JP2006225347A - Skin care composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a skin care composition which suppresses dry skin due to powder formulation and has good usability without stickiness and smear and good stability of the formulation. <P>SOLUTION: The skin care composition comprises the powder blended with 2-ethyl-1, 3-hexane diol. The powder is an inorganic pigment. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

The present invention relates to a composition for external use of skin such as cosmetics, and more particularly to a composition for external use of skin such as cosmetics, which prevents the skin from becoming bulky based on the formulation of powder, has good usability, and has excellent formulation stability. .

Cosmetics containing more than a certain amount of powder, such as makeup cosmetics, in the composition for external use on skin may dehydrate the skin when applied to the skin and may physically damage the skin, which may cause skin irritation. Are known. Conventionally, in order to prevent this roughness, a moisturizing agent is often added from the viewpoint of protecting moisture of the skin, and an oil component is excessively added to physically improve slipping.

However, there is a problem that excessive moisturizing agent causes stickiness of use and aggregation of powder. In addition, excessive oil content tends to give glare to the skin, and also causes skin problems such as makeup loss and acne.

An attempt to use an amide form of tranexamic acid was made for the problem of skin roughness in cosmetics containing a specific amount or more of this powder (Patent Document 1), but the compound used in the patent was at room temperature. Since it is a solid, it does not fit well with the powder, and there is a problem in the stability of the preparation over time, and therefore further improvement has been desired.
Patent No. 3398206

In view of such circumstances, the present inventors have been able to prevent the skin from becoming bulky in a composition for external use such as cosmetics in which a powder is blended in a specific amount or more. As a result of intensive studies aimed at obtaining a composition for external use with good familiarity and excellent formulation stability, it was found that the above problems can be solved by adding 2-ethyl-1,3-hexanediol together with the powder, The present invention has been completed.
That is, the present invention is a combination of powder and 2-ethyl-1,3-hexanediol, which has not been achieved with the conventional technology, and there is no skin roughness, and there is no skin glare, stickiness, and makeup loss. It is a composition for external use on skin, such as cosmetics, which has good usability, has good compatibility with other ingredients such as powder, has no powder aggregation, and has excellent formulation stability.

  Formulation of 2-ethyl-1,3-hexanediol together with powder suppresses skin roughness, prevents skin glare, stickiness, makeup loss, good usability, no powder aggregation, and formulation It is possible to provide a composition for external use on skin such as cosmetics, which is excellent in stability.

The external composition for skin according to the present invention is a cosmetic.
The composition for external use of the skin of the present invention is a makeup cosmetic.
The external composition for skin of the present invention is a basic cosmetic.
The external composition for skin of the present invention is characterized in that the content of powder in the external composition for skin is 1.0% by mass or more.
The external composition for skin of the present invention is characterized in that the content of 2-ethyl-1,3-hexanediol in the external composition for skin is 0.001 to 5.0% by mass.

Examples of the powder used in the present invention include mica, sericite, talc, kaolin, calcium carbonate, magnesium carbonate, anhydrous silicic acid, aluminum oxide, barium sulfate, bengara, yellow iron oxide, black iron oxide, chromium oxide, ultramarine, bitumen, Carbon black, titanium dioxide, zinc oxide, titanium mica, fish scale foil, bismuth oxychloride, boron nitride, photochromic pigment, synthetic fluorophlogopite, composite fine particle powder and other inorganic pigments, polyethylene powder, polymethyl methacrylate powder, polyethylene Examples thereof include polymer powders such as terephthalate / polymethyl methacrylate laminated powder and nylon powder.

The content of the powder used in the present invention in the external composition for skin may be appropriately determined according to the purpose of blending, and is not particularly limited, but the effect of the present invention is remarkable when the content is 1.0% by mass or more. .

  Although 2-ethyl-1,3-hexanediol used in the present invention is a known substance, it suppresses the skin roughness while satisfying the stability of the preparation, and does not cause glare or stickiness of the skin or makeup loss. The ability to provide a composition for external use on the skin is novel.

The 2-ethyl-1,3-hexanediol of the present invention can be produced by a known synthesis method. It is also commercially available from Tokyo Chemical Industry Co., Ltd. and can be easily obtained.

The 2-ethyl-1,3-hexanediol of the present invention has stereoisomerism due to its structure, but in the present invention, it may be a single compound or a mixture thereof, and the mixing ratio is not questioned. Absent. Further, although optical isomerism occurs, it may be optically active, racemic, or a mixture thereof, or may be a single or a mixture of their stereoisomerism, and their mixing ratio is not limited.

The 2-ethyl-1,3-hexanediol of the present invention is a transparent liquid substance having a high boiling point, so that crystals do not precipitate after molding with a powder, and the compounding components such as powder, oil and moisture are not affected. Familiarity is improved, and familiarity between components is improved. There is no problem of aggregation and discoloration over time, and the stability of the preparation is improved. Moreover, it does not deteriorate or volatilize over time, and the effect does not decrease.

The content of the 2-ethyl-1,3-hexanediol of the present invention in the composition for external use in skin is 0.001 to 5.0% by mass in consideration of improvement of skin roughness due to powder and stability of the preparation, Preferably it is 0.01-2.0 mass%. If the amount is too small, the improvement effect cannot be ensured, and if it is added excessively, problems such as stickiness occur.

