JP2006000728A - Method for preparing ballast water and apparatus for preparing ballast water to be loaded onto vessel - Google Patents

Method for preparing ballast water and apparatus for preparing ballast water to be loaded onto vessel Download PDF

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JP2006000728A
JP2006000728A JP2004178351A JP2004178351A JP2006000728A JP 2006000728 A JP2006000728 A JP 2006000728A JP 2004178351 A JP2004178351 A JP 2004178351A JP 2004178351 A JP2004178351 A JP 2004178351A JP 2006000728 A JP2006000728 A JP 2006000728A
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seawater
ballast water
ballast
membrane
tank
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Hiroya Honda
博也 本田
Kakichi Ito
嘉吉 伊藤
Tatsumi Shimono
達観 下野
Yoji Akitani
鷹二 秋谷
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ZOUSUI SOKUSHIN CENTER
ZOUSUI SOKUSHIN CT
Organo Corp
Mitsubishi Rayon Co Ltd
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ZOUSUI SOKUSHIN CENTER
ZOUSUI SOKUSHIN CT
Organo Corp
Mitsubishi Rayon Co Ltd
Japan Organo Co Ltd
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<P>PROBLEM TO BE SOLVED: To provide a method for efficiently preparing such ballast water that a microbe which does not live originally in a specified sea area is not brought in the specified sea area and the marine environment is not damaged even when a large quantity of such ballast water is discharged from a ship, and to provide an apparatus for preparing ballast water to be loaded onto a vessel. <P>SOLUTION: This method for preparing ballast water comprises a microbe removing step of removing the microbe in the seawater loaded onto the vessel by making the seawater pass through a microbe filtering membrane on board and a backwashing step of backwashing the microbe filtering membrane. A filtrate obtained at the microbe removing step is used as ballast water. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、船舶の航行時における重心安定のために積載する海洋環境に悪影響を与えないバラスト水(以下、単に「バラスト水」とも言う。)の製造方法及び船舶搭載バラスト水製造装置に関する。   The present invention relates to a method for manufacturing ballast water (hereinafter also simply referred to as “ballast water”) and a ship-mounted ballast water manufacturing apparatus that do not adversely affect the marine environment to be loaded for the purpose of stabilizing the center of gravity during navigation of the ship.

原油タンカー、鉱石運搬船、自動車運搬船等は空荷や積載貨物量が少ない状態で航行する場合がある。その際、船体が浮力により浮き上がり、スクリューや方向舵が水面下に没しなかったり、水面上の船体が風の影響を大きく受けて操縦性が損なわれ航行上極めて危険な状態となる。このため、通常の船舶は航行時の浮力を調整するため、通常載荷重量の30〜40重量%のバラスト水を積載する。   Crude oil tankers, ore carriers, car carriers, etc. may sail with low or no cargo. At that time, the hull is lifted by buoyancy, and the screw and rudder are not submerged under the surface of the water, or the hull on the surface of the water is greatly affected by the wind and the maneuverability is impaired, making it extremely dangerous. For this reason, in order to adjust the buoyancy at the time of navigation, a normal ship carries a ballast water of 30 to 40% by weight of the normal load.

例えば、原油タンカーによる輸送は産油国と消費国の往復となり、消費国から産油国への航行では積荷がなく、消費国で船舶内の油槽に停泊区域の海水等を積載してバラスト水としている。一方、バラスト水を積んだ船舶は産油国の近海、あるいは港湾でバラスト水を排出して、原油を再度積載している。   For example, transportation by crude oil tankers is a round trip between oil-producing countries and consuming countries, and there is no cargo when navigating from consuming countries to oil-producing countries. . On the other hand, a ship loaded with ballast water discharges the ballast water in the sea near the oil-producing country or at a port and reloads with crude oil.

近年、船舶から排出されるバラスト水により特定海域に本来生息しない微生物が持ち込まれ、これに起因して海洋生態系の破壊が生じ、当該水域住民の生活に重大な被害を与えるだけではなく、全世界的な海洋環境の破壊が生じており、深刻な国際問題となっている。このため、バラスト水中の微生物除去を目的として、国際的な規模で各種の方法が検討されている。   In recent years, ballast water discharged from ships has brought in microorganisms that do not inherently live in specific waters, which has resulted in the destruction of marine ecosystems, not only causing serious damage to the lives of those waters. The destruction of the global marine environment has occurred and has become a serious international problem. For this reason, various methods have been studied on an international scale for the purpose of removing microorganisms in the ballast water.

バラスト水として汲み込まれる海水中の微生物を除去する方法としては、例えば海水を加熱して微生物を死滅させる方法(特開2003−181443号公報)、海水に紫外線を照射して微生物を不活性化させる方法(特表2000−515803号公報、特開平11−265684号公報)、海水を電解装置に通して死滅させる方法(特開2003−334563号公報)、ヨウ素で処理する方法(特表2002−504851号公報)及び次亜塩素酸で処理する方法(特開平04−322788号公報)等が提案されている。
特開2003−181443号公報(特許請求の範囲) 特表2000−515803号公報(特許請求の範囲) 特開平11−265684号公報(特許請求の範囲) 特開2003−334563号公報(特許請求の範囲) 特表2002−504851号公報(特許請求の範囲) 特開平04−322788号公報(特許請求の範囲) 特開平2003−154360号公報(特許請求の範囲)
As a method for removing microorganisms in seawater pumped as ballast water, for example, a method of killing microorganisms by heating seawater (Japanese Patent Laid-Open No. 2003-181443), inactivating the microorganisms by irradiating the seawater with ultraviolet rays (Japanese Unexamined Patent Publication No. 2000-515803, Japanese Unexamined Patent Publication No. 11-265684), a method of killing seawater through an electrolyzer (Japanese Unexamined Patent Publication No. 2003-334563), a method of treating with iodine (Special Table 2002) No. 504851) and a method of treating with hypochlorous acid (Japanese Patent Laid-Open No. 04-322788) have been proposed.
JP 2003-181443 A (Claims) JP 2000-515803 A (Claims) JP 11-265684 A (Claims) JP 2003-334563 A (Claims) Japanese translation of PCT publication No. 2002-504851 (Claims) JP 04-322788 A (Claims) JP 2003-154360 A (Claims)

しかしながら、海水を加熱する方法は、加熱エネルギーの調達手段によっては経済的ではなく、また微生物を完全に死滅させるのが困難である。また、海水に紫外線を照射する方法は、全ての微生物を死滅又は不活性化させるために要する電力が膨大であり、また高流量の海水を処理するには多数のUV装置を並列に設置しなければない等装置の設置コストを高騰させる。また、海水を電解装置に通し電解で生成する塩素イオンの殺菌効果で微生物を死滅させる方法は、微生物の中には塩素イオンで死滅しないものも存在し、全ての微生物を死滅させることができない。また、海水をヨウ素や次亜塩素酸等の薬剤で処理する方法は、微生物の種類によっては死滅させるのに高濃度の薬剤が必要となり、処理後の海水の中和に多大の中和剤を使用せざるを得ない。   However, the method of heating seawater is not economical depending on the heating energy procurement means, and it is difficult to completely kill microorganisms. In addition, the method of irradiating seawater with ultraviolet rays requires a huge amount of power to kill or inactivate all the microorganisms, and in order to process high-flow seawater, many UV devices must be installed in parallel. Increase the cost of installing the equipment. Further, in the method of killing microorganisms by the bactericidal effect of chlorine ions generated by electrolysis by passing seawater through an electrolyzer, some microorganisms are not killed by chlorine ions, and all microorganisms cannot be killed. In addition, the method of treating seawater with chemicals such as iodine and hypochlorous acid requires a high concentration of chemicals to be killed depending on the type of microorganisms. It must be used.

