JP2007534126A5 - - Google Patents
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- JP2007534126A5 JP2007534126A5 JP2007508963A JP2007508963A JP2007534126A5 JP 2007534126 A5 JP2007534126 A5 JP 2007534126A5 JP 2007508963 A JP2007508963 A JP 2007508963A JP 2007508963 A JP2007508963 A JP 2007508963A JP 2007534126 A5 JP2007534126 A5 JP 2007534126A5
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- JP
- Japan
- Prior art keywords
- ions
- ion
- ion mobility
- voltage
- transient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 150000002500 ions Chemical class 0.000 claims description 804
- 230000005684 electric field Effects 0.000 claims description 125
- 230000001052 transient effect Effects 0.000 claims description 113
- 238000000766 differential mobility spectroscopy Methods 0.000 claims description 75
- 230000007423 decrease Effects 0.000 claims description 18
- 238000000926 separation method Methods 0.000 claims description 18
- 238000005040 ion trap Methods 0.000 claims description 17
- 230000001133 acceleration Effects 0.000 claims description 15
- 238000001871 ion mobility spectroscopy Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 12
- 238000013467 fragmentation Methods 0.000 claims description 11
- 238000006062 fragmentation reaction Methods 0.000 claims description 11
- 230000000737 periodic effect Effects 0.000 claims description 11
- 230000004888 barrier function Effects 0.000 claims description 8
- 238000003795 desorption Methods 0.000 claims description 7
- 238000000065 atmospheric pressure chemical ionisation Methods 0.000 claims description 6
- 238000005251 capillar electrophoresis Methods 0.000 claims description 6
- 238000001698 laser desorption ionisation Methods 0.000 claims description 6
- 238000004949 mass spectrometry Methods 0.000 claims description 6
- 238000004587 chromatography analysis Methods 0.000 claims description 4
- 238000000688 desorption electrospray ionisation Methods 0.000 claims description 4
- 238000000132 electrospray ionisation Methods 0.000 claims description 4
- 238000010265 fast atom bombardment Methods 0.000 claims description 4
- 238000009616 inductively coupled plasma Methods 0.000 claims description 4
- 230000002285 radioactive effect Effects 0.000 claims description 4
- 238000004992 fast atom bombardment mass spectroscopy Methods 0.000 claims description 3
- 238000004817 gas chromatography Methods 0.000 claims description 3
- 238000004811 liquid chromatography Methods 0.000 claims description 3
- 238000000816 matrix-assisted laser desorption--ionisation Methods 0.000 claims description 3
- PXHVJJICTQNCMI-RNFDNDRNSA-N nickel-63 Chemical compound [63Ni] PXHVJJICTQNCMI-RNFDNDRNSA-N 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 238000004808 supercritical fluid chromatography Methods 0.000 claims description 3
- 208000035699 Distal ileal obstruction syndrome Diseases 0.000 claims description 2
- 238000004252 FT/ICR mass spectrometry Methods 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000000451 chemical ionisation Methods 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 claims description 2
- 238000004150 penning trap Methods 0.000 claims description 2
- 230000003252 repetitive effect Effects 0.000 claims description 2
- 102100022704 Amyloid-beta precursor protein Human genes 0.000 claims 1
- 101000823051 Homo sapiens Amyloid-beta precursor protein Proteins 0.000 claims 1
