JP2009234967A - Cleansing agent composition - Google Patents
Cleansing agent composition Download PDFInfo
- Publication number
- JP2009234967A JP2009234967A JP2008081762A JP2008081762A JP2009234967A JP 2009234967 A JP2009234967 A JP 2009234967A JP 2008081762 A JP2008081762 A JP 2008081762A JP 2008081762 A JP2008081762 A JP 2008081762A JP 2009234967 A JP2009234967 A JP 2009234967A
- Authority
- JP
- Japan
- Prior art keywords
- component
- fatty acid
- cleaning composition
- feeling
- viscosity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 73
- 239000003599 detergent Substances 0.000 title claims abstract description 30
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 51
- 239000000194 fatty acid Substances 0.000 claims abstract description 51
- 229930195729 fatty acid Natural products 0.000 claims abstract description 51
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 33
- -1 fatty acid salts Chemical class 0.000 claims abstract description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910021485 fumed silica Inorganic materials 0.000 claims abstract description 14
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000004140 cleaning Methods 0.000 claims description 46
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- XLYOFNOQVPJJNP-DYCDLGHISA-N deuterium hydrogen oxide Chemical compound [2H]O XLYOFNOQVPJJNP-DYCDLGHISA-N 0.000 claims description 2
- 238000005187 foaming Methods 0.000 abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 9
- 239000000470 constituent Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 21
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 18
- 239000007788 liquid Substances 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 15
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 14
- 239000003921 oil Substances 0.000 description 10
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- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
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- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
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- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
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- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
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- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
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- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- ZFDPAZDODACYOG-UHFFFAOYSA-M sodium;[(1,5-dimethyl-3-oxo-2-phenylpyrazol-4-yl)amino]methanesulfonate Chemical compound [Na+].CN1C(C)=C(NCS([O-])(=O)=O)C(=O)N1C1=CC=CC=C1 ZFDPAZDODACYOG-UHFFFAOYSA-M 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 230000008719 thickening Effects 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
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- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
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- 239000005639 Lauric acid Substances 0.000 description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 2
- 239000004472 Lysine Substances 0.000 description 2
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 2
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
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- 244000250129 Trigonella foenum graecum Species 0.000 description 2
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- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
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- 235000019359 magnesium stearate Nutrition 0.000 description 2
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- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- VJESJEJNMGVQLZ-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(=O)N(CCO)CCO VJESJEJNMGVQLZ-UHFFFAOYSA-N 0.000 description 1
- XGZOMURMPLSSKQ-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)N(CCO)CCO XGZOMURMPLSSKQ-UHFFFAOYSA-N 0.000 description 1
- SKDZEPBJPGSFHS-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)tetradecanamide Chemical compound CCCCCCCCCCCCCC(=O)N(CCO)CCO SKDZEPBJPGSFHS-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 235000019488 nut oil Nutrition 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- 229960001173 oxybenzone Drugs 0.000 description 1
- 229950007031 palmidrol Drugs 0.000 description 1
- HXYVTAGFYLMHSO-UHFFFAOYSA-N palmitoyl ethanolamide Chemical compound CCCCCCCCCCCCCCCC(=O)NCCO HXYVTAGFYLMHSO-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- YVBBRRALBYAZBM-UHFFFAOYSA-N perfluorooctane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YVBBRRALBYAZBM-UHFFFAOYSA-N 0.000 description 1
- 239000010702 perfluoropolyether Substances 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 229950004354 phosphorylcholine Drugs 0.000 description 1
- PYJNAPOPMIJKJZ-UHFFFAOYSA-N phosphorylcholine chloride Chemical compound [Cl-].C[N+](C)(C)CCOP(O)(O)=O PYJNAPOPMIJKJZ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- PYJBVGYZXWPIKK-UHFFFAOYSA-M potassium;tetradecanoate Chemical compound [K+].CCCCCCCCCCCCCC([O-])=O PYJBVGYZXWPIKK-UHFFFAOYSA-M 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 230000037393 skin firmness Effects 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000004291 sulphur dioxide Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- QPQANCNBWQXGTQ-UHFFFAOYSA-N trihydroxy(trimethylsilylperoxy)silane Chemical compound C[Si](C)(C)OO[Si](O)(O)O QPQANCNBWQXGTQ-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 229940118846 witch hazel Drugs 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
本発明は、炭素数12〜18の高級脂肪酸塩から選ばれる一種又は二種以上、炭素数12〜18の脂肪酸モノエタノールアミド及び/又はジエタノールアミドから選ばれる一種又は二種以上、1,2−ペンタンジオール、及び水を含有した洗浄剤組成物に関し、更に詳しくは起泡力に優れ、また良好な使用性を与える粘性を持ち、洗い上がりの肌につっぱり感のないことを特徴とする洗浄剤組成物に関するものである。さらには煙霧状シリカを含有した経時安定性にも優れていることを特徴とする洗浄剤組成物に関するものである。 The present invention is one or two or more selected from higher fatty acid salts having 12 to 18 carbon atoms, one or two or more selected from fatty acid monoethanolamides and / or diethanolamides having 12 to 18 carbon atoms, 1,2- A cleaning composition containing pentanediol and water, and more particularly, a cleaning composition characterized by excellent foaming power, viscosity giving good usability, and no feeling of tension on the skin after washing It relates to a composition. Furthermore, it is related with the cleaning composition characterized by being excellent also in the temporal stability containing the fumed silica.
近年、皮膚、毛髪等における洗浄剤組成物は、本来の機能である清浄作用に加えて、高い起泡性や洗い上がりの肌感触といった使用品質面での要求が高まっている。そのため、従来より洗浄基剤である各種界面活性剤に水溶性高分子や油剤など種々の成分を配合検討する試みがなされている。 In recent years, cleaning compositions for skin, hair, and the like have been increasingly demanded in terms of quality of use such as high foaming properties and skin feel after washing, in addition to the cleansing action that is the original function. For this reason, attempts have been made to combine various components such as water-soluble polymers and oils with various surfactants that are cleaning bases.
例えば、代表的な洗浄基剤としての高級脂肪酸塩を配合した技術としては、高級脂肪酸塩とアミドプロピルベタイン型界面活性剤とヒドロキシプロピルメチルセルロースとを組み合わせる技術がある(例えば、特許文献1参照)。高級脂肪酸塩は、様々なアニオン性界面活性剤の中でも、特に高い起泡力を有し、洗浄剤組成物に広く応用されている。 For example, as a technique in which a higher fatty acid salt as a representative cleaning base is blended, there is a technique in which a higher fatty acid salt, an amidopropyl betaine surfactant and hydroxypropylmethylcellulose are combined (for example, see Patent Document 1). Higher fatty acid salts have a particularly high foaming power among various anionic surfactants, and are widely applied to detergent compositions.
また、洗浄基剤としてはノニオン界面活性剤も多く用いられており、例えば脂肪酸アルカノールアミドと油性成分とアニオン界面活性剤とを組み合わせた技術がある(例えば特許文献2参照)。脂肪酸アルカノールアミドの中でも、脂肪酸モノエタノールアミドや脂肪酸ジエタノールアミドは、泡質やすすぎ感触を向上させることでも知られており(例えば特許文献3参照)、さらには泡立て時の泡の安定性を高める等の効果もある。また、洗浄剤組成物を増粘させる技術には、他にアクリル酸アルキルコポリマーを配合する技術、カチオン化フェヌグリークガムを配合する技術等がある(例えば特許文献4及び特許文献5)。 Moreover, many nonionic surfactants are also used as a cleaning base, for example, there is a technique in which a fatty acid alkanolamide, an oil component and an anionic surfactant are combined (see, for example, Patent Document 2). Among fatty acid alkanolamides, fatty acid monoethanolamides and fatty acid diethanolamides are also known to improve foam quality and feeling of rinsing (see, for example, Patent Document 3), and further improve foam stability during foaming. There is also the effect. In addition, other techniques for thickening the detergent composition include a technique for blending an alkyl acrylate copolymer, a technique for blending a cationized fenugreek gum, and the like (for example, Patent Document 4 and Patent Document 5).