海水中の微生物を死滅させる方法は、前述の如く、微生物の死滅に完全を期し難く、また屍骸による汚染が生態系に与える影響も懸念されている。更に死滅せずに残留した少量の微生物が輸送中に増殖することから、これらの微生物を完全に除去する方法の開発が切望されている。また、海水を濾過膜に通すことで海水中の微生物を除去する方法も知られているが(特開2003−154360号公報)、この方法で得られる膜濾過水は魚介類の洗浄等に使用されるものであって、船舶のバラスト水に使用するものではない。また、大量の海水を濾過膜により処理するには、通常、濾過面積を大きくするか、あるいは長期間を要することから効率的ではなく、従来海水を濾過膜で大量に処理することなどあり得ないことであった。   As described above, the method of killing microorganisms in seawater is difficult to completely kill microorganisms, and there is a concern about the influence of contamination by carcasses on the ecosystem. Furthermore, since a small amount of microorganisms remaining without being killed grow during transportation, development of a method for completely removing these microorganisms is eagerly desired. Moreover, although the method of removing the microbe in seawater by letting seawater pass through a filtration membrane (Unexamined-Japanese-Patent No. 2003-154360), the membrane filtration water obtained by this method is used for the washing | cleaning of seafood, etc. It is not intended for use in ship ballast water. Moreover, in order to process a large amount of seawater with a filtration membrane, it is usually not efficient because the filtration area is increased or a long period of time is required. Conventionally, a large amount of seawater cannot be treated with a filtration membrane. Was that.

従って、本発明の目的は、船舶から排出される大量のバラスト水により特定海域に本来生息しない微生物が持ち込まれることがなく、更に海洋環境を破壊することもないバラスト水の効率的な製造方法及び船舶搭載バラスト水製造装置を提供することにある。   Accordingly, an object of the present invention is to provide an efficient method for producing ballast water that does not bring in microorganisms that do not naturally inhabit a specific sea area due to a large amount of ballast water discharged from a ship, and that does not destroy the marine environment, and The object is to provide a ship-mounted ballast water production apparatus.

かかる実情において、本発明者らは鋭意検討を行った結果、船舶に積載された海水を船舶上で微生物濾過膜に通すことにより海水中の微生物を除去する微生物除去工程と、逆洗により微生物濾過膜を洗浄する逆洗工程を有し、該微生物除去工程で得られる膜濾過水をバラスト水として用いれば、大量の海水であっても、航行中に濾過膜で処理できること、汲み上げられた海水は、船舶が停泊する港湾域の海水であり、濾過膜を汚染する油分を比較的多く含むが、油分を濾過膜で処理する前に予め除去しておけば、濾過膜の処理効率が向上すること等を見出し、本発明を完成するに至った。   In such a situation, the present inventors have conducted intensive studies, and as a result, removed the microorganisms in the seawater by passing the seawater loaded on the ship through the microorganism filtration membrane on the ship, and microbial filtration by backwashing. If the membrane filtered water obtained in the microorganism removing step is used as ballast water, it can be treated with a filtered membrane during navigation, and the pumped seawater The seawater in the harbor area where the ship is anchored and contains a relatively large amount of oil that contaminates the filter membrane, but if the oil is removed in advance before it is processed with the filter membrane, the processing efficiency of the filter membrane is improved. As a result, the present invention has been completed.

すなわち、本発明(1)は、船舶に積載された海水を船舶上で微生物濾過膜に通すことにより海水中の微生物を除去する微生物除去工程と、逆洗により微生物濾過膜を洗浄する逆洗工程を有し、該微生物除去工程で得られる膜濾過水をバラスト水として用いるバラスト水の製造方法を提供するものである。   That is, the present invention (1) includes a microbial removal step of removing microorganisms in seawater by passing seawater loaded on the vessel through the microbial filtration membrane on the vessel, and a backwashing step of washing the microbial filtration membrane by backwashing. And a method for producing ballast water using membrane filtered water obtained in the microorganism removing step as ballast water.

また、本発明(2)は、前記海水は船舶内の複数のバラスト水槽にそれぞれ積載されたものであって、微生物除去工程は、一のバラスト水槽の海水を微生物濾過膜に通し、得られた膜透過水を該一のバラスト水槽に戻す循環処理であって、これを他のバラスト水槽の海水についても順次行う前記バラスト水の製造方法を提供するものである。   In the present invention (2), the seawater is respectively loaded in a plurality of ballast tanks in a ship, and the microorganism removal step is obtained by passing the seawater of one ballast tank through a microorganism filtration membrane. A circulation process for returning membrane permeated water to the one ballast water tank, which is also performed for seawater in other ballast water tanks in order.

また、本発明(3)は、前記海水は船舶内の複数のバラスト水槽の中、1つを空き水槽とし、他のバラスト水槽に積載されたものであって、微生物除去工程は、一のバラスト水槽の海水を微生物濾過膜に通し、得られた膜透過水を該空き水槽に供給するワンパス処理を行い、次いで他のバラスト水槽の海水を微生物濾過膜に通し、得られた膜透過水を空き水槽となった該一のバラスト水槽に供給するワンパス処理を行い、該ワンパス処理を順次行う前記バラスト水の製造方法を提供するものである。   In the present invention (3), the seawater is one of a plurality of ballast tanks in a ship, one of which is an empty tank, and is loaded in another ballast tank. Perform one-pass processing to pass the seawater in the aquarium through the microbial filtration membrane and supply the obtained membrane permeated water to the empty water tank, then pass the seawater in the other ballast water tank through the microbial filtration membrane, and empty the obtained membrane permeated water The present invention provides a method for producing the ballast water, in which the one-pass treatment to be supplied to the one ballast water tank that has become a water tank is performed, and the one-pass treatment is sequentially performed.

また、本発明(4)は、前記微生物濾過膜で処理する前に予め、少なくとも海水中の油分を除去する前記バラスト水の製造方法を提供するものである。   Moreover, this invention (4) provides the manufacturing method of the said ballast water which removes the oil component in seawater at least before processing with the said microorganisms filtration membrane.

また、本発明(5)は、前記微生物濾過膜が中空糸膜である前記バラスト水の製造方法を提供するものである。   Moreover, this invention (5) provides the manufacturing method of the said ballast water whose said microorganisms filtration membrane is a hollow fiber membrane.

また、本発明(6)は、前記海水中の油分を、疎水性吸着材で吸着除去する前記バラスト水の製造方法を提供するものである。   Moreover, this invention (6) provides the manufacturing method of the said ballast water which adsorbs and removes the oil component in the said seawater with a hydrophobic adsorbent.

