JP6965444B2 - Skin cleanser composition - Google Patents
Skin cleanser composition Download PDFInfo
- Publication number
- JP6965444B2 JP6965444B2 JP2020521103A JP2020521103A JP6965444B2 JP 6965444 B2 JP6965444 B2 JP 6965444B2 JP 2020521103 A JP2020521103 A JP 2020521103A JP 2020521103 A JP2020521103 A JP 2020521103A JP 6965444 B2 JP6965444 B2 JP 6965444B2
- Authority
- JP
- Japan
- Prior art keywords
- mass
- acid
- silica
- skin cleansing
- product name
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims description 54
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 97
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 42
- 239000000194 fatty acid Substances 0.000 claims description 42
- 229930195729 fatty acid Natural products 0.000 claims description 42
- 239000000377 silicon dioxide Substances 0.000 claims description 32
- 150000004665 fatty acids Chemical class 0.000 claims description 31
- 150000003839 salts Chemical class 0.000 claims description 20
- 150000005846 sugar alcohols Chemical class 0.000 claims description 14
- 229920006317 cationic polymer Polymers 0.000 claims description 12
- 239000002738 chelating agent Substances 0.000 claims description 9
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 238000010521 absorption reaction Methods 0.000 claims description 5
- 239000012459 cleaning agent Substances 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 2
- 229920000289 Polyquaternium Polymers 0.000 claims 1
- 125000005907 alkyl ester group Chemical group 0.000 claims 1
- 229920006037 cross link polymer Polymers 0.000 claims 1
- 239000006260 foam Substances 0.000 description 31
- 238000005187 foaming Methods 0.000 description 29
- -1 fatty acid salts Chemical class 0.000 description 27
- 229910002012 Aerosil® Inorganic materials 0.000 description 21
- 239000002253 acid Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000003599 detergent Substances 0.000 description 13
- 238000005406 washing Methods 0.000 description 11
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 235000019198 oils Nutrition 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229920006322 acrylamide copolymer Polymers 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- WQEPLUUGTLDZJY-UHFFFAOYSA-N pentadecanoic acid Chemical compound CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 239000005639 Lauric acid Substances 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 5
- 235000010980 cellulose Nutrition 0.000 description 5
- 230000001815 facial effect Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 241000353355 Oreosoma atlanticum Species 0.000 description 4
- 235000021314 Palmitic acid Nutrition 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 4
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- 235000021360 Myristic acid Nutrition 0.000 description 3
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 235000010356 sorbitol Nutrition 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 229960002920 sorbitol Drugs 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 2
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- QJRRBVNPIKYRQJ-UHFFFAOYSA-N 10-methylundecanoic acid Chemical compound CC(C)CCCCCCCCC(O)=O QJRRBVNPIKYRQJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-araboascorbic acid Natural products OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 2
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 235000019482 Palm oil Nutrition 0.000 description 2
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 230000002542 deteriorative effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229960001484 edetic acid Drugs 0.000 description 2
- 235000010350 erythorbic acid Nutrition 0.000 description 2
- 239000004318 erythorbic acid Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 229940026239 isoascorbic acid Drugs 0.000 description 2
- ZOCYQVNGROEVLU-UHFFFAOYSA-N isopentadecanoic acid Chemical compound CC(C)CCCCCCCCCCCC(O)=O ZOCYQVNGROEVLU-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 235000010449 maltitol Nutrition 0.000 description 2
- 239000000845 maltitol Substances 0.000 description 2
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 2
- 229940035436 maltitol Drugs 0.000 description 2
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- 239000000811 xylitol Substances 0.000 description 2
- 235000010447 xylitol Nutrition 0.000 description 2
- 229960002675 xylitol Drugs 0.000 description 2
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 2
- WGVKWNUPNGFDFJ-DQCZWYHMSA-N β-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C WGVKWNUPNGFDFJ-DQCZWYHMSA-N 0.000 description 2
- GZIFEOYASATJEH-VHFRWLAGSA-N δ-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 GZIFEOYASATJEH-VHFRWLAGSA-N 0.000 description 2
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 description 1
- RUHCWQAFCGVQJX-RVWHZBQESA-N (3s,8s,9s,10r,13r,14s,17r)-3-hydroxy-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-1-one Chemical compound C1C=C2C[C@H](O)CC(=O)[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 RUHCWQAFCGVQJX-RVWHZBQESA-N 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N (R)-alpha-Tocopherol Natural products OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- 229940031723 1,2-octanediol Drugs 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- NNOKXWHHOOMPPR-UHFFFAOYSA-N 1-ethenyl-1h-imidazol-1-ium;trichloride Chemical compound [Cl-].[Cl-].[Cl-].C=C[NH+]1C=CN=C1.C=C[NH+]1C=CN=C1.C=C[NH+]1C=CN=C1 NNOKXWHHOOMPPR-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- ZONJATNKKGGVSU-UHFFFAOYSA-N 14-methylpentadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCC(O)=O ZONJATNKKGGVSU-UHFFFAOYSA-N 0.000 description 1
- YETXGSGCWODRAA-UHFFFAOYSA-N 17-methyloctadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCCC(O)=O YETXGSGCWODRAA-UHFFFAOYSA-N 0.000 description 1
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229910002014 Aerosil® 130 Inorganic materials 0.000 description 1
- 229910002015 Aerosil® 150 Inorganic materials 0.000 description 1
- 229910002018 Aerosil® 300 Inorganic materials 0.000 description 1
- 229910002019 Aerosil® 380 Inorganic materials 0.000 description 1
- 229910002020 Aerosil® OX 50 Inorganic materials 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 235000017788 Cydonia oblonga Nutrition 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- HEBKCHPVOIAQTA-QWWZWVQMSA-N D-arabinitol Chemical compound OC[C@@H](O)C(O)[C@H](O)CO HEBKCHPVOIAQTA-QWWZWVQMSA-N 0.000 description 1
- GZIFEOYASATJEH-UHFFFAOYSA-N D-delta tocopherol Natural products OC1=CC(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 GZIFEOYASATJEH-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 229920000569 Gum karaya Polymers 0.000 description 1
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- LEVWYRKDKASIDU-IMJSIDKUSA-N L-cystine Chemical compound [O-]C(=O)[C@@H]([NH3+])CSSC[C@H]([NH3+])C([O-])=O LEVWYRKDKASIDU-IMJSIDKUSA-N 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 description 1
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- LCTONWCANYUPML-UHFFFAOYSA-M Pyruvate Chemical compound CC(=O)C([O-])=O LCTONWCANYUPML-UHFFFAOYSA-M 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 241000934878 Sterculia Species 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229940087168 alpha tocopherol Drugs 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 229940066595 beta tocopherol Drugs 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920006319 cationized starch Polymers 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 235000010389 delta-tocopherol Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 1
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- FBPFZTCFMRRESA-GUCUJZIJSA-N galactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-GUCUJZIJSA-N 0.000 description 1
- 235000010382 gamma-tocopherol Nutrition 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229940100608 glycol distearate Drugs 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 229930182817 methionine Natural products 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 1
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 1
- 239000000574 octyl gallate Substances 0.000 description 1
- 235000010387 octyl gallate Nutrition 0.000 description 1
- NRPKURNSADTHLJ-UHFFFAOYSA-N octyl gallate Chemical compound CCCCCCCCOC(=O)C1=CC(O)=C(O)C(O)=C1 NRPKURNSADTHLJ-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 239000000473 propyl gallate Substances 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 229940075579 propyl gallate Drugs 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 235000007680 β-tocopherol Nutrition 0.000 description 1
- 239000011590 β-tocopherol Substances 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
- 239000002446 δ-tocopherol Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Description
本発明は、皮膚の洗浄に用いられる皮膚洗浄剤組成物、および該組成物が容器内に充填された皮膚洗浄剤に関する。 The present invention relates to a skin cleansing composition used for washing the skin, and a skin cleansing agent in which the composition is filled in a container.