一方、上記のような洗浄剤組成物には、通常、1,3−ブチレングリコール、プロピレングリコール、ジプロピレングリコール等の多価アルコールや、安息香酸ナトリウムなどの防腐剤を配合することもまた必要な技術として検討されている(例えば、特許文献6及び特許文献7参照)。しかし前述にある高級脂肪酸塩と脂肪酸モノエタノールアミドや脂肪酸ジエタノールアミドと、1,3−ブタンジオールなどの多価アルコールとを組み合わせて洗浄剤組成物を調製した場合、この多価アルコールの配合量によって洗浄剤組成物の粘度が低下したり、また製剤の起泡力が低下したりする等の現象が知られている。(例えば非特許文献1参照) On the other hand, it is usually necessary to add a polyhydric alcohol such as 1,3-butylene glycol, propylene glycol and dipropylene glycol and a preservative such as sodium benzoate to the cleaning composition as described above. It has been studied as a technique (see, for example, Patent Document 6 and Patent Document 7). However, when a detergent composition is prepared by combining a higher fatty acid salt, fatty acid monoethanolamide, fatty acid diethanolamide and a polyhydric alcohol such as 1,3-butanediol as described above, depending on the blending amount of this polyhydric alcohol. Phenomena such as a decrease in viscosity of the cleaning composition and a decrease in foaming power of the preparation are known. (For example, see Non-Patent Document 1)
また、近年において1,2−アルカンジオールは上記多価アルコール類と比較して、優れた防腐力を有することが明らかとなってきており、1,2−アルカンジオールとα−ヒドロキシ酸とを組み合わせた技術(例えば特許文献8参照)や、1,2−オクタンジオールと高級脂肪酸塩とを組み合わせた技術(例えば特許文献9参照)等が挙げられる。
更に、上記にて述べたような洗浄剤組成物に煙霧状シリカを用いてゲル化させる技術があり、例えばイオン性界面活性剤水溶液と水溶性ポリアルキレングリコールに煙霧状シリカを配合する技術(例えば特許文献10参照)、アニオン界面活性剤と水溶性ポリアルキレングリコール、カチオン性高分子及び/又は両性の界面活性剤に、煙霧状シリカを配合する技術(例えば特許文献11参照)がある。
Further, in recent years, it has been clarified that 1,2-alkanediol has an excellent preservative power compared with the above polyhydric alcohols, and a combination of 1,2-alkanediol and α-hydroxy acid. And a technique (for example, see Patent Document 9) in which 1,2-octanediol and a higher fatty acid salt are combined.
Furthermore, there is a technique of gelling with a fumed silica in the cleaning composition as described above. For example, a technique of blending fumed silica into an aqueous ionic surfactant solution and a water-soluble polyalkylene glycol (for example, Patent Document 10), an anionic surfactant, a water-soluble polyalkylene glycol, a cationic polymer and / or an amphoteric surfactant include a technique of adding fumed silica (for example, see Patent Document 11).
しかしながら、特許文献4の例のようにアクリル酸アルキルコポリマーを用いた場合や、特許文献5の例のようにカチオン化フェヌグリークガムを用いた場合、それらの成分に由来する膜感やつっぱり感が洗い上がりの肌に生じるという場合があった。 However, when an alkyl acrylate copolymer is used as in the example of Patent Document 4 or when cationized fenugreek gum is used as in the example of Patent Document 5, the film feeling and the feeling of tension derived from those components are washed. In some cases, it occurred on the rising skin.
また、上記のような洗浄剤組成物にゲル化剤として煙霧状シリカを配合したゲル状組成物においては、煙霧状シリカを含有させる前の洗浄剤水溶液の粘度を、より高く保つことで、得られるゲル組成物の経時でのゲルの収縮を抑制し、経時安定性を向上させる必要があるが、特許文献10や特許文献11の技術の場合、防腐剤としての目的のため、プロピレングリコールや1,3−ブタンジオール、ジプロピレングリコールといった多価アルコール類を多量に配合する必要があり、結果として洗浄剤組成物の粘度低下や、起泡力が低下等が起こり、さらに経時でのゲルの収縮が起こる等の経時安定性上好ましくない場合があった。 Further, in the gel composition in which fumed silica is blended as a gelling agent in the cleaning composition as described above, it is obtained by keeping the viscosity of the aqueous cleaning solution solution before containing fumed silica higher. In the case of the techniques of Patent Document 10 and Patent Document 11, for the purpose of preservatives, propylene glycol or 1 , 3-butanediol, dipropylene glycol and other polyhydric alcohols need to be blended in large amounts. As a result, the viscosity of the cleaning composition is reduced, the foaming power is reduced, and the gel shrinks over time. In some cases, it was not preferable in terms of stability over time.
従って、起泡力に優れ、洗いあがりの肌のつっぱり感が無く、良好な使用性を与える粘性を有し、また経時安定性にも優れていることを特徴とする洗浄剤組成物の開発が望まれていた。 Therefore, the development of a detergent composition characterized by excellent foaming power, no feeling of firmness of the washed-up skin, viscosity giving good usability, and excellent stability over time It was desired.
かかる実情において、本発明者らは、上記課題を解決するために鋭意研究を重ねた結果、炭素数12〜18の高級脂肪酸塩から選ばれる一種又は二種以上と炭素数12〜18の脂肪酸モノエタノールアミド及び/又はジエタノールアミドから選ばれる一種又は二種以上、水、1,2−ペンタンジオールからなる洗浄剤組成物が、起泡力に優れ、良好な使用性を与える粘性を持ち、洗いあがりの肌のつっぱり感が無い効果に優れることを見出し、さらに煙霧状シリカを含有することにより、前記効果に加えて、経時安定性にも優れることを見出し、本発明を完成するに至った。 In such a situation, the present inventors have conducted intensive research to solve the above problems, and as a result, one or more selected from higher fatty acid salts having 12 to 18 carbon atoms and fatty acid monoesters having 12 to 18 carbon atoms. A cleaning composition comprising one or more selected from ethanolamide and / or diethanolamide, water, and 1,2-pentanediol has excellent foaming power and has a viscosity that gives good usability, and is washed out In addition to the above-mentioned effects, the present inventors have found that it is excellent in the effect that there is no feeling of skin firmness and that it contains fumed silica, and has completed the present invention.
すなわち、本発明は次の成分(A)〜(D);
(A) 炭素数12〜18の高級脂肪酸塩から選ばれる一種又は二種以上
(B) 炭素数12〜18の脂肪酸モノエタノールアミド及び/又はジエタノールアミドから選ばれる一種又は二種以上
(C) 水
(D) 1,2−ペンタンジオール
を含有することを特徴とする洗浄剤組成物に関する。
That is, the present invention includes the following components (A) to (D);
(A) One or two or more types selected from higher fatty acid salts having 12 to 18 carbon atoms (B) One or two or more types selected from fatty acid monoethanolamides and / or diethanolamides having 12 to 18 carbon atoms (C) Water (D) The present invention relates to a cleaning composition containing 1,2-pentanediol.
さらに成分(E)煙霧状シリカを含有することを特徴とする洗浄剤組成物に関する。 Furthermore, it is related with the cleaning composition characterized by containing a component (E) fumed silica.