また、本発明(7)は、汲み上げられた海水を積載する複数のバラスト水槽と、該バラスト水槽に貯留された海水中の微生物を除去する微生物濾過膜装置と、該微生物濾過膜装置で得られる膜濾過水を貯留する逆洗用タンクと、それぞれのバラスト水槽と該微生物濾過膜装置を接続する海水供給管と、該逆洗用タンクと該それぞれのバラスト水槽を接続する膜濾過水供給管を備えることを特徴とする船舶搭載バラスト水製造装置を提供するものである。   In addition, the present invention (7) is obtained by a plurality of ballast water tanks loaded with pumped seawater, a microbial filtration membrane apparatus for removing microorganisms in seawater stored in the ballast water tank, and the microbial filtration membrane apparatus. A tank for backwashing that stores membrane filtrate, a seawater supply pipe for connecting each ballast water tank and the microorganism filtration membrane device, and a membrane filtrate water supply pipe for connecting the backwash tank and each ballast water tank. Provided is a ship-mounted ballast water production apparatus characterized by comprising.

また、本発明(8)は、前記微生物濾過膜装置の前段で且つバラスト水槽の後段に、少なくとも海水中の油分を除去する油分吸着除去装置を設置する前記船舶搭載バラスト水製造装置を提供するものである。   Moreover, this invention (8) provides the said ship mounted ballast water manufacturing apparatus which installs the oil content adsorption removal apparatus which removes the oil content in seawater at the front | former stage of the said microorganisms filtration membrane apparatus and the back | latter stage of a ballast water tank. It is.

また、本発明(9)は、前記微生物濾過膜装置が、浸漬型中空糸膜装置又は加圧型中空糸膜装置である前記船舶搭載バラスト水製造装置を提供するものである。   Moreover, this invention (9) provides the said ship mounted ballast water manufacturing apparatus whose said microbe filtration membrane apparatus is an immersion type hollow fiber membrane apparatus or a pressurization type hollow fiber membrane apparatus.

本発明によれば、バラスト水として使用される大量の海水を、船舶の航行中に微生物濾過膜で効果的に処理できるため、船舶から排出されるバラスト水により特定海域に本来生息しない微生物が持ち込まれることはなく、更に海洋環境を破壊することもない。また、油分を比較的多く含む海水であっても、これらは微生物濾過膜で処理する前に予め除去されるため、微生物濾過膜が汚染されることがなく、長期間安定して処理することができる。   According to the present invention, since a large amount of seawater used as ballast water can be effectively treated with a microbial filtration membrane during navigation of the ship, microorganisms that do not originally inhabit the specific sea area are brought in by the ballast water discharged from the ship. And will not destroy the marine environment. In addition, even seawater containing a relatively large amount of oil is removed in advance before being treated with the microbial filtration membrane, so that the microbial filtration membrane is not contaminated and can be treated stably for a long period of time. it can.

本発明のバラスト水の製造方法において、船舶に積載される海水としては、特に制限されないが、通常船舶が停泊する港湾域の海水であり、該海水には、微生物の他、通常油分が0.05〜1.0%含まれ、濁度が1〜100度である。また、海水中の微生物のうち、特に国際的に問題とされる微生物としては、大腸菌群、コレラ菌、腸球菌、ミジンコの幼生、北太平洋ヒトデの幼生、アジア昆布の幼生、ゼブラ貝の幼生及び毒性藻類等が挙げられ、これらの微生物の大きさはほとんどが数μmであり、最も小さいもので0.3〜0.5μmである。   In the method for producing ballast water according to the present invention, the seawater loaded on the ship is not particularly limited, but is usually seawater in a port area where the ship is anchored. It is contained by 0.5 to 1.0%, and the turbidity is 1 to 100 degrees. In addition, among the microorganisms in seawater, microorganisms of particular international concern include coliforms, cholera, enterococci, daphnia larvae, North Pacific starfish larvae, Asian kelp larvae, zebra larvae larvae and Toxic algae and the like can be mentioned, and the size of these microorganisms is mostly several μm, and the smallest is 0.3 to 0.5 μm.

本発明のバラスト水は船舶上で製造される。これにより大量の海水を、船舶の航行中に微生物濾過膜で効果的に処理することができ、船舶から排出されるバラスト水により特定海域に本来生息しない微生物が持ち込まれることがない。本発明における微生物除去工程は、船舶に積載された海水を微生物濾過膜に通すことにより海水中の微生物を除去する工程である。   The ballast water of the present invention is manufactured on a ship. As a result, a large amount of seawater can be effectively treated with the microorganism filtration membrane during the navigation of the ship, and microorganisms that do not originally live in the specific sea area are not brought in by the ballast water discharged from the ship. The microorganism removing step in the present invention is a step of removing microorganisms in seawater by passing seawater loaded on a ship through a microorganism filtration membrane.

次に、本発明のバラスト水の製造方法の一例を図1及び図2を参照して説明する。図1はタンカーのダブルハル構造を示し、(A)は船体の船首船尾方向に直交する方向に沿って切断した模式断面図、(B)は船体の船首船尾方向に沿って切断した模式断面図である。図2は本例のバラスト水の製造方法を実施する装置のフロー図である。海水は、例えば図1に示すようなダブルハル構造における複数の室に分割されたバラスト水槽2に積載される。すなわち、図1中、船舶1は内側の槽が原油槽3であり、外側の槽がバラスト水槽2である。バラスト水槽2は本例では、船舶の幅方向に2分割、船舶の長さ方向に3分割された都合6つのバラスト水槽11〜16を有する。   Next, an example of the manufacturing method of the ballast water of this invention is demonstrated with reference to FIG.1 and FIG.2. FIG. 1 shows a double hull structure of a tanker, (A) is a schematic cross-sectional view cut along a direction orthogonal to the bow stern direction of the hull, and (B) is a schematic cross-sectional view cut along the bow stern direction of the hull. is there. FIG. 2 is a flow diagram of an apparatus for carrying out the method for producing ballast water of this example. Seawater is loaded on a ballast water tank 2 divided into a plurality of chambers in a double hull structure as shown in FIG. 1, for example. That is, in FIG. 1, in the ship 1, the inner tank is the crude oil tank 3, and the outer tank is the ballast water tank 2. In this example, the ballast tank 2 has six ballast tanks 11 to 16 which are divided into two in the width direction of the ship and into three in the length direction of the ship.