脂肪酸塩を使用した洗浄剤組成物は、皮脂汚れの洗浄力や、洗浄後のさっぱり感の良さから好まれているが、泡立てたときの起泡力および泡ボリュームに改善の余地があった。そこで、脂肪酸塩を使用した洗浄剤組成物に他の界面活性剤や水溶性高分子を配合し、泡の膜強度を上げることで、起泡力および泡ボリュームを向上させる技術が提案されている(特許文献1、2)。 Detergent compositions using fatty acid salts are preferred because of their detergency for sebum stains and their refreshing feel after cleaning, but there is room for improvement in foaming power and foam volume when foamed. Therefore, a technique has been proposed in which a detergent composition using a fatty acid salt is blended with another surfactant or a water-soluble polymer to increase the foam film strength to improve foaming power and foam volume. (Patent Documents 1 and 2).
しかしながら、前述の方法により起泡力および泡ボリュームを向上させた洗浄剤組成物は、当該組成物を延ばしたときに糸曳きと呼ばれる現象や、洗浄後のすすぎ落ち性能が悪化するという問題がある。 However, the detergent composition having improved foaming power and foam volume by the above-mentioned method has problems such as a phenomenon called stringing when the composition is stretched and deterioration of rinsing performance after cleaning. ..
本発明は、泡立てたときの良好な起泡力および泡ボリュームを有し、かつ洗浄後のすすぎ落ち性能が改善された皮膚洗浄剤組成物を提供することを目的とする。 An object of the present invention is to provide a skin cleansing composition having good foaming power and foam volume when foamed and having improved rinsing performance after washing.
本発明者は、鋭意検討した結果、脂肪酸塩を使用した洗浄剤組成物に、シリカ、カチオン性ポリマーおよび糖アルコールを配合することにより、泡立てたときの起泡力および泡ボリューム、並びに洗浄後のすすぎ落ち性能に優れた皮膚洗浄剤組成物が得られることを見出し、本発明を完成させた。 As a result of diligent studies, the present inventor has added silica, a cationic polymer, and a sugar alcohol to a detergent composition using a fatty acid salt to provide foaming power and foam volume at the time of foaming, and after cleaning. The present invention has been completed by finding that a skin cleansing composition having excellent rinsing performance can be obtained.
すなわち、本発明は
〔1〕高級脂肪酸および/またはその塩を5.0〜50質量%、シリカを1.0〜10質量%、カチオン性ポリマーを0.1〜4.0質量%、および糖アルコールを0.5〜10質量%含有する皮膚洗浄剤組成物、
〔2〕高級脂肪酸および/またはその塩を5.0〜50質量%、シリカを1.0〜10質量%、カチオン性ポリマーを0.1〜2.0質量%、および糖アルコールを0.5〜10質量%含有する、〔1〕記載の皮膚洗浄剤組成物、
〔3〕シリカの吸油量が100mL/100g〜1000mL/100gである、〔1〕または〔2〕記載の皮膚洗浄剤組成物、
〔4〕キレート剤を0.01〜1.0質量%含有する、〔1〕〜〔3〕のいずれかに記載の皮膚洗浄剤組成物、
〔5〕〔1〕〜〔4〕のいずれかに記載の皮膚洗浄剤組成物と容器とを備え、前記皮膚洗浄剤組成物が前記容器内に充填されている、皮膚洗浄剤、に関する。That is, the present invention [1] contains 5.0 to 50% by mass of higher fatty acids and / or salts thereof, 1.0 to 10% by mass of silica, 0.1 to 4.0% by mass of cationic polymers, and sugars. A skin cleaning composition containing 0.5 to 10% by mass of alcohol,
[2] 5.0 to 50% by mass of higher fatty acids and / or salts thereof, 1.0 to 10% by mass of silica, 0.1 to 2.0% by mass of cationic polymers, and 0.5% by mass of sugar alcohols. The skin cleaning agent composition according to [1], which contains 10% by mass.
[3] The skin cleansing composition according to [1] or [2], wherein the oil absorption of silica is 100 mL / 100 g to 1000 mL / 100 g.
[4] The skin cleansing composition according to any one of [1] to [3], which contains 0.01 to 1.0% by mass of a chelating agent.
[5] The present invention relates to a skin cleansing agent comprising the skin cleansing agent composition according to any one of [1] to [4] and a container, and the skin cleansing agent composition is filled in the container.
本発明の皮膚洗浄剤組成物は、泡立てたときの良好な起泡力および泡ボリュームを有し、かつ洗浄後のすすぎ落ち性能に優れる。また、該皮膚洗浄剤組成物は、キメの細かい良好な泡質を有する。 The skin cleansing composition of the present invention has good foaming power and foam volume when foamed, and is excellent in rinsing performance after washing. In addition, the skin cleansing composition has good foam quality with fine texture.
本実施形態に係る皮膚洗浄剤組成物は、高級脂肪酸および/またはその塩、シリカ、カチオン性ポリマー、および糖アルコールを必須の成分として含有する。なお、本明細書において、「〜」を用いて数値範囲を示す場合、その両端の数値を含むものとする。 The skin cleansing composition according to the present embodiment contains a higher fatty acid and / or a salt thereof, silica, a cationic polymer, and a sugar alcohol as essential components. In this specification, when a numerical range is indicated by using "~", the numerical values at both ends thereof are included.
(高級脂肪酸および/またはその塩)
本実施形態に係る皮膚洗浄剤組成物に含まれる高級脂肪酸および/またはその塩は、皮膚洗浄剤組成物の性状等に応じて、適宜選択して用いることができる。(Higher fatty acids and / or salts thereof)
The higher fatty acid and / or a salt thereof contained in the skin cleansing composition according to the present embodiment can be appropriately selected and used according to the properties of the skin cleansing composition and the like.
本明細書において「高級脂肪酸」とは、直鎖状または分枝状の、飽和または不飽和の高級脂肪酸を意味する。該高級脂肪酸の炭素数は、皮膚洗浄剤組成物の粘性や洗浄力を確保する観点から、10以上が好ましく、12以上がより好ましい。また、皮膚洗浄剤組成物の水馴染みや高温安定性の低下を防止する観点からは、20以下が好ましく、18以下がより好ましい。さらに、泡立ちや泡質をより向上させる観点から、炭素数が12〜14の脂肪酸を含有することが好ましい。 As used herein, the term "higher fatty acid" means a linear or branched, saturated or unsaturated higher fatty acid. The carbon number of the higher fatty acid is preferably 10 or more, more preferably 12 or more, from the viewpoint of ensuring the viscosity and detergency of the skin cleansing composition. Further, from the viewpoint of preventing water compatibility of the skin cleansing composition and deterioration of high temperature stability, 20 or less is preferable, and 18 or less is more preferable. Further, from the viewpoint of further improving foaming and foam quality, it is preferable to contain a fatty acid having 12 to 14 carbon atoms.
高級脂肪酸の具体例としては、例えば、ラウリン酸、トリデシル酸、ミリスチン酸、ペンタデシル酸、パルミチン酸、マルガリン酸、ステアリン酸、アラキン酸、ベヘン酸、イソカプリル酸、イソペラルゴン酸、イソカプリン酸、イソウンダカン酸、イソラウリン酸、イソトリデシル酸、イソミリスチン酸、イソペンタデシル酸、イソパルミチン酸、イソマルガリン酸、イソステアリン酸、イソノナデカン酸、イソアラキン酸、イソヘンエイコサン酸、およびイソベヘン酸等が挙げられる。高級脂肪酸の他の具体例としては、例えば、オリーブ油、ヤシ油、パーム油、綿実油等の植物性油脂;魚油および牛脂等の動物性油脂が挙げられる。 Specific examples of the higher fatty acids include lauric acid, tridecylic acid, myristic acid, pentadecylic acid, palmitic acid, margaric acid, stearic acid, araquinic acid, bechenic acid, isocapric acid, isoperalgonic acid, isocapric acid, isoundacic acid, etc. Examples thereof include isolauric acid, isotridecylic acid, isomiristic acid, isopentadecylic acid, isopalmitic acid, isomarugalic acid, isostearic acid, isononadecanoic acid, isoaraquinic acid, isoheneikosanoic acid, and isobechenic acid. Other specific examples of higher fatty acids include vegetable fats and oils such as olive oil, palm oil, palm oil and cottonseed oil; and animal fats and oils such as fish oil and beef tallow.
