JP2005136149A - Method for manufacturing semiconductor device - Google Patents

Method for manufacturing semiconductor device Download PDF

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JP2005136149A
JP2005136149A JP2003370255A JP2003370255A JP2005136149A JP 2005136149 A JP2005136149 A JP 2005136149A JP 2003370255 A JP2003370255 A JP 2003370255A JP 2003370255 A JP2003370255 A JP 2003370255A JP 2005136149 A JP2005136149 A JP 2005136149A
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wafer
semiconductor device
hole
manufacturing
interface state
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JP4727138B2 (en
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Katsuya Kuniyoshi
克哉 国吉
Katsuyuki Takahashi
克行 高橋
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Nippon Precision Circuits Inc
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Nippon Precision Circuits Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for manufacturing a semiconductor device wherein the interface state of wafer surface can be sufficiently recovered and be made small. <P>SOLUTION: The method for manufacturing a semiconductor device includes a first step to make a hole 3 corresponding to the center of a respective chip formation part 2 on the rear side of a wafer 1, and a second step to apply hydrogen annealing. The bottom of the hole 3 is made close to the surface side of the wafer 1 forming a semiconductor device formation area, so that hydrogen enters the chip formation part 2 of the wafer 1 from its rear side. As a result, the interface state occuring in the semiconductor device formation area can be recovered and be made less. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、半導体素子の製造方法に関し、特に、ウェハの界面準位を回復して、少なくすることができる半導体素子の製造方法に関する。   The present invention relates to a method for manufacturing a semiconductor device, and more particularly to a method for manufacturing a semiconductor device that can recover and reduce the interface state of a wafer.

一般に、MOS型の半導体素子においては、シリコン基板等のシリコンと酸化シリコンとの界面に存在する準位、すなわち界面準位が、しきい値電圧の不安定化要因となったり、暗電流の発生原因になる。また、アモルファスシリコンで半導体素子を形成したものにおいては、シリコングレインの表面の界面準位が移動度を低下させる原因となる。このような事態を生じるのは、界面準位は各シリコンの持つ手のうちの少なくとも一つが空きとなり、そこにエレクトロンが入ってクーロン力によりキャリアのパスに影響を及ぼす可能性があるからである。この界面準位は一般に、1〜2×1010/cm程度までは許容されるが、それより多くなると許容されないものである。 In general, in a MOS type semiconductor device, a level existing at the interface between silicon and silicon oxide, such as a silicon substrate, that is, an interface level causes destabilization of the threshold voltage or generates dark current. Cause. In the case where the semiconductor element is formed of amorphous silicon, the interface state on the surface of the silicon grain causes the mobility to decrease. This happens because at least one of the silicon's hands is vacant, and electrons may enter the interface state and affect the carrier path due to Coulomb force. . In general, this interface state is allowed up to about 1 to 2 × 10 10 / cm 2 , but not more than that.

したがって、電気的特性に優れた半導体素子をウェハに形成するには、素子を形成する前に、ウェハ表面(半導体素子を形成する面)の界面準位を十分に回復し、少なくしておくことが必要である。そのために、界面準位、すなわち界面の活性なシリコンの手に、水素を結合することにより、水素とシリコンとを共有結合させ、キャリアのパスに影響を及ぼすクーロン力の発生をなくす技術として、水素雰囲気中でウェハに高温の熱処理を行う水素アニール法が知られている。
特開平8−78427号公報
Therefore, in order to form a semiconductor element having excellent electrical characteristics on a wafer, the interface state on the wafer surface (surface on which the semiconductor element is formed) must be sufficiently recovered and reduced before the element is formed. is required. For this purpose, hydrogen is bonded to the interface state, that is, the active silicon in the interface, to covalently bond hydrogen and silicon, thereby eliminating the generation of Coulomb force that affects the carrier path. A hydrogen annealing method is known in which high-temperature heat treatment is performed on a wafer in an atmosphere.
JP-A-8-78427

しかしながら、従来一般に行われている水素アニール法では、ウェハの表裏面が窒化シリコン膜や金属膜で覆われているような場合には、被膜によって水素の侵入が妨げられ、十分に界面準位を回復して、少なくすることができなかった。本発明は、このような従来の不都合を解消し、ウェハ表面の界面準位を十分に回復して、少なくすることができる半導体素子の製造方法を提供することを目的とする。   However, in the conventional hydrogen annealing method, when the front and back surfaces of the wafer are covered with a silicon nitride film or a metal film, the coating prevents hydrogen from penetrating, and the interface state is sufficiently increased. He was unable to recover and reduce. It is an object of the present invention to provide a method for manufacturing a semiconductor device that can eliminate such conventional disadvantages and sufficiently recover and reduce the interface state on the wafer surface.

