KR20150081248A - Shampoo composition - Google Patents

Abstract

(A) a specific amount of an anionic surfactant, (B) a cationic polymer, (C) a specific amount of a silicone compound, and (D) a specific amount of a gloss-imparting agent, Wherein the component (B1) and the component (B2) are in a specific mass ratio and the component (C) is (C1) dimethylpolysiloxane and (C1) dimethylpolysiloxane. C2) amino-modified silicone, and the component (C1) and the component (C2) are in a specific mass ratio.

Description

Shampoo composition {SHAMPOO COMPOSITION}

The present invention relates to a shampoo composition.

Conventionally, a conditioner or a treatment is generally used after use of the shampoo composition for the purpose of improving the finished feeling of hair after shampooing. In addition, many techniques of shampoo compositions having the effect of improving the feel of the hair after drying by using only the shampoo composition have been developed and marketed as conditioning shampoo. As the conditioning shampoo, for example, it has been proposed to incorporate a cationic polymer, various silicone compounds, an oil component, a cationic surfactant, and the like into a shampoo composition as a texture imparting agent (see, for example, 4).

However, in the shampoo compositions of these proposals, most of the ingredients are washed away, the stiff feeling by the polymer is not expressed, the sufficient lubrication property can not be given to the hair, and the feel of the hair after drying It is not possible to obtain.

On the other hand, it has been common practice to blend a pearlizing agent to impart shine purity to the shampoo composition and to increase the value of the product, and there is a method of controlling the glossiness of the pearling agent and a method of controlling the glossiness of the pearling agent And the like have been proposed. Further, a technique of blending a pearlizing agent into a shampoo composition for stabilizing a silicone compound, which is one of the above-mentioned feel imparting agents, has also been proposed (see, for example, Patent Documents 5 to 7).

However, when a large amount of the above-described pilling agent is blended into the shampoo composition, fine and creamy foam can not be obtained when the shampoo composition is foamed at the time of shaving, and friction occurs between the foamed hair and the fingers, Deterioration of the feeling of washing of the hair such as deteriorating the fingering of the hair and disappearance of the foam at the time of rinsing are worsened, and the hair is not smooth at the time of rinsing, the drying of the hair after the hair is delayed, There is a problem that the conditioning effect such as insufficient persistence of one sensation is deteriorated.

Patent Document 1: Japanese Patent Specification No. 2010-512406 Patent Document 2: Japanese Patent Application Laid-Open No. 2007-45726 Patent Document 3: Japanese Patent Application Laid-Open No. 2006-219449 Patent Document 4: Japanese Patent Laid-Open No. 2005-506989 Patent Document 5: JP-A-2010-155903 Patent Document 6: JP-A-2006-316035 Patent Document 7: JP-A-9-500127

DISCLOSURE OF THE INVENTION The present invention is intended to solve the above-mentioned problems and achieve the following objects. In other words, it is an object of the present invention to provide a cosmetic composition which is excellent in hand marks of a hair when foaming at the time of shaving and disappearance of foaming at the time of rinsing, smoothness can be imparted to the hair at the time of rinsing, It is an object of the present invention to provide a shampoo composition which combines a high sensation of feeling of washing and a conditioning effect, which can endure a feeling of being missed for a long time.

The shampoo composition of the present invention as a means for solving the above problems comprises (A) 5 to 30 mass% of an anionic surfactant, (B) a cationic polymer, (C) 0.1 to 10 mass% (B) is composed of (B1) a cationic guar gum and (B2) a cationized cellulose, and (D) the gloss-imparting agent in an amount of 1 to 5 mass% Wherein the mass ratio (B1) / (B2) of the component (B1) to the component (B2) is 2 to 20 and the component (C) is composed of (C1) dimethylpolysiloxane and (C2) , And the mass ratio (C1) / (C2) of the component (C1) to the component (C2) is 2 to 30.

According to the present invention, it is possible to solve the above-mentioned problems in the prior art and to achieve the above object, and to provide a cosmetic composition which is excellent in hand marks of the hair when foaming at the time of shaving and disappearance of foaming at the time of rinsing, It is possible to provide a shampoo composition which can impart smoothness, has a high drying sensation after hair shaving, gives a feeling of prominent feeling to the head end after drying, and a conditioning effect.

(Shampoo composition)

The shampoo composition of the present invention is a shampoo composition comprising an anionic surfactant (hereinafter may be referred to as "component (A)"), a cationic polymer (hereinafter may be referred to as "component (B)") (Hereinafter may be referred to as "component (C)") and a gloss-imparting agent (hereinafter, may be referred to as "component (D)") .

≪ Component (A): Anionic surfactant >

The anionic surfactant as the component (A) is a component that forms a suitable foam and also serves as a cleansing agent for removing dirt adhering to the hair.

The component (A) is not particularly limited and can be appropriately selected in accordance with the purpose. For example, a sulfate type anionic surfactant having a sulfuric acid residue (remaining group), a sulfonic acid salt type anionic surfactant having a sulfonic acid residue, A carboxylate type anionic surfactant having a carboxylic acid residue, an amino acid salt type anionic surfactant having an amino acid salt residue, and the like. These may be used alone, or two or more kinds may be used in combination.

Examples of the sulfate anionic surfactant include alkyl sulfates, alkenyl sulfates, polyoxyalkylene alkyl ether sulfates, polyoxyalkylene alkenyl ether sulfates, polyoxyalkylene alkyl phenyl ether sulfates, glyceride sulfates, amides Ether sulfates and the like.

Examples of the sulfonic acid salt type anionic surfactant include alkylbenzenesulfonic acid salts, alkylsulfosuccinate alkyl ester salts, polyoxyalkylene sulfosuccinate alkyl ester salts,? -Olefin sulfonic acid salts, alkanesulfonic acid salts,? -Sulfo fatty acid ester salts And the like.

Examples of the carboxylate salt type anionic surfactant include higher fatty acid salts having 10 or more carbon atoms, alkyl ether carboxylates, and the like.

Examples of the amino acid salt type anionic surfactant include N-acyl-L-gloatomer salt and lauroylmethyl alanine salt.

The salt is not particularly limited and can be appropriately selected in accordance with the purpose. Examples thereof include alkali metal salts such as sodium and potassium; Ammonium; Alkanolamine, and the like.

Of these, polyoxyalkylene alkyl ether sulfate, polyoxyalkylene alkyl ether sulfate, alkyl sulfate, and the like are preferable as the above-mentioned sulfate anionic surfactant, (Hereinafter may be referred to as "component (A1)") and an anionic surfactant represented by the following general formula (A2) (hereinafter sometimes referred to as "component (A2)" ) Is more preferable.

