JP2021113179A - Hair improvement method - Google Patents

Abstract

To provide hair improvement methods that can greatly improve the feel of hair, and maintain the effect for a long period of time even after repeated washing of the hair.SOLUTION: A hair improvement method characterized by applying a compound represented by the following general formula (1) or a salt thereof to the hair and by performing heat treatment is used. According to the present invention, it is possible to improve the feel, such as slipperiness, finger passage, and moistness, and furthermore, depending on the type of R1, it is possible to improve the feel, such as sturdiness, cohesiveness, and flexibility. (Where, R1 represents a residue of a higher fatty acid having 8 to 33 carbon atoms having a saturated or unsaturated hydrocarbon chain of a linear or branched chain which may have a hydroxyl group. n represents the degree of polymerization of lactic acid and represents an integer from 1 to 10.)SELECTED DRAWING: None

Description

The present invention relates to a method for improving hair, which comprises applying a compound synthesized from a higher fatty acid and lactic acid to hair and performing heat treatment.

Hair mainly consists of a cuticle that covers the surface, a cortex that occupies most of the hair inside it, and a medula that exists in the center of the hair. Among them, the cuticle has a structure in which scaly structures are stacked from the root to the tip of the hair, and plays a role of protecting the inside of the hair from the outside. In recent years, structural analysis of the cuticle has progressed, and it is known that the outermost layer of the cuticle has a structure in which a long-chain fatty acid called 18-methyleicosanoic acid and a hair protein are chemically bonded.

Hair is continuously damaged on a daily basis by chemical treatments such as perm, bleaching, and hair coloring, ultraviolet rays from sunlight, heat from a dryer, and brushing. It has been found that when hair is damaged in this way, long-chain fatty acids on the surface of the cuticle are desorbed, and this damage on the surface of the cuticle impairs the slipperiness and finger passage of the hair, resulting in damage to the hair. It is one of the factors that makes you feel. As a method for improving such hair damage, a method using a long-chain fatty acid or a quaternized product of a long-chain fatty acid has been attempted (Patent Documents 1 and 2). However, in these methods, the components are washed away by daily hair washing and the like, and it is difficult to maintain the effect for a long period of time.

Lactic acid fatty acid ester (acyl lactic acid) has long been used as a raw material for cosmetics mainly for hair cosmetics, and is used not only as a surfactant to impart detergency but also as a component to improve the feel of hair. (For example, Patent Documents 3 to 5). However, the improvement effect is not always sufficient. Patent Document 6 describes that oligolactic acid fatty acid ester can be used as a surfactant for detergents, but does not describe the effect of this compound on improving hair.

JP-A-2009-126851 Japanese Patent Application Laid-Open No. 10-139620 Japanese Patent Application Laid-Open No. 09-104896 Japanese Patent Application Laid-Open No. 10-0362330 Japanese Patent Application Laid-Open No. 2009-242271 International Publication No. 2004/092314

An object of the present invention is to provide a hair improving method which has an excellent feel improving effect on hair and can maintain the effect for a long period of time even after repeated washing of hair.

（式中、Ｒ１は水酸基を有してもよい直鎖又は分岐鎖の飽和又は不飽和炭化水素鎖を有する炭素数８〜３３の高級脂肪酸の残基を表す。ｎは乳酸の重合度を表し、１〜１０の整数を示す。） As a result of diligent studies to solve the above problems, the present inventors have applied the compound represented by the following general formula (1) or a salt thereof to the hair and heat-treated the problem of the present invention. The present invention has been completed by finding that the present invention can be solved.

(In the formula, R1 represents a residue of a higher fatty acid having 8 to 33 carbon atoms having a saturated or unsaturated hydrocarbon chain of a linear or branched chain which may have a hydroxyl group. N represents the degree of polymerization of lactic acid. Indicates an integer of 1 to 10.)

According to the hair improving method of the present invention, the feel of hair such as slippery feeling, finger passage, and moist feeling can be greatly improved, and the effect is maintained for a long period of time even after repeated washing of hair.

（式中、Ｒ１は水酸基を有してもよい直鎖又は分岐鎖の飽和又は不飽和炭化水素鎖を有する炭素数８〜３３の高級脂肪酸の残基を表す。ｎは乳酸の重合度を表し、１〜１０の整数を示す。） The hair improving method of the present invention is characterized in that a compound represented by the following general formula (1) or a salt thereof is applied to hair and heat-treated.

(In the formula, R1 represents a residue of a higher fatty acid having 8 to 33 carbon atoms having a saturated or unsaturated hydrocarbon chain of a linear or branched chain which may have a hydroxyl group. N represents the degree of polymerization of lactic acid. Indicates an integer of 1 to 10.)

The compound represented by the above general formula (1) used in the present invention is a component synthesized by an esterification reaction of a higher fatty acid and lactic acid.

As the lactic acid used for the synthesis of the compound represented by the general formula (1) of the present invention, any of L-lactic acid, D-lactic acid, and DL-lactic acid can be used, but it is available and economical. From the viewpoint of, L-lactic acid can be preferably used. Further, oligolactic acid obtained by polymerizing lactic acid may be used as a starting material. Oligolactic acid can be produced by heating lactic acid to 100 to 180 ° C., more preferably 130 to 170 ° C., and polycondensing it while distilling off the generated water.

R1 of the compound represented by the general formula (1) of the present invention represents a residue of a higher fatty acid, that is, represents a hydrocarbon group excluding the carboxyl group portion of the higher fatty acid. The higher fatty acid used in the synthesis of the compound represented by the general formula (1) of the present invention has 8 to 8 carbon atoms having a saturated or unsaturated hydrocarbon chain of a straight chain or a branched chain which may have a hydroxyl group. Thirty-three higher fatty acids can be used. Specific examples of higher fatty acids include saturated direct fatty acids such as octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, tetradecanoic acid, pentadecanoic acid, hexadecanoic acid, heptadecanoic acid, octadecanoic acid, nonadecanic acid, icosanoic acid, and docosanoic acid. Chain fatty acids; isooctanoic acid, 2-ethylhexanoic acid, isononanoic acid, isodecanic acid, dimethyloctanoic acid, isoundecanoic acid, isododecanoic acid, 2-butyloctanoic acid, isotridecanoic acid, isotetradecanoic acid, isopentadecanoic acid, isohexadecanoic acid, 2-hexyldecanoic acid, isoheptadecanoic acid, isostearic acid, isononadecanoic acid, isoicosanoic acid, 2-octyldodecanoic acid, 18-methyleicosanoic acid, anteisohenicosanoic acid, 2-decyltetradecanoic acid, 2-dodecylhexadecanoic acid, 2 -Saturated branched fatty acids such as tetradecyloctadecanoic acid; Unsaturated linear fatty acids; hydroxy fatty acids such as 12-hydroxystearic acid, 9,10-dihydroxystearic acid, ricinolic acid; orange oil fatty acids, avocado oil fatty acids, macadamia nut oil fatty acids, olive oil fatty acids, jojoba oil fatty acids, sunflower seed oil fatty acids , Palm oil fatty acid, palm kernel oil fatty acid, castor oil fatty acid, wheat germ oil fatty acid, safflower oil fatty acid, cottonseed oil fatty acid, minced oil fatty acid, lanolin fatty acid and other natural fat-derived fatty acids. These may be used alone or in combination of two or more.

The compound represented by the general formula (1) of the present invention has a different hair feel improved by the method of the present invention depending on the type of R1. Specifically, the smooth feeling, finger passage, and moist feeling are the feelings that are improved in common with all the compounds of the present invention. In addition to these, when R1 is a residue of a saturated linear fatty acid, It is more excellent in the effect of improving the feeling of stickiness, and when R1 is a residue of saturated branched fatty acid, it is more excellent in the effect of improving flexibility, and when R1 is a residue of hydroxy fatty acid, it improves the feeling of cohesion. Better in effect. The lanolin fatty acid is a fatty acid obtained by hydrolyzing wool fat or lanolin obtained by purifying it, and its main components are approximately 7% by weight of normal fatty acid, 22% by weight of iso fatty acid, and 29% by weight of anteiso fatty acid. Weight%, α-hydroxynormal fatty acid 25% by weight, α-hydroxyisofatty acid 3% by weight, α-hydroxyanteiso fatty acid 1% by weight, ω-hydroxynormal fatty acid 3% by weight, ω-hydroxyisofatty acid 1% by weight, ω -Hydroxyantheiiso fatty acid is a fatty acid having a complex composition consisting of 1% by weight of a fatty acid and having a wide distribution of 9 to 33 carbon atoms. When R1 is such a residue of lanolin fatty acid, it is more excellent in the effect of improving flexibility and cohesiveness.

Among the higher fatty acids exemplified above, dodecanoic acid, tetradecanoic acid, hexadecanoic acid, octadecanoic acid, icosanoic acid, docosanoic acid, 2-hexyldecanoic acid, from the viewpoint of availability, stability and the effect of the invention. Isostearic acid, 2-octyldodecanoic acid, oleic acid, 12-hydroxystearic acid, and lanolin fatty acids are preferred, with octadecanoic acid, docosanoic acid, isostearic acid, 12-hydroxystearic acid, and lanolin fatty acids being the most preferred.

Further, isostearic acid is a general term for higher fatty acids having a branched alkyl chain and having 18 carbon atoms, and there are several kinds of compounds in generally distributed isostearic acid depending on the branched structure. Specifically, it is obtained from isostearic acid (2-heptylundecanoic acid) obtained by the Garbet method, isostearic acid (2-isoheptylisoundecanoic acid) obtained by the aldol condensation method, and by-products during the production of dimer acid. Isostearic acid (mainly isostearic acid having a methyl branched structure) is known, and any isostearic acid can be used in the present invention, but in the effect of improving the flexibility characteristic of saturated branched fatty acids, Isostearic acid obtained by the garbet method and isostearic acid obtained from a by-product during the production of dimer acid are preferable, and isostearic acid obtained from a by-product during the production of dimer acid is most preferable.

A method for producing the compound of the general formula (1) of the present invention will be described. First, the charging ratio of the higher fatty acid and lactic acid as raw materials may be 1.0: 1.0 to 1.0: 10.0 in terms of molar ratio, and 1.0: 1.1 to 1.0: 8. 0 is preferable, 1.0: 1.2 to 1.0: 7.0 is more preferable, and 1.0: 1.5 to 1.0: 6.0 is most preferable. A basic catalyst may be used as the catalyst. Specifically, metal hydroxides such as potassium hydroxide, sodium hydroxide and lithium hydroxide; carbonates such as sodium hydrogencarbonate, potassium hydrogencarbonate, potassium carbonate and sodium carbonate. Metal salts; metal alkoxides such as potassium methoxide, sodium methoxide, potassium ethoxide, sodium ethoxide, potassium-t-butoxide, sodium-t-butoxide, etc., among these, potassium hydroxide, sodium hydroxide, etc. , Potassium carbonate, sodium carbonate, potassium methoxide, sodium methoxide are preferred. The amount of catalyst is preferably 0.1 to 2.0 mol, more preferably 0.2 to 1.5 mol, per 1 mol of fatty acid. The reaction temperature is preferably 100 to 260 ° C., preferably 150 to 220 ° C. The reaction time is preferably 0.5 to 10 hours, preferably 0.5 to 3 hours. The reaction product obtained under such conditions can be used as it is as the compound of the present invention, but it may be neutralized and used in the form of a salt, and further extracted, deoxidized, washed with water and recrystallized. , It may be appropriately purified by adsorption purification, distillation, column purification, or the like.