図2中、船舶搭載バラスト水の製造装置10は、装置全体が船舶上に搭載されるものであって、汲み上げられた海水を積載する複数のバラスト水槽2(11〜16)と、バラスト水槽2に貯留された海水中の微生物を除去する微生物濾過膜装置4と、微生物濾過膜装置4で得られる膜濾過水が流入する逆洗用タンク6と、それぞれのバラスト水槽11〜16と微生物濾過膜装置4の海水流入配管28を接続する海水供給管21〜26と、逆洗用タンク6の膜濾過水流出配管38とそれぞれのバラスト水槽11〜16を接続する膜濾過水供給管31〜36を備え、必要に応じて微生物濾過膜装置4の前段に、海水中の油分を除去する油分吸着除去装置5を備える。また、油分吸着除去装置5の後段で且つ微生物濾過膜装置4の前段に、必要に応じて不図示の除濁装置を設置することができる。また、本発明の製造装置の関連設備としては、バラスト水槽2に貯留された海水を微生物濾過膜装置4に供給する送液ポンプなどがある。   In FIG. 2, the ship-mounted ballast water manufacturing apparatus 10 is mounted on the ship as a whole, and includes a plurality of ballast water tanks 2 (11 to 16) for loading the pumped seawater, and the ballast water tank 2. Microbial filtration membrane device 4 for removing microorganisms in seawater stored in the tank, a backwash tank 6 into which membrane filtrate obtained by the microbial filtration membrane device 4 flows, ballast water tanks 11 to 16 and a microbial filtration membrane. The seawater supply pipes 21 to 26 for connecting the seawater inflow pipe 28 of the device 4, the membrane filtered water outflow pipe 38 of the backwash tank 6, and the membrane filtrate water supply pipes 31 to 36 for connecting the respective ballast water tanks 11 to 16 are provided. The oil adsorption removal apparatus 5 which removes the oil component in seawater is provided in the front | former stage of the microorganisms filtration membrane apparatus 4 as needed. In addition, a turbidity device (not shown) can be installed in the subsequent stage of the oil content adsorption removing apparatus 5 and in the upstream stage of the microorganism filtration membrane apparatus 4 as necessary. Moreover, as a related facility of the manufacturing apparatus of this invention, there exists a liquid feed pump etc. which supply the seawater stored in the ballast water tank 2 to the microorganisms filtration membrane apparatus 4.

船舶搭載バラスト水の製造装置10を使用して海水中の微生物を除去する方法としては、バラスト水槽毎に微生物除去工程を実施する循環処理方法、あるいは空きバラスト水槽を利用するワンパス処理方法が挙げられる。これらは、図2中のバルブを適宜操作することで実施することができる。   Examples of the method for removing the microorganisms in the seawater using the ship-mounted ballast water manufacturing apparatus 10 include a circulation processing method in which a microorganism removal step is performed for each ballast water tank, or a one-pass processing method using an empty ballast water tank. . These can be implemented by appropriately operating the valve in FIG.

循環処理方法の一例を次に示す。先ずバラスト水槽11の海水を単独で処理する。すなわちバラスト水槽11の海水を微生物濾過膜に通し、得られた膜透過水をバラスト水槽11に戻すことにより循環処理する。次いでバラスト水槽12の海水を単独で処理する。すなわちバラスト水槽12の海水を微生物濾過膜に通し、得られた膜透過水をバラスト水槽12に戻すことにより循環処理する。これを他のバラスト水槽13〜16についても順次行う。なお、バラスト水槽11〜16中、海水供給管の海水取水口と、膜濾過水供給管の膜濾過水流出口はできるだけ離すことが好ましい。   An example of the circulation processing method is shown below. First, the seawater in the ballast tank 11 is treated alone. That is, the seawater of the ballast water tank 11 is passed through the microorganism filtration membrane, and the obtained membrane permeated water is returned to the ballast water tank 11 for circulation treatment. Next, the seawater in the ballast tank 12 is treated alone. That is, the seawater in the ballast water tank 12 is passed through the microorganism filtration membrane, and the obtained membrane permeated water is returned to the ballast water tank 12 for circulation treatment. This is sequentially performed for the other ballast water tanks 13-16. In addition, in the ballast water tanks 11 to 16, it is preferable that the seawater intake port of the seawater supply pipe and the membrane filtrate water outlet of the membrane filtrate supply pipe be separated as much as possible.

ワンパス処理方法の一例を次に示す。海水は船舶内の複数のバラスト水槽2の中、1つを空きバラスト水槽とし、他のバラスト水槽に積載する。この場合、空きバラスト水槽が膜濾過水の貯留槽となる。例えば、バラスト水槽11〜15に海水を積載し、バラスト水槽16を空きバラスト水槽とする。バラスト水槽11の海水を微生物濾過膜に通し、得られた膜透過水を空きバラスト水槽16に供給するワンパス処理を行い、次いでバラスト水槽12の海水を微生物濾過膜に通し、得られた膜透過水を空きバラスト水槽11に供給するワンパス処理を行い、該ワンパス処理を順次行う。これにより、微生物除去工程終了後は、複数のバラスト水槽の中、1つの空きバラスト水槽以外のバラスト水槽には膜濾過水が貯留されることになる。なお、膜濾過水が貯留されたバラスト水槽の配置は、船体の重心を安定に保つ位置関係にあることが好ましい。また、微生物除去工程後、バラスト水槽の底部に残存する海水のひき残し分は、次亜塩素酸など薬剤の添加や加熱処理など公知の殺菌処理が行われてもよい。この場合、この海水のひき残し分は比較的少量であるため、殺菌剤の使用量も少量でよく、また加熱に伴う消費エネルギーも少ない。   An example of the one-pass processing method is as follows. Seawater is loaded into another ballast water tank, one of which is an empty ballast tank among the plurality of ballast tanks 2 in the ship. In this case, the empty ballast water tank serves as a membrane filtrate water storage tank. For example, seawater is loaded on the ballast tanks 11 to 15 and the ballast tank 16 is an empty ballast tank. A one-pass process is performed in which the seawater in the ballast water tank 11 is passed through the microbial filtration membrane and the obtained membrane permeated water is supplied to the empty ballast water tank 16, and then the seawater in the ballast water tank 12 is passed through the microbial filtration membrane. Is supplied to the empty ballast water tank 11, and the one-pass processing is sequentially performed. Thereby, after completion | finish of a microorganism removal process, membrane filtration water will be stored in ballast water tanks other than one empty ballast water tank among several ballast water tanks. In addition, it is preferable that the arrangement | positioning of the ballast water tank in which membrane filtered water was stored has the positional relationship which keeps the gravity center of a ship body stable. Further, after the microorganism removal step, the remaining portion of the seawater remaining at the bottom of the ballast water tank may be subjected to a known sterilization treatment such as addition of a chemical such as hypochlorous acid or a heat treatment. In this case, since the remaining amount of the seawater is relatively small, the amount of the disinfectant used may be small, and the energy consumed by heating is small.

微生物濾過膜の形状としては、中空糸膜、平膜、管状膜が挙げられる。このうち、中空糸膜が、単位容量当りの濾過面積を最も大とすることができる点で好ましい。   Examples of the shape of the microorganism filtration membrane include a hollow fiber membrane, a flat membrane, and a tubular membrane. Among these, the hollow fiber membrane is preferable in that the filtration area per unit volume can be maximized.

