JP2008525548A - 良好な耐白化性を有するポリオレフィン組成物 - Google Patents
良好な耐白化性を有するポリオレフィン組成物 Download PDFInfo
- Publication number
- JP2008525548A JP2008525548A JP2007547429A JP2007547429A JP2008525548A JP 2008525548 A JP2008525548 A JP 2008525548A JP 2007547429 A JP2007547429 A JP 2007547429A JP 2007547429 A JP2007547429 A JP 2007547429A JP 2008525548 A JP2008525548 A JP 2008525548A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- polymer
- range
- amount
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 41
- 230000002087 whitening effect Effects 0.000 title abstract description 15
- 229920000098 polyolefin Polymers 0.000 title description 6
- -1 polyethylene Polymers 0.000 claims abstract description 43
- 229920000642 polymer Polymers 0.000 claims abstract description 34
- 229920001155 polypropylene Polymers 0.000 claims abstract description 27
- 239000005977 Ethylene Substances 0.000 claims abstract description 19
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004743 Polypropylene Substances 0.000 claims abstract description 18
- 239000004698 Polyethylene Substances 0.000 claims abstract description 16
- 229920000573 polyethylene Polymers 0.000 claims abstract description 16
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000008096 xylene Substances 0.000 claims abstract description 14
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 10
- 229920001198 elastomeric copolymer Polymers 0.000 claims abstract description 7
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 claims abstract description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 23
- 239000003054 catalyst Substances 0.000 claims description 19
- 229920001384 propylene homopolymer Polymers 0.000 claims description 3
- 239000002861 polymer material Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 description 16
- 229920001577 copolymer Polymers 0.000 description 14
- 238000000034 method Methods 0.000 description 13
- 125000000217 alkyl group Chemical group 0.000 description 10
- 239000007789 gas Substances 0.000 description 10
- 239000012071 phase Substances 0.000 description 10
- 239000010936 titanium Substances 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000011949 solid catalyst Substances 0.000 description 8
- 125000000753 cycloalkyl group Chemical group 0.000 description 7
- 125000005842 heteroatom Chemical group 0.000 description 7
- 150000002430 hydrocarbons Chemical group 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 239000005060 rubber Substances 0.000 description 6
- 150000003377 silicon compounds Chemical class 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 150000003900 succinic acid esters Chemical class 0.000 description 5
- 125000003342 alkenyl group Chemical group 0.000 description 4
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000005227 gel permeation chromatography Methods 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000012764 mineral filler Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000005498 phthalate group Chemical class 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- VFIOZKTXVHLWRA-UHFFFAOYSA-N (2-ethylpiperidin-1-yl)-dimethoxy-(1,1,1-trifluoropropan-2-yl)silane Chemical compound CCC1CCCCN1[Si](OC)(OC)C(C)C(F)(F)F VFIOZKTXVHLWRA-UHFFFAOYSA-N 0.000 description 1
- PJSFQEVODHCOOF-UHFFFAOYSA-N (2-ethylpiperidin-1-yl)-dimethoxy-(3,3,3-trifluoropropyl)silane Chemical compound CCC1CCCCN1[Si](CCC(F)(F)F)(OC)OC PJSFQEVODHCOOF-UHFFFAOYSA-N 0.000 description 1
