JP2006225330A - Skin lotion composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a skin lotion composition improved in stickiness or superficial feeling in the use feeling of a water soluble polymer and having a good use feeling. <P>SOLUTION: This skin lotion composition contains 1 kind or ≥2 kinds of water soluble polymers and 2-ethyl-1,3-hexanediol. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

The present invention relates to an external composition for skin such as cosmetics, and more particularly to an external composition for skin such as cosmetics that is non-sticky, has good usability, and has excellent formulation stability.

In cosmetics, quasi-drugs, pharmaceuticals, and other external skin compositions, the viscosity of the product is adjusted to make it easy to use, give a rich feeling of use, and provide a moisturizing effect on the skin. A water-soluble polymer is blended for the purpose of maintaining stability.

However, water-soluble polymers have an excellent action, but because they tend to be sticky to use and cause slipping when applied to the skin, formulations containing water-soluble polymers should be used. In many cases, it is disliked by consumers, and it has been a great difficulty in blending it into an external preparation for skin, particularly cosmetics.

In view of such circumstances, the present inventors have made extensive studies for the purpose of improving the stickiness and the feeling of upslip, which are characteristic of water-soluble polymers, and as a result, 2-ethyl-1 together with water-soluble polymers. , 3-Hexanediol was found to solve the above problems, and the present invention was completed.
2-ethyl-1,3-hexanediol used in the present invention is generally used as a pest repellent (Patent Documents 1, 2, and 3).
US2407205 WO89 / 03639 However, the present invention is a composition for external use on the skin comprising a novel combination of a water-soluble polymer and 2-ethyl-1,3-hexanediol. Thus, the present inventors have found a cosmetic with excellent usability and excellent formulation stability.

  The composition for external use of the skin of the present invention significantly improves the stickiness and slipping feeling on use feeling of the water-soluble polymer by blending the water-soluble polymer and 2-ethyl-1,3-hexanediol.

The external composition for skin according to the present invention is a cosmetic.
The external composition for skin of the present invention is a basic cosmetic.
The composition for external use of the skin of the present invention is a makeup cosmetic.
In the skin external composition of the present invention, the content of the water-soluble polymer in the skin external composition is 0.001 to 5.0% by mass.
The external composition for skin of the present invention is characterized in that the content of 2-ethyl-1,3-hexanediol in the external composition for skin is 0.001 to 5.0% by mass.

The water-soluble polymer used in the present invention is a water-soluble polymer generally used in compositions for external use on skin such as cosmetics, quasi drugs, and pharmaceuticals. Specifically, for example, gum arabic, gum tragacanth, galactan , Guar gum, carrageenan, pectin, agar, locust bin gum, mannan, quince seed gum (quince extract), alge colloid (guckweed extract), mannan, starch (rice, corn, potato, wheat), etc. Natural polymers derived from microorganisms such as dextran, succinoglucan, gellan gum, pullulan, hyaluronic acid, acetylated hyaluronic acid, chondroitin, chondroitin sulfate, natural polymers derived from animals such as gelatin, casein, albumin, collagen, methylcellulose, ethyl Cellulose-based semisynthetic polymers such as cellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate, hydroxypropylcellulose, carboxymethylcellulose, sodium carboxymethylcellulose, crystalline cellulose, cellulose, soluble starch, carboxymethyl starch, methylhydroxypropyl starch Synthetic polymers such as starch-based semi-synthetic polymers such as alginate, alginic acid, alginic acid-based semi-synthetic polymers, polysaccharide-based derivative semi-synthetic polymers, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymers, etc. Molecules, polyethylene oxide, synthetic polymers such as ethylene oxide / propylene oxide block copolymers, Sodium acrylic acid, polyethyl acrylate, and acrylic-based synthetic polymers such as polyacrylamide. Among these, plant-derived natural polymers, microorganism-derived natural polymers, cellulose-based semi-synthetic polymers, starch-based semi-synthetic polymers, and vinyl-based synthetic polymers are preferable, and quince seed gum (malmello extract), xanthan gum, carboxy More preferred are methylcellulose and carboxyvinyl polymer.

The water-soluble polymer of the present invention can be converted into an inorganic salt or an organic salt by a known method. The salt used in the present invention is not particularly limited, and examples of the inorganic salt include alkali metal salts such as sodium salt and potassium salt, alkaline earth metal salts such as calcium salt and magnesium salt, ammonium salt and the like. . Examples of the organic salt include triethylamine salt, triethanolamine salt, diethanolamine salt, basic amino acid salt and the like. Among these salts, alkali metal salts are preferable.

Content in the skin external composition of the water-soluble polymer of this invention is 0.001-5.0 mass%, Preferably it is 0.01-1.0 mass%. If the amount is too small, the effect of the water-soluble polymer will not be exhibited, and if it is incorporated excessively, problems such as stickiness will occur.

