EP1562705A4 - New catalyst structure for olefin polymerization - Google Patents

New catalyst structure for olefin polymerization

Info

Publication number
EP1562705A4
EP1562705A4 EP03779526A EP03779526A EP1562705A4 EP 1562705 A4 EP1562705 A4 EP 1562705A4 EP 03779526 A EP03779526 A EP 03779526A EP 03779526 A EP03779526 A EP 03779526A EP 1562705 A4 EP1562705 A4 EP 1562705A4
Authority
EP
European Patent Office
Prior art keywords
bonded
heteroatoms
heteroatom
different
same
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP03779526A
Other languages
German (de)
French (fr)
Other versions
EP1562705A2 (en
Inventor
Abbas Razavi
Margarito Lopez
Didier Baekelmans
Vladimir Marin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fina Technology Inc
Original Assignee
Fina Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/301,884 external-priority patent/US20040102311A1/en
Application filed by Fina Technology Inc filed Critical Fina Technology Inc
Publication of EP1562705A2 publication Critical patent/EP1562705A2/en
Publication of EP1562705A4 publication Critical patent/EP1562705A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms

Definitions

  • the present invention relates to catalyst components, catalyst systems, olefin polymerization, polymer compositions, and to articles made from such polymer compositions. More particularly the 0 present invention relates to catalysts having Ci, C 2 or Cs symmetry.
  • metallocene catalysts for olefin polymerization were commercialized that included a metallocene and an aluminum alkyl component, with a transition metal compound having two or more cyclopentadienyl (Cp) ring ligands. Accordingly, titanocenes, zirconocenes and hafnocenes have all been utilized as the transition metal component in such a metallocene containing catalyst systems for the production of polyolefins.
  • Metallocene catalysts can be cocatalyzed with an o alumoxane, rather than an aluminum alkyl, to provide a metallocene catalyst system of high activity for the production of polyolefins.
  • Group 3 metal catalysts such as scandium and yttrium complexes; Rare Earth Metal catalysts such as lanthanide and actinide-based catalysts stabilized with substituted cyclopentadienyl ligands; cationic Group 4 metal complexes including carbon-based ligands (such as alkyl ligands, allyl ligands, Cp analogues), including nitrogen-based ligands (such as amide ligands o either along or in combination with other ligands, amidinate ligands either alone or in combination with other ligands, and ⁇ -diketimate ligands), and including oxygen-based ligands (such as alkoxide ligands either alone or in combination with other ligands, bis-alkoxides with additional donors); neutral Group 4 metal complexes; Group 5 metal catalysts; Group 6 metal catalysts; Group 8 metal catalysts; Group 9 metal catalysts; Group 10 metal
  • WO 98/30612 discloses selected iron complexes of 2,6- pyridinecarboxaldehydebis(imines) and 2,6-diacyclpyridinebis(imines) as catalysts for the polymerization of propylene.
  • WO 99/12981 published on March 18, 1999, discloses catalyst complexes having a bridge comprising heteroatoms bridging R groups R 5 and R 7 , with these complexes taught as being useful "especially for polymerizing ethylene alone or for copolymerizing ethylene with higher 1-olefins" (page 2, lines 28-29).
  • the bridged R groups R 5 and R 7 are independently selected from hydrogen, halogen, and hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl. There is no teaching or suggestion to make a chiral complex suitable for producing high tacticity, crystallinity polypropylene.
  • the catalyst component can be chiral or non-chiral. In some embodiments it can be desirable
  • a method of making a bridged metallocene compound comprising contacting a metal compound of the formula M(X) 2 with a bridged compound of the formula Ri
  • a catalyst system comprising an activated bridged metallocene compound having the formula:
  • M, X, Ri, R 2 , m and Z are as defined above.
  • a method of making a catalyst system comprising contacting an activator with a bridged metallocene compound having the formula: Ri I
  • a method of forming polyolefins comprising contacting olefin monomer or mixture of monomers in the presence of an activated bridged metallocene compound having the formula:
  • a bridged metallocene catalyst component of the present invention can be represented by the following formula:
  • R 2 wherein M is a metal; each X is an atom or group covalently or ionically bonded to M and may be the same or different; Ri and R 2 may be the same or each may be different and are substituted or unsubstituted cyclopentadienyl or aromatic rings; R B is a structural bridge between the cylcopentadienyl or aromatic rings Ri and R 2 and imparts stereorigidity to the rings, and comprises at least one heteroatom bonded to M, with each of Ri and R 2 bonded to the same or different heteroatom of R B which heteroatom is also bonded to M; Z is the coordination number of M and is greater than or equal to 4; m is the number of bonds between M and the heteroatom(s) of R B and to impart stereorigidity m>2; because the number of bonds around M cannot exceed its coordination number Z; with Ri , R 2 and R B selected to provide a catalyst component with C i , C 2 or Cs symmetry.
  • the catalyst component can be chiral or non-chiral. In some embodiments it can be desirable to have the catalyst component that is chiral.
  • the metal M of the present invention may be any suitable metal useful as the metal component in metallocene catalysts. As a non-limiting example, M may be selected from among any metal as is known in the prior art to be useful as the metal component in metallocene catalysts. M will be selected to have a coordination number Z that is at least equal to the number of substituents bonded to M, that is, m number of R B heteroatom-to-metal bonds plus 2 (for both X's). M can be selected from among transition metals, lanthanides and actinides.
  • M can be selected from among group 3d, 4d or 5d transition metals, such as Fe, Co, Ni, Ru, Rh, Pd, Os, Ir and Pt. In some embodiments M can be desirably selected from among Fe, Co and Ni.
  • Ri and R 2 may be the same or each may be different and may be generally described as being substituted or unsubstituted cyclopentadienyl or aromatic rings. As non-limiting examples, Ri and R 2 may be selected from among any substituted or unsubstituted cylcopentadienyl or aromatic ring as are known in the art to be useful in metallocene catalysts. Non-limiting examples of hydrocarbon radicals suitable for use as Ri and R 2 are shown in the Examples below.
  • R ⁇ and R 2 may be described as a cylcopentadienyl or aromatic ring of the form (Cs(R') ), wherein each R' may be the same or each may be different, and R' is a hydrogen or a substituted or unsubstituted hydrocarbyl radical having 1-20 carbon atoms.
  • hydrocarbyl radicals suitable for use as R' include unsubstituted 5 and substituted alkyl, alkenyl, aryl, alkylaryl or arylalkyl radicals.
  • suitable hydrocarbyl radicals include unsubstituted and substituted methyl, ethyl, propyl, butyl, amyl, isoamyl, hexyl, isobutyl, heptyl, octyl, nonyl, decyl, cetyl, phenyl, methylene, ethylene, propylene, and other like groups.
  • RB acts as a structural bridge between the cylcopentadienyl or aromatic rings R ⁇ and R 2 and i o imparts stereorigidity to the rings, and comprises n heteroatoms ("HA") bonded to M.
  • the number of heteroatoms bonded to M can be n>l , n>2, and in some embodiments it can be desirable to have n>3.
  • An example of a suitable structural bridge R B is provided in the examples.
  • Heteroatoms useful in structural bridge R B include any that can be coordinated to the metal M by a "dative" bond, that is, a bond formed by the donation of a lone pair of electrons from the
  • RB comprises more than one heteroatom bonded to M, they may be the same heteroatom or different heteroatoms.
  • suitable heteroatoms include O, N, S, and P.
  • the heteroatoms are desirably N.
  • Ri is bonded to a heteroatom of R B which heteroatom is also bonded to M, either directly or indirectly through a different heteroatom.
  • R 2 is also bonded to a heteroatom of R B which
  • R1-R2- R B moiety can be any that does not interfere with the symmetry of the catalysts.
  • the Rl- R2- R B moiety can have the following configurations and still be within the scope of the claims of
  • R ls R 2 and RB are selected to provide a catalyst component that has Ci , C 2 or Cs symmetry. Any configuration of R] , R 2 and R B that does not disrupt the C i , C 2 or Cs symmetry known to those of ordinary skill in the art of preparing catalysts to be useful can be used with the present invention.
  • the catalyst component can be chiral or non-chiral. In some embodiments it can be desirable to have a catalyst component that is chiral.
  • Each X may be an atom or group as are known to be utilized with catalysts, and is generally covalently or ionically bonded to M. Each X may be the same or different, although commonly each X is the same. As a non-limiting example, X may be selected from among halide, sulphate, nitrate, thiolate, thiocarboxylate, BF “ , PF G “ , hydride, hydrocarbyloxide, carboxylate, substituted or unsubstituted hydrocarbyl, and heterohydrocarbyl.
  • Non-limiting examples of such atoms or groups are chloride, bromide, methyl, ethyl, propyl, butyl, octyl decyl, phenyl, benzyl, methoxide, ethoxide, isopropoxide, toxylate, triflate, fo ⁇ nate, acetate, phenoxide and benzoate. It can be desirable when X is a halide or a C ⁇ to C 20 hydrocarbyl. In some embodiments it is desirable that X is chloride.
  • the bridged catalyst component is generally made by contacting a bridge intermediate with a compound of the form M(X) 2 . More details are provided in the Examples.
  • the present invention further includes a catalyst system comprising one or more of the above described bridged catalyst components and one or more activators and or cocatalysts (as described in greater detail below) or the reaction product of an activator and/or cocatalyst, such as for example, methylaluminoxane (MAO) and optionally an alkylation/scavenging agent such as trialkylaluminum compound, for example triethylalummum (TEAL).
  • MAO methylaluminoxane
  • TEAL triethylalummum
  • the above described metallocene catalyst components may also be supported as is known in the metallocene art.
  • Typical supports may be a support such as talc, an inorganic oxide, clay, and clay minerals, ion-exchanged layered compounds, diatomaceous earth, silicates, zeolites or a resinous support material such as a polyolefin.