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920011250 Polypropylene Block Copolymer Polymers 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- MEWFSXFFGFDHGV-UHFFFAOYSA-N cyclohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCCC1 MEWFSXFFGFDHGV-UHFFFAOYSA-N 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- BTJCEVZMRIJBSM-UHFFFAOYSA-N dimethoxy-methyl-(1,1,1-trifluoropropan-2-yl)silane Chemical compound CO[Si](C)(OC)C(C)C(F)(F)F BTJCEVZMRIJBSM-UHFFFAOYSA-N 0.000 description 1
- DWNAQMUDCDVSLT-UHFFFAOYSA-N diphenyl phthalate Chemical compound C=1C=CC=C(C(=O)OC=2C=CC=CC=2)C=1C(=O)OC1=CC=CC=C1 DWNAQMUDCDVSLT-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 description 1
- NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- JAYPHJBLPAEMEX-UHFFFAOYSA-N trimethoxy(2-methylpentan-2-yl)silane Chemical compound CCCC(C)(C)[Si](OC)(OC)OC JAYPHJBLPAEMEX-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04030607 | 2004-12-23 | ||
| US65767105P | 2005-03-02 | 2005-03-02 | |
| PCT/EP2005/056264 WO2006067023A1 (en) | 2004-12-23 | 2005-11-28 | Polyolefinic compositions having good whitening resistance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2008525548A true JP2008525548A (ja) | 2008-07-17 |
| JP2008525548A5 JP2008525548A5 (enExample) | 2009-01-08 |
Family
ID=34927960
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007547429A Withdrawn JP2008525548A (ja) | 2004-12-23 | 2005-11-28 | 良好な耐白化性を有するポリオレフィン組成物 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7795352B2 (enExample) |
| EP (1) | EP1828304B1 (enExample) |
| JP (1) | JP2008525548A (enExample) |
| CN (1) | CN101084268B (enExample) |
| AT (1) | ATE424435T1 (enExample) |
| AU (1) | AU2005318245A1 (enExample) |
| BR (1) | BRPI0518119A (enExample) |
| CA (1) | CA2592143A1 (enExample) |
| RU (1) | RU2386651C2 (enExample) |
| TW (1) | TW200624497A (enExample) |
| WO (1) | WO2006067023A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017515961A (ja) * | 2014-05-28 | 2017-06-15 | バーゼル・ポリオレフィン・ゲーエムベーハー | エチレン重合体組成物及びポリオレフィン組成物におけるその用途 |
| JP2017519067A (ja) * | 2014-05-28 | 2017-07-13 | バーゼル・ポリオレフィン・ゲーエムベーハー | エチレン重合体組成物及びポリオレフィン組成物におけるその用途 |
| KR102223243B1 (ko) * | 2019-09-16 | 2021-03-04 | 한화토탈 주식회사 | 내백화성과 내열성이 우수한 폴리프로필렌 수지 조성물, 그 제조방법 및 그로부터 제조된 성형품 |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007501298A (ja) * | 2003-08-05 | 2007-01-25 | バセル ポリオレフィン イタリア エス．アール．エル． | ポリオレフィン物品 |
| US7772324B2 (en) * | 2004-10-04 | 2010-08-10 | Basell Poliolefine Italia S.R.L. | Elastomeric polyolefin compositions |
| ATE450573T1 (de) * | 2005-05-27 | 2009-12-15 | Basell Poliolefine Srl | Polyolefinische zusammensetzungen mit hoher bleichungsresistenz |
| ES2315776T3 (es) * | 2005-11-16 | 2009-04-01 | Borealis Technology Oy | Resina de polipropileno con baja contraccion, alta resistencia al impacto, rigidez y resistencia al rayado. |
| EP2376568B1 (en) * | 2009-01-13 | 2013-05-08 | Basell Poliolefine Italia S.r.l. | Polymer composition |
| EP2379609B1 (en) | 2009-01-13 | 2012-10-24 | Basell Polyolefine GmbH | Polyethylene copolymers |
| US8217116B2 (en) * | 2009-07-15 | 2012-07-10 | Braskem America, Inc. | Polypropylene composition for buried structures |
| WO2011012500A1 (en) | 2009-07-31 | 2011-02-03 | Basell Poliolefine Italia S.R.L. | Polyolefinic compositions |
| US8575272B2 (en) * | 2009-07-31 | 2013-11-05 | Basell Poliolefine Italia S.R.L. | Polyolefinic compositions |