本明細書において「高級脂肪酸塩」とは、前記の高級脂肪酸の少なくとも一部(一部または全部)をアルカリ剤でケン化または中和した化合物を意味する。高級脂肪酸塩を用いる場合には、高級脂肪酸とアルカリ剤とから高級脂肪酸塩を得た後に、他の成分と配合してもよく、高級脂肪酸とアルカリ剤とを配合することで、組成物中で高級脂肪酸塩としてもよい。なお、このような高級脂肪酸塩は、高級脂肪酸石鹸とも呼ばれる。 As used herein, the term "higher fatty acid salt" means a compound in which at least a part (part or all) of the higher fatty acid is saponified or neutralized with an alkaline agent. When a higher fatty acid salt is used, it may be blended with other components after obtaining the higher fatty acid salt from the higher fatty acid and the alkaline agent, or by blending the higher fatty acid and the alkaline agent in the composition. It may be a higher fatty acid salt. In addition, such a higher fatty acid salt is also called a higher fatty acid soap.
アルカリ剤は、中和剤として用いることができる。アルカリとしては、例えば、水酸化ナトリウム、水酸化カリウム、炭酸ナトリウム、炭酸カリウム等の無機アルカリ;モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、トリメチルアミン、トリエチルアミン、イソプロパノールアミン、モルホリン、アルギニン等の有機アルカリが挙げられる。入手が容易であり、かつ取り扱い性に優れる観点からは、水酸化ナトリウム、水酸化カリウム、およびトリエタノールアミンが好ましい。 The alkaline agent can be used as a neutralizing agent. Examples of the alkali include inorganic alkalis such as sodium hydroxide, potassium hydroxide, sodium carbonate and potassium carbonate; and organic alkalis such as monoethanolamine, diethanolamine, triethanolamine, trimethylamine, triethylamine, isopropanolamine, morpholine and arginine. Be done. Sodium hydroxide, potassium hydroxide, and triethanolamine are preferable from the viewpoint of easy availability and excellent handleability.
高級脂肪酸および/またはその塩は、泡立ちをより一層良好にする観点から、直鎖状の高級脂肪酸および/またはその塩を含むことが好ましい。一方、起泡性および組成物の安定性をより一層高める観点からは、分岐状の高級脂肪酸および/またはその塩を含んでいてもよい。 The higher fatty acid and / or a salt thereof preferably contains a linear higher fatty acid and / or a salt thereof from the viewpoint of further improving foaming. On the other hand, from the viewpoint of further enhancing the foaming property and the stability of the composition, a branched higher fatty acid and / or a salt thereof may be contained.
高級脂肪酸および/またはその塩は、洗浄力をより一層高め、組成物の安定性もより一層高め、組成物中でのシリカの分散状態をもより一層良好に維持する観点からは、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリンおよびそれらの塩からなる群から選ばれる1種以上を含むことが好ましく、ラウリン酸、ミリスチン酸、およびそれらの塩からなる群から選ばれる1種以上を含むことがより好ましい。 The higher fatty acid and / or its salt further enhances the detergency, further enhances the stability of the composition, and from the viewpoint of maintaining the dispersed state of silica in the composition even better, lauric acid, It preferably contains one or more selected from the group consisting of myristic acid, palmitic acid, stearin and salts thereof, and more preferably contains one or more selected from the group consisting of lauric acid, myristic acid and salts thereof. preferable.
前記で列挙された高級脂肪酸および/またはその塩は、1種単独で用いてもよく、2種以上を併用してもよい。高級脂肪酸および/またはその塩としては、高級脂肪酸のみを含んでいてもよく、高級脂肪酸塩のみを含んでいてもよく、高級脂肪酸と高級脂肪酸塩の双方を含んでいてもよい。 The higher fatty acids and / or salts thereof listed above may be used alone or in combination of two or more. The higher fatty acid and / or a salt thereof may contain only the higher fatty acid, may contain only the higher fatty acid salt, or may contain both the higher fatty acid and the higher fatty acid salt.
皮膚洗浄剤組成物100質量%中の高級脂肪酸および/またはその塩の含有量(高級脂肪酸と高級脂肪酸塩との合計の含有量)は、洗浄力、泡立ち、泡質、および粘度を確保する観点から、5.0質量%以上が好ましく、8.0質量%以上がより好ましく、10質量%以上がさらに好ましい。また、肌荒れや水馴染みの低下を防止する観点からは、50質量%以下が好ましく、45質量%以下がより好ましく、40質量%以下がさらに好ましい。 The content of the higher fatty acid and / or its salt (the total content of the higher fatty acid and the higher fatty acid salt) in 100% by mass of the skin cleansing composition is a viewpoint for ensuring detergency, foaming, foam quality, and viscosity. Therefore, 5.0% by mass or more is preferable, 8.0% by mass or more is more preferable, and 10% by mass or more is further preferable. Further, from the viewpoint of preventing rough skin and deterioration of water compatibility, 50% by mass or less is preferable, 45% by mass or less is more preferable, and 40% by mass or less is further preferable.
(シリカ)
本実施形態においては、公知慣用のシリカ(無水ケイ酸)を用いることができる。シリカは、疎水化処理されていない無水ケイ酸(親水性のシリカ)であってもよく、疎水化無水ケイ酸であってもよい。また、アミノ酸、エステルまたはレシチン等で表面処理されたシリカであってもよい。また、シリカは、所謂、易崩壊性シリカ粒子であってもよい。(silica)
In this embodiment, known and commonly used silica (silicic anhydride) can be used. The silica may be silicic acid anhydride (hydrophilic silica) which has not been hydrophobized, or may be hydrophobized silicic acid anhydride. Further, it may be silica surface-treated with an amino acid, an ester, lecithin or the like. Further, the silica may be so-called easily disintegrating silica particles.
シリカの平均粒径は、泡立ちの観点から、0.1μm以上が好ましく、0.5μm以上がより好ましく、1.0μm以上がさらに好ましい。また、使用時のシリカによるざらつき感を抑制できるという観点からは、50μm以下が好ましく、30μm以下がより好ましく、10μm以下がさらに好ましい。 From the viewpoint of foaming, the average particle size of silica is preferably 0.1 μm or more, more preferably 0.5 μm or more, still more preferably 1.0 μm or more. Further, from the viewpoint of suppressing the feeling of roughness due to silica during use, 50 μm or less is preferable, 30 μm or less is more preferable, and 10 μm or less is further preferable.
なお、本明細書におけるシリカの平均粒径(平均1次粒径)は、体積平均粒径である。上記平均粒径は、レーザー光回折による粒度分布測定装置を用いて測定可能である。粒度分布測定装置としては、(株)堀場製作所製「LA−920」等が挙げられる。 The average particle size (average primary particle size) of silica in the present specification is the volume average particle size. The average particle size can be measured using a particle size distribution measuring device by laser light diffraction. Examples of the particle size distribution measuring device include "LA-920" manufactured by HORIBA, Ltd.
シリカの形状は特に限定されないが、泡立ちがより一層向上するという観点、洗浄後の肌にさらさら感を付与できるという観点から、球状であることが好ましい。 The shape of silica is not particularly limited, but it is preferably spherical from the viewpoint of further improving foaming and giving a silky feeling to the skin after washing.
シリカは多孔質であることが好ましい。シリカが多孔質であることによって、泡立ちがより一層向上し、さらに、洗浄後の肌にさらさら感を付与することができる。また、複数の孔内に、皮膚上の外的な汚れ、皮膚内部から生じる皮脂、汗、および老廃角質を効果的に吸着させることができる。 Silica is preferably porous. Since the silica is porous, foaming is further improved, and the skin after washing can be given a silky feeling. In addition, external dirt on the skin, sebum, sweat, and waste keratin generated from the inside of the skin can be effectively adsorbed in the plurality of holes.
シリカの吸油量は、泡立ちの観点から、100mL/100g以上が好ましく、120mL/100g以上がより好ましく、140mL/100g以上がさらに好ましい。上限は特に限定されないが、1000mL/100gが好ましく、800mL/100g以下がより好ましく、700mL/100g以下がさらに好ましく、500mL/100g以下が特に好ましい。なお、本明細書におけるシリカの吸油量は、JIS K 5101に記載の方法に準拠して測定される。 From the viewpoint of foaming, the amount of oil absorbed by silica is preferably 100 mL / 100 g or more, more preferably 120 mL / 100 g or more, and even more preferably 140 mL / 100 g or more. The upper limit is not particularly limited, but 1000 mL / 100 g is preferable, 800 mL / 100 g or less is more preferable, 700 mL / 100 g or less is further preferable, and 500 mL / 100 g or less is particularly preferable. The amount of silica oil absorbed in the present specification is measured according to the method described in JIS K 5101.