また成分(A)の含有量が5〜25質量%、成分(B)の含有量が2〜10質量%、成分(E)の含有量が5〜15質量%であることを特徴とする洗浄剤組成物に関する。 The cleaning is characterized in that the content of the component (A) is 5 to 25% by mass, the content of the component (B) is 2 to 10% by mass, and the content of the component (E) is 5 to 15% by mass. The agent composition.
本発明の洗浄剤組成物は、起泡力に優れ、洗い上がりの肌のつっぱり感が無く、良好な使用性を与える粘性を有し、また経時安定性にも優れる品質を有する。 The cleaning composition of the present invention has excellent foaming power, no feeling of firmness of the washed-out skin, a viscosity that gives good usability, and a quality that is also excellent in stability over time.
本発明について詳細に説明する。
本発明の成分(A)である炭素数12〜18の高級脂肪酸塩は、製剤における起泡力の付与の目的で配合され、化粧品一般に通常用いられる高級脂肪酸塩であれば特に制限なく用いることができ、予め中和された脂肪酸塩であっても、脂肪酸と塩基を製造工程内で中和することにより脂肪酸塩を形成させて配合しても良い。また性状としては固形状、液状などの制限もない。このような成分(a)に用いられる炭素数12〜18の高級脂肪酸塩としては、特に限定されず、脂肪酸としては飽和、不飽和もしくは直鎖、分岐いずれの脂肪酸も用いることができるが、例えばラウリン酸、ミリスチン酸、パルミチン酸、イソステアリン酸、オレイン酸などの単一脂肪酸の他、ヤシ油脂肪酸、牛脂脂肪酸等の混合脂肪酸が挙げられる。また塩基としては、水酸化ナトリウム、水酸化カリウムなどの無機塩基、アンモニウム塩、モノエタノールアミン塩、ジエタノールアミン塩、トリエタノールアミン塩、2−アミノ−2−メチルプロパノール、2−アミノ−2−メチルプロパンジオールなどのアルカノールアミン、リジン、アルギニンなどの塩基性アミノ酸などが挙げられ、この中で無機塩基およびトリエタノールアミン塩が好ましく、特に起泡性等の観点から水酸化カリウムが好ましい。これらはあらかじめ中和物として配合してもよいし、別々に配合して中和しても構わない。尚、一部未中和の脂肪酸が存在する場合には、pHの上昇が抑えられ、皮膚刺激抑制の観点からも好ましいことから、中和率は50〜95%が好ましい。固形状の成分(A)の市販例は、固形粉末状のラウリン酸カリウムである、ニッコール KM−4150(日光ケミカルズ社製)、ラウリン酸亜鉛である、ジンクラウレート パウダーベースL(日油社製)、ステアリン酸カルシウムである、カルシウムステアレート(日油社製)等が挙げられる。また、液状の成分(A)市販例としては、ヤシ油脂肪酸カリウム液である、アルホームK−100(新日本理化社製)、ヤシ油脂肪酸トリエタノールアミン液である、アルホームT−200(新日本理化社製)、ヤシ油脂肪酸カリウム・ミリスチン酸カリウム配合液体である、ニッコールMNK−40(日光ケミカルズ社製)等が挙げられる。
The present invention will be described in detail.
The higher fatty acid salt having 12 to 18 carbon atoms, which is the component (A) of the present invention, is blended for the purpose of imparting foaming power in the preparation, and can be used without particular limitation as long as it is a higher fatty acid salt generally used in cosmetics in general. Even if the fatty acid salt is neutralized in advance, the fatty acid salt may be formed by neutralizing the fatty acid and the base in the production process. Moreover, there is no restriction | limiting, such as solid form and liquid form, as a property. The higher fatty acid salt having 12 to 18 carbon atoms used for such component (a) is not particularly limited, and as the fatty acid, any of saturated, unsaturated, linear or branched fatty acids can be used. In addition to single fatty acids such as lauric acid, myristic acid, palmitic acid, isostearic acid and oleic acid, mixed fatty acids such as coconut oil fatty acid and beef tallow fatty acid can be mentioned. Examples of the base include inorganic bases such as sodium hydroxide and potassium hydroxide, ammonium salts, monoethanolamine salts, diethanolamine salts, triethanolamine salts, 2-amino-2-methylpropanol, and 2-amino-2-methylpropane. Examples include alkanolamines such as diols, and basic amino acids such as lysine and arginine. Among them, inorganic bases and triethanolamine salts are preferable, and potassium hydroxide is particularly preferable from the viewpoint of foamability and the like. These may be blended in advance as neutralized products, or may be blended separately and neutralized. In the case where a partially unneutralized fatty acid is present, the neutralization rate is preferably 50 to 95% because an increase in pH is suppressed and this is preferable from the viewpoint of suppressing skin irritation. Commercial examples of the solid component (A) are solid powder potassium laurate, Nikkor KM-4150 (manufactured by Nikko Chemicals), zinc laurate, zinc laureate powder base L (manufactured by NOF Corporation) ), Calcium stearate (manufactured by NOF Corporation), which is calcium stearate. Moreover, as a liquid component (A) commercial example, Alhome K-100 (made by Shin Nippon Rika Co., Ltd.) which is a coconut oil fatty acid potassium liquid, Alhome T-200 which is a coconut oil fatty acid triethanolamine liquid ( New Nippon Rika Co., Ltd.), Nikkor MNK-40 (manufactured by Nikko Chemicals Co., Ltd.), which is a liquid containing potassium coconut oil fatty acid and potassium myristate.
本発明の成分(A)の含有量は、特に限定されるものではないが、5〜25質量%(以下、「質量%」は単に「%」と略す)が好ましく、また10〜20%がより好ましい。この範囲にすることで、起泡力に優れたものを得ることができる。 The content of the component (A) of the present invention is not particularly limited, but is preferably 5 to 25% by mass (hereinafter, “mass%” is simply abbreviated as “%”), and 10 to 20% is preferable. More preferred. By setting it within this range, a product having excellent foaming power can be obtained.
本発明の洗浄剤組成物に用いられる成分(B)の炭素数12〜18の脂肪酸モノエタノールアミド及び/又はジエタノールアミドは、成分(A)とともに用いることで洗浄剤組成物の粘度を向上させる目的で配合されるものである。通常、化粧品一般に通常用いられているものであれば特に制限なく用いることが出来る。具体的には、ラウリン酸モノエタノールアミド、ミリスチン酸モノエタノールアミド、パルミチン酸モノエタノールアミド、ステアリン酸モノエタノールアミド、ラウリン酸ジエタノールアミド、ミリスチン酸ジエタノールアミド、パルミチン酸ジエタノールアミド、ステアリン酸ジエタノールアミド、ヤシ油脂肪酸モノエタノールアミド、ヤシ油脂肪酸ジエタノールアミド等が挙げられる。これらの市販例としては、アミゾールCME(川研ファインケミカル社製)、アミゾールCDE(川研ファインケミカル社製)、トーホール230−XY(東邦化学社製)等が挙げられる。 The purpose of improving the viscosity of the cleaning composition by using the C12-18 fatty acid monoethanolamide and / or diethanolamide of the component (B) used in the cleaning composition of the present invention together with the component (A). It is blended with. Usually, any cosmetics generally used can be used without particular limitation. Specifically, lauric acid monoethanolamide, myristic acid monoethanolamide, palmitic acid monoethanolamide, stearic acid monoethanolamide, lauric acid diethanolamide, myristic acid diethanolamide, palmitic acid diethanolamide, stearic acid diethanolamide, palm Examples include oil fatty acid monoethanolamide and coconut oil fatty acid diethanolamide. Examples of these commercially available products include Amizole CME (manufactured by Kawaken Fine Chemical Co., Ltd.), Amizole CDE (manufactured by Kawaken Fine Chemical Co., Ltd.), To-Hole 230-XY (manufactured by Toho Chemical Co., Ltd.), and the like.