The 2-ethyl-1,3-hexanediol of the present invention can be produced by a known synthesis method. It is also commercially available from Tokyo Chemical Industry Co., Ltd. and can be easily obtained.

The 2-ethyl-1,3-hexanediol of the present invention has stereoisomerism due to its structure, but in the present invention, it may be a single compound or a mixture thereof, and the mixing ratio is not questioned. Absent. Further, although optical isomerism occurs, it may be optically active, racemic, or a mixture thereof, or may be a single or a mixture of their stereoisomerism, and their mixing ratio is not limited.

The 2-ethyl-1,3-hexanediol of the present invention is a transparent liquid substance having a high boiling point, and after preparation of the composition for external use on the skin, crystals do not precipitate even at a low temperature, and it volatilizes even at a high temperature. The stability of the external composition for skin is improved. In addition, its amphiphilic properties make it compatible with other ingredients for external use such as a water-soluble polymer, and at the same time, improves the familiarity between the ingredients, giving the water-soluble polymer a sticky feel when used. Remarkably improve the feeling of sliding.

  The content of the 2-ethyl-1,3-hexanediol of the present invention in the composition for external use on the skin is 0.001 to 5.0 mass in consideration of improvement in the stickiness and feeling of sliding on the water-soluble polymer. %, Preferably 0.01 to 2.0% by mass. If the amount is too small, the improvement effect cannot be ensured, and if it is added excessively, problems such as stickiness occur.

In addition to the water-soluble polymer and 2-ethyl-1,3-hexanediol, the external composition for skin of the present invention is a component that is usually blended in an external composition for skin such as cosmetics, quasi drugs, and pharmaceuticals, For example, powder components, liquid fats and oils, solid fats and oils, waxes, hydrocarbon oils, higher fatty acids, higher alcohols, ester oils, silicone oils, film agents, UV absorbers, sequestering agents, lower alcohols, polyhydric alcohols, sugars, Amino acids, organic amines, polymer emulsions, pH adjusters, skin nutrients, vitamins, antioxidants, antioxidant aids, bactericides and preservatives, other drugs, pigments, fragrances, water, and the like can be blended.

Moreover, the form of the composition for external use of the present invention is not particularly limited, and for example, it is liquid, gel, paste, emulsion, cream or the like. Specifically, the composition for external use of the skin of the present invention specifically includes basic cosmetics such as emulsions, creams, lotions, sunscreens, gels, serums, packs, masks, foundations, white powders / dusts, lipsticks, blushers, makeup Makeup cosmetics such as base, eyeliner, mascara, eye shadow, eyebrow, nail enamel, enamel remover, nail treatment, lotion, milky lotion, cream, fragrance, sun care (sunscreen, sun oil, after sun lotion), decolorization / Although it is body cosmetics, such as a hair remover, it is not limited to these.

Next, the present invention will be described more specifically with reference to examples. The present invention is not limited thereby. A compounding quantity is the mass%.
[Use test 1]

A lotion having the formulation shown in Table 1 was prepared according to the following production method, and the satisfaction of the feeling of use (stickiness) was evaluated by a use test.
<Manufacturing method for lotion>
POE (20) oleyl ether and methyl paraben are dissolved in a part of ethanol. In the remaining purified water and ethanol, 2-ethyl-1,3-hexanediol, dipropylene glycol, glycerin, citric acid, sodium citrate, carboxyvinyl polymer, sodium carboxymethylcellulose, xanthan gum, quince seed gum (quince seed extract) Dissolve potassium hydroxide, trisodium edetate. An ethanol phase was added to the aqueous phase and solubilized to obtain a lotion.
<Use test method>

Twenty male and female panels were used twice a day for two weeks to report satisfaction with their feeling of use. The evaluation of the feeling of use was performed by the following four grades, and the average of the grades was calculated and classified into the following criteria.
4: There is no stickiness and the feeling of use is satisfactory 3: Slightly sticky, but the feeling of use is almost satisfactory 2: Stickiness, the feeling of use is unsatisfactory 1: The sticky feeling is marked, and the feeling of use is extremely unsatisfactory

A: Evaluation point average 3.5 or more B: Evaluation point average 3.0 to less than 3.5 C: Evaluation point average 2.0 to less than 3.0 D: Evaluation point average less than 2.0

In Examples 1 to 4, the stickiness on use feeling of the water-soluble polymer is improved and the satisfaction of use is very high, whereas in Comparative Examples 1 to 4, the use feeling of the water-soluble polymer is on Due to the stickiness, the satisfaction of usability is very low. This is an effect of the present invention.