R ¹ O (CH ₂ CH ₂ O) _m SO ₃ M ¹ ... In formula (A1)

(Wherein, in the general formula (A1), R ¹ represents an alkyl or alkenyl group having 10 to 18 carbon atoms, M ¹ represents any one of an alkali metal, ammonium, and alkanolamine, Represents the number of 1 to 5 in the number of moles.]

R ² OSO ₃ M ² ... In general formula (A2)

[Wherein, in the general formula (A2), R ² represents an alkyl group having 10 to 18 carbon atoms, and M ² represents any one of an alkali metal, ammonium, and alkanolamine.]

R ¹ in formula (A1) and / or R ² in formula (A2) in the formula (A1) preferably have a number average molecular weight of from ¹ to 100, An alkyl group of 12 to 16 is preferred. Further, m in the formula (A1) is preferably 2 to 3 since smoothness can be imparted to the hair during the rinsing. In view of the fact that M ¹ in the general formula (A1) or M ² in the general formula (A2) is particularly fast in the drying of hair after hair fogging, ammonium is particularly preferable.

As the component (A), a commercially available product may be used, or a properly synthesized product may be used. Specific examples of the commercially available products include Texapon ALES 70 (POE (3) ammonium lauryl ether sulfate, BASF), Sinorin SPE-1250 (POE (2) lauryl ether sodium sulfate, Of component (A1); (A2) such as Texapon ALS 70 (ammonium lauryl sulfate, BASF), Texapon K12 (sodium lauryl sulfate, BASF), and the like.

As the component (A), it is particularly preferable to use the component (A1) and the component (A2) in combination. When the component (A) is only the component (A1), deterioration of foam disappears at the time of rinsing, the smoothness of the hair at the time of rinsing is lowered, the drying of the hair after shaving is delayed, There is a tendency that the feeling of the end of the end is reduced. When the component (A) is only the component (A2), the scratching of the hair at the time of hair firming may be deteriorated and the smoothness of the hair at the time of rinsing may be lowered.

The content of the component (A1) in the shampoo composition is preferably 3% by mass to 24% by mass, more preferably 5% by mass to 22% by mass, and particularly preferably 7% by mass to 15% by mass. When the content of the component (A1) is less than 3% by mass, the scratching of the hair at the time of hair firming is deteriorated and the smoothness of the hair at the time of rinsing is lowered. When the content is more than 24% by mass, There is a possibility that the extinction of foam disappears, the drying of the hair after shampoo is delayed, and the sensation of hairiness after drying is lowered.

The content of the component (A2) in the shampoo composition is preferably 1% by mass to 15% by mass, more preferably 2% by mass to 12% by mass, and particularly preferably 3% by mass to 10% by mass. If the content of the component (A2) is less than 1% by mass, bubble extinction at the time of rinsing is deteriorated, drying of hair after shaving is delayed, And if it exceeds 15% by mass, the scratches of the hair at the time of hair firming may deteriorate, and the smoothness of the hair at the time of rinsing may be lowered.

The content of the component (A) (the total content of the component (A1) and the component (A2) in the shampoo composition) Bubbles disappear at the time of rinsing. 5% by mass to 30% by mass, preferably 10% by mass to 25% by mass, and particularly preferably 12% by mass to 20% by mass, If the content of the component (A) is less than 5% by mass, the scratching of the hair at the time of hair firming may be deteriorated, the smoothness of the hair at the time of rinsing, When the content is more than 30% by mass, deterioration of the flesh of the hair at the time of firing, deterioration of foam disappear at the time of rinsing, deterioration of the smoothness of the hair at the time of rinsing, There is a possibility that the sensation of hairiness at the tip of the hair after drying may be lowered.

The mass ratio (A1) / (A2) of the component (A1) to the component (A2) It is preferably from 1 to 7, more preferably from 1.3 to 4, since smoothness can be imparted to the hair at the time of rinsing and a feeling of being prickly can be imparted to the hair end after drying. When the mass ratio (A1) / (A2) is less than 1, the smoothness of the hair at the time of rinsing may be lowered, and when it exceeds 7, the hair after drying may be delayed in drying.

≪ Component (B): cationic polymer >

The cationic polymer as the component (B) is a cationically polymerized product obtained by copolymerizing a cationic guar gum (hereinafter may be referred to as "component (B1)") and cationized cellulose (hereinafter sometimes referred to as "component (B2) .

&Quot; Component (B1): Cationic gum rubber "

The cationic guar gum as the component (B1) is also referred to as guar hydroxypropyl trimonium chloride, chlorinated O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum and the like.

The nitrogen content of the component (B1) is preferably 1.0% by mass to 1.8% by mass, and more preferably 1.1% by mass to 1.45% by mass in that smoothness can be imparted to the hair during rinsing.

The nitrogen content can be measured by the Kjeldahl method by decomposing the component (B1) into sulfuric acid to make ammonium sulfate, and quantifying the ammonia. Specifically, it can be measured by the method described in "General Substance Standards for Pharmaceutical Quasi-Drugs 2006 (Yakushi Daily)", General Test Methods 44. Nitrogen Determination Method.

As the component (B1), a commercially available product may be used, or a properly synthesized product may be used. Specific examples of the commercial product include JAGUAR C14S (nitrogen content: 1.3 to 1.7 mass%), JAGUAR Excel (nitrogen content: 1.0 to 3.0 mass%), Jaguar C-500 (nitrogen content: 1.15 Mass% to 1.45 mass%); JAGUA R series (manufactured by Rhodia); N-Hance CG14 (nitrogen content: 1.15 mass% to 1.45 mass%), N-Hance 3299 (nitrogen content: 1.15 mass% to 1.45 mass%), N-Hance CCG 45 ), N-Hance series (Ashland, Aqualon division); CATIGANAL G-100S (nitrogen content: 1.0 mass% to 1.7 mass%) (manufactured by Toho Chemical Industry Co., Ltd.); Guarsafe JK140 (nitrogen content: 1.3% by mass to 1.7% by mass) (manufactured by JINGKIN CHEMISTRY COMPANY). Of these, N-Hance 3299, N-Hance CCG 45 and JaguaRC-500 are particularly preferable in that hair after drying is quick in drying.

The content of the component (B1) in the shampoo composition is preferably 0.08% by mass to 1.0% by mass from the viewpoint that smoothness can be imparted to the hair during rinsing and a hairiness can be imparted to the hair ends after drying , And more preferably from 0.1 mass% to 0.8 mass%. If the content of the component (B1) is less than 0.08 mass%, the smoothness of the hair during the rinsing process may be lowered. On the other hand, if the content of the component (B1) exceeds 1.0 mass%, the disappearance of foam during rinsing is deteriorated, The feeling of being late and the feeling of the head end of the hair after drying may be lowered.

