JP2006505430A - 形状記憶合金で強化したポリマー複合体構造およびその製造方法 - Google Patents
形状記憶合金で強化したポリマー複合体構造およびその製造方法 Download PDFInfo
- Publication number
- JP2006505430A JP2006505430A JP2004550480A JP2004550480A JP2006505430A JP 2006505430 A JP2006505430 A JP 2006505430A JP 2004550480 A JP2004550480 A JP 2004550480A JP 2004550480 A JP2004550480 A JP 2004550480A JP 2006505430 A JP2006505430 A JP 2006505430A
- Authority
- JP
- Japan
- Prior art keywords
- particles
- sma
- composite structure
- resin matrix
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910001285 shape-memory alloy Inorganic materials 0.000 title claims abstract description 94
- 239000002131 composite material Substances 0.000 title claims abstract description 78
- 229920000642 polymer Polymers 0.000 title abstract description 22
- 238000004519 manufacturing process Methods 0.000 title description 8
- 239000002245 particle Substances 0.000 claims abstract description 103
- 239000011347 resin Substances 0.000 claims abstract description 64
- 229920005989 resin Polymers 0.000 claims abstract description 64
- 239000011159 matrix material Substances 0.000 claims abstract description 47
- 229910001000 nickel titanium Inorganic materials 0.000 claims abstract description 39
- HLXZNVUGXRDIFK-UHFFFAOYSA-N nickel titanium Chemical compound [Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni] HLXZNVUGXRDIFK-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 37
- 239000000956 alloy Substances 0.000 claims abstract description 37
- 239000000463 material Substances 0.000 claims abstract description 24
- 230000002411 adverse Effects 0.000 claims abstract description 9
- 230000006835 compression Effects 0.000 claims abstract description 9
- 238000007906 compression Methods 0.000 claims abstract description 9
- 230000002441 reversible effect Effects 0.000 claims abstract description 6
- 239000012798 spherical particle Substances 0.000 claims abstract 2
- 239000000835 fiber Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 229910001566 austenite Inorganic materials 0.000 claims description 8
- 229910000734 martensite Inorganic materials 0.000 claims description 7
- 239000002923 metal particle Substances 0.000 claims description 5
- 238000005728 strengthening Methods 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000011229 interlayer Substances 0.000 abstract description 18
- 239000010410 layer Substances 0.000 description 39
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 230000008901 benefit Effects 0.000 description 11
- 229920001971 elastomer Polymers 0.000 description 6
- 239000000806 elastomer Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 229920001169 thermoplastic Polymers 0.000 description 5
- 238000009727 automated fiber placement Methods 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- 238000001721 transfer moulding Methods 0.000 description 4
