JP2008500307A5 - - Google Patents
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- Publication number
- JP2008500307A5 JP2008500307A5 JP2007513909A JP2007513909A JP2008500307A5 JP 2008500307 A5 JP2008500307 A5 JP 2008500307A5 JP 2007513909 A JP2007513909 A JP 2007513909A JP 2007513909 A JP2007513909 A JP 2007513909A JP 2008500307 A5 JP2008500307 A5 JP 2008500307A5
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- group
- formula
- following formula
- direct bond
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims 39
- 125000003545 alkoxy group Chemical group 0.000 claims 24
- 229910052799 carbon Inorganic materials 0.000 claims 20
- 229910052739 hydrogen Inorganic materials 0.000 claims 20
- 125000002252 acyl group Chemical group 0.000 claims 19
- 229910052736 halogen Inorganic materials 0.000 claims 14
- 150000002367 halogens Chemical class 0.000 claims 12
- 238000000034 method Methods 0.000 claims 10
- 125000000753 cycloalkyl group Chemical group 0.000 claims 9
- 125000004430 oxygen atom Chemical group O* 0.000 claims 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 9
- 239000000178 monomer Substances 0.000 claims 8
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims 8
- 125000002947 alkylene group Chemical group 0.000 claims 7
- 125000004432 carbon atom Chemical group C* 0.000 claims 7
- -1 2-acryloyloxy-ethylcarbamoyl Chemical group 0.000 claims 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 6
- 125000004122 cyclic group Chemical group 0.000 claims 5
- 239000003999 initiator Substances 0.000 claims 5
- 238000006116 polymerization reaction Methods 0.000 claims 5
- 125000003031 C5-C7 cycloalkylene group Chemical group 0.000 claims 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 3
- 125000003884 phenylalkyl group Chemical group 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims 2
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- 125000003282 alkyl amino group Chemical group 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 2
- 125000002993 cycloalkylene group Chemical group 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- GJVFBWCTGUSGDD-UHFFFAOYSA-L pentamethonium bromide Chemical compound [Br-].[Br-].C[N+](C)(C)CCCCC[N+](C)(C)C GJVFBWCTGUSGDD-UHFFFAOYSA-L 0.000 claims 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 2
- 239000007870 radical polymerization initiator Substances 0.000 claims 2
- 238000010526 radical polymerization reaction Methods 0.000 claims 2
- 150000003254 radicals Chemical class 0.000 claims 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 claims 1
- RQHHUIVCDCFJDA-UHFFFAOYSA-N 2-[2-(2,6-diethyl-2,3,6-trimethyl-4-oxopiperidin-1-yl)oxypropanoylamino]ethyl 2-methylprop-2-enoate Chemical compound CCC1(C)CC(=O)C(C)C(C)(CC)N1OC(C)C(=O)NCCOC(=O)C(C)=C RQHHUIVCDCFJDA-UHFFFAOYSA-N 0.000 claims 1
- ZMERPQFVHICVCA-UHFFFAOYSA-N 2-[2-(2,6-diethyl-2,3,6-trimethyl-4-oxopiperidin-1-yl)oxypropanoyloxy]ethyl 2-methylprop-2-enoate Chemical compound CCC1(C)CC(=O)C(C)C(C)(CC)N1OC(C)C(=O)OCCOC(=O)C(C)=C ZMERPQFVHICVCA-UHFFFAOYSA-N 0.000 claims 1
- JTEQTZRTLYGVES-UHFFFAOYSA-N 2-[2-[tert-butyl-(1-diethoxyphosphoryl-2,2-dimethylpropyl)amino]oxypropanoylamino]ethyl prop-2-enoate Chemical compound CCOP(=O)(OCC)C(C(C)(C)C)N(C(C)(C)C)OC(C)C(=O)NCCOC(=O)C=C JTEQTZRTLYGVES-UHFFFAOYSA-N 0.000 claims 1