≪ Component (B2): Cationic cellulose &

The cationic cellulose as the component (B2) is reacted with a trimethylammonium-substituted epoxide, also called polyquaternium-10, O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride or the like Hydroxyethyl cellulose.

The nitrogen content of the component (B2) is preferably such that the foam disappears at the time of rinsing. Is preferably 1.5% by mass to 2.2% by mass, and more preferably 1.6% by mass to 2.0% by mass in that smoothness can be imparted to the hair during rinsing.

The nitrogen content can be measured by the Kjeldahl method by decomposing the component (B2) into sulfuric acid to make ammonium sulfate, and quantifying the ammonia. Specifically, it can be measured by the method described in "General Substance Standards for Pharmaceutical Quasi-Drugs 2006 (Yakushi Daily)", General Test Methods 44. Nitrogen Determination Method.

As the component (B2), a commercially available product or a suitably synthesized product may be used. Specific examples of the commercially available product include UCARE Polymer JR series such as UCARE Polymer JR400 (nitrogen content: 1.5 to 2.2 mass%) and UCARE Polymer JR-30M (nitrogen content: 1.5 to 2.2 mass% (Manufactured by Dow Chemical); (For example, CATICHANAL HC series such as CATICHANAL HC 100 and CATILINE HC 200) (manufactured by Toho Chemical Industry Co., Ltd.); Leo grade series (manufactured by Lion Corporation) of Leo Gado GP, Leo Gado KGP, and Leo Gado MGP (nitrogen content: 1.6 mass% to 2.0 mass%); MICONIUM (registered trademark) PQ10-J-400 (nitrogen content: 1.5 mass% to 2.2 mass%) (manufactured by MIWON). Among them, the disappearance of bubbles at the time of rinsing is good. MICONIUM (registered trademark) PQ10-J-400, Leo G. GP and Leo G. KGP are particularly preferred in that smoothness can be imparted to the hair during rinsing.

The content of the component (B2) in the shampoo composition is preferably 0.01% by mass to 0.5% by mass, more preferably 0.04% by mass from the viewpoint that drying of the hair after shaving is quick and a hair- % To 0.3% by mass is more preferable. If the content of the component (B2) is less than 0.01% by mass, drying of the hair after shampooing may be delayed. If the content of the component (B2) is more than 0.5% by mass, hairiness at the tips of hair after drying may deteriorate.

The content of the component (B1) and the component (B2) in the shampoo composition (hereinafter may be referred to as "content of the component (B)") is preferably from 0.1 mass% to 1.2 mass% By mass to 1.0% by mass is more preferable. If the content of the component (B) is less than 0.1% by mass, the smoothness of the hair at the time of rinsing and the feeling of being prone to the hair after drying may be lowered. On the other hand, if the content exceeds 1.2% by mass, There is a tendency that the fingering becomes worse, and the feeling of the head end of the hair after drying is lowered.

The mass ratio (B1) / (B2) of the component (B1) to the component (B2) Is preferably 2 to 20, more preferably 2.5 to 15, and most preferably 2.5 to 9 in terms of giving a feeling of being prickly to the hair ends after drying. When the mass ratio (B1) / (B2) is less than 2, the scratches of the hair at the time of hair firming are deteriorated and the smoothness of the hair at the time of rinsing is lowered. When the mass ratio is more than 20, The drying of the hair after shampooing is delayed, and the sensation of hairiness of the hair after drying may be lowered.

≪ Component (C): Silicone compound >

The silicone compound as the component (C) is composed of dimethylpolysiloxane (hereinafter may be referred to as "component (C1)") and amino-modified silicone (hereinafter referred to as "component (C2)

≪ Component (C1): Dimethylpolysiloxane >

The component (C1) is not particularly limited as long as it is dimethylpolysiloxane, and can be appropriately selected in accordance with the purpose. Examples of the component (C1) include trimethylsilyl group terminal (terminal) dimethylpolysiloxane and silanol group terminal dimethylpolysiloxane. Of these, trimethylsilyl group-terminated dimethylpolysiloxane is preferable in that a hairiness feeling can be imparted to the hair ends after drying.

The kinematic viscosity (kinematic viscosity) of the dimethylpolysiloxane at 25 캜 is preferably from 10,000 mm 2 / s to 30,000,000 mm 2 / s, more preferably from 100,000 mm 2 / s to 10,000,000 mm 2 / s, / s is more preferable, and 100,000 mm 2 / s to 1,000,000 mm 2 / s is particularly preferable.

The kinematic viscosity of the dimethylpolysiloxane at 25 캜 can be measured, for example, by the following method.

A toluene solution of dimethylpolysiloxane having a concentration of 1 g / 100 ml is prepared, and the specific viscosity (? Sp) (25 占 폚) is determined by the following equation (1). Subsequently, the intrinsic viscosity [eta] is obtained by substituting into the relational expression of Huggins expressed by the following formula (2). Huggins et al., Nakamuda, anecdote, 77, 588, 1956. Next, the intrinsic viscosity [?] Is substituted into the A. Kolorlov formula shown in the following formula (3) to determine the molecular weight (M). Finally, the kinematic viscosity (?) Of the dimethylpolysiloxane can be obtained by substituting the molecular weight (M) into the equation of A. J. Barry expressed by the following formula (4).

? sp = (? /? ₀ ) -1 ... Equation (1)

? sp = [?] + K '[?] ² ... Equation (2)

^{[η] = 0.215 × 10 -4} M 0 .65 ... Equation (3)

logη = 1.00 + 0.0123M ^{0 .5} ... Equation (4)

In the above formula (1), " eta 0 " represents the viscosity of toluene and " eta " represents the viscosity of the solution.

The above? ₀ and? Are measured in accordance with Method 1 of General Methods for Viscosity Measurement of Cosmetics Raw Materials.

The component (C1) is preferably emulsified in advance with an emulsifier in view of the efficiency of production of the shampoo composition and dispersion stability. The emulsifying agent and the emulsifying method for emulsifying the component (C1) are not particularly limited and can be suitably selected in accordance with the purpose.

The number average particle diameter of the component (C1) in the emulsion is preferably in the range of from 0.1 to 5 parts by weight, It is preferably from 0.5 mu m to 60 mu m, more preferably from 10 mu m to 50 mu m, and particularly preferably from 15 mu m to 40 mu m, from the viewpoint of rapid drying of hair after hair firing. When the number average particle diameter is less than 0.5 mu m, drying of the hair after shrinkage is delayed, and the feeling of hairiness at the head end after drying is lowered. When the number average particle diameter is more than 60 mu m, The drying of the hair after shaving is delayed, and the feeling of bruising of the hair ends after drying may be reduced.