- DZHSAHHDTRWUTF-SIQRNXPUSA-N amyloid-beta polypeptide 42 Chemical compound C([C@@H](C(=O)N[C@@H](C)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CC(O)=O)C(=O)N[C@H](C(=O)NCC(=O)N[C@@H](CO)C(=O)N[C@@H](CC(N)=O)C(=O)N[C@@H](CCCCN)C(=O)NCC(=O)N[C@@H](C)C(=O)N[C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)NCC(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CCSC)C(=O)N[C@@H](C(C)C)C(=O)NCC(=O)NCC(=O)N[C@@H](C(C)C)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](C)C(O)=O)[C@@H](C)CC)C(C)C)NC(=O)[C@H](CC=1C=CC=CC=1)NC(=O)[C@@H](NC(=O)[C@H](CC(C)C)NC(=O)[C@H](CCCCN)NC(=O)[C@H](CCC(N)=O)NC(=O)[C@H](CC=1N=CNC=1)NC(=O)[C@H](CC=1N=CNC=1)NC(=O)[C@@H](NC(=O)[C@H](CCC(O)=O)NC(=O)[C@H](CC=1C=CC(O)=CC=1)NC(=O)CNC(=O)[C@H](CO)NC(=O)[C@H](CC(O)=O)NC(=O)[C@H](CC=1N=CNC=1)NC(=O)[C@H](CCCNC(N)=N)NC(=O)[C@H](CC=1C=CC=CC=1)NC(=O)[C@H](CCC(O)=O)NC(=O)[C@H](C)NC(=O)[C@@H](N)CC(O)=O)C(C)C)C(C)C)C1=CC=CC=C1 DZHSAHHDTRWUTF-SIQRNXPUSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 238000001004 secondary ion mass spectrometry Methods 0.000 claims 1
- 230000001360 synchronised effect Effects 0.000 claims 1
- 230000037230 mobility Effects 0.000 description 308
- 239000007789 gas Substances 0.000 description 46
- 239000002184 metal Substances 0.000 description 15
- 229910052751 metal Inorganic materials 0.000 description 15
- 239000000203 mixture Substances 0.000 description 9
- 238000011144 upstream manufacturing Methods 0.000 description 6
- 230000003247 decreasing effect Effects 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 239000002360 explosive Substances 0.000 description 3
- 230000002441 reversible effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000012491 analyte Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000004323 axial length Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- -1 tetrapropylammonium ions Chemical class 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 206010013654 Drug abuse Diseases 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000013375 chromatographic separation Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000013537 high throughput screening Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000005405 multipole Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 238000005036 potential barrier Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 208000011117 substance-related disease Diseases 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0408751.6A GB0408751D0 (en) | 2004-04-20 | 2004-04-20 | Mass spectrometer |
| GB0408751.6 | 2004-04-20 | ||
| US58447604P | 2004-07-02 | 2004-07-02 | |
| US60/584,476 | 2004-07-02 | ||
| PCT/GB2005/001488 WO2005104182A2 (en) | 2004-04-20 | 2005-04-20 | Mass spectrometer |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2007534126A JP2007534126A (ja) | 2007-11-22 |
| JP2007534126A5 true JP2007534126A5 (https=) | 2012-02-23 |
| JP4950028B2 JP4950028B2 (ja) | 2012-06-13 |
Family
ID=32344045
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007508963A Expired - Fee Related JP4950028B2 (ja) | 2004-04-20 | 2005-04-20 | 質量分析計 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9880129B2 (https=) |
| EP (1) | EP1738398B8 (https=) |
| JP (1) | JP4950028B2 (https=) |
| CA (1) | CA2562802C (https=) |
| GB (3) | GB0408751D0 (https=) |
| WO (1) | WO2005104182A2 (https=) |
Families Citing this family (85)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4513488B2 (ja) * | 2004-10-06 | 2010-07-28 | 株式会社日立製作所 | イオンモビリティー分析装置及びイオンモビリティー分析方法 |
| GB0424426D0 (en) | 2004-11-04 | 2004-12-08 | Micromass Ltd | Mass spectrometer |