  • Specific inorganic oxides include silica and alumina, used alone or in combination with other inorganic oxides such as magnesia, titania, zirconia and the like.
  • Non-metallocene transition metal compounds, such as titanium tetrachloride, can also be incorporated into the supported catalyst component.
  • the inorganic oxides used as support can be characterized as having an average particle size ranging from 30-600 microns, desirably from 30-100 microns, a surface area of 50-1,000 square meters per gram, desirably from 100-400 square meters per gram, and a pore volume of 0.5-3.5 cc/g, desirably from about 0.5-2 cc/g.
  • the bridged catalysts of the present invention may be used in combination with some form of activator in order to create an active catalyst system.
  • activator is defined herein to be any compound or component, or combination of compounds or components, capable of enhancing the ability of one or more catalysts to polymerize olefins to polyolefins.
  • Alklyalumoxanes such as methylalumoxane (MAO) are commonly used as metallocene activators. Generally allcylalumoxanes contain about 5 to 40 of the repeating units.
  • Alumoxane solutions may be obtained from commercial vendors as solutions having various concentrations.
  • There are a variety of methods for preparing alumoxane non-limiting examples of which are described in U.S. Patent Nos.4,665,208, 4,952,540, 5,091,352, 5,206,199, 5,204,419,4,874,734,4,924,018, 4,908,463,4,968,827, 5,308,815, 5,329,032, 5,248,801, 5,235,081, 5,103,031 and EP-A-0 561 476, EP 0 279 586, EP-A-0 594 218 and WO 94/10180, each fully incorporated herein by reference. (As used herein unless otherwise stated “solution” refers to any mixture including suspensions.)
  • Ionizing activators may also be used to activate the bridged catalysts. These activators are neutral or ionic, or are compounds such as tri(n-butyl)ammonium tetrakis(pentaflurophenyl)borate, 5 which ionize the neutral catalyst compound. Such ionizing compounds may contain an active proton, or some other cation associated with, but not coordinated or only loosely coordinated to, the remaining ion of the ionizing compound. Combinations of activators may also be used, for example, alumoxane and ionizing activators in combinations, see for example, WO 94/07928.
  • ionic catalysts for coordination polymerization comprised of metallocene 0 cations activated by non-coordinating anions appear in the early work in EP-A-0 277 003, EP-A-0 277 004 and US patents 5,198,401 andWO-A-92/00333 (incorporated herein by reference). These teach a desirable method of preparation wherein metallocenes (bisCp and monoCp) are protonated by an anion precursor such that an alkyl/hydride group is abstracted from a transition metal to make it both cationic and charge-balanced by the non-coordinating anion.
  • Suitable ionic salts include, but 5 are not limited to, tetrakis-substituted borate or aluminum salts having fluorided aryl-constituents such as phenyl, biphenyl and napthyl.
  • noncoordinating anion means an anion that either does not coordinate to the cation or which is only weakly coordinated to the cation thereby remaining sufficiently labile to be displaced by a neutral Lewis base.
  • Compatible noncoordinating anions are those that are not o degraded to neutrality when the initially fo ⁇ ned complex decomposes. Further, the anion will not transfer an anionic substituent or fragment to the cation so as to cause it to form a neutral four coordinate metallocene compound and a neutral by-product from the anion.
  • ionizing ionic compounds not containing an active proton but capable of producing both the active metallocene cation and a noncoordinating anion is also known. See, for 5 example, EP-A-0 426 637 and EP-A-0 573 403 (incorporated herein by reference).
  • An additional method of making the ionic catalysts uses ionizing anion precursors which are initially neutral Lewis acids but form the cation and anion upon ionizing reaction with the metallocene compounds, for example the use of tris(pentafluorophenyl) borane, see EP-A-0 520 732 (incorporated herein by reference).
  • Ionic catalysts for addition polymerization can also be prepared by oxidation of the o metal centers of transition metal compounds by anion precursors containing metallic oxidizing groups along with the anion groups, see EP-A-0 495 375 (incorporated herein by reference).
  • the metal ligands include halogen moieties (for example, bis-cyclopentadienyl zirconium dichloride) which are not capable of ionizing abstraction under standard conditions, they can be converted via known alkylation reactions with organometallic compounds such as lithium or aluminum hydrides or alkyls, allcylalumoxanes, Grignard reagents, etc.
  • NCA support methods generally comprise using neutral anion precursors that are sufficiently strong Lewis acids to react with the hydroxyl reactive functionalities present on the silica surface such that the Lewis acid becomes covalently bound.
  • the activator for the metallocene supported catalyst composition is a NCA
  • the NCA is first added to the support composition followed by the addition of the bridged metallocene catalyst.
  • the activator is MAO
  • the MAO and bridged metallocene catalyst are dissolved together in solution.
  • the support is then contacted with the MAO/metallocene catalyst solution.
  • the catalysts of the present invention can be used for the polymerization of ⁇ -olefins having at least two carbon atoms or the copolymerization of mixtures of ⁇ -olefins.
  • the present catalyst can be useful for catalyzing ethylene, propylene, butylene, pentene, hexene, 4- methylpentene and also for mixtures thereof.
  • the catalysts of the present invention can be utilized for the polymerization of propylene to produce polypropylene, such as for example, high crystallinity polypropylene.
  • the polymerization and, where applicable, pre-polymerization conditions are known in the art and need not be described in detail here.
  • polymerization is accomplished by contacting together either ⁇ -olefm monomer or a mixture of ⁇ -olefins in the presence of the above described catalyst system under polymerization conditions.
  • This example shows creation of a ligand having C2/Class A symmetry.
  • the same general synthesis is followed from Example 1, with the exception that the 2,6-diisopropylaniline is replaced with indene.
  • a catalyst from the ligand of Example 3 (Intermediate with symmetry C2/Class A) is synthesized by using the same general synthesis as in Example 2, to provide the catalyst component shown below.
  • This example shows creation of a ligand having C2/Class B symmetry.
  • the first part of the synthesis for this ligand is different from that of Example 1 above.
  • the first part of the synthesis starts with the reduction of the diacetylpyridine to a diamine by using the Leuckart-Wallach reaction. 5
  • scheme 1 a general reaction is shown for the reduction of a carbonyl to an amine.
  • Example 6 i o This example illustrates the reduction of a carbonyl to an amine, specifically, the synthesis of
  • the reaction mixture was allowed to cool, and the acetopenone was removed by extraction with four 20 ml portions of toluene.
  • the aqueous acid solution was transferred to a 500 ml round-bottom flask 5 equipped for steam distillation, a solution of 62.5 g of sodium hydroxide was cautiously added to 125 ml water, and steam distilled: the distillation flask was heated so that the volume remained nearly constant.
  • Most of the amine was contained in the first 500 ml of distillate; the operation was stopped when the distillate was only faintly alkaline.
  • the distillate was extracted with five 25 ml portions of toluene, the extract was dried with sodium hydroxide pellets and fractionally distilled.
  • This example illustrates the synthesis of 2,6-(l,r-diethylhydroxyimino)-pyridine (Dioxime) 5 (Scheme 2).
  • Hydroxylamine hydrochloride (0.98 g; 14.1 mmol) and pyridine (5 mL) were placed in a flask under Argon and equipped with a magnetic stirrer.
  • 2,6-Diacetylpyridine (1,0 g; 6.1 mmol) was added and the mixture was refluxed for 8h and stured at room temperature for two days.
  • the pyridine was removed under vacuum. Water (20 mL) was added to the residue. The white solid was washed with small amounts of water.
  • This example provides a ligand for a catalyst with symmetry C2 / Class B by reacting the diamine as obtained in Example 7 with a ketone (Scheme 4).
  • This example illustrates the synthesis of bis-imine for a catalyst with C 2 / class B symmetry based on the reaction of diamine with ⁇ -tetralone (Scheme 5).
  • the diamine (0.50 g, 3.03 mmoles) and the ⁇ -tetralone (0.85 mL, 6.43 mmoles) were added to the flask at 25°C the mixture produced a clear dark yellow liquid.
  • the flask was then placed under vacuum and back-filled with argon three times and then left under argon. After stirring for 10 minutes, the mixture produced a pale yellow solid tar, which became very difficult to stir. 25 mL of ethanol was added to help stir the mixture.
  • Example 11 This example illustrates the synthesis of bis-imine for a catalyst with C 2 / class B symmetry based on the reaction of diamine with cyclohexanone (Scheme 6). The procedure as described in Example 9 was utilized for the synthesis of bis-imine.
  • This example illustrates the synthesis of bis-imine for a catalyst with C 2 / class B symmetry, based on the reaction of diamine with mesitylaldehyde (Scheme 7). The procedure as described in Example 9 was utilized for synthesis of bis-imine.
  • Example 9 The ligand (1.05 eq.) of Example 9 and the metal salt in its hydrated or anhydrous form are added together in a Schlenk flask under inert atmosphere and then charged with THF. The mixture is stirred for several hours or until no detectable unreacted salts are observed. The mixture is filtered in air and the solids are washed with Et20 and dried under vacuum.
  • Example 14 the amine of Example 14 is reacted with a ketone to provide the R group double bond to the nitrogen.
  • Example 15 an amine is reacted with the mono-acetyl inte ⁇ nediate of Example 15 to provide the R group with a single bond to the nitrogen as shown in the formula below.
  • a catalyst is then synthesized according to the procedure described in Example 13.
  • the solid-state structures of iron complexes have been determined by X-ray diffraction method of single crystals.
  • the selected crystallographic data are summarized in Table 2 and structures are depicted in the fo ⁇ nulas from Example 4 and as shown below the table.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Pyridine Compounds (AREA)