本発明の成分(B)の含有量は、特に限定されるものではないが、2〜10質量%が好ましく、さらに4〜8%がより好ましい。この範囲にすることで、洗浄剤組成物の粘度を向上させるとともに、使用性上好ましい洗浄剤組成物とすることができる。 Although content of the component (B) of this invention is not specifically limited, 2-10 mass% is preferable, and also 4-8% is more preferable. By setting it as this range, while improving the viscosity of a cleaning composition, it can be set as a preferable cleaning composition on usability.
本発明の成分(C)の水は、成分(A)の希釈溶媒や、成分(E)煙霧状シリカの膨潤溶媒としての目的で含有されるものであり、化粧品一般に通常用いられる水であれば特に制限なく用いることが出来る。 The water of component (C) of the present invention is contained for the purpose of diluting solvent of component (A) and swelling solvent of component (E) fumed silica, and is water that is generally used for cosmetics in general. It can be used without particular limitation.
本発明の成分(C)の含有量は、特に限定されないが製剤の使用に好適な粘度や使用性上の点で概ね30〜90%が好ましい。 Although content of the component (C) of this invention is not specifically limited, About 30 to 90% is preferable at the point on the viscosity suitable for use of a formulation, or usability.
本発明の成分(D)の1,2−ペンタンジオールは、洗浄剤組成物の防腐剤としての目的で配合するものである。これは従来、防腐剤として用いられているプロピレングリコール、1,3−ブタンジオール、ジプロピレングリコール、グリセリン等の多価アルコール類と比較して、約3倍程度の防腐力を有しており、洗浄剤組成物への含有量を低減することが可能である。 The component (D) 1,2-pentanediol of the present invention is blended for the purpose of preserving the cleaning composition. Compared with polyhydric alcohols such as propylene glycol, 1,3-butanediol, dipropylene glycol, and glycerin, which have been conventionally used as preservatives, this has a preservative power of about 3 times. It is possible to reduce the content in the cleaning composition.
多価アルコール類は一般に、成分(A)及び成分(B)を含む洗浄剤組成物に含有することで粘度低下が起こることが知られている。本発明において従来の多価アルコール類ではなく、成分(D)を含有させることにより、防腐力に優れるだけでなく、洗浄剤組成物の粘度低下を抑えることができ、起泡力および経時安定性の観点からも非常に有用なものとなる。このような成分(D)としては、化粧品一般に通常用いられる1,2−ペンタンジオールであれば特に制限なく用いることが出来る。また、上記成分(D)の1,2−ペンタンジオールの市販例としては、HYDROLITE−5(シムライズ社製)、OriStar PTG(Orient Stars LLC社製)等が挙げられる。 In general, it is known that polyhydric alcohols are reduced in viscosity when contained in a detergent composition containing component (A) and component (B). In the present invention, by containing the component (D) instead of the conventional polyhydric alcohols, not only the antiseptic power is excellent, but also the viscosity reduction of the cleaning composition can be suppressed, the foaming power and the stability over time. From this point of view, it is very useful. As such component (D), any 1,2-pentanediol which is generally used in cosmetics can be used without particular limitation. Moreover, as a commercial example of the 1, 2- pentanediol of the said component (D), HYDROLITE-5 (made by Simrise), OriStar PTG (made by Orient Stars LLC), etc. are mentioned.
本発明の成分(D)の含有量は、特に限定されないが、洗浄剤組成物への防腐力を付与するという点や、洗浄剤組成物の起泡力などの点から3〜7%が好ましい。 The content of the component (D) of the present invention is not particularly limited, but is preferably 3 to 7% from the viewpoint of imparting antiseptic power to the cleaning composition and foaming power of the cleaning composition. .
本発明の成分(E)の煙霧状シリカは、洗浄剤組成物の粘度を向上させるゲル化剤として用いられるものであり、化粧品一般に通常用いられる煙霧状シリカであれば特に制限なく用いることが出来る。また、成分(E)の具体例としては、特に限定されないが、5nm〜20nmの粒径であるものが好ましい。市販品としては、例えばAEROSIL 380S(日本アエロジル社製、平均粒子径:5〜7nm)、AEROSIL 200(日本アエロジル社製、平均粒子径:10〜15nm)、AEROSIL R972(日本アエロジル社製、平均粒子径:16nm)、AEROSIL R976S(日本アエロジル社製、平均粒子径:5〜10nm)等の市販品が挙げられる。 The fumed silica of the component (E) of the present invention is used as a gelling agent for improving the viscosity of the detergent composition, and can be used without particular limitation as long as it is fumed silica generally used in cosmetics in general. . Specific examples of the component (E) are not particularly limited, but those having a particle diameter of 5 nm to 20 nm are preferable. Examples of commercially available products include AEROSIL 380S (manufactured by Nippon Aerosil Co., Ltd., average particle size: 5 to 7 nm), AEROSIL 200 (manufactured by Nippon Aerosil Co., Ltd., average particle size: 10-15 nm), AEROSIL R972 (manufactured by Nippon Aerosil Co., Ltd., average particle size) And commercial products such as AEROSIL R976S (manufactured by Nippon Aerosil Co., Ltd., average particle size: 5 to 10 nm).
本発明の成分(E)の含有量は、5〜15%が好ましく、さらには7〜13%がより好ましい。含有量がこの範囲であれば、洗いあがりのつっぱり感が無く、また良好な経時安定性を有するものを得ることができる。 The content of the component (E) of the present invention is preferably 5 to 15%, more preferably 7 to 13%. If the content is within this range, it is possible to obtain a product that has no feeling of being washed up and has good stability over time.
本発明の製造方法としては、成分(A)、成分(B)、成分(C)を60℃に加温し、均一に混合溶解後、室温まで冷却したものに、成分(D)を添加し均一に混合溶解することで得られる。またこのものに成分(E)を添加し、均一に混合攪拌することで、ゲル状の洗浄剤組成物とすることが可能である。 In the production method of the present invention, the component (A), the component (B), and the component (C) are heated to 60 ° C., mixed and dissolved uniformly, and then cooled to room temperature. It is obtained by mixing and dissolving uniformly. Moreover, it is possible to make a gel-like cleaning composition by adding a component (E) to this thing and mixing and stirring uniformly.
本発明の洗浄料組成物には、上記必須成分のほかに通常化粧料に使用する成分、すなわち、油性成分、低級アルコール、保湿剤等の水性成分、紫外線吸収剤、酸化防止剤、防腐剤、油溶性高分子、油溶性樹脂、染料、清涼剤、色素、香料等を本発明の効果を妨げない範囲で適宜配合することができる。 In the cleaning composition of the present invention, in addition to the above essential components, components commonly used in cosmetics, that is, oily components, lower alcohols, aqueous components such as humectants, ultraviolet absorbers, antioxidants, preservatives, An oil-soluble polymer, an oil-soluble resin, a dye, a refreshing agent, a pigment, a fragrance, and the like can be appropriately blended within a range that does not hinder the effects of the present invention.
