WO2004047972A3 - New catalyst structure for olefin polymerization - Google Patents

New catalyst structure for olefin polymerization Download PDF

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Publication number
WO2004047972A3
WO2004047972A3 PCT/US2003/036049 US0336049W WO2004047972A3 WO 2004047972 A3 WO2004047972 A3 WO 2004047972A3 US 0336049 W US0336049 W US 0336049W WO 2004047972 A3 WO2004047972 A3 WO 2004047972A3
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WO
Grant status
Application
Patent type
Prior art keywords
olefin polymerization
ligand
catalyst structure
new catalyst
catalyst
Prior art date
Application number
PCT/US2003/036049
Other languages
French (fr)
Other versions
WO2004047972A2 (en )
Inventor
Didier Baekelmans
Margarito Lopez
Vladimir Marin
Abbas Razavi
Original Assignee
Fina Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181Cyclic ligands, including non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815Cyclic ligands, including non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/02Iron compounds
    • C07F15/025Iron compounds without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • C07F17/02Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/842Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms

Abstract

A catalyst comprising e.g. a pyridine bisimine ligand bonded to a transition metal by at least two heteroatoms of the ligand, the ligand having at least two aromatic groups or cyclopentadienyl groups on different heteroatoms of the ligand. The transition metal compound, its preparation, preparation and use of the catalyst in an olefin polymerization catalyst are also disclosed.
PCT/US2003/036049 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization WO2004047972A3 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US10/301,884 2002-11-21
US10301884 US20040102311A1 (en) 2002-11-21 2002-11-21 Bridged metallocene catalyst component, method of making, polyolefin catalyst having C1, C2, or Cs symmetry, methods of making, methods of polymerizing, olefins and products made thereof
US10/692,068 2003-10-23
US10692068 US6894180B2 (en) 2002-11-21 2003-10-23 Catalyst structure for olefin polymerization

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2004555427A JP4977322B2 (en) 2002-11-21 2003-11-12 The new catalyst structure for the polymerization of olefins
AU2003285202A AU2003285202A8 (en) 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization
CA 2503986 CA2503986A1 (en) 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization
EP20030779526 EP1562705A4 (en) 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization

Publications (2)

Publication Number Publication Date
WO2004047972A2 true WO2004047972A2 (en) 2004-06-10
WO2004047972A3 true true WO2004047972A3 (en) 2004-12-09

Family

ID=32396700

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/036049 WO2004047972A3 (en) 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization

Country Status (5)

Country Link
EP (1) EP1562705A4 (en)
JP (1) JP4977322B2 (en)
KR (1) KR20050085108A (en)
CA (1) CA2503986A1 (en)
WO (1) WO2004047972A3 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7034157B2 (en) * 2003-10-23 2006-04-25 Fina Technology, Inc. Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins
CN101106994A (en) * 2005-01-19 2008-01-16 默克公司 Aminomethyl beta-secretase inhibitors for the treatment of Alzheimer's disease
EP1746111A1 (en) * 2005-07-19 2007-01-24 Total Petrochemicals Research Feluy Polymerisation catalyst system based on dioxime ligands

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999065951A1 (en) * 1998-06-16 1999-12-23 Mitsui Chemicals, Inc. Catalyst for olefin polymerization and method of polymerizing olefin
WO1999065952A1 (en) * 1998-06-16 1999-12-23 Mitsui Chemicals, Inc. Catalyst for olefin polymerization and method of polymerizing olefin

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1243520A (en) * 1997-01-13 2000-02-02 纳幕尔杜邦公司 Polymerization of propylene
JP4674023B2 (en) * 1999-09-02 2011-04-20 出光興産株式会社 Transition metal compound, method for producing α- olefin production catalyst and α- olefin
CN1164534C (en) * 2001-07-20 2004-09-01 中国科学院化学研究所 Iron catalyst and its preparation and application
JP2003206308A (en) * 2001-11-09 2003-07-22 Idemitsu Petrochem Co Ltd Polymerization catalyst for vinyl compound, polymer of vinyl compound and its manufacturing method, and composite resin comprising the polymer

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999065951A1 (en) * 1998-06-16 1999-12-23 Mitsui Chemicals, Inc. Catalyst for olefin polymerization and method of polymerizing olefin
WO1999065952A1 (en) * 1998-06-16 1999-12-23 Mitsui Chemicals, Inc. Catalyst for olefin polymerization and method of polymerizing olefin
US6313243B1 (en) * 1998-06-16 2001-11-06 Mitsui Chemicals Inc Catalyst for olefin polymerization and method of polymerizing olefin
US6369177B1 (en) * 1998-06-16 2002-04-09 Mitsui Chemicals Inc Catalyst for olefin polymerization and method of polymerizing olefin

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1562705A2 *

Also Published As

Publication number Publication date Type
CA2503986A1 (en) 2004-06-10 application
JP4977322B2 (en) 2012-07-18 grant
KR20050085108A (en) 2005-08-29 application
JP2006507345A (en) 2006-03-02 application
EP1562705A2 (en) 2005-08-17 application
EP1562705A4 (en) 2007-04-25 application
WO2004047972A2 (en) 2004-06-10 application

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