarbani. Lido, benzalkonium chloride, hinokitiol, resorcin, methylchloroisothiazolinone / methylisothiazolinone solution (trade name: Caisson CG, manufactured by Rohm and Haas Japan), salicylic acid, pentanediol, phenoxyethanol, ethanol, etc. Can be mentioned.

  Examples of the antioxidant include dibutylhydroxytoluene, butylhydroxyanisole, ascorbic acid and the like.

  Examples of the chelating agent include disodium ethylenediaminetetraacetate, ethylenediaminetetraacetate, hexametaphosphate, and gluconic acid.

  Examples of the pH adjuster include sodium hydroxide, potassium hydroxide, citric acid, sodium citrate, succinic acid, triethanolamine, aqueous ammonia, triisopropanolamine, phosphoric acid, glycolic acid and the like.

  Examples of the ultraviolet absorbing / scattering agent include 2-hydroxy-4-methoxybenzophenone, octyldimethylparaaminobenzoate, ethylhexylparamethoxycynamate, titanium oxide, kaolin, and talc.

Examples of the vitamins include vitamin A, vitamin B group, vitamin C, vitamin D, vitamin E, vitamin F, vitamin K, vitamin P, vitamin U, carnitine, ferulic acid, γ-oryzanol, α-lipoic acid, Examples include orotic acid and derivatives thereof.
Examples of the amino acids include glycine, alanine, valine, leucine, isoleucine, phenylalanine, tryptophan, cystine, cysteine, methionine, proline, hydroxyproline, aspartic acid, glutamic acid, arginine, histidine, lysine, and derivatives thereof. It is done.

Examples of the fragrance and the fragrance composition include the fragrance components described in paragraphs [0021] to [0035] of JP-A-2003-300121, and further the fragrance described in paragraph [0050] of JP-A-2003-300111. Solvents for use.
As content of the said fragrance | flavor composition, 0.005 mass%-40 mass% are preferable with respect to cleaning composition whole quantity, and 0.01 mass%-10 mass% are more preferable.

-Manufacturing method-
There is no restriction | limiting in particular as a manufacturing method of the shampoo composition of this invention, According to the objective, it can select suitably, For example, the said (A) component, the said (B) component, the said (C) component, and the said (D) A detergent composition can be manufactured by adding a component and the said other component, stirring and mixing.

-Viscosity-
There is no restriction | limiting in particular as a viscosity of the said cleaning composition, Although it can select suitably according to the objective, 200 mPa * s-6,000 mPa * s are preferable at 25 degreeC. The viscosity adjusting agent is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include hexylene glycol and ethanol. When the viscosity is less than 200 mPa · s or exceeds 6,000 mPa · s, the foaming speed may be insufficient.
As the viscosity, for example, using a viscometer (BM type viscometer, manufactured by Tokyo Keiki Co., Ltd.) at 25 ° C., No. Using a No. 3 or No. 4 rotor, measurement can be performed at 30 rpm for 30 seconds.

-PH-
There is no restriction | limiting in particular as pH of the said cleaning composition, Although it can select suitably according to the objective, 4-7 are preferable at 25 degreeC.
The pH can be measured, for example, at 25 ° C. using a pH meter (trade name: HM-30G, manufactured by Toa DKK Corporation). The pH adjuster is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include citric acid, sodium citrate, succinic acid, sulfuric acid, 2-amino-2-methyl-1-propanol, mono Ethanolamine or a salt thereof is exemplified.

-Container-
The cleaning composition can be used by filling a container. The container is not particularly limited and can be appropriately selected according to the purpose. For example, aluminum laminate tube, EVAL tube, aluminum tube, glass-deposited plastic tube tube, mechanical or differential pressure dispenser container, squeeze Examples include containers, laminate film containers, dropper containers, bottle containers, and pump-type containers.
Examples of the material of the laminate film include polyethylene, polyethylene terephthalate, polyester, biaxially stretched polypropylene, unstretched polypropylene, polyacrylonitrile, a synthetic resin such as an ethylene-vinyl acetate copolymer, paper, and aluminum vapor-deposited plastic. . Further, the structure of the laminate film usually has two or more layers, and generally 2 to 5 layers are preferred in consideration of strength, flexibility, weather resistance and the like.
The material of the bottle is appropriately selected from, for example, polyethylene, polypropylene, polyethylene terephthalate, polystyrene, polyvinyl chloride, ethylene-vinyl alcohol resin, acrylonitrile / styrene resin, ABS resin, polyamide resin, and glass. Further, the structure of the container is preferably a single layer or a layer structure of two or more layers.