Abstract

A catalyst comprising e.g. a pyridine bisimine ligand bonded to a transition metal by at least two heteroatoms of the ligand, the ligand having at least two aromatic groups or cyclopentadienyl groups on different heteroatoms of the ligand. The transition metal compound, its preparation, preparation and use of the catalyst in an olefin polymerization catalyst are also disclosed.

Description

NEW CATALYST STRUCTURE FOR OLEFIN POLYMERIZATION
CROSS REFERENCE TO RELATED APPLICATIONS
This application claims priority from United States Patent Application Serial Nos. 5 10/301,884 filedNovember 21, 2002 and Patent Application No. 10/692,068 filed October 23, 2003. BACKGROUND OF THE INVENTION
Field of the Invention
The present invention relates to catalyst components, catalyst systems, olefin polymerization, polymer compositions, and to articles made from such polymer compositions. More particularly the 0 present invention relates to catalysts having Ci, C2 or Cs symmetry.
Description of the Related Art
As is well known, various processes and catalysts exist for the production of polyolefins. Traditional Ziegler-Natta catalyst systems utilize a transition metal compound cocatalyzed by an aluminum alkyl. 5 In the 1980's, metallocene catalysts for olefin polymerization were commercialized that included a metallocene and an aluminum alkyl component, with a transition metal compound having two or more cyclopentadienyl (Cp) ring ligands. Accordingly, titanocenes, zirconocenes and hafnocenes have all been utilized as the transition metal component in such a metallocene containing catalyst systems for the production of polyolefins. Metallocene catalysts can be cocatalyzed with an o alumoxane, rather than an aluminum alkyl, to provide a metallocene catalyst system of high activity for the production of polyolefins.
In addition to Ziegler-Natta catalysts and metallocene catalysts, a number of "non- metallocene" type catalysts have been suggested for the polymerization of olefins. Specifically, for example, in The Search for New-Generation Olefin Polymerization Catalysts: Life Beyond 5 Metallocenes, Angew. Chem. Int. Ed. 1999, 38, 428-447, Britovsek etal. review a number of olefin catalyst systems, including: Group 3 metal catalysts such as scandium and yttrium complexes; Rare Earth Metal catalysts such as lanthanide and actinide-based catalysts stabilized with substituted cyclopentadienyl ligands; cationic Group 4 metal complexes including carbon-based ligands (such as alkyl ligands, allyl ligands, Cp analogues), including nitrogen-based ligands (such as amide ligands o either along or in combination with other ligands, amidinate ligands either alone or in combination with other ligands, and β-diketimate ligands), and including oxygen-based ligands (such as alkoxide ligands either alone or in combination with other ligands, bis-alkoxides with additional donors); neutral Group 4 metal complexes; Group 5 metal catalysts; Group 6 metal catalysts; Group 8 metal catalysts; Group 9 metal catalysts; Group 10 metal catalysts; Group 13 metal catalysts.
Additionally, in Iron and Cobalt Ethylene Polymerization Catalysts Bearing 2,6- Bis(Imino)Pyridyl Ligands; Synthesis, Structures, and Polymerization Studies, J. Am. Chem. Soc. 1999, 121, 8728-8740, Britovsek et al. disclose certain iron and cobalt catalysts for the polymerization of ethylene.
WO 98/30612, published on July 16, 1998, discloses selected iron complexes of 2,6- pyridinecarboxaldehydebis(imines) and 2,6-diacyclpyridinebis(imines) as catalysts for the polymerization of propylene. WO 99/12981, published on March 18, 1999, discloses catalyst complexes having a bridge comprising heteroatoms bridging R groups R5 and R7, with these complexes taught as being useful "especially for polymerizing ethylene alone or for copolymerizing ethylene with higher 1-olefins" (page 2, lines 28-29). The bridged R groups R5 and R7 are independently selected from hydrogen, halogen, and hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl. There is no teaching or suggestion to make a chiral complex suitable for producing high tacticity, crystallinity polypropylene.
The following patents disclose bridged metallocene catalyst systems: U.S. Patent No. 5,145,819, issued September 8, 1992 to Winter et al.; U.S. Patent No. 5,158,920, issued October 27, 1992 to Razavi; U.S. Patent No. 5,243,001, issued September 7, 1993 to Winter et al.; U.S. Patent No. 6,002,033, issued December 14, 1999 to Razavi et al.; U.S. Patent No. 6,066,588, issued May 23, 2000, to Razavi et al.; U.S. Patent No. 6,177,529 Bl, issued January 23, 2001, to Razavi et al.; U.S. PatentNo. 6,194,343 Bl, issued February 27, 2001 to Collins et al.; U.S. PatentNo. 6,211,110 Bl, issued April 3, 2001 to Santi et al.; and U.S. Patent No. 6,268,518 Bl, issued July 31, 2001 to Resconi et al.
However, in spite of the above advancements, there still exists a need in the art for catalyst compositions, methods of making such compositions, methods of polymerization using such compositions, to polymer compositions, and to articles made from such polymer compositions. SUMMARY OF THE INVENTION
According to one embodiment of the present invention there is provided a bridged compound having the formula:
RB-(m)M(Z)(X)2
I R2 wherein M is a metal; each X is an atom or group covalently or ionically bonded to M and may be the same or different; R] and R2 may be the same or each may be different and are substituted or unsubstituted cyclopentadienyl or aromatic rings; RB is a structural bridge between the cylcopentadienyl or aromatic rings Ri and R2 and imparts stereorigidity to the rings, and comprises at least one heteroatom bonded to M, with each of Ri and R2 bonded to the same or different heteroatom of RB which heteroatom is also bonded to M; Z is the coordination number of M and is greater than or equal to 4; m is the number of bonds between M and heteroatoms of RB and to impart stereorigidity m is equal or greater than 2; and with Ri, R and RB selected to provide a catalyst component with , C2 or Cs symmetry. The catalyst component can be chiral or non-chiral. In some embodiments it can be desirable to have the catalyst component that is chiral.
According to another embodiment of the present invention, there is provided a method of making a bridged metallocene compound comprising contacting a metal compound of the formula M(X)2 with a bridged compound of the formula Ri
RB
R2
wherein RB, RI and R2 are as defined above.
According to another embodiment of the present invention, there is provided a catalyst system comprising an activated bridged metallocene compound having the formula:
RB-(m)M(Z)(X)2
R2
wherein M, X, Ri, R2, m and Z are as defined above.
According to still another embodiment of the present invention, there is provided a method of making a catalyst system comprising contacting an activator with a bridged metallocene compound having the formula: Ri I
RB-(m)M(Z)(X)2
I R2 wherein M, X, Ri, R2, m and Z are as defined above.
According to yet another embodiment of the present invention, there is provided a method of forming polyolefins comprising contacting olefin monomer or mixture of monomers in the presence of an activated bridged metallocene compound having the formula:
I
RB-(m)M(Z)(X)2
R2 wherein M, X, Ri, R2, m and Z are as defined above.
For all of the above embodiments, various further embodiments are provided by changing M, X, Ri, R2, m and Z as described in the detailed description. DETAILED DESCRIPTION OF THE INVENTION In one embodiment of the invention a bridged metallocene catalyst component of the present invention can be represented by the following formula: Ri
RB-(m)M(Z)(X)2
R2 wherein M is a metal; each X is an atom or group covalently or ionically bonded to M and may be the same or different; Ri and R2 may be the same or each may be different and are substituted or unsubstituted cyclopentadienyl or aromatic rings; RB is a structural bridge between the cylcopentadienyl or aromatic rings Ri and R2 and imparts stereorigidity to the rings, and comprises at least one heteroatom bonded to M, with each of Ri and R2 bonded to the same or different heteroatom of RB which heteroatom is also bonded to M; Z is the coordination number of M and is greater than or equal to 4; m is the number of bonds between M and the heteroatom(s) of RB and to impart stereorigidity m>2; because the number of bonds around M cannot exceed its coordination number Z; with Ri , R2 and RB selected to provide a catalyst component with C i , C2 or Cs symmetry.