[Use test 2]
Emulsions with the formulations shown in Table 2 were prepared according to the following production methods, and the satisfaction with the feeling of use (slip feeling) was evaluated by a use test.
<Production method of emulsion>
In purified water, glycerin, citric acid, sodium citrate, carboxyvinyl polymer, sodium carboxymethyl cellulose, xanthan gum, quince seed gum (quintuce extract), edetate trisodium, potassium hydroxide, polyoxyethylene glyceryl isostearate, monostearin Dissolve acid polyoxyethylene glycerin (aqueous phase). A solution in which 2-ethyl-1,3-hexanediol, 1,3-butylene glycol and methylparaben are dissolved (alcohol phase) is mixed with the aqueous phase. Decamethylcyclopentasiloxane, methylphenylpolysiloxane, and behenyl alcohol are mixed (oil phase), added to the aqueous phase, and emulsified using a homogenizer.
<Use test method>

Twenty male and female panels were used twice a day for two weeks to report satisfaction with their feeling of use. The evaluation of the feeling of use was performed by the following four grades, and the average of the grades was calculated and classified into the following criteria.
4: Familiar with skin without slipping, satisfactory feeling of use 3: Slightly upsliding, but almost satisfied with feeling of use 2: Sliding up, unsatisfactory of feeling of use 1: Unsatisfactory slipping and adapting to the skin, extremely comfortable to use Dissatisfaction

A: Evaluation point average 3.5 or more B: Evaluation point average 3.0 to less than 3.5 C: Evaluation point average 2.0 to less than 3.0 D: Evaluation point average less than 2.0

In Examples 5 to 8, the feeling of sliding on the use feeling of the water-soluble polymer was improved and the satisfaction of use was very high, whereas in Comparative Examples 5 to 8, the use feeling of the water-soluble polymer. Satisfaction with usability is very low due to the upper slipping feeling. This is an effect of the present invention.
Hereinafter, various compositions for external use of the skin of the present invention will be exemplified. In any of the examples, the stickiness and the slipperiness on the feeling of use possessed by the water-soluble polymer were improved, and the satisfaction of usability was high. In addition, the manufacturing method of the external composition for skin in these Examples followed the method generally used as a manufacturing method in each.

Toner lotion mass%
(Alcohol phase)
Ethanol 5.0
POE (20) oleyl ether 0.5
2-Ethyl-1,3-hexanediol 0.01
Phenoxyethanol 0.1
Methylparaben 0.1
Perfume appropriate amount (water phase)
Dipropylene glycol 6.0
Sorbit 4.0
PEG 1500 5.0
Methylcellulose 0.2
Quince Seed Gum (Quince Extract) 0.01
Purified water residue

Toner lotion mass%
Ethyl alcohol 5.0
Glycerin 1.0
1,3-butylene glycol 5.0
2-Ethyl-1,3-hexanediol 0.5
Polyoxyethylene polyoxypropylene 0.2
Decyl tetradecyl ether
Sodium hexametaphosphate 0.03
Trimethylglycine 1.0
Sodium polyaspartate 0.1
α-Tocopherol 0.1
2-L-ascorbic acid phosphate diester potassium thiotaurine 0.1
Green tea extract 0.1
Western mint extract 0.1
Iris root extract 0.1
HEDTA3 sodium 0.1
Carboxyvinyl polymer 0.05
Potassium hydroxide Appropriate amount Phenoxyethanol Appropriate amount Purified water Residual fragrance
Appropriate amount

Toner lotion mass%
Ethanol 5.0
Glycerin 0.5
Dipropylene glycol 2.0
1,3-butylene glycol 6.0
2-ethyl-1,3-hexanediol 0.001
Rosemary oil 0.01
Sage oil 0.01
Citric acid 0.02
Sodium citrate 0.08
Sodium hexametaphosphate 0.03
Hydroxypropyl-β-cyclodextrin 0.1
Mukuroji extract 0.1
Ages Extract 0.1
Lily extract 0.1
Oat extract 0.1
Togenashi extract 0.1
Kiso Extract 0.1
Lavender oil 0.1
Tounin extract 0.1
Sodium carboxymethylcellulose 0.001
Purified water residue

Milk mass%
Glycerin 3.0
2-Ethyl-1,3-hexanediol 1.0
Cetanol 1.5
Stearyl alcohol 1.8
Dimethylpolysiloxane (20cs) 1.5
Squalane 2.0
Vaseline 2.0
Isopropyl myristate 2.5
Glyceryl monostearate 1.8
Polyoxyethylene (POE = 5) glyceryl monostearate 1.8
Polyoxyethylene (POE = 20) cetyl ether 1.5
Carboxyvinyl polymer 0.25
Potassium hydroxide 0.05
L-Arginine 0.2
Dipropylene glycol 5.0
1,3-butylene glycol 3.0
Edetate trisodium 0.2
Phenoxyethanol 0.1
Ethylparaben 0.01
Butylparaben 0.01
Purified water remaining