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- 229910000990 Ni alloy Inorganic materials 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- HZEWFHLRYVTOIW-UHFFFAOYSA-N [Ti].[Ni] Chemical compound [Ti].[Ni] HZEWFHLRYVTOIW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000004917 carbon fiber Substances 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000009786 automated tape laying Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000013016 damping Methods 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 238000009787 hand lay-up Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 229910001040 Beta-titanium Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910003286 Ni-Mn Inorganic materials 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- 229910004353 Ti-Cu Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/28—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer impregnated with or embedded in a plastic substance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/10—Interconnection of layers at least one layer having inter-reactive properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/06—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
- F41H5/00—Armour; Armour plates
- F41H5/02—Plate construction
- F41H5/04—Plate construction composed of more than one layer
- F41H5/0442—Layered armour containing metal
- F41H5/0457—Metal layers in combination with additional layers made of fibres, fabrics or plastics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
- Y10T428/24612—Composite web or sheet
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/249933—Fiber embedded in or on the surface of a natural or synthetic rubber matrix
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/249933—Fiber embedded in or on the surface of a natural or synthetic rubber matrix
- Y10T428/249939—Two or more layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
- Y10T428/2996—Glass particles or spheres
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31515—As intermediate layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31515—As intermediate layer
- Y10T428/31522—Next to metal
Landscapes
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Ceramic Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Adhesive Tapes (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Powder Metallurgy (AREA)
Abstract
Description
この発明は、ポリマー複合体構造に関し、より特定的には、形状記憶合金の粒子を注入して構造の耐損傷性、損傷許容性(衝撃後圧縮強度等)、および高温性能を著しく高めた樹脂マトリックス中間層を有するポリマー複合体構造に関する。
さまざまな用途、たとえば航空機の製造における主要構造の用途として選択されかつ適切なポリマー複合体材料は、2つの主な機械的特性、すなわち、衝撃後圧縮(CAI)強度および高温−湿潤圧縮強度、より厳密にはオープンホール圧縮(OHC)強度に関して評価される。しかしながら、複合体材料のCAI強度および高温−湿潤OHC強度を高めるための手段は一般に、互いに相反する効果を生じる。より具体的には、エラストマーベースまたは熱可塑性物質ベースのポリマー粒子を用いて粒状中間層を強化する従来の方法は、複合体のCAI強度を高めるのに効果的であるが、同時に高温−湿潤圧縮強度(高温−湿潤OHC等)の特性を高めるのに概して効果的ではなく、より典型的には、互いに矛盾する関係を生じる。
この発明は、形状記憶合金(SMA)粒子で強化した中間層を有するポリマー複合体構造に向けられる。中間層内でのSMA粒子の使用は、中間層の高温−湿潤圧縮強度に悪影響を及ぼさずに中間層の耐損傷性および損傷許容性(衝撃後圧縮(CAI)強度等)を著しく高める。
態において、別個の樹脂−粒子の中間層は、樹脂中間層のマトリックスに対してSMA「粒子を多く含む」中間層として高濃度でSMA粒子を含み、ファイバ−金属積層物に類似した、連続した金属中間層の形態に近づく。樹脂マトリックス中間層内のSMA粒子の濃度は、結果的に得られる複合体積層物の所望の特性に依存して、樹脂マトリックスの体積に比例して低濃度から高濃度までの範囲を有し得ることが理解されるであろう。
1つの好ましい実施形態または複数の好ましい実施形態の以下の説明は、本質的に単に例示であり、この発明、その用途、または使途を限定するように意図されない。
することが公知であることから、中間層16の高温−湿潤圧縮強度を低下させる。SMA粒子、特にNitinol(登録商標)合金は水分を吸収しないため、中間層16の高温−湿潤圧縮強度に悪影響を及ぼさない。