Although n in the compound of the general formula (1) of the present invention represents the degree of polymerization of lactic acid, those having n in the range of 1 to 10 can be used in the present invention, and those in the range of 1 to 8 are more suitable. It can be preferably used. In the present invention, a compound having a single degree of polymerization can be used as the compound of the general formula (1), but according to the above-mentioned production method, it can be obtained as a mixture of compounds having different degrees of polymerization. Mixtures are preferred. Further, in the present invention, it is preferable that the compound contains a compound having a degree of polymerization of 2 or more. By containing a compound having a degree of polymerization of 2 or more, the effect of the present invention can be further improved. From this point of view, the average degree of polymerization of lactic acid is preferably larger than 1.0. Specifically, the average degree of polymerization of lactic acid is preferably 1.05 or more, more preferably 1.1 or more, and most preferably 1.2 or more. If the average degree of polymerization is smaller than this, the content of the compound having a degree of polymerization of 2 or more is small, so that the effect of the present invention may not be sufficiently exhibited. The average upper limit of the degree of polymerization of lactic acid is preferably 6.0 or less, more preferably 4.0 or less, and most preferably 3.0 or less. If the average degree of polymerization is larger than this, the content of the compound having a high degree of polymerization becomes too large, and the effect of the present invention may not be sufficiently exhibited. In the above production method, the closer the charging ratio of lactic acid to 1.0 mol of fatty acid is, the more compounds having n of 1 are produced, and the charging ratio of lactic acid to 1.0 mol of fatty acid is produced. As is greater than 1.0 mol, more compounds with n greater than 1 are produced. Therefore, it is possible to adjust the average degree of polymerization of lactic acid by changing the charging ratio. Further, according to the above-mentioned production method, in addition to the compound represented by the general formula (1), higher fatty acids and lactic acid as reaction raw materials remain as unreacted products in the reaction product, and a polymer of lactic acid ( Oligolactic acid) is contained as a by-product, but in the present invention, a compound containing such a component can be used as it is.

The compound represented by the general formula (1) of the present invention has a carboxylic acid structure at the terminal and is in the form of an acid, but in the present invention, a compound in the form of a salt of a carboxylic acid can also be used. The salt is not particularly limited, but specifically, alkali metal salts such as sodium and potassium; alkaline earth metal salts such as calcium and magnesium; metal salts such as aluminum, iron and zinc; lysine, arginine and guanidine. , Basic amino acid salts such as histidine and ornithine; organic amine salts such as ammonium, monoethanolamine, diethanolamine, triethanolamine and stearylamine. The hair improving effect of the present invention can be exerted in either the form of acid or the form of salt.

The hair improving method of the present invention is characterized in that the compound represented by the general formula (1) obtained by the above method or a salt thereof is applied to the hair and heat-treated. The hair improving effect can be obtained simply by applying the compound represented by the general formula (1) to the hair, but the hair improving effect can be further improved by further performing the heat treatment step, and the hair improving effect can be further improved. The effect can be sustained for a long period of time.

The temperature of the heat treatment in the hair improving method of the present invention is preferably 60 ° C. or higher, more preferably 80 ° C. or higher, and most preferably 100 ° C. or higher as the lower limit. If the treatment temperature is low, the effect of the present invention is not exhibited, or a long period of treatment is required to exert the effect, resulting in poor efficiency. The upper limit of the heat treatment temperature is preferably 220 ° C. or lower, more preferably 200 ° C. or lower, and most preferably 180 ° C. or lower. If the treatment temperature is high, the hair will be damaged by heat, and the effect of the present invention may not be sufficiently exhibited.

The heat treatment time in the hair improving method of the present invention is preferably changed depending on the treatment temperature. Specifically, in the case of treatment at 60 ° C. to 100 ° C., it is preferable to carry out the treatment for about 1 minute to 60 minutes, preferably about 3 minutes to 30 minutes. When the treatment is performed at 100 ° C. to 180 ° C., it is preferably performed for 5 seconds to 5 minutes, preferably about 10 seconds to 3 minutes. When the treatment is performed at 180 ° C. to 220 ° C., the treatment is carried out for 1 second to 60 seconds, preferably about 3 seconds to 40 seconds.

As a method of applying the heat treatment in the hair improving method of the present invention, specifically, a device such as a hair iron (straight iron, curl iron, brush iron, etc.), a dryer, etc. can be used. Alternatively, it can be performed at the same time as a perm treatment accompanied by heating such as a digital perm or a hot perm. Of these, the dryer is not always preferable because it is difficult to uniformly apply heat to the hair and it is always exposed to warm air, which may damage the hair. Therefore, methods such as curling irons, digital perms, and hot perms are preferable, and curling irons are most preferable.

As a method of applying the compound represented by the general formula (1) of the present invention to the hair, it is sufficient that the compound can be uniformly applied to the hair, and there is no particular limitation, but the compound can be applied to the hair as it is, or a solvent or cosmetics in general. A method is used in which the hair is dissolved or dispersed in a liquid oil or the like used in the above, and then applied to the hair. When the compound represented by the general formula (1) of the present invention is in a solid state, it is easy to handle and apply by diluting it, and at the same time, it improves the permeability to hair and enhances the effect of the present invention. Can be enhanced.

Examples of the solvent used for diluting the compound represented by the general formula (1) of the present invention include ethanol, 2-propanol, glycerin, diglycerin, 1,3-propanediol, propylene glycol, dipropylene glycol, 1, Examples thereof include 3-butylene glycol, 1,2-pentanediol, 1,2-hexanediol, 1,2-heptandiol and 1,2-octanediol. Liquid oils include higher alcohols such as jojoba alcohol, ceracyl alcohol, hexyldecanol, octyldodecanol, decyltetradecanol, isostearyl alcohol, and dimerdiol; palmitooleic acid, oleic acid, linoleic acid, linoleic acid, and isostear. Higher fatty acids such as acids, ricinol acids, dimer acids, hydrogenated dimer acids; alkyl lactate (12, 13), lauryl lactate, myristyl lactate, octyldodecyl lactate, trialkyl citrate (12, 13), trialkyl citrate (14, 15), triethyl citrate, tri2-ethylhexyl citrate, triisocetyl citrate, octyldodecyl citrate, dialkyl malate (12, 13), hydroxyate esters such as diisostearyl malate; glyceryl caprylate , Capricate glyceryl, oleate glyceryl, coconut oil fatty acid glyceryl, monocotton seed oil fatty acid glycerin, isostearate glyceryl, dioleate glyceryl, diisostearate glyceryl, triisostearate glyceryl, triethylhexanoate glyceryl, tri (caprylic acid / capric acid) glyceryl , Glycerin fatty acid esters such as glyceryl trioleate, glyceryl triisostearate; polyglyceryl-2 diisostearate, polyglyceryl trioleate-10, polyglyceryl triisostearate-2, polyglyceryl tetraisostearate-2, polyglyceryl pentaoleate-10 , Polyglyceryl-10 pentaisostearate, polyglyceryl-10 decaoleate, polyglyceryl-10 decaisostearate and other polyglycerin fatty acid esters; sorbitan coconut oil, sorbitan olive fatty acid, sorbitan laurate, sorbitan oleate, sorbitan sesquioleate, trio Polysorbate fatty acid esters such as sorbitan laine, sorbitan isostearate, sorbitan sesquiisostearate, sorbitan triisostearate; trimethylolpropane triethylhexanoate, pentaerythrityl tetraisostearate, neopentylglycol dicaprate, di (caprylic acid / capric acid) ) Neopentyl glycol, neopentyl glycol diethylhexanoate, neopentyl glycol dilaurate, neopentyl glycol diisostearate, neopentylglycolate diisononanonate Polyvalents such as ol, ethylene glycol dioleate, propylene glycol dioleate, neopentyl glycol dineopenate, 3-methyl-1,5-pentanediol dineopenate, 2,4-diethyl-1,5-pentanediol dineeopentanoate, etc. Alcohol fatty acid esters; diheptyl succinate, diethylhexyl succinate, diisopropyl adipate, dibutyl adipate, diethylhexyl adipate, diethyl sebacate, diisopropyl sebacate, diethylhexyl sebacate, dimer dilinoleyl, etc. Dicarboxylic acid esters; cetyl ethylhexanoate, stearyl ethylhexanoate, isostearyl ethylhexanate, hexyldecyl ethylhexanate, isononyl isononanoate, isodecyl isononanoate, isotridecyl isononanoate, isodecyl neopentate, isotridecyl neopentanoate, isopentanoate. Stearyl, octyldodecyl neodecanoate, isopropyl myristate, hexyldecyl myristate, octyldodecyl myristate, isopropyl palmitate, ethylhexyl palmitate, cetyl palmitate, octyldodecyl palmitate, ethyl oleate, oleyl oleate, octyldodecyl oleate , Monocarboxylic acid esters such as ethyl isostearate, isopropyl isostearate, octyldodecyl isostearate, octyldodecyl erucate, ethylhexyl hydroxystearate; (eicosanedioic acid / tetradecanedioic acid) polyglyceryl-10, polyglyceryl tetradecanoate-10 , Water-soluble esters such as cyclohexanedicarboxylic acid bisethoxydiglycol; Polyhydric alcohol alkyl ethers such as isostearylglyceryl ether; Palm oil, palm oil, palm kernel oil, saflower oil, olive oil, castor oil, avocado oil, Sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rose hip oil, Argania spinosa kernel oil, meadowfoam oil, persic oil, tea tree oil, peppermint oil, camellia oil, corn oil, Vegetable oils such as rapeseed oil, sunflower oil, wheat germ oil, flaxseed oil, cotton seed oil, soybean oil, peanut oil, rice bran oil, jojoba oil; dodecane, isododecane, hexadecane, isohexadecane, liquid paraffin, heavy liquid isoparaffin, light fluid Examples thereof include hydrocarbon oils such as isoparaffin, α-olefin oligomer, squalane, and hydrogenated polyisobutene. These may be blended alone or in combination of two or more. Of these, ethanol, octyldodecanol, isostearyl alcohol, oleic acid, isostearic acid, diisostearyl malate, glyceryl isostearate, glyceryl diisostearate, tri (caprylic acid / capric acid) glyceryl, polyglyceryl oleate-2, Polyglyceryl-2 isostearate, polyglyceryl-2 diisostearate, polyglyceryl-2 triisostearate, sorbitan oleate, sorbitan sesquioleate, sorbitan isostearate, sorbitan sesquiisostearate, diethyl sebacate, diisopropyl sebacate, ethylhexyl palmitate, hydroxy Ethylhexyl stearate, jojoba oil, dodecane, isododecane and the like are preferred. When diluting with a solvent or liquid oil, the compound of the present invention may be diluted in an amount of 10 to 90% by weight, preferably 20 to 80% by weight, based on the whole diluted product.

As a method of applying the compound represented by the general formula (1) of the present invention to hair, in addition to the above-mentioned method, it can also be applied to hair by blending it with a known general hair cosmetic. can. When the compound represented by the general formula (1) of the present invention is blended into a hair cosmetic, the blending amount is not particularly limited, but is preferably 0.001 to 50% by weight, more preferably 0.005 to 20% by weight. %.

The hair cosmetic containing the compound represented by the general formula (1) of the present invention includes, if necessary, additive components generally blended in the hair cosmetic, such as an oily base, a surfactant, and alcohols. , Moisturizer, Polymer / thickening / gelling agent, antioxidant, preservative, bactericidal agent, chelating agent, pH adjuster / acid / alkali, ultraviolet absorber, whitening agent, solvent, keratin peeling / dissolving agent, Antipruritic agents, anti-inflammatory agents, antiperspirants, refreshing agents, antihistamines, astringents, stimulants, hair growth agents / blood circulation promoters, reducing agents / oxidizing agents, polymer powders, hydroxy acids, vitamins and their derivatives, Sugars and derivatives thereof, organic acids, enzymes, nucleic acids, hormones, inorganic powders, fragrances, pigments and the like may be contained to the extent that the effects of the present invention are not impaired.

