JP2007516064A5 - - Google Patents
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- Publication number
- JP2007516064A5 JP2007516064A5 JP2006519986A JP2006519986A JP2007516064A5 JP 2007516064 A5 JP2007516064 A5 JP 2007516064A5 JP 2006519986 A JP2006519986 A JP 2006519986A JP 2006519986 A JP2006519986 A JP 2006519986A JP 2007516064 A5 JP2007516064 A5 JP 2007516064A5
- Authority
- JP
- Japan
- Prior art keywords
- acetic acid
- catalyst system
- rhenium
- osmium
- cadmium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 5
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N Methyl acetate Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 2
- INQOMBQAUSQDDS-UHFFFAOYSA-N Methyl iodide Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N Rhenium Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
- 239000005092 Ruthenium Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- 238000005810 carbonylation reaction Methods 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- 229910052762 osmium Inorganic materials 0.000 description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 2
- 229910052702 rhenium Inorganic materials 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
本発明は、また、酢酸メチルと有限濃度の水と、酢酸およびイリジウムカルボニル化触媒と、ヨウ化メチル助触媒と、必要に応じルテニウム、オスミウム、レニウム、亜鉛、ガリウム、タングステン、カドミウム、水銀並びにインジウムの少なくとも1種および、少なくとも1種の非ヒドロハロゲノ酸促進剤を含む触媒系とを含む液体反応組成物中で、一酸化炭素とメタノールおよび/またはその反応性誘導体とを反応させることによる酢酸の製造方法を提供する。
本発明は、さらに、触媒系がイリジウムカルボニル化触媒と、ヨウ化メチル助触媒と、必要に応じルテニウム、オスミウム、レニウム、亜鉛、ガリウム、タングステン、カドミウム、水銀およびインジウムの少なくとも1種並びに、少なくとも1種の非ヒドロハロゲノ酸促進剤を含む酢酸の製造触媒系の使用を提供する。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0316756.6 | 2003-07-17 | ||
GBGB0316756.6A GB0316756D0 (en) | 2003-07-17 | 2003-07-17 | Process |
PCT/GB2004/002686 WO2005009939A1 (en) | 2003-07-17 | 2004-06-23 | Catalyst and process for the production of acetic acid |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2007516064A JP2007516064A (ja) | 2007-06-21 |
JP2007516064A5 true JP2007516064A5 (ja) | 2012-04-19 |
JP5336701B2 JP5336701B2 (ja) | 2013-11-06 |
Family
ID=27764007
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006519986A Expired - Fee Related JP5336701B2 (ja) | 2003-07-17 | 2004-06-23 | 酢酸の製造用触媒および方法 |
Country Status (15)
Country | Link |
---|---|
US (1) | US7915446B2 (ja) |
EP (1) | EP1646602A1 (ja) |
JP (1) | JP5336701B2 (ja) |
KR (1) | KR101286321B1 (ja) |
CN (1) | CN1823031B (ja) |
BR (1) | BRPI0412708B1 (ja) |
CA (1) | CA2532234C (ja) |
GB (1) | GB0316756D0 (ja) |
MY (1) | MY146559A (ja) |
NO (1) | NO20060759L (ja) |
RS (1) | RS20060025A (ja) |
RU (1) | RU2336262C2 (ja) |
TW (1) | TWI343371B (ja) |
UA (1) | UA89475C2 (ja) |
WO (1) | WO2005009939A1 (ja) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0427821D0 (en) | 2004-12-17 | 2005-01-19 | Bp Chem Int Ltd | Catalyst and process |
GB0601863D0 (en) * | 2006-01-30 | 2006-03-08 | Bp Chem Int Ltd | Process |
GB0601865D0 (en) * | 2006-01-30 | 2006-03-08 | Bp Chem Int Ltd | Process |
GB0601861D0 (en) * | 2006-01-30 | 2006-03-08 | Bp Chem Int Ltd | Process |
EP2075070A1 (en) * | 2007-12-13 | 2009-07-01 | BP Chemicals Limited | Catalyst recovery process |
EP2303447B1 (en) * | 2008-04-29 | 2014-10-15 | Celanese International Corporation | Methanol carbonylation system having absorber with multiple solvent options |
US9421522B2 (en) | 2011-12-28 | 2016-08-23 | Eastman Chemical Company | Iridium catalysts for carbonylation |
PT2970890T (pt) | 2013-03-14 | 2020-04-24 | Massachusetts Inst Technology | Composições e métodos para expansão e cultura de células estaminais epiteliais |
JP2019506153A (ja) | 2016-01-08 | 2019-03-07 | マサチューセッツ インスティテュート オブ テクノロジー | 分化した腸内分泌細胞およびインスリン産生細胞の作製 |
US10201540B2 (en) | 2016-03-02 | 2019-02-12 | Frequency Therapeutics, Inc. | Solubilized compositions for controlled proliferation of stem cells / generating inner ear hair cells using GSK3 inhibitors: I |
US11260130B2 (en) | 2016-03-02 | 2022-03-01 | Frequency Therapeutics, Inc. | Solubilized compositions for controlled proliferation of stem cells / generating inner ear hair cells using a GSK3 inhibitor: IV |