Molding(VARJM))、樹脂注入等)に容易に組込まれる。
摩耗性の約10倍大きい。熱硬化性ポリマー複合体にNitinol(登録商標)を加えると、Nitinol(登録商標)は、複合体のG1c/G11c特性(すなわち、耐破損性を反映する機械的特性)を高めることができる。上述のように、Nitinol(登録商標)合金はまた、複合体構造に対して極めて改善された電気伝導性も提供し、したがって、度重なる落雷に対する耐久性を改善する。複合体の外側表面の全体の耐久性もまた改善される(すなわち、耐摩耗性および耐侵食性に関して)。
Machining(ATLM))、ホットドレープ成形、高度なファイバプレースメント(AFP)、およびハンドレイアップ作業に対して大きな変更を要しない。Nitinol(登録商標)合金の使用はまた、樹脂トランスファー成形(RTM)、真空アシスト樹脂トランスファー成形(VARTM)、およびシーマンの複合体による樹脂注入成形プロセス(Seamann Composite's Resin Injection Molding Process(SCRIMP))にも容易に適用することができ、ここでは、Nitinol(登録商標)合金粒子が、樹脂含浸工程の前に、予備形成品のファイバの表面に加えられるか、または予備形成品のプライの層と層との間で区画される。SMA粒子によって強化された複合体構造を用いるさらに別の特有の利点は、現行の機械加工の工程に影響を与えずに、現時点で使用されているプレプレッグ材料(すなわち、一方向のテープおよび織物のプレプレッグ)に等しい形態での使用が可能である点である。SMA粒子により強化された複合体はまた、自動テープ敷設による機械加工(ATLM)、高度なファイバプレースメント(AFP)、ホットドレープ成形および従来のハンドレイアップ等の工程で使用される現行の材料に対する、「ドロップイン」置換物として働くことも可能であると言える。認識されるように、複合体構造の中間層内でSMA粒子を用いることは、航空機の構造に大きくかつ明確な利点を有する。Nitinol(登録商標)合金粒子の振動減衰特性は、航空機の構造の疲労寿命を著しく延ばす。一般に、剛性の複合体構造が極度の音響振動および構造振動を発射中に受ける宇宙用途において、Nitinol(登録商標)合金粒子は、中間層の層間剥離および破壊に対してさらなる保護を提供する。
Claims (23)
- 材料の第1の層と、
材料の第2の層と、
材料の前記第1の層および前記第2の層との間に配置されて前記層を共に接着し、一体的な構造を形成する樹脂層と、
前記樹脂層の少なくとも一部の全体に分散して前記一体的な構造を強化する複数の形状記憶合金(SMA)粒子とを含む、複合体構造。 - 前記SMA粒子は、Nitinol(登録商標)合金粒子を含む、請求項1に記載の複合体構造。
- 前記SMA粒子は、円筒形のSMA粒子を含む、請求項1に記載の複合体構造。
- 前記SMA粒子は、楕円形のSMA粒子を含む、請求項1に記載の複合体構造。
- 前記SMA粒子は、ほぼ球形のSMA粒子を含む、請求項1に記載の複合体構造。
- 前記SMA粒子は、約50ミクロン以下の断面直径を含む、請求項1に記載の複合体構造。
- 前記SMA粒子は、オーステナイト相のSMA粒子を含む、請求項1に記載の複合体構造。
- 前記SMA粒子は、マルテンサイト相のSMA粒子を含む、請求項1に記載の複合体構造。
- 第1の繊維質層と、
第2の繊維質層と、
材料の第1の層と第2の層との間に配置されて前記層を共に接着し、一体的な構造を形成する樹脂マトリックス化合物と、
前記樹脂マトリックス層の少なくとも一部の全体に分散する複数の金属粒子とを含み、前記粒子は、可逆性かつ超弾性の歪み特性を有し、前記樹脂マトリックス化合物の高温−湿潤圧縮強度に悪影響を及ぼさずに前記一体的な構造を強化する、複合体構造。 - 前記金属粒子は、Nitinol(登録商標)合金粒子を含む、請求項9に記載の複合体構造。
- 前記金属粒子は、
楕円形の粒子、
球形の粒子、および
円筒形の粒子の1つを含む、請求項10に記載の複合体構造。 - 前記金属粒子は、約50ミクロン以下の断面直径を含む、請求項11に記載の複合体構造。
- 1対の材料層を互いに接着して耐損傷性および損傷許容性(衝撃後圧縮(CAI)強度等)を高めた複合体構造を形成するための樹脂マトリックスであって、
樹脂材料と、
前記樹脂材料の全体に分散して前記樹脂マトリックスを強化する複数の形状記憶合金(
SMA)粒子とを含む、樹脂マトリックス。 - 前記SMA粒子は、Nitinol(登録商標)合金粒子を含む、請求項1に記載の樹脂マトリックス。
- 前記SMA粒子は、円筒形、球形、および楕円形の1つを含む、請求項1に記載の樹脂マトリックス。
- 前記SMA粒子は、約50ミクロン以下の断面直径を含む、請求項1に記載の樹脂マトリックス。
- 前記SMA粒子は、オーステナイト相のSMA粒子を含む、請求項1に記載の樹脂マトリックス。
- 前記SMA粒子は、マルテンサイト相のSMA粒子を含む、請求項1に記載の樹脂マトリックス。
- 複合体構造を形成するための方法であって、
a)第1のファイバ層を設けるステップと、
b)第2のファイバ層を設けるステップと、
c)前記ファイバ層の一方の表面に樹脂マトリックスの層を配置し、前記ファイバ層の他方を前記樹脂マトリックスに接触させるステップとを含み、前記樹脂マトリックスは、前記樹脂マトリックスを強化するために前記樹脂マトリックスの樹脂内に、すなわち、前記複合体構造の樹脂内に分散する複数の形状記憶合金(SMA)粒子を含み、前記方法はさらに、
d)前記ファイバ層および前記樹脂マトリックスを加熱して前記樹脂マトリックスを硬化させ、それによって前記ファイバ層および前記樹脂マトリックスに一体的な複合体構造を形成させるステップを含む、方法。 - ステップc)はNitinol(登録商標)合金を含むSMA粒子を用いるステップを含む、請求項19に記載の方法。
- ステップc)は、約50ミクロン以下の断面直径を有するSMA粒子を用いるステップを含む、請求項19に記載の方法。
- ステップc)は、円筒、球、および楕円のうちの1つの形状をとったSMA粒子を用いるステップを含む、請求項19に記載の方法。
- ステップc)は、約50ミクロンと約0.005ミクロンとの間の断面直径を有するSMA粒子を用いるステップを含む、請求項19に記載の方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/287,561 US6989197B2 (en) | 2002-11-04 | 2002-11-04 | Polymer composite structure reinforced with shape memory alloy and method of manufacturing same |