Oily bases include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, araquil alcohol, behenyl alcohol, jojoba alcohol, chimil alcohol, seraquil alcohol, bacil alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol and dimerdiol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, Higher grades such as palmitooleic acid, oleic acid, linoleic acid, linoleic acid, erucic acid, docosahexaenoic acid, eikosapentaenoic acid, isohexadecanoic acid, anteisohenicosanoic acid, long chain branched fatty acids, dimer acid, hydrogenated dimer acid, etc. Fatty acids and metal soaps such as aluminum salts, calcium salts, magnesium salts, zinc salts, potassium and sodium salts, and nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin , Α-Olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalane, vaseline, solid paraffin and other hydrocarbons; candelilla wax, carnauba wax, rice wax, wood wax, honey wax, montan wax , Ozokerite, Celesin, Paraffin wax, Microcrystalin wax, Petrolatum, Fishertroph wax, Polyethylene wax, Ethylene-propylene copolymer and other waxes; Palm oil, Palm oil, Palm kernel oil, Saflower oil, Olive oil, Himasi oil, Avocado Oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rose hip oil, meadowfoam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat Vegetable oils and fats such as germ oil, flaxseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; beef fat, milk fat, Animal oils and fats such as horse fat, egg yolk oil, mink oil and turtle oil; animal waxes such as whale wax, lanolin and orange raffy oil; liquid lanolin, reduced lanoli Lanolins such as adsorption-purified lanolin, lanolin acetate, liquid acetate lanolin, hydroxylanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; lecithin, phosphatidylcholine , Phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingomyelin and other sphingolin lipids, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof, phospholipids such as lysolecithin; hydrogenated soybean phospholipids, partially hydrogenated soybeans Phosphorlipid derivatives such as phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids; sapogenins; saponins; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, N-lauroyl Di-L-glutamate (cholesteryl / behenyl / octyldodecyl), N-lauroyl-di-L-glutamate (cholesteryl / octyldodecyl), di-lauroyl-L-glutamate (phytosteryl / behenyl / octyldodecyl), N-lauroyl- Di (phytosteryl / octyldodecyl) L-glutamate, acyl sarcosine alkyl esters such as N-lauroyl sarcosin isopropyl, cholesteryl 12-hydroxystearate, macadamia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl, sunflower seed oil fatty acid phytosteryl, isostearyl Sterol esters such as soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long-chain branched fatty acid cholesteryl, long-chain α-hydroxy fatty acid cholesteryl; lipid complexes such as phospholipid / cholesterol complex, phospholipid / phytosterol complex; myristic acid Octyldodecyl, hexyldecyl myristate, octyldodecyl isostearate, cetyl pariminate, octyldodecyl palmitate, cetyl octanate, hexyldecyl octanoate, isotridesyl isononanoate, isononyl isononanoate, octyl isononanoate, isotridesyl isononanoate , Isotridecyl neopentate, Isostearyl neopentate, Octyldodecyl neodecanoate, Oleyl oleate, Octi oleate Ludodecyl, octyldodecyl ricinoleate, octyldodecyl lanolin fatty acid, dicaprylyl carbonate, hexyldecyl dimethyloctanoate, octyldodecyl erucate, hardened isostearic acid castor oil, ethyl oleate, ethyl avocado oil fatty acid, isopropyl myristate, isopropyl palmitate, palmitin Octyl acid, isopropyl isostearate, isopropyl lanolin fatty acid, methylheptyl laurate, methylheptyl myristate, methylheptyl palmitate, methylheptyl isostearate, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dibutyl sebacate Monoalcoholic carboxylic acid esters such as octyl, diisobutyl adipate, dioctyl adipate, dioctyl succinate, triethyl citrate; oxy such as cetyl lactate, diisostearyl malate, hydrogenated castor oil monoisostearate, γ-ercalactone Acid esters; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, glyceryl tri (capric acid / capric acid), tri (caprylic acid / capric acid / myristic acid / stearic acid) glyceryl, hydrogenated Rozin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl benoic acid, glyceryl trioctanoate, trimethylolpropane triisostearate, neopentylglycol dioctanoate, neopentyl glycol dicaprate, dioctanoic acid 2-Butyl-2-ethyl-1,3-propanediol, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogenated rosin pentaerythrityl, ditrimethylolpropane triethylhexanoate, ditrimethylol (isostearic acid / sebacic acid) Propane, pentaerythricyl triethylhexanoate, (hydroxystearic acid / stearic acid / logonic acid) dipentaerythrityl, diglyceryl diisostearate, polyglyceryl tetraisostearate, polyglyceryl nonaisostearate-10, deca (erucic acid / isostearic acid / ricinoleic acid) Polyglyceryl-8, (hexyldecanoic acid / sebacic acid) diglyceryl oligoester, glycol distearate (d. distearate) Polyhydric alcohol fatty acid esters such as (tyrene glycol), 3-methyl-1,5-pentanediol dineopenate, 2,4-diethyl-1,5-pentanediol dineopenate; alkyl ethers such as dicaprylyl ether; die Diisopropyl dimersinolate, diisostearyl dimerserinolate, dimerselyl dimerglinolate (isostearyl / phytosteryl), dimerglinolic acid (phytosteryl / behenyl), dimerserinolic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) ), Dimerdilinoleic acid Dimerdilinoleil, Diomadylinorail diisostearate, Dimersylinoleyl hydrogenated rosin condensate, Dimergylinoleic acid-cured castor oil, Dimericicic dimeric acid or Dimerdiol such as hydroxyalkyl Dimergylinoleil ether Derivatives of: Palm oil fatty acid monoethanolamide (cocamide MEA), palm oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide). MIPA), palmitate monoethanolamide (partamide MEA), palmitate diethanolamide (partamide DEA), coconut oil fatty acid methylethanolamide (cocamidomethyl MEA) and other fatty acid alkanolamides; dimethicone (dimethylpolysiloxane), highly polymerized dimethicone (dimethicone) Highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone, diphenyldimethicone, phenyldimethicone, (aminoethylaminopropylmethicone / dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin , Silicone rubber, amino-modified silicones such as aminopropyl dimethicone and amodimethicone, cationic-modified silicones, polyether-modified silicones such as dimethicone copolyol, polyglycerin-modified silicones, sugar-modified silicones, carboxylic acid-modified silicones, phosphate-modified silicones, sulfuric acid. Modified silicones, alkyl-modified silicones, fatty acid-modified silicones, alkylether-modified silicones, amino acid-modified silicones, peptide-modified silicones, fluorine-modified silicones, cation-modified and polyether-modified silicones. Silicones such as licone, amino-modified and polyether-modified silicone, alkyl-modified and polyether-modified silicone, amide alkyl-modified silicone, aminoglycol-modified silicone, aminophenyl-modified silicone, polysiloxane / oxyalkylene copolymer; Fluoro-based oils such as perfluorooctane and perfluoropolyether are preferred.

Examples of the moisturizing agent / feel improving agent include glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, and the like. Polypolymers such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymer and its polymers; diethylene glycol monoethyl ether Glycol alkyl ethers such as (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether; (eicosanedioic acid / tetradecanedioic acid) polyglyceryl-10, polyglyceryl-10 tetradecanedioate, cyclohexanedicarboxylic acid Water-soluble esters such as bisethoxydiglycol; sugar alcohols such as sorbitol, xylitol, erythritol, mannitol, martitol; glucose, fructose, galactose, mannose, treose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, Trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin, and modified cyclodextrins such as maltosylation and hydroxyalkylation), β-glucan, chitin, chitosan, Sugars and derivatives such as heparin and derivatives, pectin, arabinogalactan, dextrin, dextran, glycogen, ethyl glucoside, glucosyl ethyl methacrylate polymer or copolymer; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate , Caronine sulfate, keratosulfate, dermatan sulfate; white jellyfish extract, white jellyfish polysaccharide; fluctanes such as inulin and levan; fucoidan; tuberose polysaccharide, naturally occurring polysaccharide; organic acids such as citrate, tartaric acid and lactic acid and salts thereof. Urea; Salts such as 2-pyrrolidone-5-carboxylic acid and sodium thereof; betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threoni Amino acids such as peptides, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine and their salts; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagen degradation Peptide, hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin-degraded peptide, keratin-degraded peptide, hydrolyzed keratin, conchiolin-degraded peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soybean Protein peptides and derivatives thereof such as proteolytic peptides, wheat proteolytic peptides, hydrolyzed wheat proteins, casein-degrading peptides, acylated peptides; acylated peptides such as palmitoyl oligopeptides, palmitoyl pentapeptides, palmitoyl tetrapeptides; Peptides; Lactobacillus culture, yeast extract, eggshell membrane protein, submandibular gland mutin, hypotaurine, sesame lignan glycoside, glutathione, albumin, lactose; choline chloride, phosphorylcholine; placenta extract, aerastin, collagen, aloe extraction Peptides, Hamamelis water, Hechima water, Camomila extract, Kanzo extract, Comfrey extract, Silk extract, Izayoi rose extract, Peptide extract, Eucalyptus extract, Melilot extract and other animal / plant extracts, Natural ceramide (Types 1, 2, 3, 4, 5, 6), hydroxyceramides, pseudo-ceramides, sphingoglycolipids, ceramides and ceramides such as sugar ceramide-containing extracts are preferable.