In addition to the above powder and 2-ethyl-1,3-hexanediol, the external composition for skin of the present invention is a component that is usually blended in an external composition for skin such as cosmetics, quasi-drugs, and pharmaceuticals, such as liquids. Fats and oils, solid fats and oils, waxes, hydrocarbon oils, higher fatty acids, higher alcohols, ester oils, silicone oils, water-soluble polymers, film agents, UV absorbers, sequestering agents, lower alcohols, polyhydric alcohols, sugars, amino acids Organic amines, polymer emulsions, pH adjusters, skin nutrients, vitamins, antioxidants, antioxidant aids, bactericides and preservatives, other drugs, pigments, fragrances, water and the like can be blended.

Further, the form of the composition for external use of the skin of the present invention is not particularly limited, but for example, liquid, gel, paste, emulsion, cream, solid, powder, bilayer, sheet, stick, pencil Etc. Specifically, the external composition for skin of the present invention specifically includes basic cosmetics such as emulsions, creams, lotions, sunscreens, gels, essences, packs, masks, foundations, white powders / dusts, lipsticks, blushers, makeup Makeup cosmetics such as foundation, eyeliner, mascara, eye shadow, eyebrow, nail enamel, enamel remover, nail treatment, body cosmetics such as sunscreen, after sun care, hand care, deodorant, hair removal, etc. It is not limited.

  EXAMPLES Next, although an Example is given and this invention is demonstrated further in detail, the technical scope of this invention is not limited at all by these Examples. The unit of the blending amount is all mass%.

[Use test 1]
An emulsification foundation having the formulation shown in Table 1 was prepared and used. Further, a temperature acceleration test was performed to evaluate the stability of the preparation.

<Emulsification foundation manufacturing method>
2-ethyl-1,3-hexanediol, stearyl alcohol, stearic acid, glyceryl monostearate, POE (20) cetyl alcohol ether, liquid lanolin, liquid paraffin, methyl paraben are heated and dissolved with stirring, talc, titanium dioxide, bengara, Disperse kaolin, sericite, mica and iron oxide. This was added to an aqueous phase in which 1.3-butylene glycol, triethanolamine, Nn-propyl-trans-4-aminomethylcyclohexanecarbonamide hydrochloride and purified water were dissolved by heating and stirring, and the emulsion was stirred and cooled to obtain a foundation. Got.

<Use test method>
Twenty female panels were allowed to use it for 2 weeks and reported satisfaction with the feeling of use. The evaluation of the feeling of use was performed by the following four grades, and the average of the grades was calculated and classified into the following criteria.
4: There is no bulkiness and the feeling of use is satisfactory 3: Slightly bulky, but the feeling of use is almost satisfied 2: The texture is bulky, the feeling of use is unsatisfactory 1: The texture is extremely heavy, and the feeling of use is extremely unsatisfactory

A: Evaluation point average 3.5 or more B: Evaluation point average 3.0 to less than 3.5 C: Evaluation point average 2.0 to less than 3.0 D: Evaluation point average less than 2.0

<Temperature acceleration test>
The sample of Example and the comparative example 50g was preserve | saved for one month in a 0 degreeC and a 50 degreeC thermostat.
<Stability evaluation method>
The stability of the sample subjected to the acceleration test was evaluated according to the following criteria.
A: Good formulation stability, no change in appearance, no phenomenon such as discoloration, aggregation or cracking.
○: The formulation stability is almost good and some changes are observed, but there is no significant change in appearance that causes problems.
(Triangle | delta): There exists some problems in formulation stability and phenomena, such as one part aggregation and discoloration, are recognized.
X: There is a problem in the preparation stability, and appearance change, discoloration, aggregation, cracking, etc. are observed. In addition, ◎ and ○ are acceptable as preparations.

In Example 1, the satisfaction of usability is high and the stability is also good. This is an effect of the present invention. In Comparative Example 1, the stability is good, but the satisfaction of usability is low. In Comparative Example 2 containing a tranexamic acid amide described in Japanese Patent No. 3398206, the usability was high, but crystals were precipitated, and there was a problem in stability.

[Use test 2]
A powdery foundation having the formulation shown in Table 2 was prepared and used. Further, a temperature acceleration test was performed to evaluate the stability of the preparation.

<Production method of powdery foundation>
Mix talc, mica, kaolin, titanium dioxide, mica titanium, zinc stearate, bengara, yellow iron oxide, black iron oxide, and nylon powder in a blender. To this, 2-ethyl-1,3-hexanediol, squalane, lanolin acetate, octyldodecyl myristate, neopentyl glycol diisooctanoate, sorbitan monooleate, methylparaben, Nn-propyl-trans-4-aminomethyl Add cyclohexanecarbonamide hydrochloride and mix uniformly. This was pulverized with a pulverizer, passed through a sieve, and compression molded into an intermediate dish.

<Use test method>
The same as the usage test 1.
<Temperature acceleration test>
The same as the usage test 1.

In Example 2, the satisfaction of usability is high and the stability is also good. This is an effect of the present invention. In Comparative Example 3, the stability is good, but the satisfaction of usability is low. Moreover, although the satisfaction of usability was high in Comparative Example 4, there was a problem in stability because crystals were precipitated.

Although the utilization method of this invention is explained in full detail below, this invention is not limited to a following example, It can be used by another prescription. In addition, each Example may be what was manufactured by the conventional method in manufacture of each product, and showed only the compounding quantity. In any case, a good effect of the present invention was obtained.