シリカの市販品としては、例えば、無水ケイ酸である富士シリシア化学(株)製、商品名「サイリシア 320」、商品名「サイリシア 310P」、商品名「サイリシア 250」、商品名「サイリシア 250N」、商品名「サイリシア 350」、商品名「サイリシア 370」、商品名「サイリシア 380」、商品名「サイリシア 420」、商品名「サイリシア 430」、商品名「サイリシア 440」、商品名「サイリシア 450」および商品名「サイリシア 470」;無水ケイ酸である日本アエロジル(株)製、商品名「AEROSIL 50」、商品名「AEROSIL 90G」、商品名「AEROSIL 130」、商品名「AEROSIL 150」、商品名「AEROSIL 200」、商品名「AEROSIL 300」、商品名「AEROSIL 380」、商品名「AEROSIL 200V」および商品名「AEROSIL OX50」;無水ケイ酸であるAGCエスアイテック(株)製、商品名「サンスフェアH−31」、商品名「サンスフェアH−51」、商品名「サンスフェアH−121」、商品名「サンスフェアH−201」、商品名「サンスフェアH−32」、商品名「サンスフェアH−52」、商品名「サンスフェアH−122」、商品名「サンスフェアH−33」および商品名「サンスフェアH−53」等;ジメチルシロキシル化無水ケイ酸である日本アエロジル(株)製、商品名「AEROSIL R972」、商品名「AEROSIL R974」および商品名「AEROSIL R9200」;トリメチルシロキシル化無水ケイ酸である日本アエロジル(株)製、商品名「AEROSIL RX200」、商品名「AEROSIL R8200」、商品名「AEROSIL RX300」および商品名「AEROSIL R812S」;オクチルシロキシル化無水ケイ酸である日本アエロジル(株)製、商品名「AEROSIL R805」;シリコーンオイル処理無水ケイ酸である日本アエロジル(株)製、商品名「AEROSIL R202」、商品名「AEROSIL RY200」、商品名「AEROSIL RY200S」および商品名「AEROSIL RY300」;シリコーンコーティング処理無水ケイ酸であるAGCエスアイテック(株)製、商品名「サンスフェア H−52−ET」;メタクリルシロキシル化無水ケイ酸である日本アエロジル(株)製、商品名「AEROSIL R711」;上記昜崩壊性シリカである三好化成(株)製、商品名「シリカビーズSB−705」、鈴木油脂工業(株)製、商品名「ゴッドボールSF−16C」、商品名「ゴッドボールAF−6C」および商品名「ゴッドボールAF−16C」等が挙げられる。 Examples of commercially available silica products include silicic anhydride manufactured by Fuji Silicia Chemical Co., Ltd., product name "Syricia 320", product name "Syricia 310P", product name "Syricia 250", and product name "Sylicia 250N". Product Name "Syricia 350", Product Name "Syricia 370", Product Name "Syricia 380", Product Name "Syricia 420", Product Name "Syricia 430", Product Name "Syricia 440", Product Name "Syricia 450" Name "Syricia 470"; manufactured by Nippon Aerosil Co., Ltd., which is silicic anhydride, product name "AEROSIL 50", product name "AEROSIL 90G", product name "AEROSIL 130", product name "AEROSIL 150", product name "AEROSIL" "200", product name "AEROSIL 300", product name "AEROSIL 380", product name "AEROSIL 200V" and product name "AEROSIL OX50"; manufactured by AGC SI Tech Co., Ltd., which is silicic anhydride, product name "Sunsphere H" -31 ", product name" Sunsphere H-51 ", product name" Sunsphere H-121 ", product name" Sunsphere H-201 ", product name" Sunsphere H-32 ", product name" Sunsphere H " -52 ”, product name“ Sunsphere H-122 ”, product name“ Sunsphere H-33 ”, product name“ Sunsphere H-53 ”, etc .; manufactured by Nippon Aerosil Co., Ltd., which is dimethylsiloxylated silicic anhydride. , Product name "AEROSIL R972", product name "AEROSIL R974" and product name "AEROSIL R9200"; trimethylsiloxylated silicic anhydride manufactured by Nippon Aerosil Co., Ltd., product name "AEROSIL RX200", product name "AEROSIL R8200" , Product name "AEROSIL RX300" and product name "AEROSIL R812S"; manufactured by Nippon Aerosil Co., Ltd., which is octylsiloxylated anhydrous silicic acid, product name "AEROSIL R805"; Japan Aerosil (silicone oil-treated anhydrous silicic acid) Product name "AEROSIL R202", product name "AEROSIL RY200", product name "AEROSIL RY200S" and product name "AEROSIL RY300"; manufactured by AGC SI Tech Co., Ltd., which is a silicone-coated silicic anhydride, product name "Sansfe A H-52-ET ”; methacrylicylated silicic acid made by Nippon Aerosil Co., Ltd., trade name“ AEROSIL R711 ”; the above-mentioned disintegrating silica, manufactured by Miyoshi Kasei Co., Ltd., trade name“ silica beads SB-705 ”, manufactured by Suzuki Yushi Kogyo Co., Ltd., trade name“ Godball SF-16C ”, trade name“ Godball AF-6C ”, trade name“ Godball AF-16C ”and the like.
前記で列挙されたシリカは、1種単独で用いてもよく、2種以上を併用してもよい。 The silicas listed above may be used alone or in combination of two or more.
皮膚洗浄剤組成物100質量%中のシリカの含有量は、泡立ちの観点から、1.0質量%以上が好ましく、1.5質量%以上がより好ましく、2.0質量%以上がさらに好ましい。また、皮膚洗浄剤が固くなり使用感が低下することを防止する観点からは、10質量%以下が好ましく、9.0質量%以下がより好ましく、8.0質量%以下がさらに好ましい。 The content of silica in 100% by mass of the skin cleansing composition is preferably 1.0% by mass or more, more preferably 1.5% by mass or more, still more preferably 2.0% by mass or more, from the viewpoint of foaming. Further, from the viewpoint of preventing the skin cleansing agent from becoming hard and deteriorating the feeling of use, 10% by mass or less is preferable, 9.0% by mass or less is more preferable, and 8.0% by mass or less is further preferable.
(カチオン性ポリマー)
本実施形態において使用可能なカチオン性ポリマーとしては、特に制限はなく、目的に応じて適宜選択することができ、例えば、カチオン化セルロース、カチオン化セルロース誘導体、カチオン化澱粉、カチオン化グアーガム、カチオン化グアーガム誘導体、ジアリル四級アンモニウム塩のホモポリマー、四級化ポリビニルピロリドン誘導体、ポリグリコールポリアミン縮合物、ジアルキルジアリルアンモニウム塩/アクリルアミド共重合体、ビニルイミダゾリウムトリクロライド/ビニルピロリドン共重合体、ヒドロキシエチルセルロース/ジメチルジアリルアンモニウムクロライド共重合体、ビニルピロリドン/四級化ジメチルアミノエチルメタクリレート共重合体、ポリビニルピロリドン/アルキルアミノアクリレート共重合体、ポリビニルピロリドン/アルキルアミノアクリレート/ビニルカプロラクタム共重合体、ビニルピロリドン/メタクリルアミドプロピル塩化トリメチルアンモニウム共重合体、アルキルアクリルアミド/アクリレート/アルキルアミノアルキルアクリルアミド/ポリエチレングリコールメタクリレート共重合体等が挙げられる。これらは、1種単独で使用してもよいし、2種以上を併用してもよい。なかでも、前記無水ケイ酸が均一に再分散され、その凝集を抑制することができ、目詰りの点で、ジメチルジアリルアンモニウムクロライドの重合体、ジメチルジアリルアンモニウムクロライド/アクリルアミド共重合体、アクリル酸/塩化ジメチルジアリルアンモニウム共重合体、アクリル酸/塩化ジメチルジアリルアンモニウム/アクリルアミド共重合体が好ましい。(Cationic polymer)
The cationic polymer that can be used in the present embodiment is not particularly limited and may be appropriately selected depending on the intended purpose. For example, cationized cellulose, cationized cellulose derivative, cationized starch, cationized guar gum, cationization. Guar gum derivative, homopolymer of diallyl quaternary ammonium salt, quaternized polyvinylpyrrolidone derivative, polyglycolpolyamine condensate, dialkyldialylammonium salt / acrylamide copolymer, vinyl imidazolium trichloride / vinylpyrrolidone copolymer, hydroxyethyl cellulose / Dimethyldialylammonium chloride copolymer, vinylpyrrolidone / quaternized dimethylaminoethylmethacrylate copolymer, polyvinylpyrrolidone / alkylaminoacrylate copolymer, polyvinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer, vinylpyrrolidone / methacrylicamide Examples thereof include propyl trimethyl ammonium chloride copolymer, alkyl acrylamide / acrylate / alkyl amino alkyl acrylamide / polyethylene glycol methacrylate copolymer and the like. These may be used alone or in combination of two or more. Among them, the silicic anhydride is uniformly redispersed, its aggregation can be suppressed, and in terms of clogging, a polymer of dimethyldiallylammonium chloride, a dimethyldialylammonium chloride / acrylamide copolymer, acrylic acid / Preferably, dimethyldiallylammonium chloride copolymer and acrylic acid / dimethyldiallylammonium chloride / acrylamide copolymer.