この目的を達成するため、本発明の請求項1に係る半導体素子の製造方法は、ウェハの裏面側に、各チップ形成予定部分の一つずつに対応するよう、穴や溝などの凹部を形成する第1の工程と、水素アニールを施す第2の工程とからなるものである。前記凹部の深さは、ウェハの強度を損なわない厚さを残すように設定する。   In order to achieve this object, the semiconductor device manufacturing method according to claim 1 of the present invention forms recesses such as holes and grooves on the back side of the wafer so as to correspond to each of the chip formation scheduled portions. And a second step of performing hydrogen annealing. The depth of the recess is set so as to leave a thickness that does not impair the strength of the wafer.

同じく上記目的を達成するために、本発明の請求項2に係る半導体素子の製造方法は、ウェハの裏面側に、各チップ形成予定部分の中央部に対応するよう穴を形成する第1の工程と、水素アニールを施す第2の工程とからなるものである。   Similarly, in order to achieve the above object, a method of manufacturing a semiconductor device according to claim 2 of the present invention includes a first step of forming a hole on the back surface side of the wafer so as to correspond to the central portion of each chip formation scheduled portion. And a second step of performing hydrogen annealing.

本発明の請求項1に係る半導体素子の製造方法によれば、ウェハ裏面側に、各チップ形成予定部分の一つずつに対応するように設けた凹部から、水素が侵入することにより、半導体素子形成領域に生じている界面準位を十分に回復して、少なくすることができるという効果を奏する。   According to the method for manufacturing a semiconductor device according to claim 1 of the present invention, the hydrogen enters from the concave portion provided to correspond to each of the chip formation scheduled portions on the back surface side of the wafer. There is an effect that the interface states generated in the formation region can be sufficiently recovered and reduced.

本発明の請求項2に係る半導体素子の製造方法によれば、ウェハ裏面側に、各チップ形成予定部分の中央部に対応するよう設けた穴から、水素が侵入することにより、半導体素子形成領域に生じている界面準位を、より一層十分に回復して、少なくすることができるという効果を奏する。   According to the method for manufacturing a semiconductor device according to claim 2 of the present invention, the hydrogen enters from the hole provided on the back side of the wafer so as to correspond to the central portion of each chip formation scheduled portion. In this case, the interface state generated in the step can be more fully recovered and reduced.

以下、本発明の好適な実施形態を添付図面に基づいて説明する。はじめに、第1の工程として、図1及び図2に示すように、ウェハ1の裏面側に、各チップ形成予定部分2の中央部に対応するよう穴3を形成する。この穴3の形成は、通常のフォトリソグラフィーとエッチングとによって行うもので、穴3の断面形状は特に限定されない。   DESCRIPTION OF EXEMPLARY EMBODIMENTS Hereinafter, preferred embodiments of the invention will be described with reference to the accompanying drawings. First, as a first step, as shown in FIGS. 1 and 2, a hole 3 is formed on the back surface side of the wafer 1 so as to correspond to the central portion of each chip formation scheduled portion 2. The formation of the hole 3 is performed by ordinary photolithography and etching, and the cross-sectional shape of the hole 3 is not particularly limited.

各穴3の深さと断面の大きさは、ウェハ1の厚み及び各チップ形成予定部分2の大きさに応じて設定する。例えば、厚さ625μmのウェハ1から、縦横
1×1mmのチップを得る場合に、断面円形の穴3を形成するのであれば、各穴3の深さは400〜600μm程度、断面の最大径は300〜600μm程度が好適である。
The depth of each hole 3 and the size of the cross section are set according to the thickness of the wafer 1 and the size of each chip formation scheduled portion 2. For example, in the case of obtaining a chip of 1 × 1 mm in length and width from a wafer 1 having a thickness of 625 μm, if the holes 3 having a circular section are formed, the depth of each hole 3 is about 400 to 600 μm, and the maximum diameter of the section is About 300-600 micrometers is suitable.

