JP2008214369A - ディーゼルエンジン用燃料組成物 - Google Patents
ディーゼルエンジン用燃料組成物 Download PDFInfo
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- 239000000203 mixture Substances 0.000 title claims abstract description 37
- 239000000446 fuel Substances 0.000 title claims abstract description 34
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 39
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 33
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 31
- 230000003647 oxidation Effects 0.000 claims abstract description 30
- 239000003350 kerosene Substances 0.000 claims abstract description 17
- 238000012360 testing method Methods 0.000 claims abstract description 10
- 238000013112 stability test Methods 0.000 claims abstract description 8
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- 238000004821 distillation Methods 0.000 claims description 22
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 12
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 10
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical group CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 8
- 239000011593 sulfur Substances 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 150000001412 amines Chemical class 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000004986 phenylenediamines Chemical group 0.000 claims description 2
- 239000003921 oil Substances 0.000 abstract description 39
- 239000000463 material Substances 0.000 abstract description 20
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
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- 229930195733 hydrocarbon Natural products 0.000 description 4
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000004523 catalytic cracking Methods 0.000 description 3
- 238000004517 catalytic hydrocracking Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
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- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
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- 238000004519 manufacturing process Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
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- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
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- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000004227 thermal cracking Methods 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- PWNBRRGFUVBTQG-UHFFFAOYSA-N 1-n,4-n-di(propan-2-yl)benzene-1,4-diamine Chemical compound CC(C)NC1=CC=C(NC(C)C)C=C1 PWNBRRGFUVBTQG-UHFFFAOYSA-N 0.000 description 1
- ZRMMVODKVLXCBB-UHFFFAOYSA-N 1-n-cyclohexyl-4-n-phenylbenzene-1,4-diamine Chemical compound C1CCCCC1NC(C=C1)=CC=C1NC1=CC=CC=C1 ZRMMVODKVLXCBB-UHFFFAOYSA-N 0.000 description 1
- OPLCSTZDXXUYDU-UHFFFAOYSA-N 2,4-dimethyl-6-tert-butylphenol Chemical compound CC1=CC(C)=C(O)C(C(C)(C)C)=C1 OPLCSTZDXXUYDU-UHFFFAOYSA-N 0.000 description 1
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 description 1
- PPPNUSFRWJVHQB-UHFFFAOYSA-N 4-n-butylbenzene-1,4-diamine Chemical compound CCCCNC1=CC=C(N)C=C1 PPPNUSFRWJVHQB-UHFFFAOYSA-N 0.000 description 1