カチオン性ポリマーとしては、適宜合成したものを使用してもよいし、市販品を使用してもよい。市販品としては、例えば、Merquat 10(表示名称「ポリクオタニウム−10」、Lubrizol社製)等のカチオン化セルロース;Merquat 100、Merquat 106(いずれも、表示名称「ポリクオタニウム−6」、Lubrizol社製)等のジメチルジアリルアンモニウムクロライドの重合体;Merquat 550PR、Merquat S、Merquat 2200、Merquat 740(いずれも、表示名称「ポリクオタニウム−7」、Lubrizol社製)等のジメチルジアリルアンモニウムクロライド/アクリルアミド共重合体;Merquat 280、Merquat 281、Merquat 295(いずれも、表示名称「ポリクオタニウム−22」、Lubrizol社製)等のアクリル酸/塩化ジメチルジアリルアンモニウム共重合体;Merquat PLUS 3330(表示名称「ポリクオタニウム−39」、Lubrizol社製)等のアクリル酸/塩化ジメチルジアリルアンモニウム/アクリルアミド共重合体等が挙げられる。なかでも、「ポリクオタニウム−6」(ジメチルジアリルアンモニウムクロライドの重合体」、「ポリクオタニウム−7」(ジメチルジアリルアンモニウムクロライド/アクリルアミド共重合体)、および「ポリクオタニウム−22」(アクリル酸/塩化ジメチルジアリルアンモニウム共重合体)からなる群から選ばれる1種以上が好ましい。 As the cationic polymer, a polymer synthesized as appropriate may be used, or a commercially available product may be used. Examples of commercially available products include cationized celluloses such as Polymer 10 (labeled name "Polyquaternium-10", manufactured by Lubrizol); Polymer 100, Polymer 106 (labeled name "Polyquaternium-6", manufactured by Lubrizol) and the like. Polymers of dimethyldiallyl ammonium chlorides; , Merquat 281, Merquat 295 (all labeled name "Polyquaternium-22", manufactured by Lubrizol) and other acrylic acid / dimethyldiallyl ammonium chloride copolymers; Merquat PLUS 3330 (labeled name "Polyquaternium-39", manufactured by Lubrizol). ) And the like, acrylic acid / dimethyldiallyl ammonium chloride / acrylamide copolymer and the like. Among them, "Polyquaternium-6" (polymer of dimethyldialylammonium chloride), "Polyquaternium-7" (dimethyldialylammonium chloride / acrylamide copolymer), and "Polyquaternium-22" (acrylic acid / dimethyldialylammonium chloride) One or more selected from the group consisting of polymer) is preferable.
前記で列挙されたカチオン性ポリマーは、1種単独で用いてもよく、2種以上を併用してもよい。 The cationic polymers listed above may be used alone or in combination of two or more.
皮膚洗浄剤組成物100質量%中のカチオン性ポリマーの含有量は、泡立ちの観点から、0.1質量%以上が好ましく、0.2質量%以上がより好ましく、0.3質量%以上がさらに好ましい。また、該含有量は、4.0質量%以下が好ましく、2.0質量%以下がより好ましく、1.8質量%以下がさらに好ましく、1.6質量%以下が特に好ましい。該含有量が2.0質量%を超えると、皮膚洗浄剤に曳糸性が生じ、吐出時の切れが悪くなり、使用感が低下するおそれがある。また、洗浄後のすすぎ落ち性能が低下する傾向がある。 The content of the cationic polymer in 100% by mass of the skin cleansing composition is preferably 0.1% by mass or more, more preferably 0.2% by mass or more, and further preferably 0.3% by mass or more from the viewpoint of foaming. preferable. The content is preferably 4.0% by mass or less, more preferably 2.0% by mass or less, further preferably 1.8% by mass or less, and particularly preferably 1.6% by mass or less. If the content exceeds 2.0% by mass, the skin cleanser may be spinnable, the cut may be poor at the time of discharge, and the usability may be deteriorated. In addition, the rinsing performance after cleaning tends to deteriorate.
(糖アルコール)
本実施形態において使用可能な糖アルコールとしては、例えば、マルチトール、ソルビトール、リビトール、マンニトール、アラビトール、ガラクチトール、キシリトール、エリトリトール、およびイノシトール等が挙げられ、マルチトール、ソルビトール、キシリトールからなる群から選ばれる1種以上が好ましい。これらの糖アルコールは、1種単独で用いてもよく、2種以上を併用してもよい。(Sugar alcohol)
Examples of the sugar alcohol that can be used in the present embodiment include maltitol, sorbitol, libitol, mannitol, arabitol, galactitol, xylitol, erythritol, inositol and the like, and are selected from the group consisting of maltitol, sorbitol and xylitol. One or more of them are preferable. These sugar alcohols may be used alone or in combination of two or more.
皮膚洗浄剤組成物100質量%中の糖アルコールの含有量は、泡立ちの観点から、0.5質量%以上が好ましく、1.0質量%以上がより好ましく、1.5質量%以上がさらに好ましい。また、皮膚洗浄剤が固くなり使用感が低下することを防止する観点からは、10質量%以下が好ましく、9.0質量%以下がより好ましく、8.0質量%以下がさらに好ましい。 The content of sugar alcohol in 100% by mass of the skin cleansing composition is preferably 0.5% by mass or more, more preferably 1.0% by mass or more, still more preferably 1.5% by mass or more, from the viewpoint of foaming. .. Further, from the viewpoint of preventing the skin cleansing agent from becoming hard and deteriorating the feeling of use, 10% by mass or less is preferable, 9.0% by mass or less is more preferable, and 8.0% by mass or less is further preferable.
(その他の成分)
本実施形態に係る皮膚洗浄剤組成物は、上述した成分に加えて、キレート剤、多価アルコール、界面活性剤、酸化防止剤、増粘剤、清涼剤、シリコーン類、ビタミン類、動植物エキス、抗炎症剤、粉体類、パール化剤、着色剤、各種香料、防腐剤、殺菌剤、pH調整剤、および溶剤等を配合してもよい。(Other ingredients)
In addition to the above-mentioned components, the skin cleansing composition according to the present embodiment includes chelating agents, polyhydric alcohols, surfactants, antioxidants, thickeners, refreshing agents, silicones, vitamins, animal and plant extracts, and the like. Anti-inflammatory agents, powders, pearling agents, colorants, various fragrances, preservatives, bactericides, pH adjusters, solvents and the like may be blended.