- FGNZCFNBUTZPIM-UHFFFAOYSA-N 2-[[2-(2,6-diethyl-2,3,6-trimethyl-4-oxopiperidin-1-yl)oxy-2-methylpropanoyl]amino]ethyl prop-2-enoate Chemical compound CCC1(C)CC(=O)C(C)C(C)(CC)N1OC(C)(C)C(=O)NCCOC(=O)C=C FGNZCFNBUTZPIM-UHFFFAOYSA-N 0.000 claims 1
- VIUMEJVLXUMLBC-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl 2-(2,6-diethyl-2,3,6-trimethyl-4-oxopiperidin-1-yl)oxypropanoate Chemical compound CCC1(C)CC(=O)C(C)C(C)(CC)N1OC(C)C(=O)OCCOC(=O)C=C VIUMEJVLXUMLBC-UHFFFAOYSA-N 0.000 claims 1
- SHLLQXHKVSWDAC-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl 2-(2,6-diethyl-2,3,6-trimethyl-4-prop-2-enoyloxypiperidin-1-yl)oxypropanoate Chemical compound CCC1(C)CC(OC(=O)C=C)C(C)C(C)(CC)N1OC(C)C(=O)OCCOC(=O)C=C SHLLQXHKVSWDAC-UHFFFAOYSA-N 0.000 claims 1
- IWUWPKBDWVYAFE-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl 2-(2,6-diethyl-4-hydroxy-2,3,6-trimethylpiperidin-1-yl)oxypropanoate Chemical compound CCC1(C)CC(O)C(C)C(C)(CC)N1OC(C)C(=O)OCCOC(=O)C=C IWUWPKBDWVYAFE-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 1
- QHRYTWPLFNKZJO-UHFFFAOYSA-N [1-[1-[6-[2-(2,6-diethyl-2,3,6-trimethyl-4-prop-2-enoyloxypiperidin-1-yl)oxypropanoylamino]hexylamino]-1-oxopropan-2-yl]oxy-2,6-diethyl-2,3,6-trimethylpiperidin-4-yl] prop-2-enoate Chemical compound CCC1(C)CC(OC(=O)C=C)C(C)C(C)(CC)N1OC(C)C(=O)NCCCCCCNC(=O)C(C)ON1C(CC)(C)C(C)C(OC(=O)C=C)CC1(CC)C QHRYTWPLFNKZJO-UHFFFAOYSA-N 0.000 claims 1
- IMYIDPBWKRIKDD-UHFFFAOYSA-N [2,6-diethyl-2,3,6-trimethyl-1-[1-oxo-1-(2-prop-2-enoyloxyethoxy)propan-2-yl]oxypiperidin-4-yl] 2-methylprop-2-enoate Chemical compound CCC1(C)CC(OC(=O)C(C)=C)C(C)C(C)(CC)N1OC(C)C(=O)OCCOC(=O)C=C IMYIDPBWKRIKDD-UHFFFAOYSA-N 0.000 claims 1
- 150000003926 acrylamides Chemical class 0.000 claims 1
- 150000008360 acrylonitriles Chemical class 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- 230000005670 electromagnetic radiation Effects 0.000 claims 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 150000007522 mineralic acids Chemical class 0.000 claims 1
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 150000002976 peresters Chemical class 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- ARJOQCYCJMAIFR-UHFFFAOYSA-N prop-2-enoyl prop-2-enoate Chemical compound C=CC(=O)OC(=O)C=C ARJOQCYCJMAIFR-UHFFFAOYSA-N 0.000 claims 1
- 150000003440 styrenes Chemical class 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 0 CC(C)(C)C(N(C)C(C)(C)C)P(O*)(O*)=O Chemical compound CC(C)(C)C(N(C)C(C)(C)C)P(O*)(O*)=O 0.000 description 8
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- HFBMWMNUJJDEQZ-UHFFFAOYSA-N acryloyl chloride Chemical compound ClC(=O)C=C HFBMWMNUJJDEQZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000012230 colorless oil Substances 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04102337.5 | 2004-05-27 | ||
| EP04102337 | 2004-05-27 | ||
| PCT/EP2005/052260 WO2005118651A1 (en) | 2004-05-27 | 2005-05-17 | Alkoxyamines containing a radically polymerizable group |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008500307A JP2008500307A (ja) | 2008-01-10 |
| JP2008500307A5 true JP2008500307A5 (enExample) | 2009-09-17 |
| JP4971147B2 JP4971147B2 (ja) | 2012-07-11 |
Family
ID=34929137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007513909A Expired - Fee Related JP4971147B2 (ja) | 2004-05-27 | 2005-05-17 | ラジカル重合性基を含有するアルコキシアミン |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7619050B2 (enExample) |