- JQTYAZKTBXWQOM-UHFFFAOYSA-N 4-n-octan-2-yl-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CCCCCC)=CC=C1NC1=CC=CC=C1 JQTYAZKTBXWQOM-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 208000016444 Benign adult familial myoclonic epilepsy Diseases 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical compound C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000809 air pollutant Substances 0.000 description 1
- 231100001243 air pollutant Toxicity 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 125000002619 bicyclic group Chemical group 0.000 description 1
- 239000003225 biodiesel Substances 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000010771 distillate fuel oil Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 208000016427 familial adult myoclonic epilepsy Diseases 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- ZGNITFSDLCMLGI-UHFFFAOYSA-N flubendiamide Chemical compound CC1=CC(C(F)(C(F)(F)F)C(F)(F)F)=CC=C1NC(=O)C1=CC=CC(I)=C1C(=O)NC(C)(C)CS(C)(=O)=O ZGNITFSDLCMLGI-UHFFFAOYSA-N 0.000 description 1
- 238000004231 fluid catalytic cracking Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000002828 fuel tank Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000006078 metal deactivator Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
- C10L1/08—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
- C10L1/1832—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
Abstract
【解決手段】(1)直留灯油留分、直留軽油留分、分解軽油留分、分解灯油留分およびこれらの水素化脱硫物より成る群から選択される1種以上の中間留分を80〜0容量%、並びに(2)GTLを20容量%〜100容量%含み、EN14112試験に準拠した酸化安定性試験において、液温150℃での電気伝導度変化までの時間が4時間以上であることを特徴とするディーゼルエンジン用燃料組成物。この燃料油組成物は200ppm以下の酸化防止剤を含むことができる。
【選択図】なし
Description
酸化防止性の面から、主に沸点範囲約150℃から約200℃の沸点範囲を有するGTL灯油留分を用いるのが好ましい。
酸化安定性試験
試験装置としては、バイオディーゼルとして用いられる脂肪酸メチルエステルに関する酸化安定性試験である欧州標準規格EN14112(2003年4月)[Fat and oil derivatives - Fatty Acid Methyl Esters (FAME)-Determination of oxidation stability (accelerated oxidation test]の試験手順に準拠したスイス・メトローム社のランシマット743型を用いた。試験装置の反応容器に約3gの試料をとり、110℃又は150℃に保った試料へ毎時10リットルの流速で空気を吹き込み、排気される気体を50mLの蒸留水を加えた伝導率測定セルに通して、試験開始から酸化生成物(蟻酸及び酢酸が主成分であると考えられる)の形成が急速に増加するまでの時間を伝導率の変化によって求めてこれを誘導時間とした。このEN14112の試験では試験温度を110℃にて実施しているが、本試験においては、高温での酸化安定性を評価するため150℃の試験温度を採用した。
酸化安定性試験において基材として使用したGTL及び中間留分の性状を表1に示す。これら基材の製造法は以下に示すとおりである。
フェノール系酸化防止剤として、シェルケミカルズジャパン社製アイオノール(R)(3,5−ジ第三ブチル−4−ヒドロキシトルエン)、アミン系酸化防止剤として日揮ユニバーサル社製NU No.400(R)(有効成分としてアルキル−アリールフェニレンジアミンを50重量%含有)を使用した。
実施例1及び比較実施例2〜比較実施例7
表1に記載の各基材を試料として酸化安定性試験を行なった。得られた誘導時間を表2に示す。
GTLを含まない基材5に酸化防止剤を加えたものを試料として、誘導時間を測定した。アイオノール(R)(フェノール系酸化防止剤)及びNU No.400(R)(アミン系酸化防止剤)の量が、それぞれ350ppm及び250ppm(有効成分に換算した量。以下同じ。)である場合に、150℃で6時間以上の誘導時間が測定された。結果を表3に示す。
実施例10として、基材1(GTL灯油留分)に1ppmのNU No.400(R)(アミン系酸化防止剤)を加えたものを試料として酸化安定性を評価した。また実施例11及び12として基材3(GTL軽油留分)にそれぞれアイオノール(R)(フェノール系酸化防止剤)75ppm、NU No.400(R)50ppmを添加したものを試料とし、各試料の酸化安定性を評価した。誘導時間は実施例10(酸化防止剤1ppm)では6.4時間、実施例11(酸化防止剤75ppm)では6.2時間、実施例12(酸化防止剤50ppm)では6.1時間であり、中間留分のみを基材とした比較実施例8及び9と比較してはるかに少ない酸化防止剤の添加量で同等の酸化安定性が達成できることがわかる。
結果を表4に示す。
GTL(基材1及び3)と中間留分(基材5)との各種混合基材(GTL含量が80〜20容量%)に対して酸化防止剤を8〜200ppm添加したものを試料とし、各試料の酸化安定性を評価した。各試料の性状と得られた誘導時間を表5に示す。いずれの場合にも、中間留分のみを基材とした比較実施例8及び9と比較してはるかに少ない酸化防止剤の添加量で同等の酸化安定性が達成できることがわかる。
Claims (7)