As the surfactant, anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants, polymer surfactants and the like are preferable. The HLB of the surfactant is not particularly limited and can be used from a low HLB of about 1 to a high HLB of about 20, and it is also preferable to combine a low HLB and a high HLB. Examples of preferred surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulphates such as sodium lauryl sulphate, triethanolamine lauryl sulphate and ammonium lauryl sulphate; laureth. Polyoxyethylene alkyl sulfates such as sodium sulphate and triethanolamine laures sulphate; sodium cocoyl methyl taurine, potassium cocoyl methyl taurine, sodium lauroyl methyl taurine, sodium myristyl methyl taurine, sodium lauroyl methyl alanine, sodium lauroyl sarcosin, lauroyl sarcosin triethanol. Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroyl glutamate; sodium cocoyl glutamate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine. , Acylamino acid salts such as lysine Na dilauroyl glutamate; Polyoxyethylene alkyl ether acetates such as sodium laureth acetate; Sulfonic acid ester salts such as sodium lauroyl monoethanolamide succinate; Fatty acid alkanolamide ether carboxylates; Polyoxyethylene Fat amine sulfate; fatty acid alkanolamide sulfate; hardened coconut oil fatty acid fatty acid glyceride sulfate such as sodium glycerin sulfate; alkylbenzene polyoxyethylene sulfate; olefin sulfonate such as α-olefin sulfonate sodium; lauryl lauryl sulfosuccinate disodium Alkyl sulfosuccinates such as sodium dioctyl sulfosuccinate; alkyl ether sulfosuccinates such as laureth sulfosuccinate disodium, monolauroyl monoethanolamide polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate; sodium tetradecylbenzene sulfonate Alkylbenzene sulfonates such as triethanolamine tetradecylbenzene sulfonic acid; alkylnaphthalene sulfonates; alkane sulfonates; α-sulfo fatty acid methyl ester salts; acyl ISEthionate; alkyl glycidyl ether sulfonates; alkyl sul Polyethylene salt; alkyl ether phosphate such as sodium laureth phosphate, sodium dilaures phosphate, sodium trilaureth phosphate, sodium monoolesphosphate; alkyl phosphate such as potassium lauryl phosphate; sodium caseinate; alkylaryl ether phosphate Salts; fatty acid amide ether phosphates; phospholipids such as phosphatidylglycerol, phosphatidylinositol, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof; Sexual surfactants, etc .; Among nonionic surfactants, laureth (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steares (polyoxyethylene stearyl ether), behenes (polyoxyethylene behenyl) Polyoxyethylene alkyl ethers with various polyoxyethylene additions such as ether), isosteares (polyoxyethylene isostearyl ether), octyldodeces (polyoxyethylene octyldodecyl ether); polyoxyethylene alkylphenyl ether; polyoxy Polyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil monopyroglutamic acid monoisostearic acid diester, polyoxyethylene Hardened castor oil and castor oil derivatives such as maleic acid; polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene / polyoxypropylene cetyl Polyoxy such as ether, polyoxyethylene / polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene / polyoxypropylene monobutyl ether, polyoxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene / polyoxypropylene glycerin ether, etc. Ethylene / polyoxypropylene alkyl ether; polyoxyethylene / polyoxypropylene glycol; (poly) glycerin polyoxypropylene glycol such as PPG-9 diglyceryl; glyceryl stearate, isos Glyceryl tearate, Glyceryl palmitate, Glyceryl myristate, Glyceryl oleate, Glyceryl coconut oil, Glycerin monocotton seed oil, Glycerin monoercaate, Glycerin sesquioleate, α, α'-Glycerin pyroglutamate oleate, Glycerin monostearate Partial esters of glycerin fatty acids such as malic acid; polyglyceryl-2 stearate, 3, 4, 4, 5, 6, 8, 10, distearate polyglyceryl-6, 10, triglyceryl-2, Polyglyceryl decastearate-10, polyglyceryl isostearate-2, 3, 4, 4, 5, 6, 8, 10, diisostearate, polyglyceryl-2 diisostearate (diglyceryl diisostearate), 3, 10, tri Polyglyceryl-2 isostearate-2, polyglyceryl-2 tetraisostearate, polyglyceryl-10 decaisostearate, polyglyceryl oleate-2, 3, 4, 5, 6, 6, 8, 10, polyglyceryl dioleate-6, Polyglycerin fatty acid esters such as polyglyceryl-2 trioleate and polyglyceryl-10 decaoreate; ethylene glycol monofatty acid esters such as ethylene glycol monostearate; propylene glycol monofatty acid esters such as propylene glycol monostearate; partial fatty acid esters of pentaerythritol. Sorbitol partial fatty acid ester; Martinol partial fatty acid ester; Martinol ether; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate. , Penta-2-ethylhexylate diglycerol sorbitan, tetra-2-ethylhexylate diglycerol sorbitan and other sorbitan fatty acid esters; sucrose fatty acid ester, methylglucoside fatty acid ester, undecylate trehalose and other sugar derivative partial esters; Alkyl glucoside; alkyl polyglycoside; glycolipids such as mannosyl erythritol lipid; lanolin alcohol; reduced lanolin; polyoxyethylene distearate, polytylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene dioleate Etc. Polyoki Siethylene fatty acid mono and diester; polyoxyethylene / propylene glycol fatty acid ester; polyoxyethylene glycerin monostearate, polyoxyethylene glycerin monoisostearate, polyoxyethylene monooleate such as polyoxyethylene glycerin triisostearate, etc. Polyoxyethylene glycerin fatty acid ester; polyoxyethylene sorbitan fatty acid ester such as polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol Polyoxyethylene sorbitol fatty acid esters such as monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene sorbitol pentaoleate, polyoxyethylene sorbitol monostearate; polyoxyethylene methyl glucoside fatty acid esters; polyoxyethylene alkyl ether fatty acids Esters; Polyoxyethylene animal and vegetable oils and fats such as polyoxyethylene sorbitol honey; Alkyl glyceryl ethers such as isostearyl glyceryl ether, Kimyl alcohol, ceracyl alcohol, and batyl alcohol; Polyhydric alcohol alkyl ethers; Polyoxyethylene alkyl amines; Tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponin and sophorolipid; polyoxyethylene fatty acid amide; palm oil fatty acid monoethanolamide (cocamide MEA), palm oil fatty acid diethanolamide (cocamide) DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitate monoethanolamide (partamide MEA), palmitate diethanolamide (partamide DEA) Alkanolamides such as coconut oil fatty acid methylethanolamide (cocamidomethyl MEA); alkyldimethylamine oxides such as lauramine oxide, cocamine oxide, stearamine oxide, behenamine oxide; alkylethoxydimethylamine oxide; polyoxyethylene Alkyl mercaptan; Polyether-modified siri such as dimethicone copolyethylene Silicone-based nonionic surfactants such as cones, polysiloxane / oxyalkylene copolymers, polyglycerin-modified silicones, and sugar-modified silicones; among cationic surfactants, behentrimonium chloride, stealtrimonium chloride, and setri Alkyltrimethylammonium chlorides such as monium chloride and lauryltrimonium chloride; alkyltrimethylammonium bromides such as stearyltrimonium bromide; dialkyldimethylammonium chlorides such as distearyldimonium chloride and dicocodimonium chloride; stearamidepropyldimethylamine and stearamide. Fatty acid amidamines such as ethyl diethylamine and salts thereof; Alkyl ether amines such as stearoxypropyl dimethylamine and salts or quaternary salts thereof; Long chain branched fatty acids (12-31) aminopropyl ethyl dimethyl ammonium, lanolin fatty acids amino ethyl sulfate Fatty acid amide type quaternary ammonium salt such as propylethyldimethylammonium; polyoxyethylene alkylamine and its salt or quaternary salt; alkylamine salt; fatty acid amide guanidium salt; alkyletheraminemonium salt; alkyltrialkylene glycolammonium salt Benzalconium salt; benzethonium salt; pyridinium salt such as cetylpyridinium chloride; imidazolinium salt; alkylisoquinolinium salt; dialkylmoriphonium salt; polyamine fatty acid derivative; aminomodified silicone such as aminopropyldimethicone and amodimethicone , Cationic-modified silicone, cationic-modified and polyether-modified silicone, amino-modified and polyether-modified silicone, and other silicone-based cationic surfactants; for amphoteric surfactants, N such as lauryl betaine (lauryl dimethylaminoacetate betaine) -Alkyl-N, N-dimethyl amino acid betaine; fatty acid amide alkyl-N, N-dimethyl amino acid betaine such as cocamidopropyl betaine and lauramidopropyl betaine; imidazoline type betaine such as sodium cocoamphoacetate and sodium lauroammonium acetate; alkyldimethyltaurine Alkyl sulfobetaines such as, sulfate-type betaines such as alkyldimethylaminoethanol sulfate esters; phosphoric acid-type betaines such as alkyldimethylaminoethanol phosphates; phosphatidylcholine, phosphatidylethanolamine, phospha Sphingomyelin lipids such as thidylserine and sphingomyelin, lysolecithin, hydrogenated soybean phospholipids, partially hydrogenated soybean phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids, phospholipids such as lecithin hydroxide; Surfactants and the like; Among the high molecular weight surfactants, polyvinyl alcohol, sodium alginate, starch derivatives, tragant gum, acrylate / alkyl methacrylic acid copolymers; various silicone-based surfactants are preferable.

Examples of the polymer / thickener / gelling agent include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, farcerelan, karaya gum, trolley aoi, cara gum, tragant gum, pectin, pectic acid and sodium. Salts such as salts, salts such as alginic acid and sodium salts, mannan; starches such as rice, corn, potatoes, wheat; xanthan gum, dextran, succinoglucan, curdran, hyaluronic acid and its salts, zansan gum, purulan, gellan gum, chitin , Chitosan, agar, casso extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose and salts such as sodium thereof, methyl hydroxypropyl cellulose, sodium cellulose sulfate, dialkyldimethyl Ammonium sulfate cellulose, crystalline cellulose, cellulose powder and other cellulose and derivatives thereof; starch-based polymers such as soluble starch, carboxymethyl starch, methylhydroxypropyl starch, methyl starch, hydroxypropyltrimonium chloride starch, corn starch aluminum octenyl succinate, etc. Alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), vinylpidridone / vinyl alcohol copolymer, polyvinylmethyl ether; polyethylene glycol, polypropylene glycol, polyoxyethylene Polyoxypropylene copolymer; amphoteric methacrylate copolymer such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrelites / stearyl acrylate / ethylamine methacrylate) copolymer; (dimethicone / vinyldimethicone) cloth Polymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP; partially saponified polyvinyl acetate, maleic acid copolymer; vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymer; Acrylic resin alkanolamine; polyester, water-dispersible polyester; polya Crylamide; polyacrylic acid ester copolymer such as ethyl polyacrylate, carboxyvinyl polymer, salt such as polyacrylic acid and sodium salt thereof, acrylic acid / methacrylic acid ester copolymer; acrylate / alkyl methacrylic acid Polymers: cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, acrylic acid such as polyquaternium-39. -Diallyldimethylammonium chloride-acrylamide copolymer, acrylic acid-cationized metaacrylic acid ester copolymer, acrylic acid-cationized metaacrylic acid amide copolymer, polyquaterium-47 and other acrylic acid-methyl acrylate-chloride Methacrylate propyltrimethylammonium copolymer, choline chloride methacrylate polymer; cationized oligosaccharides, cationized dextran, cationized polysaccharides such as guarhydroxypropyltrimonium chloride; polyethyleneimine; cationic polymers; polyquaternium-51 and the like. 2-Polymer of methacryloyloxyethyl phosphorylcholine, polymer with butyl methacrylate copolymer, etc .; acrylic resin emulsion, ethyl polyacrylate emulsion, polyacrylic alkyl ester emulsion, polyvinyl acetate resin emulsion, natural rubber latex, synthetic Polymer emulsions such as latex; nitrocellulose; polyurethanes and various copolymers; various silicones; various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and Its salts; dextrin fatty acid esters such as dextrin palmitate, dextrin myristinate; silicic anhydride, fuming silica (ultrafine anhydrous silicic acid), aluminum magnesium silicate, sodium magnesium silicate, metal soap, metal dialkyl phosphate, Bentonite, hectrite, organically modified clay minerals, sucrose fatty acid esters, fructo-oligosaccharide fatty acid esters are preferred.

Examples of solvents and propellants include lower alcohols such as ethanol, 2-propanol (isopropyl alcohol), butanol, and isobutyl alcohol; glycols such as propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, and isopentyldiol. Kind: Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as: ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, glycol ether esters such as propylene glycol monoethyl ether acetate; glycol esters such as diethoxyethyl succinate and ethylene glycol disuccinate; benzyl Preferables include propellants such as alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate, acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation freon; LPG, dimethyl ether, and carbon dioxide.

Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; bisulfite derivatives such as propyl bisulfite; vitamin C (ascorbic acid) and / or its derivatives; erythorbic acid and its derivatives; Sulfites such as sodium sulfite; hydrogen sulfites such as sodium hydrogen sulfite; thiosulfites such as sodium thiosulfite; metahydrosulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride are preferable. Is listed as. As the reducing agent, thioglycolic acid, cysteine, cysteamine and the like are preferable. As the oxidizing agent, hydrogen peroxide solution, ammonium persulfate, sodium bromate, percarbonate and the like are preferable.

