JP2005503452A5 - - Google Patents
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- Publication number
- JP2005503452A5 JP2005503452A5 JP2002587483A JP2002587483A JP2005503452A5 JP 2005503452 A5 JP2005503452 A5 JP 2005503452A5 JP 2002587483 A JP2002587483 A JP 2002587483A JP 2002587483 A JP2002587483 A JP 2002587483A JP 2005503452 A5 JP2005503452 A5 JP 2005503452A5
- Authority
- JP
- Japan
- Prior art keywords
- block copolymer
- saturated
- block
- unsaturated
- hydrophobic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001400 block copolymer Polymers 0.000 claims description 20
- 125000003118 aryl group Chemical group 0.000 claims description 18
- 229920006395 saturated elastomer Polymers 0.000 claims description 18
- 230000002209 hydrophobic effect Effects 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 150000001336 alkenes Chemical class 0.000 claims description 10
- 125000002355 alkine group Chemical group 0.000 claims description 10
- 125000002252 acyl group Chemical group 0.000 claims description 8
- 125000000623 heterocyclic group Chemical group 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 4
- -1 thioether-thiones Substances 0.000 claims description 3
- BGPJLYIFDLICMR-UHFFFAOYSA-N 1,4,2,3-dioxadithiolan-5-one Chemical compound O=C1OSSO1 BGPJLYIFDLICMR-UHFFFAOYSA-N 0.000 claims description 2
- 125000004423 acyloxy group Chemical group 0.000 claims description 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 2
- 125000004414 alkyl thio group Chemical group 0.000 claims description 2
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000002243 precursor Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 7
- 239000012736 aqueous medium Substances 0.000 claims 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 4
- 239000003973 paint Substances 0.000 claims 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- 239000000080 wetting agent Substances 0.000 claims 3
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- 239000012459 cleaning agent Substances 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- 230000009477 glass transition Effects 0.000 claims 2
- 230000000873 masking effect Effects 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 2
- 150000003254 radicals Chemical class 0.000 claims 2
- 239000000243 solution Substances 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 claims 1
- 239000012988 Dithioester Substances 0.000 claims 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 claims 1
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 239000003599 detergent Substances 0.000 claims 1
- 229920000359 diblock copolymer Polymers 0.000 claims 1
- 239000012990 dithiocarbamate Substances 0.000 claims 1
- 150000004659 dithiocarbamates Chemical class 0.000 claims 1
- 125000005022 dithioester group Chemical group 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 230000007062 hydrolysis Effects 0.000 claims 1
- 238000006460 hydrolysis reaction Methods 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
- 229920000428 triblock copolymer Polymers 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000012991 xanthate Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28884401P | 2001-05-04 | 2001-05-04 | |
| US60/288,844 | 2001-05-04 | ||
| PCT/FR2002/001349 WO2002090409A2 (fr) | 2001-05-04 | 2002-04-19 | Copolymeres a blocs tensioactifs prepares par polymerisation radicalaire controlee |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005503452A JP2005503452A (ja) | 2005-02-03 |
| JP2005503452A5 true JP2005503452A5 (enExample) | 2006-06-15 |
| JP4744783B2 JP4744783B2 (ja) | 2011-08-10 |
Family
ID=23108901
