JP2006241050A - Cosmetic - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a highly stable cosmetic without problems such as deterioration of odors or discoloration though 1,3-butylene glycol is formulated. <P>SOLUTION: The cosmetic is characterized as formulating the 1,3-butylene glycol and 2-ethyl-1,3-hexanediol. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

The present invention relates to a cosmetic, and more particularly, to a cosmetic blended with 1,3-butylene glycol having excellent stability and no odor deterioration or discoloration over time.

1,3-butylene glycol has high safety and stability, and is a moisturizer widely blended in cosmetics due to its versatility and high use record.
However, cosmetics containing 1,3-butylene glycol often cause odor deterioration and coloring over time. Odor deterioration has become a major problem in cosmetics, and often limits the blending of 1,3-butylene glycol. In addition, these phenomena such as odor degradation and coloration are various, such as when they occur in temperature stability tests, or when they occur in light stability tests such as by sunlight irradiation, and there is no particular tendency to the phenomenon. Since the amount of components and coloring components is very small, the cause is unknown, and therefore there is a problem that a prevention method cannot be established.

So far, this phenomenon has been dealt with by adding flavor to the preparation, coloring it, or using a light-shielding bottle.

However, in recent years, consumers have favored unscented and uncolored preparations, and these deterioration phenomena have become a major problem in the preparation of preparations. Therefore, makeup using 1,3-butylene glycol is incorporated. There has been a strong demand for a formulation that does not cause stability problems such as odor degradation and discoloration.

  As a result of intensive studies by the present inventors in order to achieve the above object, the odor of the preparation can be obtained by adding 2-ethyl-1,3-hexanediol to the preparation containing 1,3-butylene glycol. The inventors have found that a preparation having significantly improved preparation stability can be obtained without causing phenomena such as deterioration and discoloration, and the present invention has been completed.

Here, 2-ethyl-1,3-hexanediol used in the present invention is a known substance (Patent Documents 1, 2, and 3), but is generally used as a pest repellent.
US2407205 WO89 / 03639 JP 5-94828 A

That is, the present invention is a novel cosmetic excellent in formulation stability, in which 2-ethyl-1,3-hexanediol is blended with 1,3-butylene glycol and does not cause phenomena such as odor degradation and discoloration.

The present invention is characterized in that the cosmetic is a basic cosmetic, a makeup cosmetic, and a body cosmetic.
In the cosmetic, the present invention is characterized in that the proportion of 1,3-butylene glycol in the cosmetic is 0.01 to 10.0% by mass.
In the cosmetic, the present invention is characterized in that the proportion of 2-ethyl-1,3-hexanediol in the cosmetic is 0.01 to 5.0% by mass.
In the cosmetic, the proportion of 2-ethyl-1,3-hexanediol in the cosmetic is 1.0% of the proportion of 1,3-butylene glycol in the cosmetic. It is the above.

In the cosmetics of the present invention, by adding 1,3-butylene glycol and 2-ethyl-1,3-hexanediol, there is no problem of odor deterioration or discoloration, and the stability is significantly improved. Can be provided.

Hereinafter, embodiments of the present invention will be described in more detail.
1,3-butylene glycol used in the present invention is a humectant widely blended in cosmetics, and the content in the cosmetics is not particularly limited, but is preferably 0.01 to 10.0% by mass. . If the amount is too small, the moisturizing effect will not be exhibited, and if it is added excessively, problems such as stickiness will occur.

2-ethyl-1,3-hexanediol used in the present invention can be produced by a known synthesis method. It is also commercially available from Tokyo Chemical Industry Co., Ltd. and can be easily obtained.

The 2-ethyl-1,3-hexanediol used in the present invention has stereoisomerism due to its structure, but in the present invention, it may be a single compound or a mixture thereof, and the mixing ratio thereof is also It doesn't matter. Further, although optical isomerism occurs, it may be optically active, racemic, or a mixture thereof, or may be a single or a mixture of their stereoisomerism, and their mixing ratio is not limited.