中空糸膜は、中空構造を有し、更に該中空構造を形成する孔に連通して、膜面の該孔に連通する細孔を多数形成したものであり、外圧式と内圧式とがある。本発明において、微生物濾過膜として精密濾過膜を用いる場合、中空糸膜の細孔の径としては、0.01〜0.4μm、好ましくは0.01〜0.3μmである。また、限外濾過膜を用いる場合は、中空糸膜の細孔の径としては、0.002〜0.01μmである。海水中に生息する細菌や幼生等の微生物の大きさは通常数μm、最小のものでも0.3〜0.5μm程度であり、従って、上記細孔径の中空糸膜を使用すれば、海水中のこれらの細菌、幼生等の微生物をほぼ完全に除去することができる。また、膜面に付着した微生物を除去して、その濾過能力を回復するために逆洗を行うが、本逆洗とは別に、濾過中に膜面の外側から気泡でバブリングして膜面に付着した微生物を剥離除去する操作ができる点で外圧式中空糸膜を使用することが好ましい。   The hollow fiber membrane has a hollow structure, and further has a plurality of pores communicating with the holes forming the hollow structure and communicating with the holes on the membrane surface, and there are an external pressure type and an internal pressure type. . In the present invention, when a microfiltration membrane is used as the microorganism filtration membrane, the pore diameter of the hollow fiber membrane is 0.01 to 0.4 μm, preferably 0.01 to 0.3 μm. Moreover, when using an ultrafiltration membrane, it is 0.002-0.01 micrometer as a diameter of the pore of a hollow fiber membrane. The size of microorganisms such as bacteria and larvae inhabiting seawater is usually several μm, and the smallest is about 0.3 to 0.5 μm. Therefore, if a hollow fiber membrane having the above pore diameter is used, These microorganisms such as bacteria and larvae can be almost completely removed. In addition, backwashing is performed to remove microorganisms adhering to the membrane surface and restore its filtration ability, but separately from this backwashing, bubbles are bubbled from the outside of the membrane surface during filtration to the membrane surface. It is preferable to use an external pressure type hollow fiber membrane in that an operation of peeling and removing attached microorganisms can be performed.

また、中空糸膜は浸漬型中空糸膜装置又は加圧型中空糸膜装置として使用される。浸漬型中空糸膜装置を用いる方法は、海水貯槽中に浸漬された該装置の該中空糸の内側をヘッド差又は吸引ポンプによる吸引等で通水し、海水中の微生物を除去する方法である。また、浸漬型中空糸膜装置及び加圧型中空糸膜装置ともに、前述した通り、中空糸膜の下方から微細な気泡を発生させて、中空糸膜に付着した微生物を適宜剥離させながら、膜の表面を洗浄しつつ濾過することができる。   The hollow fiber membrane is used as an immersion type hollow fiber membrane device or a pressure type hollow fiber membrane device. The method using the submerged hollow fiber membrane device is a method of removing microorganisms in the seawater by passing the inside of the hollow fiber of the device immersed in the seawater storage tank by a head difference or suction by a suction pump or the like. . In addition, as described above, both the immersion type hollow fiber membrane device and the pressure type hollow fiber membrane device generate fine bubbles from below the hollow fiber membrane, and appropriately remove the microorganisms adhering to the hollow fiber membrane. It can be filtered while washing the surface.

本発明で使用する精密濾過膜の素材としては、ポリエチレン、ポリプロピレン、ポリスルホン、ポリ塩化ビニリデン、ポリフッ化ビニリデン、塩素化ポリエチレン、塩素化ポリプロピレン、ポリアクリロニトリル、酢酸セルロースなどが挙げられる。   Examples of the material for the microfiltration membrane used in the present invention include polyethylene, polypropylene, polysulfone, polyvinylidene chloride, polyvinylidene fluoride, chlorinated polyethylene, chlorinated polypropylene, polyacrylonitrile, and cellulose acetate.

海水を微生物濾過膜に通す方法としては、特に制限されないが、微生物濾過膜を組み込んだ微生物濾過膜装置の2基以上を並列配置するようにしてもよい。この場合、一の微生物濾過膜装置が逆洗工程であっても、他の微生物濾過膜装置は微生物除去工程を実施することができ、多量の膜濾過水を連続して得ることができる。   The method for passing seawater through the microbial filtration membrane is not particularly limited, but two or more microbial filtration membrane devices incorporating the microbial filtration membrane may be arranged in parallel. In this case, even if one microbial filtration membrane device is in the backwashing step, the other microbial filtration membrane device can perform the microbial removal step, and a large amount of membrane filtered water can be obtained continuously.

バラスト水の製造方法の逆洗工程は、逆洗により微生物濾過膜を洗浄する工程である。微生物除去工程において、時間が経過するにつれ、膜の目詰まりの原因物質となる微生物等が微生物濾過膜に付着して膜の入口と出口で膜差圧が上昇してくる。このため、海水の濾過を停止し、膜濾過水を洗浄水として微生物濾過膜を逆洗する。逆洗工程を行うことにより、微生物濾過膜の濾過機能が回復する。そして、逆洗工程を終えると、再度微生物除去工程に移り、これを繰り返し行うことで、長期間に亘る濾過を可能にする。なお、逆洗により生成する微生物濃縮液は、次亜塩素酸など薬剤の添加や加熱処理など公知の殺菌処理が行われれる。この微生物濃縮液は比較的少量であるため、殺菌剤の使用量も少量でよく、また加熱に伴う消費エネルギーも少ない。   The backwashing step of the ballast water production method is a step of washing the microbial filtration membrane by backwashing. In the microorganism removal process, as time elapses, microorganisms or the like that cause clogging of the membrane adhere to the microorganism filtration membrane, and the membrane differential pressure rises at the inlet and outlet of the membrane. For this reason, the filtration of seawater is stopped, and the microbial filtration membrane is back-washed using the membrane filtrate as washing water. By performing the backwashing step, the filtration function of the microorganism filtration membrane is restored. And when the backwashing process is completed, it moves to a microorganism removal process again, and filtration over a long period of time is enabled by performing this repeatedly. Note that the microbial concentrate produced by backwashing is subjected to known sterilization treatments such as addition of chemicals such as hypochlorous acid and heat treatment. Since this microbial concentrate is relatively small, the amount of the bactericide used may be small, and the energy consumed by heating is small.

本発明のバラスト水の製造方法において、微生物濾過膜で処理する前に予め、海水中の油分を除去することが、微生物濾過膜の目詰まりを防止し、濾過能力の低下を防止することができる点で好ましい。すなわち、海水中の油分も微生物濾過膜で捕捉されるが、微生物や他の濁質と異なり、油分は膜面に付着すると前記のバブリングや逆洗工程では容易に除去することができず、微生物濾過膜を目詰まりさせ、濾過能力の低下の原因となる。   In the method for producing ballast water of the present invention, removing oil in seawater in advance before treating with a microbial filtration membrane can prevent clogging of the microbial filtration membrane and prevent a reduction in filtration capacity. This is preferable. That is, oil in seawater is also captured by the microbial filtration membrane, but unlike microorganisms and other turbid substances, if the oil adheres to the membrane surface, it cannot be easily removed by the above bubbling or backwashing process, It clogs the filtration membrane and causes a reduction in filtration capacity.

海水の油分を除去する方法としては、特に制限されず、公知の油水分離装置を用いることができる。油水分離装置は、疎水性吸着材を用いたものが、簡易な方法で且つ高い油分吸着能力を示すので好ましい。疎水性吸着材としては、親油性のポリエチレンやポリプロピレン等の素材で作製された不織布フィルター、粉体物、及び中空糸膜が挙げられる。具体的には、油分吸着材「ダイヤマルス(商標登録)」を使用すると、極めて効率よく油分を除去することができる。海水の油分の除去工程により、例えば油分0.05〜1.0%の海水は、油分0.005〜0.02%の海水とすることができる。   The method for removing oil from seawater is not particularly limited, and a known oil / water separator can be used. As the oil / water separator, a device using a hydrophobic adsorbent is preferable because it is a simple method and exhibits a high oil adsorption capability. Examples of the hydrophobic adsorbent include a non-woven filter made of a material such as lipophilic polyethylene or polypropylene, a powder, and a hollow fiber membrane. Specifically, when the oil adsorbent “Diamarus (registered trademark)” is used, the oil can be removed extremely efficiently. For example, seawater having an oil content of 0.05 to 1.0% can be converted to seawater having an oil content of 0.005 to 0.02% by the oil removal process of seawater.