-Use-
The use of the cleaning composition of the present invention is not particularly limited and may be appropriately selected depending on the purpose. Examples thereof include shampoos, whole body shampoos, body shampoos, hand soaps, facial cleansers, and the like. Whole body shampoos and body shampoos are preferred. In the case of a shampoo, it can be used not only for human hair but also for animal hair such as pets.

  EXAMPLES The present invention will be specifically described below with reference to examples of the present invention, but the present invention is not limited to these examples. In the following examples, “%” represents “% by mass”, and the contents of the respective components described in Examples and Comparative Examples are all in terms of pure content.

(Examples 1-28, Comparative Examples 1-4)
According to the compositions shown in Tables 1 to 6, the cleaning compositions of Examples 1 to 28 and Comparative Examples 1 to 4 were prepared by a conventional method.
Specifically, first, (B) component, (C) component, (D) component, common component, part of purified water are lined up with 3 one motor (trade name: HEIDEN FBLHEIDEN1200, manufactured by Shinto Kagaku Co., Ltd.) Were mixed evenly at 25 ° C. using an inclined paddle. Subsequently, the pH at 25 ° C. was measured using a pH meter HM-30V (manufactured by Toa DKK Co., Ltd.), and the pH was adjusted to 6.0 using citric acid. When pH 6.0 was reached, component (A) was added and mixed uniformly at 25 ° C., then, using a viscometer (BM type viscometer, manufactured by Tokyo Keiki Co., Ltd.) Using 3 rotors, the viscosity was measured at 60 rpm for 12 seconds. Using hexylene glycol, the viscosity was adjusted to 1,000 mPa · s at 25 ° C. After adjusting the viscosity, finally the remaining purified water was added, and water was added so as to be 100% by mass as a whole.

About each obtained cleaning composition, various characteristics were evaluated based on the following evaluation method. The results are shown in Tables 1 to 6.

<Evaluation method of detergency, speed of foaming, creaminess of foam, smoothness of skin during rinsing, smoothness of skin after drying, and softness of hair after drying>
After exercising in a room with a temperature of 27 ° C and a humidity of 70% RH, the female panelists used 20 women at a dose of about 6 mL / dose, and they were fully foamed (hair and body). ) Was washed off with a shower at a tap water temperature of 40 ° C. and a flow rate of 250 mL / 3 seconds. After drying, based on the following evaluation method and criteria, "detergency", "speed of foaming", "creaminess of foam", "smoothness of skin after rinsing", "smoothness of skin after drying" ”And“ softness of hair after drying ”were evaluated.

<< Detergency >>
The “detergency” was evaluated based on the following evaluation criteria by the number of respondents who answered “they have detergency” among the 20 female specialized panels. Here, “having detergency” means that the scalp and hair sebum is removed and the skin feels clean.
[Evaluation criteria]
◎: At least 18 out of 20 women-specialized panels answered that they have “detergency” ◎ to ○: From 15 to 17 out of 20 women-specialized panels answered that they had “detergency” ○: Panel dedicated to women 11 to 14 out of 20 responded that they have “detergency” △: 7 to 10 out of 20 women specialized panels answered that they had “detergency” ×: 6 out of 20 women specialized panels Names below responded that they have detergency

<< Speed of foaming >>
The “fastness of foaming” was evaluated based on the following evaluation criteria by the number of respondents who answered “fast foaming” among the 20 women-specialized panels. Here, “fast foaming” means that when 6 mL of each cleaning composition is taken and foamed throughout the body (hair and body), the number of reciprocations until foaming is small.
[Evaluation criteria]
◎: More than 18 out of 20 women-specialized panel responded that “Foaming is fast” ◎ to ○: 15-out of 17 women-specialized panel and 17 or less responded that “Early Foaming” ○: 20 panels dedicated to women 11 to 14 of them answered “Early foaming” △: 7 to 10 out of 20 female professional panel responded “Early foaming” ×: 6 or less of 20 female specialized panels said “ Reply “Fathering is fast”