| US8440968B2 (en) | 2005-02-14 | 2013-05-14 | Micromass Uk Limited | Ion-mobility analyser |
| GB0503010D0 (en) * | 2005-02-14 | 2005-03-16 | Micromass Ltd | Mass spectrometer |
| US9024255B2 (en) * | 2007-07-11 | 2015-05-05 | Excellims Corporation | Intelligently controlled spectrometer methods and apparatus |
| US8785848B2 (en) * | 2007-07-11 | 2014-07-22 | Excellims Corporation | Parallel ion mass and ion mobility analysis |
| US7700913B2 (en) * | 2006-03-03 | 2010-04-20 | Ionsense, Inc. | Sampling system for use with surface ionization spectroscopy |
| US8026477B2 (en) | 2006-03-03 | 2011-09-27 | Ionsense, Inc. | Sampling system for use with surface ionization spectroscopy |
| CN101063672A (zh) | 2006-04-29 | 2007-10-31 | 复旦大学 | 离子阱阵列 |
| RU2327245C2 (ru) * | 2006-05-03 | 2008-06-20 | Евгений Васильевич Мамонтов | Способ масс-селективного анализа ионов по времени пролета и устройство для его осуществления |
| GB0624679D0 (en) * | 2006-12-11 | 2007-01-17 | Shimadzu Corp | A time-of-flight mass spectrometer and a method of analysing ions in a time-of-flight mass spectrometer |
| DE102008005281B4 (de) | 2008-01-19 | 2014-09-18 | Airsense Analytics Gmbh | Verfahren und Vorrichtung zur Detektion und Identifizierung von Gasen |
| RU2387043C2 (ru) * | 2008-04-10 | 2010-04-20 | Евгений Васильевич Мамонтов | Способ формирования двумерного линейного поля и устройство для его осуществления |
| CN101738429B (zh) * | 2008-11-26 | 2013-04-03 | 岛津分析技术研发（上海）有限公司 | 离子分离、富集与检测装置 |
| US8207497B2 (en) | 2009-05-08 | 2012-06-26 | Ionsense, Inc. | Sampling of confined spaces |
| US8716655B2 (en) * | 2009-07-02 | 2014-05-06 | Tricorntech Corporation | Integrated ion separation spectrometer |
| US8822949B2 (en) | 2011-02-05 | 2014-09-02 | Ionsense Inc. | Apparatus and method for thermal assisted desorption ionization systems |
| US8901488B1 (en) | 2011-04-18 | 2014-12-02 | Ionsense, Inc. | Robust, rapid, secure sample manipulation before during and after ionization for a spectroscopy system |
| RU2476870C1 (ru) * | 2011-11-02 | 2013-02-27 | Федеральное государственное унитарное предприятие "Научно-исследовательский технологический институт имени А.П. Александрова" | Способ разделения и регистрации ионов в газе (варианты) |
| WO2013067366A2 (en) * | 2011-11-02 | 2013-05-10 | Leco Corporation | Ion mobility spectrometer |
| US9230790B2 (en) | 2011-12-30 | 2016-01-05 | Dh Technologies Development Pte. Ltd. | DC ion funnels |
| GB2519007B (en) * | 2012-07-31 | 2018-09-19 | Leco Corp | Ion mobility spectrometer with high throughput |
| WO2014036465A1 (en) * | 2012-08-31 | 2014-03-06 | The Regents Of The University Of California | A spatially alternating asymmetric field ion mobility spectrometry |
| FI2906937T3 (fi) | 2012-10-10 | 2023-03-17 | Smiths Detection Watford Ltd | Kannettava todisteenkeruujärjestelmä ja menetelmä järjestelmän käyttämiseksi |
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| US8809769B2 (en) | 2012-11-29 | 2014-08-19 | Bruker Daltonics, Inc. | Apparatus and method for cross-flow ion mobility spectrometry |
| US9916969B2 (en) * | 2013-01-14 | 2018-03-13 | Perkinelmer Health Sciences Canada, Inc. | Mass analyser interface |
| CN104112642B (zh) * | 2013-04-18 | 2017-05-24 | 岛津分析技术研发（上海）有限公司 | 离子导引装置以及离子导引方法 |
| DE112014005868B4 (de) | 2013-12-24 | 2026-03-26 | Micromass Uk Limited | Wanderwellen-IMS mit Gegenstrom von Gas |
| WO2015107612A1 (ja) * | 2014-01-14 | 2015-07-23 | 株式会社島津製作所 | イオン移動度分析装置及び質量分析装置 |