海水中の油分を除去することは微生物濾過膜の汚染防止において必要であるが、微生物濾過膜における微生物除去の負荷を低減させるために海水中の濁質を予め除去することが好ましい。海水中の濁質を除去する方法としては、特に制限されず、公知の除濁装置を用いることができる。除濁装置としては、砂濾過装置、ポリエチレンやポリプロピレン製の不織布濾過布を備えた装置、濾過槽体中に立設された繊維の束に濁質を吸着させる長繊維束除濁装置等が挙げられる。油分吸着材「ダイヤマルス(商標登録)」を使用すると油分の除去と濁質を共に除去することができる点で好ましい。   Removal of oil in seawater is necessary to prevent contamination of the microbial filtration membrane, but it is preferable to remove turbidity in seawater in advance in order to reduce the load of microbial removal on the microbial filtration membrane. It does not restrict | limit especially as a method of removing the turbidity in seawater, A well-known turbidity removal apparatus can be used. Examples of the turbidity removal device include a sand filtration device, a device provided with a nonwoven fabric filter cloth made of polyethylene or polypropylene, a long fiber bundle turbidity removal device that adsorbs turbidity to a bundle of fibers erected in a filtration tank body, and the like. It is done. Use of an oil adsorbent “Diamarus (registered trademark)” is preferred in that both oil removal and turbidity can be removed.

実験例1
実際の船舶を使用することなく、図3に示した陸上設置の実験用バラスト水製造装置を用いて行った。すなわち、船舶が停泊する国内のA港湾域の海水(以下「原海水」と言う。)を実験用バラスト水製造装置の原海水タンクに汲み上げ、この海水を下記の運転条件で処理した。原海水及び処理水(膜濾過水)の大腸菌群を下記測定方法により測定した。なお、原海水の油分はn−ヘキサン抽出物として8mg/l、原海水の濁度は5度であった。
Experimental example 1
The actual ballast water production apparatus installed on land shown in FIG. 3 was used without using an actual ship. That is, seawater (hereinafter referred to as “raw seawater”) in port A in Japan where the ship is anchored was pumped into the raw seawater tank of the experimental ballast water production apparatus, and this seawater was treated under the following operating conditions. The coliforms of raw seawater and treated water (membrane filtered water) were measured by the following measuring method. The oil content of the raw seawater was 8 mg / l as an n-hexane extract, and the turbidity of the raw seawater was 5 degrees.

(実験用バラスト水製造装置)
図3に示す装置を用いた。実験用バラスト水製造装置20は中空糸膜型微生物濾過装置4aを主体とするもので、処理槽8に処理能力3m/時の精密濾過膜からなる中空糸膜モジュール7「ステラポアSUR31534」(三菱レイヨン製)を浸漬したものを用いた。また、原海水タンク11aと中空糸膜型微生物濾過装置4a間は配管21(28)で接続し、中空糸膜型微生物濾過装置4aと逆洗タンク6間は処理水管42で接続し、逆洗タンク6と処理水貯槽16a間はオーバーフロー管38で接続した。処理水管42には吸引ポンプ44を設置した。また逆洗ポンプ45を設置し、逆洗タンク6内の濾過水を逆洗配管43によって前記精密濾過膜を逆洗できるようにした。
(Experimental ballast water production system)
The apparatus shown in FIG. 3 was used. The experimental ballast water production apparatus 20 is mainly composed of a hollow fiber membrane type microbial filtration device 4a, and a hollow fiber membrane module 7 “STELLAPORE SUR31534” (Mitsubishi) comprising a microfiltration membrane with a treatment capacity of 3 m 3 / hour in a treatment tank 8. What dipped Rayon) was used. The raw seawater tank 11a and the hollow fiber membrane type microbial filtration device 4a are connected by a pipe 21 (28), and the hollow fiber membrane type microbial filtration device 4a and the backwash tank 6 are connected by a treated water pipe 42 and backwashed. An overflow pipe 38 was connected between the tank 6 and the treated water storage tank 16a. A suction pump 44 was installed in the treated water pipe 42. Further, a backwash pump 45 was installed so that the filtered water in the backwash tank 6 could be backwashed with the backwash pipe 43.

(運転方法)
模擬ワンパス処理方法で行った。すなわち、原海水を中空糸膜型微生物濾過装置4aに3m/時の処理量で供給した。微生物除去工程においては、ブロワ−46からの空気を中空糸膜モジュール7の下部に設置したディストリビュータ41から微細な気泡としてバブリングして、中空糸膜表面に付着した微生物等を剥離しながら濾過を行った。また微生物除去工程15分に対して、逆洗工程1分とし、これを繰り返した。また、微生物が濃縮された廃液は、中空糸膜型微生物濾過装置4aの処理槽8の下部から適宜抜液した。
(how to drive)
The simulated one-pass processing method was used. That is, the raw seawater was supplied to the hollow fiber membrane type microbial filtration device 4a at a treatment rate of 3 m 3 / hour. In the microorganism removal step, air from the blower 46 is bubbled as fine bubbles from the distributor 41 installed in the lower part of the hollow fiber membrane module 7, and filtration is performed while removing microorganisms and the like adhering to the hollow fiber membrane surface. It was. Moreover, it was set as 1 minute of backwashing processes with respect to 15 minutes of microorganism removal processes, and this was repeated. Moreover, the waste liquid in which the microorganisms were concentrated was appropriately drained from the lower part of the treatment tank 8 of the hollow fiber membrane type microorganism filtration device 4a.

(微生物の測定方法)
大腸菌群は、BGLB培地(Brilliant Green Lactose Bile Broch)に試料を添加し、35℃で24時間培養した後、大腸菌群を計測した。
(Method for measuring microorganisms)
The coliform group was added to a BGLB medium (Brilliant Green Lactose Bile Broch) and cultured at 35 ° C. for 24 hours, and then the coliform group was counted.

(処理結果)
原海水中の大腸菌群数は3500個/100mlであったが、処理水に大腸菌群は検出されなかった。また処理水のn−ヘキサン抽出物は検出されず、濁度は2度以下であった。ただし濾過運転の初期における逆洗直後の所定流量での差圧は0.01MPa以下であったが、濾過運転170時間後における逆洗直後の差圧は0.045MPaであった。
(Processing result)
The number of coliforms in the raw seawater was 3500/100 ml, but no coliforms were detected in the treated water. Moreover, the n-hexane extract of the treated water was not detected, and the turbidity was 2 degrees or less. However, the differential pressure at a predetermined flow rate immediately after backwashing at the initial stage of the filtration operation was 0.01 MPa or less, but the differential pressure immediately after backwashing after 170 hours of filtration operation was 0.045 MPa.

実験例2
下記実験用バラスト水製造装置及び下記の運転条件で処理した以外は、実験例1と同様の方法で行った。
Experimental example 2
The same procedure as in Experimental Example 1 was performed, except that the treatment was performed under the following experimental ballast water production apparatus and the following operating conditions.