| EP (1) | EP1749032B1 (enExample) |
| JP (1) | JP4971147B2 (enExample) |
| KR (1) | KR101246639B1 (enExample) |
| CN (2) | CN101712646B (enExample) |
| AT (1) | ATE387464T1 (enExample) |
| DE (1) | DE602005005045T2 (enExample) |
| WO (1) | WO2005118651A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7825200B2 (en) * | 2003-02-28 | 2010-11-02 | The Regents Of The University Of California | Controlled free radical grafting from polyolefins |
| US7812100B2 (en) * | 2005-10-26 | 2010-10-12 | Ciba Corporation | Alkoxyamines containing unsaturated groups |
| DE102006062439A1 (de) * | 2006-12-27 | 2008-07-03 | Byk-Chemie Gmbh | Kamm(block)copolymere |
| TWI492956B (zh) * | 2009-12-01 | 2015-07-21 | Mitsubishi Rayon Co | 使用具有哌啶骨架的單體之聚合物的製造方法及成型體 |
| US10316114B2 (en) | 2010-03-30 | 2019-06-11 | Basf Se | End-functionalized polymers |
| CN102351972B (zh) * | 2011-07-28 | 2014-04-23 | 中山大学 | 一种含烷氧胺基团的热可逆自修复交联聚合物 |
| EP2995631A1 (en) | 2014-09-12 | 2016-03-16 | Borealis AG | Process for producing graft copolymers on polyolefin backbone |
| JP7356698B2 (ja) * | 2019-06-21 | 2023-10-05 | 学校法人五島育英会 | 化合物、化合物の製造方法、重合体の製造方法、重合体 |
| CN111285796B (zh) * | 2020-02-28 | 2021-09-21 | 合肥鑫晟光电科技有限公司 | 单体、聚合物、树脂组合物、基板及制备方法、显示装置 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1189875B1 (en) * | 1999-07-02 | 2004-08-04 | Ciba SC Holding AG | Mono and multifunctional alkoxyamines for the preparation of functionalized macromers |
| ES2319252T3 (es) * | 1999-09-07 | 2009-05-06 | Bayer Materialscience Ag | Oligomeros y polimeros telequelicos. |
| JP4707222B2 (ja) * | 1999-11-29 | 2011-06-22 | 株式会社Adeka | Ｎ−置換カルバモイルオキシ−２，２，６，６−テトラメチル−４−ピペリジルアクリレート誘導体 |
| TW541303B (en) * | 2000-03-22 | 2003-07-11 | Ciba Sc Holding Ag | 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides |
| TW557305B (en) * | 2000-12-14 | 2003-10-11 | Ciba Sc Holding Ag | N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith |
| DE60223689T2 (de) * | 2001-07-05 | 2008-10-30 | Ciba Holding Inc. | Multifunktionale alkoxyamine auf grundlage von polyalkylpiperidinen, polyalkylpiperazinonen und polyalkylmorpholinonen, und deren verwendung als polymerisationsregulatoren/-initiatoren |
| JP4204241B2 (ja) * | 2002-03-19 | 2009-01-07 | 三菱レイヨン株式会社 | 高分子ラジカル重合開始剤および共重合体の製造方法 |
| US6680362B1 (en) * | 2003-02-05 | 2004-01-20 | 3M Innovative Properties Company | Ring-opened azlactone initiators for nitroxide-mediated polymerization |
-
2005
- 2005-05-17 CN CN2009102526966A patent/CN101712646B/zh not_active Expired - Fee Related
- 2005-05-17 CN CN200580016626A patent/CN100586963C/zh not_active Expired - Fee Related
- 2005-05-17 EP EP05742775A patent/EP1749032B1/en not_active Expired - Lifetime
- 2005-05-17 KR KR1020067027402A patent/KR101246639B1/ko not_active Expired - Fee Related
- 2005-05-17 AT AT05742775T patent/ATE387464T1/de not_active IP Right Cessation
- 2005-05-17 US US11/596,436 patent/US7619050B2/en not_active Expired - Fee Related
- 2005-05-17 DE DE602005005045T patent/DE602005005045T2/de not_active Expired - Lifetime
- 2005-05-17 JP JP2007513909A patent/JP4971147B2/ja not_active Expired - Fee Related
- 2005-05-17 WO PCT/EP2005/052260 patent/WO2005118651A1/en not_active Ceased
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