油性成分としては、化粧品に一般に使用される動物油、植物油、合成油等の起源の固形油、半固形油、液体油、揮発性油等の性状を問わず、炭化水素類、油脂類、ロウ類、硬化油類、エステル油類、脂肪酸類、高級アルコール類、シリコーン油類、フッ素系油類、油性ゲル化剤類等が挙げられる。具体的には、流動パラフィン、スクワラン、ワセリン、ポリイソブチレン、ポリブテン、モンタンワックス等の炭化水素類、オリーブ油、ヒマシ油、ミンク油、マカデミアンナッツ油等の油脂類、モクロウ、ミツロウ、ゲイロウ等のロウ類、セチルイソオクタネート、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸オクチルドデシル、ジイソステアリン酸ポリグリセリル、ロジン酸ペンタエリスリットエステル、ジオクタン酸ネオペンチルグリコール、キャンデリラワックス等のエステル類、ステアリン酸、ラウリン酸、ミリスチン酸、ベヘニン酸、イソステアリン酸、オレイン酸等の脂肪酸類、ステアリルアルコール、セチルアルコール、ラウリルアルコール、オレイルアルコール、イソステアリルアルコール、ベヘニルアルコール等の高級アルコール類、メチルポリシロキサン、メチルフェニルポリシロキサン、トリメチルシロキシケイ酸、高重合メチルポリシロキサン、高重合メチルフェニルポリシロキサン、架橋型メチルポリシロキサン、架橋型メチルフェニルポリシロキサン、架橋型ポリエーテル変性メチルポリシロキサン、メタクリル変性ポリシロキサン、ステアリル変性メチルポリシロキサン、ポリビニルピロリドン変性メチルポリシロキサン、ポリエーテル変性ポリシロキサン低重合度ジメチルポリシロキサン、高重合度ジメチルポリシロキサン、ポリオキシアルキレン・アルキルメチルポリシロキサン共重合体、アルコキシ変性ポリシロキサン、架橋型オルガノポリシロキサン、フッ素変性ポリシロキサン等のシリコーン類、パーフルオロデカン、パーフルオロオクタン、パーフルオロポリエーテル等のフッ素系油剤類、デキストリン脂肪酸エステル、蔗糖脂肪酸エステル、デンプン脂肪酸エステル、イソステアリン酸アルミニウム、ステアリン酸カリウム、12―ヒドロキシステアリン酸等の油性ゲル化剤等が挙げられ、これらを一種又は二種以上用いることができる。 Oily components include hydrocarbons, fats and waxes, regardless of the nature of solid oils, semi-solid oils, liquid oils, volatile oils, etc. , Hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorinated oils, oily gelling agents and the like. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, polyisobutylene, polybutene and montan wax, oils and fats such as olive oil, castor oil, mink oil, macadamian nut oil, wax such as owl, beeswax and gay wax Cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, polyglyceryl diisostearate, pentaerythritol ester of rosin acid, neopentyl glycol dioctanoate, candelilla wax, stearic acid, lauric acid , Fatty acids such as myristic acid, behenic acid, isostearic acid, oleic acid, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, Higher alcohols such as nyl alcohol, methylpolysiloxane, methylphenylpolysiloxane, trimethylsiloxysilicic acid, highly polymerized methylpolysiloxane, highly polymerized methylphenylpolysiloxane, crosslinked methylpolysiloxane, crosslinked methylphenylpolysiloxane, crosslinked Polyether-modified methylpolysiloxane, methacryl-modified polysiloxane, stearyl-modified methylpolysiloxane, polyvinylpyrrolidone-modified methylpolysiloxane, polyether-modified polysiloxane low polymerization dimethylpolysiloxane, high polymerization dimethylpolysiloxane, polyoxyalkylene alkylmethyl Polysiloxane copolymers, alkoxy-modified polysiloxanes, crosslinked organopolysiloxanes, silicones such as fluorine-modified polysiloxanes, perfluoro Fluorine oils such as decane, perfluorooctane, perfluoropolyether, oily gelling agents such as dextrin fatty acid ester, sucrose fatty acid ester, starch fatty acid ester, aluminum isostearate, potassium stearate, 12-hydroxystearic acid, etc. 1 type, or 2 or more types can be used.
水性成分としては、水に可溶な成分であれば何れでもよく、その他に、例えばエチルアルコール、ブチルアルコール等の低級アルコール、プロピレングリコール、1,3−ブチレングリコール、ジプロピレングリコール、ポリエチレングリコール等のグリコール類、グリセリン、ジグリセリン、ポリグリセリン等のグリセロール類、アロエベラ、ウイッチヘーゼル、ハマメリス、キュウリ、レモン、ラベンダー、ローズ等の植物抽出液が挙げられる。また保湿剤として、例えばタンパク質、ムコ多糖、コラーゲン、エラスチン、ケラチン等が挙げられ、これらより一種又は二種を用いることができる。 As the aqueous component, any component that is soluble in water may be used. Besides, for example, lower alcohols such as ethyl alcohol and butyl alcohol, propylene glycol, 1,3-butylene glycol, dipropylene glycol, polyethylene glycol and the like. Glycerols such as glycols, glycerin, diglycerin and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose. Examples of the humectant include protein, mucopolysaccharide, collagen, elastin, keratin and the like, and one or two of them can be used.
紫外線吸収剤としては、例えばベンゾフェノン系、パラアミノ安息香酸系、ケイ皮酸系、サリチル酸系、4−tert−ブチル−4´−メトキシベンゾイルメタン、オキシベンゾン等が挙げられ、これらより一種又は二種を用いることができる。 Examples of the ultraviolet absorber include benzophenone-based, paraaminobenzoic acid-based, cinnamic acid-based, salicylic acid-based, 4-tert-butyl-4'-methoxybenzoylmethane, oxybenzone, and the like. One or two of these are used. be able to.
酸化防止剤としては、例えばα−トコフェロール、アスコルビン酸等、美容成分としては例えばビタミン類、消炎剤、生薬等、防腐剤としては、例えばパラオキシ安息香酸エステル、フェノキシエタノール等が挙げられ、これらより一種又は二種を用いることができる。 Examples of the antioxidant include α-tocopherol and ascorbic acid, examples of the beauty component include vitamins, anti-inflammatory agents, herbal medicines, and examples of the antiseptic include paraoxybenzoic acid ester and phenoxyethanol. Two types can be used.
本発明の洗浄剤組成物の用途は、洗顔料、クレンジング料、シャンプー、ボディー洗浄料等を例示することができる。また洗浄剤組成物の性状としては、低粘度である液状から成分(E)を含有することで粘度を増加させてゲル状とすることが可能である。本発明にはおいては成分(D)を用いることで防腐力に優れるだけでなく、洗浄剤組成物の粘度低下を抑えることができる。またさらに成分(E)を含有することで、起泡力および経時安定性の観点からも非常に有用なものとすることが可能となることからゲル状洗浄剤組成物において特に優れた効果を得ることができる。 Examples of the use of the cleaning composition of the present invention include facial cleansing agents, cleansing agents, shampoos, body cleaners and the like. Moreover, as a property of a cleaning composition, a viscosity can be increased by containing a component (E) from the liquid with a low viscosity, and it can be made into a gel form. In the present invention, by using the component (D), not only the antiseptic power is excellent, but also the viscosity reduction of the cleaning composition can be suppressed. Further, by containing the component (E), it is possible to make it very useful also from the viewpoint of foaming power and stability over time, so that a particularly excellent effect is obtained in the gel detergent composition. be able to.
液状洗浄剤組成物としては、ディスペンサーやポンプ等の容器での使用が想定され、またゲル状洗浄剤組成物としては、チューブ容器での使用が想定されるが、これに限定されるものではない。 The liquid detergent composition is assumed to be used in a container such as a dispenser or pump, and the gel detergent composition is assumed to be used in a tube container, but is not limited thereto. .