| WO2011036021A1 (en) | 2009-09-22 | 2011-03-31 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| WO2011036002A1 (en) * | 2009-09-22 | 2011-03-31 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| US8569419B2 (en) | 2009-09-22 | 2013-10-29 | Basell Poliolefine Italia, s.r.l. | Propylene polymer compositions |
| CN102666713B (zh) | 2009-12-23 | 2014-11-26 | 巴塞尔聚烯烃意大利有限责任公司 | 用于注塑排水系统的聚烯烃组合物 |
| CN102985478B (zh) * | 2010-07-23 | 2015-04-29 | 巴塞尔聚烯烃意大利有限责任公司 | 丙烯聚合物组合物 |
| CN103154124B (zh) * | 2010-10-14 | 2015-12-09 | 巴塞尔聚烯烃意大利有限责任公司 | 汽车内饰元件 |
| CN102453279B (zh) * | 2010-10-22 | 2013-06-12 | 中国石油化工股份有限公司 | 一种用于生产碳酸饮料瓶盖的聚丙烯组合物 |
| EP2463413B1 (en) | 2010-12-07 | 2014-01-29 | Basell Poliolefine Italia S.r.l. | Polyolefin fibres |
| WO2012098086A1 (en) | 2011-01-18 | 2012-07-26 | Basell Poliolefine Italia S.R.L. | Polyolefin composition |
| EP2592111A1 (en) | 2011-11-11 | 2013-05-15 | Basell Poliolefine Italia S.r.l. | Polymer composition for bumpers and interiors and polyethylene-based resin precursor |
| EP2592112A1 (en) | 2011-11-11 | 2013-05-15 | Basell Poliolefine Italia S.r.l. | Polymer composition for bumpers and interiors and polyethylene-based resin precursor |
| EP2676972A1 (en) | 2012-06-19 | 2013-12-25 | Basell Polyolefine GmbH | Process for the obtainment of a polyolefin composition |
| US9908952B2 (en) * | 2013-11-15 | 2018-03-06 | W.R. Grace & Co.-Conn. | Propylene-based polymer with reduced high-molecular weight portion |
| US20170210893A1 (en) * | 2014-07-07 | 2017-07-27 | Basell Poliolefine Italia S.R.L. | Polyolefin composition |
| CN105524348A (zh) * | 2014-09-29 | 2016-04-27 | 中国石油化工股份有限公司 | 一种聚丙烯组合物和聚丙烯材料 |
| EP3201268B1 (en) * | 2014-10-01 | 2018-12-12 | Basell Poliolefine Italia S.r.l. | Propylene-based copolymer composition for pipes |
| WO2018031564A1 (en) | 2016-08-08 | 2018-02-15 | Ticona Llc | Thermally conductive polymer composition for a heat sink |
| EP3647356B8 (en) * | 2018-10-31 | 2022-03-30 | Borealis AG | Polyolefin composition with improved balance of properties |
| EP3877464B1 (en) | 2018-11-07 | 2022-10-12 | Borealis AG | Polyolefin composition with improved impact and whitening resistance |
| ES2977491T3 (es) | 2018-11-23 | 2024-08-26 | Borealis Ag | Composición de polipropileno con propiedades ópticas y resistencia al blanqueamiento mejoradas |
| US12359047B2 (en) | 2019-04-12 | 2025-07-15 | Borealis Ag | Low stress whitening polypropylene composition |
| CN110172210A (zh) * | 2019-04-29 | 2019-08-27 | 东莞市莎米特箱包有限公司 | 一种防花白的箱包壳复合材料及其制备方法 |
| CN113388204B (zh) * | 2020-03-13 | 2022-08-19 | 中国石油化工股份有限公司 | 聚烯烃组合物和聚烯烃材料及其制备方法 |
| JP7570511B2 (ja) | 2020-10-28 | 2024-10-21 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 再生ポリオレフィンから得られるポリオレフィン組成物 |
| US20230383109A1 (en) | 2020-10-28 | 2023-11-30 | Basell Poliolefine Italia S.R.L. | Polyolefins compositions obtained from recycled polyolefins |
| EP4339239A1 (en) * | 2022-09-14 | 2024-03-20 | Basell Poliolefine Italia S.r.l. | Polyolefins compositions obtained from recycled polyolefins |
| EP4339240A1 (en) * | 2022-09-14 | 2024-03-20 | Basell Poliolefine Italia S.r.l. | Polyolefins compositions obtained from recycled polyolefins |
| KR102796019B1 (ko) | 2022-11-16 | 2025-04-14 | 한화토탈에너지스 주식회사 | 저온 내충격성이 우수한 폴리프로필렌 수지 조성물 및 그로부터 제조된 성형품 |
| WO2025180846A1 (en) | 2024-03-01 | 2025-09-04 | Basell Poliolefine Italia S.R.L. | Polyolefins compositions obtained from recycled polyolefins |