The number average particle size can be determined by image processing (e.g., two-dimensional image analysis software WinROOF or the like) after the image of particles observed with an optical microscope is arbitrarily taken into a computer at 100 locations, .

As the component (C1), a commercially available product may be used, or an appropriately synthesized product may be used. As a specific example of the above-mentioned component (C1) sold as an emulsion, BY22-029 (kinematic viscosity: 100,000 mm 2 / s, number average particle diameter: 0.5 탆) (manufactured by Dow Corning Toray Co., 600,000 mm < 2 > / s, number average particle diameter: 35 mu m) (manufactured by Dow Corning); KM-902 (kinematic viscosity: 500,000 mm < 2 > / s, number average particle diameter: 0.5 m) (manufactured by Shin-Etsu Chemical Co., Ltd.); (Dynamic viscosity: 100,000 mm 2 / s, number average particle size: 0.5 탆), Leofro DMS-60 [kinematic viscosity: 10,000,000 mm 2 / s: 4,000,000 mm 2 / s: 1,000 mm 2 / s = 15:15:70 Mass ratio), number average particle diameter: 0.9 占 퐉] (the above, manufactured by Isobo Kasei Kogyo Co., Ltd.); EMU 120 (kinematic viscosity: 900,000 mm < 2 > / s, number average particle diameter: 20 mu m) (manufactured by Momentibusa Co., Ltd.). Of these, DC-7137 and EMU120 are preferable in that smoothness can be imparted to the hair during rinsing, drying of the hair after shaving is quick, and a hair-like feeling can be imparted to the hair after drying.

The content of the component (C1) in the shampoo composition is preferably 0.03 mass% to 4.5 mass%, more preferably 0.5 mass% to 3.8 mass%, and particularly preferably 1 mass% to 2.8 mass%. If the content of the component (C1) is less than 0.03% by mass, the hairiness at the tip of the hair after drying may be reduced. If the content of the component (C1) is more than 4.5% by mass, There is a feeling that the tip of the head can be reduced.

≪ Component (C2): Amino-modified silicone >

The amino-modified silicone as the component (C2) is not particularly limited and can be appropriately selected in accordance with the purpose. For example, aminoethylaminopropylsiloxane-dimethylsiloxane copolymer (hereinafter referred to as "amodimicicon" , Aminoethylaminopropylmethylsiloxane-dimethylsiloxane copolymer (hereinafter sometimes referred to as " aminomethylaminopropylmethicone dimethicone copolymer "), amino-modified organopolysiloxane chain (chain) A copolymer having a block chain with an alkylene chain (hereinafter sometimes referred to as "linear aminopolyether-modified silicone"), aminopropyldimethicone, and the like. These may be used alone, or two or more kinds may be used in combination. Of these, amodimethicone and a straight chain aminopolyether-modified silicone are preferable in that smooth hair can be imparted during rinsing.

As the component (C2), a commercially available product or a properly synthesized product may be used. Specific examples of commercially available products of the component (C2) include SM8904CE, BY22-079, FZ-4671 (Amodimicicon emulsion, Dow Dow Corning Silicone), DC2-8194 (Dow Corning), KF -8004, KF-867S, KF-880 (manufactured by Shin-Etsu Chemical Co., Ltd.); Aminomethylaminopropylmethicone dimethicone copolymers such as KF-8005 (manufactured by Shin-Etsu Chemical Co., Ltd.); SILSTYLE 201 (bis-isobutyl PEG-14 / amodimicicon copolymer), SILSTYLE 401 (bis-butyloxymodimetimecone / PEG-60 / Copolymers) (available from Dow Corning Toray Silicone Co., Ltd.); And aminopropyldimethicone such as KF-8015, KF-865, KF-8017, KF-8018 and KF-8020 (manufactured by Shin-Etsu Chemical Co., Ltd.). Of these, SILSTYLE 401 is preferred.

The content of the component (C2) in the shampoo composition is preferably 0.01% by mass to 1.5% by mass, more preferably 0.05% by mass to 1% by mass, and particularly preferably 0.1% by mass to 1% by mass. When the content of the component (C2) is less than 0.01% by mass, the smoothness of the hair at the time of rinsing is lowered, and the feeling of hairiness at the hair ends after drying is lowered. When the content is more than 1.5% by mass, There is a delay in the drying of the hair, and it sticks and becomes strong.

The total content of the component (C1) and the component (C2) in the shampoo composition (hereinafter sometimes referred to as the " content of the component (C) ") is such that a hair- , It is preferably 0.1% by mass to 5% by mass, more preferably 0.8% by mass to 4% by mass, and further preferably 1.2% by mass to 3% by mass. When the content of the component (C) is less than 0.1% by mass, drying of the hair after shrinkage is delayed, and the feeling of bruising at the hair ends after drying is lowered. When the content is more than 5% (C) is an emulsion, the emulsion particles may coalesce to deteriorate the stability of the emulsion particles. In addition, the feeling on the head end of the hair after drying may be lowered .

The mass ratio (C1) / (C2) of the component (C1) to the component (C2) is preferably from 2 to 5 at the point of smoothness of the hair at the time of rinsing, fast drying of the hair after shaving, To 30, and preferably from 5 to 25. When the mass ratio (C1) / (C2) is less than 2, the drying of the hair after shaving is delayed and the stickiness is generated even after drying, There is a case that the composition becomes a composition. If the mass ratio (C1) / (C2) exceeds 30, the smoothness of the hair at the time of rinsing may be lowered.

≪ Component (D): Gloss giving agent >

The shampoo composition as the component (D) may be imparted with a pearl-like luster in the shampoo composition (sometimes referred to as "gloss agent", "pearlizing agent", "pearlizing agent", etc.). This is advantageous in that the value of the product can be increased.

In addition, the component (D) not only imparts a pearly shine to the shampoo composition, but also improves the sharpness of the hair at the time of shaving, accelerates the drying of the hair after shaving, .

The component (D) is not particularly limited and can be appropriately selected in accordance with the purpose. Examples thereof include hydroxystearate, polyethylene glycol monostearate, polyethylene glycol distearate, ethylene glycol monostearate, Stearic acid monoethanolamide, stearic acid monoethanol stearate, and the like. These may be used alone, or two or more kinds may be used in combination. Of these, ethylene glycol distearate is preferable in that it has good pearl luster and dispersion stability.

The component (D) is generally dispersed as a crystalline material (crystalline material) in a shampoo composition, so that a pearly shine can be imparted to the shampoo composition.

