JP2006507345A5 - - Google Patents

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JP2006507345A5
JP2006507345A5 JP2004555427A JP2004555427A JP2006507345A5 JP 2006507345 A5 JP2006507345 A5 JP 2006507345A5 JP 2004555427 A JP2004555427 A JP 2004555427A JP 2004555427 A JP2004555427 A JP 2004555427A JP 2006507345 A5 JP2006507345 A5 JP 2006507345A5
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bonded
heteroatoms
different
same
heteroatom
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JP2004555427A
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JP4977322B2 (en
JP2006507345A (en
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Priority claimed from US10/301,884 external-priority patent/US20040102311A1/en
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Priority claimed from PCT/US2003/036049 external-priority patent/WO2004047972A2/en
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Claims (8)

式
Figure 2006507345
 （ここで、Ｍは３ｄ、４ｄ又は５ｄの遷移金属であり；各ＸはＭに結合した原子または基であり、そして同一であるかあるいは異なっており；Ｒ1およびＲ2は同一、あるいは異なっており、そして置換あるいは非置換のシクロペンタジエニル基であり；ＲBはＲ1およびＲ2の間の構造的架橋であり、そしてＭに結合する３つのヘテロ原子を含んでなり、Ｒ1およびＲ2の各々はＲBの同一の、あるいは異なるヘテロ原子に結合し、ヘテロ原子は又Ｍにも結合し；ＺはＭの配位数であり、そして４よりも大きいか、あるいは４に等しく；ｍはＭとＲＢのヘテロ原子の間の結合数であり、そしてｍ≧２であり；そしてＲ1、Ｒ2およびＲBはＣ1、Ｃ2あるいはＣS対称性を付与するように選択される）
を含んでなる触媒系。 formula
Figure 2006507345
 (Wherein M is a 3d, 4d or 5d transition metal; each X is an atom or group attached to M and is the same or different; R 1 and R 2 are the same or different And a substituted or unsubstituted cyclopentadienyl group; R B is a structural bridge between R 1 and R 2 and comprises three heteroatoms bonded to M, R 1 And R 2 are each bonded to the same or different heteroatom of R B , the heteroatom is also bonded to M; Z is the coordination number of M and is greater than 4 or Equally; m is the number of bonds between the heteroatoms of M and RB, and m ≧ 2, and R 1 , R 2 and R B give C 1 , C 2 or C S symmetry Selected)
A catalyst system comprising: ヘテロ原子がＯ、Ｎ、Ｓ、およびＰからなる群から選択される請求項１に記載の系。   The system of claim 1 wherein the heteroatom is selected from the group consisting of O, N, S, and P. Ｒ1が前記ヘテロ原子の１つに結合し、そしてＲ2が前記ヘテロ原子の異なる１つに結合する請求項１に記載の系。 The system of claim 1 , wherein R 1 is bonded to one of the heteroatoms and R 2 is bonded to a different one of the heteroatoms. Ｍが本質的にＦｅ、ＣｏおよびＮｉからなる群から選択される請求項１に記載の系。   The system of claim 1 wherein M is selected from the group consisting essentially of Fe, Co and Ni. ＭがＦｅであり、そしてＲ1が前記３個のヘテロ原子の１つに結合し、そしてＲ2はＲ1が結合するヘテロ原子と異なるヘテロ原子に結合し；
ＭがＦｅ、ＣｏおよびＮｉから選択される請求項１に記載の系。 M is Fe and R 1 is bonded to one of the three heteroatoms, and R 2 is bonded to a heteroatom different from the heteroatom to which R 1 is bonded;
The system of claim 1 wherein M is selected from Fe, Co and Ni. 各Ｘがハライドおよび置換あるいは非置換の炭化水素からなる群から独立に選択される請求項５に記載の系。   6. A system according to claim 5, wherein each X is independently selected from the group consisting of halides and substituted or unsubstituted hydrocarbons. 賦活剤を式
Figure 2006507345
 （ここで、Ｍは３ｄ、４ｄ又は５ｄの遷移金属であり；各ＸはＭに結合した原子または基であり、そして同一であるかあるいは異なり；Ｒ1およびＲ2は同一であるか、あるいは異なり、そして置換あるいは非置換のシクロペンタジエニル基であり；ＲBはＲ1およびＲ2の間の構造的架橋であり、そしてＭに結合する３個のヘテロ原子を含んでなり、Ｒ1およびＲ2の各々がＲBの同一の、あるいは異なるヘテロ原子に結合し、ヘテロ原子はＭにも結合し；ＺはＭの配位数であり、そして４よりも大きいか、あるいは４に等しく；ｍはＭとＲBのヘテロ原子の間の結合数であり、そしてｍ≧２であり；そしてＲ1、Ｒ2およびＲBが触媒成分にＣ1、Ｃ2あるいはＣS対称性を付与するように選択される）
を有する架橋化合物と接触させることを含んでなる触媒系を製造する方法。 Activator formula
Figure 2006507345
 (Wherein M is a 3d, 4d or 5d transition metal; each X is an atom or group bonded to M and is the same or different; R 1 and R 2 are the same, or Different and substituted or unsubstituted cyclopentadienyl groups; R B is a structural bridge between R 1 and R 2 and comprises three heteroatoms bonded to M, R 1 And R 2 are each bonded to the same or different heteroatom of R B , the heteroatom is also bonded to M; Z is the coordination number of M and is greater than or equal to 4 M is the number of bonds between the heteroatoms of M and R B and m ≧ 2, and R 1 , R 2 and R B impart C 1 , C 2 or C S symmetry to the catalyst component; Selected to do)
A process for producing a catalyst system comprising contacting with a crosslinking compound having 式
Figure 2006507345
 （ここで、Ｍは３ｄ、４ｄ又は５ｄの遷移金属であり；各ＸはＭに結合した原子または基であり、そして同一であるかあるいは異なり；Ｒ1およびＲ2は同一、あるいは異なり、そして置換あるいは非置換のシクロペンタジエニル基であり；ＲBはＲ1およびＲ2の間の構造的架橋であり、そしてＭに結合する３個のヘテロ原子を含んでなり、Ｒ1およびＲ2の各々はＲBの同一の、あるいは異なるヘテロ原子に結合し、ヘテロ原子はＭにも結合し；ＺはＭの配位数であり、そして４よりも大きいか、あるいは４に等しく；ｍはＭとＲBのヘテロ原子の間の結合数であり、そしてｍ≧２である）
を含んでなる触媒系。 formula
Figure 2006507345
 (Wherein M is a 3d, 4d or 5d transition metal; each X is an atom or group attached to M and is the same or different; R 1 and R 2 are the same or different; and a substituted or unsubstituted cyclopentadienyl group; R B is a structural bridge between R 1 and R 2, and comprises a three heteroatoms bonded to M, R 1 and R 2 Are bonded to the same or different heteroatoms of R B , the heteroatoms are also bonded to M; Z is the coordination number of M and is greater than or equal to 4; Number of bonds between M and R B heteroatoms, and m ≧ 2)
A catalyst system comprising:
JP2004555427A 2002-11-21 2003-11-12 A new catalyst structure for olefin polymerization. Expired - Fee Related JP4977322B2 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US10/301,884 2002-11-21
US10/301,884 US20040102311A1 (en) 2002-11-21 2002-11-21 Bridged metallocene catalyst component, method of making, polyolefin catalyst having C1, C2, or Cs symmetry, methods of making, methods of polymerizing, olefins and products made thereof
US10/692,068 US6894180B2 (en) 2002-11-21 2003-10-23 Catalyst structure for olefin polymerization
US10/692,068 2003-10-23
PCT/US2003/036049 WO2004047972A2 (en) 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization

Publications (3)

Publication Number Publication Date
JP2006507345A JP2006507345A (en) 2006-03-02
JP2006507345A5 true JP2006507345A5 (en) 2006-12-28
JP4977322B2 JP4977322B2 (en) 2012-07-18

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JP2004555427A Expired - Fee Related JP4977322B2 (en) 2002-11-21 2003-11-12 A new catalyst structure for olefin polymerization.

Country Status (6)

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EP (1) EP1562705A4 (en)
JP (1) JP4977322B2 (en)
KR (1) KR20050085108A (en)
AU (1) AU2003285202A1 (en)
CA (1) CA2503986A1 (en)
WO (1) WO2004047972A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7034157B2 (en) * 2003-10-23 2006-04-25 Fina Technology, Inc. Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins
AU2006206653A1 (en) * 2005-01-19 2006-07-27 Merck & Co., Inc. Aminomethyl beta-secretase inhibitors for the treatment of Alzheimer's disease
EP1746111A1 (en) * 2005-07-19 2007-01-24 Total Petrochemicals Research Feluy Polymerisation catalyst system based on dioxime ligands
AR124328A1 (en) * 2020-12-15 2023-03-15 Shell Int Research AN OLIGOMERIZATION CATALYST, METHOD OF PREPARATION AND PROCESS FOR USING THE CATALYST
CN114874362B (en) * 2022-03-18 2023-05-23 中国科学院青岛生物能源与过程研究所 Pyridinimine oxime iron catalyst, preparation method thereof and application thereof in conjugated diene polymerization

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0889910B1 (en) * 1996-03-27 2003-03-19 Dow Global Technologies Inc. Solution polymerization process with dispersed catalyst activator
EP0951489B1 (en) * 1997-01-13 2004-10-06 E.I. Du Pont De Nemours And Company Polymerization of propylene
JP2000001512A (en) * 1998-06-16 2000-01-07 Mitsui Chemicals Inc Catalyst for olefin polymerization and method for polymerizing olefin
EP1004599A4 (en) * 1998-06-16 2003-06-04 Mitsui Chemicals Inc Catalyst for olefin polymerization and method of polymerizing olefin
CA2347385A1 (en) * 1999-09-02 2001-03-15 Haruhito Sato Transition metal compounds, catalysts for the production of .alpha.-olefins and process therefor
CN1164534C (en) * 2001-07-20 2004-09-01 中国科学院化学研究所 Iron catalyst and its prepn and application
ATE344268T1 (en) * 2001-08-01 2006-11-15 Shell Int Research LIGANDS AND CATALYST SYSTEMS CONTAINING THEM FOR THE PRODUCTION OF LINEAR ALPHA-OLEFINS FROM ETHYLENE
JP2003206308A (en) * 2001-11-09 2003-07-22 Idemitsu Petrochem Co Ltd Polymerization catalyst for vinyl compound, polymer of vinyl compound and its manufacturing method, and composite resin comprising the polymer

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