Water-in-oil emulsification foundation Mass%
Purified water Residual propylene glycol 4.0
Glycerin 2.0
2-Ethyl-1,3-hexanediol 5.0
Sodium metaphosphate appropriate amount of bentonite 2.0
Potassium hydroxide 0.4
Palmitic acid 1.2
Isostearic acid 1.0
Titanium oxide 10.0
Iron oxide Appropriate amount Silica-coated zinc oxide 5.0
Barium sulfate 3.0
Talc 4.0
Mica 2.0
Mica titanium 1.0
Glycerol monostearate 1.0
Polyisoethylene stearic acid polyoxyethylene sorbitan 0.5
Cetyl alcohol 0.4
Batyl alcohol 0.5
Liquid paraffin 5.0
Dimethylpolysiloxane 5.0
2-ethylhexyl paramethoxycinnamate 3.0
Vaseline 1.0
Perfume

Water-in-oil type emulsification foundation Mass% Spherical nylon 10.0
Porous silica powder 8.0
Mica titanium 2.0
Silicone-treated sericite 2.0
Silicone-treated mica 12.0
Silicone-treated titanium dioxide 5.0
Silicone-treated iron oxide 2.0
Purified water Residual 2-ethyl-1,3-hexanediol 1.0
Decamethylcyclopentasiloxane 18.0
Dimethylpolysiloxane 5.0
Squalane 1.0
Polyoxyethylene-modified dimethylpolysiloxane 2.0
Phenoxyethanol 0.1
Methylparaben 0.1
Perfume

Water-in-oil emulsified solid foundation Mass%
Microcrystalline wax 5.0
Dimethylpolysiloxane 10.0
Decamethylcyclopentasiloxane 30.0
Polyoxyethylene / methylpolysiloxane copolymer 2.0
Dipropylene glycol 3.0
Palmitic acid 0.5
Sorbitan sesquiisostearate 1.0
2-Ethyl-1,3-hexanediol 3.0
Alkyl-modified silicone resin coated yellow iron oxide 3.0
Alkyl modified silicone resin coated bengara 1.0
Alkyl-modified silicone resin-coated black iron oxide Appropriate amount of alkyl-modified silicone resin-coated silicic acid 2.0
Alkyl-modified silicone resin coated titanium oxide 15.0
Alkyl-modified silicone resin coated sericite 10.0
Titanium oxide Bengala coated mica 3.0
Cross-linked silicone powder (Trefil E-506) 3.0
N-lauroyl-L-lysine 0.1
Tocopherol acetate 0.1
δ-tocopherol 0.1
Methylparaben 0.1
Merirot Extract 2.0
Purified water residue

Oil-in-water emulsified solid foundation Mass%
Microcrystalline wax 1.0
Dimethylpolysiloxane 15.0
Decamethylcyclopentasiloxane 2.0
1,3-butylene glycol 6.0
2-Ethyl-1,3-hexanediol 0.5
Candelilla Row 3.0
Isostearic acid 1.0
Ethylene glycol fatty acid ester 0.1
Lanolin fatty acid octyldodecyl 0.5
2-Alkyl-N-carboxymethyl 4.0
-N-hydroxyethylimidazolinium betaine titanium oxide 7.5
Barium sulfate 5.0
Titanium oxide 7.0
Talc 3.0
Silicic anhydride 4.0
Cross-linked silicone powder (Trefil E-506) 0.1
Sodium metaphosphate 0.1
Hydroxypropyl-β-cyclodextrin 0.1
DL-α-tocopherol acetate 0.1
Hamamelis extract 0.1
Peonies extract 0.1
Sodium chondroitin sulfate 0.1
Sodium hyaluronate 0.1
Methylparaben 0.1
Butylparaben 0.02
Bengala appropriate amount yellow iron oxide appropriate amount black iron oxide appropriate amount xanthan gum 0.2
Sodium carboxymethylcellulose 0.2
Merirot Extract 2.0
Purified water residue

Solid foundation (both) Mass%
Dimethylpolysiloxane 5.0
Isostearic acid 0.5
Diisostearyl malate 3.0
Tri-2-ethylhexane sanglyceryl 1.0
Sorbitan sesquiisostearate 1.0
2-Ethyl-1,3-hexanediol 0.1
Spherical PMMA-coated mica 6.0
Prism tone powder YR 1.0
Fine zinc oxide 0.5
Fine particle titanium oxide 2.0
Synthetic phlogopite 2.0
Metal soap treated talc 8.0
Spherical silica 5.0
Vitamin E acetate 0.1
δ Tocopherol 0.1
Ethylparaben 0.1
Methyl trimethoxycinnamate 1.0
Bis (trimethylsiloxy) silylisopentyl
2-methoxyhexyl paramethoxycinnamate 3.0
Spherical polyalkyl acrylate powder 6.0
Methyl hydrogen polysiloxane coated talc
Methyl hydrogen polysiloxane-coated sericite 20.0
Methyl hydrogen polysiloxane-coated titanium oxide 15.0
Methyl hydrogen polysiloxane coated pigment (colorant) 5.0