The method for preparing the dispersion of the crystalline material is not particularly limited and may be appropriately selected in accordance with the purpose. For example, a method of dissolving the component (D) and maintaining the component (D) A method in which the component (D) is dispersed and mixed in a high-alcohol aqueous solution, followed by cooling. Examples of the higher alcohol include cetyl alcohol and the like.

By adding the dispersion of the crystalline material of the component (D) to the shampoo composition so that the component (D) is in a predetermined concentration, the shampoo composition can be appropriately imparted with a pearl-like luster.

The median particle size of the dispersion of the crystalline material of the component (D) is not particularly limited and may be appropriately selected in accordance with the intended use. The particle diameter is preferably 0.5 탆 to 6 탆, more preferably 1.0 탆 to 3.0 탆. When the median grain size is less than 0.5 占 퐉, the flesh quality of the hair at the time of hair firming is deteriorated, the smoothness of the hair at the time of rinsing is lowered, and a pearly luster can not be given, Something to throw away. If the median grain size exceeds 6 mu m, drying of the hair after shrinkage may be delayed, and the feeling of bruising of the hair after drying may be lowered, resulting in deterioration of desirable washing sensation.

The dispersed form of the crystalline material of the component (D) is preferably a needle-like crystal. By forming acicular crystals, the smoothness of hair during rinsing is improved.

The median grain size is generally referred to as D50, and is the diameter at which the larger side and the smaller side become equal (equal amount) when the dispersion is divided into two by a certain particle diameter. Specifically, the relative refractive index with respect to water was set to 1.08 using a laser diffraction particle size distribution analyzer (LA-920, manufactured by Horiba Ltd.), and the crystal of the component (D) prepared in advance before the addition to the shampoo composition By measuring the particle size distribution of the dispersion of water, the median particle size can be calculated.

The content of the component (D) is 1% by mass to 5% by mass and 1% by mass to 1% by mass in terms of the smoothness of the hair at the time of rinsing, the quickness of drying of the hair after hair dressing, 3% by mass is preferable. When the content of the component (D) is less than 1% by mass, drying of the hair after hair fogging is delayed, and hairiness at the tip of the hair after drying is reduced. When the content is more than 5% The drying of the hair after the drying is delayed, and the feeling of hairiness at the end of the hair after drying is lowered.

≪ Other components >

There are no particular limitations on the other ingredients as long as they do not impair the effect of the present invention. Examples of the other ingredients include various additives commonly used in common shampoo compositions.

Specific examples of the other components include hydrocarbons such as liquid paraffin and squalane; Esters such as isopropyl myristate; Vegetable oils such as springtime, almond oil, and jojoba oil; Plant extracts such as birch extract; Cationic surfactants such as behenyltrimethylammonium chloride; Nonionic surfactants such as polyoxyethylene alkyl ethers, glycerin fatty acid esters, sucrose fatty acid esters, polyglycerin fatty acid esters and polyoxyethylene hydrogenated castor oil; Amphoteric surfactants such as lauric acid amide propyl betaine, lauric acid amide prohydroxysulfoyl betaine and lauryl dimethyl amine oxide; Gallic acid derivatives; Amino acids such as glycine, serine, and arginine; Anti-inflammatory agents such as pyrrolidone carboxylic acid or salts, herbal medicines, vitamins, dipotassium glycyrrhizinate and glycyrrhetinic acid; Anti-dandruff agents such as pyrrotonone olamine and zinc pyrithione; Fungicides such as isopropylmethylphenol and triclosan; Tar color; UV absorbers such as oxybenzone and 2-ethylhexyl methoxy cinnamate; Antioxidants such as dibutylhydroxytoluene; Humectants such as glycerin and trimethylglycine; Solvents such as water, ethanol and hexylene glycol; Anionic polymers such as acrylic acid-based polymers and acrylate / stearate-20 methacrylate copolymers; Nonionic polymers such as vinyl pyrrolidone type polymers; Amphoteric polymers such as diallyldimethylammonium chloride / acrylic acid chloride; Inorganic powders such as anhydrous silica and magnesia silica; Organic powders such as nylon and polyethylene; Spices ; PH adjusting agents such as citric acid, sodium citrate and glycolic acid; Amines; Preservatives such as sodium benzoate; Stabilizers such as hydroxyethanediphosphonic acid, dibutylhydroxytoluene, disodium edetate, and the like; And the like. These may be used alone, or two or more kinds may be used in combination.

<pH>

The pH of the shampoo composition is not particularly limited and can be appropriately selected in accordance with the purpose. It is preferably 5.0 to 6.0 at 25 占 폚.

The pH can be measured, for example, at 25 占 폚 by using a pH meter (HM-30G, manufactured by Dongdaikake K.K.) as the shampoo composition which is diluted 10 times with purified water.

The pH of the shampoo composition can be adjusted using a desired pH adjusting agent. The pH adjuster is not particularly limited and may be appropriately selected in accordance with the purpose. Examples of the pH adjuster include citric acid, succinic acid, sulfuric acid, 2-amino-2-methyl-1-propanol, monoethanolamine, .

<Viscosity>

The viscosity of the shampoo composition is not particularly limited and may be suitably selected in accordance with the purpose. It is preferably 1 Pa · s to 30 Pa · s at 25 ° C.

The viscosity can be measured by using, for example, a viscometer (BM type viscometer, manufactured by TOKIMEC). 4 rotor at 30 rpm for 20 seconds and then at 25 ° C.

<Container>

The shampoo composition can be used by filling the container. The container is not particularly limited and may be appropriately selected in accordance with the purpose. Examples of the container include a tube such as an aluminum laminate tube, an EVAL tube, an aluminum tube, a glass evaporated plastic tube, a dispenser vessel by mechanical or differential pressure, Squeeze containers, laminate film containers, eyedropper containers, bottle containers, pump-type containers, and the like.

Examples of the material of the laminate film include synthetic resins such as polyethylene, polyethylene terephthalate, polyester, biaxially oriented polypropylene, unoriented polypropylene, polyacrylonitrile and ethylene-vinyl acetate copolymer, paper, aluminum And vapor-deposited plastic. The laminate film usually has two or more layers and is preferably two to five layers in consideration of strength, flexibility, weather resistance, and the like.

Examples of the material of the bottle include resins such as polyethylene, polypropylene, polyethylene terephthalate, polystyrene, polyvinyl chloride, ethylene-vinyl alcohol resin, acrylonitrile-styrene resin, ABS resin and polyamide, Is selected. The structure of the container is preferably a single layer or a layer structure of two or more layers.

<Applications>

The shampoo composition is excellent in the fingering of the hair at the time of foaming and the disappearance of foaming at the time of rinsing, and it is possible to impart smoothness to the hair at the time of rinsing, to allow the hair to dry quickly after shaving, It is possible to give a feeling of being absurd and to have a high washing sensation and a conditioning effect which can sustain it. For example, skin cleansing shampoo, damage care shampoo, mild shampoo, rinse in shampoo, dandruff removal It can be used suitably for shampoo and the like.