2-Ethyl-1,3-hexanediol used in the present invention is a transparent liquid substance having a high boiling point, and after preparation of cosmetics, crystals do not precipitate even at low temperatures and can be volatilized even at high temperatures. Without improving the stability of cosmetics. In addition, because of its amphiphilicity, it is well-familiar with other ingredients of cosmetics, and at the same time, it improves the familiarity between ingredients, and remarkably improves the stability of the formulation system.

  The content of the 2-ethyl-1,3-hexanediol of the present invention in the cosmetic can be appropriately combined with a desired amount with respect to the blending of 1,3-butylene glycol. Considering the effect of improving odor degradation and discoloration of 1,3-butylene glycol preparations, if the content of 1,3-butylene glycol increases, more 2-ethyl-1,3-hexanediol needs to be blended However, the effect is recognized by mixing 1.0% or more with respect to 1,3-butylene glycol, and there is no upper limit to the effect.

  The proportion of the 2-ethyl-1,3-hexanediol of the present invention in the cosmetic needs to be the minimum amount calculated by the blending ratio described above with respect to the content of 1,3-butylene glycol in the cosmetic. The upper limit of blending is not particularly limited as long as a cosmetic can be formed. However, if it is incorporated excessively, problems such as stickiness occur, and therefore, blending of 5.0% by mass or less is preferable.

In addition to 1,3-butylene glycol and 2-ethyl-1,3-hexanediol, the cosmetic of the present invention is a component that is usually blended in cosmetics, such as powder components, liquid fats, solid fats, waxes, hydrocarbons. Oil, higher fatty acid, higher alcohol, ester oil, silicone oil, film agent, UV absorber, sequestering agent, lower alcohol, polyhydric alcohol, water-soluble polymer, sugar, amino acid, organic amine, polymer emulsion, pH Preparation agents, skin nutrients, vitamins, antioxidants, antioxidant aids, bactericidal preservatives, other drugs, pigments, fragrances, water, and the like can be blended.

Further, the form of the cosmetic of the present invention is not particularly limited, and for example, it is liquid, gel, paste, emulsion, cream or the like. In addition, the cosmetics of the present invention specifically include basic cosmetics such as emulsions, creams, lotions, sunscreens, gels, serums, packs, masks, foundations, white powders / dusts, lipsticks, blushers, makeup bases, Makeup cosmetics such as eyeliner, mascara, eye shadow, eyebrow, nail enamel, enamel remover, nail treatment, lotion, milky lotion, cream, fragrance, sun care (sunscreen, sun oil, after sun lotion), decolorization and hair removal Although it is body cosmetics, such as an agent, it is not limited to these.

Next, the present invention will be described more specifically with reference to examples. The present invention is not limited thereby. A compounding quantity is the mass%.
[Usage test and stability test]

A lotion having the formulation shown in Table 1 was prepared according to the following production method, and a use test and a stability test were conducted.
<Manufacturing method for lotion>
Dissolve citric acid, trisodium citrate, and trisodium edetate in purified water (aqueous phase). 2-ethyl-1,3-hexanediol (excluding the comparative example) is dissolved in an alcohol, ethanol, glycerin, 1,3-butylene glycol, and POE (60) hydrogenated castor oil. Mix the aqueous and alcohol phases.

<Use test method>
Twenty female panels were used twice a day for two weeks to report satisfaction with their feeling of use. The evaluation of the feeling of use was performed by the following four grades, and the average of the grades was calculated and classified into the following criteria.
4: There is no stickiness and the feeling of use is satisfactory 3: Slightly sticky, but the feeling of use is almost satisfactory 2: Stickiness, the feeling of use is unsatisfactory 1: The sticky feeling is marked, and the feeling of use is extremely unsatisfactory

A: Evaluation point average 3.5 or more B: Evaluation point average 3.0 to less than 3.5 C: Evaluation point average 2.0 to less than 3.0 D: Evaluation point average less than 2.0

<Stability test>
1. Temperature Stability Test Samples of Examples and Comparative Examples (50 g) were placed in a 50 mL screw tube and stored in a thermostatic bath at 0 ° C. and 50 ° C. for 1 month.