Solid foundation (both) Mass%
Ceresin 0.5
Dimethylpolysiloxane (6cs) 2.0
Methylphenylpolysiloxane 1.0
Squalane 7.0
Squalane (vegetable) 1.0
Sorbitan sesquiisostearate 1.0
2-Ethyl-1,3-hexanediol 0.5
Glycerol-modified silicone resin-coated calcined sericite 16.0
Glycerol-modified silicone resin coated sericite 7.0
Yellow iron oxide coated mica titanium 0.1
Fine particle titanium oxide 5.0
Talc 10.0
Titanium oxide coated sericite 0.1
Boron nitride 2.5
Bengala-coated mica titanium 0.1
Phytosterol 0.1
Ascorbyl dipalmitate 0.1
DL-α-tocopherol acetate 0.1
D-δ-tocopherol 0.1
Ethylparaben 0.1
2-Ethylhexyl paramethoxycinnamate 1.0
Spherical polyalkyl acrylate powder 8.0
Methyl hydrogen polysiloxane-coated mica Residual methyl hydrogen polysiloxane-coated iron oxide Titanium oxide sintered product 10.0
Methyl hydrogen polysiloxane-coated sericite 5.0
Methyl hydrogen polysiloxane-coated titanium oxide 9.0
Methyl hydrogen polysiloxane coated flaky titanium oxide 5.0
Methyl hydrogen polysiloxane coated pigment (colorant) 5.0
Perfume

Solid foundation (single use)
Dimethylpolysiloxane 2.0
Decamethylcyclopentasiloxane 30.0
Behenyl alcohol 1.0
Batyl alcohol 1.5
Liquid paraffin 3.0
Vaseline 1.0
Ceresin 1.0
Methylpolysiloxane 1.0
Methylphenyl polysiloxane (500CS) 2.0
Methylphenylpolysiloxane 3.0
Sorbitan sesquiisostearate 0.5
2-Ethyl-1,3-hexanediol 0.01
Zinc oxide
2.0
Low temperature calcined zinc oxide 1.0
Iron oxide / titanium oxide sintered product 20.0
Flaked titanium oxide 2.0
Firing Saite 10.0
Synthetic phlogopite residual boron nitride 1.0
Cross-linked silicone powder (Trefil E-506) 1.0
N-lauroyl-L-lysine 2.0
Hydroxypropyl-β-cyclodextrin 0.1
DL-α-tocopherol acetate 0.1
D-δ-tocopherol 0.1
Methylparaben 0.1
Ethylparaben 0.02
Bengala appropriate amount yellow iron oxide appropriate amount black iron oxide appropriate amount spherical alkyl polyacrylate powder 3.0

Solid foundation (wet) Mass%
α-olefin oligomer 3.0
Dimethylpolysiloxane 8.0
Methyl hydrogen polysiloxane 0.5
Sorbitan sesquiisostearate 1.0
2-ethyl-1,3-hexanediol 0.001
Calcium hydrogen phosphate 3.0
Alkyl-modified silicone resin coated yellow iron oxide 2.0
Alkyl modified silicone resin coated bengara 1.0
Alkyl-modified silicone resin-coated black iron oxide Appropriate amount of alkyl-modified silicone resin-coated titanium oxide 10.0
Alkyl modified silicone resin coated talc 5.0
Low-temperature calcined zinc oxide 5.0
Barium sulfate 2.0
Firing sericite 10.0
Phlogopite residual spherical polymethylsilsesquioxane powder 3.0
Cross-linked silicone / reticulated silicone block copolymer powder 5.0
DL-α-tocopherol acetate 0.1
D-δ-tocopherol 0.1
Thiotaurine 0.1
Methylparaben 0.1
2-methoxyhexyl paramethoxycinnamate 3.0
Silicic anhydride 1.0
Titanium oxide 2.0

Solid foundation (oil) mass%
α-olefin oligomer 10.0
Microcrystalline wax 0.5
Ceresin 5.0
Dimethylpolysiloxane 15.0
Methylphenyl polysiloxane 10.0
Macadamia nut oil 0.1
Carnauba 0.1
Glyceryl tri-2-ethylhexanoate 7.0
Cetyl 2-ethylhexanoate 10.0
Sorbitan sesquiisostearate 1.5
2-Ethyl-1,3-hexanediol 2.0
Mica 0.5
Aluminum stearate 1.0
Cross-linked silicone powder (Trefil E-506) 8.0
N-lauroyl-L-lysine 0.1
D-δ-tocopherol appropriate amount Bengala appropriate amount yellow iron oxide appropriate amount calcium alginate powder 1.0
Nylon powder Residual spherical silica 1.0
Titanium oxide 1.0

Stick foundation (oil-based) Mass%
Ceresin 5.0
Dimethylpolysiloxane 10.0
Decamethylcyclopentasiloxane 10.0
Dodecamethylcyclohexasiloxane 20.0
Carnauba 0.5
Candelilla wax 0.5
Tri-2-ethylhexane sanglyceryl residual sesquiisostearate sorbitan 1.5
2-Ethyl-1,3-hexanediol 5.0
Titanium oxide 8.0
Kaolin 10.0
Mica 12.0
Mica titanium / polyalkyl acrylate composite powder 1.0
Polyalkyl acrylate coated mica titanium 1.0
Titanium oxide MT-014TV 5.0
Black iron oxide coated mica titanium 0.5
Tocopherol acetate 0.1
δ-tocopherol 0.1
Bengala appropriate amount of yellow iron oxide
Appropriate amount of zinc oxide treated ultramarine
Appropriate amount of black iron oxide
Proper amount of fragrance
Appropriate amount