Examples of antibacterial agents or preservatives include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben, and butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane. 1,2-Alcandiols such as diols; Alkyl glyceryl ethers such as 2-ethylhexyl glyceryl ether (ethylhexyl glycerin); Glycerin fatty acid esters such as glyceryl caprylate, glyceryl caprate, and glyceryl (caprylic acid / capric acid); Salicylic acid; sodium benzoate; isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; imidazolinium urea; dehydroacetic acid and salts thereof; phenols; halogenated bisphenols such as triclosan, acid amides, quaternary Ammonium salts; trichlorocarbanide, zincpyrythion, benzalkonium chloride, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophen, hinokithiol; phenol, isopropylphenol, cresol, timol, parachlorophenol, phenylphenol, Other phenols such as sodium phenylphenol; phenylethyl alcohol, photosensitizers, antibacterial zeolite, and silver ions are preferable, but when used as an antibacterial agent or an antiseptic for the purpose of antiseptic, cosmetics or skin. From the viewpoint of the safety of external preparations, phenoxyethanol; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol and 1,2-octanediol; alkylglyceryl such as 2-ethylhexyl glyceryl ether. Ethers; It is more preferable to use glycerin fatty acid esters such as glyceryl caprylate, glyceryl caprate, and glyceryl (capric acid / capric acid).

Examples of the chelating agent include edetates (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytate; ethidroic acid and the like. Phosphonic acid and salts such as sodium salts thereof; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphate; sodium citrate, citric acid, alanine, dihydroxyethylglycine , Gluconic acid, ascorbic acid, succinic acid, tartrate acid are preferred. As pH adjusters / acids / alkalis, citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol Amin, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylated Preferred are sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate and ammonium carbonate.

Powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, white mica, gold mica, synthetic mica, red mica, black mica, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, cay. Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (eg zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, red iron oxide, yellow iron oxide, black iron oxide, ultramarine, dark blue, carbon black, titanium oxide, fine and ultrafine titanium oxide, zinc oxide , Fine and ultrafine zinc oxide, alumina, silica, fumigant silica (ultrafine anhydrous silicic acid), mica titanium, fish scale foil, boron nitride, photochromic pigment, synthetic fluorine gold mica, fine particle composite powder, gold, aluminum, etc. Inorganic powders of various sizes and shapes, and these are treated with silicones such as hydrogen silicone and cyclic hydrogen silicone or other surface treatment agents such as silane or titanium coupling agents to make them hydrophobic or Inorganic powder such as hydrophilized powder; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene and acrylic acid copolymer resin powder, polyester powder, benzoguanamine resin powder, polyethylene terephthalate -Polymethylmethacrylate laminated powder, polyethylene terephthalate, aluminum, epoxy laminated powder, etc., urethane powder, silicone powder, Teflon (registered trademark) powder, and other organic powders and surface treatment powders of various sizes and shapes, organic and inorganic Composite powders are preferred. Inorganic salts include sodium chloride-containing salts such as salt, normal salt, rock salt, sea salt, and natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, ginger, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, etc. Aluminum / potassium sulfate (myoban), aluminum / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na / 2Na / 3Na phosphate, phosphoric acid Potassiums, calcium phosphates and magnesium phosphates are preferred.

Examples of the ultraviolet absorber include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, and N, N-dimethylparaaminobenzoate ethyl. An benzoic acid-based UV absorber such as ester, N, N-dimethylparaaminobenzoic acid butyl ester, N, N-dimethylparaaminobenzoic acid ethyl ester; anthranylic acid-based UV absorber such as homomentyl-N-acetylanthranilate; salicylic acid And salicylic acid-based ultraviolet absorbers such as sodium salt, amylsalicylate, menthylsalicylate, homomentylsalicylate, octylsalicylate, phenylsalicylate, benzylsalicylate, p-isopropanol phenylsalicylate; octylcinnamate, ethyl-4-isopropylcinnamate, methyl. -2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p-methoxy cinnamate, isopropyl-p-methoxy cinnamate, isoamyl-p-methoxy Synnamete, 2-ethylhexyl p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (synoxate), cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenyl Cyraxic acid-based ultraviolet absorbers such as cinnamate, 2-ethylhexyl α-cyano-β-phenyl cinnamate (octocrine), glycerylmono-2-ethylhexanoyl-diparamethoxycinnamate, ferulic acid and derivatives thereof; 2, 4-Dihydroxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2', 4,4'-tetrahydroxybenzophenone, 2-hydroxy- 4-Methoxybenzophenone (oxybenzon-3), 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4' Benzophenones such as −phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone UV absorbers; 3- (4'-methylbenziliden) -d, l-phenyl, 3-benziliden-d, l-phenyl; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5 -Methylphenylbenzotriazole; 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole; 2- (2'-hydroxy-5'-methylphenylbenzotriazole; dibenzalazine; dianisoilmethane; 5-( 3,3-Dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octylriazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate 2- (2'-Hydroxy-5'-methylphenyl) benzotriazole, 1- (3,4-dimethoxyphenyl) -4,4-dimethyl-1,3-pentandione, dimethoxybenzilidendioxoimidazolidine propionic acid Hydantin derivatives such as 2-ethylhexyl, phenylbenzimidazole sulfonic acid, terephthalylidene dicanfursulfonic acid, drometrizole trisiloxane, methyl anthranilate, rutin and its derivatives, oryzanol and its derivatives are preferred.

Examples of the whitening agent include hydroquinone glycosides such as arbutin and α-arbutin and their esters; ascorbic acid, ascorbic acid phosphate ester salts such as ascorbic acid, ascorbic acid phosphate sodium salt and ascorbic acid phosphate ester magnesium salt, and ascorbic acid. Ascorbic acid fatty acid ester such as tetraisopalmitic acid ester, ascorbic acid alkyl ether such as ethyl ether ascorbic acid, ascorbic acid glucoside such as ascorbic acid-2-glucoside and its fatty acid esters, ascorbic acid sulfate ester, tocopheryl ascorbyl phosphate Ascorbic acid derivatives such as ... Ascorbic acid is preferred.

Examples of vitamins and derivatives thereof include vitamin A such as retinol, retinol acetate, and retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxin hydrochloride, pyridoxin dioctanoate, pyridoxin dipalmitate, etc. Vitamin B group such as flavin adenin dinucleotide, cyanocobalamine, folic acid, nicotinic acid such as nicotinic acid amide / benzyl nicotinate, choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; α, Vitamin E such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphate ester salt such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate ester magnesium salt, tetra ascorbic acid Ascorbic acid fatty acid ester such as isoparmic acid ester, ascorbic stearate, ascorbic palmitate, ascorbic dipalmitate, alkyl ether ascorbic acid such as ethyl ether ascorbic acid, ascorbic acid glucoside such as -2-glucoside ascorbic acid and its fatty acid ester , Ascorbic acid derivatives such as tocopheryl ascorbic acid; tocopherol nicotinate, tocopherol acetate, tocopherol linoleate, tocopherol ferulate, tocopherol derivatives such as tocopherol phosphate, and other vitamin derivatives, tocotrienol, and other various vitamin derivatives are preferable. Is listed as.

Anti-inflammatory and anti-inflammatory agents include glycyrrhizinic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokithiol, guaiazulene, allantin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract. , Plant extracts such as Honoha extract are preferred. As hair growth agents, blood circulation promoters, and stimulants, plant extracts and tinctures such as senburi extract, togarashi tincture, ginger tincture, ginger extract, and cantarist tincture; , Borneol, cyclanderate, cinnaridine, trazoline, acetylcholine, verapamil, cepharanthin, γ-orizanol, cepharanthin, vitamin E and derivatives such as tocopherol nicotinate / tocopherol acetate, γ-orizanol, nicotinic acid and nicotinic acid amide / benzyl nicotinate. Derivatives such as ester inositol hexanicotinate and nicotine alcohol, allantin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, flavanonol derivative, stigmasterol or stigmasterol and its glycoside, minoxidil are preferable. Is listed as. As the hormones, estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like are preferable. Other medicinal agents such as anti-wrinkle agents, anti-aging agents, tightening agents, cold sensitizers, warming agents, wound healing promoters, stimulant relievers, analgesics, cell activators, etc. include retinols, retinoic acids, retinoins. Tocopheryl acid; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and its glycosides / esterified products, hydroxycapric acid, long-chain α-hydroxy fatty acid, long-chain α-hydroxy fatty acid cholesteryl and other α- or β-Hydroxy acids and their derivatives; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosin; creatin; ceramides, spingosins; caffeine, xanthin and its derivatives; coenzyme Q10, carotene, lycopene , Astaxanthin, lutein, α-lipoic acid, platinum nanocolloids, fullerene and other antioxidants and active oxygen scavengers; catechins; quercetin and other flavones; isoflavones; Polyphenols such as anthocyanidin, chlorogenic acid, apple polyphenols; derivatives such as rutin and glycosides; derivatives such as hesperidin and glycosides; lignan glycosides; Glycoside, gingerol; fragrance substances such as menthol, camphor, sedrol and derivatives thereof; capsaicin, vanillin and derivatives; insect repellents such as diethyl toluamide; complexes of physiologically active substances and cyclodextrins are preferred. Can be mentioned.

Plant / animal / microbial extracts include iris extract, acitaba extract, asunaro extract, asparagus extract, avocado extract, flaxseed extract, almond extract, altea extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, ginkgo extract. , Inchikou extract, Uikyo extract, Ukon extract, Woolong tea extract, Uwaurushi extract, Agetsu extract, Echinashi leaf extract, Enmeisou extract, Ogon extract, Oubaku extract, Ouren extract, Omugi extract, Otanenjinjin extract, Otogirisou extract, Odori kosou extract, Ononis extract , Dutch mustard extract, orange extract, dried seawater, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolyzed silk, cucumber extract, chamomile extract, oil-soluble chamomile extract, carrot extract, kawarayomogi Extract, crow wheat extract, calcade extract, kanzo extract, oil-soluble kanzo extract, kiwi extract, kiou extract, kikurage extract, kina extract, cucumber extract, kiri leaf extract, guanosine, guava extract, kujin extract, cutinashi extract, kumazasa extract, clara extract, walnut Extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, quail extract, gentiana extract, gennoshouko extract, tea extract, yeast extract, koboku extract, coffee extract, gobo extract, rice extract, rice Fermented extract, fermented rice bran extract, rice germ oil, comfrey extract, collagen, moss peach extract, saishin extract, psycho extract, saitai extract, saffron extract, salvia extract, sabonsou extract, sasa extract, sanzashi extract, sansha extract, sansho Extract, Shiitake extract, Jio extract, Shikon extract, Shiso extract, Shinanoki extract, Shimotsukesou extract, Jatoba extract, Shakuyaku extract, Shokyu extract, Shobu root extract, Shirakaba extract, White chrysanthemum extract, Sugina extract, Stevia extract, Stevia fermented product, Nishikawayanagi extract, Seiyoukizuta extract, Seiyousanzashi extract, Seiyouniwatoko extract, Seiyounokogirisou extract, Seiyouhakka extract, Sage extract, Zeniaoi extract, Senkyu extract, Senburi extract, Souhakuhi extract, Daiou extract, Dai Zu extract, Taisou extract, Thyme extract, Dandelion extract, Local clothing extract, Tea extract, Chouji extract, Chigaya extract, Chinpi extract, Tea tree oil, Jincha extract, Togarashi extract, Touki extract, Tokinsenka extract, Tounin extract, Tohi extract, Dokudami extract, Tomato Extract, Natto extract, Carrot extract, Carrot extract, Novara extract, Hibiscus extract, Bakumondou extract, Hass extract, Parsley extract, Birch extract, Honey, Hamamelis extract, Paris etalia extract, Hikiokoshi extract, Bisaborol, Hinoki extract, Bifizus bacterium extract, Biwa extract, Fukitanpopo extract, Fukinotou extract, Bukuryo extract, Butcher bloom extract, Grape extract, Grape seed extract, Propolis, Hechima extract, Benibana extract, Peppermint extract, Bodaiju extract, Button extract, Hop extract, Maikaika extract, Pine extract, Maronie extract , Mizubasho extract, Mukuroji extract, Melissa extract, Mozuku extract, Peach extract, Yagurumagiku extract, Eucalyptus extract, Yukinoshita extract, Yuzu extract, Yuri extract, Yokuinin extract, Yomogi extract, Lavender extract, Green tea extract, Eggshell membrane extract, Apple extract, Louis Boss tea extract , Reishi extract, lettuce extract, lemon extract, lotus extract, lotus extract, rose extract, rosemary extract, roman chamomile extract, royal jelly extract, crackle extract and the like are preferable.

Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, and pyridoxine. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, zinc paraphenol sulfonate and the like. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum / potassium sulfate, tannic acid and the like. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease and the like. Preferred examples of nucleic acids include ribonucleic acid and a salt thereof, deoxyribonucleic acid and a salt thereof, and disodium adenosine triphosphate.

As fragrances, acetylsedrene, amylcinnamaldehyde, allylamylglycolate, β-ionone, isoe super, isobutylquinolin, iris oil, iron, indol, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragor, Eugenol, Oak Moss, Opoponax Resinoid, Orange Oil, Eugenol, Oranthiol, Galaxolid, Carbachlor, L-Carbon, Kamfer, Cannon, Carrot Seed Oil, Clove Oil, Methyl Cylate, Geraniol, Geranyl nitrile , Isobornyl acetate, Geranyl acetate, Dimethylbenzylcarbinate acetate, Styralyl acetate, Cedril acetate, Telepinel acetate, pt-butylcyclohexyl acetate, Vetiberyl acetate, benzyl acetate, Linaryl acetate, Isopentyl salicylate, benzyl salicylate, Sandalwood oil, Santa roll, Cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citroneral, cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylux Reginoid, Cedarwood Oil, Sedren, Sedrol, Celori Seed Oil, Thyme Oil, Damascon, Damasenon, Timor, Tuberose Absolute, Decanal, Decalactone, Terpineol, γ-Terpinen, Triplar, Nerol, Nonanar, 2,6-Nonadienor, Nonalactone, Pachori Alcohol, vanilla absolute, vanillin, basil oil, patcholi oil, hydroxycitroneral, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitgrain oil, hexylcinnamaldehyde, cis-3-hexenol, peruvian balsam, vetiver oil, vetiverol , Peppermint oil, pepper oil, heliotropin, bergamot oil, benzylbenzoate, borneol, milresinoid, muskketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-menton, eucalyptus oil, β-yonone, lime oil , Lavender oil, D-limonen, linalol, lylar, lilial, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, synthetic fragrances such as various essential oils and natural Fragrances and various blended fragrances are preferred.

Dyes / colorants / dyes / pigments include brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, and blue 204. , Blue 205, Blue 403, Blue 404, Green 3, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1, Red 105-1, Red 106, Red 2, Red 3, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206, Red 207 , Red 208, Red 213, Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230-1, Red 230-2, Red 231, Red 232, Red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503 , Red 504, Red 505, Red 506, Orange 201, Orange 203, Orange 204, Orange 205, Orange 206, Orange 207, Orange 401, Orange 402, Orange 403, Yellow 201, Yellow 202-1, Yellow 202-2, Yellow 203, Yellow 204, Yellow 205, Yellow 4, Yellow 401, Yellow 402, Yellow 403-1, Yellow 404, Yellow Legal dyes such as 405, Yellow 406, Yellow 407, Yellow 5; Other acidic dyes such as Acid Red 14; Basic dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow; HC Yellow 2, HC Yellow 5, HC Red 3, 4-hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine, HC Blue 2, Basic Blue 26 and other nitro dyes; Disperse dyes; Inorganic white pigments such as titanium dioxide and zinc oxide; Inorganic red pigments such as iron oxide (Bengala) and iron titanate; Inorganic brown pigments such as γ-iron oxide; Inorganic yellow such as yellow iron oxide and yellow clay System pigments: Inorganic black pigments such as black iron oxide and low-order titanium oxide; Inorganic substances such as mango violet and cobalt violet Purple pigments; Inorganic green pigments such as chromium oxide, chromium hydroxide, cobalt titanate; Inorganic blue pigments such as ultramarine and dark blue; Titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored oxidation Pearl pigments such as titanium coated mica, bismuth oxychloride, fish scale foil; metal powder pigments such as aluminum powder, copper powder, and gold; anthracinones such as astaxanthin and alizarin, anthocyanidins, β-carotene, catenal, capsantin, calcon, calsamine, Naftquinones such as quercetin, crosin, chlorophyll, curcumin, cochineal, and ciconin, bixins, flavones, betacyanidine, henna, hemoglobin, lycopene, riboflavin, natural pigments and dyes such as rutin; p-phenylenediamine, toluene-2,5 -Intermediate oxidation dyes such as diamine, o-, m-, or p-aminophenol, m-phenylenediamine, 5-amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine and salts thereof. Body and couplers; auto-oxidizing dyes such as indolin; dihydroxyacetones are preferred.

As the water, in addition to normal water and purified water, hard water, soft water, natural water, deep ocean water, electrolytic alkaline ionized water, electrolytically acidic ionized water, ionized water, and cluster water are preferable.

In addition to these, cosmetic raw material standards, compounding ingredient standards by cosmetic type, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), pharmaceutical non-pharmaceutical raw material standards, Japanese Pharmacy, pharmaceutical additives Ingredients described in standards, official food additive official documents, etc., and Japanese and foreign patent gazettes and patent publication gazettes (including publication gazettes and republications) whose international patent classification IPC belongs to the classification of A61K7 and A61K8 It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the described ingredients, in known combinations, blending ratios, and blending amounts.

The types of hair cosmetics of the present invention will be described in more detail. Shampoos such as oil shampoos, cream shampoos, conditioning shampoos, indulgence shampoos, hair coloring shampoos, and rinse-integrated shampoos; rinses, treatments, hair packs, hair foams, etc. , Hair mousse, hair spray, hair mist, hair wax, hair gel, water grease, set lotion, color lotion, hair tonic, hair liquid, pomade, tic, hair cream, hair blow, split hair coat, hair oil, permanent wave agent, straight perm Agents, oxidative hair dyes, hair bleaches, hair color pretreatments, hair color aftertreatments, perma pretreatments, perma aftertreatments, hair manicures, and hair restorers are preferred.

The hair cosmetic formulation of the present invention includes emulsified cosmetics such as oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, and O / W / O type. , Oil-based cosmetics, solid cosmetics, liquid cosmetics, paste-like cosmetics, stick-like cosmetics, volatile oil-type cosmetics, powder-like cosmetics, jelly-like cosmetics, gel-like cosmetics, paste-like cosmetics, Formulation types such as emulsified polymer type cosmetics, sheet-like cosmetics, mist-like cosmetics, and spray-type cosmetics are preferable.

Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to these Examples.

Synthesis example 1
50.0 g (0.176 mol) of stearic acid (octadecanoic acid), 42.2 g (0.422 mol) of 90% L-lactic acid, 48% in a 300 mL reactor equipped with a stirrer, thermometer and gas introduction tube. 8.8 g (0.105 mol) of an aqueous sodium hydroxide solution was charged, and the reaction was carried out at 190 ° C. for 1 hour in a nitrogen atmosphere while distilling off the produced water to obtain a reaction product as a pale yellow solid.

Synthesis example 2
40.0 g (0.141 mol) of stearic acid (octadecanoic acid), 38.0 g (0.380 mol) of 90% L-lactic acid, 48% in a 300 mL reactor equipped with a stirrer, thermometer and gas introduction tube. 11.7 g (0.141 mol) of an aqueous sodium hydroxide solution was charged, and the reaction was carried out at 190 ° C. for 1 hour in a nitrogen atmosphere while distilling off the produced water to obtain a reaction product as a pale yellow solid.

Synthesis example 3
30.0 g (0.1 mol) of stearic acid (octadecanoic acid), 60.0 g (0.6 mol) of 90% L-lactic acid, 48% in a 300 mL reactor equipped with a stirrer, thermometer and gas introduction tube. 8.3 g (0.1 mol) of an aqueous sodium hydroxide solution was charged, and the reaction was carried out at 190 ° C. for 1 hour in a nitrogen atmosphere while distilling off the produced water to obtain a reaction product as a pale yellow solid.

Synthesis example 4
50.0 g (0.176 mol) of stearic acid (octadecanoic acid) and 42.2 g (0.422 mol) of 90% L-lactic acid were charged into a 300 mL reactor equipped with a stirrer, a thermometer and a gas introduction tube. While distilling off the produced water, the reaction was carried out at 190 ° C. for 1 hour in a nitrogen atmosphere to obtain a reaction product as a pale yellow solid.

Synthesis example 5
45.0 g (0.132 mol) of behenic acid (docosanoic acid), 35.7 g (0.357 mol) of 90% L-lactic acid, 48% in a 300 mL reactor equipped with a stirrer, thermometer and gas introduction tube. 11.0 g (0.132 mol) of an aqueous sodium hydroxide solution was charged, and the reaction was carried out at 190 ° C. for 1 hour in a nitrogen atmosphere while distilling off the produced water to obtain a reaction product as a pale yellow solid.

Synthesis example 6
60.0 g (0.211 mol) of stearic acid (octadecanoic acid), 21.1 g (0.211 mol) of 90% L-lactic acid, 48% in a 300 mL reactor equipped with a stirrer, thermometer and gas introduction tube. 15.8 g (0.190 mol) of an aqueous sodium hydroxide solution was charged, and the reaction was carried out at 190 ° C. for 1 hour in a nitrogen atmosphere while distilling off the produced water to obtain a reaction product as a pale yellow solid.

Synthesis example 7
40.0 g (0.141 mol) of isostearic acid (mainly isostearic acid having a methyl branched structure) and 38.0 g (0) of 90% L-lactic acid in a 300 mL reactor equipped with a stirrer, a thermometer and a gas introduction tube. .380 mol), 11.7 g (0.141 mol) of 48% aqueous sodium hydroxide solution was charged, and the reaction was carried out at 190 ° C. for 1 hour in a nitrogen atmosphere while distilling off the water to be produced, and reacted as a pale yellow liquid substance. The product was obtained.

Synthesis example 8
40.0 g (0.141 mol) of isostearic acid (2-heptylundecanoic acid), 34.1 g (0.340 mol) of 90% L-lactic acid in a 300 mL reactor equipped with a stirrer, thermometer and gas introduction tube. , 11.7 g (0.141 mol) of a 48% aqueous sodium hydroxide solution was charged, and the reaction product was obtained as a pale yellow liquid by reacting at 190 ° C. for 1 hour in a nitrogen atmosphere while distilling off the produced water. rice field.

Synthesis example 9
40.0 g (0.141 mol) of isostearic acid (2-isoheptylisoundecanoic acid), 34.1 g (0.340 mol) of 90% L-lactic acid in a 300 mL reactor equipped with a stirrer, thermometer and gas introduction tube. 11.7 g (0.141 mol) of a 48% aqueous sodium hydroxide solution was charged, and the reaction product was reacted at 190 ° C. for 1 hour in a nitrogen atmosphere while distilling off the water to be produced, and the reaction product was formed as a pale yellow liquid. Got

Synthesis example 10
40.0 g (0.133 mol) of 12-hydroxystearic acid, 36.0 g (0.359 mol) of 90% L-lactic acid, 48% water in a 300 mL reactor equipped with a stirrer, thermometer and gas inlet tube. 11.1 g (0.133 mol) of an aqueous sodium oxide solution was charged, and the reaction was carried out at 190 ° C. for 1 hour in a nitrogen atmosphere while distilling off the produced water to obtain a reaction product as a pale yellow solid.