Example

Hereinafter, the present invention will be described in detail by way of examples of the present invention, but the present invention is not limited to these examples at all. In the following examples and comparative examples, unless otherwise specified, "%" represents "% by mass", and the content of each component represents a net conversion value. For example, in the case of a shampoo composition containing 3.1% of a dimethylpolysiloxane emulsion having 65% silicon content, the net conversion value of the component (C1) is 2.0%.

(Examples 1 to 42, Comparative Examples 1 to 19)

Shampoo compositions having the compositions and contents shown in Tables 1 to 7 below were prepared according to the following production methods.

&Lt; Preparation method of shampoo composition >

- Preparation of Ethylene Glycol Distearate Crystal Water Dispersion (1)

The ethylene glycol distearate crystal water dispersion as component (D) was prepared by the following method.

(Final concentration) 10%, ammonium lauryl sulfate (Texapon ALS 70, manufactured by BASF), 5% concentration of polyoxyethylene (3) ammonium lauryl ether sulfate (Texapon ALES 70, BASF), and cetyl alcohol (Manufactured by BASF) so as to have a final concentration of 2.5% was maintained at 80 캜 and stirred in a 2-L beaker. Ethylene glycol distearate (Tegin EGS, Evonik) dissolved at 80 캜 was gradually added to the aqueous solution so as to have a final concentration of 4.5% while agitating the water solution, and the mixture was stirred at 80 占 폚 using a three-one motor (FBL1200, HEIDEN Manufactured by Tokushu Kika Kogyo Co., Ltd.) and dispersed and mixed at 4,500 rpm for 10 minutes using a homomixer (manufactured by Tokushu Kika Kogyo Co., Ltd.) after homogeneous mixing at 100 rpm for 30 minutes using four slant paddles.

Subsequently, the obtained dispersion mixture was immersed in a water bath and cooled in a dispersion tank at 35 DEG C (at a cooling rate of 1 DEG C / minute) while stirring at 100 rpm using four sheets of warp paddles to obtain 4.5% ethylene glycol distearate To prepare a crystal water dispersion.

The median particle diameter of the 4.5% ethylene glycol distearate crystal aqueous dispersion (1) was measured using a laser-induced particle size distribution analyzer (LA-920, manufactured by Horiba Co., Ltd.) with a relative refractive index with respect to water being 1.08 Respectively. The median particle diameter was 2.0 탆. The dispersed form of the crystal was a needle bed.

- Preparation of Ethylene Glycol Distearate Crystal Water Dispersion (2)

A method similar to the preparation of the ethylene glycol distearate crystal aqueous dispersion (1), except that the stirring time by the homomixer was changed from 10 minutes to 20 minutes in the preparation of the ethylene glycol distearate crystal water dispersion (1) , An ethylene glycol distearate crystal water dispersion (2) was prepared.

The median particle diameter of the ethylene glycol distearate crystal aqueous dispersion (2) measured by the above method was 0.5 탆. The dispersed form of the crystal was a needle bed.

Preparation of Ethylene Glycol Distearate Crystal Water Dispersion (3)

Ethylene glycol distearate crystals were prepared in the same manner as in the preparation of the aqueous dispersion of ethylene glycol distearate (1) except that dispersion and mixing by a homomixer were not carried out in the preparation of the aqueous dispersion of ethylene glycol distearate crystals (1) To prepare a Tealate Crystal Water Dispersion (3).

The median particle diameter of the ethylene glycol distearate crystal aqueous dispersion (3) measured by the above method was 6.0 탆.

- Preparation of Shampoo Composition -

The components (A), (B), (C) and common components shown in the following Tables 1 to 7 were added so as to have the contents (converted into pure fractions) shown in the following Tables 1 to 7, And stirred for 30 minutes. Subsequently, as the component (D), any one of the aqueous dispersions (1 to 3) of the ethylene glycol distearate crystals was added so as to have the contents shown in Tables 1 to 7 in terms of pure ethylene glycol distearate For example, when the content of the component (D) is 1.5%, 33.3% of a 4.5% ethylene glycol distearate dispersion is added) and stirred for 30 minutes. And citric acid was added thereto to adjust the pH to 5.8, thereby obtaining the shampoo compositions of Examples and Comparative Examples.

The ethylene glycol distearate crystal water dispersion (1 to 3) contains polyoxyethylene laurylsulfate ammonium and laurylsulfate as the components (A) as described in the preparation method, The content of the component (A) represented by 1 to 7 was expressed as a value obtained by adding the contents derived from the ethylene glycol distearate crystal water dispersion (1 to 3).

<Sensory Evaluation>

Regarding the shampoo compositions of Examples and Comparative Examples, it was confirmed that "shampooing of hair at the time of shaving is good", "good bubble extinction at the time of rinsing", "smoothness of hair at the time of rinsing", " Fast drying of hair after shaving ", and" sensation of bruising of hair after drying "were evaluated and evaluated based on the following evaluation criteria. The results are shown in Tables 1 to 7 below.

«Evaluation method»

Step 1: Wet the hair of 20 professional female panelists sufficiently with water, apply the shampoo composition to the professional paneler's hair at a dose of about 6 g / dose, massage the scalp with the fingers, I bubbled enough.

Step 2: Next, the sample was rinsed with tap water having a temperature of 40 占 폚 by using a shower having a flow rate of 250 ml / 3 seconds.

Step 3: Next, the hair was sufficiently wiped with a towel, and then the hair was naturally dried.

The above steps 1 to 3 were carried out once a day, and after continuous use for 7 days, each evaluation was carried out.

- It is good to smoothen the hair at the time of shaving -

In Step 1 of the above-described evaluation method, on the seventh day after the continuous use, evaluation was made as to whether or not the hair of the shampoo composition is good in the state of foamed with the shampoo composition, based on the following evaluation criteria.

- Good bubble disappearance during rinsing -

In Step 2 of the above-described evaluation method, on the seventh day after the continuous use, evaluation of bubble extinction was made based on the following evaluation criteria.

- Smoothness of hair during rinsing -

In Step 2 of the above evaluation method, the smoothness of hair during washing with tap water on the seventh day after use was evaluated based on the following evaluation criteria.

- Fast drying of hair after hair removal -

In Step 3 of the evaluation method, the dry state of the hair after naturally drying (after 2 hours from shrinkage) was checked on the 7th day of continuous use, and the case where the hair was completely dried was evaluated as &quot; &Quot; and evaluated based on the following evaluation criteria.