US10213511B2 (en) | 2016-03-02 | 2019-02-26 | Frequency Therapeutics, Inc. | Thermoreversible compositions for administration of therapeutic agents |
CN108067222B (zh) * | 2016-11-15 | 2020-09-22 | 中国科学院大连化学物理研究所 | 活性炭载体负载的硫促进的铱基催化剂及其制备和应用 |
CA3048220A1 (en) | 2016-12-30 | 2018-07-05 | Frequency Therapeutics, Inc. | 1h-pyrrole-2,5-dione compounds and methods of using them to induce self-renewal of stem/progenitor supporting cells |
CN109759055B (zh) * | 2017-11-09 | 2022-04-15 | 中国科学院大连化学物理研究所 | 一种活性炭负载的含硫铱基催化剂及其制备与应用 |
CN108097319A (zh) * | 2017-12-19 | 2018-06-01 | 宁夏大学 | 羰基化制备醋酸的铑钌联用双金属催化剂及其制备方法 |
WO2020037326A1 (en) | 2018-08-17 | 2020-02-20 | Frequency Therapeutics, Inc. | Compositions and methods for generating hair cells by downregulating foxo |
AU2019321641A1 (en) | 2018-08-17 | 2021-04-15 | Frequency Therapeutics, Inc. | Compositions and methods for generating hair cells by upregulating Jag-1 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1941449C3 (de) * | 1968-08-15 | 1979-07-26 | Monsanto Co., St. Louis, Mo. (V.St.A.) | Verfahren zur Herstellung von Monocarbonsäuren |
JPS4924459B1 (ja) * | 1969-08-27 | 1974-06-22 | ||
CA1195340A (en) * | 1980-11-14 | 1985-10-15 | The Standard Oil Company | Selective hydrocarboxylation of propylene to isobutyric acid |
US4629809A (en) * | 1983-07-21 | 1986-12-16 | Texaco Inc. | Process for selectively preparing acetic acid by carbonylation of methanol in the presence of a novel iodide-free catalyst system |
US5281751A (en) | 1983-12-02 | 1994-01-25 | Union Carbide Chemicals And Plastics Company Inc. | Synergistic production of carboxylic acids from alcohols |
JP2782363B2 (ja) * | 1989-08-25 | 1998-07-30 | 日本石油化学株式会社 | α−(4−イソブチルフェニル)プロピオン酸またはそのエステルの製造方法 |
US5672743A (en) * | 1993-09-10 | 1997-09-30 | Bp Chemicals Limited | Process for the production of acetic acid |
FR2703351A1 (fr) | 1993-03-31 | 1994-10-07 | Rhone Poulenc Chimie | Procédé de préparation d'acides carboxyliques ou des esters correspondants en présence d'un catalyseur à base de rhodium et d'iridium. |
US5696284A (en) * | 1995-06-21 | 1997-12-09 | Bp Chemicals Limited | Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof |
US5710325A (en) * | 1996-11-01 | 1998-01-20 | E. I. Du Pont De Nemours And Company | Manufacture of adipic acid |
US5831120A (en) * | 1996-11-19 | 1998-11-03 | Watson; Derrick John | Process for the production of acetic acid |
GB9626324D0 (en) * | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
US6521783B1 (en) * | 1998-01-29 | 2003-02-18 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for preparing oxygenates |
GB9819079D0 (en) * | 1998-09-03 | 1998-10-28 | Bp Chem Int Ltd | Carbonylation process |
GB9926855D0 (en) * | 1999-11-12 | 2000-01-12 | Bp Chem Int Ltd | Process |
GB9926854D0 (en) | 1999-11-12 | 2000-01-12 | Bp Chem Int Ltd | Process |
GB0212974D0 (en) | 2002-06-06 | 2002-07-17 | Bp Chem Int Ltd | Process |
-
2003
- 2003-07-17 GB GBGB0316756.6A patent/GB0316756D0/en not_active Ceased
-
2004
- 2004-06-23 UA UAA200601526A patent/UA89475C2/uk unknown
- 2004-06-23 KR KR1020057025331A patent/KR101286321B1/ko not_active IP Right Cessation
- 2004-06-23 EP EP04743037A patent/EP1646602A1/en not_active Withdrawn
- 2004-06-23 RS YUP-2006/0025A patent/RS20060025A/sr unknown
- 2004-06-23 JP JP2006519986A patent/JP5336701B2/ja not_active Expired - Fee Related
- 2004-06-23 US US10/563,920 patent/US7915446B2/en not_active Expired - Fee Related
- 2004-06-23 CN CN200480020623XA patent/CN1823031B/zh not_active Expired - Fee Related
- 2004-06-23 RU RU2006104673/04A patent/RU2336262C2/ru not_active IP Right Cessation
- 2004-06-23 WO PCT/GB2004/002686 patent/WO2005009939A1/en active Application Filing
- 2004-06-23 BR BRPI0412708-0B1A patent/BRPI0412708B1/pt not_active IP Right Cessation
- 2004-06-23 CA CA2532234A patent/CA2532234C/en not_active Expired - Fee Related
- 2004-06-25 TW TW093118521A patent/TWI343371B/zh not_active IP Right Cessation
- 2004-07-14 MY MYPI20042811A patent/MY146559A/en unknown
-
2006
- 2006-02-17 NO NO20060759A patent/NO20060759L/no unknown
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