Synthesis example 11
In a 300 mL reactor equipped with a stirrer, thermometer, and gas introduction tube, 50.0 g (0.134 mol), 90% L- 32.1 g (0.321 mol) of lactic acid and 11.1 g (0.134 mol) of a 48% aqueous sodium hydroxide solution were charged, and while distilling off the produced water, the reaction was carried out at 190 ° C. for 1 hour in a nitrogen atmosphere, and yellow. The reaction product was obtained as a brown soft solid.

After the reaction products of Synthesis Examples 1 to 9 were subjected to trimethylsilylation treatment, gas chromatography (GC) measurement was performed under the following conditions, and the results obtained showed that the general formula (1) contained in the reaction products was obtained. The range of the degree of polymerization of lactic acid of the compound of) and the average degree of polymerization of lactic acid were calculated. The results obtained are shown in Table 1.

<GC analysis conditions>
Equipment: GC-2014 (Shimadzu Corporation)
Column: CP-SimDist UltimeMetal (inner diameter 0.53 mm, film thickness 0.53 μm, length 10 m, manufactured by Agilent)
Carrier gas: He (linear velocity 114.4 cm / s)
Detector: Hydrogen flame ion detector Detector temperature: 380 ° C
Injection temperature: 380 ° C
Measurement conditions: 60 ° C → 10 ° C / min → 380 ° C (8 min)

From the results in Table 1, the compounds of the general formula (1) contained in the reaction products of Synthesis Examples 1 to 9 had a degree of polymerization of lactic acid in the range of 1 to 10 and an average degree of polymerization of lactic acid of 1.0. It was in the range of ~ 6.0.

<Evaluation of hair improvement effect 1>
Diluted solutions of the reaction products of Synthesis Examples 1, 7 and 11 were prepared with the compositions shown in Table 2 (Examples 1 to 3). For comparison, a diluted solution containing no compound of the present invention was prepared (Comparative Example 1). These were applied to hair and the effect of improving damaged hair was evaluated. The test method was as follows. The results are shown in Table 3.

(Test method)
Healthy black hair was bleached once with a commercially available two-agent bleaching agent to prepare a bundle of damaged hair. Next, 4 g of the damaged hair bundle was immersed in 1.6 g of the diluted solution of Example 1 and uniformly applied, and then air-dried to obtain a hair bundle A1 (application only). A part of the hair bundle A1 was heat-treated twice at 140 ° C. for 15 seconds with a hair iron to obtain hair bundle B1 (after heat treatment). A part of the hair bundle B1 was further washed with a 3% aqueous solution of sodium laureth sulfate, washed with water 5 times, and then air-dried to obtain a hair bundle C1 (after washing the hair). Similarly, the diluent of Example 2 is used for hair bundles A2 to C2, the diluent of Example 3 is used for hair bundles A3 to A3, and the diluent of Comparative Example 1 is used for hair bundles A4 to C2. C4 was prepared. The hair improvement effect was evaluated by sensory evaluation (7 panelists) for each of the prepared hair bundles. The evaluation was performed by comparing 6 points of smoothness, finger passage, moistness, firmness, flexibility, and cohesiveness with untreated hair bundles (damaged hair).

From the results in Table 3, the compound of the general formula (1) of the present invention was blended, whereas the comparative example 1 in which the compound of the general formula (1) of the present invention was not blended had almost no damage improving effect. In Examples 1 to 3, the feel of the hair was greatly improved, and the effect was further improved by applying the heat treatment. Further, for the heat-treated hair bundle, the hair improving effect is maintained even if the hair is repeatedly washed with a 3% aqueous solution of sodium laureth sulfate, and the effect can be maintained for a long period of time by the method of the present invention. Do you get it.

<Evaluation of hair improvement effect 2>
A hair conditioner containing the reaction products of Synthesis Examples 1 to 11 with the compositions shown in Tables 4 and 5 was prepared. In addition, as a control, a hair conditioner containing no reaction product was prepared. The obtained hair conditioner was evaluated for its hair improving effect by the following method. The results are also shown in Tables 4 and 5.

<Evaluation method>
Healthy black hair was bleached once with a commercially available two-agent bleaching agent to prepare 5 g of damaged hair bundles. 0.5 g of each hair conditioner was applied to the prepared hair bundle, left for 2 minutes, rinsed under running water for 30 seconds, towel-dried, and then heat-treated twice at 140 ° C. for 15 seconds with a hair iron. The obtained hair bundle was evaluated for hair improvement effect by sensory evaluation (7 panelists). The evaluation was performed by comparing with a control containing no compound of the present invention. In addition, the obtained hair bundle was washed with a 3% aqueous solution of sodium laureth sulfate and washed with water, and the sustainability of the effect was evaluated from the changes before and after washing the hair.

From the results of Tables 4 and 5, the hair treated by the method of the present invention using the hair conditioner containing the compound of the general formula (1) of the present invention has a significantly improved feel as compared with the control, and the hair is washed. However, the effect was sustained.

Example 15 Hair mist compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Reaction product of Synthesis Example 1 0.1
Reaction product of Synthesis Example 7 0.1
Neosolue-DiSM (Nippon Fine Chemical Co., Ltd.) 0.1
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.1
Caprilyl glugoside 0.15
Dimethicone 0.1
Setrimonium chloride (30%) 6.0
EDTA-4Na 0.1
Ethanol 8.0
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Each component was uniformly stirred and mixed.

Example 16 Hair essence compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Reaction product of Synthesis Example 1 0.1
Reaction product of Synthesis Example 7 0.1
Neosolue-DiSM (Nippon Fine Chemical Co., Ltd.) 0.2
Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 1.0
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.5
Cetanol 1.0
Stealtrimonium chloride (63%) 0.8
Dicocodimonium chloride (75%) 2.8
Solves Tetraoleate-60 1.0
PEG-40 hydrogenated castor oil 0.2
Part B Methylparaben 0.1
Etidronic acid 0.1
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 80 ° C. to dissolve it. Part B was placed in another container and heated to about 80 ° C. to dissolve it. Part B was gradually added to part A and mixed uniformly.

Example 17 Hair lotion compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Reaction product of Synthesis Example 1 0.2
Reaction product of Synthesis Example 7 0.2
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.2
PEG-4 3.0
Menthol 0.05
Ethanol 50.0
Part B Pyridoxine HCl 0.1
Glycyrrhizinate 2K 0.1
Licorice extract 0.05
BG 3.0
Ascorbic acid 0.2
Panthenol 2.0
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A Each component is mixed (Part A). Part B Each component is mixed (Part B). Add part B to part A and mix evenly.

Example 18 Sleeping habit correction compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Reaction product of Synthesis Example 1 0.2
Reaction product of Synthesis Example 7 0.5
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.5
N-Methylpyrrolidone 2.0
Glycerin 2.0
Pentylene glycol 2.0
Behentrimonium chloride (80%) 0.6
Ethanol 20.0
Phytic acid 0.1
Dimethicone Propyl PG Betaine 1.0
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Dissolve all ingredients uniformly.

Example 19 Hair cream compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Reaction product of Synthesis Example 1 5.0
Reaction product of Synthesis Example 7 5.0
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 2.0
Cetanol 4.0
Dimethicone (500cs) 5.0
Dimethicone (100,000 cs) 1.0
Glyceryl stearate 2.8
Oles-10 Phosphate 0.8
Glyceryl stearate (SE) 1.6
Part B 1,3-propanediol 10.0
Phenoxyethanol 0.4
Methylparaben 0.2
10% NaOH 0.6
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was added to another container and heated to about 80 ° C. to dissolve it. Part B was added to part A, and the mixture was stirred and mixed.

Example 20 Hair wax compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Reaction product of Synthesis Example 1 2.0
Reaction product of Synthesis Example 7 3.0
Microcrystalline wax 10.0
Triethylhexanoin 5.0
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 1.0
Candelilla Row 6.0
Ercolano LH (Nippon Fine Chemical Co., Ltd.) 5.0
Hydroxystearic acid 4.0
Glyceryl stearate (Leodor MS-60) 1.0
Glyceryl stearate (Nikkor MGS-BSE) 1.0
Behenes-2 4.0
Behenes-20 10.0
Phenoxyethanol 0.6
Methylparaben 0.2
BG 3.0
Part B PEG-90M 0.2
Amount of purified water totaling 100 Part C Citric acid (1%) Appropriate amount Na citrate (1%) Appropriate amount ------------- −−−−−−−−−−−−
(Preparation method)
Take parts A and B, respectively, heat to about 80 ° C, and mix uniformly. Part B is gradually added to part A with stirring, mixed uniformly, and then cooled (part D). Add part C to part D to adjust the pH to 6.

Example 21 Hair spray compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Undiluted solution prescription)
Part A Reaction product of Synthesis Example 1 0.5
Reaction product of Synthesis Example 7 1.5
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 2.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 1.0
LUSPLAN DA-R (Nippon Fine Chemical Co., Ltd.) 2.0
Part B PEG hydrogenated castor oil 0.02
Part C fragrance 0.05
Ethanol (anhydrous) A total amount of 100 (filling prescription)
Undiluted solution 55.0
LPG 45.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B is added to part A (part D). Part C was added to and mixed with part D, and the stock solution was filled in a can and then filled with gas.

Example 22 Shampoo compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Reaction product of Synthesis Example 1 0.2
Reaction product of Synthesis Example 7 0.5
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.2
Cocoyl Glutamic Acid TEA (30%) 50.0
Lauroyl sarcosine Na (30%) 10.0
Na tetradecene sulfonate (36%) 15.0
PEG-150 5.0 distearate
Methylparaben 0.2
Phenoxyethanol 0.5
Propylene glycol 1.0
Inulin-SC (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 1.5
Part B cationized guar gum 0.2
Amount of purified water totaling 100 Part C Phosphoric acid (10%) Appropriate amount −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− −−−−−
(Preparation method)
Parts A and B were taken, heated to about 80 ° C., and mixed uniformly. Part A was added to part B, mixed uniformly, and then cooled (part D). Part C was added to part D to adjust the pH to 6-6.5.

Example 23 Rinse-in shampoo compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Reaction product of Synthesis Example 1 0.5
Reaction product of Synthesis Example 7 0.5
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.5
Cocamidopropyl Betaine (30%) 20.0
Sodium Lauryl Sulfate TEA (40%) 15.0
Cocamide DEA 2.0
Cocoyl Glutamic Acid TEA (30%) 30.0
Ethylene glycol distearate 1.2
Polyquaternium-10 1.6
Stearyltrimonium bromide (70%) 0.6
Phenoxyethanol 0.2
Part B Methylparaben 0.2
Na benzoate 0.4
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A and B were taken, heated to about 80 ° C., and mixed uniformly. Part A was added to part B, mixed uniformly, and then cooled.

Example 24 Shampoo for hair color compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Reaction product of Synthesis Example 1 0.3
Reaction product of Synthesis Example 7 0.3
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.5
Cocoyl methyl taurine Na (30%) 15.0
Olefin (C14-16) Na Sulfonate (36%) 13.0
Sodium cocoamphoacetate (30%) 8.0
PPG-12-PEG-50 lanolin 2.5
Cocoyl glutamic acid (30%) 7.0
Polyquaternium-10 1.0
Lauramide propyl hydroxysultaine / water 4.0
PEG-20 hydrogenated castor oil 2.0
Etidronic acid 0.2
PG 0.2
Benzyl alcohol 2.0
Methylparaben 0.2
Phenoxyethanol 0.2
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
All components were leveled, heated to 80 ° C., stirred uniformly, mixed and then cooled.