Milk mass%
Dimethylpolysiloxane 2.0
Behenyl alcohol 1.0
Batyl alcohol 0.5
Glycerin 5.0
1,3-butylene glycol 7.0
2-Ethyl-1,3-hexanediol 1.0
Erythritol 2.0
Hardened oil 3.0
Squalane 6.0
Tetra-2-ethylhexanoic acid pentaerythrit 2.0
Polyoxyethylene glyceryl isostearate 1.0
Polyoxyethylene glycerol monostearate 1.0
Potassium hydroxide appropriate amount Sodium hexametaphosphate 0.05
Phenoxyethanol appropriate amount carboxyvinyl polymer 0.1
Purified water residue

Milk mass%
Stearic acid 2.5
Cetyl alcohol 1.5
2-Ethyl-1,3-hexanediol 1.0
Vaseline 5.0
Liquid paraffin 10.0
POE (10) monooleate 2.0
PEG 1500 3.0
Triethanolamine 1.0
Phenoxyethanol 0.3
Sodium bisulfite 0.01
Carboxyvinyl polymer 0.05
Perfume Appropriate amount of purified water

Milk mass%
Liquid paraffin 7.0
Vaseline 3.0
Decamethylcyclopentasiloxane 2.0
Behenyl alcohol 1.0
Glycerin 5.0
Dipropylene glycol 7.0
Polyethylene glycol 1500 2.0
2-Ethyl-1,3-hexanediol 2.0
Jojoba oil 1.0
Isostearic acid 0.5
Stearic acid 0.5
Behenic acid 0.5
Tetra-2-ethylhexanoic acid pentaerythritol 3.0
Cetyl 2-ethylhexanoate 3.0
Glycerol monostearate 1.0
Polyoxyethylene glycerol monostearate 1.0
Potassium hydroxide 0.1
Sodium hexametaphosphate 0.05
Stearyl glycyrrhetinate 0.05
L-Arginine 0.1
Royal Jelly Extract 0.1
Tocopherol acetate 0.1
Acetylated sodium hyaluronate 0.1
Edetate trisodium 0.05
4-t-butyl-4'-methoxydibenzoylmethane 0.1
2-Ethylhexyl paramethoxycinnamate 0.1
Carboxyvinyl polymer 0.15
Purified water residue

Milk mass%
Vaseline 5.0
Behenyl alcohol 0.5
Batyl alcohol 0.5
Glycerin 7.0
1,3-butylene glycol 7.0
1,2-pentanediol 1.0
2-Ethyl-1,3-hexanediol 5.0
Xylit 3.0
Polyethylene glycol 20000 2.0
Hardened oil 2.0
Jojoba oil 2.0
Squalane 5.0
Isostearic acid 0.5
Tetra-2-ethylhexanoic acid pentaerythrit 2.0
Polyoxyethylene hydrogenated castor oil 0.5
Lauryldimethylaminoacetic acid betaine 0.4
Potassium hydroxide appropriate amount Sodium pyrosulfite 0.01
Sodium hexametaphosphate 0.05
Dipotassium glycyrrhizinate 0.05
Trimethylglycine 3.0
Arbutin 3.0
Yeast extract 0.1
Tocopherol acetate 0.1
Thiotaurine 0.1
Clara extract 0.1
Bengala appropriate amount quince seed gum (quince extract) 0.1
Carboxyvinyl polymer 0.2
Phenoxyethanol Suitable amount Purified water Residual

Gel mass%
95% ethanol 5.0
Dipropylene glycol 15.0
2-Ethyl-1,3-hexanediol 3.0
POE (50) oleyl ether 2.0
Carboxyvinyl polymer 1.0
Sodium hydroxide 0.15
Phenoxyethanol 0.1
Perfume Appropriate amount of purified water

Gel mass%
Dimethylpolysiloxane 5.0
Glycerin 2.0
1,3-butylene glycol 5.0
2-Ethyl-1,3-hexanediol 1.0
Polyethylene glycol 1500 3.0
Polyethylene glycol 20000 3.0
Cetyl octanoate 3.0
Citric acid 0.01
Sodium citrate 0.1
Sodium hexametaphosphate 0.1
Dipotassium glycyrrhizinate 0.1
Ascorbic acid glucoside 2.0
Tocopherol acetate 0.1
Ogon Extract 0.1
Yukinoshita extract 0.1
Edetate trisodium 0.1
Xanthan gum 0.3
Acrylic acid / alkyl methacrylate copolymer 0.05
(Pemulen TR-2)
Agar powder 1.5
Phenoxyethanol Appropriate amount Dibutylhydroxytoluene Appropriate amount of purified water Residue