- Sensation of the head of the hair after drying -

In step 3 of the above evaluation method, the feeling on the tip of the head after naturally drying (after 24 hours from shaving) on the seventh day after use was evaluated based on the following evaluation criteria.

«Evaluation Criteria»

The evaluation of the evaluation was made on the basis of the evaluation method described above. The evaluation results were evaluated in terms of "good skin scratching at the time of shaving", "good bubble extinction at the time of rinsing", "smoothness of hair at rinsing" The following evaluation criteria of the four stages were prepared by the number of persons judged as "good" with respect to "feeling of the head end of the hair after drying".

◎: Of 20 persons, 16 or more judged "good".

○: Of the 20 persons, 11 or more and 15 or less judged "good".

△: Among 20 persons, 6 or more and 10 or less were judged as "good".

X: Of 20 persons, five or less were judged as "good".

(Example 43)

The mild shampoo of Example 43 was prepared in the same manner as in Examples 1 to 42 and Comparative Examples 1 to 19 except that the following compositions and contents were changed to Examples 1 to 42 and Comparative Examples 1 to 19. The mild shampoo of Example 43 was subjected to sensory evaluations as in Examples 1 to 42 and Comparative Examples 1 to 19, and the results are shown in Table 1. &quot; Good skin scratching during shaving &quot;, &quot; , "Smoothness of hair at the time of rinsing", "speed of drying of hair after hair frying", and "hairiness of hair after drying" were evaluated.

[Composition and content]

POE (3) Ammonium lauryl ether sulfate [Component (A1)]: 11.0%

Ammonium lauryl sulfate [Component (A2)]: 6.0%

Lauric acid amide propyl betaine: 1.0%

Lauryldimethylamine oxide: 0.2% &lt; RTI ID = 0.0 &gt;

- Cationic Goura rubber A [Component (B1)]: 0.3%

Cationic cellulose A [Component (B2)]: 0.1%

Dimethylpolysiloxane C [Component (C1)]: 2.0%

Amino-modified silicone C [Component (C2)]: 0.2%

Ethylene glycol distearate 1 [Component (D)]: 1.5%

 (Ethylene glycol distearate crystal water dispersion (1))

POE (20) hardened castor oil: 0.2%

· Hexylene glycol: 0.2%

· Sodium benzoate: 0.3%

Hydroxyethane diphosphonic acid: 0.2%

· Spices: 0.5%

· Citric acid: The amount is adjusted so that the pH is 5.8.

· Purified water: the remainder

Total: 100%

Mass ratio (A1) / (A2): 1.8

Mass ratio (B1) / (B2): 3

Mass ratio (C1) / (C2): 10

[Evaluation results]

· It is good to smoothen the hair at the time of shaving: ◎

Good bubble extinction at the time of rinsing: ◎

· Smooth hair when rinsed: ◎

· Quick drying of hair after hair removal: ◎

· The feeling of the head end of the hair after drying: ◎

(Example 44)

The shampoo for damage care of Example 44 was prepared in the same manner as in Examples 1 to 42 and Comparative Examples 1 to 19 except that the following compositions and contents were changed to the following compositions and contents in Examples 1 to 42 and Comparative Examples 1 to 19 . Further, with respect to the damage-care shampoo of Example 44, the sensory evaluations as in Examples 1 to 42 and Comparative Examples 1 to 19 were carried out, and it was found that the "shampoo of hair at the time of shaving" Good "," smoothness of hair at the time of rinsing "," fast drying of hair after hair firing ", and" feeling of bruising at the head end after drying "were evaluated.

[Composition and content]

POE (3) Ammonium lauryl ether sulfate [Component (A1)]: 9. 0%

Ammonium lauryl sulfate [Component (A2)]: 6.0%

Acylglutamate triethanolamine: 1.5%

Lauryldimethylamine oxide: 0.3%

Lauric acid amide propyl hydroxysulfobetaine: 0.5%

Component (A) (Component (B1)): 0.2%

Cationic cellulose A [Component (B2)]: 0.05%

Dimethylpolysiloxane A [Component (C1)]: 2.0%

Amino-modified silicone B [Component (C2)]: 0.3%

Ethylene glycol distearate 1 [Component (D)]: 1.5%

 (Ethylene glycol distearate crystal water dispersion (1))

· Sodium benzoate: 0.9%

Arginine: 0.1%

Plant Extract A: 0.1%

Plant Extract B: 0.1%

· Birch tree extract: 0.1%

· Yellow No. 203: 0.001%

· Yellow No. 5: 0.002%

· Spices: 0.5%

· Citric acid: The amount is adjusted so that the pH is 5.8.

· Purified water: the remainder

Total: 100%

Mass ratio (A1) / (A2): 1.5

Mass ratio (B1) / (B2): 4

Mass ratio (C1) / (C2): 6.7

[Evaluation results]

· It is good to smoothen the hair at the time of shaving: ◎

Good bubble extinction at the time of rinsing: ◎

· Smooth hair when rinsed: ◎

· Quick drying of hair after hair removal: ◎

· The feeling of the head end of the hair after drying: ◎

(Example 45)

The dandruff-removing shampoo of Example 45 was prepared in the same manner as in Examples 1 to 42 and Comparative Examples 1 to 19 except that the following compositions and contents were changed to Examples 1 to 42 and Comparative Examples 1 to 19. Further, the dandruff-removing shampoo of Example 45 was subjected to sensory evaluation as in Examples 1 to 42 and Comparative Examples 1 to 19, and the results were shown as &quot; good to be scratched at the time of shaving &quot;, &Quot;, &quot; smoothness of hair at the time of rinsing &quot;, &quot; fastness of drying of hair after shaving &quot;, and &quot;

[Composition and content]

POE (3) Ammonium lauryl ether sulfate [Component (A1)]: 10.0%

Ammonium lauryl sulfate [Component (A2)]: 5.0%

Lauric acid amide propyl betaine: 0.4% &lt; RTI ID = 0.0 &gt;

- Cationic Goura rubber A [Component (B1)]: 0.3%

Cationic cellulose B [Component (B2)]: 0.1%

Glycerin: 0.3%

Dimethylpolysiloxane A [Component (C1)]: 2.0%

Amino-modified silicone D [Component (C2)]: 0.3%

Ethylene glycol distearate 1 [Component (D)]: 1.5%

 (Ethylene glycol distearate crystal water dispersion (1))

· Pyrrotonolamine: 0.1%

· Zinc pyrithione: 1.0%

Acrylate / stearate-20 methacrylate copolymer: 0.3%

· Sodium benzoate: 0.5%

· Trimethylglycine: 0.1%

Dibutylhydroxytoluene: 0.01%

Oxybenzone: 0.1%

· Spices: 0.5%

· Sodium citrate: 0.3%

· Citric acid: The amount is adjusted so that the pH is 5.8.