(実験用バラスト水製造装置)
図4に示す装置を用いた。図4の装置において図3の装置と同一構成要素には同一符号を付してその説明を省略し、異なる点について主に説明する。すなわち、図4の装置において、図3の装置と異なる点は、原海水タンク11aと中空糸膜型微生物濾過装置4a間に、処理能力3m/時の油水分離装置「ダイヤマルスRH−03」(三菱レイヨンエンジニアリング社製)5を配置した点にある。
(Experimental ballast water production system)
The apparatus shown in FIG. 4 was used. In the apparatus of FIG. 4, the same components as those of the apparatus of FIG. 3 are denoted by the same reference numerals, description thereof is omitted, and different points will be mainly described. That is, the apparatus of FIG. 4 is different from the apparatus of FIG. 3 in that an oil / water separator “Diamarus RH-03” having a processing capacity of 3 m 3 / hour is provided between the raw seawater tank 11a and the hollow fiber membrane type microorganism filtration apparatus 4a. (Mitsubishi Rayon Engineering Co., Ltd.) 5 is located.

(運転方法)
模擬ワンパス処理方法で行った。すなわち、原海水を中空糸膜型微生物濾過装置4aに3m/時の処理量で供給した。微生物除去工程においては、ブロワー41からの空気を中空糸膜モジュール7の下部に設置したディストリビュータ41から微細な気泡としてバブリングし、中空糸膜表面に付着した微生物等を剥離させながら、濾過を続けた。また、微生物除去工程15分に対して、逆洗工程1分とし、これを繰り返した。また、微生物が濃縮された廃液は、中空糸膜型微生物濾過装置4aの処理槽8の下部から適宜抜液した。
(how to drive)
The simulated one-pass processing method was used. That is, the raw seawater was supplied to the hollow fiber membrane type microbial filtration device 4a at a treatment rate of 3 m 3 / hour. In the microorganism removal step, air was blown as fine bubbles from the distributor 41 installed in the lower part of the hollow fiber membrane module 7 and filtration was continued while peeling microorganisms and the like adhering to the surface of the hollow fiber membrane. . Moreover, it was set as the back washing process 1 minute with respect to the microorganism removal process 15 minutes, and this was repeated. Moreover, the waste liquid in which the microorganisms were concentrated was appropriately drained from the lower part of the treatment tank 8 of the hollow fiber membrane type microorganism filtration device 4a.

(処理結果)
原海水中の大腸菌群数は3500個/100mlであったが、処理水に大腸菌群は検出されなかった。また処理水のn−ヘキサン抽出物は検出されず、濁度は2度以下であった。なお、濾過運転の初期における逆洗直後の所定流量での差圧は0.01MPa以下であり、濾過運転170時間後における逆洗直後の差圧も同様にして0.01MPa以下であり、原海水中の油分を予め油水分離装置で除去することにより、精密濾過膜の油分による汚染が効果的に防止できた。
(Processing result)
The number of coliforms in the raw seawater was 3500/100 ml, but no coliforms were detected in the treated water. Moreover, the n-hexane extract of the treated water was not detected, and the turbidity was 2 degrees or less. The differential pressure at a predetermined flow rate immediately after backwashing at the initial stage of the filtration operation is 0.01 MPa or less, and the differential pressure immediately after backwashing after 170 hours of filtration operation is similarly 0.01 MPa or less. The oil content in the microfiltration membrane was effectively prevented by removing the oil content in the oil / water separator in advance.

実験例3
浸漬型の中空糸膜型微生物濾過装置4aに代えて、加圧型の中空糸膜型微生物濾過装置(不図示)を用い、実験例1と同じように気泡による洗浄と定期的な逆洗工程を行った。但し、気泡による洗浄は、膜処理装置への通水を中断し、約5分間、膜の下部から空気を流入して得られる気泡によるバブリングを行った。なお、加圧型の中空糸膜型微生物濾過装置で用いた中空糸膜モジュールは、処理能力3m/時の精密濾過膜である「ステラポアG型UMF−2024WFA」3本(三菱レイヨン社製)を用いた。また、中空糸膜型微生物濾過装置の前段に、処理能力3m/時の油水分離装置「ダイヤマルスRH−03」を配置した。
Experimental example 3
Instead of the immersion type hollow fiber membrane type microbial filtration device 4a, a pressure type hollow fiber membrane type microbial filtration device (not shown) is used, and in the same manner as in Experimental Example 1, cleaning with bubbles and periodic backwashing steps are performed. went. However, the cleaning with bubbles was performed by bubbling with bubbles obtained by interrupting the water flow to the membrane treatment apparatus and injecting air from the lower part of the membrane for about 5 minutes. The hollow fiber membrane module used in the pressurization type hollow fiber membrane type microbial filtration apparatus is composed of three “Stelapore G type UMF-2024WFA” (manufactured by Mitsubishi Rayon Co., Ltd.), which is a microfiltration membrane with a processing capacity of 3 m 3 / hour. Using. In addition, an oil / water separator “Diamarus RH-03” having a treatment capacity of 3 m 3 / hour was disposed in the front stage of the hollow fiber membrane type microorganism filtration device.

(処理結果)
原海水中の大腸菌群数は3500個/100mlであったが、処理水に大腸菌群は検出されなかった。また処理水のn−ヘキサン抽出物は検出されず、濁度は2度以下であった。なお、精密濾膜の差圧データも実験例2と同様であった。
(Processing result)
The number of coliforms in the raw seawater was 3500/100 ml, but no coliforms were detected in the treated water. Moreover, the n-hexane extract of the treated water was not detected, and the turbidity was 2 degrees or less. The differential pressure data of the microfiltration membrane was the same as in Experimental Example 2.

各実施例に示すように、原海水タンク内に貯留された原海水をバラスト水製造装置で処理することにより、原海水中の大腸菌群が検出されない程度まで除去された。また中空糸膜型微生物濾過装置の前段に油水分離装置を設置することにより、精密濾過膜の油分による汚染を効果的に防止することができた。   As shown in each example, the raw seawater stored in the raw seawater tank was processed with a ballast water production apparatus, and thus the coliforms in the raw seawater were removed to the extent that they were not detected. In addition, by installing an oil-water separator in front of the hollow fiber membrane type microorganism filtration device, it was possible to effectively prevent contamination of the microfiltration membrane due to oil.

(A)は船体の船首船尾方向に直交する方向に沿って切断した模式断面図、(B)は船体の船首船尾方向に沿って切断した模式断面図である。(A) is the schematic cross section cut along the direction orthogonal to the bow stern direction of the hull, (B) is the schematic cross section cut along the bow stern direction of the hull. 本例の船舶搭載バラスト水製造装置のフロー図である。It is a flowchart of the ship mounted ballast water manufacturing apparatus of this example. 実験例1で使用した実験用バラスト水製造装置のフロー図である。It is a flowchart of the experimental ballast water manufacturing apparatus used in Experimental example 1. 実験例2で使用した実験用バラスト水製造装置のフロー図である。It is a flowchart of the experimental ballast water manufacturing apparatus used in Experimental example 2.

