JP2009062538A - 熱伝達媒体及びこれを利用した熱伝達方法 - Google Patents
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Abstract
【解決手段】具体的に熱伝達媒体は、複数個のナノ粒子含有膜を含み、ナノ粒子が、膜に対して入射する光を吸収することで対象体に熱を伝達する。また、このような熱伝達媒体を利用した熱伝達方法は、複数個のナノ粒子を含むナノ粒子含有膜を形成する段階と、前記膜を光に露出させる段階と、及び前記ナノ粒子が入射された光を吸収することにより熱が生成され、この熱を対象体に伝達する段階とを含む。このとき、複数個のナノ粒子含有膜は、対象体に直接塗布してよく、中間層上に塗布してもよい。また、複数個のナノ粒子含有膜は、透明フィルム上に塗布し、これを対象体上に位置してマスクのように使用してもよい。
【選択図】図1
Description
2.5 ×10−4 M HAuCl4及び2.5 ×10−4M tri−sodium citrateを含む20mlの水溶液(aqueous solution)を円錐状(conical)のフラスコ内に用意した。次に、0.6mlのアイスコールド0.1 M NaBH4溶液(0.6 ml of ice cold 0.1 M NaBH4 solution)を前記水溶液に攪拌しながら一度に全て添加した。この溶液はNaBH4添加直後ピンク色に変わりながら粒子形成が現れた。この溶液中の粒子達は製造後2−5時間内にシード(Seed)として使用した。
上記製造したよく分散されたロッド状のAuナノ粒子水溶液を室温〜50℃の間の温度でドロップキャスティング(drop casting)し膜を形成した。この際、当該Auナノ粒子を含有する膜の厚さは500nmであった(膜の厚さは約100nm〜数百マイクロンに当たり、この厚さを調整可能である)。
11、51、61:ナノ粒子含有膜
52、62:プラスチック基板
53:二酸化チタン(TiO2)ペースト
63:有機物またはその他の物質がコーティングされた熱処理を必要とする部分
Claims (25)
- 対象体に熱を伝達する熱伝達媒体において、
複数個のナノ粒子を有するナノ粒子含有膜を含み、
前記ナノ粒子は、前記ナノ粒子含有膜に対して入射する光を吸収するものであり、かつ前記膜は光を吸収することにより発生する熱を前記対象体に伝達するものである、熱伝達媒体。 - 前記ナノ粒子含有膜は、前記対象体に直接形成される、請求項1に記載の熱伝達媒体。
- 前記ナノ粒子含有膜は、前記熱伝達後エッチングにより前記対象体から除去される、請求項2に記載の熱伝達媒体。
- 前記ナノ粒子含有膜は、前記対象体上の中間層に形成される、請求項1〜3のいずれか1項に記載の熱伝達媒体。
- 前記ナノ粒子含有膜は赤外線(IR)透明フィルム上に位置する、請求項1〜4のいずれか1項に記載の熱伝達媒体。
- 前記ナノ粒子は、Au、Cu、Ag、Ti、Al、Pd、Pt、Rh、Ir、Fe、W、およびNiからなる群から選択される少なくとも一つまたはこれらを混合して使用する、請求項1〜5のいずれか1項に記載の熱伝達媒体。
- 前記ナノ粒子含有膜は一定のパターンで配置され、前記パターンに対応する所定の位置に熱を伝達する請求項1〜6のいずれか1項に記載の熱伝達媒体。
- 特定波状において最大の吸光度を示すように、入射する光の波長により前記ナノ粒子の粒径を調節することにより前記熱伝達を制御する、請求項1〜7のいずれか1項に記載の熱伝達媒体。
- 前記ナノ粒子含有膜に対して入射する光は、可視光線領域または近赤外線領域の光である請求項1〜8のいずれか1項に記載の熱伝達媒体。
- 前記ナノ粒子含有膜は、プラスチック基板またはガラス基板上に位置するものであり、
プラスチック基板またはガラス基板に形成される前記ナノ粒子含有膜の焼きなまし(アニーリング)工程に前記熱伝達媒体が使用される請求項1〜9のいずれか1項に記載の熱伝達媒体。 - 前記プラスチック基板またはガラス基板に塗布されるナノ粒子含有膜は、有機物、金属、炭素、または無機物を含む請求項10に記載の熱伝達媒体。
- 前記プラスチック基板は、二酸化チタン(TiO2)ペーストをコーティングしたプラスチック基板である請求項10または11に記載の熱伝達媒体。
- 請求項1に記載の熱伝達媒体を使用する熱伝達方法。
- 対象体に熱を伝達する方法であって、
複数個のナノ粒子を含むナノ粒子含有膜を形成する段階と、
前記ナノ粒子含有膜を光に露出させる段階、及び
入射された光を前記ナノ粒子が吸収することにより熱が生成され、当該熱を対象体に伝達する段階と、を含む熱伝達方法。 - 前記ナノ粒子含有膜を形成する段階において、前記ナノ粒子含有膜を前記対象体に直接形成する請求項14に記載の熱伝達方法。
- 前記熱伝達する段階後、前記ナノ粒子含有膜をエッチングにより前記対象体から除去する請求項15に記載の熱伝達方法。
- 前記ナノ粒子含有膜形成段階において、前記ナノ粒子含有膜を前記対象体上の中間層に形成する請求項14〜16のいずれか1項に記載の熱伝達方法。
- 前記ナノ粒子含有膜形成段階において、前記ナノ粒子含有膜を赤外線(IR)透明フィルム上に位置させる請求項14〜17のいずれか1項に記載の熱伝達方法。
- 前記ナノ粒子含有膜形成段階において、前記ナノ粒子は、Au、Cu、Ag、Ti、Al、Pd、Pt、Rh、Ir、Fe、W、およびNiからなる群から選択される少なくとも一つまたはこれらを混合して使用する請求項14〜18のいずれか1項に記載の熱伝達方法。
- 前記ナノ粒子含有膜形成段階において、所定のパターンに対応する所定の位置に熱を伝達するよう前記ナノ粒子含有膜を前記所定パターンに配置する請求項14〜19のいずれか1項に記載の熱伝達方法。
- 特定波状において最大の吸光度を示すように、前記ナノ粒子の粒径を調節することにより前記熱伝達を制御する請求項14〜20のいずれか1項に記載の熱伝達方法。
- 前記光に露出する段階において、前記入射する光は、可視光線領域または近赤外線領域の光である請求項14〜21のいずれか1項に記載の熱伝達方法。
- 前記熱伝達方法に使用された熱伝達媒体は、プラスチック基板またはガラス基板に形成された前記膜の焼きなまし工程に使用される請求項14〜22のいずれか1項に記載の熱伝達方法。
- 前記プラスチック基板またはガラス基板に形成されたナノ粒子含有膜は、有機物、金属、炭素、または無機物を含む請求項23に記載の熱伝達方法。
- 前記プラスチック基板は、二酸化チタン(TiO2)ペーストをコーティングしたプラスチック基板である請求項23また24に記載の熱伝達方法。
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JP5449722B2 (ja) | 2014-03-19 |
KR101494672B1 (ko) | 2015-02-24 |
US20120024505A1 (en) | 2012-02-02 |
US20090065734A1 (en) | 2009-03-12 |
US8945687B2 (en) | 2015-02-03 |
US8062738B2 (en) | 2011-11-22 |
CN101381597A (zh) | 2009-03-11 |
KR20090026103A (ko) | 2009-03-11 |
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