The catalyst component can be chiral or non-chiral. In some embodiments it can be desirable to have the catalyst component that is chiral. The metal M of the present invention may be any suitable metal useful as the metal component in metallocene catalysts. As a non-limiting example, M may be selected from among any metal as is known in the prior art to be useful as the metal component in metallocene catalysts. M will be selected to have a coordination number Z that is at least equal to the number of substituents bonded to M, that is, m number of RB heteroatom-to-metal bonds plus 2 (for both X's). M can be selected from among transition metals, lanthanides and actinides. M can be selected from among group 3d, 4d or 5d transition metals, such as Fe, Co, Ni, Ru, Rh, Pd, Os, Ir and Pt. In some embodiments M can be desirably selected from among Fe, Co and Ni. Ri and R2 may be the same or each may be different and may be generally described as being substituted or unsubstituted cyclopentadienyl or aromatic rings. As non-limiting examples, Ri and R2 may be selected from among any substituted or unsubstituted cylcopentadienyl or aromatic ring as are known in the art to be useful in metallocene catalysts. Non-limiting examples of hydrocarbon radicals suitable for use as Ri and R2 are shown in the Examples below. As a nonlimiting example, R\ and R2 may be described as a cylcopentadienyl or aromatic ring of the form (Cs(R') ), wherein each R' may be the same or each may be different, and R' is a hydrogen or a substituted or unsubstituted hydrocarbyl radical having 1-20 carbon atoms. Non-limiting examples of hydrocarbyl radicals suitable for use as R' include unsubstituted 5 and substituted alkyl, alkenyl, aryl, alkylaryl or arylalkyl radicals. More specific non-limiting examples of suitable hydrocarbyl radicals include unsubstituted and substituted methyl, ethyl, propyl, butyl, amyl, isoamyl, hexyl, isobutyl, heptyl, octyl, nonyl, decyl, cetyl, phenyl, methylene, ethylene, propylene, and other like groups.
RB acts as a structural bridge between the cylcopentadienyl or aromatic rings R\ and R2 and i o imparts stereorigidity to the rings, and comprises n heteroatoms ("HA") bonded to M. The number of heteroatoms bonded to M can be n>l , n>2, and in some embodiments it can be desirable to have n>3. An example of a suitable structural bridge RB is provided in the examples.
Heteroatoms useful in structural bridge RB include any that can be coordinated to the metal M by a "dative" bond, that is, a bond formed by the donation of a lone pair of electrons from the
15 heteroatom. Where RB comprises more than one heteroatom bonded to M, they may be the same heteroatom or different heteroatoms. Non-limiting examples of suitable heteroatoms include O, N, S, and P. In some embodiments the heteroatoms are desirably N.
Ri is bonded to a heteroatom of RB which heteroatom is also bonded to M, either directly or indirectly through a different heteroatom. Likewise, R2 is also bonded to a heteroatom of RB which
2 o heteroatom is also bonded to M, either directly or indirectly through a different heteroatom. Ri and R2 may be bonded to the same heteroatom that is also bonded to M, or may be bonded to different heteroatoms which different heteroatoms are also bonded to M. The structure of the R1-R2- RB moiety can be any that does not interfere with the symmetry of the catalysts. For example, the Rl- R2- RB moiety can have the following configurations and still be within the scope of the claims of
25 the present invention:
1 Ri H2
R, R2 H3 = M
In some embodiments a bridging group having four heteroatoms would be within the scope of the present invention. According to one embodiment of the present invention, Rls R2 and RB are selected to provide a catalyst component that has Ci , C2 or Cs symmetry. Any configuration of R] , R2 and RB that does not disrupt the C i , C2 or Cs symmetry known to those of ordinary skill in the art of preparing catalysts to be useful can be used with the present invention. The catalyst component can be chiral or non-chiral. In some embodiments it can be desirable to have a catalyst component that is chiral.
Each X may be an atom or group as are known to be utilized with catalysts, and is generally covalently or ionically bonded to M. Each X may be the same or different, although commonly each X is the same. As a non-limiting example, X may be selected from among halide, sulphate, nitrate, thiolate, thiocarboxylate, BF ", PFG ", hydride, hydrocarbyloxide, carboxylate, substituted or unsubstituted hydrocarbyl, and heterohydrocarbyl. Non-limiting examples of such atoms or groups are chloride, bromide, methyl, ethyl, propyl, butyl, octyl decyl, phenyl, benzyl, methoxide, ethoxide, isopropoxide, toxylate, triflate, foπnate, acetate, phenoxide and benzoate. It can be desirable when X is a halide or a C\ to C20 hydrocarbyl. In some embodiments it is desirable that X is chloride. The bridged catalyst component is generally made by contacting a bridge intermediate with a compound of the form M(X)2. More details are provided in the Examples.
The present invention further includes a catalyst system comprising one or more of the above described bridged catalyst components and one or more activators and or cocatalysts (as described in greater detail below) or the reaction product of an activator and/or cocatalyst, such as for example, methylaluminoxane (MAO) and optionally an alkylation/scavenging agent such as trialkylaluminum compound, for example triethylalummum (TEAL). The above described metallocene catalyst components may also be supported as is known in the metallocene art. Typical supports may be a support such as talc, an inorganic oxide, clay, and clay minerals, ion-exchanged layered compounds, diatomaceous earth, silicates, zeolites or a resinous support material such as a polyolefin. Specific inorganic oxides include silica and alumina, used alone or in combination with other inorganic oxides such as magnesia, titania, zirconia and the like. Non-metallocene transition metal compounds, such as titanium tetrachloride, can also be incorporated into the supported catalyst component. The inorganic oxides used as support can be characterized as having an average particle size ranging from 30-600 microns, desirably from 30-100 microns, a surface area of 50-1,000 square meters per gram, desirably from 100-400 square meters per gram, and a pore volume of 0.5-3.5 cc/g, desirably from about 0.5-2 cc/g.
The bridged catalysts of the present invention may be used in combination with some form of activator in order to create an active catalyst system. The term "activator" is defined herein to be any compound or component, or combination of compounds or components, capable of enhancing the ability of one or more catalysts to polymerize olefins to polyolefins. Alklyalumoxanes such as methylalumoxane (MAO) are commonly used as metallocene activators. Generally allcylalumoxanes contain about 5 to 40 of the repeating units.
Alumoxane solutions, particularly methylalumoxane solutions, may be obtained from commercial vendors as solutions having various concentrations. There are a variety of methods for preparing alumoxane, non-limiting examples of which are described in U.S. Patent Nos.4,665,208, 4,952,540, 5,091,352, 5,206,199, 5,204,419,4,874,734,4,924,018, 4,908,463,4,968,827, 5,308,815, 5,329,032, 5,248,801, 5,235,081, 5,103,031 and EP-A-0 561 476, EP 0 279 586, EP-A-0 594 218 and WO 94/10180, each fully incorporated herein by reference. (As used herein unless otherwise stated "solution" refers to any mixture including suspensions.)
Ionizing activators may also be used to activate the bridged catalysts. These activators are neutral or ionic, or are compounds such as tri(n-butyl)ammonium tetrakis(pentaflurophenyl)borate, 5 which ionize the neutral catalyst compound. Such ionizing compounds may contain an active proton, or some other cation associated with, but not coordinated or only loosely coordinated to, the remaining ion of the ionizing compound. Combinations of activators may also be used, for example, alumoxane and ionizing activators in combinations, see for example, WO 94/07928.
Descriptions of ionic catalysts for coordination polymerization comprised of metallocene 0 cations activated by non-coordinating anions appear in the early work in EP-A-0 277 003, EP-A-0 277 004 and US patents 5,198,401 andWO-A-92/00333 (incorporated herein by reference). These teach a desirable method of preparation wherein metallocenes (bisCp and monoCp) are protonated by an anion precursor such that an alkyl/hydride group is abstracted from a transition metal to make it both cationic and charge-balanced by the non-coordinating anion. Suitable ionic salts include, but 5 are not limited to, tetrakis-substituted borate or aluminum salts having fluorided aryl-constituents such as phenyl, biphenyl and napthyl.
The term noncoordinating anion (NCA) means an anion that either does not coordinate to the cation or which is only weakly coordinated to the cation thereby remaining sufficiently labile to be displaced by a neutral Lewis base. Compatible noncoordinating anions are those that are not o degraded to neutrality when the initially foπned complex decomposes. Further, the anion will not transfer an anionic substituent or fragment to the cation so as to cause it to form a neutral four coordinate metallocene compound and a neutral by-product from the anion.