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002587483A Expired - Lifetime JP4744783B2 (ja) | 2001-05-04 | 2002-04-19 | 制御されたラジカル重合によって造られる界面活性ブロックコポリマー |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US20020198347A1 (enExample) |
| EP (1) | EP1397403B1 (enExample) |
| JP (1) | JP4744783B2 (enExample) |
| AT (1) | ATE388970T1 (enExample) |
| DE (1) | DE60225550T2 (enExample) |
| WO (1) | WO2002090409A2 (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6716948B1 (en) | 1999-07-31 | 2004-04-06 | Symyx Technologies, Inc. | Controlled-architecture polymers and use thereof as separation media |
| US6855840B2 (en) | 2002-02-11 | 2005-02-15 | University Of Southern Mississippi | Chain transfer agents for raft polymerization in aqueous media |
| US6667376B2 (en) * | 2002-03-22 | 2003-12-23 | Symyx Technologies, Inc. | Control agents for living-type free radical polymerization and methods of polymerizing |
| MXPA05001005A (es) * | 2002-07-26 | 2005-05-16 | Atofina | Composicion adhesiva para un medio humedo, con base en copolimeros de bloqueo que comprenden por lo menos un bloque hidrofilo. |
| FR2848557B1 (fr) | 2002-12-13 | 2006-07-07 | Atofina | Copolymeres a gradient solubles ou du moins dispersibles dans l'eau comme dans les solvants organiques |
| JP4254292B2 (ja) * | 2003-03-24 | 2009-04-15 | 星光Ｐｍｃ株式会社 | 水性顔料分散剤およびその製造方法 |
| US6919409B2 (en) | 2003-06-26 | 2005-07-19 | Symyx Technologies, Inc. | Removal of the thiocarbonylthio or thiophosphorylthio end group of polymers and further functionalization thereof |
| US6762257B1 (en) * | 2003-05-05 | 2004-07-13 | 3M Innovative Properties Company | Azlactone chain transfer agents for radical polymerization |
| JP2005002325A (ja) * | 2003-05-19 | 2005-01-06 | Canon Inc | ポリマー、それを含有するポリマー含有組成物、インク組成物、該インク組成物を用いたインク付与方法および装置 |
| DE602004008468T2 (de) | 2003-06-26 | 2008-05-21 | Jsr Corp. | Photoresistzusammensetzungen |
| WO2005000924A1 (en) | 2003-06-26 | 2005-01-06 | Symyx Technologies, Inc. | Photoresist polymers |
| US7250475B2 (en) | 2003-06-26 | 2007-07-31 | Symyx Technologies, Inc. | Synthesis of photoresist polymers |
| US20090018270A1 (en) * | 2003-09-03 | 2009-01-15 | Regan Crooks | Copolymer having a controlled structure and use thereof |
| US7632905B2 (en) * | 2004-04-09 | 2009-12-15 | L'oreal S.A. | Block copolymer, composition comprising it and cosmetic treatment process |
| JP5113988B2 (ja) * | 2005-03-31 | 2013-01-09 | 株式会社日本触媒 | セメント混和剤用ポリカルボン酸系ポリマー |
| FR2885367B1 (fr) * | 2005-05-03 | 2007-07-27 | Rhodia Chimie Sa | Organosol stabilise par des polymeres sequences amphiphiles |
| DE602006006825D1 (de) * | 2006-08-17 | 2009-06-25 | Rhodia Operations | Blockcopolymere, Verfahren zu deren Herstellung und ihre Verwendung in Emulsionen |
| ES2563498T3 (es) | 2007-08-27 | 2016-03-15 | Borealis Technology Oy | Equipo y procedimiento para producir gránulos de polímero |
| FR2965564B1 (fr) * | 2010-09-30 | 2012-10-26 | Rhodia Operations | Preparation de polymeres hydrophiles de haute masse par polymerisation radicalaire controlee |
| FR2975100B1 (fr) * | 2011-05-13 | 2014-09-26 | Oreal | Polymere sequence comprenant de l'acrylate d'isobutyle et de l'acide acry-lique, composition cosmetique et procede de traitement |
| MX354132B (es) * | 2011-10-24 | 2018-02-14 | Rhodia Operations | Preparacion de los polimeros en bloques anfifilicos por medio de la polimerizacion micelar por radicales controlada. |
| FR2986234B1 (fr) * | 2012-01-31 | 2014-06-13 | Rhodia Operations | Stabilisants reactifs poly(n-vinyl lactame) vivants pour polymerisation en phase dispersee |
| FR2986235B1 (fr) * | 2012-01-31 | 2015-02-06 | Rhodia Operations | Stabilisants reactifs poly(n-vinyl lactame) vivants pour polymerisation en phase dispersee |