PCT/US2003/035160 WO2004041951A2 (en) | 2002-11-04 | 2003-11-04 | Polymer composite structure reinforced with shape memory alloy and method of manufacturing same |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006505430A true JP2006505430A (ja) | 2006-02-16 |
JP4319143B2 JP4319143B2 (ja) | 2009-08-26 |
Family
ID=32175719
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004550479A Pending JP2006505655A (ja) | 2002-11-04 | 2003-11-04 | 形状記憶合金で強化したポリマー複合体構造およびその製造方法 |
JP2004550480A Expired - Lifetime JP4319143B2 (ja) | 2002-11-04 | 2003-11-04 | 形状記憶合金で強化したポリマー複合体構造およびその製造方法 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004550479A Pending JP2006505655A (ja) | 2002-11-04 | 2003-11-04 | 形状記憶合金で強化したポリマー複合体構造およびその製造方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US6989197B2 (ja) |
EP (2) | EP1565535B1 (ja) |
JP (2) | JP2006505655A (ja) |
AU (2) | AU2003290611A1 (ja) |
CA (3) | CA2505242C (ja) |
ES (2) | ES2722626T3 (ja) |
WO (2) | WO2004041950A2 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010508416A (ja) * | 2006-11-06 | 2010-03-18 | ヘクセル コンポジット、リミテッド | 改良型複合材料 |
US11990588B2 (en) | 2019-04-09 | 2024-05-21 | Lg Energy Solution, Ltd. | Battery cell including short-circuit inducing member and safety evaluation method using same |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7431981B2 (en) * | 2002-11-04 | 2008-10-07 | The Boeing Company | Polymer composite structure reinforced with shape memory alloy and method of manufacturing same |
WO2005028910A1 (ja) * | 2003-09-24 | 2005-03-31 | Bridgestone Corporation | 制振合金部材及びそれを用いた防振ゴム、床振動減衰装置、タイヤ、スチールコード、免震ゴム |
CA2551080C (en) * | 2004-01-19 | 2011-07-05 | Elaco Pty Ltd. | High strength, impact resistant, elastic composite laminates |
WO2005089157A2 (en) * | 2004-03-12 | 2005-09-29 | General Motors Corporation | Morphable body moldings, rub strips, and bumpers |
CN1977026A (zh) * | 2004-06-17 | 2007-06-06 | 埃克森美孚上游研究公司 | 可变密度钻探泥浆 |
GB0423948D0 (en) * | 2004-10-28 | 2004-12-01 | Qinetiq Ltd | Composite materials |
US20100098929A1 (en) * | 2005-07-11 | 2010-04-22 | John Anthony Dispenza | Impact resistant composite material |
JP4969363B2 (ja) | 2006-08-07 | 2012-07-04 | 東レ株式会社 | プリプレグおよび炭素繊維強化複合材料 |
US7807258B2 (en) * | 2006-09-22 | 2010-10-05 | Board Of Trustees Of Michigan State University | Topologically controlled composite structure |
GB2473226A (en) * | 2009-09-04 | 2011-03-09 | Hexcel Composites Ltd | Composite materials |
US20150210039A1 (en) * | 2006-11-06 | 2015-07-30 | Hexcel Composites Limited | Composite materials |
US7777165B2 (en) * | 2007-02-02 | 2010-08-17 | Raytheon Company | Methods and apparatus for adjustable surfaces |
WO2008148769A2 (en) * | 2007-06-04 | 2008-12-11 | Arcelik Anonim Sirketi | A cooking range |
US7878459B2 (en) * | 2007-06-29 | 2011-02-01 | The Boeing Company | Aircraft systems with shape memory alloy (SMA) actuators, and associated methods |
US8038133B2 (en) * | 2007-09-13 | 2011-10-18 | Mcpherson Mathew A | Coaxial tube damper |
US7935214B2 (en) * | 2007-11-06 | 2011-05-03 | The Boeing Company | Toughened resin fiber laminates with titanium particles |