The use of ionizing ionic compounds not containing an active proton but capable of producing both the active metallocene cation and a noncoordinating anion is also known. See, for 5 example, EP-A-0 426 637 and EP-A-0 573 403 (incorporated herein by reference). An additional method of making the ionic catalysts uses ionizing anion precursors which are initially neutral Lewis acids but form the cation and anion upon ionizing reaction with the metallocene compounds, for example the use of tris(pentafluorophenyl) borane, see EP-A-0 520 732 (incorporated herein by reference). Ionic catalysts for addition polymerization can also be prepared by oxidation of the o metal centers of transition metal compounds by anion precursors containing metallic oxidizing groups along with the anion groups, see EP-A-0 495 375 (incorporated herein by reference). Where the metal ligands include halogen moieties (for example, bis-cyclopentadienyl zirconium dichloride) which are not capable of ionizing abstraction under standard conditions, they can be converted via known alkylation reactions with organometallic compounds such as lithium or aluminum hydrides or alkyls, allcylalumoxanes, Grignard reagents, etc. See EP-A-0 500 944 and EP-A1-0 570 982 (incorporated herein by reference) for in situ processes describing the reaction of alkyl aluminum compounds with dihalo-substituted metallocene compounds prior to or with the addition of activating anionic compounds.
Desirable methods for supporting ionic catalysts comprising metallocene cations and NCA are described in U.S. Patent Nos. 5,643,847; 6,143,686; and 6,228,795 (all fully incorporated herein by reference) . These NCA support methods generally comprise using neutral anion precursors that are sufficiently strong Lewis acids to react with the hydroxyl reactive functionalities present on the silica surface such that the Lewis acid becomes covalently bound.
Additionally, when the activator for the metallocene supported catalyst composition is a NCA, desirably the NCA is first added to the support composition followed by the addition of the bridged metallocene catalyst. When the activator is MAO, desirably the MAO and bridged metallocene catalyst are dissolved together in solution. The support is then contacted with the MAO/metallocene catalyst solution. Other methods and order of addition will be apparent to those skilled in the art.
The catalysts of the present invention can be used for the polymerization of α-olefins having at least two carbon atoms or the copolymerization of mixtures of α-olefins. For example, the present catalyst can be useful for catalyzing ethylene, propylene, butylene, pentene, hexene, 4- methylpentene and also for mixtures thereof. The catalysts of the present invention can be utilized for the polymerization of propylene to produce polypropylene, such as for example, high crystallinity polypropylene. The polymerization and, where applicable, pre-polymerization conditions are known in the art and need not be described in detail here. In general, polymerization is accomplished by contacting together either α-olefm monomer or a mixture of α-olefins in the presence of the above described catalyst system under polymerization conditions. The following examples are given as particular embodiments of the invention and to demonstrate the practice and advantages thereof. Examples
These examples are provided merely to illustrate a few embodiments of the present invention, and are not intended to and do not limit the specification or scope of the claims. In these examples, all manipulations of air/moisture-sensitive materials were performed on a conventional vacuum/inert atmosphere line using standard Schlenk line techniques.
Example 1
The procedure as described in WO 99/12981 was utilized for synthesis of ligand intermediate
5 A of the formula as shown below:
2,6-diisopropylaniline (3.46 ml, 18.4 mmol) was added dropwise to a solution of 2,6- diacetylpyridine (1.5 g, 9.2 mmol) in absolute ethanol (25 ml) A few drops of glacial acetic acid was added and the solution was refluxed for 48 h. Concentration of the solution to half volume and o cooling to 78°C gave intermediate A as pale yellow crystals (80 %). The calculated values for the intermediate C33H43N3 is: C, 82.3%; H 8.9%; N 8.7%. The observed results of the intermediate produced were: C, 81.9%; H 8.5%; 8.7%. Fast atom bombardment mass spectrometry (FABMS) results are: M+ (481). NMR analysis results are: 1HNMR (CDC13): 8.6 B 7.9 [m, 3H, C5H3N], 7.2 B 6.9 [m, 6H, C6(CHMe2)H3], 2.73 [sept, 4H, CHMe2], 2.26[s, 6H, C5H3N(CMeNAr)2] and 5 1.16[m, 24H, CHMe2].
Example 2
250 mg, 1.09 eq. of Intermediate A, and 95 mg of FeC12*4H20 was weighed into a 10 ml Schlenk flask containing a stirbar. The flask was placed on a Schlenk manifold, backfilled 3 times with argon, and 10 ml of tetrahydrofurane (THF) were added while stirring. After 2 h, the THF was o removed under vacuum. The resulting deep blue solid (formula below) was washed twice with ether and dried under vacuum.
Example 3
This example shows creation of a ligand having C2/Class A symmetry. The same general synthesis is followed from Example 1, with the exception that the 2,6-diisopropylaniline is replaced with indene.
1-Amino-indene (18.4 mmol) was added to a solution of 2,6-diacetylpyridine (9.2 mmol) in absolute ethanol (50 ml). A few drops of glacial acetic acid was added and the solution is refluxed for 48 h. Concentration of the solution was reduced to half volume and the solution was cooled to room temperature and filtered to give the intermediate shown below.
Example 4
A catalyst from the ligand of Example 3 (Intermediate with symmetry C2/Class A) is synthesized by using the same general synthesis as in Example 2, to provide the catalyst component shown below.
Example 5
This example shows creation of a ligand having C2/Class B symmetry. The first part of the synthesis for this ligand is different from that of Example 1 above. The first part of the synthesis starts with the reduction of the diacetylpyridine to a diamine by using the Leuckart-Wallach reaction. 5 In scheme 1 below, a general reaction is shown for the reduction of a carbonyl to an amine.
Scheme 1. Reduction of a carbonyl compounds to amines (Leuckart-Wallach
Reaction):
O HCO2NH4 (or HCONH2), HCO2H *- RoCHNH + CO,
R" ~R H20
Example 6 i o This example illustrates the reduction of a carbonyl to an amine, specifically, the synthesis of
1 -phenylethylamine (Vogel's Practical Organic Chemistry including qualitative organic analysis, 4th Ed, Fumiss, B.S., et al., School of Chemistry Thames Polytechnic Longman Scientific and Technical, 1978). 126 g (2.0 mol) of ammonium formate, 72 g (0.6 mol) of acetophenone and a few chips of porous porcelain were added to a 250 ml flask fitted with a Claisen still-head carrying a
15 short fractionating column; a thermometer expending nearly to the bottom of the flask was inserted, and a short condenser was set for downward distillation to the side arm. The flask was heated (either with a heating mantle or in an air batch); the mixture first melted to two layers and distillation occurs. The mixture became homogeneous at 150 - 155 °C and reaction took place with slight frothing. Heating was continued, until the temperature reached 185 °C (about 2 hours);
2 o acetophenone, water and ammonium carbonate distill. The heating was stopped at 185 °C, the upper layer of acetophenone was separated from the distillate and returned without drying to the flask. The mixture was heated for 3 hours at 180-185 °C and allowed to cool; the acetophenone may be recovered from the distillate by extraction with 20 ml portions of toluene. The reaction mixture was transferred to a 250 ml separatory funnel and shaken with two 75 ml portions of water to remove
25 foπnamide and ammonium formate. The crude (1 -phenylethyl)formamide was transferred into the original reaction flask and the aqueous layer was extracted with two 20 ml portions of toluene. The toluene extracts were transfeπed to the flask, 75 ml of concentrated hydrochloric acid and a few chips of porous porcelain were added. The mixture was heated cautiously until about 40 ml of toluene was collected, and boiled gently under reflux for a further 40 minutes; hydrolysis proceeded rapidly to 1-phenylethylamine hydrochloride except for a small layer of unchanged acetophenone. The reaction mixture was allowed to cool, and the acetopenone was removed by extraction with four 20 ml portions of toluene. The aqueous acid solution was transferred to a 500 ml round-bottom flask 5 equipped for steam distillation, a solution of 62.5 g of sodium hydroxide was cautiously added to 125 ml water, and steam distilled: the distillation flask was heated so that the volume remained nearly constant. Most of the amine was contained in the first 500 ml of distillate; the operation was stopped when the distillate was only faintly alkaline. The distillate was extracted with five 25 ml portions of toluene, the extract was dried with sodium hydroxide pellets and fractionally distilled. o Toluene distilled over at 111 °C, followed by the phylethylamine. The latter was collected as a fraction of b.p. 180-190 °C (the bulk of the product distilled at 184-186 °C (3); the yield was 43g (59%).