キレート剤は、泡立ちや泡質をより一層向上させることを目的として配合することができる。キレート剤としては、例えば、エデト酸、ニトリロ三酢酸、ヒドロキシエチルエチレンジアミン三酢酸、ジエチレントリアミン五酢酸、トリエチレンテトラミン六酢酸、シクロヘキサンジアミン五酢酸、グリシン、セリン、アラニン、リジン、シスチン、チロシン、メチオニン、アスコルビン酸、クエン酸、リンゴ酸、酒石酸、乳酸、シュウ酸、マロン酸、マレイン酸、エリソルビン酸、コハク酸、フマル酸、ピルビン酸、サリチル酸、ポリアクリル酸、ポリマレイン酸、ピロリン酸塩、トリポリリン酸、ポリリン酸、およびオルトリン酸、並びにこれらの塩等が挙げられ、エデト酸およびその塩が好適に用いられる。 The chelating agent can be blended for the purpose of further improving foaming and foam quality. Examples of the chelating agent include edetic acid, nitrilotriacetic acid, hydroxyethylethylenediamine triacetic acid, diethylenetriaminepentacetic acid, triethylenetetraminehexacetic acid, cyclohexanediaminepentacetic acid, glycine, serine, alanine, lysine, cystine, tyrosine, methionine and ascorbin. Acids, citric acid, malic acid, tartaric acid, lactic acid, oxalic acid, malonic acid, maleic acid, erythorbic acid, succinic acid, fumaric acid, pyruvate, salicylic acid, polyacrylic acid, polymaleic acid, pyrophosphate, tripolyphosphate, polyphosphorus Examples thereof include acids, ortholic acids, and salts thereof, and edetic acid and salts thereof are preferably used.
キレート剤を配合する場合の皮膚洗浄剤組成物100質量%中のキレート剤の含有量は、キレート剤を配合することによる効果が充分に得られるという観点から、0.01質量%以上が好ましく、0.03質量%以上がより好ましく、0.05質量%以上がさらに好ましい。上限は特に限定されないが、1.0質量%以下が好ましく、0.3質量%以下がより好ましく、0.2質量%以下がさらに好ましく、0.1質量%以下が特に好ましい。 The content of the chelating agent in 100% by mass of the skin cleansing composition when the chelating agent is blended is preferably 0.01% by mass or more from the viewpoint that the effect of blending the chelating agent can be sufficiently obtained. 0.03% by mass or more is more preferable, and 0.05% by mass or more is further preferable. The upper limit is not particularly limited, but 1.0% by mass or less is preferable, 0.3% by mass or less is more preferable, 0.2% by mass or less is further preferable, and 0.1% by mass or less is particularly preferable.
多価アルコールとしては、化粧品原料として用いられている公知の保湿剤を使用することができる。多価アルコールの具体例としては、例えば、グリセリン、濃グリセリン、ジグリセリン、ポリグリセリン、エチレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、1,3−ブチレングリコール、1,2−ペンタンジオール、1,2−ヘキサンジオール、および1,2−オクタンジオール等が挙げられる。多価アルコールを使用することにより、洗浄後の保湿性がより一層高くなる。前記の多価アルコールは、1種単独で用いてもよく、2種以上を併用してもよい。 As the polyhydric alcohol, a known moisturizer used as a raw material for cosmetics can be used. Specific examples of the polyhydric alcohol include glycerin, concentrated glycerin, diglycerin, polyglycerin, ethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, 1,2-pentanediol, and 1, , 2-Hexanediol, 1,2-octanediol and the like. By using a polyhydric alcohol, the moisturizing property after washing is further enhanced. The above-mentioned polyhydric alcohol may be used alone or in combination of two or more.
界面活性剤としては、例えば、ラウリン酸アシルメチルタウリン塩、ポリオキシエチレン酢酸エーテル塩、アルキルアシルグルタミン酸塩、アルキルアシルグリシン塩、アルキルリン酸塩、ポリオキシエチレンアルキルリン酸塩酸等のアニオン界面活性剤;塩化ジステアリルジメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化ステアリルジメチルベンジルアンモニウム等のカチオン界面活性剤;アルキルアミドプロピルベタイン、アルキルアミノ酢酸ベタイン、アルキルイミダゾリウムベタイン、アルキルヒドロキシエチルベタイン等の両性界面活性剤;モノステアリン酸ポリエチレングリコール、ジステアリン酸ポリエチレングリコール、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンソルビタンエステル、モノステアリン酸グリセリン、ポリオキシエチレンコレステロールエーテル、ポリオキシエチレンフィトステロールエーテル等の非イオン界面活性剤等が挙げられる。 Examples of the surfactant include anionic surfactants such as acylmethyl taurine laurate, polyoxyethylene acetate ether salt, alkylacyl glutamate, alkylacylglycine salt, alkyl phosphate, and polyoxyethylene alkyl phosphate. Cationic surfactants such as distearyldimethylammonium chloride, stearyltrimethylammonium chloride, stearyldimethylbenzylammonium chloride; amphoteric surfactants such as alkylamide propyl betaine, alkylaminoacetic acid betaine, alkylimidazolium betaine, alkylhydroxyethyl betaine; Nonionic surfactants such as polyethylene glycol monostearate, polyethylene glycol distearate, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitan ester, glycerin monostearate, polyoxyethylene cholesterol ether, and polyoxyethylene phytosterol ether. Be done.
酸化防止剤としては、例えば、ジブチルヒドロキシトルエン、ブチルヒドロキシアニソール、没食子酸プロピル、没食子酸オクチル、α−トコフェロール、β−トコフェロール、γ−トコフェロール、δ−トコフェロール、天然ビタミンE、エリソルビン酸、オルトトリルビグアナイド、チオジプロピオン酸ジラウリル、パラヒドロキシアニソール、およびフィチン酸等が挙げられる。 Examples of antioxidants include dibutylhydroxytoluene, butylhydroxyanisole, propyl gallate, octyl gallate, α-tocopherol, β-tocopherol, γ-tocopherol, δ-tocopherol, natural vitamin E, erythorbic acid, orthotolylbiguanide. , Dilauryl thiodipropionate, parahydroxyanisole, phytic acid and the like.
増粘剤としては、例えば、アラビアガム、トラガントガム、グアガム、ローカストビーンガム、カラヤガム、アイリスモス、クインスシード、ゼラチン、セラック、ロジン、およびカゼイン等の天然高分子化合物;カルボキシメチルセルロース、ヒドロキシエチルセルロース、メチルセルロース、エチルセルロース、アルギン酸ナトリウム、エステルガム、ニトロセルロース、ヒドロキシプロピルセルロース、結晶セルロース等の半合成高分子化合物;ポリビニルアルコール、ポリビニルピロリドン、ポリアクリル酸ナトリウム、カルボキシビニルポリマー、ポリビニルメチルセルロース、ポリアミド樹脂等の合成高分子化合物等が挙げられる。 Thickeners include, for example, natural polymeric compounds such as Arabic gum, tragant gum, guagam, locust bean gum, karaya gum, iris moss, quince seed, gelatin, cellac, rosin, and casein; carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose, etc. Semi-synthetic polymer compounds such as ethyl cellulose, sodium alginate, ester gum, nitrocellulose, hydroxypropyl cellulose, crystalline cellulose; synthetic polymers such as polyvinyl alcohol, polyvinylpyrrolidone, sodium polyacrylate, carboxyvinyl polymer, polyvinylmethyl cellulose, polyamide resin, etc. Examples include compounds.
清涼剤としては、例えば、l−メントール、カンファ、およびl−メンチルグリセリルエーテル等が挙げられる。 Examples of the refreshing agent include l-menthol, camphor, l-menthylglyceryl ether and the like.
溶剤としては、例えば、水や、エタノール等のアルコール類が挙げられる。 Examples of the solvent include water and alcohols such as ethanol.
本実施形態において使用する水としては、例えば、イオン交換水、限外濾過水、逆浸透水、蒸留水等の純水、超純水等が挙げられる。 Examples of the water used in the present embodiment include ion-exchanged water, ultra-filtered water, reverse osmosis water, pure water such as distilled water, and ultrapure water.