US8225478B2 (en) * | 2008-01-30 | 2012-07-24 | The Boeing Company | Memory shape bushings and bearings |
GB0807593D0 (en) * | 2008-04-28 | 2008-06-04 | Rolls Royce Plc | A composite article comprising a shape memory material member |
US8382042B2 (en) * | 2008-05-14 | 2013-02-26 | Raytheon Company | Structure with reconfigurable polymer material |
US8016249B2 (en) * | 2008-05-14 | 2011-09-13 | Raytheon Company | Shape-changing structure member with embedded spring |
US7939178B2 (en) * | 2008-05-14 | 2011-05-10 | Raytheon Company | Shape-changing structure with superelastic foam material |
US8058595B2 (en) * | 2008-06-18 | 2011-11-15 | Raytheon Company | Collapsible shape memory alloy (SMA) nose cones for air vehicles, method of manufacture and use |
US8262032B2 (en) * | 2008-11-13 | 2012-09-11 | Raytheon Company | Collapsible wing beams and method |
US8056853B2 (en) | 2008-11-25 | 2011-11-15 | Raytheon Company | Reconfigurable wing and method of use |
US8387536B2 (en) | 2008-12-04 | 2013-03-05 | Raytheon Company | Interceptor vehicle with extendible arms |
US8573535B2 (en) * | 2009-03-27 | 2013-11-05 | Raytheon Company | Shape-change material and method |
RU2477627C1 (ru) * | 2011-07-18 | 2013-03-20 | Общество с ограниченной ответственностью "ИЛЬКОМ" | Полимерный композиционный материал |
WO2013066439A1 (en) | 2011-11-04 | 2013-05-10 | Raytheon Company | Chord-expanding air vehicle wings |
WO2013144639A1 (en) | 2012-03-30 | 2013-10-03 | Mbda Uk Limited | Composite material suitable for a morphing skin |
GB2500699A (en) * | 2012-03-30 | 2013-10-02 | Mbda Uk Ltd | Composite morphing skin for an aircraft |
US10661885B2 (en) * | 2012-05-16 | 2020-05-26 | The Boeing Company | Shape memory alloy active spars for blade twist |
US9360271B1 (en) | 2013-03-14 | 2016-06-07 | Mcp Ip, Llc | Vibration damper |
WO2015076908A2 (en) | 2013-09-13 | 2015-05-28 | Brandeis University | Polymeric materials having active cross-linkers, methods for making them, and use thereof |
US10099434B2 (en) | 2014-09-16 | 2018-10-16 | General Electric Company | Composite airfoil structures |
US9821530B2 (en) * | 2014-11-25 | 2017-11-21 | The Boeing Company | Composite laminate including interlayers with through-plane regions fused to fiber beds |
WO2019041004A1 (en) * | 2017-09-01 | 2019-03-07 | Embraer S.A. | RETRACTABLE ATTACHMENT BITS HAVING AN AUTONOMOUSLY CURVING AIR FLOW DEVICE TO REDUCE NOISE |
GB201811543D0 (en) * | 2018-07-13 | 2018-08-29 | Rolls Royce Plc | Fan blade containment |
US11565505B2 (en) | 2019-09-10 | 2023-01-31 | General Electric Company | Laminate assembly with embedded conductive alloy elements |
CN113308176B (zh) * | 2021-06-01 | 2022-04-12 | 宁波格林斯粉末涂装有限公司 | 一种聚酯树脂粉末涂料 |
CN116927953A (zh) | 2022-03-31 | 2023-10-24 | 通用电气公司 | 具有形状记忆合金颗粒的表面 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59193934A (ja) * | 1983-04-18 | 1984-11-02 | Omron Tateisi Electronics Co | プラスチツク成形品 |
JPH041287A (ja) * | 1990-04-18 | 1992-01-06 | Mitsubishi Electric Corp | 導電性接着剤 |
JPH04207100A (ja) | 1990-11-30 | 1992-07-29 | Showa Electric Wire & Cable Co Ltd | 導電性樹脂組成物 |
JPH07525U (ja) * | 1992-06-15 | 1995-01-06 | 泰文 古屋 | 複合機能材料製造プロセス |
JPH0636613A (ja) | 1992-07-16 | 1994-02-10 | Rohm Co Ltd | 電子部品用接合材料およびそれを用いた電子機器 |
JPH06212018A (ja) * | 1993-01-14 | 1994-08-02 | Yasubumi Furuya | 高分子基複合機能性材料 |
DE69507771T2 (de) * | 1994-11-16 | 1999-07-22 | Daiwa Seiko Inc | Angelrute mit Schnurinnenführung |
JPH08199080A (ja) * | 1995-01-26 | 1996-08-06 | Mitsubishi Cable Ind Ltd | 形状記憶複合体 |
US5614305A (en) | 1995-02-08 | 1997-03-25 | Virginia Tech Intellectual Properties, Inc. | Impact and perforation resistant composite structures |
US5700337A (en) | 1996-03-01 | 1997-12-23 | Mcdonnell Douglas Corporation | Fabrication method for composite structure adapted for controlled structural deformation |
GB9827367D0 (en) * | 1998-12-11 | 1999-02-03 | Dow Deutschland Inc | Adhesive resin composition |
JP2000311920A (ja) * | 1999-04-26 | 2000-11-07 | Matsushita Electric Ind Co Ltd | 電子部品接続材料及びそれを用いた電子機器 |
JP2000334883A (ja) * | 1999-05-27 | 2000-12-05 | Agency Of Ind Science & Technol | 可逆的に形状変化する高分子成形品 |
JP2001311072A (ja) * | 2000-04-27 | 2001-11-09 | Hitachi Chem Co Ltd | 摩擦材組成物及び摩擦材組成物を用いた摩擦材 |
-
2002
- 2002-11-04 US US10/287,561 patent/US6989197B2/en not_active Expired - Lifetime
-
2003
- 2003-11-04 CA CA 2505242 patent/CA2505242C/en not_active Expired - Lifetime
- 2003-11-04 CA CA 2505241 patent/CA2505241C/en not_active Expired - Lifetime
- 2003-11-04 WO PCT/US2003/035159 patent/WO2004041950A2/en active Application Filing
- 2003-11-04 ES ES03786580T patent/ES2722626T3/es not_active Expired - Lifetime
- 2003-11-04 WO PCT/US2003/035160 patent/WO2004041951A2/en active Application Filing
- 2003-11-04 JP JP2004550479A patent/JP2006505655A/ja active Pending
- 2003-11-04 JP JP2004550480A patent/JP4319143B2/ja not_active Expired - Lifetime
- 2003-11-04 EP EP03786580.5A patent/EP1565535B1/en not_active Expired - Lifetime
- 2003-11-04 ES ES03783145T patent/ES2717133T3/es not_active Expired - Lifetime
- 2003-11-04 AU AU2003290611A patent/AU2003290611A1/en not_active Abandoned
- 2003-11-04 AU AU2003295394A patent/AU2003295394A1/en not_active Abandoned
- 2003-11-04 EP EP03783145.0A patent/EP1563027B1/en not_active Expired - Lifetime
- 2003-11-04 CA CA 2779040 patent/CA2779040C/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010508416A (ja) * | 2006-11-06 | 2010-03-18 | ヘクセル コンポジット、リミテッド | 改良型複合材料 |
JP2015007245A (ja) * | 2006-11-06 | 2015-01-15 | ヘクセル コンポジッツ、リミテッド | 改良型複合材料 |
JP2015166464A (ja) * | 2006-11-06 | 2015-09-24 | ヘクセル コンポジッツ、リミテッド | 改良型複合材料 |
JP2017071778A (ja) * | 2006-11-06 | 2017-04-13 | ヘクセル コンポジッツ、リミテッド | 改良型複合材料 |
US11990588B2 (en) | 2019-04-09 | 2024-05-21 | Lg Energy Solution, Ltd. | Battery cell including short-circuit inducing member and safety evaluation method using same |
Also Published As
Publication number | Publication date |
---|---|
EP1563027B1 (en) | 2019-01-09 |
EP1565535A2 (en) | 2005-08-24 |
AU2003295394A1 (en) | 2004-06-07 |
WO2004041950A3 (en) | 2004-09-23 |
AU2003290611A1 (en) | 2004-06-07 |
CA2505242C (en) | 2012-01-17 |
WO2004041951A2 (en) | 2004-05-21 |
CA2779040A1 (en) | 2004-05-21 |
CA2505242A1 (en) | 2004-05-21 |
CA2779040C (en) | 2015-04-28 |
ES2722626T3 (es) | 2019-08-14 |
CA2505241C (en) | 2012-10-02 |
EP1563027A2 (en) | 2005-08-17 |
EP1565535B1 (en) | 2019-02-20 |
ES2717133T3 (es) | 2019-06-19 |
US20040086699A1 (en) | 2004-05-06 |
WO2004041950A2 (en) | 2004-05-21 |
US6989197B2 (en) | 2006-01-24 |
JP2006505655A (ja) | 2006-02-16 |
CA2505241A1 (en) | 2004-05-21 |
WO2004041951A3 (en) | 2004-09-16 |
JP4319143B2 (ja) | 2009-08-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4319143B2 (ja) | 形状記憶合金で強化したポリマー複合体構造およびその製造方法 | |
US8298656B2 (en) | Polymer composite structure reinforced with shape memory alloy and method of manufacturing same | |
EP1805006B1 (en) | Composite structures | |
US20160032939A1 (en) | Airfoil structures | |
US20130330496A1 (en) | Composite structure with low density core and composite stitching reinforcement | |
NZ548594A (en) | High impact strength, elastic, composite, fibre, metal laminate | |
JP5228518B2 (ja) | 風車翼ならびにその成形金型および製造方法 | |
JP4107475B2 (ja) | 繊維強化複合材料用の補強繊維 | |
Gupta et al. | Comparative study of damping in pristine, steel, and shape memory alloy hybrid glass fiber reinforced plastic composite beams of equivalent stiffness | |
US20040086706A1 (en) | Polymer composite structure reinforced with shape memory alloy and method of manufacturing same | |
Singh C et al. | A review on wire mesh reinforced polymer composite | |
US20040086705A1 (en) | Polymer composite structure reinforced with shape memory alloy and method of manufacturing same | |
US9834649B1 (en) | Shaped fiber composites | |
US20040086704A1 (en) | Polymer composite structure reinforced with shape memory alloy and method of manufacturing same | |
Porter et al. | continuation-in-part of application No. 10/287,561, resin has shape memory alloy (SMA) particles intermixed in filed on Nov. 4, 2002, now Pat. No. 6,989,197. the resin to toughen the material when the material is used in | |
JPH04267139A (ja) | 炭素繊維強化複合材料プリプレグシート | |
Kinnan et al. | Shaped fiber composites | |
Raghava | Development and characterization of controlled interphase composites (CIC) materials for damage tolerant applications | |
Deepak | Investigation of tribological behaviour of advanced composite material | |
Nensi et al. | Thermal and Mechanical Performance of Shape Memory Reinforced Carbon Composites | |
Evensen et al. | Low Velocity Impact of Spectra®/Carbon Fiber Laminates Under Varied Temperature | |
SHAFFER et al. | 1. A Polymer Composites 1.1 Description |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20060629 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20090120 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20090325 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20090519 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20090527 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120605 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 4319143 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130605 Year of fee payment: 4 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
EXPY | Cancellation because of completion of term |