| US10371665B2 (en) * | 2014-06-06 | 2019-08-06 | Micromass Uk Limited | Mobility selective attenuation |
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| US10607826B2 (en) | 2015-07-28 | 2020-03-31 | University Of Florida Research Foundation, Incorporated | Atmospheric pressure ion guide |
| WO2017042918A1 (ja) * | 2015-09-09 | 2017-03-16 | 株式会社島津製作所 | イオン移動度分析装置 |
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| WO2017195723A1 (ja) * | 2016-05-13 | 2017-11-16 | 株式会社島津製作所 | 粒子荷電装置 |
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| GB2562690B (en) | 2016-09-27 | 2022-11-02 | Micromass Ltd | Post-separation mobility analyser |
| US11668719B2 (en) | 2017-09-20 | 2023-06-06 | The Trustees Of Indiana University | Methods for resolving lipoproteins with mass spectrometry |
| JP7102733B2 (ja) | 2018-01-04 | 2022-07-20 | 株式会社リコー | イオン検出装置及び電界非対称波形イオン移動度分光分析システム |
| US11232941B2 (en) | 2018-01-12 | 2022-01-25 | The Trustees Of Indiana University | Electrostatic linear ion trap design for charge detection mass spectrometry |
| CN112840434A (zh) | 2018-05-14 | 2021-05-25 | 莫比莱昂系统有限公司 | 离子迁移率谱仪与质谱仪的耦合 |
| JP6874906B2 (ja) * | 2018-05-16 | 2021-05-19 | 株式会社島津製作所 | 飛行時間型質量分析装置 |
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| GB201808892D0 (en) | 2018-05-31 | 2018-07-18 | Micromass Ltd | Mass spectrometer |
| GB201808893D0 (en) | 2018-05-31 | 2018-07-18 | Micromass Ltd | Bench-top time of flight mass spectrometer |
| GB201808894D0 (en) | 2018-05-31 | 2018-07-18 | Micromass Ltd | Mass spectrometer |
| GB201808936D0 (en) | 2018-05-31 | 2018-07-18 | Micromass Ltd | Bench-top time of flight mass spectrometer |
| GB201808932D0 (en) | 2018-05-31 | 2018-07-18 | Micromass Ltd | Bench-top time of flight mass spectrometer |
| US11373849B2 (en) | 2018-05-31 | 2022-06-28 | Micromass Uk Limited | Mass spectrometer having fragmentation region |
| GB201808912D0 (en) | 2018-05-31 | 2018-07-18 | Micromass Ltd | Bench-top time of flight mass spectrometer |
| EP4376051A3 (en) | 2018-06-04 | 2024-09-25 | The Trustees of Indiana University | Charge detection mass spectrometry with real time analysis and signal optimization |
| WO2019236139A1 (en) | 2018-06-04 | 2019-12-12 | The Trustees Of Indiana University | Interface for transporting ions from an atmospheric pressure environment to a low pressure environment |
| JP7398810B2 (ja) | 2018-06-04 | 2023-12-15 | ザ・トラスティーズ・オブ・インディアナ・ユニバーシティー | 静電線形イオン・トラップにイオンを捕獲する装置および方法 |
| WO2019236143A1 (en) | 2018-06-04 | 2019-12-12 | The Trustees Of Indiana University | Apparatus and method for calibrating or resetting a charge detector |
| JP7398811B2 (ja) | 2018-06-04 | 2023-12-15 | ザ・トラスティーズ・オブ・インディアナ・ユニバーシティー | 高スループット電荷検出質量分光分析のためのイオン・トラップ・アレイ |
| US12089932B2 (en) | 2018-06-05 | 2024-09-17 | Trace Matters Scientific Llc | Apparatus, system, and method for transferring ions |
| JP7285023B2 (ja) | 2018-11-20 | 2023-06-01 | ザ・トラスティーズ・オブ・インディアナ・ユニバーシティー | 単一粒子質量分光分析のためのオービトラップ |
| CA3118567A1 (en) | 2018-12-03 | 2020-06-11 | The Trustees Of Indiana University | Apparatus and method for simultaneously analyzing multiple ions with an electrostatic linear ion trap |
| US10651025B1 (en) | 2018-12-21 | 2020-05-12 | Thermo Finnigan Llc | Orthogonal-flow ion trap array |
| WO2020219527A1 (en) | 2019-04-23 | 2020-10-29 | The Trustees Of Indiana University | Identification of sample subspecies based on particle charge behavior under structural change-inducing sample conditions |