Family Cites Families (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1456359A (fr) | 1964-12-28 | 1966-10-21 | Dow Chemical Co | Compositions de polypropylène de résistance améliorée aux chocs et leur préparation |
| NL162661B (nl) | 1968-11-21 | 1980-01-15 | Montedison Spa | Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1. |
| YU35844B (en) | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| IT1096661B (it) | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| JPS5543152A (en) * | 1978-09-22 | 1980-03-26 | Chisso Corp | Preparation of copolymer |
| DE2849114C2 (de) * | 1978-11-11 | 1982-12-23 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung einer Polypropylen-Formmasse und ihre Verwendung zur Herstellung von Formkörpern |
| US4395519A (en) * | 1979-04-18 | 1983-07-26 | Mitsui Petrochemical Industries, Ltd. | Physically blended propylene polymer composition |
| IT1209255B (it) | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
| IT1140221B (it) | 1981-10-14 | 1986-09-24 | Montedison Spa | Composizioni polipropileniche aventi migliorate caratteristiche di resistenza all'urto alle basse temperature e procedimento di preparazione |
| JPS5883016A (ja) | 1981-11-13 | 1983-05-18 | Mitsui Petrochem Ind Ltd | プロピレンブロツク共重合体の製法 |
| IT1190681B (it) | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1190683B (it) | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| JPS58152038A (ja) * | 1982-03-04 | 1983-09-09 | Mitsui Toatsu Chem Inc | 射出成形用ポリプロピレン組成物 |
| JPS6028411A (ja) * | 1983-07-26 | 1985-02-13 | Chisso Corp | 高剛性エチレン・プロピレン共重合体の製造方法 |
| IT1206128B (it) * | 1984-07-30 | 1989-04-14 | Himont Inc | Composizioni polipropileniche resistenti all'urto aventi migliorata resistenza allo sbiancamento. |
| US4950720A (en) * | 1988-04-29 | 1990-08-21 | Exxon Chemical Patents Inc. | Modified polypropylene, process for making and article made from the same |
| IT1227260B (it) | 1988-09-30 | 1991-03-28 | Himont Inc | Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta |
| IT1227893B (it) * | 1988-12-14 | 1991-05-14 | Himont Inc Centerville Road Ne | Composizioni polipropileniche aventi buona trasparenza e migliorata resistenza all'urto |
| IT1230133B (it) * | 1989-04-28 | 1991-10-14 | Himont Inc | Composizioni polipropileniche plasto-elastiche |
| CA1331239C (en) * | 1989-08-23 | 1994-08-02 | Lewis R. Leonard | Thermoplastic olefin polymer and method of preparing same |
| US6156846A (en) * | 1989-11-28 | 2000-12-05 | Idemitsu Petrochemical Co., Ltd. | Flexible polypropylene resins, propylene bases elastomer compositions and process for production of olefin polymers |
| IT1240417B (it) * | 1990-02-28 | 1993-12-15 | Himont Inc | Procedimento per la produzione di film e corpi laminari polipropilenici e prodotti cosi' ottenuti |
| IT1256663B (it) * | 1992-12-15 | 1995-12-12 | Himont Inc | Composizioni polipropileniche aventi buona trasparenza e migliorata resistenza all'urto. |
| CA2128920C (en) * | 1993-07-28 | 1999-06-01 | Akihiko Yamamoto | Propylene polymer compositions |
| CN1104444C (zh) * | 1994-04-11 | 2003-04-02 | 三井化学株式会社 | 丙烯聚合物组合物的制备方法 |
| IL117114A (en) | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
| CA2256707C (en) | 1996-05-27 | 2004-12-21 | Mitsui Chemicals, Incorporated | Crystalline polypropylene, process for preparing the same, polypropylene composition, and thermoformed article |