本実施形態に係る水の含有量は、特に制限されず、高級脂肪酸および/またはその塩、シリカ、カチオン性ポリマー、糖アルコールおよびその他の成分を除いた残部を、その含有量とすることができる。皮膚洗浄剤組成物100質量%中の水の含有量は、特に限定されないが、30.0〜90.0質量%が好ましく、35.0〜85.0質量%がより好ましく、40.0〜80.0質量%がさらに好ましく、45.0〜75.0質量%が特に好ましい。 The content of water according to the present embodiment is not particularly limited, and the content can be the balance excluding higher fatty acids and / or salts thereof, silica, cationic polymers, sugar alcohols and other components. .. The content of water in 100% by mass of the skin cleansing composition is not particularly limited, but is preferably 30.0 to 90.0% by mass, more preferably 35.0 to 85.0% by mass, and 40.0 to 40.0 to 40.0% by mass. 80.0% by mass is more preferable, and 45.0 to 75.0% by mass is particularly preferable.
(皮膚洗浄剤組成物の他の詳細)
本実施形態に係る皮膚洗浄剤組成物の性状としては、例えば、液状、ペースト状、ジェル状、クリーム状、および泡状等が挙げられる。なかでも、経時的な保管安定性に優れるという観点から、ペースト状またはクリーム状であることが好ましい。(Other details of skin cleanser composition)
Examples of the properties of the skin cleansing composition according to the present embodiment include liquid, paste, gel, cream, and foam. Of these, a paste or cream is preferable from the viewpoint of excellent storage stability over time.
本実施形態に係る皮膚洗浄剤組成物の用途としては、例えば、固形石鹸、ボディーシャンプー、ハンドソープ、および洗顔料等が挙げられるが、泡立てたときの良好な起泡力および泡ボリュームを有し、かつ洗浄後のすすぎ落ち性能に優れ、さらにはキメの細かい良好な泡質を有することから、洗顔料として使用することが好ましい。洗顔料としては、例えば、洗顔液、洗顔フォーム、および洗顔クリーム等が挙げられる。 Uses of the skin cleansing composition according to the present embodiment include, for example, bar soap, body shampoo, hand soap, facial cleanser, etc., and have good foaming power and foam volume when foamed. Moreover, it is preferable to use it as a washing pigment because it has excellent rinsing performance after washing and has good foam quality with fine texture. Examples of facial cleansers include facial cleansers, facial cleansers, and facial cleansers.
(皮膚洗浄剤)
本実施形態に係る皮膚洗浄剤は、容器と、該容器内に充填されている前記の皮膚洗浄剤組成物とを備える。(Skin cleanser)
The skin cleansing agent according to the present embodiment includes a container and the skin cleansing agent composition filled in the container.
容器としては、例えば、ポンプ容器、エアゾール容器、およびチューブ容器等が挙げられ、チューブ容器が好ましい。 Examples of the container include a pump container, an aerosol container, a tube container, and the like, and a tube container is preferable.
以下、本発明を実施例に基づいてさらに詳細に説明するが、本発明はこれら実施例にのみ限定されるものではない。なお、配合量は、特記しない限り、有効成分の配合量であり、「質量%」で表す。 Hereinafter, the present invention will be described in more detail based on Examples, but the present invention is not limited to these Examples. Unless otherwise specified, the blending amount is the blending amount of the active ingredient and is represented by "mass%".
以下、実施例および比較例において用いた各種材料をまとめて示す。
脂肪酸1:オレオソリューションズ社製のEdenor C12−99 MY(ラウリン酸)
脂肪酸2:オレオソリューションズ社製のEdenor C14−99 MY(ミリスチン酸)
脂肪酸3:オレオソリューションズ社製のEdenor C16−98 MY(パルミチン酸)
脂肪酸4:オレオソリューションズ社製のEdenor C18−98 MY(ステアリン酸)
シリカ1:AGCエスアイテック(株)製のサンスフェアH−51(平均粒径:5.0μm、吸油量:150mL/100g)
シリカ2:AGCエスアイテック(株)製のサンスフェアH−52(平均粒径:5.0μm、吸油量:300mL/100g)
シリカ3:AGCエスアイテック(株)製のサンスフェアH−201(平均粒径:12.0μm、吸油量:150mL/100g)
カチオン性ポリマー:Lubrizol社製のMerquat 550PR(表示名称「ポリクオタニウム−7」、ジメチルジアリルアンモニウムクロライド/アクリルアミド共重合体)
キレート剤:アクゾノーベル(株)製のディゾルビンNA−X(エデト酸四ナトリウム四水塩)Hereinafter, various materials used in Examples and Comparative Examples are collectively shown.
Fatty acid 1: Edenor C12-99 MY (lauric acid) manufactured by Oreo Solutions Co., Ltd.
Fatty acid 2: Edenor C14-99 MY (myristic acid) manufactured by Oreo Solutions Co., Ltd.
Fatty acid 3: Edenor C16-98 MY (palmitic acid) manufactured by Oreo Solutions Co., Ltd.
Fatty acid 4: Edenor C18-98 MY (stearic acid) manufactured by Oreo Solutions Co., Ltd.
Silica 1: Sunsphere H-51 manufactured by AGC Si-Tech Co., Ltd. (average particle size: 5.0 μm, oil absorption: 150 mL / 100 g)
Silica 2: Sunsphere H-52 manufactured by AGC Si-Tech Co., Ltd. (average particle size: 5.0 μm, oil absorption: 300 mL / 100 g)
Silica 3: Sunsphere H-201 manufactured by AGC SI-Tech Co., Ltd. (average particle size: 12.0 μm, oil absorption: 150 mL / 100 g)
Cationic polymer: Merquat 550PR manufactured by Lubrizol (labeled name "Polyquaternium-7", dimethyldialylammonium chloride / acrylamide copolymer)
Chelating agent: Dissolvin NA-X (tetrasodium edetate tetrahydrate) manufactured by AkzoNobel Co., Ltd.
(実施例1〜5および比較例1〜4)
表1に示した組成(配合量)に従い、各成分を混合し、皮膚洗浄剤組成物を調製した。得られた皮膚洗浄剤組成物について、下記評価を行った。(Examples 1 to 5 and Comparative Examples 1 to 4)
Each component was mixed according to the composition (blending amount) shown in Table 1 to prepare a skin cleansing composition. The obtained skin cleansing composition was evaluated as follows.
(1)起泡力、泡質、および泡ボリューム
各皮膚洗浄剤組成物約1.5gを掌にのせ、5gの水を加えて両手で擦り合わせて泡立てた。泡立てた際の起泡力、泡質、および泡ボリュームを評価した。なお、評価は、専門評価員3名により、25℃、湿度50%RHの恒温恒湿の条件下で実施し、協議により下記の基準で評価した。(1) Foaming power, foam quality, and foam volume About 1.5 g of each skin cleansing composition was placed on the palm, 5 g of water was added, and the skin was rubbed with both hands to foam. The foaming power, foam quality, and foam volume at the time of foaming were evaluated. The evaluation was carried out by three expert evaluators under the conditions of constant temperature and humidity of 25 ° C. and 50% humidity RH, and was evaluated according to the following criteria through consultation.
〔起泡力の評価基準〕
3:起泡力に非常に優れる
2:起泡力に優れるが、3には劣る
1:起泡力が低い[Evaluation criteria for foaming power]
3: Very good foaming power 2: Excellent foaming power, but inferior to 3: 1: Low foaming power
〔泡質の評価基準〕
3:泡が非常にキメ細かい
2:泡がキメ細かいが、3には劣る
1:泡のキメが粗い[Evaluation criteria for foam quality]
3: Very fine foam 2: Fine foam, but inferior to 3: 1: Coarse foam
〔泡ボリュームの評価基準〕
3:泡の嵩が非常に高い
2:泡の嵩が高いが、3には劣る
1:泡の嵩が低い[Evaluation criteria for foam volume]
3: Very high foam volume 2: High foam volume but inferior to 3: Low foam volume
(2)洗浄後のすすぎ性
各皮膚洗浄剤組成物約1.5gを掌にのせ、5gの水を加えて両手で擦り合わせて泡立て、この泡を用いて洗顔を行った。その後、温水で洗浄剤組成物を洗い流し、すすぎ性を評価した。なお、評価は、専門評価員3名により、25℃、湿度50%RHの恒温恒湿の条件下で実施し、協議により下記の基準で評価した。(2) Rinseability after washing Approximately 1.5 g of each skin cleansing composition was placed on the palm, 5 g of water was added and rubbed with both hands to lather, and the face was washed using this lather. Then, the detergent composition was rinsed with warm water, and the rinse property was evaluated. The evaluation was carried out by three expert evaluators under the conditions of constant temperature and humidity of 25 ° C. and 50% humidity RH, and was evaluated according to the following criteria through consultation.