Gel mass%
Ethanol 5.0
2-Ethyl-1,3-hexanediol 1.0
Lactic acid 0.3
β-glycyrrhetinic acid 0.05
Arginine hydrochloride 0.1
Peonies extract 0.1
Sulfur 0.2
POE (20) sorbitan monooleate 1.0
Sodium carboxymethylcellulose 0.5
Vinylpyrrolidone / N, N-dimethylaminoethyl methacrylate 0.5
・ Acrylic acid copolymer
Purified water residue

Essence mass%
95% ethanol 5.0
POE (20) Octyldodecanol 1.0
Pantothenyl ethyl ether 0.1
2-Ethyl-1,3-hexanediol 0.1
Potassium hydroxide 0.1
Glycerin 5.0
Dipropylene glycol 10.0
Sodium bisulfite 0.03
Carboxyvinyl polymer 0.2
Phenoxyethanol 0.3
Methylparaben 0.1
Purified water residue

Pack mass%
(Phase A)
Dipropylene glycol 5.0
POE (60) hydrogenated castor oil 5.0
(Phase B)
Olive oil 5.0
2-ethyl-1,3-hexanediol 0.001
Tocopherol acetate 0.2
Fragrance 0.2
(Phase C)
Sodium bisulfite 0.03
Polyvinyl alcohol
(Degree of saponification 90, degree of polymerization 2000) 13.0
Ethanol 5.0
Methylparaben 0.1
Phenoxyethanol 0.2
Purified water residue

Pack mass%
Ethanol 10.0
1,3-butylene glycol 6.0
2-Ethyl-1,3-hexanediol 5.0
Polyethylene glycol 4000 2.0
Olive oil 1.0
Macadamia nut oil 1.0
Phytosteryl hydroxystearate 0.05
Lactic acid 0.05
Sodium lactate 0.1
L-ascorbic acid sulfate disodium 0.1
α-Tocopherol 0.1
2-L-ascorbic acid phosphate diester potassium vitamin E acetate 0.1
Fish collagen 0.1
Chondroitin thorium sulfate 0.1
Sodium carboxymethylcellulose 0.2
Polyvinyl alcohol 12.0
Xanthan gum 0.5
Paraoxybenzoic acid ester Appropriate amount Purified water Residual perfume Appropriate amount

mass%
pack
Ethanol 3.0
Glycerin 12.0
Sorbit liquid (70%) 15.0
2-Ethyl-1,3-hexanediol 5.0
Titanium oxide 0.35
Dry aluminum hydroxide gel 0.1
Togenashi extract 0.1
Fish gelatin 0.1
Sodium polyacrylate 6.0
Sodium carboxymethylcellulose 2.0
Carboxyvinyl polymer 1.0
Purified water Residual paraoxybenzoic acid ester

mass%
pack
1,3-butylene glycol 7.0
2-Ethyl-1,3-hexanediol 3.0
Sorbit liquid 40.0
Sage oil 0.01
Kaolin 40.0
Citric acid 0.01
Sodium hexametaphosphate 0.05
Calcium chloride 0.01
Magnesium chloride 0.01
Hydroxypropyl-β-cyclodextrin 0.1
Lactic acid 0.01
Trimethylglycine 1.0
Mukuroji extract 0.1
Oat extract 0.1
Lavender oil 0.01
Pyrrolidone carboxylic acid Na 0.01
Quince Seed Extract 0.1
Crystalline cellulose powder 0.7
Sodium carboxymethylcellulose 1.0
Purified water residue

Cream mass%
Liquid paraffin 10.0
Dimethylpolysiloxane 2.0
Glycerin 10.0
1,3-butylene glycol 2.0
Erythritol 1.0
2-Ethyl-1,3-hexanediol 0.5
Polyethylene glycol 1500 5.0
Squalane 15.0
Tetra-2-ethylhexanoic acid pentaerythrit 5.0
Potassium hydroxide 0.1
Sodium hexametaphosphate 0.05
Tocopherol acetate 0.05
Phenoxyethanol 0.1
Methylparaben 0.2
Polyvinyl alcohol 0.1
Carboxyvinyl polymer 0.2
Acrylic acid / alkyl methacrylate copolymer 0.1
(Pemulen TR-2)