| JP6550908B2 (ja) * | 2015-05-08 | 2019-07-31 | 国立大学法人福井大学 | アルケニルエーテル系重合体の製造方法 |
| RU2632004C1 (ru) * | 2016-06-06 | 2017-10-02 | Федеральное государственное бюджетное учреждение науки Институт металлоорганической химии им. Г.А. Разуваева Российской академии наук (ИМХ РАН) | Способ получения коллоидного раствора узкодисперсного по молекулярной массе амфифильного блоксополимера бутилакрилата и акриловой кислоты с узким распределением мицелл по размеру |
| WO2019162805A1 (en) * | 2018-02-21 | 2019-08-29 | 3M Innovative Properties Company | Ketone-containing controlled radical initiators for polymerization reactions |
| WO2025205553A1 (ja) * | 2024-03-29 | 2025-10-02 | 富士フイルム株式会社 | 樹脂の製造方法、感活性光線性又は感放射線性樹脂組成物、感活性光線性又は感放射線性膜、パターン形成方法、及び電子デバイスの製造方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AUPM930394A0 (en) * | 1994-11-09 | 1994-12-01 | Commonwealth Scientific And Industrial Research Organisation | Block copolymer synthesis |
| FR2738573B1 (fr) * | 1995-09-08 | 1997-10-17 | Rhone Poulenc Chimie | Utilisation en tant qu'agents thermoepaississants de copolymeres multiblocs |
| DE19704714A1 (de) * | 1996-01-25 | 1997-07-31 | Basf Ag | Amphiphile Blockcopolymere |
| FR2764892B1 (fr) * | 1997-06-23 | 2000-03-03 | Rhodia Chimie Sa | Procede de synthese de polymeres a blocs |
| US6111025A (en) * | 1997-06-24 | 2000-08-29 | The Lubrizol Corporation | Block copolymer surfactants prepared by stabilized free-radical polymerization |
| DE19806853A1 (de) * | 1998-02-19 | 1999-09-02 | Basf Ag | Verfahren zur Herstellung von Polymeren aus N-Vinylverbindungen |
| FR2794463B1 (fr) * | 1999-06-04 | 2005-02-25 | Rhodia Chimie Sa | Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes |
| FR2794464B1 (fr) * | 1999-06-04 | 2005-03-04 | Rhodia Chimie Sa | Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee a l'aide de thioether-thiones |
| US6437040B2 (en) * | 1999-09-01 | 2002-08-20 | Rhodia Chimie | Water-soluble block copolymers comprising a hydrophilic block and a hydrophobic block |
| BR0013695A (pt) * | 1999-09-01 | 2002-07-16 | Rhodia Chimie Sa | Copolìmero em blocos, processos de preparação dos mesmos, e, de controle de equilìbrio hidrófilo/ hidrófobo, e utilização de copolìmeros em blocos |
| ATE275280T1 (de) * | 2000-03-02 | 2004-09-15 | Lucatron Ag | Elektronisch detektierbare resonanzetikette, insbesondere rfid-labels |
| US6507837B1 (en) * | 2000-06-08 | 2003-01-14 | Hyperphrase Technologies, Llc | Tiered and content based database searching |
| US6410005B1 (en) * | 2000-06-15 | 2002-06-25 | Pmd Holdings Corp. | Branched/block copolymers for treatment of keratinous substrates |
| BR0114371A (pt) * | 2000-10-03 | 2003-12-09 | Unilever Nv | Composição cosmética ou para o cuidado pessoal, método cosmético de tratamento de cabelo, e, uso de uma composição cosmética |
| EP1801129A3 (en) * | 2000-10-06 | 2008-02-20 | Carnegie-Mellon University | Polymerization process for ionic monomers |
| US6559233B2 (en) * | 2001-07-13 | 2003-05-06 | Rhodia Chimie | Composition comprising a copolymer at least two charged blocks and type of opposite charge |
-
2002
- 2002-04-19 WO PCT/FR2002/001349 patent/WO2002090409A2/fr not_active Ceased
- 2002-04-19 DE DE60225550T patent/DE60225550T2/de not_active Expired - Lifetime
- 2002-04-19 AT AT02727681T patent/ATE388970T1/de not_active IP Right Cessation
- 2002-04-19 JP JP2002587483A patent/JP4744783B2/ja not_active Expired - Lifetime
- 2002-04-19 EP EP02727681A patent/EP1397403B1/fr not_active Expired - Lifetime
- 2002-05-02 US US10/137,945 patent/US20020198347A1/en not_active Abandoned
-
2005
- 2005-02-01 US US11/047,940 patent/US20050131144A1/en not_active Abandoned