次に実施例を挙げて本発明を更に詳細に説明するが、本発明はこれらにより何ら限定されるものではない。 EXAMPLES Next, although an Example is given and this invention is demonstrated still in detail, this invention is not limited at all by these.
本発明品1〜9及び比較品1〜5:洗浄剤組成物(液状)
下記表1及び表2に示す洗浄剤組成物を調製し、その起泡力、洗い上がりのつっぱり感のなさ、粘度に関して下記の方法により評価した。その結果も併せて表1及び表2に示す。
Invention products 1-9 and comparative products 1-5: Detergent composition (liquid)
The cleaning compositions shown in Tables 1 and 2 below were prepared and evaluated by the following methods with respect to their foaming power, lack of feeling of being washed up, and viscosity. The results are also shown in Tables 1 and 2.
*1: ニッコール KM−4150 (日光ケミカルズ社製)
*2: アルホーム T−200 (新日本理化社製)
*3: アミゾールCME (川研ファインケミカル社製)
*4: トーホール230−XY (東邦化学社製)
*5: アミゼット 1PC (川研ファインケミカル社製)
*6: ペミュレン TR−1 (NOVEON社製)
*7: HYDROLITE−5 (シムライズ社製)
* 1: Nikkor KM-4150 (Nikko Chemicals)
* 2: Alhome T-200 (manufactured by Shin Nippon Rika Co., Ltd.)
* 3: Amidol CME (manufactured by Kawaken Fine Chemical Co., Ltd.)
* 4: Tohoru 230-XY (manufactured by Toho Chemical Co., Ltd.)
* 5: Amidette 1PC (manufactured by Kawaken Fine Chemical Co., Ltd.)
* 6: Pemulen TR-1 (Noveon)
* 7: HYDROLITE-5 (manufactured by Simrise)
(製造方法)
A:成分1〜8を60℃に加温し、均一に混合溶解させる。
B:A成分を室温まで冷却し、成分9〜11を加えて均一に混合溶解させる。
C:容器に充填し、洗浄剤組成物(液状)を得た。
(Production method)
A: Ingredients 1 to 8 are heated to 60 ° C. and mixed and dissolved uniformly.
B: A component is cooled to room temperature, and components 9 to 11 are added and mixed and dissolved uniformly.
C: The container was filled to obtain a cleaning composition (liquid).
(評価方法)
下記評価項目について各々下記方法により評価を行った。
(評価項目)
イ.起泡力
ロ.洗いあがりのつっぱり感のなさ
ハ.粘度
イについては、各試料の1質量%の水溶液を作成し、ロスマイルス法にて起泡力の評価を行った。更に得られた泡の高さ値を下記4段階判定基準により判定した。またロについては専門パネル20名による使用テストを行い、そのつっぱり感のなさについて、それぞれ下記絶対評価にて7段階に評価し評点をつけ、各試料ごとにパネル全員の評点合計からその平均値を算出し、下記4段階判定基準により判定した。ハについては、各試料の15℃における粘度を測定し、下記4段階判定基準により判定した。また粘度に関しては、芝浦システム社製 B型回転粘度計を用いて測定した。
(Evaluation methods)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
I. Foaming power b. There is no feeling of picking up after washing. Regarding the viscosity A, a 1% by mass aqueous solution of each sample was prepared, and the foaming power was evaluated by the Ross Miles method. Furthermore, the height value of the obtained foam was determined according to the following four-stage criteria. In addition, a test on the use of 20 specialist panels was conducted for b), and each of the samples was scored with 7 grades based on the following absolute evaluation, and the average value was calculated from the total score of all panel members for each sample. Calculated and judged according to the following four-step criteria. For c, the viscosity at 15 ° C. of each sample was measured and judged according to the following four-step criteria. The viscosity was measured using a B-type rotational viscometer manufactured by Shibaura System.
本発明の起泡力の評価に用いたロスマイルス法(ISO696、JIS K 3362)は、次に示す手順に準じて行なった。具体的には、試験液200mlを90cmの高さから、同濃度、同温度の試験液50mlを入れた目盛管中へ、直径2.9mmの細孔を通して流し込み、流下直後の泡の高さを測定するという方法を用いて行った。 The Ross Miles method (ISO 696, JIS K 3362) used for the evaluation of the foaming power of the present invention was performed according to the following procedure. Specifically, 200 ml of the test solution was poured from a height of 90 cm into a scale tube containing 50 ml of the test solution having the same concentration and the same temperature, through a pore having a diameter of 2.9 mm. The measurement was performed using a method.
4段階判定基準
<ロスマイルス法による泡高さ値>
◎ : 300mm以上
○ : 200mm以上300mm未満
△ : 50mm以上200mm未満
× : 50mm未満
4-stage criteria <Bubble height value by the Ross Miles method>
◎: 300 mm or more ○: 200 mm or more and less than 300 mm △: 50 mm or more and less than 200 mm ×: less than 50 mm
<洗いあがりのつっぱり感のなさ>
絶対評価基準
(評点) : (評価)
5点:良好
4点:やや良好
3点:普通
2点:やや不良
1点:不良
<There is no feeling of picking up after washing>
Absolute Evaluation Criteria (Score): (Evaluation)
5 points: good 4 points: slightly good 3 points: normal 2 points: slightly bad 1 point: bad
4段階判定基準
(判定) : (評点の平均点)
◎ : 4.5点以上 : 非常に良好
○ : 3.5点以上4.5点未満 : 良好
△ : 2.5点以上3.5点未満 : やや不良
× : 2.5点未満 : 不良
Four-step criteria (Judgment): (Average score)
◎: 4.5 points or more: Very good ○: 3.5 points or more and less than 4.5 points: Good △: 2.5 points or more and less than 3.5 points: Slightly poor ×: Less than 2.5 points: Bad
4段階判定基準
(判定) : (粘度)
◎ : 2000mPa・S以上
○ : 500mPa・S以上2000mPa・S未満
△ : 100mPa・S以上500mPa・S未満
× : 100mPa・S未満
4-step criteria (Judgment): (Viscosity)
◎: 2000 mPa · S or more ○: 500 mPa · S or more and less than 2000 mPa · S Δ: 100 mPa · S or more and less than 500 mPa · S ×: Less than 100 mPa · S
表1及び表2の結果から明らかな如く、本発明品1〜9の洗浄剤組成物は、比較品1〜5の洗浄剤組成物に比べ、起泡力、洗い上がりのつっぱり感のなさ、粘度の全てにおいて優れたものであった。これに対して、成分(A)の代わりにヤシ油脂肪酸メチルタウリンナトリウムを用いた比較品1や成分(B)の代わりにポリオキシプロピレン(1)ヤシ油脂肪酸モノイソプロパノールアミドを用いた比較品2においては、本発明の成分(A)と成分(B)の組み合わせによる増粘効果が得られず、起泡力や洗い上がりのつっぱり感のなさにおいても劣るものであった。また成分(B)の代わりにアクリル酸アルキルコポリマーを用いた比較品3においては、アクリル酸アルキルコポリマーに由来する膜感が、洗い上がりの肌に残ってしまい、洗い上がりのつっぱり感のなさの点で満足のいくものが得られなかった。また成分(D)の代わりに、1,3−ブタンジオール及びプロピレングリコールを用いて洗浄剤組成物の防腐力を同程度にした比較品4及び比較品5においては、洗浄剤組成物の粘度や起泡力が、著しく劣るものであった。 As is clear from the results of Tables 1 and 2, the detergent compositions of the present invention products 1 to 9 are less foaming power and lack of feeling of being washed up than the cleaning compositions of comparative products 1 to 5, Excellent in all viscosities. In contrast, Comparative Product 1 using coconut oil fatty acid methyl taurine sodium instead of Component (A) and Comparative Product 2 using polyoxypropylene (1) coconut oil fatty acid monoisopropanolamide instead of Component (B) In the method, the thickening effect by the combination of the component (A) and the component (B) of the present invention was not obtained, and the foaming power and the lack of feeling of being washed up were inferior. Moreover, in the comparative product 3 using the alkyl acrylate copolymer instead of the component (B), the film feeling derived from the alkyl acrylate copolymer remains on the washed-up skin, and the feeling of unsmoothness after washing is not observed. I couldn't get anything satisfactory. Moreover, in the comparative product 4 and the comparative product 5 in which the preservative power of the cleaning composition is made comparable using 1,3-butanediol and propylene glycol in place of the component (D), the viscosity of the cleaning composition is The foaming power was remarkably inferior.