Cream mass%
Vaseline 2.0
Dimethylpolysiloxane (6mPa.s) 2.0
Ethanol 5.0
Behenyl alcohol 0.5
Batyl alcohol 0.2
Glycerin 7.0
1,3-butylene glycol 5.0
Polyethylene glycol 20000 0.5
Jojoba oil 3.0
Squalane 2.0
Phytosteryl hydroxystearate 0.5
Tetra-2-ethylhexanoic acid pentaerythrit 1.0
Polyoxyethylene (60) hydrogenated castor oil 1.0
Potassium hydroxide 0.1
Sodium pyrosulfite 0.01
Sodium hexametaphosphate 0.05
Stearyl glycyrrhetinate 0.1
Pantothenyl ethyl ether 0.1
Arbutin 7.0
Tranexamic acid 1.0
Tocopherol acetate 0.1
Sodium hyaluronate 0.05
Edetate trisodium 0.05
2-Ethyl-1,3-hexanediol 1.0
4-t-butyl-4'-methoxydibenzoylmethane 0.1
Diparamethoxycinnamic acid mono-2-ethylhexanoic acid 0.1
Glyceryl
Phenoxyethanol 0.1
Methylparaben 0.05
Yellow iron oxide xanthane gum 0.1
Carboxyvinyl polymer 0.2
Purified water residue

Cream mass%
Dimethylpolysiloxane 3.0
Decamethylcyclopentasiloxane 13.0
Dodecamethylcyclohexasiloxane 12.0
Polyoxyethylene / methylpolysiloxane copolymer 1.0
Ethanol 2.0
Isopropanol 1.0
Glycerin 3.0
Dipropylene glycol 5.0
2-Ethyl-1,3-hexanediol 2.0
Polyethylene glycol 6000 5.0
Sodium hexametaphosphate 0.05
Tocopherol acetate 0.1
Caffeine 0.1
Fennel extract 0.1
Hamelis extract 0.1
Carrot extract 0.1
L-menthol appropriate amount paraoxybenzoate appropriate amount edetate trisodium 0.05
Dimorpholinopyridazinone 0.01
Methyl trimethoxycinnamate 0.1
Bis (trimethylsiloxy) silylisopentyl yellow iron oxide Appropriate amount Cobalt titanate Appropriate amount Dimethyl distearyl ammonium hectorite 1.5
Polyvinyl alcohol 0.1
Sodium carboxymethylcellulose 0.1
Trimethylsiloxysilicic acid 2.0
Purified water Residual fragrance

Cream mass%
Decamethylcyclopentasiloxane 20.0
Ethanol 5.0
Isostearyl alcohol 2.0
Dipropylene glycol 3.0
2-Ethyl-1,3-hexanediol 2.0
Isostearic acid 2.0
Glyceryl tri-2-ethylhexanoate 5.0
Cetyl 2-ethylhexanoate 2.0
Dextrin fatty acid ester coated fine particle titanium oxide (40nm) 2.0
Sodium chloride 2.0
Edetate trisodium appropriate amount ubinal T-150 (manufactured by BASF) 1.0
4-t-butyl-4′-methoxydibenzoylmethane 1.0
2-Ethylhexyl paramethoxycinnamate 7.5
Sodium carboxymethylcellulose 0.5
Ethyl cellulose 1.0
Spherical acrylic resin powder 5.0
Purified water Residual fragrance

mass%
Mascara methylpolysiloxane emulsion appropriate amount ethanol 5.0
Isopropanol 3.0
Glycerin 3.0
1,3-butylene glycol 5.0
2-Ethyl-1,3-hexanediol 1.8
Silicic anhydride 1.0
Bengala coated mica titanium (pearl agent) 9.0
Strong ammonia water 0.1
Sodium metaphosphate 0.1
Hydrolyzed wheat protein 0.1
P-Hydroxybenzoate appropriate amount sodium dehydroacetate appropriate amount black iron oxide (pigment) 1.0
Xanthan gum 1.0
Aluminum magnesium silicate 2.0
Sodium carboxymethylcellulose 1.0
Alkyl acrylate copolymer emulsion 10.0
Purified water remaining

mass%
Eyeliner iron oxide (black) 14.0
Isopropyl myristate 1.5
Polyoxyethylene sorbitan monooleate 1.0
Vinyl acetate resin emulsion 45.0
Monoammonium glycyrrhizinate 0.05
Sodium carboxymethylcellulose 5.0
Acetyltributyl citrate 1.0
Dipropylene glycol 4.0
Isopropyl alcohol 1.0
2-Ethyl-1,3-hexanediol 1.0
Phenoxyethanol 0.1
Methylparaben 0.02
Edetate trisodium 0.01
Purified water remaining