Example 7
This example illustrates the synthesis of 2,6-(l,r-diethylhydroxyimino)-pyridine (Dioxime) 5 (Scheme 2). Hydroxylamine hydrochloride (0.98 g; 14.1 mmol) and pyridine (5 mL) were placed in a flask under Argon and equipped with a magnetic stirrer. 2,6-Diacetylpyridine (1,0 g; 6.1 mmol) was added and the mixture was refluxed for 8h and stured at room temperature for two days. The pyridine was removed under vacuum. Water (20 mL) was added to the residue. The white solid was washed with small amounts of water. The dioxime was dried overnight under vacuum to afford a o white powder (1.08 g; 5.6 mmol; 92%), which was used without further purification. NMR analysis results are: JH NMR (CD2C12), δ: 7.81 (d, 2H, Hmeta, J= 7.8 Hz), 7.70 (t, 1H, ϊlpara, J= 7.8Hz), 2.79 (s, 2H, OH), 2.33 (s, 6H, Me).
Scheme 2 Synthesis of dioxime
5 Example 8
The reduction of dioxime as obtained in Example 7 to the diamine is provided by using a following synthethic procedure (Scheme 3).
Synthesis of 2,6-(l,r-diethylamino)-pyridine (Diamine). The 2,6-(l,L- diethylhydroxyimino)-pyridine (500 mg; 2.6 mmol) was added in a flask placed under Argon and equipped with a magnetic stiπer and dissolved in ethanol (10 mL) and acetic acid (6 mL). Zinc powder (6 g; 94 mmol) was added dropwise over 10 minutes. After lh of stirring a white precipitate appeared. The mixture was stiπed at room temperature for 24 h. The undissolved zinc was removed by filtration and washed with small amounts of ethanol. The filtrate was concentrated under vacuum. Small portions of water were added and evaporated to remove any remaining acetic acid. The mixture was made strongly basic (pH>12) by addition of saturated aqueous potassium hydroxide solution (around 56 mL) until all the Zn(OH)2 was redissolved. The aqueous layer was transferred in a separatory funnel and extracted with four portions of diethyl ether (20 mL). The combined organic fractions were dried over MgS0 and the solvent was removed under vacuum to afford a colorless oil (310 mg; 1.87 mmol; 72%). NMR analysis results are: ]H NMR (CD2Cl2), δ: 7.59 (t, IH, Ηpara, J= 7.8Hz), 7.14 (d, 2H, Rmeta, J= 7.8 Hz), 4.07 (q, 2H, CH, J= 6.6 Hz), 1.79 (s, 4H, NH2), 1.38 (d, 6H, Me, J= 6.6 Hz).
Scheme 3. Synthesis of diamine
Example 9
This example provides a ligand for a catalyst with symmetry C2 / Class B by reacting the diamine as obtained in Example 7 with a ketone (Scheme 4).
Scheme 4. Synthesis of a ligand for catalyst with symmetry C2 / Class B
Ligand for catalyst with C /B symmetry Example 10
This example illustrates the synthesis of bis-imine for a catalyst with C2/ class B symmetry based on the reaction of diamine with β-tetralone (Scheme 5). In a 100 mL round bottom flask equipped with a stir bar, the diamine (0.50 g, 3.03 mmoles) and the β-tetralone (0.85 mL, 6.43 mmoles) were added to the flask at 25°C the mixture produced a clear dark yellow liquid. The flask was then placed under vacuum and back-filled with argon three times and then left under argon. After stirring for 10 minutes, the mixture produced a pale yellow solid tar, which became very difficult to stir. 25 mL of ethanol was added to help stir the mixture. A clear orange-yellow solution was obtained. After stiπing for 2 hours at 25°C, the solvent was removed under vacuum and obtained left a pale yellow foamy solid. 1 H-NMR analysis showed that the product was mostly the desired bisimine ligand (78% yield). NMR analysis results are: !H NMR (300 MHz, CD2C12, 35°C) δ: 7.63 (t, 1H), 7.21 (d, 4H), 6.96 (t, 4H), 6.80 (t, 2H), 6.77 ( , 2H), 5.14 (d, 2H), 4.64 (d, 2H), 2.80 (t, 4H), 2.36 (t, 4H), 1.55 (d, 6H, Me).
Scheme 5. Synthesis of bis-imine by using β-tetralone
Example 11. This example illustrates the synthesis of bis-imine for a catalyst with C2/ class B symmetry based on the reaction of diamine with cyclohexanone (Scheme 6). The procedure as described in Example 9 was utilized for the synthesis of bis-imine.
Scheme 6. Synthesis of bis-imine by using cyclohexanone
Example 12
This example illustrates the synthesis of bis-imine for a catalyst with C2/ class B symmetry, based on the reaction of diamine with mesitylaldehyde (Scheme 7). The procedure as described in Example 9 was utilized for synthesis of bis-imine. Bis-imine: NMR analysis results are: 1H NMR (300 MHz, CD2C12, 35°C) δ: 8.7 (s, 2H, HCN), 7.66 (t, J = 7.8Hz, 1H, Hpara), (d, J = 7.8Hz, 2H, Hmeta), 6.88 (s, 4Hmeta,Mes), 4.63 (q, J = 6.6Hz, 2H, HCH3,) 2.42 (s, 12H, CH3ortho,Mes), 2.28 (s, 6H, CH3para,Mes), 1.63 (d, J = 6.6Hz, 6H, Me).
Scheme 7. Synthesis of bis-imine by using mesitaldehyde
Example 13
Another catalyst synthesis procedure to produce a catalyst with symmetry C2/Class B is the same procedure as the one described in WO 98/30612 (with the exception of different R groups and position of double bonds in the structure), and is shown in the following reaction formula:
R = Cyclic, alkyl or aryl M = Fe, Co X = Cl, Br
The ligand (1.05 eq.) of Example 9 and the metal salt in its hydrated or anhydrous form are added together in a Schlenk flask under inert atmosphere and then charged with THF. The mixture is stirred for several hours or until no detectable unreacted salts are observed. The mixture is filtered in air and the solids are washed with Et20 and dried under vacuum.
Example 14
To synthesize a ligand for catalyst with a Cs/Class B symmetry or with a Cl/Class B symmetry, a similar procedure as the one used for the C2/Class B symmetry is used. The exception is that only two different ketones are reacted with diamine. The general procedure for this synthesis is shown in the formula below (Scheme 8).
Scheme 8. Synthesis of a ligand for catalyst with Cs/ type B symmetry
Ligand for catalyst with Cs or C-] /B type symmetry Example 15
To synthesize a structure with a C2/Class C symmetry, a similar procedure as the one used for the C2/Class B symmetry is used. The exception is that only one acetyl group is reduced on the 2,6-diacetylanaline. The general procedure for this synthesis is shown in the formula below where only one of the acetyls is reduced to the amine.
Example 16
In this example, the amine of Example 14 is reacted with a ketone to provide the R group double bond to the nitrogen.
Example 17
In this Example, an amine is reacted with the mono-acetyl inteπnediate of Example 15 to provide the R group with a single bond to the nitrogen as shown in the formula below.
Example 18
A catalyst is then synthesized according to the procedure described in Example 13.
Simply by using different R groups bonded to the nitrogen atoms with a single bond, a double bond, or with one single bond and one double bond, the symmetries for Ci and Cs may also be obtained. Some examples for the different symmetries are summarized in Table 1 for the structure as shown in Table 1.
U Any patents, patent applications, articles, books, treatises, and any other publications cited herein, are hereby incorporated by reference for all that they teach or suggest.
Table 1 Table 1. Examples of Symmetries
X-Ray Data of C? symmetric iron complexes
The solid-state structures of iron complexes have been determined by X-ray diffraction method of single crystals. The selected crystallographic data are summarized in Table 2 and structures are depicted in the foπnulas from Example 4 and as shown below the table.
Table 2. Selected lengths and angles of C2 symmetric iron complexes:
Length (A) or Angle Complex 1 Complex 2 (deg) of Bonds
Fe-N(imine) 2.177; 2.228 2.222; 2.227
Fe-N(pyridine) 2.100 2.103
N(imine)-C(L) 1.453; 1.474 1.430; 1.439
N(imine)-Fe-N(imine) 146.6 146.8
Fe-N(imine)-C(L) 117.9; 123.6 122.4; 121.7
C-N(imine)-C(L) 119.6; 123.1 120.3;121.1
Complex 1: 2,6-[bis-l-(l-indanylimino)ethyl]pyridine iron (II) chloride
Complex 2: 2,6-bis[l-(l-naphthylimino)ethyl]pyridine iron dichloride *Complex 1 and 2 have the foπnulas shown above:
Figure 1. Molecular Structure of 2,6-[bis-l-(l-indanylimino)ethyl]pyridine iron (II) chloride (Complex 1) Figure 2. Molecular Structure of 2,6-bis[l-(l-naphthylimino)ethyl]pyridine iron dichloride (Complex 2):
While the illustrative embodiments of the invention have been described with particularity, it will be understood that various other modifications will be apparent to and can be readily made by those skilled in the art without departing from the scope of the invention. Accordingly, it is not intended that the scope of the claims appended hereto be limited to the examples and descriptions set forth herein but rather that the claims be construed as encompassing all the features of patentable novelty which reside in the present invention, including all features which would be treated as equivalents thereof by those skilled in the art to which this invention pertains.