本発明品10〜20及び比較品6〜11:洗浄剤組成物(ゲル状)
下記表3及び表4に示す洗浄剤組成物を調製し、その起泡力、洗いあがりのつっぱり感のなさ、経時安定性に関して下記の方法により評価した。その結果も併せて表3及び表4に示す。
Invention products 10 to 20 and comparative products 6 to 11: Detergent composition (gel)
The cleaning compositions shown in Tables 3 and 4 below were prepared and evaluated by the following methods with respect to their foaming power, lack of feeling of being washed away, and stability over time. The results are also shown in Tables 3 and 4.
*8: AEROSIL 300 (日本アエロジル社製) * 8: AEROSIL 300 (Nippon Aerosil Co., Ltd.)
(製造方法)
A:成分1〜8を60℃に加温し、均一に混合溶解させる。
B:A成分を室温まで冷却し、成分9〜11を加えて均一に混合溶解させる。
C:B成分に、成分12〜13を加えて均一に混合する。
D:容器に充填し、洗浄剤組成物を得た。
(Production method)
A: Ingredients 1 to 8 are heated to 60 ° C. and mixed and dissolved uniformly.
B: The component A is cooled to room temperature, and components 9 to 11 are added and mixed and dissolved uniformly.
C: Components 12 to 13 are added to component B and mixed uniformly.
D: The container was filled to obtain a cleaning composition.
(評価方法)
イ.起泡力
ロ.洗いあがりのつっぱり感のなさ
ニ.経時安定性
イ及びロについては実施例1と同様の方法に評価を行った。ニについては、各試料を5℃及び50℃の恒温遮光条件下に1ヶ月静置し、それぞれの1ヶ月後の状態を比較し、下記4段階判定基準により判定した。
(Evaluation methods)
I. Foaming power b. There is no feeling of squeezing after washing. The stability over time A and B were evaluated in the same manner as in Example 1. As for D, each sample was allowed to stand for 1 month under a constant temperature light-shielding condition at 5 ° C. and 50 ° C., and the state after each month was compared and determined according to the following four-stage criteria.
4段階判定基準
(判定) : (経時安定性;5℃試料と50℃試料の比較)
◎ : 離しょうが全く観察されない
○ : わずかに離しょうが観察されるが問題ないレベル
△ : 離しょうが観察され問題となるレベル
× : 著しく離しょうが観察される
4-step criteria (Judgment): (Stability over time; Comparison between 5 ° C and 50 ° C samples)
◎: The separation is not observed at all ○: The slight separation is observed but no problem △: The separation is observed and becomes a problem ×: The separation is remarkably observed
表3及び表4の結果から明らかな如く、本発明品10〜20の洗浄剤組成物は、比較品6〜11の洗浄剤組成物に比べ、起泡力、洗い上がりのつっぱり感のなさ、経時安定性の全てにおいて優れたものであった。これに対して、成分(A)の代わりにヤシ油脂肪酸メチルタウリンナトリウムを用いた比較品6及び、成分(B)の代わりにポリオキシプロピレン(1)ヤシ油脂肪酸モノイソプロパノールアミドを用いた比較品7においては、本発明の成分(A)と成分(B)の組み合わせによる増粘効果が得られず、起泡力や洗い上がりのつっぱり感のなさにおいても劣るものであり、これに煙霧状シリカを含有させても経時安定性の点で満足の行くものが得られなかった。成分(B)の代わりにアクリル酸アルキルコポリマーを用いた比較品8においては、アクリル酸アルキルコポリマーに由来する膜感が、洗い上がりの肌に残ってしまい、洗い上がりのつっぱり感のなさの点で満足の行くものが得られなかった。成分(D)の代わりに、1,3−ブタンジオール及びプロピレングリコールを用いて洗浄剤組成物の防腐力を同程度にした比較品9及び比較品10においては、洗浄剤組成物の起泡力や経時安定性が、著しく劣るものであった。成分(E)の代わりに不定形シリカを用いた比較品11においては、起泡力や洗い上がりのつっぱり感のなさ等には優れるが、煙霧状シリカを用いた場合に得られたようなゲル状の洗浄剤組成物を形成させることはできなかった。 As is clear from the results of Tables 3 and 4, the detergent compositions of the present invention products 10 to 20 are less foaming power and have no feeling of being washed up, compared to the detergent compositions of Comparative products 6 to 11. All of the stability over time was excellent. On the other hand, the comparative product 6 using coconut oil fatty acid methyl taurine sodium instead of the component (A) and the comparative product using polyoxypropylene (1) coconut oil fatty acid monoisopropanolamide instead of the component (B) In No. 7, the thickening effect by the combination of the component (A) and the component (B) of the present invention cannot be obtained, and it is inferior in foaming power and lack of feeling of being washed up. Even if it was added, no satisfactory product was obtained in terms of stability over time. In the comparative product 8 using the alkyl acrylate copolymer instead of the component (B), the film feeling derived from the alkyl acrylate copolymer remains on the washed-up skin, and there is no feeling of the feeling of washing after washing. I couldn't get anything satisfactory. In Comparative Product 9 and Comparative Product 10 in which 1,3-butanediol and propylene glycol are used in place of component (D) and the preservative power of the cleaning composition is made comparable, foaming power of the cleaning composition In addition, the stability over time was extremely inferior. The comparative product 11 using amorphous silica in place of the component (E) is excellent in foaming power and lack of feeling of being washed up, but is a gel obtained when fumed silica is used. It was not possible to form a clean detergent composition.
洗浄剤組成物(液状ボディシャンプー)
(成分) (%)
1.ヤシ油脂肪酸カリウム液(34%) *7 44
2.ヤシ油脂肪酸ジエタノールアミド *8 6
3.水 残量
4.1,2−ペンタンジオール 5
5.ポリメタクリロイルオキシエチルホスホリルコリン *9 0.1
6.香料 適量
7.赤色227号 0.1
Detergent composition (liquid body shampoo)
(Ingredient) (%)
1. Palm oil fatty acid potassium liquid (34%) * 744
2. Palm oil fatty acid diethanolamide * 8 6
3. Water remaining amount 4,1,2-pentanediol 5
5. Polymethacryloyloxyethyl phosphorylcholine * 9 0.1
6). Perfume appropriate amount 7. Red 227 0.1
*7 : アルホーム K−100 (新日本理化社製)
*8 : トーホール N220X (東邦化学工業社製)
*9 : LIPIDURE HM−600 (日油社製)
* 7: Alhome K-100 (manufactured by Shin Nippon Rika)
* 8: To Hall N220X (manufactured by Toho Chemical Industry Co., Ltd.)