· Purified water: the remainder

Total: 100%

Mass ratio (A1) / (A2): 2

Mass ratio (B1) / (B2): 3

Mass ratio (C1) / (C2): 6.7

[Evaluation results]

· It is good to smoothen the hair at the time of shaving: ◎

Good bubble extinction at the time of rinsing: ◎

· Smooth hair when rinsed: ◎

· Quick drying of hair after hair removal: ◎

· The feeling of the head end of the hair after drying: ◎

(Example 46)

A rinse-in shampoo of Example 46 was prepared in the same manner as in Examples 1 to 42 and Comparative Examples 1 to 19 except that the following compositions and contents were changed to Examples 1 to 42 and Comparative Examples 1 to 19. The rinse-in shampoo of Example 46 was subjected to sensory evaluations as in Examples 1 to 42 and Comparative Examples 1 to 19, and the results were shown as &quot; good to be scratched at the time of scarfing &quot;, &Quot;, &quot; smoothness of hair at the time of rinsing &quot;, &quot; fastness of drying of hair after shaving &quot;, and &quot;

[Composition and content]

POE (3) Ammonium lauryl ether sulfate [Component (A1)]: 9. 0%

Ammonium lauryl sulfate [Component (A2)]: 6.0%

Lauryldimethylamine oxide: 0.3%

Component (B1): 0.5% &lt; tb &gt;

Cationic cellulose A [Component (B2)]: 0.2%

Dimethylpolysiloxane A [Component (C1)]: 2.0%

Amino-modified silicone E [Component (C2)]: 0.3%

Ethylene glycol distearate 1 [Component (D)]: 1.5%

 (Ethylene glycol distearate crystal water dispersion (1))

Behenyl trimethyl ammonium chloride: 0.1%

· Disodium edetate: 0.1%

· Sodium benzoate: 0.3%

· 2-Ethylhexyl methoxy cinnamate: 0.3%

Dibutylhydroxytoluene: 0.01%

Glycolic acid: 0.1%

· Spices: 0.5%

· Citric acid: The amount is adjusted so that the pH is 5.8.

· Purified water: the remainder

Total: 100%

Mass ratio (A1) / (A2): 1.5

Mass ratio (B1) / (B2): 2.5

Mass ratio (C1) / (C2): 6.7

[Evaluation results]

· It is good to smoothen the hair at the time of shaving: ◎

Good bubble extinction at the time of rinsing: ◎

· Smooth hair when rinsed: ◎

· Quick drying of hair after hair removal: ◎

· The feeling of the head end of the hair after drying: ◎

The components used in Examples and Comparative Examples are shown in Table 8 below.

* 1: The dimethylpolysiloxane B (emulsion) in Table 8 was prepared by the following method.

Highly polymerized methylpolysiloxane having a kinematic viscosity of 10,000,000 mm 2 / s: Highly polymerized methylpolysiloxane having a kinematic viscosity of 4,000,000 mm 2 / s: Methylpolysiloxane having a kinematic viscosity of 1,000 mm 2 / s = 15 (trade name, manufactured by Shiba Seisakusho Kogyo) (Product name: NPO-97, manufactured by Lion Chemical Co., Ltd.) was added as an emulsifier to the emulsion and dispersed in water.

Examples of the embodiment of the present invention include the following.

(B) a cationic polymer; (C) 0.1% by mass to 5% by mass of a silicone compound; and (D) a gloss-imparting agent 1% by mass to 5% by mass,

Wherein the component (B) comprises (B1) a cationic guar gum and (B2) a cationized cellulose and the mass ratio (B1) / (B2) of the component (B1) 2 to 20,

Wherein the component (C) is composed of (C1) dimethylpolysiloxane and (C2) amino-modified silicone and the mass ratio (C1) / (C2) of the component (C1) 30. &Lt; / RTI &gt;

(2) The nitrogen-containing resin composition of (1), wherein the component (A) has a sulfuric acid residue, the component (B1) has a nitrogen content of 1.0 to 1.8 mass%, the component (B2) has a nitrogen content of 1.5 to 2.2 mass% The shampoo composition according to the above <1>, wherein the content of the component (B) is from 0.1% by mass to 1.2% by mass.

<3> The positive electrode active material according to <3>, wherein the component (A) contains (A1) a polyoxyethylene alkyl ether sulfuric acid ammonium salt and (A2) an ammonium alkylsulfate, and the mass ratio (A1) 1 &gt; to &lt; 2 &gt;, wherein the ratio (A) / (A2)

<4> The shampoo composition according to any one of <1> to <3>, wherein the component (D) is dispersed and the median particle diameter of the component (D) is 0.5 μm to 6 μm.

[Industrial Availability]

INDUSTRIAL APPLICABILITY The shampoo composition of the present invention is excellent in the fingering of hair and the disappearance of foam during rinsing at the time of foaming at the time of shaving and can impart smoothness to the hair at the time of rinsing and the drying of the hair after shaving is quick, It combines a high cleaning sensation and a conditioning effect that can give a sense of prolonged feeling to the tip of the head. Therefore, it can be used for surface cleansing shampoo, damage care shampoo, mild shampoo, rinse in shampoo and dandruff removal shampoo .

Claims (4)

(A) an anionic surfactant in an amount of 5 to 30 mass%, (B) a cationic polymer, (C) a silicone compound in an amount of 0.1 to 5 mass%, (D) By mass to 5% by mass,
Wherein the component (B) comprises (B1) a cationic guar gum and (B2) a cationized cellulose and the mass ratio (B1) / (B2) of the component (B1) 2 to 20,
Wherein the component (C) is composed of (C1) dimethylpolysiloxane and (C2) amino-modified silicone and the mass ratio (C1) / (C2) of the component (C1) 30. &Lt; / RTI &gt; The method according to claim 1,
Wherein the component (A) has a sulfuric acid residue, the component (B1) has a nitrogen content of 1.0 to 1.8 mass%, the component (B2) has a nitrogen content of 1.5 to 2.2 mass% Of the shampoo composition is 0.1% by mass to 1.2% by mass. 3. The method according to claim 1 or 2,
Wherein the component (A) contains (A1) a polyoxyethylene alkyl ether sulfuric acid ammonium salt and (A2) an ammonium alkylsulfate salt and further contains a mass ratio A1 / A2 of the component (A1) ) Is from 1 to 7. &lt; RTI ID = 0.0 &gt; 11. &lt; / RTI &gt; 4. The method according to any one of claims 1 to 3,
Wherein the component (D) is dispersed, and the component (D) has a median particle diameter of 0.5 탆 to 6 탆.