符号の説明Explanation of symbols

1 船舶(タンカーのバラスト構造)
2 バラスト水槽
4 微生物濾過膜装置
4a 中空糸膜型微生物濾過装置
5 油分吸着除去装置
6 逆洗タンク
7 中空糸膜モジュール
8 処理槽
10 船舶搭載バラスト水製造装置
11〜16 バラスト水槽
11a 原海水
20、30 実験用バラスト水製造装置
21〜26 海水供給管
31〜36 膜濾過水供給管
28 海水流入配管
38 膜濾過水流出配管
41 ディストリビュータ
43 逆洗配管
44 吸引ポンプ
45 逆洗ポンプ
46 ブロアー
1 Ship (ballast structure of tanker)
DESCRIPTION OF SYMBOLS 2 Ballast water tank 4 Microbial filtration membrane apparatus 4a Hollow fiber membrane type microorganism filtration apparatus 5 Oil content adsorption removal apparatus 6 Backwash tank 7 Hollow fiber membrane module 8 Treatment tank 10 Ship mounted ballast water production apparatus 11-16 Ballast water tank 11a Raw seawater 20, 30 Experimental Ballast Water Production Equipment 21-26 Seawater Supply Pipe 31-36 Membrane Filtration Water Supply Pipe 28 Seawater Inflow Pipe 38 Membrane Filtration Water Outflow Pipe 41 Distributor 43 Backwash Pipe 44 Suction Pump 45 Backwash Pump 46 Blower

Claims (9)

船舶に積載された海水を船舶上で微生物濾過膜に通すことにより海水中の微生物を除去する微生物除去工程と、逆洗により微生物濾過膜を洗浄する逆洗工程を有し、該微生物除去工程で得られる膜濾過水をバラスト水として用いることを特徴とするバラスト水の製造方法。   A microbial removal step of removing microorganisms in seawater by passing seawater loaded on the ship through a microbial filtration membrane on the vessel, and a backwashing step of washing the microbial filtration membrane by backwashing, A method for producing ballast water, wherein the membrane filtrate obtained is used as ballast water. 前記海水は船舶内の複数のバラスト水槽にそれぞれ積載されたものであって、微生物除去工程は、一のバラスト水槽の海水を微生物濾過膜に通し、得られた膜透過水を該一のバラスト水槽に戻す循環処理であって、これを他のバラスト水槽の海水についても順次行うことを特徴とする請求項1記載のバラスト水の製造方法。   The seawater is respectively loaded in a plurality of ballast tanks in a ship, and the microorganism removal step passes the seawater of one ballast tank through a microorganism filtration membrane, and uses the obtained membrane permeated water as the one ballast tank. The method for producing ballast water according to claim 1, wherein the processing is performed sequentially for seawater in other ballast water tanks. 前記海水は船舶内の複数のバラスト水槽の中、1つを空き水槽とし、他のバラスト水槽に積載されたものであって、微生物除去工程は、一のバラスト水槽の海水を微生物濾過膜に通し、得られた膜透過水を該空き水槽に供給するワンパス処理を行い、次いで他のバラスト水槽の海水を微生物濾過膜に通し、得られた膜透過水を空き水槽となった該一のバラスト水槽に供給するワンパス処理を行い、該ワンパス処理を順次行うことを特徴とする請求項1記載のバラスト水の製造方法。   The seawater is one of a plurality of ballast tanks in a ship, and one of the ballast tanks is loaded into another ballast tank, and the microorganism removal step passes the seawater of one ballast tank through a microorganism filtration membrane. The one ballast tank that performs the one-pass process of supplying the obtained membrane permeated water to the empty water tank, then passes the seawater of another ballast water tank through the microbial filtration membrane, and the obtained membrane permeated water becomes the empty water tank. The method for producing ballast water according to claim 1, wherein a one-pass process is performed, and the one-pass process is sequentially performed. 前記微生物濾過膜で処理する前に予め、少なくとも海水中の油分を除去することを特徴とする請求項1〜3のいずれか1項記載のバラスト水の製造方法。   The method for producing ballast water according to any one of claims 1 to 3, wherein at least oil in seawater is removed in advance before the treatment with the microorganism filtration membrane. 前記微生物濾過膜が中空糸膜であることを特徴とする請求項1〜4のいずれか1項記載のバラスト水の製造方法。   The said microbial filtration membrane is a hollow fiber membrane, The manufacturing method of the ballast water of any one of Claims 1-4 characterized by the above-mentioned. 前記海水中の油分を、疎水性吸着材で吸着除去することを特徴とする請求項1〜5のいずれか1項記載のバラスト水の製造方法。   The method for producing ballast water according to any one of claims 1 to 5, wherein oil in the seawater is adsorbed and removed with a hydrophobic adsorbent. 汲み上げられた海水を積載する複数のバラスト水槽と、該バラスト水槽に貯留された海水中の微生物を除去する微生物濾過膜装置と、該微生物濾過膜装置で得られる膜濾過水を貯留する逆洗用タンクと、それぞれのバラスト水槽と該微生物濾過膜装置を接続する海水供給管と、該逆洗用タンクと該それぞれのバラスト水槽を接続する膜濾過水供給管を備えることを特徴とする船舶搭載バラスト水製造装置。   A plurality of ballast water tanks loaded with pumped seawater, a microbial filtration membrane device for removing microorganisms in seawater stored in the ballast water tank, and a backwash for storing membrane filtered water obtained by the microbial filtration membrane device A ship-mounted ballast comprising a tank, a seawater supply pipe connecting each of the ballast water tanks and the microbial filtration membrane device, and a membrane filtered water supply pipe connecting the backwash tank and the respective ballast water tanks Water production equipment. 前記微生物濾過膜装置の前段で且つバラスト水槽の後段に、少なくとも海水中の油分を除去する油分吸着除去装置を設置することを特徴とする請求項7記載の船舶搭載バラスト水製造装置。   8. The ship-mounted ballast water producing apparatus according to claim 7, wherein an oil adsorption / removal device that removes at least oil in seawater is installed upstream of the microorganism filtration membrane device and downstream of the ballast water tank. 前記微生物濾過膜装置が、浸漬型中空糸膜装置又は加圧型中空糸膜装置であることを特徴とする請求項7又は8記載の船舶搭載バラスト水製造装置。








The ship-mounted ballast water production apparatus according to claim 7 or 8, wherein the microorganism filtration membrane device is an immersion type hollow fiber membrane device or a pressure type hollow fiber membrane device.








JP2004178351A 2004-06-16 2004-06-16 Method for preparing ballast water and apparatus for preparing ballast water to be loaded onto vessel Pending JP2006000728A (en)

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WO2011105260A1 (en) 2010-02-25 2011-09-01 住友電気工業株式会社 Device and method for treating ballast water for ship
WO2013125368A1 (en) 2012-02-24 2013-08-29 住友電気工業株式会社 System for treating ship ballast water
KR101585618B1 (en) * 2014-03-12 2016-01-14 김태분 Oil-water treating apparatus for foreign element removing
KR20170028993A (en) 2014-08-28 2017-03-14 스미토모덴키고교가부시키가이샤 Ballast water treatment device, and method for treating ballast water

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JP2000202247A (en) * 1999-01-12 2000-07-25 Kuraray Co Ltd Treatment of emulsion type oil-containing waste water and treating device
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JP2007229575A (en) * 2006-02-28 2007-09-13 Mitsubishi Heavy Ind Ltd Method and apparatus for detoxifying liquid, and ship provided with the apparatus
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Effective date: 20100804