| WO2020237037A1 (en) | 2019-05-21 | 2020-11-26 | MOBILion Systems, Inc. | Voltage control for ion mobility separation |
| CA3156003A1 (en) * | 2019-09-25 | 2021-04-01 | The Trustees Of Indiana University | Apparatus and method for pulsed mode charge detection mass spectrometry |
| KR102849777B1 (ko) | 2019-10-10 | 2025-08-22 | 더 트러스티즈 오브 인디애나 유니버시티 | 입자들을 식별, 선택 및 정제하기 위한 시스템 및 방법 |
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| JP7690209B2 (ja) | 2019-12-18 | 2025-06-10 | ザ・トラスティーズ・オブ・インディアナ・ユニバーシティー | 電荷測定装置を有する質量分析計 |
| CN111029241B (zh) * | 2019-12-19 | 2024-10-01 | 中国科学院合肥物质科学研究院 | 一种离子迁移速度补偿的离子迁移谱仪及方法 |
| EP4100991B1 (en) | 2020-02-03 | 2025-01-29 | The Trustees of Indiana University | A charge detection mass spectrometer and related method |
| GB2593667A (en) | 2020-02-10 | 2021-10-06 | Thermo Electron Mfg Limited | Method and apparatus for separating ions |
| KR102133334B1 (ko) * | 2020-02-25 | 2020-07-14 | 영인에이스 주식회사 | 질량분석기 |
| US12163920B2 (en) | 2020-04-06 | 2024-12-10 | MOBILion Systems, Inc. | Systems and methods for two-dimensional mobility based filtering of ions |
| US11662333B2 (en) | 2020-04-06 | 2023-05-30 | MOBILion Systems, Inc. | Systems and methods for two-dimensional mobility based filtering of ions |
| US11114290B1 (en) | 2020-05-07 | 2021-09-07 | Thermo Finnigan Llc | Ion funnels and systems incorporating ion funnels |
| US11581179B2 (en) | 2020-05-07 | 2023-02-14 | Thermo Finnigan Llc | Ion funnels and systems incorporating ion funnels |
| CN115885176A (zh) | 2020-05-22 | 2023-03-31 | 莫比莱昂系统有限公司 | 用于俘获和积累离子的方法和装置 |
| WO2021247820A1 (en) | 2020-06-05 | 2021-12-09 | MOBILion Systems, Inc. | Apparatus and methods for ion manipulation having improved duty cycle |
| CN111710586B (zh) * | 2020-06-15 | 2024-07-05 | 成都西奇仪器有限公司 | 一种循环式离子迁移区结构及高分辨率离子迁移谱仪 |
| JP7498653B2 (ja) * | 2020-12-09 | 2024-06-12 | シャープ株式会社 | イオン生成装置およびイオン移動度分析装置 |
| WO2023203621A1 (ja) * | 2022-04-18 | 2023-10-26 | 株式会社島津製作所 | 質量分析装置 |
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| US6933496B2 (en) * | 2000-06-23 | 2005-08-23 | The Regents Of The University Of California | Ion mobility sensor |
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| US6744043B2 (en) * | 2000-12-08 | 2004-06-01 | Mds Inc. | Ion mobilty spectrometer incorporating an ion guide in combination with an MS device |
| JP2005513414A (ja) | 2001-06-30 | 2005-05-12 | シオネックス・コーポレーション | 電界中におけるデータ収集および未知イオン種識別のためのシステム |
| US6630662B1 (en) * | 2002-04-24 | 2003-10-07 | Mds Inc. | Setup for mobility separation of ions implementing an ion guide with an axial field and counterflow of gas |
| GB2390478B (en) | 2002-05-17 | 2004-06-02 | Micromass Ltd | Mass spectrometer |
| JP3971958B2 (ja) * | 2002-05-28 | 2007-09-05 | 株式会社日立ハイテクノロジーズ | 質量分析装置 |
| US6791078B2 (en) * | 2002-06-27 | 2004-09-14 | Micromass Uk Limited | Mass spectrometer |
-
2004
- 2004-04-20 GB GBGB0408751.6A patent/GB0408751D0/en not_active Ceased
-
2005
- 2005-04-20 CA CA2562802A patent/CA2562802C/en not_active Expired - Fee Related
- 2005-04-20 EP EP05734046.5A patent/EP1738398B8/en not_active Expired - Lifetime
- 2005-04-20 GB GB0508007A patent/GB2413433B/en not_active Expired - Fee Related
- 2005-04-20 GB GB0619276A patent/GB2428875B/en not_active Expired - Fee Related
- 2005-04-20 WO PCT/GB2005/001488 patent/WO2005104182A2/en not_active Ceased
- 2005-04-20 US US11/568,167 patent/US9880129B2/en active Active
- 2005-04-20 JP JP2007508963A patent/JP4950028B2/ja not_active Expired - Fee Related
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