Claims

CLAIMS:
1. A bridged compound having the formula:
Ri
I
R2 wherein M is a metal; each X is an atom or group covalently or ionically bonded to M and may be the same or different; Ri and R2 may be the same or each may be different and are substituted or unsubstituted cyclopentadienyl or aromatic rings; RB is a structural bridge between the cylcopentadienyl or aromatic rings Ri and R2 and imparts stereorigidity to the rings, and comprises at least one heteroatom bonded to M, with each of Ri and R2 bonded to the same or different heteroatom of RB; Z is the coordination number of M and is greater than or equal to 4; m is the number of bonds between M and heteroatoms of RB and to impart sterorigidity m>2; and with R 5 R2 and RB selected to provide a catalyst component with C\, C2 or Cs symmetry.
2. The compound of claim 1, wherein M is selected from the group consisting of transition metals and lanthanide metals, wherein the heteroatoms are selected from the group consisting of O, N, S, and P.
3. The compound of claim 1 , wherein RB comprises at least three heteroatoms, and wherein Ri is bonded to one of the heteroatoms, and R2 is bonded to a different one of the heteroatoms.
4. The compound of claim 1 , wherein M is selected from among Fe, Co and Ni.
5. The compound of claim 1 , wherein M is Fe, RB comprises three heteroatoms bonded to M, and wherein Ri is bonded to one of the three heteroatoms, and R2 is bonded to a heteroatom different than the heteroatom to which Ri is bonded; M is selected from among Fe, Co and Ni. 6. The compound of claim 5 , wherein each X is independently selected from among halides and substituted or unsubstituted hydrocarbons.
7. A method of making a bridged compound comprising contacting a metal compound of the formula M(X)2 with a bridged compound RB of the fora la
R2 wherein M is a metal; each X is an atom or group covalently or ionically bonded to M and may be the same or different; Ri and R2 may be the same or each may be different and are substituted or unsubstituted cyclopentadienyl or aromatic rings; RB is a structural bridge between the cylcopentadienyl or aromatic rings R] and R2 and imparts stereorigidity to the rings, and comprises at least one heteroatom suitable for bonding to M, with each of R\ and R2 bonded to the same or different heteroatom of RB; and with R1} R2 and RB selected to provide a bridged metallocene compound with Ci, C2 or Cs symmetry.
8. The method of claim 7, wherein M is selected from the group consisting of transition metals and lanthanide metals, wherein the heteroatoms are selected from the group consisting of O, N, S, and P.
9. The method of claim 7, wherein RB comprises three heteroatoms, and wherein Ri is bonded to one of the three heteroatoms, and R2 is bonded to a different one of the three heteroatoms.
10. The method of claim 7, wherein M is selected from among Fe, Co and Ni. 11. The method of claim 7, wherein M is Fe, RB comprises at least three heteroatoms, and wherein Rj is bonded to one of the three heteroatoms, and R2 is bonded to a heteroatom different than the heteroatom to which R\ is bonded; M is selected from among Fe, Co and Ni. 12. The method of claim 11 , wherein each X is independently selected from among halides and substituted or unsubstituted hydrocarbons. 13. A catalyst system comprising an activated bridged compound having the formula:
Ri I
RB-(m)M(Z)(X)2
I R2 wherein M is a metal; each X is an atom or group covalently or ionically bonded to M and may be the same or different; Ri and R may be the same or each may be different and are substituted or unsubstituted cyclopentadienyl or aromatic rings; RB is a structural bridge between the cylcopentadienyl or aromatic rings R\ and R2 and imparts stereorigidity to the rings, and comprises at least one heteroatom bonded to M, with each of Ri and R2 bonded to the same or different heteroatom of RB which heteroatom is also bonded to M; Z is the coordination number of M and is greater than or equal to 4; m is the number of bonds between M and heteroatoms of RB and to impart stereorigidity m>2; and with Ri, R2 and RB selected to provide a catalyst component with Cls C2 or Cs symmetry.
14. The system of claim 13, wherein M is selected from the group consisting of transition metals and lanthanide metals, wherein the heteroatoms are selected from the group consisting of O, N, S and P.
15. The system of claim 13 , wherein RB comprises at least three heteroatoms bonded to M, and wherein Ri is bonded to one of the heteroatoms, and R2 is bonded to a different one of the heteroatoms.
16. The system of claim 13, wherein M is selected from among Fe, Co and Ni. 17. The system of claim 13 , wherein M is Fe, RB comprises three heteroatoms bonded to M, and wherein R is bonded to one of the three heteroatoms, and R2 is bonded to a heteroatom different than the heteroatom to which R] is bonded; M is selected from among Fe, Co and Ni. 18. The system of claim 17, wherein each X is independently selected from among halides and substituted or unsubstituted hydrocarbons. 19. A method of making a catalyst system comprising contacting an activator with a bridged compound having the formula: Ri
RB-(m)M Z)(X)2
R2 wherein M is a metal; each X is an atom or group covalently or ionically bonded to M and may be the same or different; Ri and R2 may be the same or each may be different and are substituted or unsubstituted cyclopentadienyl or aromatic rings; RB is a structural bridge between the cylcopentadienyl or aromatic rings Rj and R2 and imparts stereorigidity to the rings, and comprises at least one heteroatom bonded to M, with each of Ri and R2 bonded to the same or different heteroatom of RB which heteroatom is also bonded to M; Z is the coordination number of M and is greater than or equal to 4; m is the number of bonds between M and heteroatoms of RB and to impart stereorigidity m>2; and with Rls R2 and RB selected to provide a catalyst component with Cls C2 or Cs symmetry.
20. A method of forming polyolefins comprising contacting olefin monomer or mixture of monomers in the presence of an activated bridged compound having the formula:
Ri
I RB-(m)M(Z)(X)2
I
R2 wherein M is a metal; each X is an atom or group covalently or ionically bonded to M and may be the same or different; Ri and R2 may be the same or each may be different and are substituted or unsubstituted cyclopentadienyl or aromatic rings; RB is a structural bridge between the cylcopentadienyl or aromatic rings R\ and R2 and imparts stereorigidity to the rings, and comprises at least one heteroatom bonded to M, with each of R\ and R2 bonded to the same or different heteroatom of RB which heteroatom is also bonded to M; Z is the coordination number of M and is greater than or equal to 4; m is the number of bonds between M and heteroatoms of RB and to impart sterorigidity m>2; and with Ri , R2 and RB selected to provide a catalyst component with Ci, C2 or Cs symmetry.
EP03779526A 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization Withdrawn EP1562705A4 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US301884 2002-11-21
US10/301,884 US20040102311A1 (en) 2002-11-21 2002-11-21 Bridged metallocene catalyst component, method of making, polyolefin catalyst having C1, C2, or Cs symmetry, methods of making, methods of polymerizing, olefins and products made thereof
US10/692,068 US6894180B2 (en) 2002-11-21 2003-10-23 Catalyst structure for olefin polymerization
US692068 2003-10-23
PCT/US2003/036049 WO2004047972A2 (en) 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization

Publications (2)

Publication Number Publication Date
EP1562705A2 EP1562705A2 (en) 2005-08-17
EP1562705A4 true EP1562705A4 (en) 2007-04-25

Family

ID=32396700

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03779526A Withdrawn EP1562705A4 (en) 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization

Country Status (6)

Country Link
EP (1) EP1562705A4 (en)
JP (1) JP4977322B2 (en)
KR (1) KR20050085108A (en)
AU (1) AU2003285202A1 (en)
CA (1) CA2503986A1 (en)
WO (1) WO2004047972A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7034157B2 (en) * 2003-10-23 2006-04-25 Fina Technology, Inc. Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins
AU2006206653A1 (en) * 2005-01-19 2006-07-27 Merck & Co., Inc. Aminomethyl beta-secretase inhibitors for the treatment of Alzheimer's disease
EP1746111A1 (en) * 2005-07-19 2007-01-24 Total Petrochemicals Research Feluy Polymerisation catalyst system based on dioxime ligands
AR124328A1 (en) * 2020-12-15 2023-03-15 Shell Int Research AN OLIGOMERIZATION CATALYST, METHOD OF PREPARATION AND PROCESS FOR USING THE CATALYST
CN114874362B (en) * 2022-03-18 2023-05-23 中国科学院青岛生物能源与过程研究所 Pyridinimine oxime iron catalyst, preparation method thereof and application thereof in conjugated diene polymerization

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998030612A1 (en) * 1997-01-13 1998-07-16 E.I. Du Pont De Nemours And Company Polymerization of propylene
EP1125928A1 (en) * 1999-09-02 2001-08-22 Idemitsu Petrochemical Co., Ltd. Transition metal compounds, catalysts for the production of alpha-olefins and process therefor
WO2003011876A1 (en) * 2001-08-01 2003-02-13 Shell Internationale Research Maatschappij B.V. Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
CN1398836A (en) * 2001-07-20 2003-02-26 中国科学院化学研究所 Iron catalyst and its prepn and application

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0889910B1 (en) * 1996-03-27 2003-03-19 Dow Global Technologies Inc. Solution polymerization process with dispersed catalyst activator
JP2000001512A (en) * 1998-06-16 2000-01-07 Mitsui Chemicals Inc Catalyst for olefin polymerization and method for polymerizing olefin
EP1004599A4 (en) * 1998-06-16 2003-06-04 Mitsui Chemicals Inc Catalyst for olefin polymerization and method of polymerizing olefin
JP2003206308A (en) * 2001-11-09 2003-07-22 Idemitsu Petrochem Co Ltd Polymerization catalyst for vinyl compound, polymer of vinyl compound and its manufacturing method, and composite resin comprising the polymer

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998030612A1 (en) * 1997-01-13 1998-07-16 E.I. Du Pont De Nemours And Company Polymerization of propylene
EP1125928A1 (en) * 1999-09-02 2001-08-22 Idemitsu Petrochemical Co., Ltd. Transition metal compounds, catalysts for the production of alpha-olefins and process therefor
CN1398836A (en) * 2001-07-20 2003-02-26 中国科学院化学研究所 Iron catalyst and its prepn and application
WO2003011876A1 (en) * 2001-08-01 2003-02-13 Shell Internationale Research Maatschappij B.V. Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
BRITOVSEK G J P ET AL: "IRON AND COBALT ETHYLENE POLYMERIZATION CATALYSTS BEARING 2,6-BIS(IMINO)PYRIDYL LIGANDS: SYNTHESIS, STRUCTURES, AND POLYMERIZATION STUDIES", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, US, vol. 121, no. 38, 29 September 1999 (1999-09-29), pages 8728 - 8740, XP001025779, ISSN: 0002-7863 *
BRITOVSEK G J P ET AL: "OLIGOMERISATION OF ETHYLENE BY BIS(IMINO)PYRIDYLIRON AND -COBALT COMPLEXES", CHEMISTRY - A EUROPEAN JOURNAL, VCH PUBLISHERS, US, vol. 6, no. 12, 2000, pages 2221 - 2231, XP000942739, ISSN: 0947-6539 *
ZHI, MA ET AL.: "Ethylene polymerization by iron complexes with symmetrical and unsymmetrical ligands", POLYMER INTERNATIONAL, vol. 51, no. 10, 30 October 2002 (2002-10-30), pages 994 - 997, XP009080780 *

Also Published As

Publication number Publication date
CA2503986A1 (en) 2004-06-10
JP4977322B2 (en) 2012-07-18
AU2003285202A1 (en) 2004-06-18
JP2006507345A (en) 2006-03-02
AU2003285202A8 (en) 2004-06-18
WO2004047972A2 (en) 2004-06-10
EP1562705A2 (en) 2005-08-17
WO2004047972A3 (en) 2004-12-09
KR20050085108A (en) 2005-08-29

Similar Documents

Publication Publication Date Title
EP2310399B1 (en) Pyridyldiamido transition metal complexes, production and use thereof
EP1971577B1 (en) Process for the preparation of unsymmetric bis(imino) compounds
CA2329956A1 (en) Process for the production of half-sandwich transition metal based catalyst precursors
US5962714A (en) Monocyclopentadienyl transition metal catalyst and olefin polymerization process
CN100432084C (en) Non-metallocenes, method for production thereof and use thereof in polymerization of olefins
US20040248728A1 (en) Polyolefin catalyst component using non-covalent interactions
EP0784639B1 (en) Syndiotactic prochiral olefin polymerization process
US20060009350A1 (en) Cyclometallated catalysts
EP1562705A2 (en) New catalyst structure for olefin polymerization
JP4658335B2 (en) Organometallic catalyst for polymerization of unsaturated compounds
US6894180B2 (en) Catalyst structure for olefin polymerization
EP1997834A1 (en) Catalysts
Chen et al. Synthesis and catalytic properties of oxalic amidinato complexes
US6087290A (en) Si-N-Si-bridged metallocenes, their production and use
JP4857475B2 (en) Transition metal compound, olefin polymerization catalyst, and olefin polymerization method
EP1809643A1 (en) Highly soluble ferrocenyl compounds
JP2000219704A (en) Catalyst for olefin polymerization and preparation of polyolefin by using the same
DE10213191A1 (en) Non-metallocenes, processes for their preparation and their use in the polymerization of olefins
US6391988B1 (en) Tris(pyrazoyl) based anions
JP2001181336A (en) Olefin polymerization catalyst and polymerization method for olefin

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20050512

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL LT LV MK

DAX Request for extension of the european patent (deleted)
A4 Supplementary search report drawn up and despatched

Effective date: 20070328

17Q First examination report despatched

Effective date: 20080716

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20140603