次に、第2の工程として、通常の水素アニールを施す。この水素アニールは400〜450℃で0.5〜1時間行う。この際、穴3の底部が半導体形成領域を形成するウェハ1の表面側に近づくので、ウェハ1の各チップ形成予定部分2に対して、水素が裏面側から十分に侵入し、半導体素子形成領域に生じている界面準位を回復して、少なくすることができる。   Next, as a second step, normal hydrogen annealing is performed. This hydrogen annealing is performed at 400 to 450 ° C. for 0.5 to 1 hour. At this time, since the bottom of the hole 3 approaches the front surface side of the wafer 1 forming the semiconductor formation region, hydrogen sufficiently enters the chip formation scheduled portions 2 of the wafer 1 from the back surface side, and the semiconductor element formation region It is possible to recover and reduce the interface states generated in the layer.

なお、本発明は上述の実施形態に限定されるものではなく、例えば、穴3の断面形状は、円形のほか、多角形や楕円形などでもよい。また、穴3に換えて、溝を形成してもよい。   In addition, this invention is not limited to the above-mentioned embodiment, For example, the cross-sectional shape of the hole 3 may be a polygon, an ellipse, etc. other than circular. Further, a groove may be formed instead of the hole 3.

ウェハの裏面側を示す平面図。The top view which shows the back surface side of a wafer. 図1のA−A線断面図。AA sectional view taken on the line AA of FIG.

符号の説明Explanation of symbols

1 ウェハ
2 チップ形成予定部分
3 穴
1 Wafer 2 Chip formation planned part 3 Hole

Claims (2)

ウェハの裏面側に、各チップ形成予定部分に対応するよう凹部を形成する第1の工程と、水素アニールを施す第2の工程とからなることを特徴とする半導体素子の製造方法。 A method of manufacturing a semiconductor device, comprising: a first step of forming a recess on the back side of a wafer so as to correspond to each chip formation scheduled portion; and a second step of performing hydrogen annealing. ウェハの裏面側に、各チップ形成予定部分の中央部に対応するよう穴を形成する第1の工程と、水素アニールを施す第2の工程とからなることを特徴とする半導体素子の製造方法。 A method of manufacturing a semiconductor device, comprising: a first step of forming a hole on the back side of a wafer so as to correspond to a central portion of each chip formation scheduled portion; and a second step of performing hydrogen annealing.
JP2003370255A 2003-10-30 2003-10-30 Manufacturing method of semiconductor device Expired - Fee Related JP4727138B2 (en)

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JP4727138B2 JP4727138B2 (en) 2011-07-20

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01225130A (en) * 1988-03-04 1989-09-08 Fujitsu Ltd Manufacture of semiconductor device
JPH04287365A (en) * 1991-03-15 1992-10-12 Sony Corp Manufacture of semiconductor device
JPH0878427A (en) * 1994-09-08 1996-03-22 Toshiba Corp Semiconductor substrate and its manufacture
JP2000223674A (en) * 1998-11-27 2000-08-11 Nec Corp Fabrication of semiconductor integrated circuit device
JP2001244270A (en) * 2000-01-21 2001-09-07 Internatl Business Mach Corp <Ibm> Storage region and approach path for heavy hydrogen
JP2003303966A (en) * 2002-04-11 2003-10-24 Matsushita Electric Ind Co Ltd Semiconductor device and its manufacturing method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01225130A (en) * 1988-03-04 1989-09-08 Fujitsu Ltd Manufacture of semiconductor device
JPH04287365A (en) * 1991-03-15 1992-10-12 Sony Corp Manufacture of semiconductor device
JPH0878427A (en) * 1994-09-08 1996-03-22 Toshiba Corp Semiconductor substrate and its manufacture
JP2000223674A (en) * 1998-11-27 2000-08-11 Nec Corp Fabrication of semiconductor integrated circuit device
JP2001244270A (en) * 2000-01-21 2001-09-07 Internatl Business Mach Corp <Ibm> Storage region and approach path for heavy hydrogen
JP2003303966A (en) * 2002-04-11 2003-10-24 Matsushita Electric Ind Co Ltd Semiconductor device and its manufacturing method

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