| US6403708B2 (en) * | 1996-05-27 | 2002-06-11 | Mitsui Chemicals Inc | Crystalline polypropylenes, process for preparing thereof, polypropylene compositions, and thermoformed products |
| IT1302029B1 (it) * | 1998-08-19 | 2000-07-20 | Montech Usa Inc | Processo per produrre composizioni polimeriche eterofasiche ecomposizioni cosi' ottenute |
| ATE335014T1 (de) | 1999-04-15 | 2006-08-15 | Basell Poliolefine Srl | Bestandteile und katalysatoren für die olefinpolymerisation |
| US20020037979A1 (en) * | 1999-12-28 | 2002-03-28 | Robert Charles Job | Mixed ziegler/metallocene catalysts for the production of bimodal polyolefins |
| JP4574934B2 (ja) | 2000-02-02 | 2010-11-04 | バセル テクノロジー カンパニー ビー．ブイ． | オレフィン重合用成分及び触媒 |
| US6673869B2 (en) * | 2000-07-27 | 2004-01-06 | Basell Poliolefine Italia S.P.A. | Transparent elastomeric thermoplastic polyolefin compositions |
| ATE450573T1 (de) | 2005-05-27 | 2009-12-15 | Basell Poliolefine Srl | Polyolefinische zusammensetzungen mit hoher bleichungsresistenz |
-
2005
- 2005-11-28 BR BRPI0518119-4A patent/BRPI0518119A/pt not_active Application Discontinuation
- 2005-11-28 EP EP05815558A patent/EP1828304B1/en not_active Revoked
- 2005-11-28 CN CN2005800439520A patent/CN101084268B/zh not_active Expired - Lifetime
- 2005-11-28 JP JP2007547429A patent/JP2008525548A/ja not_active Withdrawn
- 2005-11-28 WO PCT/EP2005/056264 patent/WO2006067023A1/en not_active Ceased
- 2005-11-28 AT AT05815558T patent/ATE424435T1/de not_active IP Right Cessation
- 2005-11-28 AU AU2005318245A patent/AU2005318245A1/en not_active Abandoned
- 2005-11-28 CA CA002592143A patent/CA2592143A1/en not_active Abandoned
- 2005-11-28 US US11/793,843 patent/US7795352B2/en not_active Expired - Fee Related
- 2005-11-28 RU RU2007127874/04A patent/RU2386651C2/ru active
- 2005-11-30 TW TW094141995A patent/TW200624497A/zh unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017515961A (ja) * | 2014-05-28 | 2017-06-15 | バーゼル・ポリオレフィン・ゲーエムベーハー | エチレン重合体組成物及びポリオレフィン組成物におけるその用途 |
| JP2017519067A (ja) * | 2014-05-28 | 2017-07-13 | バーゼル・ポリオレフィン・ゲーエムベーハー | エチレン重合体組成物及びポリオレフィン組成物におけるその用途 |
| KR102223243B1 (ko) * | 2019-09-16 | 2021-03-04 | 한화토탈 주식회사 | 내백화성과 내열성이 우수한 폴리프로필렌 수지 조성물, 그 제조방법 및 그로부터 제조된 성형품 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW200624497A (en) | 2006-07-16 |
| ATE424435T1 (de) | 2009-03-15 |
| RU2007127874A (ru) | 2009-01-27 |
| WO2006067023A1 (en) | 2006-06-29 |
| EP1828304A1 (en) | 2007-09-05 |
| EP1828304B1 (en) | 2009-03-04 |
| CN101084268A (zh) | 2007-12-05 |
| CA2592143A1 (en) | 2006-06-29 |
| CN101084268B (zh) | 2011-09-14 |
| AU2005318245A1 (en) | 2006-06-29 |
| US20080167428A1 (en) | 2008-07-10 |
| RU2386651C2 (ru) | 2010-04-20 |
| BRPI0518119A (pt) | 2008-10-28 |
| US7795352B2 (en) | 2010-09-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2008525548A (ja) | 良好な耐白化性を有するポリオレフィン組成物 | |
| JP5175180B2 (ja) | 良好な白化抵抗を有するポリオレフィン性組成物 | |
| US7649052B2 (en) | Impact resistant polyolefin compositions | |
| EP2516546B1 (en) | Polyolefinic compositions for injection-moulded drainage systems | |
| US9000097B2 (en) | Polypropylene composition | |
| CN102575074B (zh) | 聚烯烃组合物 | |
| CN102471550B (zh) | 聚烯烃组合物 | |
| KR20080019584A (ko) | 양호한 백화 저항성을 갖는 폴리올레핀 조성물 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20081113 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20081113 |
|
| A761 | Written withdrawal of application |
Free format text: JAPANESE INTERMEDIATE CODE: A761 Effective date: 20090224 |