- (1)直留灯油留分、直留軽油留分、分解軽油留分、分解灯油留分およびこれらの水素化脱硫物より成る群から選択される1種以上の中間留分を80〜0容量%、並びに(2)GTLを20容量%〜100容量%含み、EN14112試験に準拠した酸化安定性試験において、液温150℃での電気伝導度変化までの時間が4時間以上であることを特徴とするディーゼルエンジン用燃料組成物。
- 以下の性状(1)〜(5)を満たす、請求項1に記載のディーゼルエンジン用燃料組成物:
(1)蒸留性状90%留出温度が360℃以下
(2)セタン価が45以上
(3)飽和脂肪族炭化水素化合物含有量が85容量%以上
(4)全芳香族炭化水素含有量が15容量%以下、且つ、2環以上の芳香族炭化水素含有量が2容量%以下
(5)全硫黄分が10質量ppm以下。 - さらに200ppm以下の酸化防止剤を含む、請求項1又は2に記載のディーゼルエンジン用燃料組成物。
- 酸化防止剤がフェノール系酸化防止剤又はアミン系酸化防止剤であることを特徴とする請求項3に記載のディーゼルエンジン用燃料組成物。
- 酸化防止剤がフェニレンジアミン系酸化防止剤であることを特徴とする請求項3に記載のディーゼルエンジン用燃料組成物。
- 酸化防止剤が3,5−ジ−ターシャリーブチル−4−ヒドロキシトルエンであることを特徴とする請求項3記載のディーゼルエンジン用燃料組成物。
- 150℃での電気伝導度変化までの時間が6時間以上であることを特徴とする請求項3〜6のいずれかに記載のディーゼルエンジン用燃料組成物。
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JP2007049386A JP2008214369A (ja) | 2007-02-28 | 2007-02-28 | ディーゼルエンジン用燃料組成物 |
US12/037,773 US20080256846A1 (en) | 2007-02-28 | 2008-02-26 | Fuel composition for diesel engines |
SG10201705367XA SG10201705367XA (en) | 2007-02-28 | 2008-02-27 | Fuel composition for diesel engines |
ARP080100795A AR065487A1 (es) | 2007-02-28 | 2008-02-27 | Composicion de combustible para motores diesel |
PCT/EP2008/052348 WO2008104556A1 (en) | 2007-02-28 | 2008-02-27 | Fuel composition for diesel engines |
EP08709234A EP2118243A1 (en) | 2007-02-28 | 2008-02-27 | Fuel composition for diesel engines |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010072838A2 (en) | 2008-12-26 | 2010-07-01 | Shell Internationale Research Maatschappij B.V. | Diesel fuel composition |
WO2012161018A1 (ja) * | 2011-05-26 | 2012-11-29 | Jx日鉱日石エネルギー株式会社 | 軽油組成物およびその製造方法 |
US9862897B2 (en) | 2013-02-21 | 2018-01-09 | Jx Nippon Oil & Energy Corporation | Method for producing monocyclic aromatic hydrocarbon |
US10087376B2 (en) | 2010-01-20 | 2018-10-02 | Jx Nippon Oil & Energy Corporation | Method for producing monocyclic aromatic hydrocarbons |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013525594A (ja) * | 2010-05-06 | 2013-06-20 | セイソル テクノロジー (プロプライエタリー) リミテッド | 高パラフィン系蒸留燃料を用いたディーゼルエンジン注入器汚損の改善 |
CA3080520C (en) | 2010-08-16 | 2022-01-04 | Chevron U.S.A. Inc. | Jet fuels having superior thermal stability |
US20150368576A1 (en) * | 2014-06-18 | 2015-12-24 | Shell Oil Company | Fischer tropsch derived diesel fuel formulation |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003105354A (ja) * | 2001-09-28 | 2003-04-09 | Nippon Oil Corp | 燃料油基材およびそれを含有する軽油組成物 |
WO2005021688A1 (en) * | 2003-09-03 | 2005-03-10 | Shell Internationale Research Maatschappij B.V. | Fuel compositions comprising fischer-tropsch derived fuel |
JP2006016541A (ja) * | 2004-07-02 | 2006-01-19 | Idemitsu Kosan Co Ltd | 燃料油組成物 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6180842B1 (en) * | 1998-08-21 | 2001-01-30 | Exxon Research And Engineering Company | Stability fischer-tropsch diesel fuel and a process for its production |
MY139353A (en) * | 2001-03-05 | 2009-09-30 | Shell Int Research | Process to prepare a lubricating base oil and a gas oil |
FR2839315B1 (fr) * | 2002-05-03 | 2006-04-28 | Totalfinaelf France | Additif pour ameliorer la stabilite thermique de compositions d'hydrocarbures |