* 9: LIPIDURE HM-600 (manufactured by NOF Corporation)
(製造方法)
A:成分1〜3を60℃に加熱して、均一に混合溶解させる。
B:A成分を室温まで冷却し、成分4〜7を添加し均一に混合溶解させる。
C:容器に充填し、洗浄剤組成物(液状ボディシャンプー)を得た。
実施例3の洗浄剤組成物は、起泡力に優れ、また良好な使用性を与える粘性を持ち、洗い上がりの肌につっぱり感のない洗浄剤組成物(液状ボディシャンプー)であった。
(Production method)
A: Components 1 to 3 are heated to 60 ° C. and uniformly mixed and dissolved.
B: The component A is cooled to room temperature, and components 4 to 7 are added and mixed and dissolved uniformly.
C: The container was filled to obtain a cleaning composition (liquid body shampoo).
The cleaning composition of Example 3 was a cleaning composition (liquid body shampoo) that had excellent foaming power, had a viscosity that gave good usability, and had no feeling of sticking to the washed-out skin.
洗浄剤組成物(液状洗顔料)
(成分) (%)
1.ステアリン酸マグネシウム *10 15
2.ラウリン酸モノエタノールアミド *11 3
3.ラウリン酸ジエタノールアミド 3
4.水 残量
5.1,2−ペンタンジオール 5
6.ジラウロイルグルタミン酸リシンナトリウム液(29%) *12 0.1
7.流動パラフィン *13 1
Detergent composition (liquid face wash)
(Ingredient) (%)
1. Magnesium stearate * 10 15
2. Lauric acid monoethanolamide * 11 3
3. Lauric acid diethanolamide 3
4). Water remaining amount 5.1,2-pentanediol 5
6). Dilauroyl glutamate lysine sodium solution (29%) * 12 0.1
7). Liquid paraffin * 13 1
*10 : マグネシウムステアレート (日油社製)
*11 : アミゾール LME (川研ファインケミカル社製)
*12 : ペリセア L−30 (旭化成社製)
*13 : ハイコール K−230 (カネダ社製)
* 10: Magnesium stearate (manufactured by NOF Corporation)
* 11: Amizole LME (manufactured by Kawaken Fine Chemicals)
* 12: Perisea L-30 (Asahi Kasei Corporation)
* 13: High call K-230 (manufactured by Kaneda)
(製造方法)
A:成分1〜4を60℃に加熱して、均一に混合溶解させる。
B:A成分を室温まで冷却し、成分5〜7を添加し均一に混合溶解させる。
C:容器に充填し、洗浄剤組成物(液状洗顔料)を得た。
(Production method)
A: Components 1 to 4 are heated to 60 ° C. and uniformly mixed and dissolved.
B: A component is cooled to room temperature, and components 5 to 7 are added and mixed and dissolved uniformly.
C: The container was filled to obtain a cleaning composition (liquid facial cleanser).
実施例4の洗浄剤組成物は、起泡力に優れ、また良好な使用性を与える粘性を持ち、洗い上がりの肌につっぱり感のない洗浄剤組成物(液状洗顔料)であった。 The detergent composition of Example 4 was a detergent composition (liquid facial cleanser) that had excellent foaming power, had a viscosity that gave good usability, and had no feeling of sticking to the washed-out skin.
洗浄剤組成物(ゲル状洗顔料)
(成分) (%)
1.ラウリン酸カリウム *13 15
2.ココイルメチルタウリンナトリウム液(30%) *14 20
3.オレイン酸ジエタノールアミド *15 6
4.水 残量
5.1,2−ペンタンジオール 5
6.煙霧状シリカ *16 10
7.香料 適量
Detergent composition (gel face wash)
(Ingredient) (%)
1. Potassium laurate * 13 15
2. Cocoyl Methyl Taurine Sodium Solution (30%) * 14 20
3. Oleic acid diethanolamide * 15 6
4). Water remaining amount 5.1,2-pentanediol 5
6). Haze-like silica * 16 10
7). Perfume
*13 : ニッコール ラウリン酸カリLK−120 (日光ケミカルズ社製)
*14 : ダイヤポン K−SF (日油社製)
*15 : スタホーム DOS (日油社製)
*16 : ニップシール E−220 (日本シリカ工業社製)
* 13: Nikkor Potassium laurate LK-120 (Nikko Chemicals)
* 14: Diapon K-SF (manufactured by NOF Corporation)
* 15: Starhome DOS (manufactured by NOF Corporation)
* 16: Nip seal E-220 (Nippon Silica Kogyo Co., Ltd.)
(製造方法)
A:成分1〜4を60℃に加熱して、均一に混合溶解させる。
B:A成分を室温まで冷却し、成分5を添加し均一に混合溶解させる。
C:B成分に成分6〜7を添加し、均一に混合する。
D:容器に充填し、洗浄剤組成物(ゲル状洗顔料)を得た。
(Production method)
A: Components 1 to 4 are heated to 60 ° C. and uniformly mixed and dissolved.
B: The component A is cooled to room temperature, and the component 5 is added and mixed and dissolved uniformly.
C: Components 6 to 7 are added to the B component and mixed uniformly.
D: Filled into a container to obtain a detergent composition (gel facial cleanser).
実施例5の洗浄剤組成物は、起泡力に優れ、また良好な使用性を与える粘性を持ち、洗い上がりの肌につっぱり感がなく、経時安定性に優れる洗浄剤組成物(ゲル状洗顔料)であった。
The detergent composition of Example 5 has excellent foaming power, has a viscosity that gives good usability, has no stickiness on the washed-out skin, and has excellent stability over time (gel-like face wash) Charge).
Claims (3)
(A)炭素数12〜18の高級脂肪酸塩から選ばれる一種又は二種以上
(B)炭素数12〜18の脂肪酸モノエタノールアミド及び/又はジエタノールアミドから選ばれる一種又は二種以上
(C)水
(D)1,2−ペンタンジオール
を含有することを特徴とする洗浄剤組成物 The following components (A) to (D);
(A) One or two or more types selected from higher fatty acid salts having 12 to 18 carbon atoms (B) One or two or more types selected from fatty acid monoethanolamides and / or diethanolamides having 12 to 18 carbon atoms (C) Water (D) Detergent composition comprising 1,2-pentanediol
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JP2014070021A (en) * | 2012-09-27 | 2014-04-21 | Mandom Corp | Skin cleansing agent composition and skin cleansing agent |
JP7128504B1 (en) | 2021-11-14 | 2022-08-31 | 株式会社赤玉化学 | Method for producing cleaning composition |
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JPH11322591A (en) * | 1998-02-24 | 1999-11-24 | Mandom Corp | Antiseptic microbicide and composition for applying to human body |
JP2002128658A (en) * | 2000-10-24 | 2002-05-09 | Lion Corp | Composition for controlling decrease in water content of horny layer |
JP2002363061A (en) * | 2001-05-31 | 2002-12-18 | Kose Corp | Creamy skin cleansing agent |
JP2004307360A (en) * | 2003-04-02 | 2004-11-04 | Kose Corp | Detergent composition |
JP2005206573A (en) * | 2003-12-22 | 2005-08-04 | Nippon Fine Chem Co Ltd | Diester and oil agent and cosmetic and external preparation for skin |
JP2007161641A (en) * | 2005-12-14 | 2007-06-28 | Pola Chem Ind Inc | Liquid detergent |
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JP2014070021A (en) * | 2012-09-27 | 2014-04-21 | Mandom Corp | Skin cleansing agent composition and skin cleansing agent |
JP7128504B1 (en) | 2021-11-14 | 2022-08-31 | 株式会社赤玉化学 | Method for producing cleaning composition |
JP2023072717A (en) * | 2021-11-14 | 2023-05-25 | 株式会社赤玉化学 | Method for producing detergent composition |
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