Example 25 Shampoo
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Reaction product of Synthesis Example 1 1.0
Reaction product of Synthesis Example 7 1.0
PPG-3 Caprylyl Ether 0.2
Ammonium Laureth Sulfate 5.0
Sodium Laureth Sulfate (25%) 10.0
Lauryl hydroxysultaine (30%) 10.0
Lauric acid K 1.0
Glycol distearate 0.5
Toluenesulfonic acid 0.3
Stearoxypropyl dimethylamine 0.5
PPG-17 0.3
Dimethicone (6cs) 0.1
PEG-9 Dimethicone 0.1
Amodimethicone 0.1
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.5
Neopentyl glycol diethylcaproate 0.4
Lanolin fatty acid 0.3
Isodecyl glyceryl ether 0.4
Cocamide MEA 1.0
Laureth-4 0.3
Laureth-16 0.2
Stairless-6 0.2
Phenoxyethanol 0.3
Part B Methylparaben 0.2
Na benzoate 0.3
Amount of purified water totaling 100 Part C NanoRepair-CMC (Nippon Fine Chemical Co., Ltd.) 5.0
Polyquaternium-10 0.2
Guar Hydroxypropyltrimonium Chloride 0.1
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 3.0
Purified water 6.7
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was uniformly mixed at about 80 ° C. Part B, which was set aside separately, was heated to about 60 ° C. to make it uniform. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part C was added and mixed uniformly.

Example 26 Rinse component compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Reaction product of Synthesis Example 1 2.0
Reaction product of Synthesis Example 7 2.0
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.5
Neosolue-DiSM (Nippon Fine Chemical Co., Ltd.) 0.5
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 0.5
Setrimonium chloride (30%) 5.2
Octyldodecanol 4.7
Cetanol 2.8
Stealtrimonium chloride (63%) 0.6
Diethylhexyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.3
Squalene 0.3
Myristyl Sulfate Na 0.2
Setes-40 0.1
Ores-5 0.1
Sodium cetyl sulfate 0.1
Part B citric acid 0.1
Gluconolactone 0.5
Polylysine 0.1
Polyaspartic acid 0.5
Methylparaben 0.1
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was heated to about 80 ° C. and dissolved. While stirring part B in part A, it was gradually added and mixed uniformly, stirred, and then rapidly cooled.

Example 27 Treatment compound content (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Reaction product of Synthesis Example 1 0.5
Reaction product of Synthesis Example 7 1.0
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.5
Behentrimonium chloride (80%) 2.4
Cetanol 5.2
Glyceryl stearate 1.2
Plandoll-DP (Nippon Fine Chemical Co., Ltd.) 0.2
LUSPLAN SR-DM4 (Nippon Fine Chemical Co., Ltd.) 0.4
Dimethicone 2.0
(Aminoethylaminopropylmethicone / dimethicone) copolymer
0.5
Part B 1,3-butylene glycol 5.0
Methylparaben 0.1
Propylparaben 0.1
Amount of purified water totaling 100 Part C Adenosine monophosphate (10%) Appropriate amount ------------- −−−−−
(Preparation method)
Parts A and B were taken, heated to about 80 ° C., and mixed uniformly. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled (part D). Part C was added to part D to adjust the pH to 5.2-5.7.

Example 28 Treatment compound content (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Reaction product of Synthesis Example 1 0.5
Reaction product of Synthesis Example 7 2.0
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.5
Propylene glycol 1.0
Stealtrimonium chloride (63%) 3.8
Stealtrimonium bromide (70%) 1.0
Setes-18 0.8
Oleyl alcohol 3.0
Cetanol 4.0
LUSPLAN DD-DA5 (Nippon Fine Chemical Co., Ltd.) 0.1
LUSPLAN DD-DHR (Nippon Fine Chemical Co., Ltd.) 0.3
Plandoll-ISS (Nippon Fine Chemical Co., Ltd.) 0.2
Dimethylaminopropylamide stearate 2.0
Part B Hydrolyzed Collagen 1.0
Appropriate amount of citric acid Amount of purified water totaling 100 -------------
(Preparation method)
Part A was heated to about 80 ° C. Part B was added to another container, and the mixture was heated and dissolved. Part A was gradually added to part B while stirring, mixed uniformly, stirred for 1 minute, and then rapidly cooled.

Example 29 Non-silicone hair treatment
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Reaction product of Synthesis Example 1 0.5
Reaction product of Synthesis Example 7 2.0
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.5
Neosolue-DiSM (Nippon Fine Chemical Co., Ltd.) 0.5
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.2
LUSPLAN DD-IS (Nippon Fine Chemical Co., Ltd.) 0.05
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 0.2
Propanediol 3.0
Behenamide propyl dimethylamine 1.5
Cetanol 2.2
Stearyl alcohol 0.8
Hydrogenated rapeseed oil alcohol 0.5
Neopentyl glycol diethylcaproate 0.8
Jojoba seed oil 1.0
Glyceryl stearate 0.4
Propylparaben 0.1
Cocamide MEA 0.8
Caesarpinia Spinosa Hydroxypropyltrimonium Chloride 0.1
Rice bran wax 0.5
Glycerin 1.0
Part B Methylparaben 0.1
Lactic acid 0.4
Amount of purified water totaling 100 Part C Methyl heptyl caprylate 1.0
PPG-3 Caprylyl Ether 1.0
Polyquaternium-7 0.15
Myristic acid PPG-3 benzyl ether 0.5
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was uniformly mixed at about 80 ° C. Part B, which was set aside separately, was heated to about 60 ° C. to make it uniform. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part C was added and mixed uniformly.

Example 30 Hair treatment that does not wash off Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Reaction product of Synthesis Example 1 0.5
Reaction product of Synthesis Example 7 0.5
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.5
Neosolue-DiSM (Nippon Fine Chemical Co., Ltd.) 0.2
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 2.0
LUSPLAN SR-DM4 (Nippon Fine Chemical Co., Ltd.) 0.1
Setrimonium chloride (25%) 3.8
Caprylyl glucoside (50%) 0.8
Glycerin 4.0
Phenoxyethanol 0.2
Part B Ethanol 20.0
Part C Polyquaternium-6 0.6
Polyquaternium-7 0.4
Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.05
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part C was heated to about 80 ° C. to dissolve it. Next, part A was heated to about 80 ° C. to dissolve it. Part C was added while stirring, and after mixing uniformly, the mixture was cooled to about 40 ° C. Then, part B was added and mixed uniformly.

Example 31 Leave-on treatment compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Reaction product of Synthesis Example 1 1.0
Reaction product of Synthesis Example 7 1.0
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-DiSM (Nippon Fine Chemical Co., Ltd.) 0.5
Isopropyl palmitate (Nippon Fine Chemical Co., Ltd.) 4.0
Plandoll-LG4 (Nippon Fine Chemical Co., Ltd.) 0.2
Cetanol 5.0
Isostearic acid 2.0
Stealtrimonium chloride (63%) 3.2
Behentrimonium chloride (80%) 1.0
Squalene 1.0
Sunflower seed extract 0.5
Glycerin 1.0
Part B Methylparaben 0.1
Inulin-SC (Nippon Fine Chemical Co., Ltd.) 1.0
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was heated to about 80 ° C. to dissolve it. Part B was gradually added to part A and mixed uniformly.

Example 32 Preperma liquid compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Reaction product of Synthesis Example 1 1.0
Reaction product of Synthesis Example 7 2.0
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 1.0
4-ethoxymethyl-1,3-dioxolane-2-one 1.0
Ercolano CA-NH (Nippon Fine Chemical Co., Ltd.) 0.8
Caprylyl glucoside (50%) 1.0
Appropriate amount of citric acid Appropriate amount of Na citrate Methylparaben 0.2
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Dissolve each component uniformly.

Example 33 Hair oil compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Reaction product of Synthesis Example 7 1.0
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.5
Dimethicone (30 million cps) 5.0
Dimethicone (4 million cps) 5.0
Ethanol 20.0
Olive oil 1.0
Shea fat oil 1.0
Plandoll-S (Nippon Fine Chemical Co., Ltd.) 1.0
Tri (caprylic acid / capric acid) glyceryl (Nippon Fine Chemical Co., Ltd.) 1.0
Dimethiconol 1.0
Tocopherol 0.05
Cyclopentasiloxane Amount totaling 100 -------------
(Preparation method)
Each component was uniformly stirred and mixed.

In the above formulation, the details of the ingredients described by the product names are as follows.

〇LUSPLAN DD-IS: Dimersylinorail diisostearate 〇LUSPLAN DD-DHR: Dymeridlinoleyl hydrogenated rosin condensate 〇LUSPLAN DD-DA5: Dymerdilinoleic acid Dymalidrinoleyl 〇LUSPLAN SR-DM4: Dymerdilinol Acid dimerge linoleyl, tri (caprylic acid / capric acid) glyceryl ○ LUSPLAN DA-R: dimerge linoleic acid dimarie linoleyl, hydrogenated triglyceryl rosinate 〇Inulin-SC: inulin 〇NanoRepair-CMC: quaternium-18 , Quotanium-33, Cholesterol, Ceramide 2, Ceramide 3, Ceramide 6, PG-Containing Composition 〇 Neosolue-Aqualio: Cyclohexanedicarboxylic Acid Bisethoxydiglycol 〇 Neosolue-AquaS: (Eicosandioic Acid / Tetradecanedic Acid) Polyglyceryl-10, Glycerin 〇 Neosolue-DiSM: Diisostearyl malate 〇Plandol-H: Dimarylinolic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
〇Plandol-S: Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
〇Plandol-G: Dimer dilinoleyl bis (behenyl / isostearyl / phytosteryl)
〇Plandol-DP: Bisdiglyceryl polyacyl adipate-2
〇Plandol-ISS: Phytosteryl isostearate 〇Plandol-MAS: Macadamia nut oil fatty acid phytosteryl 〇Plandol-LG2: Di (phytosteryl / octyldodecyl) lauroyl glutamate
〇Plandol-LG4: Di-lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
〇 Tremoist-TP: Snow fungus polysaccharide 〇 Tremoist-SL: Snow fungus polysaccharide aqueous solution (1%)
〇Ecolano LH: Ranorinrou 〇Ecolano CA-NH: Quotanium-33, BG

Claims (5)

A method for improving hair, which comprises applying a compound represented by the following general formula (1) or a salt thereof to hair and performing heat treatment.

(In the formula, R1 represents a residue of a higher fatty acid having 8 to 33 carbon atoms having a saturated or unsaturated hydrocarbon chain of a linear or branched chain which may have a hydroxyl group. N represents the degree of polymerization of lactic acid. Indicates an integer of 1 to 10.) The method according to claim 1, wherein the heat treatment is performed at 60 to 220 ° C. R1 of the general formula (1) is dodecanoic acid, tetradecanoic acid, hexadecanoic acid, octadecanoic acid, icosanoic acid, docosanoic acid, 2-hexyldecanoic acid, isostearic acid, 2-octyldodecanoic acid, oleic acid, 12-hydroxystearic acid and The method according to claim 1 or 2, wherein the residue is a higher fatty acid selected from lanolin fatty acids. The method according to any one of claims 1 to 3, wherein the average degree of polymerization of lactic acid of the general formula (1) is 1.0 to 6.0. A hair cosmetic containing a compound represented by the general formula (1) or a salt thereof, which is used in the method according to any one of claims 1 to 4.