NL1026215C2 (nl) * | 2003-05-19 | 2005-07-08 | Sasol Tech Pty Ltd | Koolwaterstofsamenstelling voor gebruik in CI motoren. |
JP4746826B2 (ja) * | 2003-06-05 | 2011-08-10 | 出光興産株式会社 | 燃料油組成物 |
JP5053638B2 (ja) * | 2003-09-17 | 2012-10-17 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 石油誘導ケロシンとフィッシャー・トロプシュ誘導ケロシンとのブレンド |
WO2005035695A2 (en) * | 2003-10-17 | 2005-04-21 | Sasol Technology (Pty) Ltd | Process for the production of multipurpose energy sources and multipurpose energy sources produced by said process |
US20060278565A1 (en) * | 2005-06-10 | 2006-12-14 | Chevron U.S.A. Inc. | Low foaming distillate fuel blend |
AR056027A1 (es) * | 2005-08-12 | 2007-09-12 | Shell Int Research | Composiciones de combustible |
BRPI0708012A2 (pt) * | 2006-02-03 | 2011-05-17 | Eastman Chem Co | composição, métodos para formar uma composição, e para aumentar a estabilidade oxidativa de pelo menos um ácido graxo ou éster de ácido graxo |
BRPI0715106A2 (pt) * | 2006-07-27 | 2013-06-04 | Shell Int Research | uso de um componente de combustÍvel derivado de fischer-tropsch, e, mÉtodos para formular uma composiÇço de combustÍvel, e para operar um sistema consumidor de combustÍvel |
-
2007
- 2007-02-28 JP JP2007049386A patent/JP2008214369A/ja active Pending
-
2008
- 2008-02-26 US US12/037,773 patent/US20080256846A1/en not_active Abandoned
- 2008-02-27 SG SG10201705367XA patent/SG10201705367XA/en unknown
- 2008-02-27 EP EP08709234A patent/EP2118243A1/en not_active Withdrawn
- 2008-02-27 AR ARP080100795A patent/AR065487A1/es unknown
- 2008-02-27 WO PCT/EP2008/052348 patent/WO2008104556A1/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003105354A (ja) * | 2001-09-28 | 2003-04-09 | Nippon Oil Corp | 燃料油基材およびそれを含有する軽油組成物 |
WO2005021688A1 (en) * | 2003-09-03 | 2005-03-10 | Shell Internationale Research Maatschappij B.V. | Fuel compositions comprising fischer-tropsch derived fuel |
JP2006016541A (ja) * | 2004-07-02 | 2006-01-19 | Idemitsu Kosan Co Ltd | 燃料油組成物 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010072838A2 (en) | 2008-12-26 | 2010-07-01 | Shell Internationale Research Maatschappij B.V. | Diesel fuel composition |
US10087376B2 (en) | 2010-01-20 | 2018-10-02 | Jx Nippon Oil & Energy Corporation | Method for producing monocyclic aromatic hydrocarbons |
WO2012161018A1 (ja) * | 2011-05-26 | 2012-11-29 | Jx日鉱日石エネルギー株式会社 | 軽油組成物およびその製造方法 |
JP2012246355A (ja) * | 2011-05-26 | 2012-12-13 | Jx Nippon Oil & Energy Corp | 軽油組成物およびその製造方法 |
CN103562358A (zh) * | 2011-05-26 | 2014-02-05 | 吉坤日矿日石能源株式会社 | 瓦斯油组合物及其制备方法 |
CN103562358B (zh) * | 2011-05-26 | 2015-07-08 | 吉坤日矿日石能源株式会社 | 瓦斯油组合物及其制备方法 |
US9200217B2 (en) | 2011-05-26 | 2015-12-01 | Jx Nippon Oil & Energy Corporation | Gas oil composition and method for producing same |
US9862897B2 (en) | 2013-02-21 | 2018-01-09 | Jx Nippon Oil & Energy Corporation | Method for producing monocyclic aromatic hydrocarbon |
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EP2118243A1 (en) | 2009-11-18 |
US20080256846A1 (en) | 2008-10-23 |
AR065487A1 (es) | 2009-06-10 |
WO2008104556A1 (en) | 2008-09-04 |
SG10201705367XA (en) | 2017-07-28 |
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