<Appearance evaluation method>
The appearance stability of the sample subjected to the temperature acceleration test was evaluated according to the following criteria.
A: Good formulation stability and no change in appearance such as discoloration.
○: The formulation stability is almost good, and some changes are observed, but there is no change in appearance such as a large discoloration that causes a problem.
(Triangle | delta): There exists some problem in formulation stability, and some external appearance changes, such as discoloration, are recognized.
X: There is a problem in the preparation stability, and appearance changes such as discoloration are observed.
In addition, ◎ and ○ are acceptable as preparations.

<Odor evaluation method>
Odor evaluation was performed on the sample subjected to the temperature acceleration test. Evaluation was performed with the following evaluation points by five panelists who evaluated the odor of the fragrance, and the average of the evaluation points was calculated and evaluated according to the following criteria.
4: No odor change, no problem 3: Slight odor change, but no major problem 2: Odor change, some problem 1: Clear odor change, problem

A: Evaluation point average of 3.5 or more B: Evaluation point average of 3.0 to less than 3.5 C: Evaluation point average of 2.0 to less than 3.0 D: Evaluation point average of less than 2.0 And B are acceptable. Although there is room for improvement by perfume C, C and below are rejected.

2. Light Stability Test 50 g of the samples of Examples and Comparative Examples were placed in a 50 mL screw tube, and a sun exposure 50 MJ irradiation test was performed. About the sample which gave the irradiation test, stability was evaluated on the same evaluation criteria as a temperature stability test. The results of the use test and the stability test are shown in Table 1.

In the temperature stability test and the light stability test, the appearance change and the odor change were clearly observed in Comparative Example 1, and the appearance change and a slight odor change were also recognized in Comparative Example 2. On the other hand, in Examples 1 and 2, problems such as odor degradation and discoloration were not recognized. This is an effect of the present invention. Moreover, about the usability, both the examples and comparative examples were good and satisfactory, and no decline in usability due to the incorporation of 2-ethyl-1,3-hexanediol was observed.

  Next, an emulsion having the formulation shown in Table 2 was prepared according to the following production method, and a use test and a stability test were performed in the same manner as described above.

<Production method of emulsion>
2-ethyl-1,3-hexanediol (excluding comparative examples), 1,3-butylene glycol, polyethylene glycol 1500, trisodium edetate, triethanolamine, and purified water are added and heated to 70 ° C. (aqueous phase) ). Stearic acid, cetyl alcohol, petrolatum, and squalane are dissolved, and sorbitan monooleate is added thereto and adjusted to 70 ° C. (oil phase). The oil phase is added to the aqueous phase, pre-emulsified, and uniformly emulsified with a homomixer, and then cooled.

Table 2 shows the results of these use tests and stability tests.

In the temperature stability test and the light stability test, the appearance change and the odor change were clearly observed in Comparative Example 3, and the appearance change and a slight odor change were also recognized in Comparative Example 4. On the other hand, in Examples 3 and 4, problems such as odor degradation and discoloration were not recognized. This is an effect of the present invention. Moreover, about the usability, both the examples and comparative examples were good and satisfactory, and no decline in usability due to the incorporation of 2-ethyl-1,3-hexanediol was observed.

Hereinafter, various cosmetics of the present invention will be exemplified, but none of the examples produced phenomena such as odor deterioration or discoloration of the preparation, excellent preparation stability, and good usability. In addition, the manufacturing method of the cosmetics in these Examples followed the method generally used as the manufacturing method in each.