Stick foundation (emulsification type)
Ceresin 5.0
Decamethylcyclopentasiloxane 15.0
Polyoxyethylene / methylpolysiloxane copolymer 2.0
Dodecamethylcyclohexasiloxane 20.0
Dipropylene glycol 5.0
2-Ethyl-1,3-hexanediol 2.0
Hydrogenated jojoba oil 3.0
Palmitic acid 0.5
Sorbitan sesquiisostearate 2.0
Distearyldimethylammonium chloride 0.2
Alkyl-modified silicone resin coated yellow iron oxide 2.0
Alkyl modified silicone resin coated bengara 1.0
Alkyl modified silicone resin coated black iron oxide 0.1
Alkyl-modified silicone resin-coated titanium oxide 8.0
Surface-treated titanium oxide 5.0
Bengala-coated mica titanium Appropriate amount Silica-coated mica 0.1
N-lauroyl-L-lysine 0.1
Tocopherol acetate 0.1
δ-tocopherol 0.1
Oat extract 0.1
P-Hydroxybenzoate appropriate amount Merirot extract 2.0
Polyalkyl acrylate 15.0
Purified water residue

Water-in-oil cream foundation Mass% Dimethylpolysiloxane 3.0
Decamethylcyclopentasiloxane 15.0
Polyoxyethylene / methylpolysiloxane copolymer 3.0
Glycerin 3.0
1,3-butylene glycol 5.0
2-Ethyl-1,3-hexanediol 1.0
Palmitic acid 0.5
Distearyldimethylammonium chloride 0.2
Glycerol-modified silicone resin-coated sericite 0.5
Dextrin fatty acid coated yellow iron oxide coated mica titanium 0.5
Dextrin fatty acid coated titanium oxide 2.0
Dextrin fatty acid-coated iron oxide / titanium oxide sintered product (PK) 12.0
Dextrin fatty acid coated talc 10.0
Methyl hydrogen polysiloxane treated titanium oxide coated sericite 0.5
Boron nitride 0.5
Fine particle titanium oxide 0.5
Bengala-coated mica titanium 0.5
Phytosterol 0.1
Sodium L-glutamate 1.5
Ascorbyl dipalmitate 0.1
DL-α-tocopherol acetate 0.1
Acetylated sodium hyaluronate 0.1
P-Hydroxybenzoate appropriate amount Phenoxyethanol 0.3
Bengala-coated mica titanium 0.5
Dextrin fatty acid coated yellow iron oxide 2.0
Dextrin fatty acid coated black iron oxide 0.2
Spherical nylon powder 1.0
Purified water Residual fragrance

Water-in-oil cream foundation mass%
Dimethylpolysiloxane 3.0
Decamethylcyclopentasiloxane 10.0
Polyoxyethylene / methylpolysiloxane copolymer 3.0
Dodecamethylcyclohexasiloxane 5.0
Glycerin 4.0
1,3-butylene glycol 5.0
2-Ethyl-1,3-hexanediol 0.5
Palmitic acid 0.5
Distearyldimethylammonium chloride 0.2
Metal soap treated talc 2.0
Cross-linked silicone powder (Trefil E-506) 0.1
Bengala-coated mica titanium 0.5
N-lauroyl-L-lysine 2.0
Sodium L-glutamate 2.0
Tocopherol acetate 0.1
δ-tocopherol 0.1
Methylparaben 0.1
Phenoxyethanol 0.2
Spherical nylon powder 1.0
Spherical polyalkyl acrylate powder 3.0
Merirot Extract 2.0
Purified water Residual dextrin fatty acid-treated talc 3.0
Dextrin fatty acid treated titanium dioxide 15.0
Dextrin fatty acid-treated yellow iron oxide 3.0
Dextrin fatty acid-treated black iron oxide 0.5

Water-in-oil cream foundation mass%
Dimethylpolysiloxane 15.0
Decamethylcyclopentasiloxane 20.0
Polyoxyethylene / methylpolysiloxane copolymer 5.0
High molecular weight amino-modified silicone 0.1
Glycerin 5.0
2-Ethyl-1,3-hexanediol 0.1
1,3-butylene glycol 10.0
Palmitic acid 0.5
Macadamia nut oil fatty acid cholesteryl 0.1
Distearyldimethylammonium chloride 0.2
Alkyl-modified silicone resin coated yellow iron oxide 2.0
Alkyl modified silicone resin coated bengara 1.0
Alkyl-modified silicone resin coated black iron oxide 0.3
Alkyl-modified silicone resin-coated titanium oxide 10.0
Alkyl modified silicone resin coated talc oxide 1.5
Silicone-coated spindle-shaped titanium oxide 3.0
Sodium L-glutamate 0.5
DL-α-tocopherol acetate 0.1
Paraoxybenzoic acid ester Methyl trimethoxycinnamate 0.1
Bis (trimethylsiloxy) silylisopentyldimethyldistearylammonium hectorite 1.5
Spherical nylon powder 1.0
Purified water Residual fragrance

Oil-in-water cream foundation by mass
Behenyl alcohol 0.5
Dipropylene glycol 6.0
Stearic acid 1.0
Glycerol monostearate 1.0
2-Ethyl-1,3-hexanediol 0.01
Potassium hydroxide 0.2
Triethanolamine 0.8
DL-α-tocopherol acetate 0.1
Methylparaben 0.1
Yellow iron oxide 1.0
α-olefin oligomer 3.0
Dimethylpolysiloxane (6 mPa.s) 2.0
Dimethylpolysiloxane (100 mPa.s) 5.0
Batyl alcohol 0.5
Isostearic acid 1.0
Behenic acid 0.5
Cetyl 2-ethylhexanoate 10.0
Polyoxyethylene glycerol monostearate 1.0
Titanium oxide 3.0
Mica titanium / polyalkyl acrylate composite powder 0.5
Surface-treated titanium oxide (MT-062) 10.0
Polyacrylic acid alkyl coated mica titanium 0.5
Black iron oxide coated mica titanium 0.5
Silica anhydride 6.0
2-Ethylhexyl paramethoxycinnamate 2.0
Bengala appropriate amount
Ultramarine blue
Black iron oxide
Legal dye Appropriate amount
Xanthan gum 0.1
Bentonite 1.0
Sodium carboxymethylcellulose 0.1
Purified water residue
Perfume

Oil-in-water emulsion foundation mass%
Dimethylpolysiloxane 8.0
Behenyl alcohol 0.5
Batyl alcohol 0.5
1,3-butylene glycol 5.0
2-Ethyl-1,3-hexanediol 2.0
Macadamia nut oil 0.1
Isostearic acid 1.5
Stearic acid 1.0
Behenic acid 0.5
Cetyl 2-ethylhexanoate 5.0
Polyoxyethylene glycerol monostearate 1.0
Self-emulsifying glyceryl monostearate 1.0
Yellow iron oxide coated mica titanium 2.0
Titanium oxide 4.0
Talc 0.5
Kaolin 3.0
Synthetic phlogopite 0.1
Cross-linked silicone powder 0.1
Silicic anhydride 5.0
Potassium hydroxide 0.2
Triethanolamine 0.8
DL-α-tocopherol acetate 0.1
Sodium hyaluronate 0.1
Methylparaben 0.1
2-Ethylhexyl paramethoxycinnamate 1.0
Bengala appropriate amount yellow iron oxide appropriate amount black iron oxide appropriate amount xanthan gum 0.1
Bentonite 1.0
Sodium carboxymethylcellulose 0.1
Purified water Residual fragrance

Funny (Loose type) Mass%
Glycerol-modified silicone resin-coated sericite 0.1
Yellow iron oxide coated mica titanium 0.1
Talc Residual Mica 20.0
Boron nitride 0.1
Zinc myristate 3.0
Aluminum stearate 0.1
Silicic anhydride 5.0
Cross-linked silicone powder 2.0
Silica anhydride 6.0
Bengala-coated mica titanium 0.1
Ascorbyl dipalmitate 0.01
Tocopherol acetate 0.02
2-Ethylhexanediol 2.0
2-Ethyl-1,3-hexanediol 2.0
Bengala-coated mica titanium 0.1
Yellow iron oxide 0.1
Pigment appropriate amount Fragrance appropriate amount

White powder
Talc Residual sericite 10.0
Spherical nylon powder 10.0
Boron nitride 5.0
Iron oxide 3.0
Magnesium carbonate 5.0
Squalane 3.0
Glycerin triisooctanoate 2.0
Sorbitan sesquioleate 2.0
2-Ethyl-1,3-hexanediol 0.01
Methylparaben 0.3
Perfume

Concealer (cream) mass%
Dimethylpolysiloxane 2.0
Decamethylcyclopentasiloxane 15.0
Polyoxyethylene / methylpolysiloxane copolymer 3.0
Glycerin 5.0
1,3-butylene glycol 6.0
D-man knit 1.0
2-ethyl-1,3-hexanediol 0.001
Squalane 0.5
Dextrin fatty acid coated titanium oxide 10.0
Dextrin fatty acid coated talc 10.0
Spherical polymethylsilsesquioxane powder 0.1
Bengala-coated mica titanium 0.5
Sodium L-glutamate 2.0
Wild rose extract 0.1
Phenoxyethanol 0.3
Bengala-coated mica titanium 0.5
Dextrin fatty acid coated yellow iron oxide 1.5
Dextrin fatty acid coated black iron oxide 0.5
Purified water residue

Concealer (Oil) Mass%
α-olefin oligomer 15.0
Microcrystalline wax 5.0
Ceresin 5.0
Dimethylpolysiloxane 12.0
Glyceryl tri-2-ethylhexanoate 10.0
Sorbitan sesquiisostearate 2.0
2-Ethyl-1,3-hexanediol 5.0
Yellow iron oxide coated mica titanium 0.1
Titanium oxide Residual sericite 5.0
Kaolin 10.0
Synthetic phlogopite 0.1
Cross-linked silicone powder (Trefil E-506) 1.0
Tocopherol acetate 0.1
δ-tocopherol 0.1
Sodium hyaluronate 0.1
Bengala appropriate amount yellow iron oxide appropriate amount black iron oxide appropriate amount synthetic sodium silicate / magnesium 1.0
Heavy liquid isoparaffin 2.0
Spherical polyalkyl acrylate powder 1.0
Perfume

Eyeliner mass%
Iron oxide (black) 14.0
Isopropyl myristate 1.5
Polyoxyethylene sorbitan monooleate 1.0
Vinyl acetate resin emulsion 45.0
Monoammonium glycyrrhizinate 0.05
Carboxyvinyl polymer 1.5
Acetyltributyl citrate 1.0
Dipropylene glycol 4.0
Isopropyl alcohol 1.0
2-ethyl-1,3-hexanediol 0.001
Ethylhexanediol 1.0
1,2-pentanediol 3.0
Phenoxyethanol 0.1
Methylparaben 0.02
Edetate trisodium 0.01
Purified water remaining

Eyeliner / eyebrow mass%
Liquid paraffin 1.0
Vaseline 4.0
Dimethylpolysiloxane
7.0
2-Ethyl-1,3-hexanediol 0.1
1,3-butylene glycol 0.1
Phytoteryl hydroxystearate 0.1
Sorbitan monoisostearate 1.0
Hydroxyapatite 1.0
Sericite 20.0
Mica Residual tocopherol acetate 0.02
δ-tocopherol 0.02
Phenoxyethanol 0.3
4-tert-butyl-4'-methoxydibenzoylmethane 0.1
Diparamethoxycinnamate mono-2-ethylhexanoate glyceryl 0.1
Bengala 2.0
Yellow iron oxide 7.0
Black iron oxide 10.0
Heavy liquid isoparaffin 2.0
Spherical nylon powder 0.5
Polyalkyl acrylate powder 2.0
Perfume

Eye shadow-mass%
Talc Residual Mica 15.0
Spherical nylon powder 10.0
Boron nitride 5.0
Iron oxide 3.0
Titanium oxide coated mica 5.0
Squalane 3.0
Glycerin triisooctanoate 2.0
Sorbitan sesquioleate 2.0
Ethylhexanediol 1.0
2-Ethyl-1,3-hexanediol 2.0
Methylparaben 0.1
Perfume

Aishad- / blusher (dry type)
Liquid paraffin 1.0
Vaseline 5.0
Ceresin 3.0
Dimethylpolysiloxane 1.0
Sorbitan monoisostearate 1.0
2-Ethyl-1,3-hexanediol 0.5
Mica titanium 3.0
Carmine, bitumen coated mica titanium 3.0
Talc 30.0
Mica Residual bitumen coated mica titanium 5.0
δ-tocopherol 0.05
Zinc oxide treated ultramarine 1.0
Dye Appropriate amount Polyalkyl acrylate powder 5.0
Perfume proper amount methylparaben 0.1

Aishad / blusher (oil-based type)
α-olefin oligomer 2.0
Microcrystalline wax 1.5
Ceresin 6.0
Dimethylpolysiloxane 5.0
Methylphenylpolysiloxane 5.0
Carnauba wax 2.0
Tri-2-ethylhexane sanglyceryl 20.0
Cetyl 2-ethylhexanoate Residual sorbitan sesquiisostearate 1.0
2-Ethyl-1,3-hexanediol 1.0
Titanium oxide 3.0
Boron nitride 5.0
Mica titanium 10.0
Sericite 8.0
Cross-linked silicone powder 5.0
DL-α-tocopherol acetate 0.02
D-δ-tocopherol 0.02
Bengala 0.1
Yellow iron oxide 0.2
Polyalkyl acrylate powder 15.0
Fragrance Appropriate 12-Hydroxystearic acid 3.0

Water-in-oil mascara mass%
Light isoparaffin 10.0
Dimethylpolysiloxane 1.0
Decamethylcyclopentasiloxane 12.0
Trimethylsiloxysilicic acid 12.0
Methyl polysiloxane emulsion appropriate amount ethyl alcohol 5.0
2-Ethyl-1,3-hexanediol 0.1
Isostearic acid Appropriate amount N-Lauroilleux L-Glutamic acid Appropriate amount Di (phytostearyl 2-octyldodecyl)
Dioleic acid polyethylene glycol 2.0
Diglyceryl diisostearate 1.0
Mica titanium 2.0
Aluminum stearate Appropriate amount Sodium bicarbonate 0.1
DL-α-tocopherol acetate 0.1
Methylparaben 0.1
Sodium dehydroacetate 0.2
Black iron oxide 10.0
Seaweed extract 0.1
Bentonite 1.0
Dimethyl distearyl ammonium hectorite 5.0
Polyvinyl acetate emulsion 21.0
Purified water remaining

Makeup base mass%
Dimethylpolysiloxane 6mPas 5.0
Decamethylcyclopentasiloxane Residual ethyl alcohol 8.0
Bitumen coated mica titanium 0.5
Methylsiloxane network polymer 5.0
Cross-linked silicone powder (Trefil E-506) 15.0
Citric acid 0.02
Sodium citrate 0.08
Tocopherol acetate 0.1
δ-tocopherol 0.1
Merirot Extract 3.0
2-Ethyl-1,3-hexanediol 2.0
Purified water 1.0
Poly (oxyethylene oxypropylene) 5.0
・
Methyl polysiloxy acid copolymer

Makeup base (cream)
Dimethylpolysiloxane 6mPas 5.0
Decamethylcyclopentasiloxane 25.0
Polyoxyethylene / methylpolysiloxane copolymer 3.0
Glycerin 1.0
1,3-butylene glycol 5.0
2-Ethyl-1,3-hexanediol 0.1
Xylit 0.5
Isostearic acid 0.5
Silica anhydride coated with alkyl-modified silicone resin 2.0
Talc 0.5
Aluminum stearate 1.0
Bengala-coated mica titanium 0.1
Sodium hexametaphosphate 0.05
Dipotassium glycyrrhizinate 0.1
L-serine 0.1
Hypericum extract 0.1
DL-α-tocopherol acetate 0.2
Thiotaurine 0.1
Togenashi extract 0.1
Peonies extract 0.1
Acetylated sodium hyaluronate 0.1
Yukinoshita extract 0.1
Methylparaben 0.1
Phenoxyethanol 0.2
Dextrin palmitate coated yellow iron oxide 0.1
Dimethyl distearyl ammonium hectorite 1.0
Purified water Residual trimethylsiloxysilicic acid 1.5
Spherical silicic acid 1.0
Spherical polyethylene powder 5.0
Perfume

Makeup base (cream)
Dimethylpolysiloxane 6mPas 5.0
Decamethylcyclopentasiloxane 30.0
Polyoxyethylene / methylpolysiloxane copolymer 3.0
Dodecamethylcyclohexasiloxane 1.0
Glycerin 5.0
Dipropylene glycol 5.0
2-Ethyl-1,3-hexanediol 5.0
Sage oil 0.1
Talc 0.1
Mica titanium 0.1
Cross-linked silicone powder (Trefil E-506) 3.0
Polymethylsilsesquioxane powder 10.0
Tocopherol acetate 0.1
δ-tocopherol 0.1
Thiotaurine 0.1
Western mint extract 0.1
Methylparaben 0.1
Ethylparaben 0.04
Phenoxyethanol 0.3
Edetate trisodium appropriate amount colored pigment appropriate amount dimethyl distearyl ammonium hectorite 1.5
Purified water residue

Makeup base (two-layer type)
Dimethylpolysiloxane 6mPas 2.0
Decamethylcyclopentasiloxane 40.0
Polyoxyethylene / methylpolysiloxane copolymer 2.0
1,3-butylene glycol 5.0
2-Ethyl-1,3-hexanediol 0.01
Squalane 0.5
Isostearic acid 0.5
Stearic acid 0.5
Fine zinc oxide 50nm 0.5
Fine particle titanium oxide 30nm 15.0
Aluminum stearate 1.0
Dipotassium glycyrrhizinate 0.5
DL-α-tocopherol acetate 0.1
D-δ-tocopherol 0.1
Methylparaben 0.1
Ethylparaben 0.05
Phenoxyethanol 0.3
Edetic acid trisodium appropriate amount Palmitic acid dextrin coated yellow iron oxide 0.4
Dimethyl distearyl ammonium hectorite 0.3
Purified water Residual trimethylsiloxysilicic acid 1.5
Spherical polyethylene powder 5.0
Aluminum oxide 0.2

Makeup base (milky lotion)
Dimethylpolysiloxane 2.0
Decamethylcyclopentasiloxane 5.0
Ethanol 3.0
Behenyl alcohol 0.1
Batyl alcohol 0.1
Dipropylene glycol 5.0
1,3-butylene glycol 3.0
2-Ethyl-1,3-hexanediol 1.0
Polyethylene glycol 1500 4.0
Vegetable squalane 0.1
Polyoxyethylene glyceryl isostearate 0.3
Titanium oxide Bengala-coated mica 0.3
Mica titanium 0.3
Potassium hydroxide 0.2
Sodium hexametaphosphate 0.05
Tocopherol acetate 0.1
Methylparaben 0.1
Butylparaben 0.01
Phenoxyethanol 0.3
Lithium cobalt titanate Appropriate amount of porous spherical cellulose powder 0.5
Polyethylene glycol (MW = 1 million) 0.2
Carboxyvinyl polymer 0.2
Acrylic acid / alkyl methacrylate copolymer 0.2
Purified water residue

Lipstick mass%
Microcrystalline wax 3.0
Ceresin 2.0
Polyoxyethylene / methylpolysiloxane copolymer 0.5
Methylphenylpolysiloxane Residual glycerin 0.5
Xylit 0.1
Liquid lanolin 2.0
Squalane 1.0
Glyceryl triisostearate 1.0
Macadamia nut oil fatty acid cholesteryl 2.0
Tri-2-ethylhexanesanglyceryl 15.0
Tri (hydrogenated rosin / isostearic acid) glyceryl 10.0
Silicon resin coated titanium oxide 1.0
Carmine coated mica titanium 2.0
Mica titanium 5.0
Dye proper amount citric acid 0.1
Potassium hydroxide 0.05
Hydroxypropyl-B-cyclodextrin 0.3
Pantothenyl ethyl ether 0.05
Arginine hydrochloride 0.01
DL-α-tocopherol acetate 0.05
Sodium hyaluronate 0.05
2-Ethylhexyl paramethoxycinnamate 5.0
2-Ethyl-1,3-hexanediol 1.0
Spherical cellulose powder 2.0
Heavy liquid isoparaffin 20.0
Purified water 0.5
Perfume

Lip liner mass%
Hardened oil 20.0
Macadamia nut oil 2.0
Owl 6.0
Behenic acid 10.0
Glyceryl tri-2-ethylhexanoate Residual 2-ethyl-1,3-hexanediol 0.1
Sucrose fatty acid ester 5.0
Titanium oxide 10.0
Mica 10.0
D-δ-tocopherol 0.04
Bengala 13.0
Yellow iron oxide 5.0
Black iron oxide 2.0
Sorbitan sesquiisostearate 1.0

Calamine lotion mass%
Zinc flower 1.3
Sericite 3.0
Iron oxide 0.05
Glycerin 2.0
Camphor 0.2
2-Ethyl-1,3-hexanediol 2.0
Ethyl alcohol 10.0
Purified water residue

Claims (6)

An external composition for skin comprising powder 1 and 2-ethyl-1,3-hexanediol. The external composition for skin according to claim 1, wherein the powder is an inorganic pigment. The external composition for skin according to claim 1, wherein the powder is a polymer powder. The external composition for skin according to claim 1, wherein the external composition for skin is a makeup cosmetic. The external composition for skin according to claim 1, wherein the content of the powder in the external composition for skin is 1.0% by mass or more. The skin external composition according to claim 1, wherein the content of 2-ethyl-1,3-hexanediol in the external skin composition is 0.001 to 5.0% by mass. Composition for external use.