mass%
Hair cream volatile isoparaffin 5.0
Dimethylpolysiloxane 2.0
Ethanol 5.0
Glycerin 5.0
2-Ethyl-1,3-hexanediol 1.5
Section glyceryl ether with polyoxypropylene 5.0
Isostearic acid 1.0
Polyoxyethylene hydrogenated castor oil 0.5
2-Alkyl-N-carboxymethyl 4.0
-N-hydroxyethylimidazolinium betaine sodium hydroxide 0.15
P-hydroxybenzoate appropriate amount phenoxyethanol appropriate amount edetate trisodium appropriate amount xanthan gum 0.5
Carrageenan 0.3
Vinyl acetate. Vinylpyrrolidone copolymer 2.0
Carboxyvinyl polymer 0.5
Purified water Residual highly polymerized methylpolysiloxane 2.0

mass%
Emulsion solid foundation
Microcrystalline wax 1.0
Dimethylpolysiloxane 15.0
Decamethylcyclopentasiloxane 2.0
1,3-butylene glycol 6.0
2-Ethyl-1,3-hexanediol 5.0
Candelilla Row 3.0
Isostearic acid 1.0
Ethylene glycol fatty acid ester 0.1
Lanolin fatty acid octyldodecyl 0.5
2-Alkyl-N-carboxymethyl 4.0
-N-hydroxyethylimidazolinium betaine titanium oxide 7.5
Barium sulfate 5.0
Titanium oxide 7.0
Talc 3.0
Silicic anhydride 4.0
Cross-linked silicone powder (Trefil E-506) 0.1
Sodium metaphosphate 0.1
Hydroxypropyl-β-cyclodextrin 0.1
DL-α-tocopherol acetate 0.1
Hamamelis extract 0.1
Peonies extract 0.1
Sodium chondroitin sulfate 0.1
Sodium hyaluronate 0.1
Methylparaben 0.1
Butylparaben 0.02
Bengala appropriate amount yellow iron oxide appropriate amount black iron oxide appropriate amount xanthan gum 0.2
Sodium carboxymethylcellulose 0.2
Merirot Extract 2.0
Purified water residue

mass%
Water-in-oil cream foundation dimethylpolysiloxane 3.0
Decamethylcyclopentasiloxane 15.0
Polyoxyethylene / methylpolysiloxane copolymer 3.0
Glycerin 3.0
1,3-butylene glycol 5.0
2-Ethyl-1,3-hexanediol 2.0
Palmitic acid 0.5
Distearyldimethylammonium chloride 0.2
Glycerol-modified silicone resin-coated sericite 0.5
Dextrin fatty acid coated yellow iron oxide coated mica titanium 0.5
Dextrin fatty acid coated titanium oxide 2.0
Dextrin fatty acid-coated iron oxide / titanium oxide sintered product (PK 12.0
Dextrin fatty acid coated talc 10.0
Methyl hydrogen polysiloxane treatment 0.5
Titanium oxide coated sericite boron nitride 0.5
Fine particle titanium oxide 0.5
Bengala-coated mica titanium 0.5
Phytosterol 0.1
Sodium L-glutamate 1.5
Ascorbyl dipalmitate 0.1
DL-α-tocopherol acetate 0.1
Carboxyvinyl polymer 0.1
Potassium hydroxide appropriate amount paraoxybenzoic acid appropriate amount phenoxyethanol 0.3
Bengala-coated mica titanium 0.5
Dextrin fatty acid coated yellow iron oxide 2.0
Dextrin fatty acid coated black iron oxide 0.2
Spherical nylon powder 1.0
Purified water Residual fragrance

mass%
Oil-in-water cream foundation behenyl alcohol 0.5
Dipropylene glycol 6.0
Stearic acid 1.0
Glycerol monostearate 1.0
2-Ethyl-1,3-hexanediol 2.0
Potassium hydroxide 0.2
Triethanolamine 0.8
DL-α-tocopherol acetate 0.1
Methylparaben 0.1
Yellow iron oxide 1.0
α-olefin oligomer 3.0
Dimethylpolysiloxane (6 mPa.s) 2.0
Dimethylpolysiloxane (100 mPa.s) 5.0
Batyl alcohol 0.5
Isostearic acid 1.0
Behenic acid 0.5
Cetyl 2-ethylhexanoate 10.0
Polyoxyethylene glycerol monostearate 1.0
Titanium oxide 3.0
Mica titanium / polyalkyl acrylate composite powder 0.5
Surface-treated titanium oxide (MT-062) 10
Polyacrylic acid alkyl coated mica titanium 0.5
Black iron oxide coated mica titanium 0.5
Silica anhydride 6.0
2-Ethylhexyl paramethoxycinnamate 2.0
Bengala appropriate amount
Ultramarine blue
Black iron oxide
Legal dye Appropriate amount
Xanthan gum 0.1
Bentonite 1.0
Sodium carboxymethylcellulose 0.1
Purified water residue
Perfume

mass%
Two-layer type latex foundation ethanol 10.0
Glycerin 10.0
1,3-butylene glycol 7.0
2-Ethyl-1,3-hexanediol 2.0
Silica-coated titanium oxide 8.0
Synthetic phlogopite 3.0
Spherical silica 5.0
Bengala coated mica titanium (color rendering pearl G) 2.0
Sodium chloride 0.3
Hydroxypropyl-β-cyclodextrin 0.1
Mukuroji extract 0.1
Green tea extract 0.1
Lily extract 0.1
Bengala 0.1
Carboxyvinyl polymer 0.1
Porous spherical cellulose 0.1
Lavender extract 0.1
Purified water residue

mass%
Oil-in-water emulsion foundation
Dimethylpolysiloxane 8.0
Behenyl alcohol 0.5
Batyl alcohol 0.5
1,3-butylene glycol 5.0
Macadamia nut oil 0.1
Isostearic acid 1.5
Stearic acid 1.0
Behenic acid 0.5
Cetyl 2-ethylhexanoate 5.0
Polyoxyethylene glycerol monostearate 1.0
Self-emulsifying glyceryl monostearate 1.0
Yellow iron oxide coated mica titanium 2.0
Titanium oxide 4.0
Talc 0.5
Kaolin 3.0
Synthetic phlogopite 0.1
Cross-linked silicone powder 0.1
Silicic anhydride 5.0
Potassium hydroxide 0.2
Triethanolamine 0.8
DL-α-tocopherol acetate 0.1
Sodium hyaluronate 0.1
Methylparaben 0.1
2-Ethylhexyl paramethoxycinnamate 1.0
Bengala appropriate amount yellow iron oxide appropriate amount black iron oxide appropriate amount xanthan gum 0.1
Bentonite 1.0
Sodium carboxymethylcellulose 0.1
Purified water Residual fragrance

Makeup base (cream)
α-olefin oligomer 10.0
Dimethylpolysiloxane 5.0
Behenyl alcohol 0.5
Batyl alcohol 0.5
1,3-butylene glycol 5.0
2-Ethyl-1,3-hexanediol 0.5
Isostearic acid 1.0
Stearic acid 1.0
Behenic acid 1.0
Cetyl 2-ethylhexanoate 2.0
N-laureuil L-glutamic acid 0.1
Di (phytostearyl 2-octyldodecyl)
Polyoxyethylene glycerol monostearate 2.0
Self-emulsifying glyceryl monostearate 0.5
Talc 0.5
Mica titanium 0.5
Black iron oxide coated mica titanium 0.1
Potassium hydroxide 0.2
Sodium metaphosphate 0.5
Tocopherol acetate 0.1
Methylparebene 0.1
Ethylpareven 0.1
Phenoxyethanol 0.3
2-methoxyhexyl paramethoxycinnamate 3.0
Colored pigment appropriate amount carboxyvinyl polymer 0.1
Bentonite 1.0
Sodium carboxymethylcellulose 0.1
Spherical polyalkyl acrylate powder 0.1
Purified water Residual spherical silicic acid 5.0
Titanium oxide 5.0
Perfume

mass%
Makeup base (milky lotion)
Dimethylpolysiloxane 2.0
Decamethylcyclopentasiloxane 5.0
Ethanol 3.0
Behenyl alcohol 0.1
Batyl alcohol 0.1
Dipropylene glycol 5.0
1,3-butylene glycol 3.0
2-Ethyl-1,3-hexanediol 0.3
Polyethylene glycol 1500 4.0
Vegetable squalane 0.1
Polyoxyethylene glyceryl isostearate 0.3
Titanium oxide Bengala-coated mica 0.3
Mica titanium 0.3
Potassium hydroxide 0.2
Sodium hexametaphosphate 0.05
Tocopherol acetate 0.1
Methylparaben 0.1
Butylparaben 0.01
Phenoxyethanol 0.3
Lithium cobalt titanate Appropriate amount of porous spherical cellulose powder 0.5
Polyethylene glycol (MW = 1 million) 0.2
Carboxyvinyl polymer 0.2
Acrylic acid / alkyl methacrylate copolymer 0.2
Purified water residue

Claims (4)

A composition for external use on skin, comprising one or more water-soluble polymers and 2-ethyl-1,3-hexanediol. 2. The skin external application according to claim 1, wherein the water-soluble polymer is a plant-derived natural polymer, a microorganism-derived natural polymer, a cellulose semi-synthetic polymer, a starch semi-synthetic polymer, or a vinyl synthetic polymer. Composition. The external composition for skin according to claim 1 or 2, wherein the content of the water-soluble polymer in the external composition for skin is 0.001 to 5.0 mass%. The skin external composition according to claim 1 or 2, wherein the content of 2-ethyl-1,3-hexanediol in the skin external composition is 0.001 to 5.0 mass%. Composition for external use.