Toner lotion mass%
Ethanol 5.0
1,3-butylene glycol 6.0
Glycerin 5.0
Oleyl alcohol 0.1
2-Ethyl-1,3-hexanediol 1.5
POE (20) sorbitan monolaurate 0.5
POE (15) lauryl ether 0.5
2-phenoxyethanol appropriate amount methylparaben appropriate amount perfume appropriate amount purified water remainder

Toner lotion mass%
Sorbit 4.0
1,3-butylene glycol 8.0
Glycerin 2.0
POE (20) oleyl alcohol ether 0.5
Methylcellulose 0.2
Quince Seed 0.1
2-Ethyl-1,3-hexanediol 2.0
1,2-pentanediol 0.1
2-phenoxyethanol appropriate amount methylparaben appropriate amount perfume appropriate amount purified water remainder

Toner lotion mass%
(Alcohol phase)
Ethanol 5.0
Oleyl alcohol 0.2
2-Ethyl-1.3-hexanediol 1.0
POE (20) sorbitan monolaurate 0.5
POE (15) lauryl ether 0.5
4,5-Dimorpholino-3-hydroxypyridazine 0.1
2-phenoxyethanol appropriate amount methylparaben appropriate amount perfume appropriate amount (water phase)
1,3-butylene glycol 5.0
1,2-pentanediol 1.0
Glycerin 5.0
Purified water residue

Toner lotion mass%
(Alcohol phase)
Ethanol 5.0
POE (20) oleyl ether 0.5
2-Ethyl-1.3-hexanediol 0.1
2-phenoxyethanol appropriate amount methylparaben appropriate amount perfume appropriate amount (water phase)
1,3-butylene glycol 1.0
Dipropylene glycol 6.0
Sorbit 4.0
PEG 1500 5.0
Methylcellulose 0.2
Quince Seed 0.1
Purified water residue

Toner lotion mass%
Ethanol 10.0
2-Ethyl-1.3-hexanediol 0.01
Glycerin 2.0
1,3-butylene glycol 0.5
Dipropylene glycol 1.0
Isostearic acid 0.1
Poly (oxyethylene oxypropylene) 1.0
・ Methylpolysiloxane copolymer lauryldimethylaminoacetic acid betaine 0.1
Citric acid 0.02
Sodium citrate 0.08
Sodium hexametaphosphate 0.01
Hipotaurine 0.1
Chamomile extract 0.1
Lavender oil 0.001
Phenoxyethanol appropriate amount active hydrogen water 1.0
Purified water residue

Toner lotion mass%
Ethyl alcohol 5.0
Glycerin 1.0
2-Ethyl-1.3-hexanediol 5.0
1,3-butylene glycol 5.0
Polyoxyethylene polyoxypropylene 0.2
Decyl tetradecyl ether sodium hexametaphosphate 0.03
Trimethylglycine 1.0
Sodium polyaspartate 0.1
α-Tocopherol 0.1
2-L-ascorbic acid phosphate diester potassium thiotaurine 0.1
Green tea extract 0.1
Western mint extract 0.1
Iris root extract 0.1
HEDTA3 sodium 0.1
Carboxyvinyl polymer 0.05
Potassium hydroxide 0.02
Phenoxyethanol Appropriate amount Purified water Residual perfume Appropriate amount

Toner lotion mass%
Glycerin 2.0
1,3-butylene glycol 0.01
2-Ethyl-1.3-hexanediol 0.01
Erythritol 1.0
Polyoxyethylene methyl glucoside 1.0
Polyoxyethylene hydrogenated castor oil 0.5
Citric acid 0.02
Sodium citrate 0.08
Phenoxyethanol appropriate amount N-coconut oil fatty acid acyl L-arginine ethyl 0.1
・ DL-pyrrolidone carboxylic acid purified water

Toner lotion mass%
Ethanol 5.0
Glycerin 0.5
Dipropylene glycol 2.0
2-Ethyl-1.3-hexanediol 3.0
1,3-butylene glycol 6.0
Rosemary oil 0.01
Sage oil 0.01
Citric acid 0.02
Sodium citrate 0.08
Sodium hexametaphosphate 0.03
Hydroxypropyl-β-cyclodextrin 0.1
Mukuroji extract 0.1
Ages Extract 0.1
Lily extract 0.1
Oat extract 0.1
Togenashi extract 0.1
Kiso Extract 0.1
Lavender oil 0.1
Tounin extract 0.1
Sodium alginate 0.001
Purified water residue

Milk mass%
Glycerin 3.0
2-Ethyl-1,3-hexanediol 1.5
Cetanol 1.5
Stearyl alcohol 1.8
Dimethylpolysiloxane (20cs) 1.5
Squalane 2.0
Vaseline 2.0
Isopropyl myristate 2.5
Glyceryl monostearate 1.8
Polyoxyethylene (POE = 5) glyceryl monostearate 1.8
Polyoxyethylene (POE = 20) cetyl ether 1.5
Carboxyvinyl polymer 0.25
Potassium hydroxide 0.05
L-Arginine 0.2
Dipropylene glycol 5.0
1,3-butylene glycol 3.0
1,2-pentanediol 0.1
Edetate trisodium 0.2
2-phenoxyethanol Parabens appropriately Purified water Remaining amount

Milk mass%
Decamethylcyclopentasiloxane 3.0
Methylphenylpolysiloxane 3.0
Behenyl alcohol 1.0
1,3-butylene glycol 10.0
2-Ethyl-1,3-hexanediol 3.0
Polyoxyethylene glyceryl isostearate 1.5
Polyoxyethylene glycerol monostearate 1.0
Dipotassium glycyrrhizinate 0.05
Trimethylglycine 1.0
L-ascorbic acid 2-glucoside 2.0
Edetate trisodium 0.1
2-Ethylhexyl paramethoxycinnamate 7.0
Xanthan gum 0.1
Carboxyvinyl polymer 0.3
Phenoxyethanol Appropriate amount Purified water Residual perfume Appropriate amount

Milk mass%
Cetanol 1.0
Glycerin 5.0
2-Ethyl-1,3-hexanediol 0.1
1,3-butylene glycol 1.0
Polyethylene glycol 20000 2.0
Tetra (2-ethylhexanoic acid / paramethoxycinnamic acid) 3.0
Pentaerislit di-2-ethylhexyl succinate 3.0
Potassium hydroxide 0.1
Edetate trisodium 0.1
Methyl bis (trimethylsiloxy) trimethoxycinnamate 2.0
Silylisopentyl 4-t-butyl-4′-methoxydibenzoylmethane 2.0
2-Ethylhexyl paramethoxycinnamate 2.0
Diparamethoxycinnamate mono-2-ethylhexanoate glyceryl 2.0
Carboxyvinyl polymer 0.15
Acrylic acid / alkyl methacrylate copolymer
0.1
(Pemulen TR-1)
Paraben Appropriate amount Phenoxyethanol Appropriate amount Purified water Residual fragrance Appropriate amount

Milk mass%
Decamethylcyclopentasiloxane 15.0
Trimethylsiloxysilicate 5.0
Polyoxyethylene / methylpolysiloxane copolymer 5.0
Glycerin 5.0
2-Ethyl-1,3-hexanediol 0.01
1,3-butylene glycol 0.1
Maltitol solution 2.0
Macadamia nut oil 2.0
Squalane 2.0
Cholesteryl hydroxystearate 0.5
Cetyl 2-ethylhexanoate 2.0
Distearyldimethylammonium chloride 0.2
L-ascorbic acid sulfate disodium 0.1
α-Tocopherol 0.1
2-L-ascorbic acid phosphate diester potassium acetate tocopherol 0.05
Fish collagen 0.4
Sodium chondroitin sulfate 0.01
Sodium hyaluronate 0.1
Edetate trisodium 0.05
Diparamethoxycinnamic acid mono-2-ethylhexanoate glyceryl 0.05
Aluminum magnesium silicate 0.3
Paraben Appropriate amount of purified water Residual

Gel mass%
2-Ethyl-1,3-hexanediol 2.0
Glycerin 2.0
1,3-butylene glycol 5.0
Potassium hydroxide 0.1
Fish collagen 20.0
Edetic acid-3Na 0.05
Carboxyvinyl polymer 0.25
P-Hydroxybenzoate appropriate amount purified water remaining

Essence mass%
95% ethanol 2.0
1,3-butylene glycol 2.0
POE (20) Octyldodecanol 1.0
Pantothenyl ethyl ether 0.1
2-Ethyl-1,3-hexanediol 0.1
Potassium hydroxide 0.1
Glycerin 5.0
Dipropylene glycol 10.0
Sodium bisulfite 0.03
Carboxyvinyl polymer 0.2
Preservative Appropriate amount of purified water

Pack mass%
Ethanol 10.0
1,3-butylene glycol 0.01
2-Ethyl-1,3-hexanediol 0.01
Polyethylene glycol 4000 2.0
Olive oil 1.0
Macadamia nut oil 1.0
Phytosteryl hydroxystearate 0.05
Lactic acid 0.05
Sodium lactate 0.1
L-ascorbic acid sulfate disodium 0.1
α-Tocopherol 0.1
2-L-ascorbic acid phosphate diester potassium vitamin E acetate 0.1
Fish collagen 0.1
Chondroitin thorium sulfate 0.1
Sodium carboxymethylcellulose 0.2
Polyvinyl alcohol 12.0
P-Hydroxybenzoic acid ester
Appropriate amount

Cream mass%
2-Ethyl-1,3-hexanediol 1.0
Stearyl alcohol 3.5
Stearic acid 2.0
Squalane 10.5
Isopropyl myristate 7.5
Polyoxyethylene (POE = 25) cetyl alcohol ether 3.0
Glycerol monostearate 2.0
Tocopherol acetate 0.2
Monoammonium glycyrrhizinate 0.05
Glycerin 3.0
Dipropylene glycol 5.0
1,2-pentanediol 0.1
1,3-butylene glycol 5.0
2-phenoxyethanol 0.1
Edetate trisodium 0.01
Preservative Suitable amount Purified water Remaining

Cream mass%
Liquid paraffin 10.0
Dimethylpolysiloxane 2.0
Glycerin 10.0
1,3-butylene glycol 1.0
Erythritol 1.0
2-Ethyl-1,3-hexanediol 1.0
Polyethylene glycol 1500 5.0
Squalane 15.0
Tetra-2-ethylhexanoic acid pentaerythrit 5.0
Potassium hydroxide 0.1
Sodium hexametaphosphate 0.05
Tocopherol acetate 0.05
Preservative appropriate amount hydroxypropyl methylcellulose 0.3
Polyvinyl alcohol 0.1
Carboxyvinyl polymer 0.2
Acrylic acid / alkyl methacrylate copolymer (Pemulene TR-2) 0.1

Cream mass%
Vaseline 2.0
Dimethylpolysiloxane (6mPa.s) 2.0
Ethanol 5.0
Behenyl alcohol 0.5
Batyl alcohol 0.2
Glycerin 7.0
1,3-butylene glycol 10.0
Polyethylene glycol 20000 0.5
Jojoba oil 3.0
Squalane 2.0
Phytosteryl hydroxystearate 0.5
Tetra-2-ethylhexanoic acid pentaerythrit 1.0
Polyoxyethylene (60) hydrogenated castor oil 1.0
Potassium hydroxide 0.1
Sodium pyrosulfite 0.01
Sodium hexametaphosphate 0.05
Stearyl glycyrrhetinate 0.1
Pantothenyl ethyl ether 0.1
Arbutin 7.0
Tranexamic acid 1.0
Tocopherol acetate 0.1
Sodium hyaluronate 0.05
Edetate trisodium 0.05
2-Ethyl-1,3-hexanediol 5.0
4-t-butyl-4'-methoxydibenzoylmethane 0.1
Diparamethoxycinnamic acid mono-2-ethylhexanoic acid 0.1
Glyceryl
Preservative Appropriate amount Yellow iron oxide Appropriate amount Xanthan gum 0.1
Carboxyvinyl polymer 0.2
Purified water residue

Cream mass%
2-Ethyl-1,3-hexanediol 1.0
Methylphenylpolysiloxane 5.0
Stearyl alcohol 2.0
Glycerin 5.0
Dipropylene glycol 5.0
Sorbit liquid (70%) 5.0
Stearic acid 1.5
Palmitic acid 1.0
Tetra-2-ethylhexanoic acid pentaerythrit 4.0
Self-emulsifying glyceryl monostearate 1.0
Potassium hydroxide 0.15
Octyl methoxycinnamate 6.0
Vaseline 2.0
Tranexamic acid 2.0
1,3-butylene glycol 4.0
Squalane 3.0
Sodium citrate 0.1
Acetylated sodium hyaluronate 0.1
Xanthan gum 0.2
Bentonite 1.0
Paraben Appropriate amount Purified water Residual perfume Appropriate amount

Jelly pack mass%
Polyoxyethylene oleyl alcohol ether 0.5
2-Ethyl-1,3-hexanediol 1.0
Monoammonium glycyrrhizinate 0.05
Carboxymethylcellulose 5.0
Ethanol 12.0
Polyvinyl alcohol 12.0
1,3-butylene glycol 5.0
1,2-pentanediol 0.3
Preservative Appropriate amount Trisodium edetate 0.01
Purified water remaining

Solid powder foundation mass%
Microcrystalline wax 1.0
Dimethylpolysiloxane 15.0
Decamethylcyclopentasiloxane 2.0
1,3-butylene glycol 3.0
2-Ethyl-1,3-hexanediol 0.3
Candelilla Row 3.0
Isostearic acid 1.0
Ethylene glycol fatty acid ester 0.1
Lanolin fatty acid octyldodecyl 0.5
2-Alkyl-N-carboxymethyl 4.0
-N-hydroxyethylimidazolinium betaine titanium oxide 7.5
Barium sulfate 5.0
Titanium oxide 7.0
Talc 3.0
Silicic anhydride 4.0
Cross-linked silicone powder (Trefil E-506) 0.1
Sodium metaphosphate 0.1
Hydroxypropyl-β-cyclodextrin 0.1
DL-α-tocopherol acetate 0.1
Hamamelis extract 0.1
Peonies extract 0.1
Sodium chondroitin sulfate 0.1
Sodium hyaluronate 0.1
Paraoxybenzoic acid appropriate amount Bengala appropriate amount yellow iron oxide appropriate amount black iron oxide appropriate amount xanthan gum 0.2
Sodium carboxymethylcellulose 0.2
Merirot Extract 2.0
Purified water residue

Water-in-oil emulsification foundation Mass%
Dimethylpolysiloxane 3.0
Decamethylcyclopentasiloxane 15.0
Polyoxyethylene / methylpolysiloxane copolymer 3.0
Glycerin 3.0
2-Ethyl-1,3-hexanediol 0.2
1,3-butylene glycol 1.0
Palmitic acid 0.5
Distearyldimethylammonium chloride 0.2
Glycerol-modified silicone resin-coated sericite 0.5
Dextrin fatty acid coated yellow iron oxide coated mica titanium 0.5
Dextrin fatty acid coated titanium oxide 2.0
Dextrin fatty acid-coated iron oxide / titanium oxide sintered product (PK) 12.0
Dextrin fatty acid coated talc 10.0
Methyl hydrogen polysiloxane treated titanium oxide coated sericite 0.5
Boron nitride 0.5
Fine particle titanium oxide 0.5
Bengala-coated mica titanium 0.5
Phytosterol 0.1
Sodium L-glutamate 0.1
Ascorbyl dipalmitate 0.1
DL-α-tocopherol acetate 0.1
Acetylated sodium hyaluronate 0.1
Paraoxybenzoic acid ester Appropriate amount Phenoxyethanol Appropriate amount Bengala coated mica titanium 0.5
Dextrin fatty acid coated yellow iron oxide 2.0
Dextrin fatty acid coated black iron oxide 0.2
Spherical nylon powder 1.0
Purified water Residual fragrance

Eyeliner mass%
1,3-butylene glycol 7.0
2-Ethyl-1,3-hexanediol 0.7
Polyethylene glycol 300 3.0
Polyoxyethylene (30) behenyl ether 2.0
P-Hydroxybenzoate appropriate amount sodium dehydroacetate appropriate amount carbon black 7.0
Alkyl acrylate copolymer emulsion 6.0
Purified water Remaining fragrance Appropriate amount Black iron oxide Appropriate amount

Eye shadow-mass%
Decamethylcyclopentasiloxane 16.0
Methylphenylpolysiloxane 1.0
Batyl alcohol 1.0
1,3-butylene glycol 0.1
2-Ethyl-1,3-hexanediol 0.1
Macadamia nut oil 0.1
Stearic acid 1.0
Palmitic acid 1.0
Self-emulsifying glyceryl monostearate 1.0
Self-emulsifying propylene glycol stearate 1.0
Bengala-coated mica titanium (pearl agent) 13
Synthetic phlogopite 0.1
Silica anhydride 2.0
Triethanolamine 1.0
DL-α-tocopherol acetate 0.1
Paraoxybenzoic acid ester Appropriate amount Phenoxyethanol Appropriate amount Xanthan gum 0.1
Bentonite 1.0
Sodium carboxymethylcellulose 0.1
Trimethylsiloxysilicate 5.0
Purified water Residual stearyl alcohol 0.5
Behenyl alcohol 0.5

Lipstick mass%
Liquid paraffin 20.0
Polyoxyethylene / methylpolysiloxane copolymer 0.5
Methylphenyl polysiloxane 0.5
Glycerin 1.0
1,3-butylene glycol 3.0
2-Ethyl-1,3-hexanediol 1.5
Diisostearyl phosphate, residual pigment 1.0
Pantothenyl ethyl ether 0.01
Arginine hydrochloride 0.01
Sodium hyaluronate 0.01
Dye Suitable amount Synthetic sodium silicate / magnesium 1.5
Dextrin palmitate 2.5
Heavy liquid isoparaffin 20.0
Purified water 1.0

Mascara mass%
Methyl polysiloxane emulsion appropriate amount ethanol 5.0
Isopropanol 3.0
Glycerin 3.0
1,3-butylene glycol 0.01
2-Ethyl-1,3-hexanediol 0.01
Silicic anhydride 1.0
Bengala coated mica titanium (pearl agent) 9.0
Strong ammonia water 0.1
Sodium metaphosphate 0.1
Hydrolyzed wheat protein 0.1
P-Hydroxybenzoate appropriate amount sodium dehydroacetate appropriate amount black iron oxide (pigment) 1.0
Xanthan gum 1.0
Aluminum magnesium silicate 2.0
Sodium carboxymethylcellulose 1.0
Alkyl acrylate copolymer emulsion 10.0
Purified water remaining

Claims (4)

Cosmetics containing 1,3-butylene glycol and 2-ethyl-1,3-hexanediol. The cosmetic according to claim 1, wherein a proportion of 1,3-butylene glycol in the cosmetic is 0.01 to 10.0% by mass. The cosmetic according to claim 1, wherein the proportion of 2-ethyl-1,3-hexanediol in the cosmetic is 0.01 to 5.0 mass%. The cosmetic according to claim 1, wherein the proportion of 2-ethyl-1,3-hexanediol in the cosmetic is 1.0% or more with respect to the proportion of 1,3-butylene glycol in the cosmetic. Cosmetics characterized by being.