〔洗浄後のすすぎ性の評価基準〕
3:すすぎ性に非常に優れる
2:すすぎ性に優れるが、3には劣る
1:すすぎ性が低い[Evaluation criteria for rinseability after cleaning]
3: Very good rinsing property 2: Excellent rinsing property, but inferior to 3: 1: Low rinsing property
表1の結果より、本実施形態に係る皮膚洗浄剤組成物は、良好な起泡力、泡質、泡ボリューム、および洗浄後のすすぎ落ち性能を有することがわかる。 From the results in Table 1, it can be seen that the skin cleansing composition according to the present embodiment has good foaming power, foam quality, foam volume, and rinsing performance after washing.
処方例1
ラウリン酸 5.0質量%
ミリスチン酸 10.0質量%
パルミチン酸 4.0質量%
ステアリン酸 10.0質量%
シリカ 1.0質量%
マーコート550PR 0.1質量%
ソルビトール 0.5質量%
濃グリセリン 20.0質量%
水酸化カリウム 適量
エデト酸四ナトリウム四水塩 0.05質量%
l−メントール 0.5質量%
香料 0.2質量%
精製水 残部Prescription example 1
Lauric acid 5.0% by mass
Myristic acid 10.0% by mass
Palmitic acid 4.0% by mass
Stearic acid 10.0% by mass
Silica 1.0% by mass
Marcourt 550PR 0.1% by mass
Sorbitol 0.5% by mass
Concentrated glycerin 20.0% by mass
Potassium hydroxide Appropriate amount tetrasodium edetate tetrahydrate 0.05% by mass
l-Menthol 0.5% by mass
Fragrance 0.2% by mass
Purified water balance
本発明の皮膚洗浄剤組成物は、起泡力、泡質、泡ボリューム、および洗浄後のすすぎ落ち性能が良好な皮膚洗浄剤組成物として利用できる。 The skin cleansing composition of the present invention can be used as a skin cleansing composition having good foaming power, foam quality, foam volume, and rinsing performance after washing.
Claims (4)
シリカを1.0〜10質量%、
ポリクオタニウム−6、ポリクオタニウム−7、ポリクオタニウム−22、およびポリクオタニウム−39からなる群より選ばれる1種または2種以上のカチオン性ポリマーを0.1〜4.0質量%、および
糖アルコールを0.5〜10質量%含有する皮膚洗浄剤組成物(ただし、アクリル酸及び/又はメタクリル酸と、アクリル酸及び/又はメタクリル酸のC1〜C5アルキルエステルとを共重合した架橋ポリマーを含有する洗浄剤組成物を除く)であって、前記シリカの吸油量が100mL/100g〜1000mL/100gである皮膚洗浄剤組成物。 5.0-50% by weight of higher fatty acids and / or salts thereof,
Silica 1.0-10% by mass,
Polyquaternium-6, polyquaternium-7, Po Rikuotaniumu -22, and one member selected from the group consisting of Polyquaternium -39 or more cationic polymer 0.1-4.0 wt%, and the sugar alcohol 0. Skin cleaning agent composition containing 5 to 10% by mass (however, cleaning agent composition containing a crosslinked polymer copolymerized with acrylic acid and / or methacrylic acid and C1 to C5 alkyl ester of acrylic acid and / or methacrylic acid. A skin cleaning agent composition having an oil absorption of 100 mL / 100 g to 1000 mL / 100 g of the silica.
前記皮膚洗浄剤組成物が前記容器内に充填されている、皮膚洗浄剤。 The skin cleansing composition according to any one of claims 1 to 3 and a container are provided.
A skin cleanser in which the skin cleansing composition is filled in the container.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2018097234 | 2018-05-21 | ||
JP2018097234 | 2018-05-21 | ||
PCT/JP2019/016691 WO2019225238A1 (en) | 2018-05-21 | 2019-04-18 | Skin cleanser composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPWO2019225238A1 JPWO2019225238A1 (en) | 2020-09-24 |
JP6965444B2 true JP6965444B2 (en) | 2021-11-10 |
Family
ID=68615601
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2020521103A Active JP6965444B2 (en) | 2018-05-21 | 2019-04-18 | Skin cleanser composition |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP6965444B2 (en) |
CN (1) | CN111065370A (en) |
WO (1) | WO2019225238A1 (en) |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2827515B1 (en) * | 2001-07-20 | 2005-06-03 | Oreal | FOAMING COMPOSITION BASED ON SILICA AND CATIONIC POLYMER |
JP4260427B2 (en) * | 2002-05-15 | 2009-04-30 | 東邦化学工業株式会社 | Cosmetic composition |
JP2006083140A (en) * | 2004-09-17 | 2006-03-30 | Lion Corp | Skin-cleansing agent composition |
JP5088459B2 (en) * | 2005-08-01 | 2012-12-05 | ライオン株式会社 | Skin cleanser composition |
JP2011162708A (en) * | 2010-02-12 | 2011-08-25 | Shiseido Co Ltd | Detergent composition |
JP5454319B2 (en) * | 2010-04-07 | 2014-03-26 | 三菱化学株式会社 | Foam modifying copolymer |
JP5864208B2 (en) * | 2011-10-25 | 2016-02-17 | 花王株式会社 | Cleaning composition |
JP6059052B2 (en) * | 2013-03-19 | 2017-01-11 | 花王株式会社 | Cleaning composition |
JP6125896B2 (en) * | 2013-05-14 | 2017-05-10 | 富士フイルム株式会社 | Skin cleanser |
JP2017119656A (en) * | 2015-12-28 | 2017-07-06 | ライオン株式会社 | Liquid skin cleansing composition |
GB2552400B (en) * | 2016-04-26 | 2021-05-26 | Pz Cussons Int Ltd | Personal cleansing composition |
-
2019
- 2019-04-18 CN CN201980004411.9A patent/CN111065370A/en active Pending
- 2019-04-18 JP JP2020521103A patent/JP6965444B2/en active Active
- 2019-04-18 WO PCT/JP2019/016691 patent/WO2019225238A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
WO2019225238A1 (en) | 2019-11-28 |
JPWO2019225238A1 (en) | 2020-09-24 |
CN111065370A (en) | 2020-04-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5088459B2 (en) | Skin cleanser composition | |
JP6183849B2 (en) | Skin cleanser composition | |
JP2014024875A (en) | Liquid detergent held in non-gas foamer container | |
KR20060009896A (en) | Detergent composition | |
JP5968692B2 (en) | Liquid detergent composition | |
JP2011038004A (en) | Detergent composition | |
JP2004035524A (en) | Composition for suppressing lowering in water content in corneal layer | |
JP2018016625A (en) | Cleansing cosmetic for scalp | |
JPH0812993A (en) | Detergent composition | |
JP4934254B2 (en) | Weakly acidic detergent composition | |
JP2005154360A (en) | Skin cleansing agent composition | |
KR101168434B1 (en) | Detergent composition | |
JP3970861B2 (en) | Cleaning composition | |
JP6965444B2 (en) | Skin cleanser composition | |
JP2010150175A (en) | Shampoo composition | |
JP7323396B2 (en) | skin cleanser composition | |
JP2017214372A (en) | Skin cleansing composition | |
JP5192871B2 (en) | Cleaning composition | |
JP5919156B2 (en) | Skin cleanser composition and skin cleanser | |
JP2008056608A (en) | Cleansing agent composition for skin | |
JP2005023069A (en) | Skin-cleansing composition | |
JP2020002050A (en) | Skin washing agent composition | |
JP7150050B2 (en) | skin cleanser composition | |
JP7440885B2 (en) | shampoo composition | |
JP2019081715A (en) | Composition for washing keratin substance |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20200107 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20210216 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20210415 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20210720 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20210913 |
|
C60 | Trial request (containing other claim documents, opposition documents) |
Free format text: JAPANESE INTERMEDIATE CODE: C60 Effective date: 20210913 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20210927 |
|
C21 | Notice of transfer of a case for reconsideration by examiners before appeal proceedings |
Free format text: JAPANESE INTERMEDIATE CODE: C21 Effective date: 20210928 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20211019 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20211020 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6965444 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |