JP2006342348A - 不動態化無機ナノ粒子を調製するための低エネルギー法 - Google Patents
不動態化無機ナノ粒子を調製するための低エネルギー法 Download PDFInfo
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- JP2006342348A JP2006342348A JP2006143019A JP2006143019A JP2006342348A JP 2006342348 A JP2006342348 A JP 2006342348A JP 2006143019 A JP2006143019 A JP 2006143019A JP 2006143019 A JP2006143019 A JP 2006143019A JP 2006342348 A JP2006342348 A JP 2006342348A
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- Prior art keywords
- alumina
- nanoparticles
- titanium dioxide
- inorganic nanoparticles
- treated
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- 239000002105 nanoparticle Substances 0.000 title claims abstract description 92
- 238000000034 method Methods 0.000 title claims abstract description 55
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- 239000004408 titanium dioxide Substances 0.000 claims abstract description 76
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- 239000002245 particle Substances 0.000 claims abstract description 68
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 50
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 45
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- 150000001450 anions Chemical class 0.000 claims abstract description 13
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims abstract description 12
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- -1 citrate ions Chemical class 0.000 claims description 15
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- 235000003270 potassium fluoride Nutrition 0.000 claims description 5
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- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
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- 239000000395 magnesium oxide Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
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- 150000002739 metals Chemical class 0.000 description 1
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- 238000012986 modification Methods 0.000 description 1
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- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 1
- MQWFLKHKWJMCEN-UHFFFAOYSA-N n'-[3-[dimethoxy(methyl)silyl]propyl]ethane-1,2-diamine Chemical compound CO[Si](C)(OC)CCCNCCN MQWFLKHKWJMCEN-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229940085991 phosphate ion Drugs 0.000 description 1
- 238000013032 photocatalytic reaction Methods 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
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- 229920001721 polyimide Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
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- 229920005989 resin Polymers 0.000 description 1
- 230000025600 response to UV Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical class S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 description 1
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- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
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- 238000012546 transfer Methods 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
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- 238000004846 x-ray emission Methods 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3653—Treatment with inorganic compounds
- C09C1/3661—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3615—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
- C09C1/3623—Grinding
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3692—Combinations of treatments provided for in groups C09C1/3615 - C09C1/3684
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/64—Optical properties, e.g. expressed in CIELAB-values b* (yellow-blue axis)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/66—Hue (H*)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31942—Of aldehyde or ketone condensation product
- Y10T428/31949—Next to cellulosic
- Y10T428/31964—Paper
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/135,584 US7276231B2 (en) | 2005-05-23 | 2005-05-23 | Lower-energy process for preparing passivated inorganic nanoparticles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006342348A true JP2006342348A (ja) | 2006-12-21 |
| JP2006342348A5 JP2006342348A5 (enExample) | 2009-07-09 |
Family
ID=36847640
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006143019A Withdrawn JP2006342348A (ja) | 2005-05-23 | 2006-05-23 | 不動態化無機ナノ粒子を調製するための低エネルギー法 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US7276231B2 (enExample) |
| EP (1) | EP1726625A1 (enExample) |
| JP (1) | JP2006342348A (enExample) |
| KR (1) | KR20060121695A (enExample) |
| AU (1) | AU2006202179B2 (enExample) |
| CA (1) | CA2546309A1 (enExample) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016501289A (ja) * | 2012-11-13 | 2016-01-18 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | シリカ含有自己分散型顔料を製造する方法 |
| JP2016501320A (ja) * | 2012-11-13 | 2016-01-18 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 自己分散型顔料を含む装飾紙 |
| JP2016504213A (ja) * | 2012-11-13 | 2016-02-12 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 自己分散型顔料を含む装飾紙から作られる積層体 |
| JP2016505406A (ja) * | 2012-11-13 | 2016-02-25 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 自己分散型顔料を含む装飾紙から調製される積層体 |
| JP2016505721A (ja) * | 2012-11-13 | 2016-02-25 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 自己分散型顔料を含む装飾紙 |
| JP2016505654A (ja) * | 2012-11-13 | 2016-02-25 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 自己分散顔料 |
| JP2016506421A (ja) * | 2012-11-13 | 2016-03-03 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 自己分散顔料の調製方法 |
| JP2016507593A (ja) * | 2012-11-13 | 2016-03-10 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | シリカ含有自己分散型顔料 |
| JP2018027881A (ja) * | 2016-05-10 | 2018-02-22 | セラニーズ・インターナショナル・コーポレーション | 二酸化チタンを含有するスラリー |
| JP2022553012A (ja) * | 2019-10-18 | 2022-12-21 | イネオス・ピグメンツ・ユーエスエー・インコーポレイテッド | 増強された耐久性を有する色素及びそれを用いて作製された可塑性材料 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050129634A1 (en) * | 2003-12-16 | 2005-06-16 | Frerichs Scott R. | Passivated nano-titanium dioxide particles and methods of making the same |
| US7276231B2 (en) * | 2005-05-23 | 2007-10-02 | E I Du Pont De Nemours And Company | Lower-energy process for preparing passivated inorganic nanoparticles |
| US7790658B2 (en) | 2005-05-27 | 2010-09-07 | University of Florida Research Foundaction, Inc. | Inert wear resistant PTFE-based solid lubricant nanocomposite |
| GB0526328D0 (en) * | 2005-12-23 | 2006-02-01 | Ici Plc | Particulate metal oxide |
| TW200737520A (en) * | 2006-03-17 | 2007-10-01 | Univ Nat Chiao Tung | Gate dielectric structure and an organic thin film transistor based thereon |
| EP2057235B1 (de) | 2006-08-25 | 2018-05-02 | Sachtleben Chemie GmbH | Anorganisch oberflächenmodifizierte ultrafeine partikel |
| WO2010037076A1 (en) * | 2008-09-29 | 2010-04-01 | E.I. Du Pont De Nemours And Company | Coating compositions having improved solar reflectivity and uv protection |
| US9982209B2 (en) | 2012-05-14 | 2018-05-29 | University Of Florida Research Foundation, Inc | Low-wear fluoropolymer composites |
| AU2015343361B2 (en) | 2014-11-06 | 2019-06-20 | The Chemours Company Fc, Llc | Preparation of lacing resistant, titanium dioxide particles for use in photodurable thin film production |
| CN104877393B (zh) * | 2015-04-08 | 2018-03-30 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种低吸油量钛白粉及其制备方法 |
| WO2017014747A1 (en) | 2015-07-20 | 2017-01-26 | Hewlett-Packard Development Company, L.P. | Non-newtonian white inks |
| US10472530B2 (en) | 2015-07-20 | 2019-11-12 | Hewlett-Packard Development Company, L.P. | White inks |
| WO2017014746A1 (en) | 2015-07-20 | 2017-01-26 | Hewlett-Packard Development Company, L.P. | White inks |
| US10486029B2 (en) | 2015-11-17 | 2019-11-26 | Acushnet Company | Golf ball displaying improved adhesion between TiO2-pigmented layer incorporating silane-containing adhesion promoter and an adjacent differing layer |
| EP3678635A4 (en) | 2017-09-05 | 2021-06-02 | Vizor, LLC | INORGANIC SUN SCREEN WITH HIGHER PROTECTION AGAINST UV RADIATION |
| CN111484756B (zh) * | 2020-05-22 | 2022-02-08 | 中信钛业股份有限公司 | 一种提高氧化铝包覆钛白粉分散稳定性的方法 |
| CN111621171B (zh) * | 2020-05-22 | 2022-02-08 | 中信钛业股份有限公司 | 一种提高钛白粉表面二氧化硅包覆层致密性的方法 |
| CN112142353B (zh) * | 2020-10-16 | 2021-09-21 | 东北大学 | 一种高效无害化处理铝灰的方法 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE870242C (de) | 1941-09-26 | 1953-03-12 | Degussa | Verfahren zum Verdicken von Fluessigkeiten |
| US3834924A (en) * | 1972-06-08 | 1974-09-10 | Huber Corp J M | Process for manufacturing surface modified inorganic pigments |
| US3915735A (en) * | 1974-03-06 | 1975-10-28 | Malvern Minerals Company | Process for preparing modified silicic fillers |
| US4141751A (en) * | 1975-10-24 | 1979-02-27 | Malvern Minerals Company | Process for preparing modified particulate and/or fibrous, crystalline and amorphous inorganic substances |
| US4191737A (en) * | 1978-10-02 | 1980-03-04 | Conoco, Inc. | Increasing alumina slurry life |
| US4416699A (en) * | 1982-01-21 | 1983-11-22 | E. I. Du Pont De Nemours & Co. | Alumina coated TiO2 |
| US4460655A (en) * | 1983-04-04 | 1984-07-17 | E. I. Du Pont De Nemours And Company | TiO2 Pigment bearing a coating with fluoride ions and laminate and coating based thereon |
| US4737194A (en) | 1986-04-30 | 1988-04-12 | E. I. Du Pont De Nemours And Company | Titanium dioxide pigment coated with cerium cations, selected acid anions, and alumina |
| GB8908995D0 (en) | 1989-04-20 | 1989-06-07 | Tioxide Group Plc | Particulate material |
| DE4202695C2 (de) | 1992-01-31 | 1993-12-09 | Degussa | Oberflächenmodifiziertes, pyrogen hergestelltes Titandioxid |
| US5393510A (en) * | 1992-07-22 | 1995-02-28 | Rheox, Inc. | High solids content titanium dioxide suspension |
| DE4235996A1 (de) | 1992-10-24 | 1994-04-28 | Degussa | Flammenhydrolytisch hergestelltes Titandioxid-Mischoxid, Verfahren zu seiner Herstellung und Verwendung |
| US6193795B1 (en) | 1993-08-02 | 2001-02-27 | Degussa Corporation | Low structure pyrogenic hydrophilic and hydrophobic metallic oxides, production and use |
| US5607994A (en) | 1994-02-28 | 1997-03-04 | E. I. Du Pont De Nemours And Company | Processibility and lacing resistance when silanized pigments are incorporated in polymers |
| US5562990A (en) | 1994-02-28 | 1996-10-08 | E. I. Du Pont De Nemours And Company | Organosilicon treatment of TiO2 pigment bearing a coating with fluoride ions |
| US5698177A (en) | 1994-08-31 | 1997-12-16 | University Of Cincinnati | Process for producing ceramic powders, especially titanium dioxide useful as a photocatalyst |
| DE19500674A1 (de) | 1995-01-12 | 1996-07-18 | Degussa | Oberflächenmodifizierte pyrogen hergestellte Mischoxide, Verfahren zu ihrer Herstellung und Verwendung |
| EP1261667B1 (en) * | 1999-11-12 | 2011-10-05 | Millennium Inorganic Chemicals, Inc. | Processes for preparing hydrophobic inorganic oxide pigments |
| US6429237B2 (en) * | 2000-04-13 | 2002-08-06 | E. I. Du Pont De Nemours & Company | Wire coating compositions |
| US20020155059A1 (en) | 2001-04-24 | 2002-10-24 | Tekna Plasma Systems Inc. | Plasma synthesis of titanium dioxide nanopowder and powder doping and surface modification process |
| US20030027897A1 (en) * | 2001-04-26 | 2003-02-06 | Mei Henry L. | Modified silane treated pigments or fillers and compositions containing the same |
| GB0130658D0 (en) | 2001-12-21 | 2002-02-06 | Acma | Particulate metal oxide |
| EP1558015B1 (en) | 2002-08-30 | 2009-10-07 | Sony Corporation | Image extraction device, image extraction method, image processing device, image processing method, and imaging device |
| US6962006B2 (en) * | 2002-12-19 | 2005-11-08 | Acusphere, Inc. | Methods and apparatus for making particles using spray dryer and in-line jet mill |
| US20050129634A1 (en) * | 2003-12-16 | 2005-06-16 | Frerichs Scott R. | Passivated nano-titanium dioxide particles and methods of making the same |
| US7276231B2 (en) * | 2005-05-23 | 2007-10-02 | E I Du Pont De Nemours And Company | Lower-energy process for preparing passivated inorganic nanoparticles |
-
2005
- 2005-05-23 US US11/135,584 patent/US7276231B2/en not_active Expired - Fee Related
-
2006
- 2006-05-11 CA CA 2546309 patent/CA2546309A1/en not_active Abandoned
- 2006-05-12 EP EP20060009814 patent/EP1726625A1/en not_active Withdrawn
- 2006-05-22 KR KR1020060045679A patent/KR20060121695A/ko not_active Withdrawn
- 2006-05-23 JP JP2006143019A patent/JP2006342348A/ja not_active Withdrawn
- 2006-05-23 AU AU2006202179A patent/AU2006202179B2/en not_active Ceased
-
2007
- 2007-08-06 US US11/890,399 patent/US20080085967A1/en not_active Abandoned
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016501289A (ja) * | 2012-11-13 | 2016-01-18 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | シリカ含有自己分散型顔料を製造する方法 |
| JP2016501320A (ja) * | 2012-11-13 | 2016-01-18 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 自己分散型顔料を含む装飾紙 |
| JP2016504213A (ja) * | 2012-11-13 | 2016-02-12 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 自己分散型顔料を含む装飾紙から作られる積層体 |
| JP2016505406A (ja) * | 2012-11-13 | 2016-02-25 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 自己分散型顔料を含む装飾紙から調製される積層体 |
| JP2016505721A (ja) * | 2012-11-13 | 2016-02-25 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 自己分散型顔料を含む装飾紙 |
| JP2016505654A (ja) * | 2012-11-13 | 2016-02-25 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 自己分散顔料 |
| JP2016506421A (ja) * | 2012-11-13 | 2016-03-03 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 自己分散顔料の調製方法 |
| JP2016507593A (ja) * | 2012-11-13 | 2016-03-10 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | シリカ含有自己分散型顔料 |
| JP2018027881A (ja) * | 2016-05-10 | 2018-02-22 | セラニーズ・インターナショナル・コーポレーション | 二酸化チタンを含有するスラリー |
| JP2022058574A (ja) * | 2016-05-10 | 2022-04-12 | アセテート・インターナショナル・エルエルシー | 二酸化チタンを含有するスラリー |
| JP7313110B2 (ja) | 2016-05-10 | 2023-07-24 | アセテート・インターナショナル・エルエルシー | 二酸化チタンを含有するスラリー |
| JP2022553012A (ja) * | 2019-10-18 | 2022-12-21 | イネオス・ピグメンツ・ユーエスエー・インコーポレイテッド | 増強された耐久性を有する色素及びそれを用いて作製された可塑性材料 |
Also Published As
| Publication number | Publication date |
|---|---|
| US7276231B2 (en) | 2007-10-02 |
| US20060264552A1 (en) | 2006-11-23 |
| EP1726625A1 (en) | 2006-11-29 |
| AU2006202179A1 (en) | 2006-12-07 |
| CA2546309A1 (en) | 2006-11-23 |
| US20080085967A1 (en) | 2008-04-10 |
| KR20060121695A (ko) | 2006-11-29 |
| AU2006202179B2 (en) | 2011-09-22 |
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