<< Creamy property of foam >>
The “foam creaminess” was evaluated based on the following evaluation criteria by the number of respondents who answered “foam is creamy” among 20 women-specialized panels. Here, “bubbles are creamy” means that 6 mL of each detergent composition is taken, the palms are rubbed together so that the palms of both hands are reciprocated, and the appearance of the bubbles is visually observed when both hands are reciprocated 10 times. This means that the bubbles are fine and soft when observed.
[Evaluation criteria]
◎: 18 or more out of 20 women-specialized panel responded that "bubbles are creamy" ◎ ~ ○: 15 to 17 out of 20 women-specialized panels answered that "bubbles are creamy" ○: Women 11 to 14 out of 20 professional panels responded that “foam is creamy” △: 7 to 10 out of 20 professional panelists responded that “foam is creamy” ×: Special panel for women Less than 6 out of 20 responded that the bubbles are creamy

<< Skin smoothness during rinsing >>
The “smoothness of the skin at the time of rinsing” was evaluated based on the following evaluation criteria by the number of respondents who answered “the skin at the time of rinsing was smooth” among the 20 female specialized panels.
[Evaluation criteria]
◎: 18 or more out of 20 women-specialized panel responded that “the skin when rinsing is smooth” ◎ to ○: 15 to 17 out of 20 women-specialized panel “smooth when rinsing. ○: 11 to 14 out of 20 women-specialized panel responded that “the skin when rinsing is smooth” △: 7 to 10 out of 20 female-specialized panels expressed “skin at the time of rinsing” ×: 6 or less of 20 female specialist panels answered that “the skin during rinsing is smooth”

<< Skin smoothness after drying >>
The “smoothness of the skin after drying” was evaluated based on the following evaluation criteria by the number of respondents who answered “smooth of the skin after drying” among the 20 women-specialized panels.
[Evaluation criteria]
◎: More than 18 out of 20 women-specialized panel responded that “the skin is smooth after drying” ◎ to ○: 15 to 17 out of 20 women-specialized panel is “the skin is smooth after drying” ○: 11 to 14 out of 20 women-specialized panel responded that “the skin is smooth after drying” △: 7 to 10 out of 20 female-specialized panels were “skin after drying” No: 6 out of 20 female professional panels answered that the skin is smooth after drying.

<< Softness of hair after drying >>
The “softness of hair after drying” was evaluated based on the following evaluation criteria by the number of respondents who answered “soft hair after drying” among the 20 women-specialized panels.
[Evaluation criteria]
◎: More than 18 out of 20 female professional panel responded that “the hair after drying is soft” ◎ to ○: 15 or more out of 20 female professional panel responded that “the hair after drying is soft” ○ : 11 to 14 out of 20 women-specialized panels answered “soft hair after drying” △: 7 to 10 out of 20 female-specialized panels answered “soft hair after drying” × : Out of 20 women-specialized panels, 6 or less responded that “the hair after drying is soft”

<Evaluation method for lack of irritation when it enters eyes>
A sample diluted to 1% was filled in an eye drop container, and three male panelists showed the absence of irritation when entering the eyes according to the following evaluation criteria according to the number of people who responded that there was no irritation.
[Evaluation criteria]
A: All three people judged that “no eye irritation”.
○: Two people judged that “no eye irritation”.
Δ: One person judged “no eye irritation”.
X: All three persons judged that “there is eye irritation”.

In addition, the specific content of the raw material used by the cleaning agent composition of Examples 1-28 and Comparative Examples 1-4 is as showing below.

Claims (2)

A cleaning composition comprising the following components (A) to (D):
(A) Polyethylene glycol ether of diester or triester of oleic acid and methyl glucose (B) Alkyl glucoside selected from lauryl glucoside and / or decyl glucoside (C) Polyoxyethylene alkyl ether sulfate salt (D) Lauramide propyl betaine Betaine amphoteric surfactant selected from and / or cocamidopropyl betaine betaine (A) The content of polyethylene glycol ether of oleic acid and methyl glucose diester or triester is 0.01 to 5% by mass,
(B) The content of alkyl glucoside selected from lauryl glucoside and / or decyl glucoside is 0.1 to 10% by mass,
(C) The content of the polyoxyethylene alkyl ether sulfate salt is 0.1 to 10% by mass,
(D) Content of betaine amphoteric surfactant chosen from lauramidopropyl betaine and / or cocamidopropyl betaine betaine is 0.1-5 mass% mass%, It is characterized by the above-mentioned. Cleaning composition.